TW200923450A - Light guide, method for manufacturing the same, and surface light source device having light guide - Google Patents
Light guide, method for manufacturing the same, and surface light source device having light guide Download PDFInfo
- Publication number
- TW200923450A TW200923450A TW97140051A TW97140051A TW200923450A TW 200923450 A TW200923450 A TW 200923450A TW 97140051 A TW97140051 A TW 97140051A TW 97140051 A TW97140051 A TW 97140051A TW 200923450 A TW200923450 A TW 200923450A
- Authority
- TW
- Taiwan
- Prior art keywords
- light
- photocurable resin
- sheet
- layer
- guiding member
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 18
- 238000004519 manufacturing process Methods 0.000 title claims description 13
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- -1 methyl enoate Chemical compound 0.000 claims description 7
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 claims description 2
- 238000000016 photochemical curing Methods 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
- ZXPNCBRARAKXEC-UHFFFAOYSA-N C1(CCCCC1)C1=C(C(C2=CC3=CC=CC=C3C2=C1)=O)C1=CC=CC=C1 Chemical compound C1(CCCCC1)C1=C(C(C2=CC3=CC=CC=C3C2=C1)=O)C1=CC=CC=C1 ZXPNCBRARAKXEC-UHFFFAOYSA-N 0.000 claims 1
- RWMLVMBSSADKRA-UHFFFAOYSA-L bismuth(2+);diacetate Chemical compound [Bi+2].CC([O-])=O.CC([O-])=O RWMLVMBSSADKRA-UHFFFAOYSA-L 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
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- OVUMARHRUFUFSP-UHFFFAOYSA-N ethane-1,2-diol;prop-2-enoic acid Chemical compound OCCO.OC(=O)C=C.OC(=O)C=C OVUMARHRUFUFSP-UHFFFAOYSA-N 0.000 claims 1
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- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims 1
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- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 description 6
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- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
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- 229910001507 metal halide Inorganic materials 0.000 description 4
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
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- 239000003999 initiator Substances 0.000 description 3
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 3
- 239000002964 rayon Substances 0.000 description 3
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- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 2
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
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- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
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- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 description 1
- FGLXTRRGELKYNO-UHFFFAOYSA-N 4-hydroxy-2-methylidenepentanoic acid Chemical compound CC(O)CC(=C)C(O)=O FGLXTRRGELKYNO-UHFFFAOYSA-N 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
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- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
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- 241001328813 Methles Species 0.000 description 1
- VAYJHNINWKKBJU-UHFFFAOYSA-N OC=1C(=C(C(C2=CC3=CC=CC=C3C12)=O)C1=CC=CC=C1)C1CCCCC1 Chemical compound OC=1C(=C(C(C2=CC3=CC=CC=C3C12)=O)C1=CC=CC=C1)C1CCCCC1 VAYJHNINWKKBJU-UHFFFAOYSA-N 0.000 description 1
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- 230000015572 biosynthetic process Effects 0.000 description 1
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- WKAYRWBOFSKJPB-UHFFFAOYSA-N ethyl carbamate prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCOC(N)=O WKAYRWBOFSKJPB-UHFFFAOYSA-N 0.000 description 1
- VLTICMVRVQWWIQ-UHFFFAOYSA-N ethyl carbamate;phthalic acid Chemical compound CCOC(N)=O.OC(=O)C1=CC=CC=C1C(O)=O VLTICMVRVQWWIQ-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
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- 230000005499 meniscus Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- YKWNDAOEJQMLGH-UHFFFAOYSA-N phenyl 2,2-diphenylacetate Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)C(=O)OC1=CC=CC=C1 YKWNDAOEJQMLGH-UHFFFAOYSA-N 0.000 description 1
- AHYFSRXBEJICKT-UHFFFAOYSA-N phthalic acid;prop-2-enamide Chemical compound NC(=O)C=C.OC(=O)C1=CC=CC=C1C(O)=O AHYFSRXBEJICKT-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
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- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
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- 239000007921 spray Substances 0.000 description 1
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- 238000001721 transfer moulding Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0065—Manufacturing aspects; Material aspects
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0033—Means for improving the coupling-out of light from the light guide
- G02B6/0035—Means for improving the coupling-out of light from the light guide provided on the surface of the light guide or in the bulk of it
- G02B6/004—Scattering dots or dot-like elements, e.g. microbeads, scattering particles, nanoparticles
- G02B6/0043—Scattering dots or dot-like elements, e.g. microbeads, scattering particles, nanoparticles provided on the surface of the light guide
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0033—Means for improving the coupling-out of light from the light guide
- G02B6/005—Means for improving the coupling-out of light from the light guide provided by one optical element, or plurality thereof, placed on the light output side of the light guide
- G02B6/0053—Prismatic sheet or layer; Brightness enhancement element, sheet or layer
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Planar Illumination Modules (AREA)
- Light Guides In General And Applications Therefor (AREA)
- Optical Elements Other Than Lenses (AREA)
Abstract
Description
九、發明說明: 【發明所屬之技術 本發明是關於—種 光源而使用的面光源爭;f成可作為液晶顯示裝置的背 -種該導光部材的製造言較好的 導光部材’進而關於 光源裝置。 去以及—種使用該導光部材的面 【先前技術】 在作為液晶顯示骏 ^ 置 中,使用矩形狀的導光罝的背光源而使用的面光源裝一 端面,沿著該光入射妒=材的至少1個端面來作為光入射 者棒狀的一次光源,S而配置直管型螢光燈等的線狀或 的光入射端面導入$兮、..該一次光源發出的光從導光部材 導光部材的兩個主面2光部材的内部,使該光從作為該 從導光部材的光出射面:::二光出射面而出射。為了使 出射面法較_向,岐时稜鏡片材。補先 ^年來,為了降低電力消耗,正廣泛细發光二極體 (Light Emitting Diode ’ LED)等的點狀的燈以取代螢光 燈等的線狀或者棒狀的燈,來作為液晶顯示裝置的一次光 源。LED可實現小尺寸’對於使用如此的LED構成的面 光源裝置,要求進一步的薄型化。而且,隨著液晶顯示震 置的使用領域的擴大’對於小型的液晶顯示裝置,尤其^ 求面光源裝置的進一步的薄型化。 為了響應如此的要求,對於面光源裝置的導光部材, 200923450 口:步:f型化’且要求厚度小於等於左右 r哀刹」例於日本專利特開2005_228612號公報 獻1)記載有一種導光體,苴厚 :’。且於背面或/及表面形成有多個凹或二二 [專利文獻1]曰本專利特開2005_228612公報 丙稀s 利文獻1中記载的光學部材是由聚甲基 (polymethyl methacrylate ,ΡΜΜΑ) 斗構成’藉由對該透明材料進行射出成形或壓 而,述背面或/及表面的光控制部。因此,: =二而=也形成光控制部的微細的表面形狀。而 解、+ ^ #其他部材接觸而造賴傷的問題。為了 此的問題,考慮使料準確地形絲面形狀且高硬 度的級化性樹絲形絲面具有微細構造料光部材。 .古具;、:六2化性樹脂或多或少地在靠近紫外區域的短 ㈣。因此,當使用光硬化性樹脂 的著色匕4色:二ί:會在導光過程中出現被稱為黃變 的背光料=顯:晶顯示裝置 寸生降低,因此不佳。尤其當減薄 =部材的厚度在導辆程中光硬化性概層表面上 的王反射:人數變夕,容易引起著色。因此,薄型的導光部 ^中,尤其是對―—_課題 【發明内容】 本發明的一個目的在於解決如此的問題,提供一種容 200923450 適人靜面表 1傷,可抑制著色,且 適口用於面先源裝置的導光部材。 的在於提供—種如^月的另一目 之導光部材的面光源裝ΐ先梢的衣造方法以及使用如此 根據本H作為達成如上所述目的之 一 種導光備透光性片材以及透光性的光二 曰曰上u透光性片材具有第〗表面以及該 2表面’上述透光性的光硬化 ;於目 材的至少上述第】表面上。此導光㈣= 在丄严光硬化性樹腊層於表面具有凹凸構造,附著於 上=光性片材的第]表面上的上述光硬化性樹脂平 均厚度以及附著於上述透光性片材的第2表面^ 硬化性樹脂層的平均厚度的合計小於等於3〇㈣。^先 當第2表面上未附有上述光硬化性樹脂層時,广、: ^計是附著於第1表面上的上述光硬化性樹脂層的;^厚 於本發明的一態樣中,附著於上述透光性片材 表面上的魏性樹絲卩及_於上述 的第2表面上的上述光硬化性樹脂層中的至少— 厚度小於等於20 々的平均 ^發明的„態樣中,上述凹凸構造為粗輪 構造或者稜__構造。於本發明的—態#中 ) 上述透光性片材的第i表面上的光硬化性樹脂層的上 凸構造為粗糙面構造,附著於上述透光性片材的第2表面IX. Description of the Invention: [Technical Field of the Invention] The present invention relates to a surface light source used for a light source; f is a light guide member which can be used as a backlight of a liquid crystal display device. Regarding the light source device. And a surface using the light guiding member. [Prior Art] In the liquid crystal display, a surface light source used in a rectangular light guide backlight is used to mount an end surface along which the light is incident. At least one end surface of the material is used as a primary light source of a light incident person, and a linear or light incident end surface such as a straight tube type fluorescent lamp is disposed in S, and the light emitted from the primary light source is guided from the light guide. The inside of the two main surfaces 2 of the component light guiding member is emitted from the light emitting surface of the light guiding member: the two light emitting surface. In order to make the exit surface method more _, 岐 稜鏡 。 