200940023 九、發明說明： 【發明所屬之技術領域】 種包括該擦洗構件之清 本發明係關於一種擦洗構件及一200940023 IX. Description of the invention: [Technical field of the invention] The invention includes a scrubbing member and a cleaning member
潔物品Q 【先前技術】 包括由一或數種針織或編織紗製成的擦洗構件之洗滌產 品已被用於清洗盤子、平底銷、壺、玻璃器、 丹、水槽或其Cleaning Article Q [Prior Art] A washing product comprising a scrubbing member made of one or several knitted or woven yarns has been used for washing dishes, flat bottom pins, jugs, glassware, dan, sink or its
他廚房用品。此外，包括該擦洗構件及一吸水性構件諸如 聚胺甲酸酯泡棉之洗滌產品亦為吾人所知。 在清洗盤子或其他類似廚房（用品）表面時，消費者視包 沫為清潔能力的一項指標。同時，吾人期可輕易清除頑固 性污潰，例如食物污斑、皂垢或油污。 【發明内容】 本發明提供一種擦洗構件，其包括一底紗及一疏水性針 織再解織紗，其中該底紗與該疏水性針織再解織紗經編織 在一起以形成一由疏水性針織再解織紗製成之絨。此外， 本發明亦提供一種包括該擦洗構件及一吸水性構件之清潔 物品。 【實施方式】 本發明之該擦洗構件1包含一種底紗10及一疏水性針織 再解織紗12。該底紗10與該疏水性針織再解織紗12被編織 在一起，藉此在該擦洗構件之該表面上可形成由疏水性針 織再解織紗製成之絨。在一些實施例中，該擦洗構件可包 含一扁平紗14，且該扁平紗14可被編織入該底紗丨〇，藉此 136291.doc -6 - 200940023 在該擦洗構件之該表面上亦可形成由扁平紗14製成之絨。 本發明之該底紗1 〇包含一般用於擦洗產品或擦拭產品之 紗。該底紗10之實例性材料包括但不限於聚丙烯、聚對苯 一甲酸乙一醇醋（PET)、聚苯乙稀或尼龍。該底紗可為羊 毛紗。該底紗之總細度包含但不限於，例如約1〇分德士至 200分德士。該底紗1 〇可包含單纖維絲或多纖維絲。 本發明之該疏水性針織再解織紗12包含一針織再解織 (KdK)紗’其由疏水性紗’諸如聚丙婦、聚對苯二甲酸乙 瘳 二醇酯（PET)或聚苯乙烯製成。該KdK紗12為具有鬆軟質 感，且可採用已知的方法，例如在初期生產之後解開該針 織物來製備。若該KdK紗12在本發明之該擦洗構件丨之該 表面上形成絨，則其可形成三維結構。當該擦洗構件j與 清潔劑一起使用時，該三維結構亦可提供更多的泡沫。在 本發明中，在該擦洗構件1之該表面上形成由疏水性KdK 紗製成之絨’則可提供更多的泡沫。 ❹ 該KdK紗12之總細度可例如為但不限於約1〇分德士至約 1000分德士。該KdK紗12可包含單纖維絲或多纖維絲，例 如從1條纖維絲（1F)至約1〇〇條纖維絲（1〇〇F)。由該KdK紗 12製成之絨的高度不限於但可為約〇 ^ mm至約1〇瓜瓜。 本發明之該擦洗構件i可進一步包含一扁平紗14。該扁 平紗14包含但不限於一塑膠膜，諸如一由聚丙烯、ρΕτ或 聚苯乙烯製成之膜。該扁平紗14之示例性厚度可為約2〇 μχη至約50 μϋ1且該扁平紗14之寬度可為約〇 i〇mm至約1〇 〇 mm。若該扁平紗在該擦洗構件上形成絨，則該等絨之高 136291.doc 200940023 度可為約0.1 mm至約10 mm。該擦洗構件之每平方米之示 例性重量不限於，但可為約140克至約1400克。 可按如下步驟製備本發明之該擦洗構件1 :將該底紗1〇 與該疏水性KdK紗12編織在一起以在該擦洗構件1之該表 面上形成由疏水性KdK紗12製成之絨。若採用扁平紗μ， 可將該扁平紗14編織入該底紗1 〇，且在該擦洗構件1之該 表面上形成織。該普通編織方法’例如圓編針織，可被運 用以製備本發明之該擦洗構件1。在該擦洗構件1之該表面 ^ 上之由該KdK紗及/或該扁平紗製成之絨可為割絨。 在一實施例中，本發明之一清潔物品2包含本發明之該 擦洗構件1及一吸水性構件3。在一些實施例中，該清潔物 品之該吸水性構件3可被層壓至該擦洗構件丨，如圖2所 示，或被包含於由該擦洗構件丨製成之一袋中，如圖3所 示。該吸水性構件3包含但不限於例如天然海綿、纖維素 海綿、塑膠泡棉諸如聚胺曱酸酯泡棉、織物或非織物。 ❹ 可使用熟悉此技術者知曉之方法，例如黏結、超音波縫 合來層疊該擦洗構件1及該吸水性構件3進而製備本發明之 該清潔物品2。或者’可將該吸水性構件3包含於由該擦洗 構件i製成之-袋中進而製備本發明之該清潔物品2。可使 用下列已知方法製備該袋：例如將藉由圓編針織製得的圓 柱形擦洗構件i之頂部與底部縫合或黏結。該袋 或開放式的。 本發明之該擦洗構件1或該清潔物品2可用於洗條、押 洗、擦拭或擦淨廚房用具。本發明之該擦洗構件!或該： 136291.doc 200940023 潔物品2可單獨使用，亦可與諸如液態、凝膠、粉末或固 態的洗滌劑或肥皂組合使用。本發明之該擦洗構件1或該 清潔物品2具有由疏水性KdK紗12製成的絨，所以若使用 該等洗滌劑或肥皂時可形成更多的泡沫。 在本說明書中，可用到以下縮寫· KdK : Knit de knit(針織再解織）；PET :聚對苯二曱酸乙二酯；pp :聚丙 烯。 實例 起泡測試 使用TERUMO公司的5 mL注射器（無針頭）將濃度為〇.075 mL/L(水）之 Jokinnodekiru JOY溶液（5 mL，日本 P&G之廚 房洗滌劑）注射入該樣品中。一垂直混合器（AS ONE出品之 RUD-101)被用於產生泡沫。該垂直混合器以36次/分之速 度運行20次。泡珠的量是確定的。表1中顯示該等結果。 皂垢清除測試 異丙醇的脂肪酸鈣分散液被均勻地塗散於一不銹鋼板 (JIS G4305 (SUS304) 2B)上。該乙醇在一熱板上被乾燥且 被加熱兩分鐘以產生一測試板。然後，所得到的每一樣品 藉由拖拉該樣品橫越一測試板同時施加130克拇指壓力來 刮擦該測試板。表1中顯示該等結果。 