TW200811865A - Mixed-use memory array and method for use therewith - Google Patents
Mixed-use memory array and method for use therewith Download PDFInfo
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- TW200811865A TW200811865A TW96123305A TW96123305A TW200811865A TW 200811865 A TW200811865 A TW 200811865A TW 96123305 A TW96123305 A TW 96123305A TW 96123305 A TW96123305 A TW 96123305A TW 200811865 A TW200811865 A TW 200811865A
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Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C11/00—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
- G11C11/56—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using storage elements with more than two stable states represented by steps, e.g. of voltage, current, phase, frequency
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C13/00—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
- G11C13/0002—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C17/00—Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards
- G11C17/14—Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards in which contents are determined by selectively establishing, breaking or modifying connecting links by permanently altering the state of coupling elements, e.g. PROM
- G11C17/16—Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards in which contents are determined by selectively establishing, breaking or modifying connecting links by permanently altering the state of coupling elements, e.g. PROM using electrically-fusible links
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C17/00—Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards
- G11C17/14—Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards in which contents are determined by selectively establishing, breaking or modifying connecting links by permanently altering the state of coupling elements, e.g. PROM
- G11C17/16—Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards in which contents are determined by selectively establishing, breaking or modifying connecting links by permanently altering the state of coupling elements, e.g. PROM using electrically-fusible links
- G11C17/165—Memory cells which are electrically programmed to cause a change in resistance, e.g. to permit multiple resistance steps to be programmed rather than conduct to or from non-conduct change of fuses and antifuses
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C17/00—Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards
- G11C17/14—Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards in which contents are determined by selectively establishing, breaking or modifying connecting links by permanently altering the state of coupling elements, e.g. PROM
- G11C17/18—Auxiliary circuits, e.g. for writing into memory
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C2211/00—Indexing scheme relating to digital stores characterized by the use of particular electric or magnetic storage elements; Storage elements therefor
- G11C2211/56—Indexing scheme relating to G11C11/56 and sub-groups for features not covered by these groups
- G11C2211/564—Miscellaneous aspects
- G11C2211/5641—Multilevel memory having cells with different number of storage levels
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C2213/00—Indexing scheme relating to G11C13/00 for features not covered by this group
- G11C2213/30—Resistive cell, memory material aspects
- G11C2213/33—Material including silicon
Landscapes
- Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Semiconductor Memories (AREA)
- Read Only Memory (AREA)
Abstract
Description
200811865 九、發明說明: 【先前技術】 非揮發性記憶體陣列甚至當關閉裝置電源時仍維持其資 料。在可單次程式化記憶體陣列中,每一記憶體單元經形 成為處於一初始未經程式化狀態,並且可予以轉換成一經 程式化狀態。此項變更係永久性,並且此等記憶體單元係200811865 IX. INSTRUCTIONS: [Prior Art] Non-volatile memory arrays maintain their data even when the unit is powered off. In a single-programmable memory array, each memory cell is shaped to be in an initial unprogrammed state and can be converted to a stylized state. This change is permanent and these memory units are
不可擦除。在其它類型記憶體中,記憶體單元係可擦除並 且可重寫多次。 吞己憶體單元亦可變化於每一記憶體單元可達成之若干資 料狀態中。可藉由改變可偵測到之記憶體單元的某特性來 儲存一資料狀態,諸如在一既定施加之電壓或該記憶體單 元内一電晶體之臨限電壓之下流動通過該記憶體單元的電 流。一資料狀態係記憶體單元之一相異值,諸如一資料 或一資料 ’’ 1π。 一些用於達成可擦除或多狀態記憶體單元之方案複雜。 舉例而言,浮動閘極與S〇N〇S記憶體單元藉由儲存電荷來 運作,其中經儲存之電荷存在、不存在或電荷量改變一電 晶體臨限電壓。彼等記憶體單元係三端子式裝置,在對於 現代積體電路中競爭力所需的非常小型尺寸下,彼等記憶 體單元相對難以製造與運作。 其它記憶體單元藉由改變相對奇特的材料(如硫屬)之電 :率來運作。在大多數半導體生產設施中,硫屬難以配合 使用且可具挑戰性。 藉由具有以易於縮放至小 尺寸之結構使用習知半導體材 121888.doc 200811865 的非揮發性記憶體陣 料形成的可擦除或多狀態記憶體單元 列來提供實質上優點。 【發明内容】 本發明係藉由下令往、书s 咕〆、予以定義,並且在此段落中的 任何内容Μ應視為對請求項之限制。Cannot be erased. In other types of memory, the memory cells are erasable and rewritable multiple times. The swallowing unit can also be changed in several data states that can be achieved for each memory unit. A data state can be stored by changing a characteristic of the detectable memory cell, such as flowing through the memory cell under a predetermined applied voltage or a threshold voltage of a transistor in the memory cell Current. A data state is a distinct value of one of the memory cells, such as a data or a data '' 1π. Some solutions for achieving erasable or multi-state memory cells are complex. For example, the floating gate and the S〇N〇S memory cell operate by storing a charge, wherein the stored charge is present, absent, or the amount of charge changes by a transistor threshold voltage. These memory cells are three-terminal devices that are relatively difficult to manufacture and operate in very small sizes required for competitiveness in modern integrated circuits. Other memory cells operate by changing the electrical rate of relatively exotic materials such as chalcogen. In most semiconductor manufacturing facilities, chalcogenide is difficult to use and can be challenging. A substantial advantage is provided by having an erasable or multi-state memory cell column formed from a non-volatile memory matrix of conventional semiconductor material 121888.doc 200811865 in a structure that is easily scaled to a small size. SUMMARY OF THE INVENTION The present invention is defined by the following, and any content in this paragraph should be construed as limiting the claim.
精由間介,下文描述之較佳具體實施例提供—種混合用 途記憶體陣列及其使用方法。在—項較佳具體實施例中, 提供一種記憶輯列,其包括:m㈣單元,其 運作為可單次程式化記憶體單元;及-第二組記憶體單 一八運作為可重寫記憶體單元。在另一項較佳具體實施 一】中提供-種記憶料列,其包括:—第—組記憶體單 ^其運作為用-正向偏壓予以程式化之記憶體單元;及 第一組$憶體單元,其運作為用一逆向偏壓予以程式化 之圯體單7〇。揭示其它具體實施例,並且每一具體實施 例可予以單獨或組合運用。 現在將參考附圖來說明較佳具體實施例。 【實施方式】 已知,藉由施加電脈衝,由經摻雜複晶矽形成之電阻器 的電阻可予以修整,在穩定電阻狀態之間進行調整。已使 用此等可修整式電阻器作為積體電路中的元件。 但疋’在非揮發性記憶體單元中使用可修整式複晶矽電 器了來儲存資料狀態不是習知做法。製作複晶石夕電阻器 之記憶體陣列存在困難。如果在大交叉點(cr〇ss_p〇int)記 體陣列中使用電阻器作為記憶體單元,則當施加電壓至 121888.doc 200811865 一所選a己憶體單元時,則在整個記憶體陣列將有非所要洩 漏穿過半所選與非所選記憶體單元。舉例而言,請參考圖 1,假定施加一電壓於位元線B與字線A之間以設定、重設 或感測所擇記憶體單元S。電流意欲流動通過所擇記憶體 單元S。但是,某洩漏電流可在替代路徑(舉例而言,介於 位元線B與子線A之間)上流動通過非所擇記憶體單元Ui、 U2與U3。有許多此類替代路徑可存在。 藉由形成每一記憶體單元作為一包括一個二極體的兩端 子式裝置,可大幅減小洩漏電流。二極體具有非線性 I-V(電流電壓)特性,允許低於開通電壓的極少量電流流動 及高於開通電壓的較高電流流動。一般而言,二極體亦作 為單向闊,以使電流往一方向行進比往另一方向行進更容 易。因此,只要所擇擇的加偏壓方案確保僅所擇記憶體單 元經受到高於開通電壓的正向電流,則可大幅減小沿非預 定路徑(諸如圖1之U1-U2-U3非正常路徑)的茂漏電流。 Herner等人於2004年9月29日申請之美國專利申請案第 10/955,549 號"Nonvolatile Memory Cell With〇m aThe preferred embodiment of the invention described below provides a hybrid memory array and method of use thereof. In a preferred embodiment, a memory array is provided, comprising: m (four) cells operating as a single-programmed memory cell; and - a second set of memory operating as a rewritable memory Body unit. In another preferred embodiment, a memory material column is provided, comprising: a first group memory device that operates as a memory unit programmed with a forward bias; and a first group The memory unit is operated as a body block that is stylized with a reverse bias. Other specific embodiments are disclosed, and each specific embodiment can be utilized individually or in combination. Preferred embodiments will now be described with reference to the drawings. [Embodiment] It is known that the resistance of a resistor formed by doped polysilicon can be trimmed by applying an electric pulse to adjust between stable resistance states. These trimmable resistors have been used as components in an integrated circuit. However, it is not customary to use a trimtable polysilicon device in a non-volatile memory cell to store data. There is a difficulty in fabricating a memory array of a compound crystal shi resistor. If a resistor is used as a memory cell in a large cross-point (cr〇ss_p〇int) memory array, then when a voltage is applied to 121888.doc 200811865, a selected memory cell will be used throughout the memory array. There is a need to leak through the semi-selected and non-selected memory cells. For example, referring to FIG. 1, it is assumed that a voltage is applied between the bit line B and the word line A to set, reset, or sense the selected memory cell S. The current is intended to flow through the selected memory unit S. However, a leakage current may flow through the non-selected memory cells Ui, U2, and U3 over an alternate path (e.g., between bit line B and sub-line A). There are many such alternative paths that can exist. By forming each memory cell as a two-terminal device including a diode, the leakage current can be greatly reduced. The diode has a non-linear I-V (current-voltage) characteristic that allows a very small amount of current flow below the turn-on voltage and a higher current flow above the turn-on voltage. In general, the diode is also unidirectional, so that it is easier to travel in one direction than in the other. Therefore, as long as the selected biasing scheme ensures that only the selected memory cell is subjected to a forward current higher than the turn-on voltage, the non-predetermined path can be greatly reduced (such as U1-U2-U3 of FIG. 1 is abnormal). Path) leakage current. U.S. Patent Application Serial No. 10/955,549, filed on Sep. 29, 2004, to "Nonvolatile Memory Cell With 〇m a
Dielectric Antifuse Having High- and Low-Impedance States"(下文稱為’549申請案並且特此以引用方式併入本 文中)描述一種單片三維記憶體陣列,其中以半導體接面 二極體之複晶半導體材料的電阻率狀態來儲存記憶體單元 之資料狀態。此記憶體單元係一種具有兩種資料狀態之= 單次程式化記憶體單元。二極體經形成為處於高電阻率狀 態;施加程式化電壓使二極體永久變換成低電阻率狀態。 121888.doc 200811865 在本發明具體實施例φ, Α 中糟由轭加適當的電脈衝,由經 摻雜半導體材料所形成之情_ 導體二極體)可達成:種體:件(諸如,549申請案之半 —種、四種或四種以上穩定電阻率狀 ,電阻ιΓ月其它具體實施例中,可使半導體材料從初始 而電阻率狀態轉換成較低電阻率狀態;接著,在施… 的電脈衝下,可返回至較高電阻率狀態。可個別地或組合 地採用彼等具體實施例’以形成可具有兩種或兩種以上資Dielectric Antifuse Having High-and Low-Impedance States" (hereinafter referred to as the '549 application and incorporated herein by reference) describes a single-chip three-dimensional memory array in which a semiconductor junction diode is used as a polycrystalline semiconductor The resistivity state of the material to store the data state of the memory cell. This memory unit is a single-programmed memory unit with two data states. The diode is formed in a high resistivity state; applying a stylized voltage permanently transforms the diode into a low resistivity state. 121888.doc 200811865 In a specific embodiment of the invention φ, Α 由 由 由 由 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 轭 _ _ _ _ 549 549 549 549 549 549 549 549 549 549 549 549 549 549 549 549 549 549 549 549 Half of the application - kind, four or more kinds of stable resistivity, in other specific embodiments, the semiconductor material can be converted from the initial resistivity state to the lower resistivity state; Under the electrical pulse, it can be returned to a higher resistivity state. The specific embodiments can be used individually or in combination to form two or more types of resources.
料狀態並且可以係可單次程式化或可重寫之記憶體單元。、 如所述’在記.it體單元之導體之間包含—個二極體允許 其形成於高密集交又點記憶體陣列中。在本發明較佳具體 實施例中’接著,複晶、非晶系或微晶半導體記憶體元件 經形成以串聯於二極體,或更佳方式為’形成為二極體本 身。 在此論述中,自較高電阻率狀態至較低電阻率狀態之轉 變將稱為”設定”轉變,其係受到設定電流、設定電壓或設 定脈衝所影響;自較低電阻率狀態至較高電阻率狀態之逆 轉隻將稱為"重設”轉變,其係受到重設電流、重設電壓或 重設脈衝所影響。 在較佳可單次程式化具體實施例中,一複晶半導體二極 體與介電破裂反溶絲配對,然而,在其它具體實施例 中’可省略反溶絲。 圖2綠示根據本發明較佳具體實施例形成之記憶體單 元。—底導體12係由傳導材料(例如,鎢)所形成並且往一 第一方向延伸。在底部導體12中可包含障壁層與黏著層。 121888.doc 200811865 複曰曰半¥體—極體2具有一底部重摻雜n型區4; 一本質區 6 ,…圖未經摻雜;及_頂部重摻雜區8,然而此二極體 之疋向可顛倒。無淪此二極體之定向,其將稱為p小η二極 體。在一些具體實施例中’包含介電破裂反熔絲14。頂部 V體16可用相同於底部導體12之方式及材料予以形成並且 4不同於該第方向之—第二方向延伸。複晶半導體二極 體2被垂直佈置於底部導體12與頂部導體16之間。 複晶半導體二極體2係形成為處於高電阻率狀態。此記 憶,單元可形成於—適合基板上方,舉例而言,一單結晶 石夕晶圓上方。圖增示於交叉點記憶體陣列中形成此等裝 置的記憶體層級之一部分中二極體2係佈置於底部導 體12與頂部導體16之間(在此圖中省略反溶絲可將多 重記憶體層級堆疊於一基板上,以形成一高度密度單片三 維記憶體陣列。 在此論述中…意圖未經摻雜之半導體材料區描述為一 本質區。但是,熟悉此項技術者應明白,實際上,本質區 可包括-低濃度Ρ型或η型摻雜物。摻雜物可自相鄰區擴散 進入本質區’或可能於沉積期間歸因於來自早先沉積之污 染而存在於沉積室中m明白,經㈣之本f半導 體材料(諸如⑦)可包括缺陷’而造成其猶如經輕微η掺雜。 使用用詞"本質"來描㈣、鍺1錯合金或某其它半導體 材料非意欲暗示此區未含任何摻雜物,亦非意欲暗示此區 係完全電中性。 可藉由施加適當的電脈衝’使經摻雜複晶或微晶半導體 121888.doc 200811865 材料(例如,矽)之電阻率於穩定狀態之間改變。經發現, 在較佳具體實施例中,有利地配合二極體在正向偏壓下來 實行設定轉變,而配合二極體在逆向偏壓下更易於達成及 控制重設轉變。但是,在一些狀況中,可配合二極體在逆 向偏壓下來達成設定轉變,而配合二極體在正向偏壓下來 達成重設轉變。 半導體切換行為複雜。對於二極體,配合二極體在正向 偏壓下已達成設定轉變與重設轉變兩者。一般而言,配合 二極體在正向偏壓下施加之重設脈衝(其足以使構成二極 體的複晶半導體材料自一既定電阻率狀態切換至一較高電 阻率狀態)的振幅低於相對應之設定脈衝(其將相同複晶半 導體材料自相同電阻率狀態切換至一較低電阻率狀態)並 且具有較長之脈衝寬度。 在逆向偏壓下進行切換呈現出相異的行為。假定複晶p_ i-n二極體(像是圖2中所示之二極體)在逆向偏壓下經受到 一相對長切換脈衝。在施加切換脈衝之後,施加較小之讀 取脈衝(例如,2伏),並且測量流動通過處於讀取電壓之電 流(稱為讀取電流)。隨著在逆向偏壓下之切換脈衝之電壓 在後續脈衝中增大,後續讀取電流以兩個伏特變更,如圖 4所示。將理解到,初始時隨著逆向電壓與切換脈衝的電 μ增大,當在每一切換脈衝後施加讀取電壓時,讀取電流 增大,即,在設定方向中,半導體材料(在此情況中,半 導體材料係矽)的初始轉變係朝向較低電阻率。一旦切換 脈衝抵達一定逆向偏壓電壓(圖4中之£點,在此實例中係 121888.doc 200811865 約_14.6伏),讀取電流突然開始下降,原因係達成重設且 石夕電阻率增大。當開始施加逆向偏壓切換脈衝,切換電壓 (在此切換電壓下,設定趨勢被逆轉並且二極體之矽開始 重设)係取決於(例如)構成二極體的石夕之電阻率狀態而變 化。接著,將理解到,藉由所擇適當之電壓,配合二極體 在逆向偏壓下可達成構成二極體的半導體材料之設定或重 _ 本發明之兄憶體單元的相異資料狀態對應於構成二極體 的複晶或微晶半導體材料的電阻率狀態,其係藉由當施加 讀取電壓時偵測流動通過記憶體單元(介於頂部導體16與 底部導體12之間)的電流予以辨別。較佳方式為,介於任 一相異資料狀態與任何不同相異資料狀態之間的流動之電 流係至少2之因數,以允許介於狀態之間的差異係易於可 偵測。 可使用記憶體單元作為可單次程式化記憶體單元或可重 馨 寫記憶體單元,並且可具有兩種、三種、四種或四種以上 相異資料狀態。在正向偏壓與逆向偏壓下,可使記憶體單 元依任何順序自任何其資料狀態轉換成任何其它其資料狀 態。 將提供數項較佳具體實施例實例。但是,應明白,彼等 實例無限制意圖。熟悉此項技術者應明白,用以程式化兩 端子式裝置(包括一個二極體及複晶或微晶半導體材料)之 其它方法將屬於本發明範_内。 可單次程式化多位準記憶體單元 121888.doc 200811865 在本發明之一較佳具體實施例中,一 、 形成之-β鱗λ 由複晶半導體材料 置介電破裂反溶絲係,聯方式排列且佈 置於頂邛與底部導體之間。兩 卻 ^ ^ ιμ ^ , 式裝置係用作為可單次 /準記憶體’在較佳具體實施例m有-種 或四種資料狀態。 /…、有一種 圖2繪示一較佳記憶體單 — 曰曰丰導…丄 早凡-極體2較佳係用複晶或微 日日丰導體材料所形成,例如, 人人 7 鍺、或一矽及/或鍺之The material state can be a single-programmed or rewritable memory unit. As described above, the inclusion of a diode between the conductors of the body unit allows it to be formed in a highly dense interconnected memory array. In a preferred embodiment of the invention, the polycrystalline, amorphous or microcrystalline semiconductor memory component is formed to be connected in series with the diode, or more preferably, to form the diode itself. In this discussion, the transition from the higher resistivity state to the lower resistivity state will be referred to as the "set" transition, which is affected by the set current, set voltage, or set pulse; from the lower resistivity state to higher The reversal of the resistivity state will only be referred to as a "reset" transition, which is affected by reset current, reset voltage, or reset pulses. In a preferred single-programmed embodiment, a polycrystalline semiconductor The diode is paired with a dielectric rupture anti-solving filament, however, in other embodiments, the anti-solvent filament can be omitted. Figure 2 illustrates green memory cells formed in accordance with a preferred embodiment of the present invention. - Bottom conductor 12 Formed by a conductive material (for example, tungsten) and extending in a first direction. The barrier layer and the adhesive layer may be included in the bottom conductor 12. 