sheet. In order to reduce the power consumption, a dot-shaped lamp such as a Light Emitting Diode (LED) is used as a liquid crystal display device instead of a linear or rod-shaped lamp such as a fluorescent lamp. Primary light source. The LED can be realized in a small size. For a surface light source device using such an LED, further thinning is required. Further, as the field of use of the liquid crystal display is expanded, the size of the liquid crystal display device is further reduced in thickness. In order to respond to such a request, for the light guiding member of the surface light source device, 200923450: step: f-type 'and thickness is required to be equal to or less than the left and right r sorrow." Japanese Patent Laid-Open Publication No. 2005-228612 (1) describes a guide. Light body, thick and thick: '. Further, a plurality of concave or two-two are formed on the back surface or/and the surface. [PTL 1] The optical member described in the Japanese Patent Publication No. 2005-228612 is a polymethyl methacrylate (ΡΜΜΑ). The hopper constitutes a light control unit that describes the back surface or/and the surface by injection molding or pressing the transparent material. Therefore, :=2 and = also form a fine surface shape of the light control portion. And the solution, + ^ # other parts contact and damage. In order to solve this problem, it is considered that the graded dendritic filament surface which accurately shapes the surface of the filament and has a high hardness has a fine structure material member. . Ancient tools;,: hexa-2 resin is more or less short in the vicinity of the ultraviolet region (four). Therefore, when the color of the photocurable resin is used, the color of the color is 匕4: a backlight which is called yellowing appears in the light guiding process = display: the crystal display device is lowered, which is not preferable. In particular, when the thickness of the material is reduced, the thickness of the material is reflected by the king on the surface of the photohardenable layer in the conduction process: the number of people changes, and coloring is likely to occur. Therefore, in the thin light-guiding portion, especially for the "---the subject matter", an object of the present invention is to solve such a problem, and to provide a suitable environment for the surface of the 200923450, which can suppress coloration and is palatable. A light guiding member for a surface source device. Provided is a method for fabricating a surface light source of a light guide member of another type such as a month, and a light-transmitting sheet which is used according to the present H for achieving the above-mentioned purpose. The photo-transparent optically-transparent sheet has a first surface and a light-curing of the two surfaces 'the above-mentioned light transmissiveness; on at least the first surface of the target. The light guide (4) = has an uneven structure on the surface of the sturdy photo-curable wax layer, and has an average thickness of the photocurable resin adhered to the surface of the upper surface of the optical sheet and adheres to the light-transmissive sheet The second surface ^ The total thickness of the curable resin layer is equal to or less than 3 〇 (four). When the photocurable resin layer is not attached to the second surface, the film is adhered to the photocurable resin layer on the first surface, and is thicker than an aspect of the present invention. In the above-described aspect of the invention, at least the thickness of the above-mentioned photocurable resin layer on the surface of the above-mentioned light-transmissive sheet is less than or equal to 20 々. The concavo-convex structure is a rough wheel structure or a rib structure. The epitaxial structure of the photocurable resin layer on the i-th surface of the light-transmitting sheet is a rough surface structure, and is attached to the above-mentioned Second surface of the light transmissive sheet
C ί j 200923450 上的光,化性樹脂層的上述凹凸構造為棱鏡列排列構造。 於么明的-態樣中,上述透光性片材的厚度為2⑻ 二二二°於本發明的樣中’上述透光性片材沿著 其表面的农大尺寸小於等於IQem,厚度為刚〜㈣。 匕,日^明的—恶樣中,構成上述光硬化性樹脂層的樹 脂混5物令,樹脂硬化物的】咖厚的γι值小於等於2 〇。 於明?―祕巾,構成上述光硬化性樹脂層的樹脂主 成为中,树脂硬化物的2 mm厚的YI值小於等於2〇,且 以60°C進行500小時的熱處理後的γι㈣增加小於等於 ϋΓίΓ月的一態樣中,構成上述光硬化性樹脂層的樹 月曰犯σ物中,樹脂硬化物的1〇 mm厚的γι值小於等於 3.0/且以60¾進行5〇〇小時的熱處理後的γι值的增加小 於等於0.5。 於本發明的—態樣中,上述光硬化性樹脂層含有乙二 酸醋、已二醇二丙_®旨、Ε〇改質氫化魏A 丁二醇二甲基丙軸、丁二醇二丙稀酸醋、 新戍一私—丙稀酸西旨以及2邊基丙基丙稀酸自旨中的任一 個,以作為光硬化性樹脂的構成單位。於本發明的一能樣 中倾概是由實質上料絲基_脂構成。 ft的—11樣中’上述透光性片材是由實質上不 含有苯ί㈣樹脂構成。於本發_ —態樣中,上述透 片材的自由的殘留硫醇小於等於100重量解。於本 的-=中,上述透光性片材是由以聚甲基丙稀酸甲醋作 為主構成皁位的樹脂構成。於本發明的一態樣中,上述 200923450 光性片材包含第ι透光層以及第2透光層而構成,上述第 1透先層與土述光硬化性樹脂層接觸且厚度小於等於⑽ //m二上述第2透光層接合於上述第}透光層。於本發明 的悲松中,上述第i透光層包含丙稀酸醋與甲基丙稀酸 甲醋的共聚物’上述丙稀酸s旨具有以碳數Η 的羧基。 于工四日儿 而且,根據本發明,作為達成如上所述目的之方法, Ο Ο 提供一料光部材的製造方法,用於製造上述的導光部 ,。此製造方法的舰在於,利__出或者輯聚合 “製作上34透光性片材,於該透紐片材的至少上述第i 表面上塗佈光硬化性樹脂組成物,將购賴部材的轉印 面的形狀购至該光硬化倾驗成物上,以製作上述凹 凸構造,再使上述光硬化性樹脂組成物硬化,從而 述光硬化性樹脂層。 於本發明的-態樣中,上述光硬化性樹餘成物包含 L起始劑,該聚合起始綱丨分子構造_包含的苯環 的錄小於等於丨。於本發_—‘紐巾,上述光硬化性 Μ脂組成物中的上述聚合起始劑的濃度為請〜 於本發態樣中,上述聚合起始劑是〗♦基_環己 I笨基_曱_者2_勝2_?基]_笨基_丙垸小酮。於本 ^月的-態樣中’在上述光硬化性樹脂組成物的塗佈後, 直至使上述光硬化性樹驗成物硬化為止的期間内,以40 〜80度對塗佈有上述光硬化性樹脂組成物的透光 進行加熱處理。 200923450 而且,根據本發明,作太、去上、, 提供-種面光源裝置,c上所述目的之機構, 鄰接於該導絲料光部材; 在上述導光部材的透先性:;=7;欠=二以與附 性樹脂層相對向之方式而配置的偏紅件。述光硬化 於本發明的一態樣中,糾盆# t^ 脂層的上述凹凸二:C ί j 200923450 The above-mentioned uneven structure of the light-sensitive resin layer is a prism array structure. In the aspect of the invention, the thickness of the light-transmissive sheet is 2 (8) 222 ° in the sample of the present invention, 'the above-mentioned light-transmissive sheet has a size of less than or equal to IQem along the surface of the light-transmissive sheet, and the thickness is just ~ (four). In the case of the smear, the resin composition constituting the photocurable resin layer has a γι value of 2 〇 or less. In the resin of the photocurable resin layer, the YI value of the 2 mm thick of the cured resin is 2 小于 or less, and the γι (4) increase after heat treatment at 60 ° C for 500 hours is less than that. In one aspect of the ϋΓίΓ month, the 硬化ι value of the resin cured product having a thickness of 1 mm thick of 3.0 mm or less and 603 Γ 以 〇〇 〇〇 〇〇 603 603 603 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂The increase in the value of γι is less than or equal to 0.5. In the aspect of the invention, the photocurable resin layer contains oxalic acid vinegar, hexane dipropylene-based, hydrazine-modified hydrogenated Wei A butanediol dimethyl propane, butanediol Any of acrylic acid vinegar, chlorpyrifos-acrylic acid, and 2-hydroxypropyl acrylic acid is used as a constituent unit of the photocurable resin. In one aspect of the invention, it is composed of substantially filament-based fat. The above-mentioned light transmissive sheet of ft is composed of a resin which does not substantially contain benzoic acid. In the present invention, the free residual mercaptan of the above-mentioned sheet is less than or equal to 100 parts by weight. In the present invention, the above-mentioned light-transmitting sheet is composed of a resin having a polymethyl methacrylate methyl vinegar as a main constituent soap. In one aspect of the invention, the 200923450 optical sheet comprises a first light transmitting layer and a second light transmitting layer, and the first first layer is in contact with the photocurable resin layer and has a thickness of less than or equal to (10) //m 2 The second light transmissive layer is bonded to the first light transmissive layer. In the sorrow of the present invention, the ith light-transmissive layer contains a copolymer of acrylic acid vinegar and methyl methacrylate methyl vinegar. The above-mentioned acrylic acid s has a carboxyl group having a carbon number of Η. Further, according to the present invention, in accordance with the present invention, as a method for achieving the above object, a method for producing a light-emitting member for producing the above-described light guiding portion is provided. The ship of the manufacturing method consists in producing a 34-transparent sheet, coating a photocurable resin composition on at least the i-th surface of the through-sheet, and purchasing the sheet material. The shape of the transfer surface is purchased from the photo-curing composition to prepare the uneven structure, and the photocurable resin composition is cured to form a photocurable resin layer. In the aspect of the invention, The photocurable tree remainder comprises an L initiator, and the polymerization starting group molecular structure includes a benzene ring of less than or equal to 丨. In the present invention, the photocurable rouge composition The concentration of the above polymerization initiator in the present invention is the same as in the aspect of the invention, the above polymerization initiator is 〖 ♦ _ _ _ _ _ _ _ _ _ _ _ _ _ 2 2 2 2 2 2 2 2 2 2 In the case of the present invention, after the application of the photocurable resin composition, the coating is applied at 40 to 80 degrees until the photocurable resin composition is cured. The light-transmitting resin composition is light-transmitted and heat-treated. 200923450 Moreover, according to the present invention, Too, go up, provide a kind of surface light source device, the mechanism for the purpose of c, adjacent to the light guide member; the transparency of the light guide member:; = 7; The reddish member is disposed in a manner corresponding to the resin layer. The light hardening is described in one aspect of the present invention, and the above-mentioned unevenness of the grease layer is:
^且錢硬化鋪m述凹凸構造為稜鏡列排列構 而、明的—態'樣中,以來自上述偏光元件的出射光 的鱼^、f。座‘的χ值以及y值的相對於上述導光部材内 距的導光距離的變化率的至少—方小於等 於 0.0008/cin。 根據如上所述的本發明,藉由使附著於透光性片材的 表面上^硬化性翻層的平均厚度的合計小於等於30 = m、,可提供一種容易準確地形成表面形狀,表面難以劃 知,並且可抑制著色,且適合用於面光源裝置的導光部材。 為讓本發明之上述和其他目的、特徵和優點能更明顯 易懂,下文特舉實施例,並配合所附圖式,作詳細說明如 下。 【實施方式】 以下’—邊參照圖式一邊對本發明的導光部材、其製 造方法以及使用該部材與方法的面光源裝置的實施形態。 200923450 圖1 (a)、圖1 (b)是表示本發明的導光部材的實施 形悲的示思性剖面圖。圖1 (a)與圖1 (b)表示相互正交 的縱剖面。 導光部材具備透光性片材2以及透光性的光硬化性樹 脂層4、6三透光性片材2具有第1表面(圖中的上表面) 21以及孩第1表面21的相反侧的第2表面(圖中的下表 面)22 ° 一個光硬化性樹脂層4附著於透光性片材的第1 η^ And the money hardening is described as a sinuous arrangement, and in the "state", the fish ^, f from the light emitted from the polarizing element. The χ value of the ‘ and the rate of change of the y value relative to the light guiding distance of the inner distance of the light guiding member are less than or equal to 0.0008/cin. According to the invention as described above, it is possible to easily and accurately form the surface shape by making the total thickness of the hardened layer which is adhered to the surface of the light-transmitting sheet less than or equal to 30 = m, and it is difficult to form the surface. It is known and can suppress coloring, and is suitable for use as a light guiding member of a surface light source device. The above and other objects, features and advantages of the present invention will become more <RTIgt; [Embodiment] Hereinafter, embodiments of a light guiding member of the present invention, a method for producing the same, and a surface light source device using the member and method will be described with reference to the drawings. 200923450 Fig. 1 (a) and Fig. 1 (b) are schematic cross-sectional views showing the implementation of the light guiding member of the present invention. Fig. 1 (a) and Fig. 1 (b) show longitudinal sections which are orthogonal to each other. The light guiding member includes the light transmissive sheet 2 and the light transmissive photocurable resin layer 4, and the three translucent sheet 2 has the first surface (upper surface in the drawing) 21 and the opposite side of the first surface 21 of the child. The second surface on the side (the lower surface in the drawing) 22 ° One photocurable resin layer 4 adheres to the first η of the light-transmitting sheet
