TW200901945A - Textile including X-ray detective material, bandage detective for X-ray, and producing method of bandage detective for X-ray - Google Patents

Abstract

To provide a textile including a X-ray detective material having a high detective resolution by using a X-ray detective machine, a bandage detective for X-ray comprising such textile thereof having good elasticity, and a producing method for such bandage. Thus, the present invention relates to a bandage detective for X-ray comprising a textile including a X-ray detective material etc, wherein a sticky protecting means consisting of a substrate and a pressure sensitive adhesive layer is comprised, and a pad is provide on the sticky protecting means, which is composed of a textile including a X-ray detective material covered by partially or wholly by protecting means and arranged in the specific distance in the textile.

Description

200901945 IX. Description of the invention: [Technical field of invention] Detecting month? h There are fabrics containing Xf-line detectable materials, X-ray measurement Si: aster; and x-ray inspection, ΐ detection 53⁄43⁄43⁄43⁄4 f L · [Prior Art] 有, 田 m braided belts, etc., which are detached from the food and are mixed into the food, etc. The adhesive layer 105 and the 塾: ^, the undercoat layer 1 〇 4 102 - part of his f have :: 1: G1 ’ ? Support Document 1). In addition, as a 'Resin film of the patent material 103', or a 12-dimensional intrusion of a metal material, or a miscellaneous interfiber and a weaving of a metal fiber, the t-belt and the first and the The surface is integrally formed and stretched (to prevent the tape 202 from being damaged) 203 Patent Document 2). In the case of the contraction of the 14th (for example, 'see patent diH day), the actual fairness is 3-13304 (the scope of the utility model Γ document 2: 曰本特开属-_号 (patent application 200901945 [invention content] However] 'patent document 1 The first-aid bandage disclosed in the present invention has a problem that the sensitivity of the X-ray detector is low due to the uniform arrangement of the metal material in a part of the baffle body forming the substrate, because the type and form of the current metal material are limited. Moreover, the adhesive tape disclosed in Patent Document 2, although the laminate layer (metal particle adhesion layer) is on the surface of the substrate without impairing its degree of extension, the metal layer is easily peeled off from the surface of the substrate, and The detection is prone to deviations, and there is a significant problem that the X-ray S is significantly damaged by the expansion and contraction of the first-aid bandage 4, which is difficult to be placed at a specific position, or a feeling of foreign matter is generated.

J, the sensitivity of the x-ray detector is good, and it is difficult to generate 7 from this x. The detectable material is detected by the s-line ? ? ; 1 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009

;Ϊ ^-ί X Out??ίϊί (2) The line detector accurately detects. You can use the X-ray f' sensitivity to be less than μ, and you can get it. (Save 5; If there is any material, 位 位 准 二 准 准 准 准 准 准 准 : : : : : : : : : : : : : : : : : : : : : : : : : : : : The measurement of the material is sensitive to the t-strainable test line for the inspection of the instrument. If the test is repeated, the line is π to make the shot ρ*° where the X-WP-:, the shoulder is only one of the Because of the insufficiency, the tear is placed in the stretch. With the damage * / 3 Ζ 检 # 于 于 于 于 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉 泉The measured % of the test object can be covered by the line #: X*: Including the material for the light, the material is composed of such material, and can be woven by using X-ray detectable material such as seam = 乍'帛5加In the non-woven fabric, 'it is easy and the position is 疋' and thus the detachment is further reduced _==.

And, the x-ray-containing detectable (tetra) I 200901945 3 constituting the present invention is selected from the group consisting of polyester fiber, polyamide fiber, polyacrylic acid (four) city dimension, polyamine sl fiber, polycondensation dimension, polyethylene; rayon And at least one of cotton fibers, pulp fibers, and polyvinyl chloride fibers. m π颂•跃 By using the transparent fiber in this way, it is not only easy to sigh ίίΣίί material! ^ knows the state of being covered, exists in position 'and easy to woven the wire in ίί; ί non-woven, and can stably improve the X aA, the fabric of the invention containing the Χ-ray detectable material J: The ray-ray detecting material is arranged at equal intervals in the 3' plane range: # The configuration of the ray detecting material becomes easy, and the HX ray can be checked With a small amount of force applied, it is still possible to effectively prevent deviation from a specific position. Further, since the arrangement is performed at equal intervals in the above range, variations in sensitivity are not required, and it is possible to accurately recognize not only the non-existent position of the X-ray detectable material but also the non-existent position of the X-ray detectable material. An x-ray detectable material is placed between the children, and (10)I is used for x-ray detectable materials. Other values, such as values in the range of 65 to 100 mm. It can also be configured for intervals of more than 60_200901945 lOinm, 2 〇mm === minus ^, for example, it can be mixed. Configuration, 30-day interval configuration, χ ray detectable material cloth $ ί sensitivity of the meter, f and halogen: t increase for X-ray inspection containing X-ray detectable material 4 帛 4 "f is added" Cloth-specific shape and 'even for non-metallic materials, Jin, De late P glass, shells and stones, can also be fat-free, 'easy to keep inside the X-rays containing the i-materials. The value is better for her when the average particle size is