121888.doc 200811865 The retort half body-pole body 2 has a bottom remix a hetero-n-type region 4; an intrinsic region 6, ... is undoped; and a top heavily doped region 8, however, the orientation of the dipole can be reversed. Without the orientation of the diode, it will be called Is a p small η diode. In some embodiments 'Contains dielectric rupture antifuse 14. The top V body 16 can be formed in the same manner and material as the bottom conductor 12 and 4 is different from the first direction - the second direction extends. The polycrystalline semiconductor diode 2 is vertically arranged Between the bottom conductor 12 and the top conductor 16. The polycrystalline semiconductor diode 2 is formed in a high resistivity state. The memory can be formed on the substrate, for example, a single crystal silicon wafer. The figure is shown in a portion of the memory level of the intersection memory array in which the diode 2 is disposed between the bottom conductor 12 and the top conductor 16 (the reverse solution is omitted in this figure) Multiple memory levels are stacked on a substrate to form a high density monolithic three dimensional memory array. In this discussion, the undoped semiconductor material region is described as an essential region. However, those skilled in the art should It is understood that, in fact, the intrinsic region may include - a low concentration of yttrium-type or n-type dopants. The dopant may diffuse from the adjacent region into the intrinsic region' or may be attributed to deposition from earlier deposition during deposition. Dyeing and present in the deposition chamber, m understands that the semiconductor material (such as 7) can be included in the defect (4) to cause it to be slightly η-doped. Use the word "essence" to describe (4), 锗1 wrong The alloy or some other semiconductor material is not intended to imply that this region does not contain any dopants, nor is it intended to imply that the region is fully electrically neutral. The doped polycrystalline or microcrystalline semiconductor can be made by applying an appropriate electrical pulse. .doc 200811865 The resistivity of a material (e.g., helium) changes between steady states. It has been found that in a preferred embodiment, it is advantageous to cooperate with the diode to perform a set transition under forward bias, with a dipole The body is easier to achieve and control the reset transition under reverse bias. However, in some cases, the diode can be reverse biased to achieve a set transition, and the diode is forward biased to achieve reset. change. Semiconductor switching behavior is complex. For diodes, the mating diodes have achieved both set transitions and reset transitions under forward bias. In general, the amplitude of the reset pulse applied by the diode under forward bias (which is sufficient to switch the polycrystalline semiconductor material constituting the diode from a predetermined resistivity state to a higher resistivity state) is low. The corresponding set pulse (which switches the same polycrystalline semiconductor material from the same resistivity state to a lower resistivity state) and has a longer pulse width. Switching under reverse bias presents a different behavior. It is assumed that the polycrystalline p_i-n diode (such as the diode shown in Fig. 2) is subjected to a relatively long switching pulse under reverse bias. After the switching pulse is applied, a smaller read pulse (e.g., 2 volts) is applied and the measurement flows through the current at the read voltage (referred to as the read current). As the voltage of the switching pulse under reverse bias increases in subsequent pulses, the subsequent read current changes by two volts, as shown in FIG. It will be understood that initially, as the electrical voltage of the reverse voltage and the switching pulse increases, when a read voltage is applied after each switching pulse, the read current increases, that is, in the set direction, the semiconductor material (here In the case, the initial transformation of the semiconductor material system is toward a lower resistivity. Once the switching pulse reaches a certain reverse bias voltage (the point in Figure 4, in this example is 121888.doc 200811865 about _14.6 volts), the read current suddenly begins to drop, due to the reset and the increase in the Shih-hs resistivity. Big. When the reverse bias switching pulse is applied, the switching voltage (at which the set trend is reversed and the turns of the diodes begin to reset) depends on, for example, the resistivity state of the diodes that constitute the diode. Variety. Next, it will be understood that the setting or weight of the semiconductor material constituting the diode can be achieved under the reverse bias by the appropriate voltage, and the dissimilar data state of the dimming unit of the present invention corresponds to The resistivity state of the polycrystalline or microcrystalline semiconductor material constituting the diode is detected by flowing a current through the memory cell (between the top conductor 16 and the bottom conductor 12) when a read voltage is applied Identify it. Preferably, the current flowing between any of the distinct data states and any of the different data states is at least 2 factors to allow for differences between states to be easily detectable. The memory unit can be used as a single-programmable memory unit or a rewritable memory unit, and can have two, three, four or more different data states. Under forward bias and reverse bias, the memory cells can be converted from any of their data states to any other data state in any order. Several examples of preferred embodiments will be provided. However, it should be understood that their examples are not intended to be limiting. Those skilled in the art will appreciate that other methods for programming a two-terminal device, including a diode and a polycrystalline or microcrystalline semiconductor material, will be within the scope of the present invention. Single-programmed multi-level memory unit 121888.doc 200811865 In a preferred embodiment of the invention, a -β scale λ is formed by a polycrystalline semiconductor material to dielectrically rupture the anti-solving filament system, Arranged and arranged between the top and bottom conductors. The two devices are used as a single/quasi-memory, and in the preferred embodiment m there are - or four data states. FIG. 2 illustrates a preferred memory device, which is preferably formed by a polycrystalline or micro-conductor conductor material, for example, 7 人Or one and/or one
白至。更佳方式為’二極體2係複晶石夕。在此實例中,底 部重摻雜區4係η型,並且頂部重摻雜區,型,然而二極 體之極性可顛倒。記憶體單元包括頂部導體之一部分、底 部導體之一部分及一個二極體’該二極體佈置於該等導體 之間。 當形成時,複晶矽之二極體2係處於高電阻率狀態,並 且介電破裂反熔絲14原封不動。圖5繪示在各種狀態中的 記憶體單元之電流的機率標㈣。請參考圖5, #施加讀 取電壓(例如,2伏)於頂部導體16與底部導體12之間(配合 一極體2在正向偏壓下)時,介於頂部導體16與底部導體12 之間流動的讀取電流較佳係在奈安培範圍内,例如,小於 約5奈安培。圖5之圖表上的區域¥相對應於記憶體單元之 一第一資料狀態。對於記憶體陣列中的一些記憶體單元, 此圯憶體單元將未經受設定脈衝或重設脈衝,並且此狀態 將被讀取作為該記憶體單元之一資料狀態。此第一資料狀 態將稱為V狀態。 施加一第一電脈衝(較佳配合二極體2在正向偏壓下)於 121888.doc -12· 200811865 頂部導體16與底部導體12之間。此脈衝係(例如)介於約8伏 與約12伏之間,例如,約1()伏。電流係(例如)介於⑽微 安培與約200微安培之間。脈衝寬度較佳係介於約_奈秒 與約500奈秒之間。此第―電脈衝使介電破裂反熔絲⑽ 裂且使二極體2之半導體材料自-第-電阻率狀態切換至 :第二電阻率狀態’第二電阻率狀態低於第—電阻率狀 態^第二資料狀態將稱為P狀態’並且圖5中將此轉變標 不為ν·>ρ"。纟2伏讀取電壓下流動於頂部導體μ與底部 導體12之間的電流係約1G微安培或以上。構成:極體2之 半導體材料電阻率減少約1咖至約2_之因數。在其它且 體實施例中’電阻率變化小,但是介於任一資料狀態二壬 -其它貧料狀態之間將係至少2之因數,較佳係至少3或$ 之因數’並且更典型係1〇〇或以上之因數。記憶體陣列中 的一些記憶體單元將係以此資料狀態予以讀取,並且將未 =額外設定脈衝❹設脈衝。此第二資料狀態將稱為p 頂:電脈衝(較佳配合二極體2在逆向偏壓下)於 二=部導體12之間。此脈衝係(例如)介於約-8 冬14伏之間,較佳介於約韻與約七伏之間 伏。電流係(例如)介於約80微安培與約· ::脈衝寬度係(例如)介於約刚奈秒與一 ==°°奈秒與約1微秒之間,更佳係介 材料自第二電:=。二第二電脈衝使二極體2之半導體 4切換至一第三電阻率狀態,第三電 121888.doc -13- 200811865 率狀ι回於第二電阻率狀態。在2伏讀取電壓下流動於 頂4導體16與底部導體12之間的電流係介於約10奈安培與 、、、不女培之間,較佳介於約100奈安培與約5⑽奈安培 之間二記憶體陣列中的一些記憶體單元將係以此資料狀態 :二=取,亚且將未經受額外設定脈衝或重設脈衝。此第 資料狀怨將稱為R狀態,並且圖5中將此轉變標示 f,P->Rft 〇 、 _ 為了達第四資料狀態,施加一第三電脈衝(較佳配合二 極體2在正向偏壓下)於頂部導體16與底部導體12之間。此 脈2係(例如)介於約8伏與約12伏之間(例如,約職),而 電机係介於約5微安培與約2〇微安培之間。此第三電脈衝 使一極體2之半導體材料自第三電阻率狀態切換至一第四 電阻率狀恶,第四電阻率狀態低於第三電阻率狀態,並且 車乂佳電阻率高於第二電阻率狀態。在2伏讀取電壓下流動 /員邻V體16與底部導體12之間的電流係約15微安培與 ’約4.5,安培之間。記憶體陣列中的一些記憶體單元將係 以此資料狀態(其將稱為s狀態)予以讀取,並且圖5中將此 轉變標示為”R+S"。 Μ於任何兩種相鄰資料狀態在讀取電壓(例如2伏)下之 電流是異較佳係至少2之因數。舉例而言,處於資料狀態尺 己U體單元的|買取電流較佳至少兩倍於處於資料狀 〜v之任何記憶體單元的讀取電流;處於資料狀態s之任何 〜早元的讀取電流較佳至少兩倍於處於資料狀態R之 4何°己^體單元的讀取電流;以及處於資料狀態P之任何 121888.doc -14- 200811865 記憶體單元的讀取電流較佳至少兩倍於處於資料狀態Si 任何記憶體單元的讀取電流。舉例而言,在資料狀態R下 之讀取電流可係兩倍於在資料狀態V下之讀取電流;在資 料狀態S下之讀取電流可係兩倍於在資料狀態R下之讀取電 流;及在資料狀態P下之讀取電流可係兩倍於在資料狀態S 下之讀取電流。如果彼等範圍被定義為較小,則差異可能 相當較大;舉例而言,如果最高電流V狀態之記憶體單元 可具有5奈安培之讀取電流,以及最低電流R狀態之記憶體 單元可具有100奈安培之讀取電流,則電流差異將係20之 因數。藉由選擇其它限制,可確保介於相鄰記憶體狀態之 間的讀取電流差異將係至少3之因數。 下文將予以描述。可應用反覆性讀取-驗證-寫入過程, 以確保在一設定脈衝或重設脈衝之後,記憶體單元係處於 經定義之資料狀態中之一者,並且非處於彼等資料狀態之 間。 到目前為止,已論述介於一資料狀態中最高電流與第二最 高相鄰資料狀態中最低電流之間的差異。處於相鄰資料狀態 之大多數記憶體單元的讀取電流之差異仍然較大;舉例而 言,處於V狀態之記憶體單元可具有1奈安培之讀取電流; 處於R狀態之記憶體單元可具有100奈安培之讀取電流;處於 S狀態之記憶體單元可具有2微安培(2000奈安培)之讀取電 流;及處於P狀態之記憶體單元可具有20微安培之讀取電 流。彼等每一相鄰狀態中之電流可相差10或以上之因數。 已描述具有四種相異資料狀態之記憶體單元。為了輔助 121888.doc -15- 200811865 辨別資料狀態,選擇三種資料狀態(而非四種資料狀態)可 為較佳方式。舉例而言,一種三狀態式記憶體單元可係形 成為處於資料狀態v、設定至資料狀態P,接著重設至資料 狀恶R。此記憶體單元不具有第四資料狀態s。在此情況 中,介於相鄰資料狀態(例如,介於尺與!>資料狀態)之間的 差異可能顯著較大。 如所述程式化一種含如所述之記憶體單元的可單次程式 φ 化記憶體陣列,每一記憶體單元被程式化至三種相異資料 狀恶中之一者(在一具體實施例中)或四種相異資料狀態中 之一者(在一替代具體實施例中)。這些僅係實例;顯然 地,可有三種或四種以上相同電阻率狀態及相對應之資料 狀態。 但疋,在含可單次程式化記憶體單元之記憶體陣列中, 可用各種方式來程式化該等記憶體單元。舉例而言,請參 考圖6,圖2之記憶體單元可經形成為為處於一第一狀態(v | 狀恶)。一第一電脈衝(較佳在正向偏壓下)使破裂反熔絲Μ 破4且使一極體之複晶矽自一第一電阻率狀態切換至一第 二電阻率狀態(第二電阻率狀態低於第一電阻率狀態);使 忑隐體單元處於p狀態,在此實例中,p狀態係最低電阻率 狀恶。一第二電脈衝(較佳在逆向偏壓下)使二極體之複晶 矽自第一電阻率狀態切換至一第三電阻率狀態(第三電阻 率狀恶同於第二電阻率狀態),使記憶體單元處於s狀態。 :第三電脈衝(較佳在逆向偏壓下)使二極體之複晶矽自第 一電阻率狀態切換至一第四電阻率狀態(第三電阻率狀態 121888.doc -16- 200811865 高於第二電阻率狀態),使記憶體單元處於R狀態。對於任 何既定記憶體單元,任何資料狀態(V狀態、R狀態、S狀態 及P狀態)可被讀取作為該記憶體單元之一資料狀態。圖6 中標示每一轉變。圖中繪示四種相異狀態;視需要,可有 三種或三種以上狀態。 在其它具、體實施例中,每一相繼電脈衝可使二極體之半 導體材料切換至一相繼較低電阻率狀態。如圖7中所示,White to. A more preferred method is the 'diode 2 series polycrystalline stone. In this example, the bottom heavily doped region 4 is n-type and top heavily doped regions, type, however the polarity of the dipoles can be reversed. The memory unit includes a portion of the top conductor, a portion of the bottom conductor, and a diode. The diode is disposed between the conductors. When formed, the diode 2 of the polysilicon is in a high resistivity state, and the dielectric rupture antifuse 14 is intact. Fig. 5 is a graph showing the probability of current of a memory cell in various states (4). Referring to FIG. 5, #apply a read voltage (for example, 2 volts) between the top conductor 16 and the bottom conductor 12 (with the body 2 being forward biased), between the top conductor 16 and the bottom conductor 12 The read current flowing between is preferably in the range of naamper, for example, less than about 5 nanoamperes. The area ¥ on the graph of Fig. 5 corresponds to a first data state of the memory unit. For some memory cells in the memory array, the memory cell will not be pulsed or reset, and this state will be read as one of the data states of the memory cell. This first data state will be referred to as the V state. A first electrical pulse is applied (preferably with the diode 2 under forward bias) between 121888.doc -12 200811865 top conductor 16 and bottom conductor 12. This pulse is, for example, between about 8 volts and about 12 volts, for example, about 1 volt. The current system is, for example, between (10) microamperes and about 200 microamperes. The pulse width is preferably between about _ nanoseconds and about 500 nanoseconds. The first electrical pulse causes the dielectric rupture antifuse (10) to split and switches the semiconductor material of the diode 2 from the -first resistivity state to: the second resistivity state 'the second resistivity state is lower than the first resistivity The state ^second data state will be referred to as the P state' and this transition is not labeled as ν·>ρ" in FIG. The current flowing between the top conductor μ and the bottom conductor 12 at a read voltage of 纟 2 volts is about 1 G microamperes or more. Composition: The resistivity of the semiconductor material of the polar body 2 is reduced by a factor of about 1 ga to about 2 _. In other embodiments, the 'resistivity change is small, but between any data state and other poor state, it will be at least 2, preferably at least 3 or a factor of ' and more typical. A factor of 1〇〇 or more. Some of the memory cells in the memory array will be read with this data state and will not have an additional set pulse pulse. This second data state will be referred to as p-top: an electrical pulse (preferably with diode 2 under reverse bias) between the two-part conductors 12. This pulse is, for example, between about -8 and 14 volts, preferably between about rhyme and about seven volts. The current system (for example) is between about 80 microamperes and about a :: pulse width system (for example) between about just nanoseconds and nanoseconds and about 1 microsecond. Second electricity: =. The second electrical pulse switches the semiconductor 4 of the diode 2 to a third resistivity state, and the third electrical state returns to the second resistivity state. The current flowing between the top 4 conductor 16 and the bottom conductor 12 at a read voltage of 2 volts is between about 10 nanoamperes and amps, preferably between about 100 nanoamperes and about 5 (10) nanoamperes. Some of the memory cells in the two memory arrays will be in this data state: two = f, and will not be pulsed or reset by additional settings. This data will be referred to as the R state, and in Figure 5 this transition is denoted by f, P-> Rft 〇, _ for the fourth data state, a third electrical pulse is applied (preferably with diode 2) Under forward biasing) between the top conductor 16 and the bottom conductor 12. The pulse 2 is, for example, between about 8 volts and about 12 volts (e.g., a job), and the motor system is between about 5 microamperes and about 2 microliters. The third electrical pulse causes the semiconductor material of the one body 2 to switch from the third resistivity state to a fourth resistivity state, the fourth resistivity state is lower than the third resistivity state, and the ruthenium good resistivity is higher than Second resistivity state. The current between the flow-side V body 16 and the bottom conductor 12 at a read voltage of 2 volts is between about 15 microamps and about 4.5 amps. Some of the memory cells in the memory array will be read by this data state (which will be referred to as the s state), and this transition is labeled "R+S" in Figure 5. Μ 任何 任何 任何 任何 任何 任何The current at the read voltage (for example, 2 volts) is a factor of at least 2. For example, the buy current in the data state of the U body unit is preferably at least twice as large as the data value. The read current of any memory cell; the read current of any ~ early element in the data state s is preferably at least twice the read current of the body unit in the data state R; and the data state Any of the 121888.doc -14- 200811865 memory cells preferably have at least twice the read current of any memory cell in the data state Si. For example, the read current in the data state R can be Is twice the read current in the data state V; the read current in the data state S can be twice the read current in the data state R; and the read current in the data state P can be Twice the reading power in the data state S Flow. If their range is defined as small, the difference may be quite large; for example, if the highest current V state memory cell can have 5 nanoamps of read current and the lowest current R state of memory The cell can have a read current of 100 nanoamperes, and the current difference will be a factor of 20. By choosing other limits, it is ensured that the difference in read current between adjacent memory states will be at least a factor of 3. It will be described. A repetitive read-verify-write process can be applied to ensure that the memory cells are in one of the defined data states after a set pulse or reset pulse, and are not in their data. Between states. So far, the difference between the highest current in a data state and the lowest current in the second highest adjacent data state has been discussed. The read current of most memory cells in adjacent data states The difference is still large; for example, the memory cell in the V state can have a read current of 1 nanoamperes; the memory cell in the R state can have 100 nanoamperes The current is read; the memory cell in the S state can have a read current of 2 microamperes (2000 nanoamperes); and the memory cells in the P state can have a read current of 20 microamps. The currents in the state can differ by a factor of 10 or more. Memory cells with four distinct data states have been described. To aid in the identification of data states, select three data states (instead of four data states). For example, a three-state memory unit can be formed in the data state v, set to the data state P, and then reset to the data state R. The memory cell does not have the fourth. Data status s. In this case, the difference between adjacent data states (eg, between the ruler and the !> data state) may be significantly larger. As programmed, a single-program φ memory array containing the memory cells as described, each memory cell being programmed to one of three distinct data traits (in a specific embodiment) Medium) or one of four distinct data states (in an alternate embodiment). These are merely examples; obviously, there may be three or more identical resistivity states and corresponding data states. However, in a memory array containing a single-programmable memory cell, the memory cells can be programmed in a variety of ways. For example, referring to FIG. 6, the memory unit of FIG. 2 can be formed to be in a first state (v|like). a first electrical pulse (preferably under forward bias) causes the rupture antifuse to break 4 and switch the monolayer of the polar body from a first resistivity state to a second resistivity state (second The resistivity state is lower than the first resistivity state; the germanium stealth cell is placed in the p state, and in this example, the p state is the lowest resistivity. a second electrical pulse (preferably under reverse bias) switches the polysilicon of the diode from a first resistivity state to a third resistivity state (the third resistivity is the same as the second resistivity state) ), the memory unit is in the s state. The third electrical pulse (preferably under reverse bias) switches the polysilicon of the diode from the first resistivity state to a fourth resistivity state (third resistivity state 121888.doc -16-200811865 high) In the second resistivity state, the memory cell is in the R state. For any given memory unit, any data state (V state, R state, S state, and P state) can be read as one of the data states of the memory cell. Each transition is labeled in Figure 6. The four different states are shown in the figure; there may be three or more states as needed. In other embodiments, each successive electrical pulse can switch the semiconductor material of the diode to a successive lower resistivity state. As shown in Figure 7,