實例1 起泡測試之樣品 由TORAY公司之25 μιη厚的細切PET薄膜製成的具有 0.7575 mm寬度之扁平紗及由MITSUBISHI RAYON股份有 136291.doc 200940023 限公司之PP製成的具有330分德士/1 之KdK紗被編織入 由MITSUBISHI RAYON股份有限公司之羊毛PP製成的具 tHis kitchen supplies. Further, a washing product comprising the scouring member and a water absorbing member such as polyurethane foam is also known. When cleaning the surface of a dish or other similar kitchen (supply), the consumer sees the envelope as an indicator of the ability to clean. At the same time, it is easy to remove stubborn stains such as food stains, scum or oil. SUMMARY OF THE INVENTION The present invention provides a scrubbing member comprising a bottom yarn and a hydrophobic knitted re-woven yarn, wherein the ground yarn and the hydrophobic knitted re-woven yarn are woven together to form a hydrophobic knitted re-solution. Velvet made of woven yarn. Further, the present invention also provides a cleaning article comprising the scouring member and a water absorbing member. [Embodiment] The scouring member 1 of the present invention comprises a ground yarn 10 and a hydrophobic knitted re-woven yarn 12. The ground yarn 10 is woven with the hydrophobic knitted re-woven yarn 12, whereby a pile made of a hydrophobic needle-re-woven yarn can be formed on the surface of the scouring member. In some embodiments, the scrubbing member can comprise a flat yarn 14 and the flat yarn 14 can be woven into the bottom yarn loop, whereby 136291.doc -6 - 200940023 can also be on the surface of the scrubbing member. The pile made of the flat yarn 14 is formed. The base yarn 1 of the present invention comprises yarns which are generally used for scrubbing products or wiping products. Exemplary materials for the ground yarn 10 include, but are not limited to, polypropylene, polyethylene terephthalate (PET), polystyrene or nylon. The ground yarn can be a sheep yarn. The total fineness of the ground yarn includes, but is not limited to, for example, about 1 to about 200 cents. The ground yarn 1 〇 may comprise a monofilament or a multifilament. The hydrophobic knitted re-twisted yarn 12 of the present invention comprises a knitted re-knitted (KdK) yarn which is made of a hydrophobic yarn such as polypropylene, polyethylene terephthalate (PET) or polystyrene. to make. The KdK yarn 12 has a soft texture and can be prepared by a known method such as unwinding the needle fabric after initial production. If the KdK yarn 12 is formed into a pile on the surface of the scouring member 本 of the present invention, it can form a three-dimensional structure. The three-dimensional structure also provides more foam when the scrubbing member j is used with a cleaning agent. In the present invention, the formation of the velvet made of hydrophobic KdK yarn on the surface of the scouring member 1 provides more foam.