By configuring G, the specific ray-detectable material of the X-ray detector can be obtained in a spherical shape, and the singularity of the lion can be specified. The cloth box f containing the x-ray detectable material which is not invented at the time of inspection can be improved by the Π冓 ' ', and the other is 由于 嚣 01 01 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣 嚣Reduced functionality. And when the fabric constituting the X-ray detectable material of the present invention, the fabric has at least a laminate of the first fabric and the second fabric, and the X-ray detectable material is disposed in the first cloth and the second Between the cloths. By doing so, the fixing of the X-ray detecting material to the cloth containing the X-ray detectable material can be improved, and the deviation from the specific position can be effectively prevented. Further, since a plurality of fabrics (first cloth and second cloth) are used to sandwich a specific X-ray detectable material from the upper and lower directions, it is possible to form an X-ray detectable material from the outside without being recognized. When used as an absorbent pad in a bandage, the foreign body sensation can be further alleviated. Further, another aspect of the present invention is a bandage for X-ray inspection, comprising: a bonding protection member comprising a substrate and an adhesive layer; and an absorbent pad provided at a specific position on the bonding and protecting member, the x-ray detecting The bandage is characterized in that the absorbent pad is composed of a fabric containing an X-ray detectable material which is attached to the X-ray detectable material which is fully or partially covered with the covering in the fabric (woven or non-woven fabric). Configured at specific intervals. That is, since the absorption pad contains a specific X-ray detecting material, it is. This makes it possible to produce a bandage for X-ray detection which is stable not only to the sensitivity of the X-ray detector but also without compromising the stretchability. Therefore, even in the case of being mixed with a metal package, it is possible to detect using x-ray detection with good sensitivity. In addition, at the stage of the fabric containing the X-ray detectable material, although a plurality of X-ray detectable materials are prepared and arranged at a specific interval, at least one ray may be included in the stage of processing into the shape of the absorbent pad. Just check the material. Further, in the case of the X-ray detecting bandage of the present invention, it is convenient to use the adhesive of the 200901945 material (according to JIS-L, 96) to maintain good use as a can body and to obtain a line for metal inspection. When the detector is mixed with the base material, the adhesive is formed by the fact that when the bandage is mixed with the food of the food, the manufacturing process can be easily observed by visual inspection. The method of manufacturing the bandage of the X-ray detecting tape of the special tape-protecting component of the bonding protection component, the step of collecting the pad: forming the bonding protection component comprising the following materials to form the absorption In the step of the pad, the upper ray detectable material cloth is tied to the fabric, and the material is disposed at intervals of the material of the covering material; and the laminated adhesive protection detection: the specific m temple jjjj of the material is determined to be 2 X-rays塾Materials' Therefore, the absorbing pad is cut into i=3=:Yi 5 200901945 Gold 2 Time χ: X-ray inspection with good sensitivity. Line Detector Factory, [Embodiment] [Embodiment 1] ..!〇%i :10b?t la^f4L74 II. (10) χ-containing ray can be detected 43⁄4 people cloth n:: cloth x-ray inspection material . 帛 ,, line! 布 cloth (帛 / staple) method, air laying method, melting ^; m ^ t bi〇 = y lace) 12 200901945 straight furnace for the shape of the ,, for example length 15 ~ (10) coffee, should be. A non-woven fabric composed of two short fibers of 6 ΙΟΟμιη is entangled with each other, and is, for example, a long fiber of lm to 100 m or more and a long cold of 5 〜. The value of 100 mm is entangled with each other and maintained in a non-woven fabric shape, and nt ln sets the thickness of the fabric (uncompressed state) to a value within the range of the value of G·5 to 3 mm. Moreover, the value determined by 33 is more appropriate. The actual rule is set to such a thickness of the fabric, and the balance between the speciality and the long-term secret fa1 can be well realized. According to this, since the cloth is too thin, there is a case where the cloth is lowered: or the formation of the elongated object becomes difficult. On the other hand, if the cloth is too thick, it will be difficult to reduce the fabric or make it difficult to compile the long object. If the medium == is the thickness of the fabric, it can be suitable for in; the value of the weight of the fabric (uncompressed state) is set to the range of mg m, and the value is set to 30~300g/rn2. Preferably, the value in the range of 5 〇 to i5 〇 g/m 2 is set, and by setting the weight of the cloth, the specific operability and the ease of intercalation of the elongated object can be well achieved. Balance. That is to say, this is because when the cloth is too light, the cloth may be formed, the workability is lowered, or the formation of the elongated object becomes difficult. On the other hand, if the cloth is too heavy, the operation of the cloth may be reduced, or the formation of the elongated object may become difficult. Further, it is preferable to set the volume density (uncompressed state) of the fabric to 13 200901945, 0. 005~0·5g/cm2, and set the value in the range of 〇·01~0· lg/cm2 by %. Preferably, it is more suitable to use the value in the range of Hudingjie〇·〇5~0. 08g/cm2. The reason is that by setting the bulk density of the cloth, the specific operability of ^ and the ease of intercalation of the elongated object are also 丄 = 丄 because the volume density value of the fabric is small, r- 帛, the workability is reduced, or the formation of the long object becomes more difficult, which is due to the decrease in the operability of the volume density value of the cloth, or the long fit = end (2) isi: when the cloth * bulk density is Workable, the fabric is selected from polyester fiber, polyamide fiber, and! Preferably, at least one of acrylic fibers, polyolefin fibers, polyurethane fibers, individual fibers, and cotton fiber paper (10) i-gas fibers is used. In the case of fabrics made of such fibers, it becomes easier to manufacture the fabric, and in the case of the absorbent pad in the second layer, the absorption of the body fluid and the liquid medicine is used as the dimension. If the cloth is made of rayon and polyester fiber, and the mixed fiber of polyethylene and wax is made of I propylene fiber and polyester fiber, the fiber composition between light and durability can be obtained.