表面21上’另—個光硬化性樹脂層6附著於透光性片材的 第2表面22上。 透光性片材2較好的是厚度為200〜800 βπι。透光 性片材2的厚度更好的是300〜700 /zm,尤其好的是4〇〇 600 導光部材使入射至光入射端面的光一邊在兩 個主面上重複内面全反射一邊進行導光。作為該内面全反 巧2的光f動作之一,有波長選擇即著色。該著色現象隨 反f次數的增多而顯著出現。因此’藉由使透光性片 勺尽度大於等於2〇〇 ’可降低内面全反射的次數 而抑制著多, 可 二匕亚且可使面光源裝置的發光面積增加。例如, 發光面積增大至沿著透光性片材2的表面的最大尺寸 句40 cm /*去 , 工石。另一方面,作為與導光部材組合使用的一 ~人光源,你丨+7 , 不了溥型的LED,但其發光部的尺寸例如為250 堂# 左右。因此,藉由使透光性片材2的厚度小於 寻於8〇π 筆置、“111’在使用如上所述的小型LED來實現面光源 ί入分的薄型化時,可將—次光源發出的光幾乎全部 、 &光部材内進行有效利用,從而可將光利用效率維 12 200923450 持得較高。而且,藉由使透光性片材2 ㈣可獲得適宜的可撓性,錢予光=寺於80 而製造導光部材時,可連續地供給長條的透才2、, 從而可獲得製造上的優點。 ^ w 在發光面積相對較小的透光性片材2中 表面的最大尺寸小於等於⑽的透光性片材2中= Γ 的疋250〜350 ”。其原因在於,此時,由於導光距離 相對較短,因此即使減低厚度,著色的影響亦較少先藉由 使透光性片材2的厚度小於等於 字模等的擠出法來廉價地製造透光性片材2,夢曰由使用光 c 光硬化性樹脂層4、6各白矣而目士 性樹,的凹凸構造為=:造具有 鏡列相互平行地制*成=造域侧構造是多個稜 即,平均厚度按以下方式定義。 片材的第〗或者;2二2,層的透光性 22的整個面上進行積八,脸的南度分佈在表面2卜 22 ^字所獲得的積分值除以表面21、 的平均;^ 於本發明中,該光硬化性樹月旨層4、6 的千均厂子度的合計小於等於3〇_,較好的是小於等於 200923450 20 //m ’進而好的是小於等於15 。另外,光硬化社 樹脂層4、6的平均厚度的至少一方小於等於2 ^ 好的是小於等於10 //m,進而好的是小於等於5 藉由使光硬化性樹脂層4、6的平均厚度為如上所述,艮 . 目導光部材的薄型偏導致導光触巾的光硬化^樹= . 表面上的全反射次數變多時,亦可降低與此相伴的光硬/匕 性樹脂層内的導光過程中的著色(黃變=與亮度★十中的 錢的X值、丫值以及Z值相關)。另外,於本發明^色 1 使用YI值(YellowIndex,黃色指數)來表示黃變^程度。 所謂γι值,是指將從白色或者無色向黃色偏移(shift)"的 值用正(plus )的數值來表示的值,可由日本工業規才夂 JIS-Z8701中規定的3刺激值X、γ、z,並根據下述式, 而求出黃色度(YI值)。 工 ΥΙ=[< 1.28χΧ~1.06χΖ>/Υ]χΐ〇〇 為了減少黃變,光硬化性樹脂層的厚度越薄越好。因 此’不要求微細構造的構造(例如,稜鏡列排列構造)較 I) 好的是藉由熱轉印等來對透光性片材2自身進行賦形。當 於一個表面上形成粗糙面構造,而於其相反的表面上形成 稜鏡列排列構造時,較好的是粗糙面構造形成於光硬化性 樹脂層内’其厚度小於等於10 //m (更好的是小於等於5 ' 稜鏡列排列構造是使稜鏡列經熱轉印而形成於透光 性片材上。 而且,為了減低如上所述的著色,較好的是,光硬化 性樹脂層4、6的光硬化性樹脂中,1 mm厚的γ〗值小於 14 200923450 等於2.0。即,構成光硬化性樹脂層4、6的樹脂混合物(樹 脂組成物)中,樹脂硬化物的! mm厚的竹值小於等於 2.0。 YI缺好的是小於等於15,尤其好的是小於等於 1.0。 而且較好的是,構成光硬化性樹闕4、6的樹脂混 合物中,樹脂硬化物的10 mm厚的YI值小於等於3 〇。藉 - 此,即使導光部材進行薄型化,亦可抑制著色。作為對於 發揮如此之功能有利的光硬化性樹脂的構成單位,可例示On the surface 21, another photocurable resin layer 6 is adhered to the second surface 22 of the light-transmitting sheet. The light-transmitting sheet 2 preferably has a thickness of 200 to 800 βπι. The thickness of the light-transmitting sheet 2 is more preferably 300 to 700 /zm, and particularly preferably 4 to 600. The light-guiding member allows the light incident on the light incident end face to be repeated while the inner surface is totally reflected on the two main surfaces. Light guide. One of the light f actions of the inner surface full reflex 2 is coloring, that is, coloring. This coloring phenomenon remarkably appears as the number of anti-f times increases. Therefore, the number of times of total reflection of the inner surface can be reduced by reducing the number of times of the light-transmissive sheet by 2 〇〇 or more, and the light-emitting area of the surface light source device can be increased. For example, the light-emitting area is increased to 40 cm /* along the maximum dimension of the surface of the light-transmitting sheet 2, and the work stone. On the other hand, as a one-person light source used in combination with the light guiding member, you 丨+7, but the LED of the 溥 type is not used, but the size of the light-emitting portion is, for example, about 250 ##. Therefore, by making the thickness of the light-transmitting sheet 2 smaller than that of the 8〇π pen and "111' for thinning the surface light source using the small LED as described above, the secondary light source can be used. Almost all of the emitted light is used effectively in the light-emitting material, so that the light utilization efficiency can be kept high. In addition, by making the light-transmissive sheet 2 (4) obtain appropriate flexibility, money When the light guide member is manufactured at 80, the light guide member can be continuously supplied to the strip 2, and the manufacturing advantage can be obtained. ^ w The surface of the light-transmitting sheet 2 having a relatively small light-emitting area The maximum size is less than or equal to (10) in the light-transmitting sheet 2 = Γ 疋 250 to 350 ”. This is because, at this time, since the light guiding distance is relatively short, even if the thickness is reduced, the influence of coloring is less likely to be inexpensively produced by an extrusion method in which the thickness of the light-transmitting sheet 2 is equal to or less than a font or the like. In the translucent sheet 2, the concealed structure is made of a light-colored c-curable resin layer 4, 6 and a white-skinned tree, and the concavo-convex structure is made to have a mirror row parallel to each other. The configuration is a plurality of ribs, and the average thickness is defined as follows. The sheet is 〗 〖OR; 2 2 2, the entire surface of the layer of light transmissive 22 is integrated with eight, the south of the face is distributed over the surface 2 b 22 words obtained by dividing the integral value divided by the average of the surface 21; In the present invention, the total number of thousands of plants of the photohardenable tree layer 4, 6 is less than or equal to 3 〇 _, preferably less than or equal to 200923450 20 // m ' and further preferably 15 or less. In addition, at least one of the average thicknesses of the light-hardening resin layers 4 and 6 is 2 or less, preferably 10 // m or less, and more preferably 5 or less, by averaging the photocurable resin layers 4 and 6. The thickness is as described above, 艮. The thinness of the light guiding member causes the light hardening of the light guiding contact to be lightened. When the number of total reflections on the surface is increased, the light hard/elastic resin accompanying this can also be reduced. Coloring during light guiding in the layer (yellowing = correlation with the X value, enthalpy value and Z value of the money in the brightness ★ ten). Further, in the present invention, the YI value (Yellow Index, yellow index) is used to indicate the degree of yellowing. The value of γι refers to a value that is shifted from white or colorless to yellow by the value of plus (plus), which can be expressed by the Japanese Industrial Code 夂 JIS-Z8701. γ, z, and the yellowness (YI value) was obtained according to the following formula. Work = [<1.28χΧ~1.06χΖ>/Υ]χΐ〇〇 In order to reduce yellowing, the thickness of the photocurable resin layer is as thin as possible. Therefore, the structure in which the fine structure is not required (for example, the array structure) is preferable to I. The light-transmissive sheet 2 itself is shaped by thermal transfer or the like. When a rough surface structure is formed on one surface and a matrix arrangement structure is formed on the opposite surface, it is preferred that the rough surface structure is formed in the photocurable resin layer to have a thickness of 10 // m or less ( More preferably, the 排列 array structure is such that the ruthenium column is formed on the light-transmitting sheet by thermal transfer. Further, in order to reduce the coloring as described above, it is preferred that the sclerosing property is good. In the photocurable resin of the resin layers 4 and 6, the γ value of 1 mm thick is less than 14 200923450 and equal to 2.0. That is, in the resin mixture (resin composition) constituting the photocurable resin layers 4 and 6, the resin cured product The mm value of the bamboo value is less than or equal to 2.0. The YI deficiency is less than or equal to 15, particularly preferably less than or equal to 1.0. Moreover, it is preferred that the resin mixture constituting the photocurable tree 阙 4, 6 is a resin cured product. The YI value of the 10 mm thick is less than or equal to 3 〇. Therefore, even if the light guiding member is made thinner, coloring can be suppressed. As a constituent unit of the photocurable resin which is advantageous for such a function, it can be exemplified.
