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TW200745250A - Hydrogenated block copolymer, resin composition containing such hydrogenated block copolymer, their crosslinked product and their crosslinked foam - Google Patents

Hydrogenated block copolymer, resin composition containing such hydrogenated block copolymer, their crosslinked product and their crosslinked foam

Info

Publication number
TW200745250A
TW200745250A TW096105327A TW96105327A TW200745250A TW 200745250 A TW200745250 A TW 200745250A TW 096105327 A TW096105327 A TW 096105327A TW 96105327 A TW96105327 A TW 96105327A TW 200745250 A TW200745250 A TW 200745250A
Authority
TW
Taiwan
Prior art keywords
block copolymer
hydrogenated block
weight
crosslinked
resin composition
Prior art date
Application number
TW096105327A
Other languages
Chinese (zh)
Other versions
TWI343398B (en
Inventor
Sigeru Sasaki
Katsunori Nitta
Yoshifumi Araki
Jung-Sik Yoon
Gi-Yong Um
Chong Sun Yoo
Original Assignee
Asahi Kasei Chemicals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kasei Chemicals Corp filed Critical Asahi Kasei Chemicals Corp
Publication of TW200745250A publication Critical patent/TW200745250A/en
Application granted granted Critical
Publication of TWI343398B publication Critical patent/TWI343398B/zh

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0846Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
    • C08L23/0853Ethene vinyl acetate copolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04Plastics, rubber or vulcanised fibre
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B3/00Footwear characterised by the shape or the use
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/04Reduction, e.g. hydrogenation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0846Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
    • C08L23/0869Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Disclosed is a hydrogenated block copolymer for producing a foam which is excellent in tear strength, compression set resistance, low rebound resilience and wear resistance. Specifically disclosed is a hydrogenated block copolymer of a vinyl aromatic compound and a conjugated diene. This hydrogenated block copolymer is characterized in that: (a) the vinyl aromatic content is more than 35% by weight but not more than 90% by weight; (b) the amount of vinyl aromatic polymer block is not more than 40% by weight; (c) the weight average molecular weight is from 5104 to 100104; and (d) the hydrogenation degree of double bonds derived from the conjugated diene is less than 70%.
TW096105327A 2006-02-13 2007-02-13 Hydrogenated block copolymer, resin composition containing such hydrogenated block copolymer, their crosslinked product and their crosslinked foam TW200745250A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2006035776 2006-02-13

Publications (2)

Publication Number Publication Date
TW200745250A true TW200745250A (en) 2007-12-16
TWI343398B TWI343398B (en) 2011-06-11

Family

ID=38371403

Family Applications (1)

Application Number Title Priority Date Filing Date
TW096105327A TW200745250A (en) 2006-02-13 2007-02-13 Hydrogenated block copolymer, resin composition containing such hydrogenated block copolymer, their crosslinked product and their crosslinked foam

Country Status (7)

Country Link
US (1) US20090312449A1 (en)
EP (1) EP1985641A4 (en)
JP (1) JP5502319B2 (en)
KR (1) KR101006613B1 (en)
CN (1) CN101384631B (en)
TW (1) TW200745250A (en)
WO (1) WO2007094216A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8415428B2 (en) 2008-02-08 2013-04-09 Asahi Kasei Chemicals Corporation Thermoplastic elastomer composition and method for producing the same
US11939456B2 (en) 2017-07-21 2024-03-26 Tsrc Corporation Composition for preparing a foam, foam, and shoe employing the same

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2682802T3 (en) * 2008-12-22 2018-09-21 Asahi Kasei Kabushiki Kaisha Crosslinkable and foamable composition, crosslinked foam and shoe midsole comprising them
WO2011040585A1 (en) * 2009-09-30 2011-04-07 株式会社クラレ Container stopper comprising foam-molded article
TWI443141B (en) * 2010-03-08 2014-07-01 Asahi Kasei Chemicals Corp A composition for a foam, a method for producing the same, and a foam
WO2012084914A1 (en) * 2010-12-23 2012-06-28 Basf Se Thermoplastic elastomer composition and method for the production thereof
KR101288538B1 (en) * 2011-04-15 2013-07-22 한국신발피혁연구원 foam composition for insole with excellent shape-recovery and method for manufacture of the same
CN103459431B (en) * 2011-05-27 2015-01-21 旭化成化学株式会社 Method for manufacturing hydrogenated conjugated diene copolymer
JP5626540B2 (en) * 2012-04-02 2014-11-19 オンキヨー株式会社 Speaker diaphragm and speaker using the same
CN102617970B (en) * 2012-04-26 2014-03-05 湖南汇中新材料有限公司 Composition of hydrogenated segmented copolymer elastomer-nylon 6
ES2606834T3 (en) * 2013-12-20 2017-03-28 Continental Reifen Deutschland Gmbh Mixture of rubber and car tires
KR101842818B1 (en) * 2014-01-23 2018-03-27 아사히 가세이 가부시키가이샤 Block copolymer and adhesive composition
CA2970915A1 (en) * 2014-12-18 2016-06-23 Henkel IP & Holding GmbH Foamable hot melt gasket sealants and use thereof
KR102041739B1 (en) * 2015-09-09 2019-11-06 아사히 가세이 가부시키가이샤 film
US10815352B2 (en) * 2016-05-18 2020-10-27 Kuraray Co., Ltd. Molded foam body, dam rubber, composite body of dam rubber and panel, and method for increasing sound transmission loss
IT201700009739A1 (en) * 2017-01-30 2018-07-30 Alberto Del Biondi S P A Footwear for magnetotherapy
EP3378877B1 (en) * 2017-02-28 2019-06-19 Evonik Oil Additives GmbH Hydrogenated polybutadienes useful as lubricant additives
ES2950414T3 (en) 2018-10-30 2023-10-09 China Petroleum & Chem Corp Conjugated diolefin/hydrogenated styrene copolymer, foaming material thereof and application thereof
JP7275857B2 (en) * 2019-05-24 2023-05-18 ブリヂストンスポーツ株式会社 Golf ball resin composition
JP7426853B2 (en) * 2020-02-28 2024-02-02 Eneos株式会社 thermoplastic elastomer composition
JP7580611B2 (en) * 2020-12-31 2024-11-11 株式会社ブリヂストン Functionalized hydrogenated interpolymers containing non-hydrogenated polymer segments
JP7573566B2 (en) * 2021-06-07 2024-10-25 李長榮化學工業股▲ふん▼有限公司 Crosslinkable and foamable compositions, foams obtained therefrom, compositions for foaming and uses thereof - Patents.com