As shown in Fig. 1b, the embossing 16 of at least the first non-stretched right 10a (including the first-web layer, the following phase H1〇b (3 second web layer, the same below)) is woven into The first - non-woven pool and the second weaving cloth · 200901945

After the H change position ^; then {seven 'J# person special 1 edited from m material ^) #射材检α测可成检线结构 can shoot this line X If the shot is stopped by X The line shape can be long and rational, and it is easy to cover. It is used to be used as a detector for the detection of X-ray detectable materials. It is used as a detector for the detection of stretcher Ϊ 了 了 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效 有效A non-woven fabric and a second non-woven fabric are provided between the outer surface of the second non-woven fabric 2. the covering material 12 can be detected at a specific interval (fgg-covered X-ray j '2a is a substantially cylindrical The cross section of the elongated object 16 in which the "ray detecting material 12 is covered with the covering material 14" and arranged at equal intervals is

19, the rib pattern is substantially cylindrical X-ray detectable; bf * % L = a plurality of filaments (fibers) of the covering 2 covered 'and elongated at equal intervals to = 榖The part is equipped with a X-ray-detectable material, and the covering 14 made of the material (fiber) is covered with a wire 15 by using a wire 15 200901945, which is a substantially rectangular X-ray material 14a. The base material for a covering material in one part of the covering material 14 is a long form of the covering material 16 S which is another part of the covering material 14 and is covered with a 'area' at equal intervals. Ethylene foam, silicone rubber, natural rubber, etc. The detection of the A-shaped rectangular x-ray shown by ^ & ® is also not particularly limited, and can be obtained by twisting a metal poise or a metal plate into a specific width. The outlines of the elongated objects 16 are arranged to be covered, and the X-ray soft spherical lion iron, which is measurable (elliptical), is immersed in the U-shaped = f material. That is, the thus made as the flute 9r> E3 cuts the elongated object w by the shape 16' as shown in Fig. 2e, as shown in Fig. 2e, and the red record is not recorded. The X-containing detectable material of the shirt is, and in the specific county newspaper Ifi shown in Figures 2a to 2e, since the X-ray detectable material is arranged as discontinuous = long ϋ 16, it can provide, for example, damage. When the X-ray-containing material and the pad are not stretched, as shown in Fig. 2a, it is preferable that the X-ray detecting material 12 of the specific county is entangled at equal intervals in the range of 3 to 60 mm and covered with the covering 14. (1) Configuration, that is, to detect the X-rays contained in the elongate object: p, 丨妯 夕 ί 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围 围In the fabric of a specific long X-ray detectable material, the collateral detectable material deviates from the position of the financial position. Moreover, in order to effectively prevent x-rays from being detected, not only the adjacent intervals of the detectable materials, but also the position of the material can be detected, and the if f is placed in the position. Therefore, the X-rays which can be processed by using the cut-off device and the X-rays are so sensitive to the X-ray detector that they are included in the elongated body at equal intervals. That is to say, this fx ray detectable material is arranged at equal intervals, 'for example, when using _band absorption 塾, #供不(四) end band stretching (4) containing x-ray can be 17 200901945 x ray ray detectable material to select From iron (including (four), stainless steel, aluminum, copper, silver, antimony (sentences including iron ore), film, film, glass, shell and / head, ί: step, high to x shot for easy processing The X-rays of a specific shape can be detected and the 2 series is due to the fact that even the non-metallic material bones and the S-plates are not only glass-like, but also light-weight, and the sound is held in the cloth (10) X-ray detection. Instrument $角ί ϋ line detector, metal (including _ as X-ray using iron according to this ^ if and dry _, because the shutdown is almost / / / I. The state of the wrap is there ί i ' f ϊ time to play For the X-ray detector, metal regrets ~ Μ 用 用 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀When adding a specific force, the volume is more than the amount of gold, and the type of the material is often in the shape of the material and is limited to the average particle size of the X-ray detectable material. The value of the ball is equivalent to the range of 0.1 to 3 legs. η ! The average particle diameter of the line detection material is less than the value of O.limn, and the detection sensitivity of the X-ray detector may be significant. When the gold particle size exceeds 3 mm, the texture is enhanced, or the stability of the x-ray detecting material contained in the enamel is 平 初 ) ) ) 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 And the value in the range of 0.2~lmm is more suitable in the range of 0.3~O.Smm. The value is shot and I is in the production line. When the material is linear, the average length is e. It is more suitable to be in the range of 0.3 to 3 mm dry circumference. Improve the use of X-ray detector, metal tSi ^ sensitivity, and otherwise reduce the linear ray contained in the flat material of the absorbent pad. Test material Ο range (10) find. · (d) face should be set to (^ ugly ^ "~ ^ circumference value is more than propylene s dimension is 5 = self =, dimensional, poly, fiber, polyolefin fiber m «fiber and polyvinyl chloride hexahydrate? From ??' by the fiber, woven into the fabric becomes more easy, and X-ray can be detected _=中易变19 200901945 ΙίΜί^ΐ外^! The thickness (diameter) of Yu Weiwei is set to, for example, a value in the range of μιη, and it is also possible to collect a plurality of such fibers and 捻 [Example 2] - The second embodiment is as shown in Fig. 4a and Fig. 4b, which has a substrate 58 and a bonding member 6g, and a fabric 18 of a hybrid protective component. The X-ray detecting material 12 which is entirely or β-coated with the covering material 14 is disposed at a specific interval. 