TW200712066A - Redox polymerization of vinyl aromatic monomers by photosynthesis - Google Patents
Redox polymerization of vinyl aromatic monomers by photosynthesisInfo
- Publication number
- TW200712066A TW200712066A TW095127196A TW95127196A TW200712066A TW 200712066 A TW200712066 A TW 200712066A TW 095127196 A TW095127196 A TW 095127196A TW 95127196 A TW95127196 A TW 95127196A TW 200712066 A TW200712066 A TW 200712066A
- Authority
- TW
- Taiwan
- Prior art keywords
- vinyl aromatic
- catalyst bed
- photoreductant
- reactor
- aromatic polymer
- Prior art date
Links
- 229920002554 vinyl polymer Polymers 0.000 title abstract 6
- 239000000178 monomer Substances 0.000 title abstract 3
- 230000029553 photosynthesis Effects 0.000 title 1
- 238000010672 photosynthesis Methods 0.000 title 1
- 238000007717 redox polymerization reaction Methods 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 5
- 229920000642 polymer Polymers 0.000 abstract 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 abstract 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 239000003638 chemical reducing agent Substances 0.000 abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 2
- -1 transition metal salt Chemical class 0.000 abstract 2
- BDSPTFQIOAEIII-UHFFFAOYSA-N 2,3,4a,6,7,8a-hexahydro-[1,4]dioxino[2,3-b][1,4]dioxine-2,3,6,7-tetrol Chemical compound O1C(O)C(O)OC2OC(O)C(O)OC21 BDSPTFQIOAEIII-UHFFFAOYSA-N 0.000 abstract 1
- VLUWLNIMIAFOSY-UHFFFAOYSA-N 2-methylbenzenesulfinic acid Chemical compound CC1=CC=CC=C1S(O)=O VLUWLNIMIAFOSY-UHFFFAOYSA-N 0.000 abstract 1
- KSFOVUSSGSKXFI-GAQDCDSVSA-N CC1=C/2NC(\C=C3/N=C(/C=C4\N\C(=C/C5=N/C(=C\2)/C(C=C)=C5C)C(C=C)=C4C)C(C)=C3CCC(O)=O)=C1CCC(O)=O Chemical compound CC1=C/2NC(\C=C3/N=C(/C=C4\N\C(=C/C5=N/C(=C\2)/C(C=C)=C5C)C(C=C)=C4C)C(C)=C3CCC(O)=O)=C1CCC(O)=O KSFOVUSSGSKXFI-GAQDCDSVSA-N 0.000 abstract 1
- 244000028419 Styrax benzoin Species 0.000 abstract 1
- 235000000126 Styrax benzoin Nutrition 0.000 abstract 1
- 235000008411 Sumatra benzointree Nutrition 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- 229960005070 ascorbic acid Drugs 0.000 abstract 1
- 235000010323 ascorbic acid Nutrition 0.000 abstract 1
- 239000011668 ascorbic acid Substances 0.000 abstract 1
- 229960002130 benzoin Drugs 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 abstract 1
- 230000005670 electromagnetic radiation Effects 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229940096419 glyoxal trimer Drugs 0.000 abstract 1
- 235000019382 gum benzoic Nutrition 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 150000002696 manganese Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 abstract 1
- 229960000907 methylthioninium chloride Drugs 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229950003776 protoporphyrin Drugs 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 229930187593 rose bengal Natural products 0.000 abstract 1
- AZJPTIGZZTZIDR-UHFFFAOYSA-L rose bengal Chemical compound [K+].[K+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 AZJPTIGZZTZIDR-UHFFFAOYSA-L 0.000 abstract 1
- 229940081623 rose bengal Drugs 0.000 abstract 1
- STRXNPAVPKGJQR-UHFFFAOYSA-N rose bengal A Natural products O1C(=O)C(C(=CC=C2Cl)Cl)=C2C21C1=CC(I)=C(O)C(I)=C1OC1=C(I)C(O)=C(I)C=C21 STRXNPAVPKGJQR-UHFFFAOYSA-N 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- YNHJECZULSZAQK-UHFFFAOYSA-N tetraphenylporphyrin Chemical compound C1=CC(C(=C2C=CC(N2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3N2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 YNHJECZULSZAQK-UHFFFAOYSA-N 0.000 abstract 1
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 abstract 1
- 229960004418 trolamine Drugs 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F112/02—Monomers containing only one unsaturated aliphatic radical
- C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F112/06—Hydrocarbons
- C08F112/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/198,542 US20070032562A1 (en) | 2005-08-04 | 2005-08-04 | Redox polymerization of vinyl aromatic monomers by photosynthesis |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200712066A true TW200712066A (en) | 2007-04-01 |
