[go: up one dir, main page]

TW200734051A - Silica carriers - Google Patents

Silica carriers

Info

Publication number
TW200734051A
TW200734051A TW096101618A TW96101618A TW200734051A TW 200734051 A TW200734051 A TW 200734051A TW 096101618 A TW096101618 A TW 096101618A TW 96101618 A TW96101618 A TW 96101618A TW 200734051 A TW200734051 A TW 200734051A
Authority
TW
Taiwan
Prior art keywords
carriers
catalyst compositions
silica carriers
angstroms
preparing
Prior art date
Application number
TW096101618A
Other languages
Chinese (zh)
Inventor
Jean W Beeckman
Jason Wu
Theodore E Datz
Ralph Dehaas
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Publication of TW200734051A publication Critical patent/TW200734051A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Silicon Compounds (AREA)

Abstract

This invention relates to amorphous carriers having a silica content of at least about 85 wt%, a pore volume determined by mercury intrusion porosimetry of from 0.8 cm<SP>3</SP>/g to 1.0 cm<SP>3</SP>/g and a median pore size of about 180 Angstroms or greater, to methods of preparing said carriers, to catalyst compositions comprising said carriers and to catalytic conversion processes using catalyst compositions comprising said carriers.
TW096101618A 2006-01-17 2007-01-16 Silica carriers TW200734051A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US75943306P 2006-01-17 2006-01-17
US81308906P 2006-06-13 2006-06-13

Publications (1)

Publication Number Publication Date
TW200734051A true TW200734051A (en) 2007-09-16

Family

ID=38050922

Family Applications (1)

Application Number Title Priority Date Filing Date
TW096101618A TW200734051A (en) 2006-01-17 2007-01-16 Silica carriers

Country Status (4)

Country Link
AR (1) AR059062A1 (en)
RU (1) RU2418037C2 (en)
TW (1) TW200734051A (en)
WO (1) WO2007084440A1 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011096990A2 (en) 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation catalyst and process
WO2011096991A1 (en) 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation process
WO2012036819A1 (en) 2010-09-14 2012-03-22 Exxonmobil Chemical Patents Inc. Dehydrogenation process of cyclohexanone and phenol compositions
JP6014943B2 (en) 2010-12-17 2016-10-26 エクソンモービル ケミカル パテンツ インコーポレイテッド Dehydrogenation catalyst and method
CN103261126B (en) 2010-12-17 2015-04-01 埃克森美孚化学专利公司 Process of producing cyclohexylbenzene
CN103380077B (en) 2011-02-21 2016-08-31 埃克森美孚化学专利公司 hydrogen purification method
JP2014522382A (en) 2011-03-28 2014-09-04 エクソンモービル ケミカル パテンツ インコーポレイテッド Dehydrogenation method
BR112013033694B1 (en) * 2011-06-28 2020-04-22 Shell Int Research hydroprocessing catalyst composition containing a support material, an amine component and a polar additive that does not contain amine and a method for preparing that composition
CA2840387C (en) * 2011-06-28 2020-09-01 William Douglas Gillespie An ether amine additive impregnated composition useful in the catalytic hydroprocessing of hydrocarbons, a method of making such composition
SG11201502981QA (en) 2012-11-30 2015-05-28 Exxonmobil Chem Patents Inc Dehydrogenation process
CN105772105B (en) * 2014-12-16 2019-04-16 中国石油化工股份有限公司 A kind of modified hydrogen at-ing catalyst carrier and preparation method thereof
US20190176131A1 (en) * 2017-12-11 2019-06-13 Exxonmobil Chemical Patents Inc. Methods of Making Supported Mixed Metal Dehydrogenation Catalysts

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2093176A5 (en) * 1970-06-04 1972-01-28 Pechiney Saint Gobain
CA1177811A (en) * 1981-04-13 1984-11-13 Theo G. Spek Process for the preparation of silica particles; silica particles with a narrow pore diameter distribution, catalysts made therefrom and use of these catalysts
GB8701740D0 (en) * 1987-01-27 1987-03-04 Shell Int Research Catalytic conversion of hydrocarbon oils
NL8901893A (en) * 1989-07-21 1991-02-18 Veg Gasinstituut Nv Selective oxidn. catalyst - used to oxidise sulphur cpds. partic. hydrogen sulphide to elemental sulphur
US5143887A (en) * 1989-12-28 1992-09-01 Chevron Research And Technology Company Catalyst system for removal of calcium from a hydrocarbon feedstock
AU658131B2 (en) * 1990-11-07 1995-04-06 Davy Process Technology Limited Hydrodesulphurisation process
US5169822A (en) * 1991-06-17 1992-12-08 Texaco Inc. Catalysts for removal of impurities by the hydroprocessing of hydrocarbons
US6013598A (en) * 1996-02-02 2000-01-11 Exxon Research And Engineering Co. Selective hydrodesulfurization catalyst
RU2197323C1 (en) * 2001-05-23 2003-01-27 Открытое акционерное общество "Катализатор" Oil fraction hydrofining catalyst and method of preparation thereof

Also Published As

Publication number Publication date
RU2418037C2 (en) 2011-05-10
WO2007084440A1 (en) 2007-07-26
AR059062A1 (en) 2008-03-12
RU2008130966A (en) 2010-02-27

Similar Documents

Publication Publication Date Title
TW200734051A (en) Silica carriers
IN2012DN00739A (en)
WO2011082991A3 (en) Catalyst and method for hydrogenating aromates
MX356604B (en) Zeolite having copper and alkali earth metal supported thereon.
TW200708480A (en) Powdered lime composition, method of preparing same and use thereof
UA83923C2 (en) PROCESS FOR PREPARING HSICL3 BY CATALYTIC HYDRODEHALOGENATION OF SICL4 &lt;http://v3.espacenet.com/textdoc?DB=EPODOC&amp;IDX=KR20070008649&amp;F=0&gt;
WO2008071610A3 (en) Method for producing catalysts and their use for the gas phase oxidation of olefins
MX2008010481A (en) Compounds having 5-ht6 receptor affinity.
WO2011133876A3 (en) Oligonucleotides comprising acyclic and abasic nucleosides and analogs
WO2009097082A8 (en) Spray-dried transition metal zeolite and its use
GB0510143D0 (en) Novel compounds A1
WO2006136357A3 (en) Crystalline modifications to pyraclostrobin
WO2010036848A3 (en) Methods for promoting syngas-to-alcohol catalysts
PA8676401A1 (en) METHODS TO PURIFY TIGECICLINE
WO2007093258A3 (en) Porous magnesia and process for preparing the same
UA95083C2 (en) Azeotrope compositions comprising 1,2,3,3,3-pentafluoropropene and hydrogen fluoride and processes for the production and purification of 1,2,3,3,3-pentafluoropropene
MY145567A (en) Method for producing ethylene and propylene
MY151231A (en) Hydrogenation catalyst, particularly for carbon disulphide
WO2009006087A3 (en) Solid phosphoric acid with controlled macroporosity
WO2009146202A3 (en) Transketalized compositions, synthesis, and applications
UA95620C2 (en) Catalyst compositions and method of carbon oxychlorination using thereof
WO2009147313A3 (en) Use of sulfur-based supports for catalytic reforming
WO2010077026A2 (en) Cation exchange zeolite catalyst, and method for producing mono-iodo benzene through a transiodination reaction using same
WO2009143825A3 (en) Silicon containing halogenide, method for producing the same, and use of the same
UA74430C2 (en) PHENYLHETEROCYCLIC ETHERS DERIVATIVES AS serotonin re-uptake inhibitors