50 ΪΓ 构 ί 实施 实施 实施 实施 实施 1 1 1 1 1 1 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材In the case of the adhesive protection component in the sputum, the sizing agent and the sulphur sputum sputum are exemplified by a membrane such as a polyurethane membrane, a phenyl sulfide membrane, a polyimine membrane, and (2). When the polythene film is used to form a substrate or a non-woven fabric as a substrate, the material & can be used to suppress the low humidity, and the adhesive protection component of the barb with excellent followability of the activity is _ίίί .曰 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 获得 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材The value in the range of 疋成.Na is more suitable. When ί二美=The ratio of the substrate is too large and the operation is difficult. The surface of the substrate is preferably provided with a reinforced exfoliation component. Use the stripping assembly, use the outside, 3 swing function iSSSi material is appropriate, or "constant (2) thickness value is appropriate and 'to make the thickness of the substrate into a 5~2 shoulder _ range of mechanical ίίίί low thickness If it is less than 5 (10), there is adhesion and ίίίί 降低 ΐ ΐ 从而 从而 从而 从而 从而 从而 从而 Ο 的 的 的 的 的 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 It becomes more difficult, and it is easy to derive the value of 5S from the skin etc. in the part of the peeling and the (4) component, etc. (f is set to 10~i,000*·1"1 in the range of Μδ It is more suitable for the range of 15~_μηι. Specification 11 夕^0^^ Temple 5: 昃5 extension rate (depending on the thick sound of this industrial material ^ ις眭疋When it is 15 (10) or more, if the basis drought is 5 to 15 μm, it is easy to obtain an excellent feeling of use. (3) The buffer layer 200901945 has excellent properties of non-protective components and substrates, not only Protective effect of the affected area. When the surface of the layer is uneven, the shape is such that the buffer layer is made of non-woven fabric, etc., and one of them is f.'.: a gas epoxide polyamine s resin, a polypropylene resin. , Polyacetate resin, or polythickness·· 10~ΙΟΟμιη Unit weight: 1〇~lOOg/y (4) Hydrophobic treated layer and, although not shown, the substrate layer (including the layer)宜. He Zhihan α is placed in the hydrophobic area ίίΐ two to make the brush work, outdoor objects [the SSI ring! Adhesive protection component stripping. 2 and effectively prevent the b矽 椒 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( The value in the range of ~2000g/m2.24 hours is suitable. The reason is 'by controlling the moisture permeability of the substrate in this way, even in the case of passing brush work, outdoor work or medical field, etc., it is also easy to prevent 22 200901945 from: thus not only preventing the adhesion protection component from the sanitary environment. The peeling of the substrate with the value of ii is set to i5GGg/m2.24 hours () (6) identification mark and decorative layer, ίί layer 予 予, but for the surface setting of the substrate Mark Song; use f to set digital mark, Chinese mark, graphic mark, etc., you can see - the best fit: ί "5ίί can significantly improve the use of adhesive protection components due to the display of digital patterns, Chinese characters As a decorative U layer, the decorative layer such as the pattern and the shape of the pattern: the embossed pattern or the photographic pattern can not only mention the ease of use of the adhesive protection component, but also enhance the value of the scent. In particular, by providing a decorative layer containing a fluorescent agent, it is possible to improve the visibility at night. (The base metal particles are as shown in Figs. 4a and 4b, and the base material 56 for the base material 58 of the adhesive protective member 6 is contained in the base material 56. The reason is that the metal particles are contained by The X-ray in the absorption pad can be used to detect the interaction between the material and the metal particles in the substrate. That is, the system can further improve the quality of the instrument and the X-ray detector. X-ray inspection of components 23 200901945 The sensitivity of the bandage. Moreover, the hunting contains such metal particles, and when the substrate of the point-and-matching can-group is mixed into food, etc., it can also be detected by a measuring instrument or an X-ray detector. The condition is detected. Further, the type of the metal particles is not particularly limited, and is selected from the group consisting of S?, and the class S is suitable for the improvement of the base material: : The sensitivity of the instrument and the metal detector, and the angle of the cheaper ray detector, the metal detector, and the low-intelligence, the use of iron particles is preferred, and the sensitivity of the beta instrument. Shoot The average particle size of the metal particles in the detector and metal detection range is G·5, the value of m is 5; the gold diameter is less than 0, and the sensitivity of the detector is loyal to the measuring instrument and the metal in the substrate. If it is not 'there is a uniform dispersion reduction. Ten difficulties, or the flexibility, extension of the substrate 2, so the value of the average particle size of the metal particles is set to 3~25 Qing 24 200901945 It is preferable to set the value in the range of 5 to 2 〇Mm. The metal λ amount is taken as the weight of the genus, and the addition amount of the genus granule is reduced to 3 (the value within the 3 weight is the reason for the silk Ϊ) If the amount of the metal particles added is less than G 1% by weight, there is a uniform dispersion in (2). Therefore, when the total amount of the coffin is 100% by weight, The value of i ΐ 疋 疋 疋 3 3 3 3 3 3 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2. Pressure sensitive adhesive, acrylic humiliation 6 5 often J and sensitive adhesive layer to use organic Na ^, the reason is, by The use of an organic polyoxane-based pressure-sensitive adhesive can exhibit moderate adhesion to the skin, and can also improve creep resistance, water resistance, and chemical resistance. Also as such an organic polyoxane pressure A representative example of the sensitive adhesive is, for example, an organic polyoxyalkylene obtained by dehydration condensation of a fluorene resin having a structure represented by the general formula (1) or the general formula (2). 25 200901945 CH, ?H3 /R1 (. General formula (1)