Family
ID=37718424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW095127196A TW200712066A (en) | 2005-08-04 | 2006-07-26 | Redox polymerization of vinyl aromatic monomers by photosynthesis |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20070032562A1 (zh) |
| EP (1) | EP1910424A4 (zh) |
| TW (1) | TW200712066A (zh) |
| WO (1) | WO2007018995A2 (zh) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020047042A1 (en) * | 2018-08-28 | 2020-03-05 | University Of Louisville Research Foundation | Organic polymers as photocatalysts |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3666743A (en) * | 1971-02-02 | 1972-05-30 | Hercules Inc | Polymerization of 1-olefins with tetrakis(bicycloheptyl)chromium compounds as catalysts |
| US4315998A (en) * | 1974-06-12 | 1982-02-16 | Research Corporation | Polymer-bound photosensitizing catalysts |
| US4202992A (en) * | 1978-03-03 | 1980-05-13 | Phillips Petroleum Company | Process for producing hydroperoxides |
| JPS55115484A (en) * | 1979-02-28 | 1980-09-05 | Asahi Chem Ind Co Ltd | Heterogeneous sensitizer for photosensitized oxidation |
| DE3152896A1 (de) * | 1981-06-09 | 1983-06-16 | Chiyoda Chem Eng Construct Co | Verfahren zum hydrocracken von kohlenwasserstoffen |
| DE3338393A1 (de) * | 1982-10-23 | 1984-04-26 | Arakawa Kagaku Kogyo K.K., Osaka | Verfahren zur herstellung eines hydrierten erdoelharzes |
| US4677137A (en) * | 1985-05-31 | 1987-06-30 | Minnesota Mining And Manufacturing Company | Supported photoinitiator |
| US5075347A (en) * | 1986-11-24 | 1991-12-24 | The Dow Chemical Company | Method for the preparation of hydroperoxide derivatives of rubbery polymers |
| US4828683A (en) * | 1987-02-06 | 1989-05-09 | Phillips Petroleum Company | Hydrofining employing a support material for fixed beds |
| US4849076A (en) * | 1987-10-13 | 1989-07-18 | Neckers Douglas C | Continuous oxidation method |
| US4857587A (en) * | 1987-12-24 | 1989-08-15 | Fina Technology, Inc. | Continuous process including recycle stream treatment for the production of high impact polystyrene |
| US5075346A (en) * | 1990-12-03 | 1991-12-24 | Arco Chemical Technology, Inc. | Tertiary ethers as blowing agents for foam polymer systems |
| FR2686607B1 (fr) * | 1992-01-24 | 1995-03-17 | Celliose Lobo Entreprise | Systeme photosensible sous irradiation visible et ultra-violette pour compositions filmogenes pigmentees photoreticulables. |
| US5683589A (en) * | 1995-03-13 | 1997-11-04 | University Of Western Ontario | Photocatalytic reactor |
| JP3723312B2 (ja) * | 1997-02-25 | 2005-12-07 | 富士写真フイルム株式会社 | 光重合性組成物 |
| DE10009060A1 (de) * | 2000-02-25 | 2001-09-06 | Dlr Ev | Solarer Photoreaktor |
| US6770716B1 (en) * | 2003-03-04 | 2004-08-03 | Fina Technology, Inc. | Use of accelerators in free-radical polymerizations of styrene |
| US7250452B2 (en) * | 2003-09-26 | 2007-07-31 | 3M Innovative Properties Company | Dental compositions and methods with arylsulfinate salts |
| US7041733B2 (en) * | 2003-10-23 | 2006-05-09 | Fina Technology, Inc. | Controlling particle size in HIPS using metal carboxylates |
| US7087689B1 (en) * | 2005-04-27 | 2006-08-08 | Fina Technology, Inc. | Method for polymerizing styrene |
| US7439277B2 (en) * | 2005-05-19 | 2008-10-21 | Fina Technology, Inc. | In-situ preparation of hydroperoxide functionalized rubber |
-
2005
- 2005-08-04 US US11/198,542 patent/US20070032562A1/en not_active Abandoned
-
2006
- 2006-07-19 EP EP06787931A patent/EP1910424A4/en not_active Withdrawn
- 2006-07-19 WO PCT/US2006/028127 patent/WO2007018995A2/en not_active Ceased
- 2006-07-26 TW TW095127196A patent/TW200712066A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007018995A3 (en) | 2007-10-04 |
| EP1910424A4 (en) | 2009-06-17 |
| EP1910424A2 (en) | 2008-04-16 |
| US20070032562A1 (en) | 2007-02-08 |
| WO2007018995A2 (en) | 2007-02-15 |
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