乙二醇二丙烯酸酯(Ethylene Glycol Diacrylate,EDA)、 已一醇一丙稀酸醋(Hexanediol Diacrylate,HDDA)、EO 改貝氫化雙齡A 一丙細酸酉旨(Hyperbranched Polyethylene,HBPE)、丁二醇二甲基丙烯酸醋(Butylene Glycol Dimethacrylate,BOM )、丁二醇二丙烯酸酯 (Butanediol Diacrylate,C4DA)、新戊二醇二丙烯酸酯 (Neopentyl Glycol Diacrylate,NPA)以及 2-經基丙基丙 稀酸酯(2-hydroxypropyl Acrylate,ΗΡΑ)。而且,亦可使 用多官能丙烯酸胺基曱酸酯混合物(第一工業製藥製造: 〇 GX8662V)等,該多官能丙烯酸胺基曱酸酯混合物是由相 對於六亞曱二異氰酸醋(Hexamethylene Diisocyanate ’ HDI)而對2-羥基-1-丙烯醯氧基-3-曱基丙烯醯氧基丙烷 (新中村化學工業製造)進行2當量胺基甲酸酯化反應所 獲得的化合物(Urethane Tetracrylate ’ U4HA)以及 HDI、 HDI3量體(異氰尿酸酯型)、ΗΡΑ、季戊四醇四丙烯酸酯 (Pentaerythritol Tetraacrylate,ΡΕΤΑ )而合成。該些物質 可發揮以下功能,即,防止由苯環的7Γ共軛系的電子躍遷 15 200923450 吸,弓丨起的著色。即,藉由將該 可容=獲得實質上不含有笨基的主成分, 2由承^就防止著色方財慮,較好的是,透光性片姑 =胃上不含有笨環的概 f生片材 =’透光性片材2中自由的殘_巧色方 ,二重量啊,更好的是小於等於^ 3 =於等 ’丄:丄專於1 PPm。藉此,即使在光硬化性樹脂層4、:疋 〇 成時經由透弁性另姑9办、社/ A, a 6的形 ^ ii; ΐ 处尤性片材2亦不會發生黃變。尤1, 著色防止性的觀點考慮,較好的 完=3!:質上Τΐ有苯環的= 人 展(本基)的樹脂,而且意味著亦 ϋ t躍遷吸心丨起的著色不會造綱題的極微量的 =。更洋細地敍述’於本發明中,所謂極微量,較好的 s2ί量%以下’更好的是小於等於1重量’尤其好的 = ’、、於等於0.5重量。而且,於本發明中,光硬化性樹脂 曰=及其中所用的光硬化性樹脂,進而光硬化性樹脂的主 、^較好的疋Υΐ值不會因溫度而發生較大變動。例 如車乂好的是使用於60〇c環境下進行5〇〇小時的熱處理後 YI值的變化不超過α5的材料,對於透光性片材而言,較 好的亦疋於6〇〇C環境下進行5〇〇小時的熱處理後γΙ值的 變化不超過0.5。 為了防止導光部材的破損,可使透光性片材2中含有 16 200923450 橡膠成分。藉此,ρ你② 軟性、可亦可提高透紐片材2的柔 縣成八擊吸收性等,因此難以破損。另外, 強,因此,就著色防ί的觀m u的者色容易變 的异小㈣认止的氣考慮’橡膠成分的含量較好 少、立㈣t 4量%,進而好的是小於等於1G重量%, 尤其好的疋小於等於5重量%。 Ο ϋ 化性SHI光部材的強度,而且為了賦予提高與光硬 如It:::,緊貼性等的效果(賦予易黏結層),例 片。材2,上匕5弟1透光層及第2透光層而構成的透光性 、十、第2、秀二弟1透光層與光硬化性樹脂層4、6接觸,上 ==!接合於該第\透光層。第1透光層的厚度較 ”二9;掃1〇〇 _,進而好的是小於等於75 _, 尤其好的疋小於等於50 _。其中,為 果的目的,上述第1透光層較好的是(U〜50 _的薄;, 以降低對透光性或膜物性的影響。 曰 ,當使光硬化性樹脂層4、6 _於透光性 片材2的弟1表面以及第2表面上日士 由作為基材的第2透光層搬以及^;可使透光性片材2 的兩面上的第1透光層204、206而二於第2透光層2〇2 個第i透光層204、2〇6中的任—方而:成。亦可不使用2 可使用層壓法(laminate)。而且^光層彼此間的接合Ethylene Glycol Diacrylate (EDA), Hexanediol Diacrylate (HDDA), EO, Hydrobranched Polyethylene (HBPE), Ding Butylene Glycol Dimethacrylate (BOM), Butanediol Diacrylate (C4DA), Neopentyl Glycol Diacrylate (NPA), and 2-Phenylpropylpropyl 2-hydroxypropyl Acrylate (ΗΡΑ). Further, a polyfunctional urethane phthalate mixture (manufactured by Daiichi Kogyo Co., Ltd.: 〇GX8662V) or the like may be used, and the polyfunctional acrylamide phthalate mixture is made of Hexamethylene relative to Hexamethylene diisocyanate (Hexamethylene). Diisocyanate 'HDI) is a compound obtained by subjecting 2-hydroxy-1-propenyloxy-3-mercaptopropenyloxypropane (manufactured by Shin-Nakamura Chemical Co., Ltd.) to 2 equivalents of urethanation reaction (Urethane Tetracrylate) 'U4HA) and HDI, HDI3 (isocyanurate type), hydrazine, pentaerythritol Tetraacrylate (ΡΕΤΑ) and synthesized. These substances can function to prevent electronic transition from the 7-fluorene conjugated system of the benzene ring. That is, by obtaining the main component which does not substantially contain a stupid base, it is preferable to prevent the coloring by the support, and it is preferable that the translucent film does not contain a stupid ring on the stomach. f raw sheet = 'transparent sheet 2 free residue _ smart color square, two weight ah, better is less than or equal ^ 3 = wait for '丄: 丄 specializes in 1 PPm. Therefore, even in the case of the photocurable resin layer 4, the smear of the sheet 2 does not undergo yellowing. . In particular, from the viewpoint of coloring prevention, it is better to finish =3!: the resin of the benzene ring = the base (the base), and it means that the color of the 跃t jump will not rise. A very small amount of =. More specifically, in the present invention, the term "very small amount, preferably s2 % by weight or less" is more preferably equal to or less than 1 part by weight, and particularly preferably equal to 0.5 part by weight. Further, in the present invention, the photocurable resin 曰 = the photocurable resin used therein and the preferred enthalpy of the photocurable resin are not greatly changed by temperature. For example, it is good to use a material that does not change the YI value after heat treatment for 5 hours in a 60 〇c environment, and for a light-transmissive sheet, it is better than 6 〇〇C. The change in γ Ι value after the heat treatment for 5 hours in the environment does not exceed 0.5. In order to prevent breakage of the light guiding member, the light transmissive sheet 2 may contain 16 200923450 rubber component. Therefore, the softness of the ρ you 2 can also improve the absorbability of the sturdy sturdy sturdy slabs of the sturdy sheet 2, and thus it is difficult to break. In addition, it is strong, and therefore, the color of the coloring is easy to change. (4) The gas that is recognized is considered to be 'the content of the rubber component is preferably small, the amount of the vertical (four) t 4 is, and preferably the weight is less than or equal to 1 G. %, especially good 疋 is less than or equal to 5% by weight. Ο The strength of the SHI light member, and the effect of improving the adhesion to light, such as It:::, adhesion, etc. (giving the easy-bonding layer), for example. The material 2, the light transmissive layer formed by the upper layer 5 and the second light-transmitting layer, and the light transmissive layer of the second, second and second brothers 1 are in contact with the photocurable resin layers 4 and 6, and the upper == Bonded to the first light transmissive layer. The thickness of the first light-transmitting layer is smaller than "two 9; sweep 1 〇〇 _, and further preferably less than or equal to 75 _, especially preferably 疋 is less than or equal to 50 _. Among them, for the purpose of the first light-transmitting layer It is good (U~50 _ thin; to reduce the influence on light transmittance or film physical properties. 曰, when the photocurable resin layer 4, 6 _ is on the surface of the translucent sheet 2 and the first (2) The surface of the translucent sheet 2 is transported by the second light-transmitting layer as the substrate, and the first light-transmitting layers 204 and 206 on both sides of the light-transmitting sheet 2 are disposed on the second light-transmitting layer 2〇2. Any one of the ith light-transmissive layers 204 and 2〇6 may be formed. Alternatively, a laminate may be used without using 2. The bonding of the optical layers to each other is also possible.
可使用以多層將透光性片材共_的方料於第2基材I 造上的步驟不會增加的觀點而言, 車父好的疋多層共按出。 200923450 其中’較好的是,光硬化性樹脂或者第Μ 射率與第2透過層的折射率大致綱,或 \ 透過層的折射率(即大於等於較第2透過層的挢2 ,的值)二若光硬化性樹脂或者第]透過‘的 第2透光層高某程度以上,則導光膜 :、射率較 Γ Ο 所夾著的平面導波路構造,印使對,低折射率層 狀,亦會造成光難以向外部出射的傾:面二予微細凹凸形 當使光硬錄鍋層4、6^怎麼好。 以及第2表面上時,可抑制導光部才 材2的第1 圖3是表示製作如上所述的導曲的發生。 形態的示意圖。該實施形態中,導^材的方法的—實施 首先,製作透光性片材2。於圖;工被J續地製造。 模31的熔融擠出,將由所需的合成^中,藉由使用T字 32擠出。使該熔融膜32通過冷卻_知材料構成的熔融膜 32冷卻而作為透光性片材2。該方~33,藉此將該熔融膜 的厚度小於等於5〇〇 " m的情况。、5於透光性片材2 的其他方法’有藉由練聚合心為製作透光性片材2 性片材2的厚度超過500 gn!的情况邊手法適合於透光 接著,於透光性片材2的第1表 、 樹脂組成物,將轉印用模部材34的輪21上塗佈光硬化性 光硬化性樹脂組成物上以製作凹凸印面的形狀轉印至該 並經由透光性片材2對光硬化性樹^造’藉由紫外線燈35 射而使之硬化,製作出光硬化性樹^成物進行紫外線照 性片材2的第2表面22上塗佈光9 θ 4。繼而’於透光 又化性樹脂組成物,將轉 200923450 印用模部材36的轉印面的形狀轉印至光硬化性樹脂組成 物上以製作凹凸構造,藉由紫外線燈37並經由光硬化性樹 脂層4以及透光牲片材2來對光硬化性樹脂組成物進行紫 外線照射而使之硬化,製作出光硬化性樹脂層6。將藉此 而獲得的導光部材40經由導輥38而取出。 ΟIt is possible to use a plurality of layers in which the light-transmissive sheet is laminated on the second substrate I without increasing the number of layers. 200923450 wherein 'the photocurable resin or the second refractive index of the photocurable resin or the second transmission layer is substantially the same, or the refractive index of the permeation layer (that is, a value greater than or equal to 挢2 of the second transmission layer). When the photo-curable resin or the second light-transmissive layer of the second light-transmitting resin is higher than a certain degree, the light-guide film: the plane waveguide structure sandwiched by the 射 射 is printed, and the low refractive index is printed. The layered shape also causes the light to be difficult to be emitted to the outside: the surface is made of a fine concavo-convex shape, so that the light hard recording layer 4, 6^ is good. In the case of the second surface, the first light guide portion 2 can be suppressed. Fig. 3 is a view showing the occurrence of the above-described guide war. Schematic diagram of the form. In the embodiment, the method of guiding the material is carried out. First, the light-transmitting sheet 2 is produced. In the figure; the work was continuously manufactured by J. The melt extrusion of the die 31 will be extruded from the desired synthesis by using the T-shape 32. The molten film 32 is cooled by a molten film 32 composed of a cooling material to be a light-transmitting sheet 2. This side is ~33, whereby the thickness of the molten film is less than or equal to 5 〇〇 " m. 5, the other method of the light-transmitting sheet 2 is to form a light-transmissive sheet 2, and the thickness of the sheet 2 is more than 500 gn! The first sheet and the resin composition of the sheet 2 are coated with a photocurable photocurable resin composition on the wheel 21 of the transfer mold member 34, and the shape of the embossed surface is transferred thereto. The sheet 2 is cured by a UV lamp 35 to produce a photocurable resin, and the second surface 22 of the ultraviolet ray sheet 2 is coated with light 9 θ 4 . . Then, in the light-transmissive resin composition, the shape of the transfer surface of the printing mold member 36 was transferred to the photocurable resin composition to form a concavo-convex structure, and the light was cured by the ultraviolet lamp 37. The resin layer 4 and the light-transmitting sheet 2 are cured by ultraviolet irradiation of the photocurable resin composition to produce a photocurable resin layer 6. The light guiding member 40 thus obtained is taken out via the guide roller 38. Ο
較好的是,光硬化性樹脂組成物中所包含的聚合起始 劑中’ 1分子構造内所包含的苯環的個數小於等於卜其原 因在於,雖光聚合起始劑大多含有苯環,但丨分子構造内 =包含的苯環的個數越少,則越難以引起導光部材的黃 ’文。作為如此之聚合起始劑,可列舉卜羥基-環己基-苯基_ 曱酮(例如汽巴精化(Ciba Specialty Chemicals)製造: 士gacurel84)或者2♦基_2-甲基_ι_苯基酮(例如 j精化製造:Dar()eure⑺3)。而且,光硬化性樹脂組成 ^的聚合起始劑的濃度較好的是0.01〜1重量%,更好 j疋〇.03〜0·5重量%,進而好的是0.05〜0.1重量〇/❶。聚 口 ^始刮巾所包含的苯環的濃度會料光部材的*變造In the polymerization initiator contained in the photocurable resin composition, the number of the benzene rings contained in the 'molecular structure is less than or equal to the reason that the photopolymerization initiator mostly contains a benzene ring. However, the smaller the number of benzene rings included in the molecular structure of the 丨, the more difficult it is to cause the yellow light of the light guiding member. As such a polymerization initiator, there may be mentioned hydroxy-cyclohexyl-phenyl fluorenone (for example, manufactured by Ciba Specialty Chemicals: gaccel 84) or 2♦ yl-2-methyl_ι-benzene Ketone (for example, j refined manufacturing: Dar () eure (7) 3). Further, the concentration of the polymerization initiator of the photocurable resin composition is preferably 0.01 to 1% by weight, more preferably j疋〇.03 to 0.5% by weight, and further preferably 0.05 to 0.1% by weight/❶. . The concentration of the benzene ring contained in the squeegee will change the color of the material.