HO-SI—〇-i-si-〇-f-SI-〇H CH3 \ R2 /n CHS 二^和' respectively denotes methyl or stupid, "indicates CH3 H3C-SI-CH3 〇HO- -- SI—Οι Ο H3C-S 卜 CH3 CH-, Η Formula (2) (In the formula (2), m represents an integer of 1040000.) Further, in the formula (1), R1 and R2 each represent a fluorenyl group. Or, in order to impart heat resistance to the adhesive layer, the value of the methyl group and the base group (methyl/phenyl group) is set to be in the range of 25/75 to 98/2, and the value is set to 85. Values in the range of /15 to 95/5 are more suitable. In the white formula (1) or the general formula (2), in consideration of the workability in the adhesive layer of the cloth, the viscosity of the pressure-sensitive adhesive is usually adjusted to 2000 to 200000 cP (25t:) to adjust 11 and 1! The value is appropriate. And added to the organic polyoxyalkylene-based pressure-sensitive adhesive (integral ft 1 〇 30% by weight) or in combination with the organic polyoxo sulphur-sensitive adhesive (the total amount of 1 〇〇 weight) %) uses an acrylic adhesive. By using such an acrylic adhesive, the combination of the acryl and the b'b does not reduce the cohesive force of the adhesive, and the adhesion can be easily improved. Examples of the type of the f-acrylic acid-based adhesive include propylene, which is exemplified by di-hexyl-ethylhexyl acrylate and butyl acrylate. 26 200901945 An acid-based copolymer is used as a representative example. Further, the mixing ratio of the above 2-ethylhexyl acrylate and butyl acrylate is adjusted so as to be 20:80 to 80:20 by weight: 20:80 to 40:60. In this case, if the ratio of 2-ethylhexyl acrylate is too small, the cohesive force of the binder may increase and the adhesive strength may decrease. On the other hand, when the ratio of 2-ethylhexyl acrylate is too large, the aggregation of the binder is too low, and the adhesive strength tends to decrease. Further, as the monomer component constituting the acrylic binder, acrylamide or ethylene-based acid may be blended in an amount of not more than 5% by weight based on the total amount. Further, considering the compatibility with the organopolyoxygenated binder, it is preferable to set the viscosity of the acrylic adhesive to a value in the range of 5 〇〇 to 2 〇〇〇〇 cp (25 ° C). (2) Additives