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6079005A (en) * 1983-10-07 1985-05-04 Asahi Chem Ind Co Ltd Hydrogenation of living polymer
US4501857A (en) * 1983-01-20 1985-02-26 Asahi Kasei Kogyo Kabushiki Kaisha Method for hydrogenation of polymer
JPS60220147A (en) * 1984-04-18 1985-11-02 Asahi Chem Ind Co Ltd Olefin hydrogenation catalyst and method for hydrogenating polymers using the catalyst
JPH0615649B2 (en) * 1984-07-26 1994-03-02 旭化成工業株式会社 Hydrogenated block copolymer composition
EP0245505B2 (en) * 1985-10-11 1996-08-14 Asahi Kasei Kogyo Kabushiki Kaisha Terminal-modified block copolymer and composition containing said copolymer
ES2059446T3 (en) * 1987-07-16 1994-11-16 Asahi Chemical Ind COMPOSITION OF A SPECIFIC HYDROGENATED BLOCK COPOLYMER AND PROCESS FOR ITS MANUFACTURE.
JPH0699503B2 (en) * 1988-05-16 1994-12-07 旭化成工業株式会社 Polymer modification method
US5216074A (en) * 1989-07-17 1993-06-01 Japan Synthetic Rubber Co., Ltd. Thermoplastic elastomer composition
US5708092A (en) * 1994-05-13 1998-01-13 Fmc Corporation Functionalized chain extended initiators for anionic polymerization
US5527753A (en) * 1994-12-13 1996-06-18 Fmc Corporation Functionalized amine initiators for anionic polymerization
JP3598429B2 (en) * 1996-08-27 2004-12-08 株式会社クラレ Thermoplastic resin composition
US7256238B2 (en) * 2001-07-18 2007-08-14 Asahi Kasei Chemicals Corporation Modified block copolymer
JP4208176B2 (en) * 2001-08-10 2009-01-14 旭化成ケミカルズ株式会社 Functional group-containing block copolymer and composition thereof
JP3448582B2 (en) * 2001-11-12 2003-09-22 リケンテクノス株式会社 Thermoplastic elastomer composition, molded product thereof and composite molded product
JP2003286384A (en) * 2002-01-22 2003-10-10 Riken Technos Corp Thermoplastic elastomer composition and thermoplastic resin composition using the same
JP4060105B2 (en) * 2002-03-25 2008-03-12 旭化成ケミカルズ株式会社 Hydrogenated copolymer composition
JP4248185B2 (en) * 2002-03-25 2009-04-02 旭化成ケミカルズ株式会社 Dynamically cross-linked hydrogenated copolymer
AU2003231455A1 (en) * 2002-04-25 2003-11-10 Asahi Kasei Chemicals Corporation Block copolymer and composition thereof
JP4566505B2 (en) * 2002-08-29 2010-10-20 株式会社クラレ Thermoplastic polymer composition
JP2004091529A (en) * 2002-08-29 2004-03-25 Kuraray Co Ltd Thermoplastic elastomer composition
JP4067935B2 (en) * 2002-10-28 2008-03-26 株式会社クラレ Composition for thermoplastic foam and foam
WO2004090028A1 (en) * 2003-04-10 2004-10-21 Asahi Kasei Chemicals Corporation Polymer foam containing hydrogenated copolymer
JP4776155B2 (en) * 2003-10-21 2011-09-21 旭化成ケミカルズ株式会社 Hydrogenated copolymer
JP4473094B2 (en) * 2004-02-20 2010-06-02 リケンテクノス株式会社 Thermoplastic elastomer composition and thermoplastic resin composition using the same
JP4436194B2 (en) * 2004-06-18 2010-03-24 リケンテクノス株式会社 Thermoplastic elastomer composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8415428B2 (en) 2008-02-08 2013-04-09 Asahi Kasei Chemicals Corporation Thermoplastic elastomer composition and method for producing the same
US11939456B2 (en) 2017-07-21 2024-03-26 Tsrc Corporation Composition for preparing a foam, foam, and shoe employing the same

Also Published As

Publication number Publication date
EP1985641A4 (en) 2010-02-10
JPWO2007094216A1 (en) 2009-07-02
JP5502319B2 (en) 2014-05-28
HK1129409A1 (en) 2009-11-27
US20090312449A1 (en) 2009-12-17
CN101384631A (en) 2009-03-11
KR101006613B1 (en) 2011-01-07
TWI343398B (en) 2011-06-11
KR20080091807A (en) 2008-10-14
CN101384631B (en) 2011-03-09
WO2007094216A1 (en) 2007-08-23
EP1985641A1 (en) 2008-10-29

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