舉例而言’記憶體單元可自初始V狀態進展至R狀態、自R 狀恶進展至S狀態及自S狀態進展至P狀態,對於每一狀 悲,讀取電流係至少兩倍於前一狀態之讀取電流,每者相 對應於一相異資料狀態。此方案可在記憶體單元不包含任 何反熔絲時更有利。在此實例中,在正向偏壓或逆向偏壓 下施加脈衝。在替代具體實施例中,可有三種資料狀態或 四種以上資料狀態。 在一項具體實施例中,記憶體單元包括圖8所示之複晶 石夕或微晶二極體2 ’該二極體包括底部重摻雜p型區4、中 間本質或輕掺雜區6及頂部重摻雜n型區8。如同先前之具 體實施例中,此二極體2可血_人 ” ”電破裂反熔絲以串聯方 式排列且佈置於頂部與底部導 .^ ^ α 叮々一広Α 1净體之間。底部重摻雜ρ型區4 可經原位摻雜,即,摻雜方式 ^ ^ 稭由於》儿積複晶矽期問 使如供妓摻雜物的氣體(諸如⑷㈣ 併入於隨之形成的薄財。 *摻雜物原子被 請參考圖9,經發現, 態,其中在2伏讀取電壓 此記憶體單元經形成為處於¥狀 下,介於頂部導體16與底部導體 121888.doc -17- 200811865 之間的電流低於約80奈安培。一第一電脈衝(較佳在正 向偏遂下予以施加)使介電破裂反溶絲14(若有存在)破裂, 並且使二極體2之複晶石夕自一第一電阻率狀態切換至一第 二二電阻率狀態(第二電阻率狀態低於第一電阻率狀態);使 記憶體單元處於資料狀態P。在資料狀態p中,在讀取電墨 下介於頂部導體16與底部|體12之間的電流係約i微安培 與約4微安培之間。一第二電脈衝(較佳在逆向偏壓下予以 • 施加)使二極體2之複晶矽自第二電阻率狀態切換至一第三 電阻率狀態,弟二電阻率狀態低於第一電阻率狀態。第三 電阻率狀態對應於資料狀態M。在資料狀態“中,在讀取 電壓下介於頂部導體16與底部導體12之間的電流係約1〇微 女培。如同先4之具體實施例中,介於相鄰資料狀態之任 何記憶體單兀之間(介於V狀態之最高電流記憶體單元與p 狀態之最低電流記憶體單元之間,或介於p狀態之最高電 流記憶體單元與Μ狀態之最低電流記憶體單元之間)的電流 | 差異較佳係至少2之因數,較佳係3或以上之因數。任何資 料狀態(V、Ρ或Μ)皆可被偵測為該記憶體單元之一資料狀 態。 圖4展現出當半導體二極體經受逆向偏壓時,一般而 έ ’半導體材料初始時歷經至較低電阻率之設定轉變,接 著’隨著電壓增大,歷經至較高電阻率之重設轉變。對於 此特定二極體,運用頂部重摻雜η型區8,並且較佳運用藉 由用ρ型摻雜物原位摻雜所形成之底部重摻雜區4,隨著增 大中之逆向偏壓而自設定轉變切換至重設轉變,不會如同 121888.doc -18- 200811865 其它具體實施例之二極體-樣突然或急劇地發生。此意謂 著運用此二極體較易於控制在逆向偏壓下之設定轉變。 可重寫記憶體單元 在-組具體實施例中,記憶體單元作用為可重寫記憶體 單元,其可重複切換於兩種或三種資料狀態之間。 圖1〇繪示可作為彳重寫記憶體單元之記憶體單元。此記 憶體單元相同於圖2所示之記憶體單元,惟不包含介電破 _ 肢㈣除外。大多數可重寫具體實施例在記憶體單元不 包含反熔絲,然而若需要,可包含一個反熔絲。 明參考圖11,在第一較佳具體實施例中,記隐體單元係 形成為處於高電阻率狀態V,而在2伏下之電流約5奈安培 或以下對於大夕數可重寫具體實施例,初始v狀態不用 作為Π己憶體單元之一資料狀態。施加一第一電脈衝(較佳 配合二極體2在正向偏壓下)於頂部導體16與底部導體12之 間。此脈衝係(例如)介於約8伏與約12伏之間,較佳約1〇 瞻伏。此第一電脈衝使二極體2之半導體材料自一第一電阻 率狀態切換至一第二電阻率狀態,第二電阻率狀態低於第 一電阻率狀態。在較隹具體實施例中,p狀態亦不用作為 5己饭體單元之一資料狀態。在其它具體實施例中,p狀熊 將用作為記憶體單元之一資料狀態。 施加一第二電脈衝(較佳配合二極體2在逆向偏壓下)於 頂部導體16與底部導體12之間。此脈衝係(例如)介於約彳 伏與約-14伏之間,較佳介於約_9伏與約_13伏之間,更佳 係約-10伏或_11伏。所要求之電壓將隨本質區之厚度而變 121888.doc -19· 200811865 化。此弟二電脈衝使二極體 〇 極體2之+導體材料自第二電阻率 狀怨切換至一第三電阻率狀離 一& 干狀μ K 弟三電阻率狀態高於第 一電阻率狀態。在較佳且辦每 ^ σ /、體貝知例中,R狀態對應於記憶 體皁7〇之一資料狀態。 >可施加一第三電脈衝於頂部導體16與底部導體12之間, 較佳在正向偏壓下。此脈衝係(例如)介於約5.5伏與約9伏 車乂 U 6.5伏’而電流係介於約1G微安培與約微For example, the 'memory cell can progress from the initial V state to the R state, from the R-like progress to the S state, and from the S state to the P state. For each sorrow, the read current is at least twice the previous one. The state of the read current, each corresponding to a different data state. This scheme is more advantageous when the memory unit does not contain any antifuse. In this example, a pulse is applied under forward bias or reverse bias. In alternative embodiments, there may be three data states or more than four data states. In a specific embodiment, the memory cell comprises a polycrystalline or microcrystalline diode 2' as shown in FIG. 8 and the dipole comprises a bottom heavily doped p-type region 4, an intermediate or lightly doped region 6 and top heavily doped n-type region 8. As in the previous specific embodiment, the diode 2 is electrically rupturable and arranged in a series arrangement between the top and bottom electrodes. The bottom heavily doped p-type region 4 can be doped in situ, that is, the doping method ^ ^ straw due to the "children's product", such as the gas supply of the dopant (such as (4) (four) is incorporated into the formation The thinner of the dopant. * Refer to Figure 9, for the dopant atom, where the memory cell is formed at a voltage of 2 volts and is formed in the shape of a ¥, between the top conductor 16 and the bottom conductor 121888.doc The current between -17 and 200811865 is less than about 80 nanoamperes. A first electrical pulse (preferably applied under positive bias) causes the dielectric rupture antifusing filament 14 (if present) to rupture and cause The bimorph of the polar body 2 switches from a first resistivity state to a second two resistivity state (the second resistivity state is lower than the first resistivity state); and the memory cell is in the data state P. In state p, the current between the top conductor 16 and the bottom body 12 under reading the ink is between about 1 microamperes and about 4 microamperes. A second electrical pulse (preferably under reverse bias) Applying (applying) to switch the polysilicon of the diode 2 from the second resistivity state to a third resistivity state, The second resistivity state is lower than the first resistivity state. The third resistivity state corresponds to the data state M. In the data state "the current between the top conductor 16 and the bottom conductor 12 at the read voltage is about 1 In the specific embodiment of the first 4, between any memory cells in the adjacent data state (between the highest current memory cell in the V state and the lowest current memory cell in the p state) The current | difference between the highest current memory cell in the p state and the lowest current memory cell in the Μ state is preferably a factor of at least 2, preferably a factor of 3 or more. Any data state (V) , Ρ or Μ) can be detected as one of the data states of the memory cell. Figure 4 shows that when the semiconductor diode is subjected to reverse bias, generally the semiconductor material initially passes to a lower resistivity. The transition is set, followed by 'reset transition to higher resistivity as the voltage increases. For this particular diode, the top heavily doped n-type region 8 is used, and preferably by doping with p-type In situ doping The bottom heavily doped region 4, switching from the set transition to the reset transition with increasing reverse bias, does not resemble the diode of the other embodiments as in the case of 121888.doc -18-200811865 This occurs sharply. This means that it is easier to control the set transition under reverse bias using the diode. Rewritable Memory Unit In a specific embodiment, the memory unit acts as a rewritable memory unit. , which can be repeatedly switched between two or three data states. Figure 1A shows a memory unit that can be used as a 彳 rewrite memory unit. This memory unit is the same as the memory unit shown in Figure 2, but Except for dielectric breaks (4), most rewritable embodiments do not include an antifuse in the memory unit, but may include an antifuse if desired. Referring to FIG. 11, in the first preferred embodiment, the stealth unit is formed in a high resistivity state V, and the current at 2 volts is about 5 nanoamperes or less. In an embodiment, the initial v state is not used as one of the data states of the memory unit. A first electrical pulse (preferably with the diode 2 under forward bias) is applied between the top conductor 16 and the bottom conductor 12. This pulse is, for example, between about 8 volts and about 12 volts, preferably about 1 Torr. The first electrical pulse causes the semiconductor material of the diode 2 to switch from a first resistivity state to a second resistivity state, the second resistivity state being lower than the first resistivity state. In a more specific embodiment, the p-state is also not used as a data state for one of the five-cell units. In other embodiments, the p-bear will be used as a data state for one of the memory cells. A second electrical pulse is applied (preferably with the diode 2 under reverse bias) between the top conductor 16 and the bottom conductor 12. The pulse is, for example, between about 彳V and about -14 volts, preferably between about -9 volts and about _13 volts, more preferably about -10 volts or -11 volts. The required voltage will vary with the thickness of the nature zone. The second electric pulse causes the +conductor material of the diode bungee body 2 to switch from the second resistivity to a third resistivity, and the dry resistive state is higher than the first resistance. Rate status. In the preferred embodiment, the R state corresponds to one of the memory states of the memory soap. > A third electrical pulse can be applied between the top conductor 16 and the bottom conductor 12, preferably under forward bias. This pulse is, for example, between about 5.5 volts and about 9 volts 乂 U 6.5 volts and the current system is between about 1 G microamperes and about micro
安培之間’較佳係約5。微料與約刚微安培之間。此第 二電脈衝使二極體2之半導體姑袓& 干V骽材科自苐三電阻率狀態R切換 士-第四電阻率狀態’第四電阻率狀態低於第三電阻率狀 悲。在較佳具體實施例中’ s狀態對應於記憶體單元之一 資料狀態。 在此可重寫、兩狀態具體實施例中,感測或讀取r狀態 與S狀態以作為資料狀態。記憶體單元可重複切換於該兩 種狀L之間。舉例而言’ 一第四電脈衝(較佳配合二極體2 在逆向偏壓下)使二極體之半導體材料自第四電阻率狀態S ㈣至第五電阻率狀態R(其實質上相同於第三電阻率^。 一第五電脈衝(較佳配合二極體2在正向偏壓下)使二極體之 半導體㈣自第五電阻率狀態以讀至第A冑阻率狀態 S(其實質上相同於第四電阻率s),以此類推。可能更難以 使記憶體單元返回初始乂狀態與第二p狀態;因此,在可重 寫記憶體單元中,彼等狀態可能未用作為資料狀態。可能 較佳方式為,在記憶體陣列到達使用者之前(例如,在= 造廠或測試設施中),實行第一電脈衝(其使記憶體單元自\ 121888.doc -20- 200811865 初始V狀態切換至P狀態)及第二電脈衝(其使記憶體單元自 P狀態切換至R狀態)兩者。在其它具體實施例中,可能較 佳方式為,在記憶體陣列到達使用者之前,僅實行第一電 脈衝(其使記憶體單元自初始v狀態切換至p狀態)。 如圖11所示’在提供的實例中,介於處於一資料狀態中 之任何圮憶體單元與處於相鄰資料狀態(在此情況中,係R 敕料狀恶(介於約10奈安培與5〇〇奈安培之間)與尺資料狀態 _ (介於約1 ·5微安培與4.5微安培之間))之任何記憶體單元之 間的介於頂部導體16與底部導體12之間在讀取電壓(例 如,2伏)下流動的電流之間的差異係至少3之因數。取決 於對於所一資料狀態所選擇之範圍,該差異可能係2、3、 5或以上之因數。 在替代具體實施例中,一種可重寫記憶體單元可依任何 順序切換於三種或三種以上資料狀態之間。可配合二極體 在正向偏壓或逆向偏壓下來實行設定轉變或重設轉變。 藝 在所描述之單次可程式化具體實施例與可重寫具體實施 例兩者中,指明資料狀態對應於構成二極體之複晶或微晶 半導體材料的電阻率狀態。資料狀態不對應於電阻率切換 金屬氧化物或氮化物之電阻率狀態,如同Hemer等人於 2006年3月31日申請之美國專利申請案第11/395,995號 ”N〇nv〇latile Memory Cell c〇mpHsing、川〇心 _ &Preferably, the amperage is about 5. Between the micro-material and about just micro-amperes. This second electrical pulse causes the diode 2 of the diode 2 & dry V coffin to self-苐 three resistivity state R switch - the fourth resistivity state 'the fourth resistivity state is lower than the third resistivity . In the preferred embodiment the 's state corresponds to a data state of one of the memory cells. In this rewritable, two-state embodiment, the r state and the S state are sensed or read as the data state. The memory unit can be repeatedly switched between the two forms L. For example, a fourth electrical pulse (preferably with diode 2 under reverse bias) causes the semiconductor material of the diode to be substantially the same from the fourth resistivity state S (four) to the fifth resistivity state R At a third resistivity, a fifth electrical pulse (preferably with the diode 2 under forward bias) causes the semiconductor of the diode (4) to read from the fifth resistivity state to the third resistivity state S. (which is substantially the same as the fourth resistivity s), and so on. It may be more difficult to return the memory cell to the initial chirp state and the second p state; therefore, in the rewritable memory cell, the states may not Used as a data state. It may be preferable to perform a first electrical pulse (for example, to make the memory cell from \121888.doc -20) before the memory array reaches the user (for example, in a factory or test facility) - 200811865 initial V state switching to P state) and a second electrical pulse (which causes the memory cell to switch from the P state to the R state). In other embodiments, it may be preferred to arrive at the memory array Before the user, only the first electrical pulse is implemented (its The memory unit switches from the initial v state to the p state. As shown in FIG. 11 'in the provided example, any memory cell in a data state is in a neighboring data state (in this case, Any memory unit of R 敕 状 ( 介于 (between about 10 nanoamperes and 5 〇〇 nai ampere) and the ruler state _ (between about 1.25 microamperes and 4.5 microamperes) The difference between the current flowing between the top conductor 16 and the bottom conductor 12 at a read voltage (eg, 2 volts) is a factor of at least 3. Depending on the range selected for a data state, The difference may be a factor of 2, 3, 5 or above. In an alternative embodiment, a rewritable memory unit may be switched between three or more data states in any order. Performing a set transition or resetting a bias or reverse bias. In the described single programmable embodiment and the rewritable embodiment, the data state is indicated to correspond to a complex of diodes. Crystal or microcrystalline semiconductor material The state of the resistivity. The data state does not correspond to the resistivity switching metal oxide or nitride resistivity state, as described in U.S. Patent Application Serial No. 11/395,995, filed on March 31, 2006. Latile Memory Cell c〇mpHsing, Sichuan Heart _ &
Resistance-Switching Material”中之描述,該案由本發明受 讓人所擁有並且特此以引用方式併入本文中。 逆向偏壓設定與重設 121888.doc -21- 200811865 在到目前為止描述之根據具體實施例形成及程式化之記 憶體單元陣列中,記憶體單元在逆向偏壓中經受到大電壓 的任何步驟已相較於逆向偏M步驟使$漏電流減小。 請參考圖12,假設跨所擇記憶體單元8施加正向偏壓之 1〇伏y待使用之實際電壓將取決於許多因素,其包括記 憶體早7L之構造、㈣物量、本質區高度料;職僅僅 係貝例)。位70線B0被設定至10伏,並且字線冒〇被設定至 接地A 了確保半所擇記憶體單元F (其與所擇記憶體單元 S共用位元線B0)維持低於二極體之開通電壓,字線冒丨被 設定至低於但相當接近位元線別之電壓;舉例而言,字線 W1可被设定至9.3伏,使得跨記憶體單元F施加〇 7伏(圖中 僅繪示一個記憶體單元F,但可有數百、數千或以上)。同 樣地,為了確保半所擇記憶體單元H (其與所擇記憶體單 元S共用字線W0)維持低於二極體之開通電壓,位元線B i 被δ又疋至尚於但相當接近字線w 〇之電壓丨舉例而言,位 元線Β1可被設定至〇·7伏,使得跨記憶體單元Η施加〇·7伏 (再次,可有數千個記憶體單元Η)。非所擇記憶體單元u (其不與所擇記憶體單元S共用字線w〇,亦不共同位元線 Β0)經受到-8.6伏。由於可有數百萬個非所擇記憶體單元 U ’而導致§己彳思體陣列内顯著的浪漏電流。 圖13繪示跨記憶體單元施加大逆向偏壓(例如,作為重 設脈衝)之有利加偏壓方案。位元線別被設定至_5伏,並 且字線W0被設定至5伏,使得跨所擇記憶體單元s施加·1〇 伏;二極體係處於逆向偏壓中。以不足以使非刻意設定 121888.doc -22- 200811865 或重設半所擇記憶體單元F與η的低逆向偏壓,設定字線 W1與位元線Β1至接地,使半所擇記憶體單元f與η經受_5 伏。一般而言’以逆向偏壓進行設定或重設似乎發生在或 接近使二極體轉變成逆向擊穿之電壓(其一般高於_5伏)。 運用此方案,使無跨非所擇記憶體單元U之電壓,導致 無逆向 >喪漏。結果,如(舉例而言)gcheuerlein等人連同本 案同曰申請且早先以引用方式併入本文中之美國專利申請 案弟 11/461,352 號 ’’Dual Data-Dependent Busses for Coupling Read/Write Circuits to a Memory Array’’(代理人 槽案號碼第023-0051號)中之進一步描述,可顯著增大頻 寬。 圖13之加偏壓方案僅僅係實例;顯然地,可使用許多其 它方案。舉例而言,位元線B0可被設定至〇伏,字線臀〇可 被設定至_1〇伏,以及位元線B1與字線W1可被設定至_5 伏。在圖13之方案中,跨所擇記憶體單元s、半所擇記憶 體單元Η與F以及非所擇記憶體單元u之電壓將相同。在另 一項實例中,位元線Β0可被設定至接地,字線w〇可被設 定至10伏,以及位元線B1與字線W1可被設定至5伏。 反覆式設定與重設 到目前為止,此論述已描述施加一適當電脈衝,以使二 極體之半導體材料自一電阻率狀態切換至一不同電阻率狀 恶,因此使§己憶體單元切換於兩種相異資料狀態之間。實 務上,彼等設定步驟與重設步驟可係反覆式處理程序。 如所述,介於在相鄰資料狀態中於讀取期間流動之電流 121888.doc -23- 200811865 之間的差異較佳係至少2之因數;在許多具體實施例中, 可能較佳方式為,建置每一資料狀態之電流範圍,並且相 隔3、5、1〇或以上之因數。 請參考圖14,如所述,以2伏讀取電壓,資料狀態V可被 定義為5奈安培或以下之讀取電流,資料狀態R可被定義為 約1〇奈安培與約500奈安培之間,資料狀態S可被定義為約 1.5微安培與約4.5微安培之間,及資料狀態P可被定義為高 於約10微安培。熟悉此項技術者應明白彼等僅係實例。在 另一具體實施例中,舉例而言,資料狀態V可被定義於較 小範圍内,其中以2伏讀取電壓,讀取電流為5奈安培或以 下。實際讀取電流將隨記憶體單元之特性、記憶體陣列之 構造、所擇讀取電壓及許多其它因素而變化。 假定可單次程式化記憶體單元係處於資料狀態P。施加 逆向偏壓之電脈衝至記憶體單元,使記憶體單元切換至資 料狀態S。但是,在一些案例中,可能在施加電脈衝之後 讀取電流非處於所要範圍中;即,二極體之半導體材料之 電阻率狀態高於或低於所要狀態。舉例而言,假定在施加 電脈衝之後,記憶體單元之讀取電流係處於圖表上所示之 Q點,介於S狀態與P狀態電流範圍之間中。 施加電脈衝以使記憶體單元切換至所要資料狀態之後, 可讀取記憶體單元以判定是否抵達所要資料狀態。如果抵 達所要資料狀態’則施加額外脈衝。舉例而言,當威測到 電流Q時,施加額外重設脈衝以增大半導體材料之電阻 率、減小讀取電流進入相對應於S資料狀態之範圍中。如 121888.doc •24- 200811865 上文所述,可在正向偏壓或逆向偏壓下施加此設定脈衝。 額外脈衝的振幅(電壓或電流)之脈衝寬度可長於或短於原 始脈衝。在額外設定脈衝後,再次讀取記憶體單元,接著 適當地施加設定脈衝或重設脈衝,直到讀取電流係處於所 要範圍中。 在兩端子式裝置(諸如包括所描述之二極體的記憶體單 元)中,這將特別有利於進行讀取以驗證設定或重設及進 行調整(若需要)。跨二極體施加大逆向偏壓可使二極體受 損;因此,當配合二極體在逆向偏壓下來實行設定或重設 時,最小化逆向偏壓電壓係有利的做法。 