Sit若聚合起始劑的濃度大於1重量%,則導光部 _ 題化。另—方面,若聚合姑劑的濃度小於 重里/〇,則聚合容易變得不夠充分。 性,ίΐΐ高透絲片材2與級化性樹闕4的緊貼 中,是,在進行光硬化時或者在光硬化之前的步驟 下於40 t光性片材2與光硬化性樹脂層4相接觸的狀態 該保持日進!1好的是50〜70度。 勺疋 勺3秒以上。但是,若該時間過長, 19When the concentration of the polymerization initiator in Sit is more than 1% by weight, the light guiding portion is formed. On the other hand, if the concentration of the polymerization agent is less than the weight/rhodium, the polymerization tends to be insufficient. The adhesion between the high-filament sheet 2 and the graded tree 4 is at 40 t of the optical sheet 2 and the photo-curable resin layer at the time of photohardening or before the photo-hardening step. The state of the 4-phase contact should be maintained at a daily rate! 1 is 50 to 70 degrees. Spoon 勺 spoon for more than 3 seconds. However, if the time is too long, 19
200923450 則該f處理步驟會變長,因為不怎麼好(較好的是最大為 小於等於10秒)。該些時間可藉由適當地選定光硬化性樹 脂與透光性片材2或者第〗透光層的材料而縮短。藉由在 如此之條$下進行光硬化,可提从硬化性職層與透光 性片·!才Γ緊貼性。若溫度低於40度,則難以體現出緊貼硬 化若孤度大於8〇度,則有時會造成膜強度下降而導致加 工變得不穩定。 而且,為了提高光硬化性樹脂層與透光性片材的緊貼 性’作為透光性片材2或者第丨透光層綱、施的材料, 可使用將玻璃轉移溫度(Tg)較低的丙烯酸酯單體北 而成的材料,更好的是均聚物的Tg低於1〇度的材料^。作 為上述丙烯酸料體,較好的是具有由魏卜6的醇經醋 化的羧基的丙烯酸酯。 作為尤其不會有損透明性而能賦予緊貼層的材料,較 好的是使曱基丙烯酸曱酯(Methl Methacrylate,_ )盥 丙烯酸甲酯(Methyl Acrylate ’ MA )共聚合而成的材料(= 下,亦稱作丙烯酸酯共聚物)。該MA的含量較好的是5 〜20重量%,進而好的是10〜15重量%。若大於等^2〇 重量%,則玻璃轉移溫度會降低,作為膜物性不佳。而且, 若小於等於5重量%,财時會無法獲得充分的緊貼性提 高。而且,為了維持透光性片材的機械物性,較, 上述丙烯_旨共雜用作透光性片材_丨透光層=、 206。 轉印用模部材34、36 的轉印面的形狀轉印可按圖 4 20 Ο ϋ 200923450 (a)、圖4 (b)所示的方式 嘴N向轉印用模部材%% =⑷中,自噴出^ 組成物。該噴附的光硬化 P面贸附光硬化性樹鹿 3 4、3 6的轉印面與透光由轉印用模部材 照射。而且,圖4 (b) φ Γ所夾持者,並受到紫外線 嘴N注入至轉印用模3 脂組成物自喷出嗔 之間。該注人的光硬化印面與透光性片材2 %的轉印面與透光性由轉印用模部材34、 射。其中,若光硬化性材^爾線照 (以下,亦總稱作透光性美 材或者弟1透光層 好的是,使如上所述的^喷仙^性不夠充分’則較 在由上述_所夾持的進向錢紐基材的喷附 處理。作杨祕理的妓,;度進行加熱 8〇度的爐的内部通過數秒鐘㈣;;。在將溫度奴成4〇〜 周面==面轉?用模部材34,呈輥狀,且其外 四口又马升y狀轉印面,但本發明並不 例如,如圖5所示,亦可使用呈 =於如此之形悲。 面的轉印賴仙41 j 讀且早面設為形狀轉印 而呈;: = :經由― 組成物,於此處進行料線_。持技硬化性樹月曰 圖6是表示使用如上所述的導 —貫施形態的示意性分解立體圖。 、面絲裝置的 導光部材4〇以透光性片材2的第k及第2表面位於 21 200923450 配置,χγ面_彡狀呈具有χ方向邊 Λ狀°鄰接於導光部材則丫之面内 面面(該端面作為光入射端面而發揮 源的多個_〇。以°二宜;=:置有作為-次光2 镇 ,、附者於¥先口W 40的透光性片材2 表面)上的光硬化性樹脂層4 (該層的表 而配置==光Γ面而發揮功能)相對向的方式, 著;㈣稜鏡片材6G。另-方面,以與附 的透光性片材2的第2表面(下表面)上 相對_方ί脂層6(該層的表面稱為導光部材的背面) 1的方式,她置有作為反光元件的反射膜70。 Ο 光部;bf· ^ED5Q, ^的光經由該光騎端面而被導入至導 於導来心内亚藉由光出射面以及背面上的内面全反射而 形成=Γ0内被引導向χγ面内的方向。於光出射面上 該粗tit魏性樹脂層4的凹凸構造的粗趟面構造, 射。L 7揮光出射功能,以所需的出射率使光出 並被再-㈠於導光’自背面出射的规反射m7G所反射, 性樹腊it至導光部材4G内。於背面形成有作為光硬化 方向上^凸構造的稜鏡列排列構造,該稜鏡列於X 到會聚=能因此可獲得使γζ_糾行進方向分佈得 將γ =片,6G的下表面(作為入光面而發揮功能)作為 面。自mV夕個棱鏡列相互平行地排列而成的稜鏡列形成 V光部材40的光出射面相對於其法線方向(z方向) 200923450 而於xz面内分佈上傾斜出射的光入射至稜鏡片材入光面 的稜鏡列,並藉由内面全反射而使行進方向偏向大致2方 向。經偏向的光自稜鏡片材60的上表面(作為出光面而發 揮功能)出射。 ’ [實施例] 以下,藉由實施例進一步說明本發明。 另外,於以下的實施例以及比較例中,色座禕(X值 以及y值)以及YI值按如下方式進行測定。 [色座標(X值以及丫值)的測定方法] 製作圖6的實施形態的面光源裳置,使用亮度計 (τ〇Ρ_製造:BM7) LM,測定出法線方向上的χ值以 及y值。自導光部材光入射端面位置朝向導光部材中心 亚在沿著導光部材4Q的第丨表面且與光人射端面及第 1表面的交線正交的方向[x方向]的導光部材4〇的中心線 所對應的線C上’使亮度計以2職間距移動,順次進行 ^標的X值以及gp ’求出以由作為偏光元 件的稜鏡片材6 0而來的出射光所測定出的色座標的X值以 及y值的、相對於導光部材40内的與光入射端面相距的導 光距離的變化。其中,於面光源裝置中,使用白色㈣(日 亞化學製造:NSSWG57A)來作為LED5G,將該LED5〇 以5.1 mm間距排列60個。導光部材4〇的尺寸為η?瓜爪 U方向)x3G7 mm (Y方向),透光性片材2的厚度為 〇.5職。而且’將直至導光距離12⑽為止的色座標χ值 以及y值的變化率作為最小平方近似直線的斜度而求出。 23 200923450 [光硬化性樹脂的yi值的測定方法] 製作厚度1 mm且直徑6 cm的圓形狀的光硬化性樹脂 片來作為YI值測定用樣品,使用自動分光光度儀(日立 製造:U-3500型)來進行YI值的測定。將無樣品的狀態 作為基礎(base)來進行後台數值修正,求出使用樣品時 的YI值。在評價用樣品的製作時,使用金屬鹵化物燈無 電極燈D燈泡(FUSION LH-10 )來作為紫外線照射裝置’ 以60%的出力’使用每!盞燈為24〇 w/cm功率(1〇〇%輪 出時)的三盞燈。紫外線照射裝置與樣品的距離為53.3 醒’最終對樣品進行以照度計測定為1〇〇〇 mJ/cm2 (土3〇 mJ/cm2)的能量的5J秒的UV照射而進行光硬化性樹脂 的聚合,製作出樣品。而且,在光聚合後將樣品放置i週 之後,進行YI值的測定。樣品製作條件或uv能量照射量 或樣品放置時間會影響到隨後的γι值,因此必須使該些 條件一直相同而進行Yj值的測定。 一 [實施例1]200923450 The f processing step will be longer because it is not so good (preferably, the maximum is less than or equal to 10 seconds). These times can be shortened by appropriately selecting the materials of the photocurable resin and the light transmissive sheet 2 or the light transmissive layer. By performing light hardening under such a price, it is possible to improve the adhesion from the hardenable layer to the light-transmitting sheet. If the temperature is lower than 40 degrees, it is difficult to show that the adhesion is hard. If the degree of segregation is more than 8 degrees, the film strength may be lowered and the processing may become unstable. Further, in order to improve the adhesion between the photocurable resin layer and the light-transmitting sheet, as the material of the light-transmitting sheet 2 or the second light-transmitting layer, a glass transition temperature (Tg) can be used. The material of the acrylate monomer in the north is more preferably a material having a Tg of less than 1 degree in the homopolymer. As the above acrylic material, an acrylate having a carboxyl group which is acetated with a Weib 6 alcohol is preferred. As a material which can impart an adhesion layer in particular without impairing transparency, a material obtained by copolymerizing Methl Methacrylate (_) 盥 methyl acrylate (Methyl Acrylate ' MA ) is preferred ( = Lower, also known as acrylate copolymer). The content of the MA is preferably from 5 to 20% by weight, more preferably from 10 to 15% by weight. If it is more than equal to 2% by weight, the glass transition temperature is lowered, and the physical properties of the film are not good. Further, if it is 5% by weight or less, sufficient adhesion improvement cannot be obtained at a time. Further, in order to maintain the mechanical properties of the light-transmitting sheet, the above-mentioned propylene is used as a light-transmitting sheet _ 丨 light-transmitting layer = 206. The transfer of the transfer surface of the transfer mold members 34 and 36 can be carried out in the manner of the nozzle N shown in Fig. 4 20 234 ϋ 200923450 (a), Fig. 4 (b), and the transfer mold member %% = (4). Spray the ^ composition. The transfer surface of the sprayed light-curing P-faced light-curing tree deer 3 4, 36 and the light transmission are irradiated by the transfer mold member. Further, in Fig. 4(b), φ Γ is held by the ultraviolet ray N to be injected between the transfer mold 3 and the grease composition from the discharge 嗔. The light-hardened printing surface of the injection and the transfer surface of the translucent sheet and the light transmissive property are emitted from the transfer mold member 34. Among them, if the photocurable material is taken as a line (hereinafter, it is also generally referred to as a translucent material or a light transmissive layer of the younger one, so that the above-mentioned The _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The circumferential surface == face rotation? The mold member 34 is in the form of a roll, and the outer four ports are raised to the y-shaped transfer surface. However, the present invention is not, for example, as shown in FIG. The shape of the sorrow. The face of the transfer Lai Xian 41 j read and the early face is set to shape transfer; : = : through the composition, the material line _ here. Hold the technology hardening tree month Figure 6 is to show A schematic exploded perspective view of the above-described guiding form is used. The light guiding member 4 of the upper threading device is disposed such that the kth and second surfaces of the light transmissive sheet 2 are located at 21 200923450, and the χγ surface is shaped like The surface of the in-plane surface of the crucible is adjacent to the light-conducting member (the end surface serves as a light incident end surface and serves as a source of a plurality of _ 〇. - The light-curable resin layer 4 on the surface of the light-transmissive sheet 2 of the first-order light-shield of the first-order light, and the surface of the light-transmissive sheet 2 (the surface of the layer is arranged to have a function of the surface of the layer) (4) 稜鏡 sheet 6G. On the other hand, on the second surface (lower surface) of the attached light-transmitting sheet 2, the surface of the layer is called light guide On the back side of the member), she is provided with a reflective film 70 as a light reflecting element. Ο Light portion; bf·^ED5Q, ^ light is introduced into the inner core through the light riding end face. The exit surface and the inner surface on the back surface are totally reflected to form a direction in which Γ0 is guided in the χγ plane. The rough surface structure of the concavo-convex structure of the thick tit-wei resin layer 4 on the light exit surface is emitted. The light exit function causes the light to be emitted at a desired exit rate and is again reflected by the spectroscopic reflection m7G emitted from the back side of the light guide, and the tree is turned into the light guiding member 4G. In the direction of the convex structure of the convex structure, the 稜鏡 is listed in X to convergence = so that the γζ_correction direction can be obtained to be γ = slice, 6G The lower surface (functioning as a light-incident surface) serves as a surface. The light-emitting surface of the V-light member 40 is formed by the alignment of the mV prism columns in parallel with each other with respect to the normal direction (z direction) 200923450. The light obliquely emitted in the xz plane is incident on the array of the entrance surface of the enamel sheet, and the traveling direction is deflected by substantially two directions by total reflection on the inner surface. The deflected light is self-twisted from the upper surface of the sheet 60. (Effects as a light-emitting surface). [Examples] Hereinafter, the present