总 The total fineness of the KdK yarn 12 can be, for example, but not limited to, about 1 to about 1000 decibels. The KdK yarn 12 may comprise a monofilament or a multifilament, for example, from 1 filament (1F) to about 1 filament (1〇〇F). The height of the pile made of the KdK yarn 12 is not limited to but may be from about 〇 ^ mm to about 1 〇. The scrubbing member i of the present invention may further comprise a flat yarn 14. The flat yarn 14 includes, but is not limited to, a plastic film such as a film made of polypropylene, ρΕτ or polystyrene. An exemplary thickness of the flat yarn 14 can range from about 2 〇 μχη to about 50 μϋ1 and the width of the flat yarn 14 can range from about 〇i〇mm to about 1〇 〇 mm. If the flat yarn forms a pile on the scrubbing member, the height of the pile may be from about 0.1 mm to about 10 mm. The exemplary weight per square meter of the scouring member is not limited, but may range from about 140 grams to about 1400 grams. The scouring member 1 of the present invention can be prepared by weaving the base yarn 1 〇 with the hydrophobic KdK yarn 12 to form a velvet made of the hydrophobic KdK yarn 12 on the surface of the scouring member 1 . If a flat yarn μ is used, the flat yarn 14 can be woven into the base yarn 1 〇, and a woven fabric is formed on the surface of the scouring member 1. This conventional weaving method, such as circular knitting, can be used to prepare the scouring member 1 of the present invention. The pile made of the KdK yarn and/or the flat yarn on the surface ^ of the scouring member 1 may be cut pile. In one embodiment, a cleaning article 2 of the present invention comprises the scouring member 1 and a water absorbing member 3 of the present invention. In some embodiments, the water absorbing member 3 of the cleaning article can be laminated to the scouring member 丨, as shown in FIG. 2, or included in a bag made of the scouring member, as shown in FIG. Shown. The water absorbing member 3 includes, but is not limited to, for example, a natural sponge, a cellulose sponge, a plastic foam such as a polyurethane foam, a woven fabric or a non-woven fabric. ❹ The cleaning member 2 of the present invention can be prepared by laminating the scouring member 1 and the water absorbing member 3 by a method known to those skilled in the art, such as bonding and ultrasonic stitching. Alternatively, the water absorbing member 3 may be contained in a bag made of the scouring member i to prepare the cleaning article 2 of the present invention. The bag can be prepared by the following known methods: for example, the top and bottom of the cylindrical scrubbing member i obtained by circular knitting are sewn or bonded. The bag is either open or open. The scouring member 1 or the cleaning article 2 of the present invention can be used for washing, rinsing, wiping or wiping kitchen utensils. The scouring member of the present invention! or the: 136291.doc 200940023 The cleaning article 2 can be used alone or in combination with a detergent or soap such as a liquid, gel, powder