製造考量The description in the Resistance-Switching Material, which is owned by the assignee of the present invention and incorporated herein by reference in its entirety herein. In the memory cell array formed and programmed in the embodiment, any step of the memory cell subjected to a large voltage in the reverse bias has reduced the leakage current compared to the reverse bias M step. Referring to FIG. 12, assume a cross The selected memory unit 8 applies a forward bias of 1 〇 y. The actual voltage to be used will depend on a number of factors, including the memory 7L configuration, (4) volume, and the nature of the material; Bit 70 line B0 is set to 10 volts, and the word line is set to ground A to ensure that the half-selected memory unit F (which shares the bit line B0 with the selected memory unit S) remains below the pole The turn-on voltage of the body, the word line is set to a voltage lower than but relatively close to the bit line; for example, the word line W1 can be set to 9.3 volts, so that 〇7 volts is applied across the memory unit F ( Only one note is shown in the figure Body unit F, but there may be hundreds, thousands or more. Similarly, in order to ensure that the half-selected memory unit H (which shares the word line W0 with the selected memory unit S) remains below the opening of the diode The voltage, the bit line B i is δ 疋 to the voltage that is still close to the word line w 丨. For example, the bit line Β 1 can be set to 〇·7 volts, so that 跨 is applied across the memory unit 〇 7 volts (again, there may be thousands of memory cells Η). The unselected memory cell u (which does not share the word line w〇 with the selected memory cell S, nor the common bit line Β0) is subjected to - 8.6 volts. There are millions of unselected memory cells U' that result in significant leakage currents in the array. Figure 13 illustrates the application of large reverse bias across memory cells (eg, as A favorable biasing scheme for resetting the pulse. The bit line is set to _5 volts, and the word line W0 is set to 5 volts, so that 1 volt is applied across the selected memory cell s; In the reverse bias, it is not enough to make the non-deliberate setting of 121888.doc -22- 200811865 or reset the half of the selected memory cells F and η Reverse bias, set word line W1 and bit line Β1 to ground, so that half-selected memory cells f and η are subjected to _5 volts. Generally, setting or resetting with reverse bias seems to occur at or near The diode is converted to a reverse breakdown voltage (which is generally higher than _5 volts). Using this scheme, the voltage across the unselected memory unit U is caused, resulting in no reverse & erroneous leakage. Results, such as (for example The ''Dual Data-Dependent Busses for Coupling Read/Write Circuits to a Memory Array'' of the US Patent Application Serial No. 11/461,352, filed by the same application and hereby incorporated by reference. Further description in Agent Slot Number No. 023-0051 can significantly increase the bandwidth. The biasing scheme of Figure 13 is merely an example; obviously, many other schemes can be used. For example, bit line B0 can be set to 〇, word line 〇 can be set to _1 〇, and bit line B1 and word line W1 can be set to _5 volts. In the scheme of Fig. 13, the voltage across the selected memory cell s, the half-selected memory cells Η and F, and the unselected memory cell u will be the same. In another example, bit line Β0 can be set to ground, word line w 〇 can be set to 10 volts, and bit line B1 and word line W1 can be set to 5 volts. Overriding and resetting So far, this discussion has described the application of an appropriate electrical pulse to switch the semiconductor material of the diode from a resistivity state to a different resistivity, thus switching the § memory cell Between two different data states. In practice, their setup and reset steps can be repeated procedures. As noted, the difference between the currents 121888.doc -23-200811865 flowing during the reading in the adjacent data state is preferably a factor of at least 2; in many embodiments, a preferred approach may be , set the current range of each data state, and the factor of 3, 5, 1 or more. Referring to FIG. 14, as described, the voltage is read at 2 volts, and the data state V can be defined as a read current of 5 nanoamperes or less. The data state R can be defined as about 1 nanoamperes and about 500 nanoamperes. Between the data states S can be defined as between about 1.5 microamperes and about 4.5 microamps, and the data state P can be defined as greater than about 10 microamperes. Those skilled in the art should understand that they are merely examples. In another embodiment, for example, the data state V can be defined in a smaller range, wherein the voltage is read at 2 volts and the read current is 5 nanoamperes or less. The actual read current will vary with the characteristics of the memory cell, the configuration of the memory array, the selected read voltage, and many other factors. It is assumed that the single-programmed memory cell is in the data state P. A reverse biased electrical pulse is applied to the memory cell to switch the memory cell to the data state S. However, in some cases, the read current may not be in the desired range after the application of the electrical pulse; that is, the resistivity state of the semiconductor material of the diode is above or below the desired state. For example, assume that after applying an electrical pulse, the read current of the memory cell is at the Q point shown on the graph, between the S state and the P state current range. After an electrical pulse is applied to switch the memory cell to the desired data state, the memory cell can be read to determine if the desired data state is reached. An additional pulse is applied if the desired data status is reached. For example, when the current Q is measured, an additional reset pulse is applied to increase the resistivity of the semiconductor material and reduce the read current into a range corresponding to the S data state. As described above, this set pulse can be applied under forward or reverse bias as described above. The pulse width (voltage or current) of the extra pulse may be longer or shorter than the original pulse. After the additional set pulse, the memory cell is read again, and then the set pulse or reset pulse is applied as appropriate until the read current is in the desired range. In a two-terminal device, such as a memory unit including the described diodes, this would be particularly advantageous for reading to verify settings or resets and adjustments if needed. Applying a large reverse bias across the diode can damage the diode; therefore, it is advantageous to minimize the reverse bias voltage when the mating diode is set or reset in reverse bias. Manufacturing considerations
Herner等人於2006年6月8曰申請之美國專利申請案第 11/148,530 號”Nonvolatile Memory Cell Operating by Increasing Order in Polycrystalline Semiconductor Material” ;及Herner於2004年9月29日申請之美國專利申 請案第 10/954,510 號"Memory Cell Comprising a Semiconductor Junction Diode Crystallized Adjacent to a Silicide” (彼等案皆由本發明受讓人所擁有並且特此皆以 引用方式併入本文中),描述相鄰於適當矽化物之複晶矽 之結晶化影響複晶矽之屬性。某些金屬矽化物(諸如矽化 鈷與矽化鈦)之晶格結構非常接近矽之晶格結構。當非晶 系或微晶矽經結晶化成接觸於彼等矽化物中之一者時,在 結晶化期間,矽化物之晶格結構為矽提供模版。所得複晶 矽將經高度定序,並且缺陷相當低。當用導電率增強摻雜 121888.doc -25- 200811865 物予以摻雜時,此高品質複晶矽在形成時具相當高傳導 性。 相比之下,當非晶系或微晶矽材料經結晶化成未接觸於 具有矽化物(此矽化物之晶格良好匹配於矽)之矽時,舉例 而言’僅接觸於諸如二氧化矽與氮化鈦(二氧化矽與氮化 鈦之晶格顯著不匹配於矽),則所得複晶矽將具有許多更 大程度之缺陷,並且以此方式結晶化之經摻雜複晶矽在形 成時將非常低之傳導性。 在本發明態樣中,形成二極體之半導體材料切換於兩種 或兩種以上電阻率狀態之間,在既定讀取電壓下改變流動 通過二極體之電流,不同的電流(與電阻率狀態)相對應於 相異之資料狀態。經發現,由相鄰於魏物或提供結晶化 模板之類似材料而尚未結晶化的高度缺陷矽(或其它適當 的半導體材料,諸如鍺或矽-鍺合金)所形成的二極體展現 出更有利的切換行為。 不希望又約束於任何特定理論,據信,支持所觀察電阻 率變的項可旎機制在於,高於臨限振幅的設定脈衝致 使摻雜物原子移出晶界(此處摻雜物原子為非活性)進入晶 體主體(此處摻雜物原子將增大傳導率且降低半導體材料 之電阻)。相比之下,重設脈衝可致使摻雜物原子移回晶 界降低傳‘率且增大電阻。❻*,可能亦有其它機制運 作或作為替代,諸如複晶材料定序程度增大或減小。 經發現,相鄰於適當矽化物之經結晶化極低缺陷矽的電 P率狀L無去如同當半導體材料具有較高程度缺陷時一樣 121888.doc -26 - 200811865 易於切換。缺陷存在或大量晶界存在可能允許較易於切 換。在較佳具體實施例中,於是,形成二極體之複晶或微 晶材料未經結晶化而相鄰於與其具有小晶格不匹配的材 料。小晶格不匹配係(舉例而言)約百分之3或以下之晶格不 匹配。 證據已建議切換行為可集中於本質區中之改變。已在電 阻器與p-i-n二極體中觀察切換行為,並且非限於p-i-n二極 體,但是使用p-i-n二極體可能特別有利。到目前為止描述 之具體實施例包括p-i-n二極體。但是,在其它具體實施例 中,二極體可代替地係p-n二極體,並且具有微不足道或 無本質區。 將提供描述製造本發明較佳具體實施例之詳細實例。 Herner等人於2002年12月19曰申請之美國專利申請案第 10/320,470 號”An Improved Method for Making High Density Nonvolatile Memory"(並且由於被放棄,此以引用 方式併入本文中)中提出的製造細節將有助於以來自’549申 請案之資訊來形成彼等具體實施例之二極體。亦可自 Hemer等人於2004年12月17曰申請之美國專利申請案第 11/015,824 號 ’’Nonvolatile Memory Cell Comprising a Reduced Height Vertical Diode"(該案由本發明受讓人所擁 有並且特此以引用方式併入本文中)導出有用的資訊。為 了避免混淆本發明,將不納含來自彼等申請案的所有細 節,但是應明白,未意圖排除來自彼等申請案的資訊。 範例 121888.doc -27- 200811865 =评細,造單—記憶體層級。可堆疊額外記憶體層級, 母者以早片方式形成於在其下方之記憶體層級的上方。 在此具體實施例中,複晶半導體二極體將用作為可切換記 憶體元件。 月多考圖15a,§己憶體之形成開始於基板i。此基板 ⑽可係此項技術所熟知之任何半導基板,諸如單結晶 夕iv iv化合物(如矽_鍺或矽_鍺_碳卜化合物、I。 • =IHb 口物、在此等基板上的磊晶層或任何其它半導材 料。基板可包括經製造於其中的積體電路。 在土板1 〇〇上形成一絕緣層〗〇2。絕緣層^μ可係氧化 矽、氮化矽、高介電膜、Si_c_〇韻或任何其它適合絕緣 材料。 在基板與絕緣體上方形成第一導體200。可在絕緣層102 :傳導層1〇6之間包括-黏著層1〇4,以協助傳導層1〇6黏 著於絕緣層102。如果上伏傳導層係鶴,則較佳係氮化鈦 ,作為黏著層1 〇4。 接下來待沉積之層係傳導層1〇6。傳導層106可包括此項 技術所熟知之任何傳導層材料,諸如鶴或其它材料,包括 鉅、鈦、銅、鈷或其任何合金。 一已/儿積將形成導體軌的所有層,將使用任何適合的 遮罩與蝕刻製程來圖案化及蝕刻彼等層,以形成實質上平 行實貝上共面導體2〇〇,如圖15&之剖面圖所示。在一項 /、體實施 <列中,$冗積光阻,並且藉由微影及彼等經餘刻之 層來圖案化該光阻,並且接著使用標準製程技術來移除該 121888.doc -28- 200811865 光阻。可替代地藉由鑲嵌方法來形成導體2〇〇。 接下來,在導體執200上方及之間沉積一介電材料1〇8。 介電材料108可係任何已知之電絕緣材料,例如,氧化 石夕、氮化石夕及/或氮氧化石夕。在一較佳具體實施例中,可 使用二氧化矽作為介電材料i 〇8。 最後,移除位於導體軌200最頂部上過量的介電材料 1〇8,曝露出藉由介電材料1〇8來分隔之導體執2〇〇之最頂 ⑩部,並且留下實質上平坦表面1〇9。圖15a繪示所得結構。 藉由此項技術所熟知之任何製程(諸如化學機械拋光(cMp) 或回蝕)來實行過滿介電之移除,以形成平坦表面ι〇9。可 有利使用的回蝕的技術描述於Raghuram等人於2〇〇4年6月 3〇曰提出之美國專利申請案第1〇/883417號,,N〇nSelective Unpattemed Etchback to Expose Buried Patterned Features ’並且特此以引用方式併入本文中。在此階段, 已在基板1 〇〇上以第一高度形成複數個實質上平行之第一 I 導體。 —接下來明參考圖15b,將在完成之導體執2〇〇上方形成 “直柱(為了喊省空間,圖15b中未繪示出基板;將 :二有基板存在)。較佳方式為,沉積一障壁層ιι〇以作為 Z平坦化導體軌之後的第_層。可在障壁層中使用任何適 I之材料’包括氮化鎢、氮化鈕、氮化鈦或彼等材料之組 :在較佳具體實施例中,使用氮化鈦作為障壁層。若 障壁層係氮化鈦,則可依相同於上文所述之沉積黏著層的 方式來沉積障壁層。 121888.doc -29· 200811865 接下來,沉積將被圖案化成為柱的半導體材料。該半導 體材料可係石夕、鍺、石夕·鍺合金或其它適合半導體或^導 體口金。為了簡單明瞭,本分說明書將半導體材料指稱為 矽,但是熟悉此項技術者應明白可選擇任何彼等其它適合 材料以作為替代。 在較佳具體實施例中,柱包括半導體接面:極體。本文 中使用用詞"接面二極體"來指稱具有非歐姆傳導屬性、且 • 有兩端子式電極以及係由半導體材料(其-電極處係㈣: 另-電極處係η型)所製成之半導體裝置。實例包括Η二極 體及η-p二極體(其具有接觸的p型半導體材料與η型半導體 材料’諸如齊納二極體)以及…二極體(其中本質(未經摻 雜)半導體材料被插入於ρ型半導體材料與11型半 之間。 竹 可藉由此項技術所熟知的任何沉積摻雜方法來形成 重摻雜區112。可沉積且接著摻雜石夕,但是較佳藉由於沉 積石夕期間使提供η型摻雜物原子(例如,麟)的施體氣體流動 進行原位摻雜。重摻雜區m之厚度較佳係介於約⑽ 約800埃之間。 ' ,、 可藉由此項技術所熟知的任何方法來形成本質層114。 層114可係矽、鍺或任何矽或鍺之合金 約議埃與約测埃之間,較佳係約W度係,^於 請重新參考圖15 b,剛固、竹拉μ卜、* 剛剛/儿積的半導體層114與 同下伏阻障層110—起祧R將連 起破圖案化及蝕刻以形成柱300。柱 300應具有約相同於下方之導體2⑼之間距與寬度,使得每 121888.doc 200811865 一柱300被形成於導體200之最頂部。可容許一些錯位。 可使用適合遮罩與蝕刻製程來形成柱300。舉例而言, 可沉積光阻、使用標準微影技術來圖案化並且蝕刻該光 阻,接著移除該光阻。替代做法為,可在半導體層堆疊最 頂部上(在頂部上具有底部抗反射塗層(BARC))形成某其它 材料(例如,二氧化矽)之硬遮罩,接著予以圖案化及蝕 刻。同樣地,可使用介電抗反射塗層(DARC)作為硬遮 罩。 於Chen於2003年12月5曰申請之美國專利申請案第 10/728436號,’Photomask Features with Interior Nonprinting Window Using Alternating Phase Shifting";或 Chen於 2004 年4月1日申請之美國專利申請案第10/8153 12號"Photomask Features with Chromeless Nonprinting Phase Shifting Window”(彼等案皆由本發明受讓人所擁有並且皆特此以 引用方式併入本文中)中描述之微影技術有利於用於實行 在形成根據本發明之記憶體陣列中使用的任何微影步驟。 在半導體柱300上方及之間沉積介電材料108,以填滿柱 之間的間隙。介電材料108可係任何已知之電絕緣材料, 例如,氧化矽、氮化矽及/或氮氧化矽。在一較佳具體實 施例中,使用二氧化矽作為絕緣材料。 接下來,移除位於柱300最頂部上的介電材料,曝露出 藉由介電材料108分隔之柱300之最頂部,並且留下實質上 平坦表面。藉由此項技術所熟知之任何製程(諸如CMP或 回蝕)來實行過滿介電之移除。在CMP或回蝕之後,實行 121888.doc -31 - 200811865 離子植入,形成頂部重摻雜P型區i 16。p型摻雜物較佳係 硼或BCI3。此植入步驟完成二極體U1之形成。圖i5b繪示 所得結構。在剛剛形成的二極體中,底部重摻雜區1 i 2係η 型’並且頂部重摻雜區116係ρ型;顯然地,極性可顛倒。 請參考圖15c,接下來,在每一重掺雜ρ型區U6之頂部 上形成介電破裂反熔絲層118。反熔絲118較佳係藉由在迅 速熱退火(例如,約600度)中氧化下伏矽所形成的二氧化矽 _ 層。反熔絲U8之厚度可約20埃。替代做法為,可沉積反 熔絲11 8。 可用相同於底部導體2〇〇之方式來形成頂部導體4〇〇,舉 例而言,藉由沉積黏著層12〇 (較佳由氮化鈦所製成)及傳 導層122 (較佳由鎢所製成)。接著,使用任何適合的遮罩 與蝕刻製程來圖案化及蝕刻傳導層122及黏著層12〇,以形 成實質上平行、實質上共面導體4〇〇,如圖15。之左至右跨 頁K申所$纟&佳具體實施例中,沉積光阻,並且藉U.S. Patent Application Serial No. 11/148,530, entitled "Nonvolatile Memory Cell Operating by Increasing Order in Polycrystalline Semiconductor Material", and U.S. Patent Application, filed on Sep. 29, 2004. No. 10/954,510 "Memory Cell Comprising a Semiconductor Junction Diode Crystallized Adjacent to a Silicide" (all of which are owned by the assignee of the present invention and hereby incorporated herein by reference) The crystallization of the complex crystal enthalpy affects the properties of the polycrystalline germanium. The lattice structure of some metal halides (such as cobalt telluride and titanium telluride) is very close to the lattice structure of germanium. When amorphous or microcrystalline germanium is crystallized When it is contacted with one of the tellurides, during the crystallization, the lattice structure of the telluride provides a stencil for the ruthenium. The resulting ruthenium ruthenium will be highly ordered and the defects are rather low. When the material is doped, the high quality polycrystalline germanium is relatively highly conductive when formed. In contrast, The amorphous or microcrystalline germanium material is crystallized to be in contact with germanium having a germanide (the crystal lattice of the germanide is well matched to germanium), for example, 'only in contact with, for example, ceria and titanium nitride (two If the lattice of yttrium oxide and titanium nitride is significantly mismatched to 矽), the resulting ruthenium ruthenium will have many more defects, and the doped ruthenium crystallized in this way will be very low in formation. Conductivity. In the aspect of the invention, the semiconductor material forming the diode is switched between two or more resistivity states, and the current flowing through the diode is changed at a predetermined read voltage, and different currents are Corresponding to the state of the data in the resistivity state. It has been found that highly defective germanium (or other suitable semiconductor material such as germanium or germanium) has not been crystallized by a similar material adjacent to the material or providing a crystallized template. The bismuth formed by bismuth-tellurium alloy exhibits a more favorable switching behavior. Without wishing to be bound by any particular theory, it is believed that the mechanism that supports the observed resistivity change is that it is above the threshold. The set pulse of amplitude causes the dopant atoms to move out of the grain boundary (where the dopant atoms are inactive) into the crystal body (where the dopant atoms will increase the conductivity and reduce the resistance of the semiconductor material). Resetting the pulse may cause the dopant atoms to move back to the grain boundary to reduce the transmission rate and increase the resistance. ❻*, there may be other mechanisms to operate or as an alternative, such as increasing or decreasing the degree of sequencing of the polycrystalline material. It was found that the electrical P-rate L of the crystallized very low defect 相邻 adjacent to the appropriate bismuth compound did not have the same ease as when the semiconductor material had a higher degree of defects. 121888.doc -26 - 200811865 Easy to switch. The presence of defects or the presence of a large number of grain boundaries may allow for easier switching. In a preferred embodiment, then the polycrystalline or microcrystalline material forming the diode is not crystallized adjacent to the material having a small lattice mismatch. A small lattice mismatch system (for example) does not match a lattice of about 3 percent or less. Evidence has suggested that switching behavior can focus on changes in the essential area. Switching behavior has been observed in resistors and p-i-n diodes and is not limited to p-i-n diodes, but the use of p-i-n diodes may be particularly advantageous. Specific embodiments described so far include p-i-n diodes. However, in other embodiments, the diodes may alternatively be p-n diodes and have negligible or no intrinsic regions. Detailed examples describing the fabrication of preferred embodiments of the invention will be provided. U.S. Patent Application Serial No. 10/320,470, entitled "An Improved Method for Making High Density Nonvolatile Memory" (also incorporated herein by reference). The details of the manufacture will help to form the diodes of the specific embodiments of the invention from the '549 application. U.S. Patent Application Serial No. 11/015,824, filed on December 17, 2004, to Hemer et al. ''Nonvolatile Memory Cell Comprising a Reduced Height Vertical Diode" (which is owned by the assignee of the present invention and hereby incorporated by reference herein in its entirety in its entirety in its entirety in the entireties in the entireties in All details of the case, but it should be understood that it is not intended to exclude information from their applications. Example 121888.doc -27- 200811865=Review, order-memory level. Stackable additional memory level, mother early The chip mode is formed above the memory level below it. In this embodiment, the polycrystalline semiconductor diode will be used as a cuttable Memory element. Figure 15a, § The formation of the memory begins with substrate i. This substrate (10) can be any semi-conductive substrate well known in the art, such as a single crystal iv iv compound (such as 矽 锗 or矽_锗_Carb compound, I. • = IHb mouthpiece, epitaxial layer on any of these substrates or any other semiconductive material. The substrate may include an integrated circuit fabricated therein. Forming an insulating layer 〇2. The insulating layer can be yttrium oxide, tantalum nitride, high dielectric film, Si_c_〇 rhyme or any other suitable insulating material. The first conductor 200 is formed over the substrate and the insulator. Between the insulating layer 102: the conductive layer 1〇6, an adhesive layer 1〇4 is included to assist the conductive layer 1〇6 to adhere to the insulating layer 102. If the upper conductive layer is a crane, it is preferably titanium nitride. Adhesive layer 1 〇 4. Next to the layer to be deposited is conductive layer 1 〇 6. Conductive layer 106 may comprise any conductive layer material well known in the art, such as cranes or other materials, including giant, titanium, copper, cobalt or Any of its alloys. All the layers will form all the layers of the conductor track and will use any The mask and etch process are used to pattern and etch the layers to form a substantially parallel scalloped coplanar conductor 2〇〇 as shown in the cross-sectional view of FIG. 15 & In the column, $ is redundant, and the photoresist is patterned by lithography and their remaining layers, and then the standard process technique is used to remove the photoresist from 121888.doc -28-200811865. The conductor 2〇〇 can alternatively be formed by a damascene method. Next, a dielectric material 1 〇 8 is deposited over and between the conductor holders 200. Dielectric material 108 can be any known electrically insulating material, such as, for example, oxidized stone, nitrided, and/or nitrous oxide. In a preferred embodiment, cerium oxide can be used as the dielectric material i 〇8. Finally, the excess dielectric material 1 〇 8 on the top of the conductor track 200 is removed, exposing the top 10 of the conductors separated by the dielectric material 1 〇 8 and leaving substantially flat The surface is 1〇9. Figure 15a depicts the resulting structure. Excessive dielectric removal is performed by any process well known in the art, such as chemical mechanical polishing (cMp) or etch back to form a planar surface 〇9. A technique that can be advantageously used for eclipse is described in U.S. Patent Application Serial No. 1/883,417 issued by Raghuram et al., June 3, 2014, N〇nSelective Unpattemed Etchback to Expose Buried Patterned Features' and This is hereby incorporated by reference. At this stage, a plurality of substantially parallel first I conductors have been formed on the substrate 1 at a first height. - Referring next to Figure 15b, a "straight column will be formed over the finished conductor 2 (in order to save space, the substrate is not shown in Figure 15b; there will be: two substrates present). Preferably, A barrier layer is deposited as the first layer after Z flattening the conductor track. Any suitable material may be used in the barrier layer 'including tungsten nitride, nitride button, titanium nitride or a combination of materials thereof: In a preferred embodiment, titanium nitride is used as the barrier layer. If the barrier layer is titanium nitride, the barrier layer can be deposited in the same manner as described above for depositing the adhesion layer. 