invention will be further described by way of examples. In addition, in the following examples and comparative examples, color coordinates X (X value and y value) and YI The values were measured as follows. [Measurement method of color coordinates (X value and 丫 value)] The surface light source of the embodiment of Fig. 6 was produced, and the χ value in the normal direction was measured using a luminance meter (τ〇Ρ_manufactured: BM7) LM. y value. The light guiding member of the light incident end surface position of the light guiding member toward the center of the light guiding member is in a direction [x direction] along the second surface of the light guiding member 4Q and orthogonal to the intersection of the light emitting end surface and the first surface. On the line C corresponding to the center line of the 4th line, the brightness meter is moved at the position of the two positions, and the X value and the gp' of the target are sequentially determined by the emitted light from the 稜鏡 sheet 60 as the polarizing element. The X value of the color coordinates and the change of the y value with respect to the light guiding distance from the light incident end surface in the light guiding member 40. Among them, in the surface light source device, white (four) (manufactured by Nissan Chemical Co., Ltd.: NSSWG57A) was used as the LED 5G, and the LEDs 5〇 were arranged at a pitch of 5.1 mm. The size of the light guiding member 4A is η? melon claw U direction) x3G7 mm (Y direction), and the thickness of the light transmitting sheet 2 is 〇.5 position. Further, the chromaticity target value and the rate of change of the y value up to the light guiding distance 12 (10) are obtained as the inclination of the least square approximation straight line. 23 200923450 [Method for measuring the yi value of photocurable resin] A circular photocurable resin sheet having a thickness of 1 mm and a diameter of 6 cm was prepared as a sample for YI value measurement using an automatic spectrophotometer (manufactured by Hitachi: U- Model 3500) was used to determine the YI value. The background value correction was performed using the state without the sample as a base, and the YI value at the time of using the sample was obtained. At the time of preparation of the sample for evaluation, a metal halide lamp electrodeless bulb D (FUSION LH-10) was used as the ultraviolet irradiation device, and the use was performed at 60% of the output. The xenon lamp is a three-lamp lamp with 24 〇 w/cm power (1 〇〇% round). The distance between the ultraviolet irradiation device and the sample was 53.3, and the photocurable resin was subjected to UV irradiation for 5 J seconds, which was measured by an illuminance meter to be 1 〇〇〇mJ/cm 2 (3 〇 mJ/cm 2 ). Polymerize to make a sample. Further, after the sample was left for one week after photopolymerization, the YI value was measured. The sample preparation conditions or the uv energy exposure amount or the sample placement time affect the subsequent γι value, so it is necessary to make the conditions always the same and measure the Yj value. [Example 1]
ppm;,便用各個轉印用模部材, 自由殘留硫醇約10〜20 藉由上述光硬化性樹脂而 24 200923450Ppm;, using each of the transfer mold parts, free residual mercaptan about 10~20 by the above photocurable resin 24 200923450
ΐ 的、,個面上轉印形成具有粗糙面構造的光硬化性樹 +亚在另一個面上轉印形成具有由在垂直於光入射 :二上延伸的多個棱鏡列構成的稜鏡列排列構造的 、,石’生樹脂層6。作為照射用於光硬化的紫外線的裝 置使用金屬鹵化物燈無電極燈D燈泡(FUSION LH-10), 以4〇 = 5〇〇/°的出力’使用每】盞燈為240 W/cm功率(100% 輸出的三盞燈。紫外線照射裝置與樣品的距離為53.3 Cm,最終對樣品照射以照度計測定為200〜30Θ mJ/cm2的 月b里而進行光聚合,以光硬化性樹脂來賦予兩面的凹凸構 造。製作出光硬化性樹脂層4的平均厚度為4 ,光硬 化性树脂層6的平均厚度為6 //m,且光硬化性樹脂層4、 6的平均厚度的合計為1〇 的導光部材。而且,測定 該些光硬化性樹脂層4、6的YI值時的結果為ί ο。 三菱麗陽製造:UK-6074 (40 w%)[化1]光 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , Arranged structure, stone 'raw resin layer 6. As a device for irradiating ultraviolet light for photohardening, a metal halide lamp electrodeless lamp D bulb (FUSION LH-10) is used, and a power of 4 〇 = 5 〇〇 /° is used for each xenon lamp of 240 W/cm. (100% output of three lamps. The distance between the ultraviolet irradiation device and the sample is 53.3 cm, and finally the photopolymerization is carried out by irradiating the sample with a month b of 200 to 30 Θ mJ/cm2 measured by an illuminance meter, using photocurable resin. The uneven structure of the both surfaces is provided. The average thickness of the photocurable resin layer 4 is 4, the average thickness of the photocurable resin layer 6 is 6 // m, and the total thickness of the photocurable resin layers 4 and 6 is 1 in total. The light guide member of the crucible. The result of measuring the YI value of the photocurable resin layers 4 and 6 is ί ο. manufactured by Mitsubishi Rayon: UK-6074 (40 w%) [Chem. 1]
[化1] 〇 CH^CHCOCHg 0 CH2»CH0〇C^0- 0 CHgO-C-N—0½1 O^CHOCX^[Chemical 1] 〇 CH^CHCOCHg 0 CH2»CH0〇C^0- 0 CHgO-C-N-0121 O^CHOCX^
0 H N—-C i ii H 00 H N—C i ii H 0
新中村化學製造:UJPPA (20 wt%)[化2] 25 200923450 H ^ CH3 N - CO- CHCH2〇CXX>l«CH2 [化2]Xinzhongcun Chemical Manufacturing: UJPPA (20 wt%) [Chem. 2] 25 200923450 H ^ CH3 N - CO- CHCH2〇CXX>l«CH2 [Chemical 2]
ch3 ch3 V ? ?«3 CHs CH2-N-CO-CHCH2〇COCH»CH2 三菱麗陽製造:PBOM (40 wt%)[化3] [化3] f 9^3 9^3 [實施例2] 使具有粗糙面構造的光硬化性樹脂層4的平均厚度為 5 //m’具有稜鏡列排列構造的光硬化性樹脂層6的平均 厚度為10 //m ’光硬化性樹脂層4、6的平均厚度的合計 為15 μ m ’除此以外,以與實施例1完全相同的條件製 作導光部材。 [貫施例3] 使具有粗糙面構造的光硬化性樹脂層4的平均厚度為 10 Adm’具有棱鏡列排列構造的光硬化性樹脂層6的平均 厚度為10 //m,光硬化性樹脂層4、6的平均厚度的合叶 為20 //m,除此以外,以與實施例丨完全相同的條;製 作導光部材。 ’' [比較例1] 使具有粗糙面構造的光硬化性樹脂層4的平均厚度為 26 200923450 16 "m,具有棱鏡列排列構造的光硬化性樹脂層6的平均 厚度為27 μπι,光硬化性樹脂層4、6的平均厚度的合計 為43 //m ’除此以外,以與實施例1完全相同的條件製 作導光膜。 [實施例4]Ch3 ch3 V ? ? «3 CHs CH2-N-CO-CHCH2〇COCH»CH2 Manufactured by Mitsubishi Rayon: PBOM (40 wt%) [Chemical 3] f 9^3 9^3 [Example 2] The photocurable resin layer 4 having a rough surface structure has an average thickness of 5 // m′, and the photocurable resin layer 6 having an array structure has an average thickness of 10 //m 'the photocurable resin layer 4 A light guiding member was produced under the same conditions as in Example 1 except that the total thickness of 6 was 15 μm. [Example 3] The average thickness of the photocurable resin layer 4 having a rough surface structure is 10 Adm' The average thickness of the photocurable resin layer 6 having a prism array structure is 10 // m, and the photocurable resin A light guide member was produced in the same manner as in Example 丨 except that the hinges of the average thickness of the layers 4 and 6 were 20 //m. [Comparative Example 1] The average thickness of the photocurable resin layer 4 having a rough surface structure is 26 200923450 16 "m, and the average thickness of the photocurable resin layer 6 having the prism array structure is 27 μm, light A light guiding film was produced under the same conditions as in Example 1 except that the total thickness of the curable resin layers 4 and 6 was 43 //m'. [Example 4]
' 使用聚乙二醇200二丙烯酸酯樹脂(PEDA_2〇〇)來作 為光硬化14¼¾ ’在其中混合G 5 *。/。的Irgaeure 184作為 來合起始劑,對該混合物進行uv硬化,用作導光部材的 凹凸構:^賦予光硬化性樹脂。凹凸形狀轉印是使用藉由擠 出成升v而衣k的以聚甲基丙稀酸曱酯(PMma )為主原料 的厚度5GG 的膜來作為透光性片材2 (自由殘留硫醇'Polyethylene glycol 200 diacrylate resin (PEDA 2 〇〇) was used as a photohardening 141⁄43⁄4 ' in which G 5 * was mixed. /. Irgaeure 184 was used as a starting initiator, and the mixture was subjected to uv hardening, and used as a concavo-convex structure of the light guiding member: to impart a photocurable resin. The uneven shape transfer is a film of a thickness of 5 GG using a polymethyl methacrylate (PMma) as a main raw material by extruding a v, and is used as a translucent sheet 2 (free residual mercaptan)
〜20 ppm),使用模具,藉由上述光硬化性樹脂而在 顧的-個面上轉印細⑭構造,並在該闕背面上轉印 在垂直於光入射端面的方向上延伸的多個稜鏡構造。製作 出該些各個光硬化樹脂層的平均厚度在祕面上為5以 m在稜鏡部上為10 _,合計為15㈣的導光部材。 而且,測定本樹脂的YI值時的結果為〇.7。 將以上的實施例1〜切及比較例〗中的、相對於導光 距離q的色座標的χ值以及y值的變化以及相對於光硬化 f樹脂層4、6的平均厚度的合計的X值以及y值的斜度(每 cm的變化率)分麻於圖7〜u以及表丨。如該些結果 中所見,當光硬化性樹脂層4、6的平均厚度 ; 導光的部分可目酬黃變。—般而言,若該x、y座標值的 200923450 變化率較大,則會目測到同一導光部材内的色調的變化。 [實施例5] 使用PMMA巾共聚有7重量%的嫩的材料來作為 光性片材2,以及使用已二醇二丙烯酸酯樹脂(hdda) - 來作為光硬化性樹脂,除此以外,完全與實施例4相同。 此時的YI值為Μ,如表1所示,X值以及y值的變化率 較小,分別是每1 cm為0.00041、0,00039。 [實施例6] 使用PMMA中共聚有12重量%的MA的材料來作為 透光性片材2,以及使用E〇改質氮化雙酚A二丙稀酸醋 (HBPE)來作為光硬化性樹脂,除此以外,完全與實施 例4相同。此時的YI值為〇 7,如表}所示,χ值以及^ 值的變化率較小,分別是每i cm為〇.⑽〇39、〇 〇〇〇38。 [實施例7] 使用以上下30 /zm左右的將pmmA與18重量%的 MA共聚合而成的層,將PMMA1〇〇0/(^ 44〇 厚度的 層夾在中間而成的共擠出的透光性片材2,以及使用聚丁 一醇一曱基两卸酸酉旨(p〇iybutylene Glycol Dimethacrylate ’ PB0M)來作為光硬化性樹脂,除此以外, 與實施例4完全相同。此時的γι值為〇·8,如表1所示, X值以及y值的變化率較小,是每1 〇〇〇〇45、〇〇〇〇42。 [實施例8] 將聚合起始劑的混合量設為wt%,除此以外,以 與實施例3完全相同的條件來製作導光膜。 28 200923450 [實施例9] 將聚合起始劑的混合量設為U25鲥%, 以與貫施例8完全相同的條件來製作導光膜。々、此以外, 將以上的實施例8〜9中的相對於導光距 的X值以及y _變似及相對於光硬= 色座標 的平均厚度的合計的x值以及¥值的斜度(每,月曰層4、6 率)分別示於圖12〜13以及表丨。於圖丨=的變化 〜11同樣地,橫車由是導光距離Ω r 、 中’與圖7 由貫施例3、8以及9的結果可知,聚 =才示。 量(濃度)越小,則X值以及y值的變=的混合 [表1] 丁〜和越小。 