The addition of U to the binder composition is added as an additive to the specific effect. Such a preparation type can be exemplified by an anti-inflammatory drug preparation, an anti-inflammatory analgesic agent, a g-drug 2, an expectorant, an asthma drug, an anti-hypertensive agent, an antihistamine, a town, an anesthetic, a vitamin, and the like. A single one or a group like S(9)! The sigh is G.1~30% by mass. The value of __ is the equivalent of the body coupling agent, etc., or two of the extender, 27 200901945 (3 ) Peeling adhesive force 谇Jis ζ〇237 measured the peeling strength of the tape ίίί / /: mode peeling, adherend: stainless steel plate, peeling speed: 300mm / minute) set to 3 ~ 20N / 25ram range The value is appropriate. The taste-to-adhesive force is less than 3N/25mm. The condition of S is easy to lick the skin, etc.: Therefore, the peeling of the bandage is sticky. 9: ι^25- Sticky. #面Ο Type: Organic polyoxyalkylene adhesive thickness: 10~ΙΟΟμηη [Example 3] Specific position f on the component 6〇, adhesion protection m 5〇, Jfx^( aTTo" (A) forming adhesion Steps for protecting the component 28 200901945 The step of arranging the adhesive protection component and the absorbent pad at a specific interval for the coated or partially coated X-ray ray detectable material. 1. Preparing the substrate and the adhesive to prepare the material Then, by means of the i-material Is, as shown in Fig. 5a, it can be made into a metal strip and the 'adhesive ship can usually be prepared as a solution. The content 〇- 夕 can be the embodiment 2 2. Step of forming an adhesive layer (step (A)) The substrate to the m/g forming step l _ is shown, and the use of the material is not _ off, the machine can be equal to the substrate loading 3 == a ^ ter), It is preferable to apply the coating to the knives in combination, but it is preferable to form a viscous heat treatment. Or, a cross-linking treatment is performed to cut off the condition of the material 58 to be formed, and #f is formed with the base and the shape of the adhesive layer 52, thereby forming the adhesive protection member 6〇. 3. In the "1 line ί: Measure S' diagram of the absorbing enthalpy formation step (step (8)), the elongated material disposed at a specific interval of the coating material of the covering material 14 (filament 29 200901945 is detectable) The material is thus clamped into the X-ray, etc. at a specific interval between the M. The 衫 of the 衫 配 ' ' 的 的 的 ' ' ' ' ' ' ' ' ' ' ' ' ' 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 The ray can be inspected for special shape, and the third method is not used in the same way.: Roller 33^ Broken frame|External' as a device can use cutting machine, knife, paving, cutting 4. Adhesive protection component and absorption Steps of the stacking of the pad (Step Township (〇)?〇Ζ%

Bandage 50 for radiation detection. In addition, it is included in the set_X-ray detection end belt with 5 ' after the use of Jun & ice, ίί==ΐ (thickness) sensor, χ ray it test itJii It is advisable to check the materials.疋Example 30 200901945 [Example 1] 1. Preparation of bandage for X-ray inspection (1) Preparation step of substrate and binder As for the substrate, a metal particle-containing polyurethane film having a thickness of 30 μm was prepared (metal particle: iron ball) , average particle size: 7μπι, addition amount: 25% by weight, elongation (according to JIS-L-1096): 420 ° /., thirst (according to JIS Ζ -0208): 600g / (m2. 24 hours)). On the other hand, as a binder, an oxygen-bonding adhesive (viscosity: 7.5 Pa.sec (25 ° C), solid content: 55.1% by weight, adhesion strength 7 according to JIS Z0237, and a die: T die peeling and being prepared were prepared. Viscosity: stainless steel plate, peeling speed: 300 mm / min): 12. lN / 25 mm). (2) Step of Forming Adhesive Layer Next, an adhesive layer was formed on the substrate by a roll coater so that the thickness after drying became 25 μm. (3) Step of forming the absorbent pad After the charm f: Prepare an elongated object such as T: as shown in the 2b_, an artificial non-woven fabric of a thickness of 100 μm which is bent into a valley shape in advance

U The specific interval (25mm) is mounted as X-ray inspection 1 to the object, tends to: (4), and the shape is _^^ (the thickness is Π, ίίη is arranged in 1 fabric to distribute the elongated object to the two webs.层75g/c5) of the layer containing the x-ray detection material. 〇' * * : 150^2 ^ : The TS is cut off and the cloth containing the material of the Hi line is cut and processed by the cutting machine. Then, the X-ray detecting bandage as shown in Figs. 4a and 4b is formed at a specific position of the laminated layer of the layer 31 200901945 which has been laminated on the layered substrate. 2. Evaluation of bandages for X-ray inspection (1) X-ray detection (Evaluation 1) The prepared bandage was embedded in a 100 g peanut salad, and in this state, whether or not foreign matter could be detected by an X-ray detector . In other words, the X-ray detection property of the obtained bandage (η number: 100) was examined using an X-ray detector KD7305AW (manufactured by Anritsu Kogyo Co., Ltd.), and evaluated according to the following criteria. ◎: The result of detecting 100 out of every 100. 〇: 98 to 99 results were detected for every 100. △: The result of detecting 70 to 98 per 100 pieces. X : A result of detecting less than 70 per 100. (2) Metal Detectability 1 (Evaluation 2) The prepared bandage was embedded in a 100 g peanut salad, and in this state, a metal detector was used to investigate whether or not foreign matter could be detected. In other words, the metal detector of the bandage (n number: 100) obtained by the metal detector HA-01 (manufactured by Anritsu Kogyo Co., Ltd.) was examined and evaluated based on the following criteria. ◎: The result of detecting 100 out of every 100. 〇: 99 results were detected for every 100. △: The result of detecting 70 to 98 per 100 pieces. X : A result of detecting less than 70 per 100. (3) Metal Detectability 2 (Evaluation 3) The substrate (size · 2cmxl.9cm) in the obtained end tape is buried in 32 200901945 (4) Γ Detector HA-01 (Anli Industrial Machinery Co., Ltd. (η The metal test of number,) ◎: The result of detecting 100 out of 100. 〇·· is the result of detecting 99 out of every 100. △: The result of detecting 70~98 every (10). γ\ Ο X : A result of less than 〇 is detected for every 100. (4) Convenience (Evaluation 4) Convenience ◎ 〇 △ = Estimated _ band according to the following basis (η number: 3) The use of fully extended 'can be extremely easily wound on the finger. The base is fully stretched and can be easily wound around the finger. It can be wound on the finger with a little extension. X : It is hardly stretched and it is difficult to wind on the finger (toe). (5) Foreign body sensation (evaluation 5) The obtained bandage (η number: 3) is wound on ^, and the fork beam is evaluated by finger touch. The material is based on the material. The element does not feel X-ray detectable material. 〇: There is almost no X-ray detectable material. △. Slightly feel X-ray detectable material. X · An X-ray detectable material is clearly perceived. [Examples 2 to 5] 33 200901945 Evaluation of the evaluation Example [Comparative Example 1] [Comparative Example 2] r κ,. 2: Excluding the f-containing wire The elongate, and only 5 estimates were made in the same manner as in Example 1 [Comparative Example 3] In Comparative Example 3, according to Figure 6 斛 + a length 25_ was laminated between the electric ground material and the mat. The bandage of the base aluminum film was evaluated in the same manner as in Example 1. The drought was again 1〇0qing's 200901945 Table 1