121888.doc -29· 200811865 Next, a semiconductor material to be patterned into a pillar is deposited. The semiconductor material may be a stone, a bismuth, a bismuth alloy, or other suitable semiconductor or metal conductor. For the sake of simplicity, the specification refers to semiconductor materials. For the sake of blemishes, those skilled in the art will appreciate that any other suitable material may be selected as an alternative. In a preferred embodiment, the post includes a semiconductor junction: a polar body. The term " Polar body " to refer to a semiconductor device having a non-ohmic conduction property and having a two-terminal electrode and a semiconductor material (the electrode portion (four): the other electrode portion is n-type). Examples include a dipole And η-p diodes (having a contact p-type semiconductor material and an n-type semiconductor material such as a Zener diode) and a diode (wherein an intrinsic (undoped) semiconductor material is inserted in ρ The type of semiconductor material is between the type 11 and the half. Bamboo can be formed by any deposition doping method well known in the art to form heavily doped regions 112. It can be deposited and then doped with Shi Xi, but preferably by deposition of Shi Xi The donor gas flow providing the n-type dopant atoms (for example, lining) is doped in situ during the period. The thickness of the heavily doped region m is preferably between about (10) and about 800 angstroms. The intrinsic layer 114 is formed by any method known to the art. The layer 114 may be a tantalum, niobium or any alloy of niobium or tantalum between about angstroms and about angstroms, preferably about a degree system. Referring back to Figure 15 b, the rigid, bamboo pull, and * just 114 and the same underlying barrier layer 110 - R will be patterned and etched to form a pillar 300. The pillar 300 should have a pitch and width approximately the same as the conductor 2 (9) below, such that each pole is 121888.doc 200811865 300 is formed at the very top of the conductor 200. Some misalignment can be tolerated. The pillar 300 can be formed using a suitable masking and etching process. For example, photoresist can be deposited, patterned using standard lithography techniques, and etched. And then removing the photoresist. Alternatively, a hard mask of some other material (eg, cerium oxide) may be formed on the topmost layer of the semiconductor layer stack (with a bottom anti-reflective coating (BARC) on top), It is then patterned and etched. Likewise, a dielectric anti-reflective coating (DARC) can be used as the hard mask. U.S. Patent Application Serial No. 10/728,436, filed on Jan. 5, 2003, the disclosure of which is incorporated herein by reference in its entirety, the entire entire entire entire entire entire entire entire entire entire content The lithography technique described in 10/8153 12 "Photomask Features with Chromeless Nonprinting Phase Shifting Window" (both of which are owned by the assignee of the present invention and incorporated herein by reference) Any lithographic step used in forming a memory array in accordance with the present invention. A dielectric material 108 is deposited over and between the semiconductor pillars 300 to fill the gaps between the pillars. The dielectric material 108 can be any known electrical power. Insulating material, for example, hafnium oxide, tantalum nitride, and/or hafnium oxynitride. In a preferred embodiment, ceria is used as the insulating material. Next, the dielectric material on the topmost portion of the pillar 300 is removed. Exposing the topmost portion of the pillar 300 separated by the dielectric material 108 and leaving a substantially flat surface. Any of those well known in the art The process (such as CMP or etch back) is used to perform the removal of the over-dielectric. After CMP or etch back, 121888.doc -31 - 200811865 ion implantation is performed to form the top heavily doped P-type region i 16. p-type The dopant is preferably boron or BCI 3. This implantation step completes the formation of the diode U1. Figure i5b shows the resulting structure. In the diode just formed, the bottom heavily doped region 1 i 2 is η-type' And the top heavily doped region 116 is p-type; obviously, the polarity can be reversed. Referring to Figure 15c, next, a dielectric rupture antifuse layer 118 is formed on top of each heavily doped p-type region U6. The wire 118 is preferably a layer of ruthenium dioxide formed by oxidizing the underlying ruthenium in a rapid thermal annealing (e.g., about 600 degrees). The thickness of the antifuse U8 may be about 20 angstroms. Alternatively, the deposition may be reversed. Fuse 11 8. The top conductor 4 can be formed in the same manner as the bottom conductor 2〇〇, for example, by depositing an adhesive layer 12 (preferably made of titanium nitride) and a conductive layer 122 ( Preferably made of tungsten.) Next, the conductive layer 12 is patterned and etched using any suitable masking and etching process. 2 and the adhesive layer 12〇 to form a substantially parallel, substantially coplanar conductor 4〇〇, as shown in FIG. 15. The left-to-right cross-page K is in a preferred embodiment, depositing photoresist, and borrow
由微影及彼等經㈣之層來圖案化該光阻,並且接著使用 標準製程技術來移除該光阻。 接:來,在導體執4〇〇上方及之間沉積一介電材料(圖中 未繪示)。介電材料可係任何已知之電絕緣材料,例如, 氧化矽、氮化矽及/或氮氧 A IU / 隹杈佳具體實施例 中’可使用二氧化石夕作為此介電材料。 已描述形成一第一記悴齅层 L、體層級。可在此第一記憶體層級 上形成額外㊂己憶體層級,以來 一 _ 一 开7成一早片二維記憶體陣列。 在一些具體實施例中,可在 J在圯憶體層級之間共用導體; 121888.doc -32- 200811865 即,頂部導體400將作為下一記憶體層級之底部導體。在 其它具體實施例中,在圖15c之第一記憶體層級上方形成 一層間介電(圖中未繪示),其表面經平坦化,並且一第二 記憶體層級之構造開始於此經平坦化層間介電上,而且無 共用之導體。 , 單片三維記憶體陣列係在其中在一單一基板(諸如一晶 - 圓)上方形成多重記憶體層級而且無中介基板的記憶體陣 φ 列。形成一記憶體層級的彼等層係直接沉積或生長於一現 有層級或多重層級的彼等層上方。相比之下,已藉由在單 獨的基板上形成記憶體層級並且使彼等記憶體層級彼此在 頂部上黏者建構堆璺式記憶體,如同Lee(Jy之美國專利案 苐 5,915,167號,’Three dimensional structure memory” 中所提 出。彼等基板可在接合之前予以薄化或自彼等記憶體層級 移除’但疋當在單獨基板上初始形成彼等記憶體層時,此 等記憶體不是真正的單片三維記憶體陣列。 _ 在基板上方形成之單片三維記憶體陣列包括至少一第一 呑己fe體層級(其係以高於基板之第一高度予以形成)及一第 一記憶體層級(其係以不同於第一高度之第二高度予以形 : 成)。在此多層級記憶體陣列中,可在基板上方形成三、 -四、八或甚至任何數量之記憶體層級。 在Radigan等人於2〇〇6年5月31日申請之美國專利申請案 弟 11/444,936號 Conductive Hard Mask to Protect Patterned Features During Trench Etch”中描述一種用於形成類似記 憶體陣列之替代方法,其中使用鑲嵌構造來形成導體,該 121888.doc -33- 200811865 案由本發明受讓人所擁有並且特此以引用方式併入本文 中。可代替地使用Radigan等人之方法來形成根據本發明 之記憶體陣列。 替代具體實施例 除了已描述之彼等具體實施例以外,以複晶或微晶半導 體材料之電阻率狀態來儲存其資料狀態之記憶體單元的許 多替代具體實施例亦可行並且屬於本發明範疇内。將提及 少數其它可行具體實施例,但此清單不可且非意圖詳盡列 舉。 圖16繪示以串聯於二極體1 η方式形成之可切換式記憶 體元件117。可切換式$己憶體元件117係由如所述使用電脈 衝切換於電阻率狀態之間的半導體材料所形成。如上文所 述’二極體較佳係相鄰於矽化物(諸如矽化鈷,其提供晶 化模板)予以結晶化,致使二極體之半導體材料缺陷極低 並且展現出微不足道或無切換行為。較佳方式為,可切換 式記憶體元件117經摻雜,並且應摻雜至相同於頂部重摻 雜區116的傳導類型。,167申請案中描述此裝置之製造方 法。 本文中已描述詳細製造方法,但是可使用形成相同結構 的任何其它方法,同時結果屬於本發明範疇内。 示範性應用 刚文之具體實施例描述如何可使用記憶體單元作為兩種 貧料狀態式記憶體單元、兩種以上資料狀態式記憶體單 元、可單次程式化記憶體單元或可重寫記憶體單元。此多 121888.doc -34 - 200811865 用途允許制共同記龍單元架構來提供之纪情 體產品。下文論述記憶體單元之多用途性f及其提 : 途記憶體陣列之潛力》 ''The photoresist is patterned by lithography and their layers (4), and then the photoresist is removed using standard process techniques. Connect: A dielectric material (not shown) is deposited over and between the conductors. The dielectric material can be any known electrically insulating material, for example, hafnium oxide, tantalum nitride, and/or nitrogen oxide A IU / / in particular embodiments - can be used as the dielectric material. It has been described to form a first recording layer L, a body level. An additional three-replica level can be formed on the first memory level, since the first two-in-one seven-in-one two-dimensional memory array. In some embodiments, the conductors may be shared between J levels in the memory layer; 121888.doc -32- 200811865 That is, the top conductor 400 will serve as the bottom conductor of the next memory level. In other embodiments, an inter-layer dielectric (not shown) is formed over the first memory level of FIG. 15c, the surface of which is planarized, and the construction of a second memory level begins here. The layers are dielectrically and have no shared conductors. The monolithic three-dimensional memory array is in a memory array φ column in which a plurality of memory levels are formed over a single substrate (such as a crystal-circle) and without an interposer. The layers forming a memory level are deposited or grown directly over an existing layer or layers of multiple levels. In contrast, stacked memory has been constructed by forming memory levels on separate substrates and affixing their memory levels to each other, as in Lee (Jy's U.S. Patent No. 5,915,167, ' Three dimensional structure memory. It is suggested that their substrates can be thinned or removed from their memory levels before bonding. But when these memory layers are initially formed on separate substrates, these memories are not real. a single-chip three-dimensional memory array. _ A single-chip three-dimensional memory array formed over the substrate includes at least a first fe fe body level (which is formed at a higher level than the first height of the substrate) and a first memory A level (which is formed at a second height different from the first height). In this multi-level memory array, three, four, eight or even any number of memory levels can be formed over the substrate. A method described in Radian et al., US Patent Application Serial No. 11/444,936, entitled "Conductive Hard Mask to Protect Patterned Features During Trench Etch", filed May 31, 2005. An alternative method of forming a similar array of memory, in which a mosaic is used to form a conductor, is owned by the assignee of the present invention and is hereby incorporated by reference herein in its entirety. Method of forming a memory array in accordance with the present invention. Alternative Embodiments In addition to the specific embodiments that have been described, many of the memory cells that store their data states in the resistivity state of the polycrystalline or microcrystalline semiconductor material Alternative embodiments are also possible and are within the scope of the invention. A few other possible embodiments will be mentioned, but this list is not intended to be exhaustive and enumerated. Figure 16 illustrates a switchable form formed in series with a diode 1 η. Memory element 117. The switchable $ ** element 117 is formed by a semiconductor material that is switched between resistive states using electrical pulses as described above. As described above, the 'diode is preferably adjacent to The telluride (such as cobalt telluride, which provides a crystallization template) is crystallized, resulting in a semiconductor material defect of the diode that is extremely low and exhibits Insignificant or no switching behavior. Preferably, the switchable memory element 117 is doped and should be doped to the same conductivity type as the top heavily doped region 116. The fabrication of the device is described in the '167 application. Methods. Detailed fabrication methods have been described herein, but any other method of forming the same structure can be used, with the results falling within the scope of the present invention. Exemplary Applications The specific examples of how to use memory cells as two poor materials are described. State memory cells, two or more data state memory cells, single-programmed memory cells, or rewritable memory cells. This multi-purpose 121888.doc -34 - 200811865 uses the common record system to provide the commemorative products. The versatility of memory cells and their implications are discussed below: "The potential of memory arrays"
上文所述之記憶體單元具有包含可切換式電阻材料(諸 如可組態至至少三種電阻率狀態中之一者的半導體材料) 之記憶體70件。可於形成記憶體元件期間將記憶體元件 "組態"至-電阻率狀態(例如,初始、未經程式化狀離之纪 憶體元件具有初始電阻率狀態),或藉由後續使記憶體元 件經受設定脈衝或重設脈衝來將記憶體元件"組態"至一電 阻率狀態。因為此特性,所以單一記憶體單元可依兩種不 同方式進行動作:作為可單次程式化記憶體單元或可重寫 記憶體單元。再者’因為此特性,所以單一記憶體單元可 使用兩種資料狀態或兩種以上資料狀態。據此,任何既定 製造的記憶體單元皆具有運作為具有兩種或兩種以上資料 狀態之可單次程式化記憶體單元或可重寫記憶體單元的潛 力0 如圖所示並且如上文所述,當記憶體單元運作為可單次 程式化記憶體單元時,使用一電阻率狀態來表示記憶體單 元的^料狀悲,但是當記憶體單元運作為可重寫記憶體 單元時,不使用該電阻率狀態來表示記憶體單元的一資料 狀恝。換言之,當記憶體單元係用作為可單次程式化記憶 體單7L時,在記憶體單元中可能有一"額外”狀態。舉例而 言,關於上文所述且配合圖5與圖u所描述之記憶體單 元’ δ己憶體單元被製造成處於初始電阻率狀態(V狀態), 121888.doc -35- 200811865 t且當記憶體單元運作為可單次程式化記憶體單元時,使 ^初始電阻率狀態;但是當記憶體單㈣作為可重寫記 體早元時,則不使用此初始電阻率狀態。當記憶體單元 運作為可重寫記憶體單⑽,使用兩種其它資料狀態(⑽ 憑及8狀態)來表示記憶體單元之資料狀態。(如下文所 $亦可在可單次程式化記憶體單元中使用彼等資料狀 〜)藉由改變可切換式電阻材料之電阻來達成彼等資料 狀態。再次,彼等其它資料狀態不包括僅當記憶體單元運 作為可單_人転式化記憶體單元時才用於表示資料狀態的資The memory unit described above has a memory 70 member comprising a switchable resistive material, such as a semiconductor material configurable to one of at least three resistivity states. The memory component"" to-resistivity state (e.g., the initial, unprogrammed, sigma component has an initial resistivity state) may be formed during formation of the memory component, or by subsequent The memory component is subjected to a set pulse or reset pulse to "configure" the memory component to a resistivity state. Because of this feature, a single memory cell can operate in two different ways: as a single-programmable memory cell or as a rewritable memory cell. Furthermore, because of this characteristic, a single memory unit can use two data states or two or more data states. Accordingly, any predetermined memory cell has the potential to operate as a single-programmed memory cell or rewritable memory cell having two or more data states as shown and as above As described above, when the memory unit operates as a single-programmed memory unit, a resistivity state is used to represent the memory of the memory unit, but when the memory unit operates as a rewritable memory unit, This resistivity state is used to represent a profile of the memory cell. In other words, when the memory unit is used as a single-programmable memory single 7L, there may be an "extra" state in the memory unit. For example, as described above and in conjunction with Figures 5 and u The described memory unit ' δ hex memory unit is fabricated to be in an initial resistivity state (V state), 121888.doc -35- 200811865 t and when the memory unit operates as a single-programmed memory unit, ^Initial resistivity state; but when the memory single (4) is used as a rewritable memory early element, the initial resistivity state is not used. When the memory unit operates as a rewritable memory single (10), two other materials are used. The status ((10) and 8 states) indicates the data status of the memory unit. (As shown in the following figure, the data can also be used in a single-programmed memory unit~) by changing the switchable resistance material. Resistors are used to achieve the status of their data. Again, their other data states do not include the information used to represent the status of the data only when the memory unit operates as a single-person memory unit.