or solid. The scouring member 1 or the cleaning article 2 of the present invention has velvet made of the hydrophobic KdK yarn 12, so that more foam can be formed if the detergent or soap is used. In the present specification, the following abbreviations may be used: KdK: Knit de knit (knit re-weaving); PET: polyethylene terephthalate; pp: polypropylene. Example Foaming test A Jokinnodekiru JOY solution (5 mL, Japanese P&G kitchen detergent) having a concentration of 075.075 mL/L (water) was injected into the sample using a TERUMO 5 mL syringe (without needle). A vertical mixer (RUD-101 from AS ONE) was used to create the foam. The vertical mixer was run 20 times at 36 times per minute. The amount of beads is determined. These results are shown in Table 1. Scum Cleansing Test The fatty acid calcium dispersion of isopropyl alcohol was uniformly spread on a stainless steel plate (JIS G4305 (SUS304) 2B). The ethanol was dried on a hot plate and heated for two minutes to produce a test panel. Each of the resulting samples was then scratched by pulling the sample across a test panel while applying 130 grams of thumb pressure. These results are shown in Table 1. Example 1 A sample of the foaming test was made of TORAY's 25 μιη thick fine-cut PET film with a flat yarn of 0.7575 mm width and a PP of MITSUBISHI RAYON Co., Ltd. having 136291.doc 200940023 limited company. KdK yarn of 士/1 is woven into the wool made of MITSUBISHI RAYON Co., Ltd.
有84分德士/30F之底紗中，以便形成具有由該扁平紗與該 KdK紗製成之絨的擦洗構件。將所獲得之擦洗構件進行衝 壓，以產生一直徑為60 mm之圓形擦洗構件樣品。接著， 藉由超音波焊接（鈐木汽車公司出品之鈴木塑膠焊接機 BELFA SUW-0150)將該等樣品中之該二者變成雙層的以產 生一圓形背對背樣品。將由Achilles公司出品之聚胺曱酸 酯泡棉進行衝壓，以形成一直徑為6〇 mm且厚度為22 mm 之圓形泡棉樣品。弄濕該泡棉樣品並用手擠壓，然後放入 一 300 mL燒杯中。該圓形背對背樣品被放置於該圓形泡棉 樣品上且用於該起泡測試中。被測試的樣品有三個，且表 1中顯示了該三個之平均值。 用於皂垢清除測試之樣品 將上述獲得之擦洗構件切割成長度4咖、寬度2⑽，以 形成一用於該皂垢清除測試之樣品。 實例2 起泡測試之樣品 使用如實例1之相同樣品，只是在一洗«器（由東芝公 =之=_“一—))中清洗該樣品之棒 ΓΓ 紗上之表錢理。職《器清洗了/ 分鐘，用水沖洗兩次且旋乾 v 個，且表！中顯示了該三個之平=。。被測試的樣品有三 用於息垢清除測試之樣品 136291.doc 200940023 將上述獲得之擦洗構件切割成長度4 cm、寬度2 cm ’以 便形成一用於該皂垢清除測試之樣品。 比較實例1 用於起泡測試之樣品There is a 84 dtex/30F bottom yarn to form a scrubbing member having the pile made of the flat yarn and the KdK yarn. The obtained scrubbing member was pressed to produce a sample of a circular scrubbing member having a diameter of 60 mm. Next, the two of the samples were double-layered by ultrasonic welding (Suzuki Plastic Welding Machine BELFA SUW-0150 by Tochigi Motor Co., Ltd.) to produce a round back-to-back sample. A polyamine phthalate foam from Achilles was punched to form a circular foam sample having a diameter of 6 mm and a thickness of 22 mm. The foam sample was wetted and squeezed by hand and placed in a 300 mL beaker. The round back-to-back sample was placed on the circular foam sample and used in the foaming test. There are three samples tested, and the average of the three is shown in Table 1. Sample