Evaluation of Metallic Detectable Materials for X-Ray Detectable Material Substrates for Elongation 1 Evaluation 2 Evaluation 3 Evaluation 4 Evaluation 5 Type Average Length Type Average Particle Size Example 1 Wire 2. Omm Iron Particle Ί βία ◎ ◎ 〇 ◎ ◎ Implementation Example 2 Wire 2. 5mm Iron Particles Ί μιη ◎ ◎ 〇 ◎ ◎ Example 3 Wire 3. Omm Iron Particles Ί μπι ◎ ◎ 〇 ◎ Example 4 Wire 3. 5ram Iron Particles 7^m ◎ ◎ 〇 ◎ 〇 Example 5 Wire 4. Omm Iron particles 7 jum ◎ ◎ 〇〇〇 Comparative Example 1 No iron particles 7jUm X ◎ 〇 ◎ ◎ Comparative Example 2 Wire 4. Omm Iron particles 7 jum X ◎ 〇 Δ X Comparative Example 3 Ming film 13mmx25mmxlOO Iron Particles 7jum X ◎ 〇Δ Δ 35 ▼ ▼200901945 π & * In Comparative Example 2, the iron wire contained in the elongated shape was not used, and the wire was placed in the mat with a small tweezers. As shown in Table 1, the results of the bandages of Examples 1 to 5 all have high X-ray detection (Evaluation 1) and metal detectability (Evaluation 2 and 2 and regarding ease of use (Evaluation 4) and Foreign body sensation (evaluation 5) ^ ^ is good. In addition, the bandages of Examples 1 to 5 can be accurately and accurately detected not only in the X-ray detector but also in the metal detector. μ& On the other hand, Comparative Example 1 The bandage has good sensitivity to metal detection, use, and foreign body perception, but the X-ray detection system has significantly lower sensitivity. - In the bandage (1〇〇) obtained under the conditions of Comparative Example 2, for absorption The pad contains a bandage of wire (about 1/3 of the total), which is very sensitive to X-ray detectors and metal detectors. However, most of the resulting bandages (about 2/3 of the total) are in g. At the time of manufacture or g, the wire is detached from the absorbent pad, and the bandage itself has a significantly reduced sensitivity to the X-ray detector and the metal detector. That is, the bandage of Comparative Example 2 has one or more ends due to the ratio of the presence or absence of the wire. X-ray inspection with tape Detectability (Evaluation 2) is evaluated as extremely low., and, the bandage after the wire is detached cannot be used for the test of 3 to 4, and the shape of the enamel is also large due to the iron wire. It is difficult to wrap around the finger (toe). In addition, the wire is easy to move inside the pad, so when it is used for the finger (toe), it is still obvious that the bandage of Comparative Example 3 is metal-detectable. However, the X-ray detection system has a lower sensitivity. Further, due to the elastic force of the film, it is somewhat difficult to wind the finger (toe), and it is felt that there is little difference. [Examples 6 to 10, Comparative Example 4 to 6] In Examples 6 to 10 and Comparative Examples 4 to 6, except for the use of a metal urethane film having a thickness of 3 Å (extension ratio (according to JIS_L_1〇96 specification 36 200901945): 450 ° /., The X-ray test bandage was produced and evaluated in the same manner as in Examples 1 to 5 and Comparative Examples 1 to 3 except that the moisture permeability (as defined by JISZ - 0208): 720 g/m2 * 24 hours) was used as the substrate. The results obtained are shown in Table 2. 200901945 Table 2 r \ % ϊ