料狀恶。可使用額外資料狀態(例如,介於r狀態與s狀態 之間的’’R2’’狀態)以允許可重寫記憶體單元達成三種或達 成三種以上各別資料狀態。 應/主思,在一項較佳具體實施例中,記憶體元件包括串 聯於反熔絲的切換式電阻材料(例如,半導體材料),並且 V狀態係僅當記憶體單元運作為可單次程式化記憶體單元 時才使用的電阻率狀態。原因係一旦反熔絲被燒斷,則記 憶體元件無法回到V狀態。但是,甚至當不使用反熔絲 時,可將一電阻率狀態指定作為僅當記憶體單元運作為可 單次程式化記憶體單元時才使用的狀態。亦應注意,P狀 態亦可係當記憶體單元運作為可單次程式化記憶體單元時 予以使用但是當記憶體單元運作為可重寫記憶體單元時不 予以使用的電阻率狀態。但是,在一些具體實施例中,替 代P狀態或除了 P狀態以外,使用R狀態與S狀態中之一者 或兩者來表示可單次程式化記憶體單元的一資料狀態,諸 -36 - 121888.doc 200811865 如萬可卓次程式化δ己憶體單元儲存三種或四種資料狀態 時。在此一情況中,㊂己憶體單元之可單次程式化與可重寫 用途將共同具有一電阻率狀態。舉例而言,代替具有獨特 狀態狀態之可單次程式化記憶體單元及可重寫記憶體單元 (例如,V狀態及Ρ狀態係用於可單次程式化記憶體單元, 及R狀態及S狀態係用於可重寫記憶體單元),可單次程式 化記憶體單元及可重寫記憶體單元可共同具有一狀態(例 如,s狀態與ρ狀態之間無任何差別)。然而,當記憶體單 元運作為可單次程式化記憶體單元時,仍然將使用至少一 電阻率狀態(例如,ν狀態)來表示記憶體單元的一資料狀 態;但是當記憶體單元運作為可重寫記憶體單元時,則非 如此。 此多用途的一項優點在於具有此等記憶體單元的單一積 體電路可被指定作為可單次程式化記憶體陣列或作為可重 寫記憶體陣列。此提供製造靈活性及良率提升。為了判定 e憶體陣列是否應用作為可單次程式化記憶體陣列或作為 可重寫記憶體陣列,可於製造期間(或之後)測試記憶體陣 列中的一組測試記憶體單元。舉例而言,可藉由重複程式 化、重没及設定彼等測試記憶體單元來運用彼等測試記憶 體單元。美國專利案第6,407,953號中描述一種適合的測試 技術,彼專利案經讓渡給本發明受讓人並且特此以引用方 式整份併入本文。依據測試結果,可預測記憶體陣列是否 將正確程式化以作為可重寫記憶體陣列。舉例而言,如果 測試展現出難以辨別R狀態及s狀態(彼等狀態係用於當記 121888.doc -37- 200811865 憶體陣列運作為可重寫記憶體陣列時),則該部件將很可 月b未正確程式化以作為可重寫記憶體陣列。但是,因為記 體陣列中的記憶體單元可運作為可單次程式化記憶體陣 歹J或作為可重寫兄憶體陣列,所以代替因該部件未提供所 預期可重寫結果而予以丟棄,可指定該部件作為可單次程 弋化z L體陣列。據此,共同骨幹記憶體單元架構提供製 造靈活性及良率提升。 _ 在此點,可有製造分歧。通過測試的記憶體陣列可繼續 用以進一步格式化(例如,將所有記憶體單元自¥狀態程式 化至p狀態,接著於尺狀態與s狀態之間予以運用以作為最 終資格測試),並且接著作為可重寫記憶體陣列(例如,用 於數位攝影機的記憶卡)運送至倉庫或使用者。未通過測 試的記憶體陣列可予以,裝且送至製造廠之不同部分以程 式化可單-人私式化内容。替代做法為,該部件可送至倉 庫由启庫員工或使用者現場程式化可單次程式化内容 _ (例如,使用kiosk)。未經程式化部件亦可銷售給使用者以 用作為存檔用記憶體。 較佳方式為,使用一旗標來發訊號給讀取及寫入至記憶 體陣列的裝置(例如,在主機裝置中包括記憶體陣列或硬 體/軟體的記憶體裝置上的控制器)以告知記憶體陣列係可 單次程式化記憶體陣列或可重寫記憶體陣列。"旗標"可係 儲存於記憶體陣列中的一或多個位元。舉例而言,可在記 L體陣列中的一特殊位址位置(例如,位址⑽⑽)中設定旗 標。當主機裝置偵測到旗標時,其可藉由不嘗試重新程式 121888.doc -38 - 200811865 化記憶體陣列來調適至記憶體陣列的可單次程式化性併 代替使用整個記憶體陣列作為可單次程式化記悚體二 或作為可重寫記憶料列,記憶體陣列可係”多用途产 體陣列。在此具體實施例中,由於記憶體陣列中的所^ -記憶體單元皆可用作為可單次程式化記憶體單元或用: 為可重寫記龍單元,所以_第_組記憶體單元運作為可 單次程式化記憶體單元’及一第二組記憶體單元運作為可 重寫記憶體單元。在此方式中’可在相同積體電路上可單 次程式化記憶體單元及可重寫記憶體單元。如上文所述, 可實行測試以判定-既定組記憶體單元是否應被指定作為 可單次程式化記憶體單元或可重寫記憶體單元。 圖17繪示較佳具體實施例之混合用途記憶體陣列2〇〇之 圖解。一第一組記憶體單元21〇運作為可單次程式化記憶 體單元,以及一第二組記憶體單元22〇運作為可重寫記憶 體單7G。在此具體實施例中,該兩組21〇、22〇中的記憶體 单元皆包含相同數量之每記憶體單元資料狀態,然而記憶 體單元資料狀態之數量變化係可行,如下文所述。在一項 /、體實施例中,第一組記憶體單元儲存被視為永久性且可 相關於記憶體陣列運作的資料。此資訊之實例包括(但不 限於)下列項目中之一或多項:内容管理位元、修整位 元、製造商資料及格式化資料。 内谷官理位元”指稱相關於經程式化内容之管理的資 訊。修整位元”係設定晶片上電路中各種選項的自訂資 訊。運作中’晶片上電路讀取第一組記憶體單元210中的 121888.doc -39- 200811865Materialy evil. Additional data states (e.g., ''R2'' state between the r state and the s state) may be used to allow the rewritable memory cells to achieve three or more than three distinct data states. In a preferred embodiment, the memory component includes a switched resistive material (eg, a semiconductor material) connected in series with the antifuse, and the V state is only a single operation when the memory cell operates The resistivity state that is used when staging memory cells. The reason is that once the antifuse is blown, the memory element cannot return to the V state. However, even when no antifuse is used, a resistivity state can be designated as a state to be used only when the memory cell operates as a single-programmable memory cell. It should also be noted that the P state can also be a resistivity state that is used when the memory cell operates as a single-programmable memory cell but is not used when the memory cell operates as a rewritable memory cell. However, in some embodiments, instead of or in addition to the P state, one or both of the R state and the S state are used to represent a data state of the single-programmable memory cell, the -36 - 121888.doc 200811865 When the three-dimensional stylized memory unit stores three or four data states. In this case, the single-programming and rewritable uses of the three-remembered unit will have a resistivity state in common. For example, instead of having a unique state state, a single-programmed memory cell and a rewritable memory cell (eg, V-state and state-of-state are used for a single-programmed memory cell, and R-state and S The state is for a rewritable memory unit), and the single-programmed memory unit and the rewritable memory unit can have a state together (for example, there is no difference between the s state and the ρ state). However, when the memory unit operates as a single-programmable memory unit, at least one resistivity state (eg, ν state) will still be used to represent a data state of the memory cell; however, when the memory cell operates as This is not the case when overwriting the memory unit. One advantage of this versatility is that a single integrated circuit with such memory cells can be designated as a single-programmable memory array or as a rewritable memory array. This provides manufacturing flexibility and yield improvement. To determine if an e-memory array is applied as a single-programmable memory array or as a rewritable memory array, a set of test memory cells in the memory array can be tested during (or after) manufacturing. For example, the test memory cells can be utilized by repeating the stylization, duplication, and setting of their test memory cells. A suitable test technique is described in U.S. Patent No. 6,407,953, the disclosure of which is hereby incorporated by reference in its entirety in its entirety in its entirety herein in Based on the test results, it is predicted whether the memory array will be properly programmed to act as a rewritable memory array. For example, if the test shows that it is difficult to distinguish between the R state and the s state (these states are used when the memory array is operated as a rewritable memory array), then the component will be very Month b is not properly programmed to act as a rewritable memory array. However, because the memory cells in the body array can operate as a single-programmable memory matrix or as a rewritable matrix, instead of being discarded because the component does not provide the expected rewritable results. This part can be specified as a single-pass degenerate z L-body array. Accordingly, the common backbone memory cell architecture provides manufacturing flexibility and yield improvement. _ At this point, there may be manufacturing differences. The tested memory array can continue to be further formatted (eg, stylized all memory cells from the ¥ state to the p state, then applied between the ruler state and the s state as a final qualification test), and then Shipped to a warehouse or user as a rewritable memory array (eg, a memory card for a digital camera). Memory arrays that fail the test can be loaded and sent to different parts of the manufacturing facility to program the single-person private content. Alternatively, the part can be sent to the warehouse to be programmed in the field by the Kaiku staff or the user to program the content _ (for example, using kiosk). Unprogrammed parts can also be sold to users for use as archive memory. Preferably, a flag is used to send a signal to a device for reading and writing to the memory array (for example, a controller on a memory device including a memory array or a hardware/software in the host device). The memory array is told to be a single-programmed memory array or a rewritable memory array. "flag" can be stored in one or more bits in a memory array. For example, a flag can be set in a special address location (e.g., address (10) (10)) in the L-body array. When the host device detects the flag, it can adapt to the single-programmability of the memory array by not attempting to re-program the memory array and instead use the entire memory array as a flag. The memory array can be a "multi-purpose product array" in a single program or as a rewritable memory array. In this embodiment, since the memory cells in the memory array are Can be used as a single-programmed memory unit or as: a rewritable long-range unit, so the _th-group memory unit operates as a single-programmed memory unit' and a second group of memory units operate as A rewritable memory cell. In this mode, the memory cell and the rewritable memory cell can be programmed once on the same integrated circuit. As described above, a test can be performed to determine - a predetermined set of memory Whether the unit should be designated as a single-programmable memory unit or a rewritable memory unit. Figure 17 is a diagram showing a preferred embodiment of a mixed-use memory array 2A. A first set of memory cells twenty one The operation is a single-programmed memory unit, and a second set of memory units 22 operates as a rewritable memory single 7G. In this embodiment, the two sets of memory in 21〇, 22〇 The units all contain the same number of data states per memory unit, however the number of changes in the memory unit data status is feasible, as described below. In an /, the first set of memory unit storage is considered Permanent and relevant to the operation of the memory array. Examples of this information include (but are not limited to) one or more of the following: content management bits, trim bits, manufacturer data, and formatted data. Bits refer to information related to the management of stylized content. The trim bit is a custom message that sets various options in the circuit on the wafer. The on-wafer circuit reads the first set of memory cells 210. 121888.doc -39- 200811865
修整位7L ’並且蹲靖術+ /夂杜 、、喝取之修整位元控制電路的進一步運作牛例而"’修整位元可包含用於記憶體裝置之寫入/項取電路的車乂 >[土寫入/讀取值(電流或電壓)的言史冑。”製造 商貝料T包括製造商名稱與序號。"格式化資料"指示出 :憶體陣列的不良部分;具體而t,記憶體陣列中之一特 疋列及/或仃不良及冗餘列及’或行位置。如需關於冗餘的 進^ >訊,印參閱美國專利申請案第ι〇/4〇2,385號及第 10/024,646遽,彼等專利中請案均已讓渡給本發明受讓人 並且特此以引用方式併人本文。當然,彼等資訊僅係實 例,並且可在可單次程式化記憶體單元21〇中儲存其它形 式之資訊。舉例而t,第一組記憶體單元21〇可包含遊戲 内容資料(即,遊戲的電腦程式碼),以及第二組記憶體單 元220可包含遊戲狀態資料(即,當使用者要求保存遊戲 時,在遊戲中之使用者位置的指示)。再者,可在製造廠 處或由後續使用者來程式化第一 組記憶體單元220中的資料。 組記憶體單元210或第 二 在圖17中,有可單次程式化記憶體單元的僅一個區段以 及可重冑記憶體單元的僅一個m在$ —具體實施例 中,有至少-射卜組記憶體單元運作為可單次程式化記憶 體單元或可重寫記憶體單元。圖18繪示此—具體實施例, 其中使兩個可單次程式化區段230、250與兩個可重寫區段 24〇、260交錯(即,兩相鄰組記憶體單元非皆是可單次程 式化或皆是可重寫)。如上文所述,可將任何資料儲存於 任何區段中。舉例而言,遊戲内容資料可儲存於可單次程 121888.doc -40- 200811865 式化區段230、250中,遊戲狀態資料可儲存於可重寫區段 240 、 260中 。 應注意,雖然圖17及圖18繪示依水平方式來定向該等組 記憶體單元’但是在替代具體實施例中,可依垂直方式來 定向一或多組記憶體單元。舉例而言,代替在水平列記憶 體單元中具有格式化資料(如圖17所示),格式化資料可以 係在垂直列記憶體單元中。在此方式中,冗餘資料將跨越 許多頁。亦可使用混合用途水平定向及垂直定向資訊。舉 例而言’製造資料可予以水钱向,而格式化資料可予以 垂直定向。 如圖18所示,每頁資料可包括—或多個旗標位元270, 其指示出-頁是否係可單次程式化或可重寫。纟圖18中, "1"旗標指示出可單次程式化,以及,,〇”旗標指示出可重 寫。較佳方式為,旗標係儲存於可單次程式化記憶體單元 中(即使記憶體單元係處於可重寫區段中)。再者,較佳方 式為,對於可單次程式&資料使預設讀取條件最佳化(所 以可成功讀取可單次程式化區段中儲存的可單次程式化旗 標位元與修整位元、製造資料等等),並如果旗標指示 出可重寫資料,則修改彼等讀取條件。使用旗標位元之— 項優點在於’實際上不可能使用可單次程式化記憶體單元 作為可重寫記憶體單元,反之亦然,原、因係藉由晶片上寫 電路來解譯旗標,該晶片上寫電路經程式化用❹果旗標 位元指示出一記憶體單元係可單次程式化,則防止超過: 次寫入至該記憶體單元。 121888.doc -41- 200811865 作為使用旗‘位疋的替代方案’位址空間計算與寫控制 可被移至晶片外,例如,移至主機裝置中的硬體/軟體。 舉例而言,如果使用記憶體裝置作為遊戲E,則主機裝置 中的軟體可使用用於儲存遊戲狀態資料的預先指定之位址 $間(主機裝置已知該位址空間,但記憶體未得知位址空 間)。替代做法為’可藉由儲存於記憶體陣列中之遊戲内 . 料巾、記憶料列m單次程式化部分(例如, # 己體陣列中的—特殊位址位置(例如,位址GGGG))或記憶 體裝置中與記憶體陣列分開的裝置控制器中的資訊來向主‘ 機裝置告知用於遊戲狀態資料的位址空間。 /在圖17及圖18所不之具體實施例中,就一些記憶體單元 係可2次程式化記憶體單元並且其它者係可重寫記憶體單 兀之思義而言,記憶體陣列係”混合用途"。在其它具體實 把例中,代替或除了可單次程式化/可i寫特徵,"混合用 途"記憶體陣列包含其它"混合"特徵。如上文所述,可使 _ 用旗私位元或其匕機制來判定-既定組記憶體單元的性 ^。舉例而言,在相同記憶體陣列中的第—組記憶體單元 可比第二組記憶體單元更加可靠並且溫度與電壓範圍更 寬。 作為另一項實<列,運用上文所述之較佳記憶體單元結 構’ -既定記憶體單元可係:(i)用正向偏壓予以程式化 (。例如,㈣一可單次程式化記憶體單元或可重寫記憶體 早元);或(ii)用逆向偏壓予以程式化(例如,如同一可重 寫記憶體單元,但不同於兩狀態式可單次程式化記憶體單 121888.doc -42- 200811865 元)。換言之,可單次程式化記憶體單元僅可接受正向偏 壓程式化,而可重寫記憶體單元可接受正向偏壓程式化及 逆向偏壓程式化兩者。此繪示於圖19及圖20之電路圖中。 如需正向偏壓寫入之詳細描述,請參閱美國專利案第 6,618,295號;以及如需逆向偏壓寫入之詳細描述,請參閱 美國專利申請案第11/461,339號(代理人檔案號碼第 023-0048 號)題為"Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders”及美國專利申請案第11/461,364號(代理人檔案號 碼第 023-0054號)題為"Method for Using a Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders",彼等案均已讓渡給本發明受讓人 並且特此以引用方式併入本文。據此,"混合用途"記憶體 陣列可包含:一第一組記憶體單元,其係用正向偏壓予以 程式化;及一第二組記憶體單元,其係用逆向偏壓予以程 式化。用逆向偏壓予以程式化的記憶體單元亦可用正向偏 壓予以擦除。在擦除操作(相較於寫入操作)中,一頁中的 個別資料位元不是變數,原因係在擦除操作中擦除了所有 位元。如需擦除操作之詳細描述,請參閱美國專利申請案 第11/461,339號(代理人檔案號碼第023-0048號)題為 ’’Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders"及美國專利申請 案第11/461,364號(代理人檔案號碼第023-0054號)題為 "Method for Using a Passive Element Memory Array 121888.doc •43- 200811865Dressing the 7L 'and the 蹲 术 + + / 夂 、 、 、 、 、 、 、 、 、 、 、 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 ' ' ' ' ' ' ' ' ' ' ' ' ' '乂>[The history of soil write/read values (current or voltage). "Manufacturer's material T includes the manufacturer's name and serial number. "formatted data" indicates: a bad part of the memory array; specifically, t, one of the memory arrays and/or defective and redundant Remaining and 'or row location. For more information on redundancy, see US Patent Application Nos. ι〇/4〇2,385 and 10/024,646遽, all of which have been filed in their patents. The assignee of the present invention is hereby incorporated by reference in its entirety to the extent that it is hereby incorporated by reference in its entirety in the the the the the the the the the the the the the A set of memory units 21A may include game content material (ie, a computer program code of the game), and the second set of memory units 220 may include game state data (ie, when the user requests to save the game, in the game) Further, the data in the first set of memory units 220 can be programmed at the manufacturer or by a subsequent user. The group memory unit 210 or the second is in FIG. Secondary stylized memory unit only Only one m of the segments and the re-storable memory cells are in the $-specific embodiment, and at least the intervening memory cells operate as a single-programmable memory cell or a rewritable memory cell. 18 illustrates a specific embodiment in which two singularly stylized sections 230, 250 are interleaved with two rewritable sections 24, 260 (ie, two adjacent sets of memory cells are not available) Single stylized or rewritable. As mentioned above, any data can be stored in any section. For example, game content data can be stored in a single pass 121888.doc -40- 200811865 In the segments 230, 250, the game state data may be stored in the rewritable sections 240, 260. It should be noted that although Figures 17 and 18 illustrate the orientation of the groups of memory cells in a horizontal manner, In a specific embodiment, one or more sets of memory cells can be oriented in a vertical manner. For example, instead of having formatted data in a horizontal column of memory cells (as shown in FIG. 17), the formatted data can be vertically Column memory unit. In this way, Redundant data will span many pages. Mixed-use horizontal orientation and vertical orientation information can also be used. For example, 'manufacturing data can be used for water and money, and formatted data can be oriented vertically. As shown in Figure 18, each page of information Included may be - or a plurality of flag bits 270 indicating whether the page is either single-programmable or rewritable. In Figure 18, the "1" flag indicates a single stylization, and, The "〇" flag indicates rewritable. Preferably, the flag is stored in a single-programmable memory unit (even if the memory unit is in a rewritable section). Moreover, the preferred method is to optimize the preset read conditions for the single-program & data (so the single-programmable flag