for Soda Removal Test The scouring member obtained above was cut into a length of 4 coffees and a width of 2 (10) to form a sample for the scum cleaning test. Example 2 A sample of the foaming test was carried out using the same sample as in Example 1, except that the sample of the sample was cleaned in a washing machine (by Toshiba = = "1"). The device was cleaned for 2 minutes, rinsed twice with water and spun dry v, and the three levels are shown in Table!. The sample to be tested has three samples for the smear removal test 136291.doc 200940023 The scrubbing member was cut into a length of 4 cm and a width of 2 cm' to form a sample for the soapstick removal test. Comparative Example 1 Sample for the foaming test
Aisen Kougyou有限公司出品之Awadatsu-海綿網KS303 之外網之一圓形背對背樣品是採用如實例1同樣之方式製 備而得的。該外網包含尼龍底紗及尼龍絨，但形成絨之該 尼龍並非針織再解織紗。該圓形泡棉樣品被製備、浸濕、 擠壓並放置於一燒杯中。然後，以如實例1之同樣方式將 該獲得的圓形背對背樣品放置於該泡棉樣品上。被測試的 樣品有三個，且表i中顯示了該三個之平均值。 用於皂垢清除測試之樣品 KS303之外網被切割成長度4 cm、寬度2 cm，以便形成 一用於該皂垢清除測試之樣品。 比較實例2 用於起泡測試之樣品A round back-to-back sample of Awadatsu-Sponge Net KS303 from Aisen Kougyou Co., Ltd. was prepared in the same manner as in Example 1. The outer web comprises a nylon ground yarn and nylon velvet, but the nylon forming the velvet is not a knitted re-twisted yarn. The circular foam sample was prepared, wetted, extruded and placed in a beaker. Then, the obtained round back-to-back sample was placed on the foam sample in the same manner as in Example 1. There are three samples tested, and the average of the three is shown in Table i. Sample for the scum cleaning test The outer mesh of the KS303 was cut into a length of 4 cm and a width of 2 cm to form a sample for the scum cleaning test. Comparative Example 2 Sample for foaming test
Surmtomo 3M有限公司之“以心-以如加混合網狀海綿之 外網之-圓形背對背樣品是採用如實例！之同樣的方式製 備而得的。該外網是-均勾編織且由無絨之腈綸針織物及 PET製成之針織物。該圓形泡棉樣品被製備、浸濕、擠壓 並放置於-燒杯中H以如實⑴之同樣的方式將該 獲得的圓形背對背樣品放置於該泡棉樣品上。被測試的樣 品有三個，且表1中顯示了該三個之平均值。 用於皂垢清除測試之樣品 136291.doc •11· 200940023Surmtomo 3M Co., Ltd. "The heart - in the case of a mixed mesh sponge - round back-to-back sample is prepared in the same way as the example! The outer net is - evenly woven and no Knitted acrylic knit fabric and knitted fabric made of PET. The circular foam sample was prepared, wetted, extruded and placed in a beaker. H was placed in the same manner as in the case of (1). On the foam sample, there are three samples to be tested, and the average of the three is shown in Table 1. Sample for the scum cleaning test 136291.doc •11· 200940023