脂層 的平均厚度的合計 [/zm] 聚合起始劑 溫度 [wt%]〜20 ppm), using a mold, the fine 14 structure is transferred on one surface by the photocurable resin, and a plurality of structures extending in a direction perpendicular to the light incident end surface are transferred on the back surface of the crucible稜鏡 Construction. The light guiding members having the average thickness of each of the photocurable resin layers on the secret surface of 5 m in the crotch portion and 10 _ in total, and 15 (four) in total were produced. Further, when the YI value of the present resin was measured, the result was 〇.7. The change of the χ value and the y value of the color coordinates with respect to the light guiding distance q and the total of the average thickness of the photo-curable f resin layers 4 and 6 in the above-described Example 1 to Cut and Comparative Example The value and the slope of the y value (rate of change per cm) are shown in Fig. 7~u and Table 丨. As seen in the results, when the average thickness of the photocurable resin layers 4, 6 and the light guiding portion are yellowed. In general, if the rate of change of the x, y coordinate value of 200923450 is large, the change in color tone in the same light guiding member will be visually observed. [Example 5] A PMMA towel was used to copolymerize 7 wt% of a tender material as the optical sheet 2, and a diol diacrylate resin (hdda)- was used as a photocurable resin, except that completely The same as in the fourth embodiment. The YI value at this time is Μ. As shown in Table 1, the rate of change of the X value and the y value is small, being 0.00041 and 0,00039 per 1 cm, respectively. [Example 6] A material in which 12% by weight of MA was copolymerized in PMMA was used as the light-transmitting sheet 2, and E-modified nitriding bisphenol A diacrylic acid vinegar (HBPE) was used as photocurability. The resin was completely the same as Example 4 except for the above. The YI value at this time is 〇 7, as shown in Table}, the rate of change of the χ value and the value of ^ is small, which is 〇. (10) 〇 39, 〇 〇〇〇 38 per cm. [Example 7] Using a layer obtained by copolymerizing pmmA and 18% by weight of MA in the lower 30 / zm above, a coextrusion of a layer of PMMA1〇〇0/(^44〇 thickness) was sandwiched. The light transmissive sheet 2 and the p-iybutylene Glycol Dimethacrylate 'PB0M) were used as the photocurable resin, and the same as in Example 4. The γι value at the time is 〇·8. As shown in Table 1, the rate of change of the X value and the y value is small, and is every 45 〇〇〇〇 45, 〇〇〇〇 42. [Example 8] The polymerization start A light guiding film was produced under the same conditions as in Example 3 except that the amount of the compound was changed to wt%. 28 200923450 [Example 9] The mixing amount of the polymerization initiator was set to U25鲥%, The light guiding film was produced under the same conditions as in Example 8. In addition to the above, the X values and y_ with respect to the light guiding distance in the above Examples 8 to 9 were changed and compared with the light hardness = color. The total x value of the average thickness of the coordinates and the slope of the ¥ value (the rate of each of the meniscus layers 4 and 6) are shown in Figures 12 to 13 and Table 分别, respectively. In the same manner, the crossbar is the light guiding distance Ω r , the middle ' and the results of the third embodiment, the third and the eighth, and the results are shown in Fig. 7. The poly = only. The smaller the amount (concentration), the X value and the y The value of the change = the mixture [Table 1] D = ~ and the smaller. The total thickness of the lipid layer is equal [/zm] The polymerization initiator temperature [wt%]
------1--—丄 [光硬化性樹脂主成分的YI值的測定] 製作厚度2 mm且1 cm見方的光硬化性樹脂片來作 YI值測定用樣品,使用自動分光光度儀(日立製造:秘〇為 型)來進彳f YI值關定。將練品的㈣作絲礎來進 灯後台數值修正,求出使用樣品時的γι值。在評價用析 品的製作時,使用金屬鹵化物燈無電極燈D燈泡(fusi〇= 29 200923450 LH-10)來作為紫夕卜線照射裝置,以60%的出力,使用每1 盞燈為240 W/cm功率(100%輸出時)的三盞燈。紫外線 照射裝置與樣品的距離為53.3 mm,最終對樣品進行以照 度計測定為1000 mJ/cm2 (±30 mJ/cm2)的能量的5.7秒的 UV照射而進行光硬化性樹脂的聚合,製作出樣品。而且, 在光聚合後將樣品放置1週之後,進行YI值的測定。而 且,加熱處理是使用恆溫器,將樣品於溫度60°C的環境下 放置500小時,隨後進行YI值的測定。樣品製作條件或 UV能量照射量或樣品放置時間會影響到隨後的YI值,因 此必須使該些條件一直相同而進行YI值的測定。 使用上述的方法,於用作光硬化性樹脂的主成分的以 下表2中記載的各種聚合用單體液中混合0.1 wt%的聚合 起始劑(汽巴精化製:Irgacure 184),對該混合物進行UV 硬化,將測定YI值所得的結果示於表2。另外,示出使用 了具有聚丙烯骨架的丙烯酸胺基曱酸酯(根上工業製造: MPU11)的示例,以供參考。 [表2] 聚合用單體液 YI值 1週後 加熱處理後 GX8662V 1.6 1.4 U4HA 1 1.1 PBOM 0.7 0.7 NPA 0.7 0.8 HDDA 0.8 0.8 c4da 1.6 1.8 MPU11 0.9 3.1 [光硬化性樹脂混合物的YI值的測定] 30 200923450 製作厚度10 mm真直徑6 cm的圓形狀的光硬化性樹 脂膜片來作為YI值測定用樣品,使用自動分光光度儀(曰 立製造:U-3500型)來進行YI值的測定·。將無樣品的狀 態作為基礎來進行後台數值修正,求出使用樣品時的ΥΙ 值。在評價用樣品的製作時,使用金屬鹵化物燈無電極燈 D燈泡(FUSIONLH-10)來作為紫外線照射裝置,以60% 的出力,使用每1盞燈為240 W/cm功率(1〇〇%輸出時) 的三盞燈。紫外線照射裝置與樣品的距離為53 3 mm,最 終對樣品進行以照度計測定為1500mj/cm2 (±3〇mJ/cm2) 的能量的8.6秒的UV照射而進行光硬化性樹脂的聚合, 製作出樣品。而且,在光聚合後將樣品放置〗週之後,進 行YI值的測定。而且,加熱處理是使用恆溫器,將樣品 於溫度60°c的環境下放置500小時,隨後進行γι值的測 定。樣品製作條件或UV能量照射量或樣品放置時間會影 響到隨後的YI值,因此必須使該些條件一直相同而進行 YI值的測定。 [實施例10] 於由具有以下組成的光硬化性樹脂組成的混合液構成 的聚合用單體液中,混合0.1 wt%的聚合起始劑(汽巴精 化製造:Irgacure 184),對該混合物進行uv硬化,獲得 測定用樣品。 新中村化學工㈣造:U4HA (1Qw%) 9 200923450 [化4] >OCC(i CH2= (CH3)CHCOCH2 CH2〇CC(CH3)=CH2 •CHoOCCH—CH2 o ch2=chccch2 〇 三菱麗陽製造:PBOM ( 40 wt% )[化5] [化5]------1---丄[Determination of YI value of main component of photocurable resin] A photocurable resin sheet having a thickness of 2 mm and 1 cm square was prepared for use as a sample for YI measurement, and automatic spectrophotometry was used. Instrument (Hitachi manufacturing: the secret is the type) to enter the Y f YI value. The (4) of the finished product is used as a silk foundation to enter the background value correction of the lamp, and the γι value when the sample is used is obtained. In the production of the evaluation sample, a metal halide lamp electrodeless lamp D bulb (fusi〇= 29 200923450 LH-10) was used as the purple ray line irradiation device, and each lamp was used with a 60% output. Three lamps with 240 W/cm power (100% output). The distance between the ultraviolet irradiation device and the sample was 53.3 mm, and finally the sample was subjected to UV irradiation of 5.7 seconds of energy measured by an illuminance meter of 1000 mJ/cm 2 (±30 mJ/cm 2 ) to carry out polymerization of the photocurable resin. sample. Further, after the sample was left for one week after photopolymerization, the measurement of the YI value was performed. Further, the heat treatment was carried out by using a thermostat, and the sample was allowed to stand in an environment of a temperature of 60 ° C for 500 hours, followed by measurement of the YI value. Sample preparation conditions or UV energy exposure or sample placement time will affect the subsequent YI values, so the YI values must be determined by making these conditions the same. By using the above-mentioned method, 0.1 wt% of a polymerization initiator (manufactured by Ciba Specialty Chemicals: Irgacure 184) was mixed with each of the polymerization monomer liquids described in the following Table 2 as a main component of the photocurable resin. The mixture was subjected to UV hardening, and the results obtained by measuring the YI value are shown in Table 2. Further, an example using an amino phthalic acid acrylate having a polypropylene skeleton (manufactured by Roots Industrial Co., Ltd.: MPU11) is shown for reference. [Table 2] The polymerization solution monomer liquid YI value after heat treatment for 1 week, GX8662V 1.6 1.4 U4HA 1 1.1 PBOM 0.7 0.7 NPA 0.7 0.8 HDDA 0.8 0.8 c4da 1.6 1.8 MPU11 0.9 3.1 [Determination of YI value of photocurable resin mixture] 30 200923450 A circular-shaped photocurable resin film having a thickness of 10 mm and a diameter of 6 cm is produced as a sample for measuring the YI value, and an automatic spectrophotometer (manufactured by Kyoritsu: U-3500) is used to measure the YI value. . The background value correction is performed based on the state without the sample, and the ΥΙ value when the sample is used is obtained. In the preparation of the sample for evaluation, a metal halide lamp electrodeless lamp D bulb (FUSIONLH-10) was used as the ultraviolet irradiation device, and the power was 240 W/cm per lamp with a 60% output (1〇〇). Three lights when % is output. The distance between the ultraviolet irradiation device and the sample was 53 3 mm, and finally the sample was subjected to UV irradiation of 8.6 seconds of energy measured by an illuminance meter of 1500 mj/cm 2 (±3 μm/cm 2 ) to carry out polymerization of the photocurable resin. Take out the sample. Further, after the sample was placed for a week after photopolymerization, the YI value was measured. Further, the heat treatment was carried out by using a thermostat, and the sample was allowed to stand in an environment of a temperature of 60 ° C for 500 hours, and then the measurement of the γι value was carried out. The sample preparation conditions or the UV energy irradiation amount or the sample placement time may affect the subsequent YI value, and therefore it is necessary to make the conditions always the same and measure the YI value. [Example 10] 0.1% by weight of a polymerization initiator (manufactured by Ciba Specialty Chemicals: Irgacure 184) was mixed with a polymerization monomer liquid composed of a mixed liquid composed of a photocurable resin having the following composition. The mixture was subjected to uv hardening to obtain a sample for measurement. Xinzhongcun Chemical Industry (4) Manufacture: U4HA (1Qw%) 9 200923450 [Chemical 4] >OCC(i CH2= (CH3)CHCOCH2 CH2〇CC(CH3)=CH2 •CHoOCCH-CH2 o ch2=chccch2 〇Mitsubishi Riyang Manufacturing: PBOM (40 wt%) [Chemical 5] [Chemical 5]