bit stored in the single-programizable section can be successfully read. And trimming bits, manufacturing materials, etc.), and if the flag indicates rewritable data, modify their reading conditions. The advantage of using a flag bit is that it is actually impossible to use a single-programmed memory cell as a rewritable memory cell, and vice versa. The original, the source is interpreted by a write circuit on the chip. The write-once circuit on the wafer is programmed to use a flag bit to indicate that a memory unit can be single-programmed to prevent more than: writes to the memory unit. 121888.doc -41- 200811865 As an alternative to using the flag 'location' address space calculation and write control can be moved out of the chip, for example, to hardware/software in the host device. For example, if a memory device is used as the game E, the software in the host device can use a pre-designated address for storing game state data (the host device knows the address space, but the memory is not available). Know the address space). The alternative is 'can be stored in the game in the memory array. The wipes, the memory list m a single stylized part (for example, the #-body array - special address location (for example, address GGGG) Or information in the device controller in the memory device that is separate from the memory array to inform the host device of the address space for the game state data. / In the specific embodiment of FIGS. 17 and 18, the memory array is a memory cell unit in which the memory unit can be programmed twice and the other is a rewritable memory unit. "Mixing use". In other specific examples, the "mixed use" memory array contains other "hybrid" features, as described above, in lieu of or in addition to a single stylized/i-writable feature. , can use _ flag private bit or its mechanism to determine - the nature of a given set of memory cells ^. For example, the first set of memory cells in the same memory array can be more than the second set of memory cells Reliable and wider temperature and voltage range. As another real <column, using the preferred memory cell structure described above' - a given memory cell can be: (i) programmed with forward bias (for example, (d) one can be a single stylized memory unit or rewritable memory early element); or (ii) be stylized with a reverse bias (eg, as the same rewritable memory unit, but different Two-state single-programmed memory single 12 1888.doc -42- 200811865 yuan). In other words, the single-programmed memory unit can only accept forward bias programming, while the rewritable memory unit can accept forward bias programming and reverse bias programming. Both are shown in the circuit diagrams of Figures 19 and 20. For a detailed description of the forward bias write, see U.S. Patent No. 6,618,295; and a detailed description of the reverse bias write, See U.S. Patent Application Serial No. 11/461,339 (Attorney Docket No. 023-0048) entitled "Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders" and U.S. Patent Application Serial No. 11/ 461,364 (Attorney Profile Number No. 023-0054) entitled "Method for Using a Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders", all of which have been assigned to the transfer of the present invention This is hereby incorporated by reference. Accordingly, the "hybrid" memory array can include: a first set of memory cells that are programmed with forward bias; and a second set of memory cells that are reverse biased. Stylized. A memory cell that is programmed with a reverse bias can also be erased with a forward bias. In an erase operation (compared to a write operation), individual data bits in a page are not variables because all bits are erased during the erase operation. For a detailed description of the erase operation, see U.S. Patent Application Serial No. 11/461,339 (Attorney Docket No. 023-0048) entitled ''Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders" And U.S. Patent Application Serial No. 11/461,364 (Attorney Docket No. 023-0054) entitled "Method for Using a Passive Element Memory Array 121888.doc •43- 200811865
Incorporating Reversible Polarity Word Line and Bit Line Decoders",彼等案均已讓渡給本發明受讓人並且特此以 引用方式併入本文。 到目前為止之論述係關於使用記憶體單元作為可單次程 式化記憶體單元或作為可重寫記憶體單元,並且記憶體陣 列具有可單次程式化記憶體單元與可重寫記憶體單元之混 合。但是,如上文所述,另一多用途態樣之較佳記憶體單 元在於,該記憶體單元(無論係可單次程式化記憶體單元 或係可重寫記憶體單元)可儲存兩種資料狀態或兩種以上 資料狀態。可對於每一可能的資料狀態來測試多重測試記 憶體單元,以判定在一記憶體陣列可儲存多少資料狀態。 舉例而言,可在V、P、8與化資料狀態下來對測試記憶體 單元進行測試,以推斷記憶體單元是否合意地運作為四狀 恶式可單次程式化記憶體單元。如果記憶體陣列未通過測 4 ’則可將其用作為兩狀態式記憶體陣列,在該記憶體陣 列中儲存有適當的旗標。 混合用途記憶體陣列可連同使用X種電阻率狀態的一組 記憶體單元一起使用來表示X種資料狀態,以及連同使用 γ種電阻率狀態的一第二組記憶體單元一起使用來表示Y 種資料狀態,其中X矣Y。在此方式中,記憶體陣列中的一 記憶體單元中儲存的資料狀態數量可在各組記憶體單元之 間變化。可組合上文所述之各種多用途與混合多用途。舉 例而言,記憶體陣列中的第一組記憶體單元與第二組記憶 體單元可使用不同數量之資料狀態,並且兩者皆係可單次 121888.doc -44- 200811865 :式:二兩者皆可重寫,或係可單次程式化舆可重寫之混 :體單:2,記憶體陣列的多個部分可係可單次程式化記 fe、體早7G與可會宜4 k 存X插-心早元之任何組合,其中-部分儲 存X種貝料狀態(例如 種資料狀態⑽如,兩_ Λ _且另—部分儲存¥ 上賢料狀態)。舉例而言,記憶 體陣列可具有:_笛 “ w 、有 弟一組记憶體單元,其係可單次程式化 、、八有兩種以上資料狀態(例如,用於程式化資料);及Incorporating Reversible Polarity Word Line and Bit Line Decoders", each of which has been assigned to the assignee of the present application, is hereby incorporated by reference. The discussion so far has been on the use of memory cells as a single-programmable memory cell or as a rewritable memory cell, and the memory array has a single-programmable memory cell and a rewritable memory cell. mixing. However, as described above, another preferred embodiment of the memory unit is that the memory unit (whether a single-programmed memory unit or a rewritable memory unit) can store two types of data. Status or two or more data states. Multiple test memory cells can be tested for each possible data state to determine how much data state can be stored in a memory array. For example, the test memory cells can be tested in the V, P, and 8 data states to infer whether the memory cells are desirably functioning as a four-dimensional, one-shot programmable memory cell. If the memory array fails the measurement, it can be used as a two-state memory array in which the appropriate flags are stored. A hybrid memory array can be used in conjunction with a set of memory cells using X resistivity states to represent X data states, and used in conjunction with a second set of memory cells using gamma resistivity states to represent Y species. Data status, where X矣Y. In this manner, the number of data states stored in a memory cell in the memory array can vary between groups of memory cells. The various versatile and mixed versatility described above can be combined. For example, the first set of memory cells and the second set of memory cells in the memory array can use different numbers of data states, and both can be single time 121888.doc -44- 200811865: formula: two two Can be rewritten, or can be a single stylized 舆 rewritable mix: body single: 2, multiple parts of the memory array can be single-programmed fe, body early 7G and can be 4 k Save any combination of X-insert-heart early, where - part of the X-type bedding state (for example, the state of the data (10), such as two _ _ _ and another - part of the storage of the state of the material). For example, the memory array can have: _ flute "w, a set of memory cells, which can be single-programmed, and eight or more data states (for example, for stylized data); and
一第二組記憶體單元,其係可重寫並且具有兩種以上資料 狀恶(例如,用於作為高速暫存(scratchpad)記憶體)。可有 兩個以上部分。 如上文所述’可藉由測試來判定對於任何組記憶體單元 中使用夕少貝料狀態之選擇。舉例而言,如果因為讀取電 路無法辨別V、p與R狀態而使四狀態式可單次程式化記憶 體單元未通過測試。則包含彼等測試記憶體單元的記憶體 陣列部分可用作為兩狀態式可重寫部分。在此情況中,寫 電路可使用反覆式寫程式化(如上文所述)來驗證並且接著 再次重新程式化,以將R狀態,,推"向V狀態及將8狀態,,推,, 向P狀態。換言之,反覆式回饋機制”開放"介於R狀態與S 狀態之間的"空間”。 具有不同資料狀態之多用途記憶體陣列認定:事實上, 雖然每一記憶體單元具有儲存兩種以上資料狀態之潛力, 但是最具效率使用記憶體陣列中的記憶體單元發生於記憶 體陣列並非所有記憶體單元皆儲存兩種以上狀態時。舉例 而言,在一項較佳具體實施例中,一第一組記憶體單元係 121888.doc •45- 200811865 作為可單次程式化記憶體單元,並且一第二組記憶體單元 係作為可重寫記憶體單元。圖2U會示此項具體實施例。在 此具體實施例中,用於讀取四狀態式記憶體單元之最佳電 路組態設定被儲存於中兩狀態式記憶體單元。舉例而言, 如圖21所不,頁〇中的組態位元指示出用每記憶體單元兩 狀態式讀取電路操作相對於每記憶體單元四狀態式讀取電 路操作進行讀取的頁。該等組態位元亦判定每記憶體單元 φ ㊉狀態式頁中之可用位元的限制。當寫入頁。時,組態晶 片中用於兩狀態式資料與四狀態式資料的部分。對於可單 t程式化記憶體單元使用方式,頁〇可被寫入數次以加入 指示出用於兩狀態式資料之額外部分的額外組態位元,因 為組態位元皆設定至邏輯"i",所以指示出除頁0以外,所 有頁皆被讀取為四狀態式資料(即,預設組態係僅讀取頁0 為=狀態式資料)°原生可單次程式化記憶體單元狀態(V 狀恶)係邏輯"1"。組態位元之預設組態與解譯係藉由記憶 籲 冑晶片上的邏輯編碼予以進行。列數與頁數非必然相等, 但較佳係簡單的倍數(例如,四頁對一列)。 ^ 八匕組態係可行的。舉例而言,另一應用可具有 亦、作為每記憶體單元兩狀態式資料之第三部分,其係基於 指示出記憶體陣列之第三部分中的次於最佳記憶 體單70。在還有另一應用中,記憶體陣列具有在第-部分 中的可單次程式化記憶體單元以及兩種以上狀態式可重寫 記憶體單元(例如,使用R、S與R1狀態)。最佳電路組態較 佳係儲存於兩狀態式可單次程式化記憶體單元中。另外, 121888.doc -46 - 200811865 $憶體陣列:具有在第一部分中的兩狀態式可重寫記憶體 早兀以及在第二部分中的兩種以上狀態式可重寫記憶體單 元。 明再-人附圖,圖22繪示較佳具體實施例之記憶體陣列之 圖:’其中藉由每一實體頁上的旗標位元來指示出每記憶 體早疋兩狀態之部分及每記憶體單元四狀態之部分。旗標 位元較佳係每記憶體單元兩狀態式資料。偶數數量之頁相 Φ i聯於母列。經項取為’’ Γ,的用於奇數頁之旗標位元指 不出該頁不可用。不可用之頁亦被储存在記憶體晶片外的 ^制邏輯或軟體中,並且可藉由已知之冗餘/不良區塊機 制予以重新指派。選擇性地,可使用每列共用旗標位元, f中旗標相關聯於多重頁並且指示出用於該列之每記憶體 単^狀態數量以及若干頁之不可用。較佳方式為,使用每 歹J偶數數里之頁。對於若干相鄰列,對於不良區塊表使用 的區塊較佳被定義為列的二分之一。 | ® 23繪示較佳具體實施例之記憶體陣列之圖解,其中藉 由δ己憶體陣列中儲存的轉譯表來指示出每記憶體單元兩狀 態之部分及每記憶體單元四狀態之部分。該轉譯表具有記 憶體陣列中介於邏輯頁位址與實體列之間的對應。該轉譯 表亦包含用於在一實體列處儲存之位元數量的旗標位元°。 選擇性地,該轉譯表亦具有指示出某些頁係可單次程式化 或係可重寫資料的旗標。旗標位元較佳對於用於指示之資 料類型的最佳設定來控制讀取與寫入電路。 圖24繪示較佳具體實施例之記憶體陣列之圖解,其中藉 121888.doc -47- 200811865 由每一實體頁上的旗標位元來指示出每記憶體單元兩狀雜 可單次程式化部分、每記憶體單元兩狀態可重寫部分及每 記憶體單元四狀態可單次程式化部分。在此具體實施例 中’旗標位元被儲存為每記憶體單元兩狀態式資料。偶數 數量之頁相關聯於每一列。晶片外控制器掃描旗標資訊以 建立不良區塊表。用於一些頁之旗標位元指示出該頁不可 用。旗標位元亦較佳控制晶片上讀取與寫入電路,以提供 _ 用於母§己憶體單元兩狀態式操作及可重寫相對於可單·欠程 式化操作的最佳組態。在此情況中,圖24中指示出的旗標 位元至少包含一用以指示出每記憶體單元狀態數量的位元 及一用以指示出可單次程式化或可重寫的位元在一些具體 實施例中,可使用兩個以上位元。 圖25繪使用晶片旗標與晶片外不良區塊機制之較佳具體 實施例的流程圖。提供一邏輯頁位址(步驟3〇〇)。記憶體裝 置之控制器晶片中的一不良區塊表與轉譯邏輯判定一相關 | 聯於該邏輯頁位址的初步實體位址(步驟31〇)。接著,用每 記憶體單元兩狀態之預設設定來讀取位於該初步實體位址 的旗標位元(步驟320)。如果該頁係不可用,則使用一回饋 機制來更新用於不可用之頁的寫狀態(步驟33〇),其致使該 控制器晶片更新該不良區塊表。否則,讀取或寫電路被設 定至兩狀態模式或兩種以上狀態模式(步驟34())。接著讀取 或寫入頁資料(步驟350)。 雖然可運用彼等具體實施例來使用任何適合記憶體單 元彳疋目月j幸乂 t方式為,記憶體單元包括被動式記憶體 121888.doc -48- 200811865A second set of memory cells that are rewritable and have more than two types of data (e.g., for use as a scratchpad memory). There can be more than two parts. As described above, the selection of the state of use of the smugglers in any group of memory cells can be determined by testing. For example, a four-state single-programmable memory cell fails the test if the V, p, and R states cannot be discerned because of the read circuit. The memory array portion containing their test memory cells can then be used as a two-state rewritable portion. In this case, the write circuit can be verified using a repetitive write stylization (as described above) and then re-programmed again to push the R state, push " to the V state and to the 8 state, push,, To the P state. In other words, the repeated feedback mechanism is "open" "space" between the R state and the S state. Multi-purpose memory arrays with different data states: In fact, although each memory cell has the potential to store more than two data states, the most efficient use of memory cells in memory arrays occurs in memory arrays. When all memory units are stored in more than two states. For example, in a preferred embodiment, a first set of memory cells is 121888.doc •45-200811865 as a single-programmed memory cell, and a second set of memory cells is available. Overwrite the memory unit. Figure 2U shows this particular embodiment. In this embodiment, the optimal circuit configuration settings for reading the four state memory cells are stored in the two state memory cells. For example, as shown in FIG. 21, the configuration bit in the page indicates a page that is read with respect to each memory cell four-state read circuit operation with each memory cell two-state read circuit operation. . These configuration bits also determine the limits of the available bits in each memory cell φ ten-state page. When writing to the page. When configuring the part of the wafer for the two-state data and the four-state data. For a single-table memory cell usage, the page can be written several times to include additional configuration bits indicating the extra portion of the two-state data because the configuration bits are set to logic " ;i", so that all pages except page 0 are read as four-state data (ie, the default configuration reads only page 0 = state data). Native one-time stylized memory The body unit state (V-like evil) is the logic "1". The default configuration and interpretation of the configuration bits is performed by memory-based logic coding on the wafer. The number of columns is not necessarily equal to the number of pages, but is preferably a simple multiple (for example, four pages to one column). ^ Gossip configuration is feasible. For example, another application may have, as a third portion of the two-state data per memory unit, based on indicating the next best memory bank 70 in the third portion of the memory array. In still another application, the memory array has a single-programmable memory unit in the first portion and two or more state-of-the-art rewritable memory units (e.g., using R, S, and R1 states). The optimal circuit configuration is better stored in a two-state, single-programmable memory unit. In addition, 121888.doc -46 - 200811865 $Memory array: has two state rewritable memory in the first part and two or more stateful rewritable memory cells in the second part. FIG. 22 is a diagram of a memory array of a preferred embodiment: 'where the flag bit on each physical page indicates the portion of each memory that is early and second. Part of the four states of each memory unit. The flag bit is preferably two state data per memory unit. An even number of pages Φ i are associated with the parent column. If the item is taken as '’ Γ, the flag bit for the odd page indicates that the page is not available. Unusable pages are also stored in the logic or software outside the memory chip and can be reassigned by known redundant/bad block mechanisms. Alternatively, each column of shared flag bits can be used, the flags in f are associated with multiple pages and indicate the number of states per memory and the unavailability of several pages. Preferably, the page in the number of even pairs of J is used. For several adjacent columns, the block used for the bad block table is preferably defined as one-half of the column. ® 23 shows an illustration of a memory array of a preferred embodiment in which a portion of each state of each memory cell and a portion of each state of the memory cell are indicated by a translation table stored in the delta recall array. . The translation table has a correspondence between logical page addresses and entity columns in the memory array. The translation table also contains flag bits ° for the number of bits stored in a physical column. Optionally, the translation table also has a flag indicating that certain pages are single-programmable or rewritable. The flag bit preferably controls the read and write circuits for the optimal setting of the type of information used for the indication. FIG. 24 is a diagram showing a memory array of a preferred embodiment, wherein a symbol of each memory cell is indicated by a flag bit on each physical page by 121888.doc -47-200811865 The transcribed portion, the two-state rewritable portion of each memory unit, and the four-state single-programmed portion of each memory unit. In this embodiment the 'flag bit is stored as two state data per memory unit. An even number of pages are associated with each column. The off-chip controller scans the flag information to create a bad block table. A flag bit for some pages indicates that the page is not available. The flag bit also preferably controls the read and write circuits on the wafer to provide _ for the two-state operation of the parent suffix unit and the optimizable configuration of the rewritable operation with respect to the single under-programming operation . In this case, the flag bit indicated in FIG. 24 includes at least one bit for indicating the number of states per memory unit and a bit for indicating that it can be single-programmed or rewritable. In some embodiments, more than two bits can be used. Figure 25 depicts a flow diagram of a preferred embodiment using a wafer flag and an off-chip bad block mechanism. Provide a logical page address (step 3〇〇). A bad block table in the controller chip of the memory device is associated with the translation logic to determine a preliminary physical address associated with the logical page address (step 31A). Next, the flag bit located at the preliminary physical address is read with a preset of two states per memory unit (step 320). If the page is not available, a feedback mechanism is used to update the write status for the unavailable page (step 33A), which causes the controller wafer to update the bad block table. Otherwise, the read or write circuit is set to two state modes or two or more state modes (step 34()). The page material is then read or written (step 350). Although any suitable embodiment can be used to use any suitable memory unit, the memory unit includes passive memory. 121888.doc -48- 200811865