Scotch-Brite™混合網狀海綿之該外網被切割成長度4 em 寬度2 cm，以便形成一用於該皂垢清除測試之樣品。 比較實例3 用於起泡測試之樣品 使用如實例1之相同樣品，只是使用該羊毛pp紗代替由 PP製成的針織紗。被測試的樣品有三個，且表1中顯示了 該三個之平均值。 用於皂垢清除測試之樣品 ® 將上述獲得之擦洗構件切割成長度4 cm、寬度2 cm，以 便形成一用於該皂垢清除測試之樣品。 比較實例4 用於起泡測試之樣品 由TORAY公司之25 μιη厚的細切PET薄膜製成的具有 0.7575 mm寬度之扁平紗及由MITSUBISHI RAYON股份有 限公司之羊毛PP製成的具有84分德士/30F之PP紗被均勻地 ❹ 編織以形成一不具有絨之擦洗構件。該針織物結構與比較 實例2中之擦洗構件之結構相同。該圓形泡棉樣品被製 備、次濕、擠壓及放置於一燒杯中。然後，以與實例j相 同之方式將該獲得的圓形背對背樣品放置於該泡棉樣品 上。被測忒的樣品有三個，且表1中顯示了該三個之平均 值。 用於皂垢清除測試之樣品 將上述獲得之擦洗構件切割成長度4 cm、寬度2 cm，以 便形成一用於該皂垢清除測試之樣品。 136291.doc •12- 200940023 表1 起泡測試 皂垢清除測試 實例1 3 ++ 實例2 3 ++ 比較實例1 1 + 比較實例2 1 ++ 比較實例3 2.67 + 比較實例4 2 ++ φ 起泡測試 3 :產生多於150 mL的泡沫 2 :產生多於100 mL而少於150 mL的泡泳 1 :產生少於100 mL的泡泳 皂垢清除測試 ++:清除超過10°/。之測試板的表面積（垢 + :清除少於10%之測試板的表面積（垢）。 【圖式簡單說明】 圖1為顯示本發明之該擦洗構件之一實施例之視圖。 圖2為顯示一清潔物品之一實施例之視圖。 圖3為顯示一包括一由該擦洗構件所製成的一袋之清潔 物品的另一實施例之視圖。 【主要元件符號說明】 1 擦洗構件 2 清潔物品 3 吸水構件 136291.doc -13- 200940023 ίο 12 14 底紗 針織再解織紗 扁平紗 ❹ 參 136291.doc -14-The outer web of the Scotch-BriteTM hybrid mesh sponge was cut to a length of 4 em width of 2 cm to form a sample for the soapstick removal test. Comparative Example 3 Sample for the foaming test The same sample as in Example 1 was used except that the wool pp yarn was used instead of the knitting yarn made of PP. There are three samples tested, and the average of the three is shown in Table 1. Sample for Soda Cleanup Test ® The scrubbing member obtained above was cut to a length of 4 cm and a width of 2 cm to form a sample for the scum cleaning test. Comparative Example 4 Samples for the foaming test A flat yarn of 0.7575 mm width made of TORAY's 25 μm thick fine-cut PET film and a wool of PP of MITSUBISHI RAYON Co., Ltd. The /30F PP yarn is evenly woven to form a scouring member without velvet. The knitted fabric structure was the same as that of the scrubbing member of Comparative Example 2. The circular foam sample was prepared, wetted, extruded and placed in a beaker. Then, the obtained round back-to-back sample was placed on the foam sample in the same manner as in Example j. There are three samples to be tested, and the average of the three is shown in Table 1. Sample for the scum cleaning test The scouring member obtained above was cut into a length of 4 cm and a width of 2 cm to form a sample for the scum cleaning test. 136291.doc •12- 200940023 Table 1 Foaming Test Scum Cleanup Test Example 1 3 ++ Example 2 3 ++ Comparative Example 1 1 + Comparative Example 2 1 ++ Comparative Example 3 2.67 + Comparative Example 4 2 ++ φ Bubble Test 3: Produce more than 150 mL of foam 2: Produce more than 100 mL and less than 150 mL of Bubble 1 : Produce less than 100 mL of smear cleansing test ++: Clear more than 10°/. The surface area of the test plate (scale +: clears the surface area (scale) of the test plate of less than 10%. [Schematic description of the drawings] Fig. 1 is a view showing an embodiment of the scouring member of the present invention. Figure 1 is a view showing another embodiment of a cleaning article including a bag made of the scouring member. [Main component symbol description] 1 scouring member 2 cleaning article 3 Water absorbing member 136291.doc -13- 200940023 ίο 12 14 Underlay knitting and woven yarn flat yarn ❹ 136291.doc -14-