CH3 CH3 CH2^CCOO(04HbO)9COC^OH2 三菱麗陽製造:HDDA ( 50 wt% )[化6] [化6] 〇 ο II Ιί ch2=chc〇一c6h12—〇cch=ch2 [實施例11] 將U4HA的比例設為20 W%,將PBOM的比例設為 30 Wt%,除此以外’以與實施例10相同的方法而獲得測 定用樣品。 [實施例12] 將U4HA的比例設為30 w〇//°,將PB0M的比例設為 20 wt°/。,除此以外,以與實施例相同的方法而獲付測 定用樣品。 [實施例13] 200923450 將U4HA的比例設為20 w% ’將PBOM的比例設為 20 wt°/〇,將HDDA的比例設為60 wt%,除此以外,以與 實施例10相同的方法而獲得測定用樣品。 [實施例14] 將U4HA的比例設為30 w%,將PBOM的比例設為 30 wt°/。,將HDDA的比例設為40 wt%,除此以外,以與 實施例10相同的方法而獲得測定用樣品。 [實施例15] 將U4HA的比例設為1〇 w%,將PBOM的比例設為 4〇 wt%,以50 wt%的比例使用ΗΡΑ來取代HDDA,除此 以外,以與實施例10相同的方法而獲得測定用樣品。 [實施例16] 以10 wt%的比例使用第一工業製藥製造的GX8662V 來取代U4HA,將PBOM的比例設為wt% ’除此以外, 以與實施例10相同的方法而獲得測定用樣品。 [參考例1] 將U4HA的比例設為1〇 W%,將PBOM的比例設為 40 wt%,將HDDA的比例設為40 wt%,除此以外’以與 實施例10相同的方法而獲得測定用樣品。 對於以上的實施例10〜16以及參考例1中所獲得的測 定用樣品,將測定YI值所得的結果示於以下的表3中。 200923450 [表3]CH3 CH3 CH2^CCOO(04HbO)9COC^OH2 Manufactured by Mitsubishi Rayon: HDDA (50 wt%) [Chem. 6] 化ο II Ιί ch2=chc〇一c6h12—〇cch=ch2 [Example 11] A sample for measurement was obtained in the same manner as in Example 10 except that the ratio of U4HA was 20 W% and the ratio of PBOM was 30 Wt%. [Example 12] The ratio of U4HA was set to 30 w〇//°, and the ratio of PB0M was set to 20 wt°/. Except for this, a sample for measurement was obtained in the same manner as in the examples. [Example 13] 200923450 The ratio of U4HA was set to 20 w%. The same procedure as in Example 10 was carried out except that the ratio of PBOM was 20 wt%/〇, and the ratio of HDDA was 60 wt%. A sample for measurement was obtained. [Example 14] The ratio of U4HA was set to 30 w%, and the ratio of PBOM was set to 30 wt ° /. A sample for measurement was obtained in the same manner as in Example 10 except that the ratio of HDDA was 40 wt%. [Example 15] The same ratio as in Example 10 was carried out except that the ratio of U4HA was set to 1% w%, the ratio of PBOM was set to 4% by weight, and yttrium was used in place of HDDA at a ratio of 50% by weight. The sample for measurement was obtained by the method. [Example 16] A sample for measurement was obtained in the same manner as in Example 10 except that GX8662V manufactured by K.K. Pharmaceutical Co., Ltd. was used instead of U4HA in a ratio of 10 wt%, and the ratio of PBOM was changed to wt%. [Reference Example 1] The same procedure as in Example 10 was carried out except that the ratio of U4HA was 1 〇 W%, the ratio of PBOM was 40 wt%, and the ratio of HDDA was 40 wt%. Sample for measurement. With respect to the samples for measurement obtained in the above Examples 10 to 16 and Reference Example 1, the results obtained by measuring the YI value are shown in Table 3 below. 200923450 [Table 3]
~J--LiP L_._J_-Ϊ2~~ H用具有以上的實施例1G〜16及參考例1的組成的光 性树脂’以與實施例1相同的方法制 ^ ^ 勺、、且成的 史化_1,以與實施例i相_方法可製作導光部材。 竹—Ϊ ^上可知,根據本發明,可獲得尤其作為將L E D用 一-人光源的面光源裝置用而極為薄型且色特性優里的導 =材。而且’藉由使用轉印用模部材,連續地使用光硬 i樹脂來進行形狀轉印,可製造出生產性優異且相對較 廉價的導光部材。 雖然本發明已以實施例揭露如上,然其並非用以限定 本發明丄任何熟習此技藝者,在不脫離本發明之精神和範 圍内,當可作些許之更動與潤飾,因此本發明之 當視後附之申請專利範圍所界定者為準。 【圖式簡單說明】 ,&圖1 (a)、圖i (b)是表示本發明的導光部材的實施 形恶的示意性剖面圖。 圖2是表示本發明的導光部材的實施形態的示意性剖 面圖。 ^ σ 圖3是表示製造本發明的導光部材的方法的實施形態 34 200923450 的示意圖。 圖4 ( a )、圖4 ( b )是轉印用模部材的轉印面的形狀 轉印的說明圖。 圖5是轉印用模部材的轉印面的形狀轉印的說明圖。 圖6是表示使用本發明的導光部材的面光源裝置的實 施形態的示意性分解立體圖。 圖7是表示相對於導光距離q的色座標x、y的變化的 圖。 圖8是表示相對於導光距離q的色座標x、y的變化的 圖。 圖9是表示相對於導光距離q的色座標x、y的變化的 圖。 圖10是表示相對於導光距離q的色座標X、y的變化 的圖。 圖11是表示相對於導光距離q的色座標X、y的變化 的圖。 圖12是表示相對於導光距離q的色座標X、y的變化 的圖。 圖13是表示相對於導光距離q的色座標X、y的變化 的圖。 【主要元件符號說明】 2:透光性片材 4、6 :光硬化性樹脂層 21 :第1表面 35 200923450 22 第2表面 31 T字模 32 熔融膜 33 冷卻輥 34 、36、41 : 轉 印用模部材 35 、37 :紫外 線 燈 38 、42 ' 44 : 導 輥 40 導光部材 50 LED 60 稜鏡片材 70 :反射膜 202 :第2透光層 204、206 :第1透光層 C :線 N:喷出喷嘴 LM :亮度計 36~J--LiP L_._J_-Ϊ2~~ H was prepared by the same method as in Example 1 using the optical resin having the compositions of Examples 1G to 16 and Reference Example 1 described above. In the history of _1, a light guiding member can be produced by the method of the embodiment i. As is apparent from the present invention, according to the present invention, a conductive material which is extremely thin and has excellent color characteristics, particularly for use as a surface light source device using a human-light source for L E D can be obtained. Further, by using the transfer mold member, the shape transfer is carried out by continuously using the photohard i resin, whereby a light guide member which is excellent in productivity and relatively inexpensive can be produced. Although the present invention has been disclosed in the above embodiments, it is not intended to limit the invention, and the invention may be modified and modified without departing from the spirit and scope of the invention. This is subject to the definition of the scope of the patent application. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1(a) and FIG. 1(b) are schematic cross-sectional views showing the embodiment of the light guiding member of the present invention. Fig. 2 is a schematic cross-sectional view showing an embodiment of a light guiding member of the present invention. ^ σ Fig. 3 is a schematic view showing an embodiment 34 200923450 of a method of manufacturing the light guiding member of the present invention. Fig. 4 (a) and Fig. 4 (b) are explanatory views of the transfer of the shape of the transfer surface of the transfer mold member. Fig. 5 is an explanatory view of the transfer of the shape of the transfer surface of the transfer mold member. Fig. 6 is a schematic exploded perspective view showing an embodiment of a surface light source device using the light guiding member of the present invention. Fig. 7 is a view showing changes in color coordinates x and y with respect to the light guiding distance q. Fig. 8 is a view showing changes in color coordinates x and y with respect to the light guiding distance q. Fig. 9 is a view showing changes in color coordinates x and y with respect to the light guiding distance q. Fig. 10 is a view showing changes in color coordinates X and y with respect to the light guiding distance q. Fig. 11 is a view showing changes in color coordinates X and y with respect to the light guiding distance q. Fig. 12 is a view showing changes in color coordinates X and y with respect to the light guiding distance q. Fig. 13 is a view showing changes in color coordinates X and y with respect to the light guiding distance q. [Main component symbol description] 2: Translucent sheet 4, 6: Photocurable resin layer 21: First surface 35 200923450 22 Second surface 31 T-shaped mold 32 Melt film 33 Cooling rolls 34, 36, 41: Transfer Molding members 35, 37: ultraviolet lamps 38, 42' 44 : guide roller 40 light guiding member 50 LED 60 稜鏡 sheet 70: reflecting film 202: second light transmitting layer 204, 206: first light transmitting layer C: line N: ejection nozzle LM: luminance meter 36
Claims (1)
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| JP2007272974 | 2007-10-19 | ||
| JP2007340182 | 2007-12-28 |
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| TW97140051A TW200923450A (en) | 2007-10-19 | 2008-10-17 | Light guide, method for manufacturing the same, and surface light source device having light guide |
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| JP (1) | JPWO2009051203A1 (en) |
| TW (1) | TW200923450A (en) |
| WO (1) | WO2009051203A1 (en) |
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| CN102411163B (en) * | 2010-07-23 | 2013-07-10 | 颖台科技股份有限公司 | Light guide device, backlight module and liquid crystal display with light guide device |
| TWI418864B (en) * | 2010-07-23 | 2013-12-11 | Entire Technology Co Ltd | Light-guide apparatus with micro-structure, and a backlight module and an lcd device having the same |
| CN102411164B (en) * | 2010-07-23 | 2013-07-31 | 颖台科技股份有限公司 | Light guide device, backlight module and liquid crystal display with light guide device |
| JP5636884B2 (en) * | 2010-11-08 | 2014-12-10 | 凸版印刷株式会社 | Light guide plate, backlight unit, display device, and method of manufacturing light guide plate |
| WO2012111806A1 (en) * | 2011-02-18 | 2012-08-23 | 住友化学株式会社 | Inspection device and inspection method, and manufacture method using this inspection method |
| GB2495477A (en) * | 2011-10-04 | 2013-04-17 | Exxelis Ltd | Method of making a lightguide |
| JP5738367B2 (en) * | 2013-08-19 | 2015-06-24 | シーメット株式会社 | Optical three-dimensional model with low yellowness |
| CN109891150A (en) * | 2016-06-10 | 2019-06-14 | 康宁股份有限公司 | Micro-structural and patterned light guide plate and the equipment including the light guide plate |
| JP7046953B2 (en) * | 2016-12-29 | 2022-04-04 | コーニング インコーポレイテッド | Light guide plate with fine structure and pattern, and equipment using it |
| KR20190044302A (en) * | 2017-10-20 | 2019-04-30 | 코닝 인코포레이티드 | Microstructured light guide plates and methods of manufacture |
| JP7696783B2 (en) * | 2021-08-05 | 2025-06-23 | セーレン株式会社 | Light guide plate and light emitting module |
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| JP4191498B2 (en) * | 2003-01-23 | 2008-12-03 | 日東電工株式会社 | Optical element, manufacturing method thereof, and liquid crystal display device |
| JP4411997B2 (en) * | 2004-02-13 | 2010-02-10 | 日立化成工業株式会社 | Light guide and surface light source device |
| JP2006154185A (en) * | 2004-11-29 | 2006-06-15 | Toppan Printing Co Ltd | Method for producing light guide plate having fine uneven pattern and light guide plate |
| JP2006294256A (en) * | 2005-04-05 | 2006-10-26 | Mitsubishi Rayon Co Ltd | Light guide for surface light source device and surface light source device |
| JP5137581B2 (en) * | 2005-11-17 | 2013-02-06 | 旭化成ケミカルズ株式会社 | Light guide plate |
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2008
- 2008-10-16 WO PCT/JP2008/068796 patent/WO2009051203A1/en not_active Ceased
- 2008-10-16 JP JP2008552169A patent/JPWO2009051203A1/en not_active Withdrawn
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| JPWO2009051203A1 (en) | 2011-03-03 |
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