疋件(其包含可切換式電阻材料,較佳係半導體),具體而 言,複晶二極體。其它可切換式電阻材料包括(但不限於) 二元(―)金屬氧化物、相變材料(如美國專利案第 5,751’。012號及美國專利案第4,646,266號所示)及有機材料 電I5器+例而s,包括若干有機材料層之記憶體單元, 其包括具有似二極體特性傳導之至少一層及施加電場來變 更傳導率的至少-有機材料。美國專利案第M55,i8〇號描 述有機被動元件陣列。另一可變電阻材料係摻雜有V、 Co Ni Pd、Fe或Μη之非晶系石夕,舉例而言,如美國專 利案第5,541,869號中更充分描述所述。美國專利案第 6,473,332號中講授另一類別材料。彼等材料係鈣鈦礦材 料,諸如 PruCaxMnOs (PCM0)、Lai.xCaxMn〇3 (LCMO)、LaSrMn03 (LSMO)或GdBaC〇x〇Y (GBCO)。此可 變電阻材料之另一選項係碳聚合物膜,其包含(舉例而言) 混合於塑料聚合物中之碳黑微粒或石墨,如美國專利案第 6,072,716號之講授。美國專利申請案第〇9/943,19〇號中及 美國專利申請案第09/941,544號中講授另一可切換式電阻 材料。此材料係經掺雜分子式ΑχΒ γ,之硫族玻璃,其中a包 含週期表之下列至少一元素:第IIIA族(B、Al、Ga、In、 Ti)、第 IVA族(C、Si、Ge、Sn、Pb)、第 VA族(N、P、 As、Sb、Bi)或第 VIIA族(F、Cl、Br、I、At);其中 B係選 自S、Se與Te及其混合物。摻雜物係選自貴金屬(noble metal)及過渡金屬,包括 Ag、Au、Pt、Cu、Cd、Ir、Ru、A component (which includes a switchable resistive material, preferably a semiconductor), specifically a polycrystalline diode. Other switchable resistive materials include, but are not limited to, binary (-) metal oxides, phase change materials (as shown in U.S. Patent No. 5,751 '. 012 and U.S. Patent No. 4,646,266) and organic material I5. And a memory cell comprising a plurality of organic material layers comprising at least one layer having conductivity-like conductivity and at least an organic material applying an electric field to change conductivity. U.S. Patent No. M55, i8 nicknames an array of organic passive components. The other varistor material is doped with V, Co Ni Pd, Fe or Mn, as described more fully in U.S. Patent No. 5,541,869. Another class of materials is taught in U.S. Patent No. 6,473,332. These materials are perovskite materials such as PruCaxMnOs (PCM0), Lai.xCaxMn〇3 (LCMO), LaSrMn03 (LSMO) or GdBaC〇x〇Y (GBCO). Another option for this variable resistance material is a carbon polymer film comprising, for example, carbon black particles or graphite mixed in a plastic polymer, as taught in U.S. Patent No. 6,072,716. Another switchable resistive material is taught in U.S. Patent Application Serial No. 9/943, the entire disclosure of which is incorporated herein by reference. This material is a chalcogenide glass of the doped molecular formula ΑχΒ γ, where a contains at least one of the following elements of the periodic table: Group IIIA (B, Al, Ga, In, Ti), Group IVA (C, Si, Ge) , Sn, Pb), Group VA (N, P, As, Sb, Bi) or Group VIIA (F, Cl, Br, I, At); wherein the B is selected from the group consisting of S, Se and Te, and mixtures thereof. The dopant is selected from the group consisting of noble metals and transition metals, including Ag, Au, Pt, Cu, Cd, Ir, Ru,
Co、Cr、Mn或Ni。此硫族玻璃(非晶系硫族,而非結晶狀 121888.doc -49- 200811865 :)#又仫係形成於相鄰於移動金屬離子儲藏器之記 兀中。可田甘# aa干Co, Cr, Mn or Ni. This chalcogenide glass (amorphous chalcogenide, not crystalline) is formed in a column adjacent to a moving metal ion reservoir. Ketian Gan # aa
一用某八匕固體電解質材料來取代硫族玻璃。 在:項較佳具體實施例中,元件包括串聯於半導體材料 之反:絲。在另―項較佳具體實施例中,記憶體元件包括 反熔、糸一70金屬氧化物及複晶矽二極體隔離裝置。另 記憶體單元可係二維記憶體陣列之部件,但是較 佺方式為’記憶體單元係單片三維記憶體陣列之部件,其 中記憶體單it經排列於複數層記憶體層級中,每_記憶體 層級經形成在-單_基板上方並且無任何中介基板。 目蝻較佳方式為,記憶體元件係非揮發性。但是,在一 項替代具體實施例中,在記憶體元件運作為可重寫記憶體 單元時使用的資料狀態中,記憶體元件可係揮發性。舉例 而言,記憶體元件可允許V狀態與P狀態成為永久性,但是 可允許R狀態與S狀態緩慢衰落。運用此_記憶體元件,R 狀態與S狀態將隨時間重新刷新。 前文詳細說明僅描述本發明可採用之許多形式中的少數 形式。基於此原因,詳細說明係意欲藉由闡釋說明,而不 是限制本發明。僅下列請求項(包括所有同等項)係旨在定 義本發明的範_。 【圖式簡單說明】 圖1繪示在記憶體陣列中介於記憶體單元之間的電隔離 所需的電路圖。 圖2繪示根據本發明較佳具體實施例形成之多狀態或可 重寫記憶體單元之剖視圖。 121888.doc -50- 200811865 圖3繪示包括圖2所示之記憶體單元的記憶體層級之一部 分的剖視圖。 圖4緣示本發明之記憶體單元的讀取電流隨著跨二極體 之逆向偏壓電壓增大而改變的圖表。 • 圖5繪示記憶體單元自V狀態變換至P狀態、自p狀態變 換至R狀態及自R狀態變換至S狀態的機率標緣圖。 - 圖6繪示記憶體單元自V狀態變換至P狀態、自p狀態變 _ 換至S狀態及自S狀態變換至R狀態的機率標繪圖。 圖7繪示記憶體單元自V狀態變換至R狀態、自r狀態變 換至S狀態及自S狀態變換至P狀態的機率標繪圖。 圖8繪示可在本發明具體實施例中傈用之垂直定向 二極體的剖視圖。 圖9繪示記憶體單元自ν狀態變換至?狀態及自ρ狀態變 換至Μ狀態的機率標繪圖。 圖10繪示根據本發明較佳具體實施例形成之多狀態或可 馨 重寫記憶體單元之剖視圖。 圖11繪示記憶體單元自V狀態變換至ρ狀態、自ρ狀態變 換至R狀態及自R狀態變換至S狀態、接著可重複於S狀態 與R狀態之間的機率標繪圖。 * 圖12繪示以正向偏壓加偏壓於S記憶體單元之加偏壓方 案的電路圖。 圖13繪示以逆向偏壓加偏壓於S記憶體單元之加偏壓方 案的電路圖。 圖14繪示反覆性讀取-驗證-寫入循環以使記憶體單元移 12I888.doc -51- 200811865 動進入資料狀態。 圖15a至15C繪示根據本發明具體實施例形成之記憶體層 級形成中階段的剖面圖。 圖16繪示可在本發明替代具體實施例中使用之二極體與 電阻式切換元件的剖面圖。 圖m會示較佳具體實施例之混合用途記憶體陣列之圖 ^其中組記憶體單元運作為可單次程式化記憶體 早70 ’及-弟二組記憶體單元運作為可重寫記憶體單元。 圖=會:較佳具體實施例之混合用途記憶體陣列之圖 父錯多組可單次程式化記憶體單元與可重寫記憶 圖19、、會不較佳具體實施例之電路一 偏壓予以程式化之-組記憶體單元。”展不用正向 圖2〇繪示較佳具體實施狀電路之輯,1 偏壓予以程式化之一組記憶體單元。 ’、圯向 _繪示較佳具體實施例之記憶輯列之圖解, 4體陣列之-第_部㈣存每記㈣單 離 狀態。 #部㈣存母記賴單元四種資料 圖22緣讀佳具體實施狀記憶體陣狀圖解,其 由母只體頁上的旗標位元來指示出每記憶體單元 之部分及每記憶體單元四狀態之部分。 心 圖2 3緣示較佳具體给 體只施例之記憶體陣列之圖解,复 由記憶體陣列中儲存的轉譯表來指示出每記憶體單 121888,doc -52- 200811865 態之部分及每記憶體單元四狀態之部分。 圖24繪示較佳具體實施例之記憶體陣列之圖解,其中藉 由母一實體頁上的旗標位元來指示出每記憶體單元兩狀熊 可單次程式化部分、每記憶體單元兩狀態可重寫部分及每 記憶體單元四狀態可單次程式化部分。 圖25繪使用晶片旗標與晶片外不良區塊機制之較佳具體 實施例的流程圖。One uses a certain eight-turn solid electrolyte material to replace the chalcogenide glass. In a preferred embodiment of the invention, the component comprises a reverse: wire in series with the semiconductor material. In a further preferred embodiment, the memory component comprises a reverse fused, 糸70 metal oxide and a polycrystalline germanium diode isolation device. The memory unit can be a component of the two-dimensional memory array, but the more common method is the 'memory unit is a component of a single-chip three-dimensional memory array, wherein the memory unit is arranged in a plurality of layers of memory, each _ The memory level is formed over the - single substrate and without any interposer. Preferably, the memory component is non-volatile. However, in an alternate embodiment, the memory component can be volatile in the state of the data used when the memory component operates as a rewritable memory cell. For example, a memory element may allow the V state and the P state to be permanent, but may allow the R state and the S state to slowly fade. With this _memory component, the R state and the S state will be refreshed over time. The foregoing detailed description describes only a few of the many forms in which the invention may be employed. For the sake of this reason, the detailed description is intended to be illustrative, and not to limit the invention. Only the following claims (including all equivalents) are intended to define the scope of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a circuit diagram showing the electrical isolation between memory cells in a memory array. 2 is a cross-sectional view of a multi-state or rewritable memory cell formed in accordance with a preferred embodiment of the present invention. 121888.doc -50- 200811865 FIG. 3 is a cross-sectional view showing a portion of a memory hierarchy including the memory cell shown in FIG. 2. Fig. 4 is a graph showing changes in the read current of the memory cell of the present invention as the reverse bias voltage across the diode increases. • Figure 5 illustrates the probability edge map of the memory cell transitioning from the V state to the P state, from the p state to the R state, and from the R state to the S state. - Figure 6 illustrates the probability plot of the memory unit transitioning from the V state to the P state, from the p state to the S state, and from the S state to the R state. Figure 7 is a graph showing the probability of a memory cell transitioning from a V state to an R state, from a r state to an S state, and from a S state to a P state. Figure 8 is a cross-sectional view of a vertically oriented diode that can be used in a particular embodiment of the invention. Figure 9 shows the memory cell changing from ν state to ? The state and the probability plot from the ρ state to the Μ state. Figure 10 is a cross-sectional view of a multi-state or rewritable memory cell formed in accordance with a preferred embodiment of the present invention. Figure 11 is a graph showing the probability of the memory cell transitioning from the V state to the ρ state, from the ρ state to the R state, and from the R state to the S state, and then repeatable between the S state and the R state. * Figure 12 is a circuit diagram showing the biasing scheme for biasing the S memory cell with a forward bias. Figure 13 is a circuit diagram showing the biasing scheme for biasing the S memory cell with a reverse bias. Figure 14 illustrates a repetitive read-verify-write cycle to move the memory cells into the data state. 15a through 15C are cross-sectional views showing stages in the formation of a memory level formed in accordance with an embodiment of the present invention. Figure 16 is a cross-sectional view of a diode and a resistive switching element that can be used in an alternate embodiment of the present invention. Figure m shows a diagram of a mixed-use memory array of a preferred embodiment. The memory unit operates as a single-programmed memory as early as 70' and - the two-group memory unit operates as a rewritable memory. unit. Figure = will be: a preferred embodiment of the mixed-use memory array diagram parental error group can be a single stylized memory unit and rewritable memory map 19, will be a preferred embodiment of the circuit bias Stylized-group memory unit. The display of a preferred embodiment of the circuit is not shown in Figure 2, and a bias voltage is used to program a set of memory cells. ', 圯向_ Illustrates the memory of the preferred embodiment. , 4 body array - the first part (four) save each record (four) single off state. #部(四)存母记赖 unit four data Figure 22 edge read good implementation of the memory array diagram, which is from the parent body page The flag bit indicates the portion of each memory cell and the four states of each memory cell. The heart of Figure 2 shows a better specific donor mode of the memory array of the embodiment, and the memory array The stored translation table indicates the portion of each memory bank 121888, doc-52-200811865 and the four states of each memory cell. Figure 24 is a diagram illustrating a memory array of a preferred embodiment, wherein The flag bit on the parent-physical page indicates that the two-character bear-only stylized portion of each memory unit, the two-state rewritable portion of each memory unit, and the four-state per memory unit can be single-programmed Part 25. Figure 25 depicts the use of wafer flags and poor wafers. Flowchart block preferred specific embodiment of the mechanism.
【主要元件符號說明】 2 複晶半導體二極體 4 底部重摻雜η型區(圖2) 4 底部重摻雜Ρ型區(圖8) 6 本質區 8 頂部重摻雜區(圖2) 8 頂部重摻雜η型區(圖8) 12 底部導體 14 介電破裂反熔絲 16 頂部導體 100 基板 102 絕緣層 104 黏者層 106 傳導層 108 介電材料 109 平垣表面 110 阻障層 121888.doc -53. 200811865 111 二極體 112 底部重摻雜區 114 本質層 116 頂部重摻雜P型區 117 可切換式記憶體元件 118 介電破裂反熔絲層 120 黏著層 122 傳導層 200 導體(第一導體;導體執;底部導體) (圖 15a 至 15c) 200 記憶體陣列(圖17) 210 第一組記憶體單元 220 第二組記憶體單元 230, 250 可單次程式化區段 240, 260 可重寫區段 270 旗標位元 300 柱 400 導體(導體軌;頂部導體) A,A0, A1 字線 B,BO, B1 位元線 F,H 半所擇記憶體單元 U 非所擇記憶體單元 M,P,R,S,V 記憶體單元之資料狀態 Ul,U2, U3 非所擇記憶體單元 121888.doc -54 -[Main component symbol description] 2 Polycrystalline semiconductor diode 4 Bottom heavily doped n-type region (Fig. 2) 4 Bottom heavily doped Ρ-type region (Fig. 8) 6 Essential region 8 Top heavily doped region (Fig. 2) 8 Top heavily doped n-type region (Fig. 8) 12 Bottom conductor 14 Dielectric rupture antifuse 16 Top conductor 100 Substrate 102 Insulation layer 104 Adhesive layer 106 Conductive layer 108 Dielectric material 109 Flat surface 110 Barrier layer 121888. Doc -53. 200811865 111 Diode 112 Bottom heavily doped region 114 Essential layer 116 Top heavily doped P-type region 117 Switchable memory device 118 Dielectric ruptured anti-fuse layer 120 Adhesive layer 122 Conductive layer 200 Conductor ( First conductor; conductor; bottom conductor) (Figs. 15a to 15c) 200 memory array (Fig. 17) 210 first group of memory units 220 second group of memory units 230, 250 may be programmed in a single block 240 260 rewritable section 270 flag bit 300 column 400 conductor (conductor rail; top conductor) A, A0, A1 word line B, BO, B1 bit line F, H semi-selected memory unit U not selected Memory unit M, P, R, S, V memory Ul unit of state information, U2, U3 non-selection of the memory cell 121888.doc -54 -
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| US11/496,874 US20080023790A1 (en) | 2006-07-31 | 2006-07-31 | Mixed-use memory array |
| US11/496,983 US7450414B2 (en) | 2006-07-31 | 2006-07-31 | Method for using a mixed-use memory array |
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| EP0788113B1 (en) * | 1996-01-31 | 2005-08-24 | STMicroelectronics S.r.l. | Multilevel memory circuits and corresponding reading and writing methods |
| US6034882A (en) * | 1998-11-16 | 2000-03-07 | Matrix Semiconductor, Inc. | Vertically stacked field programmable nonvolatile memory and method of fabrication |
| US7003619B1 (en) * | 2001-04-09 | 2006-02-21 | Matrix Semiconductor, Inc. | Memory device and method for storing and reading a file system structure in a write-once memory array |
| US6483734B1 (en) * | 2001-11-26 | 2002-11-19 | Hewlett Packard Company | Memory device having memory cells capable of four states |
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| EP1450261A1 (en) * | 2003-02-18 | 2004-08-25 | STMicroelectronics S.r.l. | Semiconductor memory with access protection scheme |
| WO2005066969A1 (en) * | 2003-12-26 | 2005-07-21 | Matsushita Electric Industrial Co., Ltd. | Memory device, memory circuit and semiconductor integrated circuit having variable resistance |
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