Metallic Detectable Material Evaluation of X-Ray Detectable Material Substrate for Elongation 1 Evaluation 2 Evaluation 3 Evaluation 4 Evaluation 5 Type Average Length Type Average Particle Size Example 6 Wire 2. Omm No ◎ ◎ X ◎ ◎ Example 7 ◎ X ◎ ◎ Example 8 Wire 3. Omm No ◎ ◎ X ◎ 〇 Example 9 Wire 3. 5 mm No ◎ ◎ X ◎ 〇 Example 10 Wire 4. Omm No ◎ ◎ X 〇 Δ Comparative Example 4 None or none XXX ◎ ◎ Comparative Example 5 Wire 4. Omm No XXX Δ X Comparative Example 6 Aluminum film 13mmx25mmxl00/zm No X ◎ X Δ Δ 38 200901945 2, not included in the long The wire of the state of the shape is placed in the mat with a small tweezers. As shown in Fig. 2, the bandages of Examples 6 to 10 and Comparative Examples 4 to 6 were detected by the field of the miscellaneous. However, the bandages of Examples 6 to 10 had a good emission green (tf# r The raw ("score 4") and the foreign body sensation (evaluation 5) are also good. ·> af, the bandage of Comparative Example 4 has good convenience and foreign body sensation, but X-ray detection and metal detection are remarkable. Lower Hi Silk Hi? 5 ί L The bandage of Comparative Example 5 is the same as the bandage of Comparative Example 2, and the iron content (about 2/3 of the total number) remains two: if, this 'Because there is no wire ratio in the bandage ί X-ray detection of the end band of the ray detection (evaluation is Detectability (Evaluation 2) is evaluated to be extremely low. Moreover, it is difficult to "Here the bandage is wound around the heart" when the wire is kept. The feeling of _ can still have a sense of foreign body. Sex # Although the metal has good detectability, but the X-ray detection, N*, if>/l /cry 〇8 ίίχ, the original f can be used to check the cloth (4), Use the graph to ίί, : or as a mark of the performance of the mark of the product; _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ When detecting the fabric of the material, the _ 配置 、 、 、 、 、 、 、 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 包含 。 由于A little foreign body sensation, 39 200901945 material is made of long objects, so it is not only easy to use, but also can be detected with good sensitivity using the X-ray detector shown in Figure 8. Therefore, even in X-ray inspection bandages When it is accidentally mixed into the metal package, etc., it can also be detected by an X-ray detector, and it is easy to prevent the intrusion of foreign matter. [Simplified description] 帛:^ : a - Figure b is for explanation The second to the second figure e of the X-ray detectable material is described in the fabric (non-woven fabric), and the elongated shape of the X-ray detectable material covered by the covering is the third to third figures c to A preferred example of a shape diagram of the elongated object in the second figure b. The metal detecting bandage used for the i1^b system is used for the purpose of the article, and the seventh figure w is used for explaining the conventional metal detecting. Bandage and the eighth picture is for the purpose of explaining the X-ray detector Fig. [Description of main component symbols] 200901945 ίο Fabric 10a, 10b Fabric 12 X-ray detectable material 14 Coating 16 Long object 18 Fabric 50 Bandage Ο 52 Adhesive layer 54 Metal particles 56 Raw material 58 Substrate 60 Adhesive protection component 101 First Aid Bandage 102 Support 1 / 103 Metal Material 104 Basecoat 105 Adhesive Layer 106 Pad 201 Bandage 202 Tape 203 Metal Layer 41

Claims (1)

200901945 X. Patent application scope: ϊThe fabric containing x-ray detectable materials as described in item »$», polyolefin fiber, polyurethane fiber, polyglycolate, g 4 · Xiangru The cloth containing the x-ray detectable material according to the first item: the material is arranged at equal intervals in the range of 3' planes to detect the following: \The gamma-containing ray according to the first item of the Shenli range is detectable Material cloth = 3⁄4, species,. Bone, rhyme, glass shell; and ϋ 6 · box, such as the application of x-ray detectable material according to the scope of the application of the scope of the first paragraph, as described in the scope of the patent When the ytterbium-containing measurable material is a linear object, the 8 fish, such as the χ i i i 范围 范围 范围 i i i i i i i i i 第 第 χ χ χ χ χ χ χ χ χ χ χ χ χ χ χ χ χ述=42 200901945 9· A bandage for X-ray inspection, comprising a bonded S-panel component comprising a substrate and an adhesive layer, and an absorbent pad disposed at a specific position on the adhesive protection component, wherein the absorbent pad is The fabric containing the X-ray detectable material consisting of the fabric containing the X-ray detectable material is arranged in the fabric at a predetermined interval by using X-ray detectable materials which are wholly or partially covered by the covering. 1) The X-ray detecting bandage as described in claim 9 of the patent application, the extension of the bean thread (4) illusion IS_WG9_ The X-ray inspection described in claim 9 of the patent application 刖 The substrate of the adhesion protection component contains metal particles. The bandage for detecting x-rays according to item 9 of the ninth section of the singularity i, the base material in the adhesive protection component of the first embodiment is colored. 〃τ 13. A method for producing a bandage for X-ray detection, characterized in that the adhesive protection member having a laminated layer and the X-ray detecting bandage of the absorbent pad disposed at the position of the bonding is characterized in that The method includes the following steps: (4) a method of forming the adhesive protection component; a method of: covering the fully or partially covered X-rays 35 and laminating the adhesion protection component and the absorption pad. 43