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TW200633926A - Apparatus and method for hydrogen generation - Google Patents

Apparatus and method for hydrogen generation

Info

Publication number
TW200633926A
TW200633926A TW095102682A TW95102682A TW200633926A TW 200633926 A TW200633926 A TW 200633926A TW 095102682 A TW095102682 A TW 095102682A TW 95102682 A TW95102682 A TW 95102682A TW 200633926 A TW200633926 A TW 200633926A
Authority
TW
Taiwan
Prior art keywords
reformer
gas
reformed
hydrocarbon gas
reforming
Prior art date
Application number
TW095102682A
Other languages
Chinese (zh)
Other versions
TWI394710B (en
Inventor
Hisanao Jo
Hideaki Matsuda
Hideshi Akasaka
Kazuo Michitani
Original Assignee
Air Water Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Water Inc filed Critical Air Water Inc
Publication of TW200633926A publication Critical patent/TW200633926A/en
Application granted granted Critical
Publication of TWI394710B publication Critical patent/TWI394710B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288—Evaporation of one or more of the different feed components
    • C01B2203/1294—Evaporation by heat exchange with hot process stream
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Fuel Cell (AREA)

Abstract

This present invention provides a hydrogen generator with excellent energy efficiency and can reduce equipment cost. In the hydrogen generator, a hydrocarbon gas is reformed to produce a reformed hydrogen-rich gas. The hydrogen generator comprises a reformer 1 for catalytically reacting the hydrocarbon gas together with oxygen with a catalyst to perform combustion and reforming of the hydrocarbon gas and a first heat exchanger 3 for heating the hydrocarbon gas to be introduced into the reformer 1 after heat exchange between the reformed gas and the hydrocarbon gas in a reformed gas passage 25 provided on the downstream side of the reformer 1. According to the above construction, the raw material gas to be introduced into the reformer 1 is heated by the heat of the reformed gas produced by the combustion and reforming, without the need to externally supply heat energy necessary for reforming by a burner of the like. Accordingly, the energy efficiency is improved. Furthermore, since the need to provide any burner in the reformer 1 is eliminated, the structure of the reformer 1 per se can be simplified, and at the same time, the structure for imparting heat resistance and pressure resistance can also be simplified. This advantage leads to a reduction in equipment cost.
TW095102682A 2005-01-28 2006-01-24 Apparatus and method for producing hydrogen TWI394710B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005020910A JP5165832B2 (en) 2005-01-28 2005-01-28 Hydrogen generating apparatus and method

Publications (2)

Publication Number Publication Date
TW200633926A true TW200633926A (en) 2006-10-01
TWI394710B TWI394710B (en) 2013-05-01

Family

ID=36740558

Family Applications (1)

Application Number Title Priority Date Filing Date
TW095102682A TWI394710B (en) 2005-01-28 2006-01-24 Apparatus and method for producing hydrogen

Country Status (5)

Country Link
JP (1) JP5165832B2 (en)
KR (1) KR101241848B1 (en)
CN (1) CN101111452B (en)
TW (1) TWI394710B (en)
WO (1) WO2006080544A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI617508B (en) * 2016-11-21 2018-03-11 Huang Heng Xin Biogas catalyst cogeneration unit and operation method thereof

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5400425B2 (en) * 2009-03-03 2014-01-29 Ｊｘ日鉱日石エネルギー株式会社 Hydrogen production apparatus and fuel cell system
KR101394346B1 (en) * 2012-02-29 2014-05-14 성균관대학교산학협력단 Thermophotovoltaic apparatus having reformer for generating hydrogen
KR101487835B1 (en) 2014-03-13 2015-01-30 성균관대학교산학협력단 Thermophotovoltaic apparatus having reformer for generating hydrogen
CN104609368B (en) * 2015-01-30 2016-06-22 山东益丰生化环保股份有限公司 A kind of petroleum refinery is resolved the method that exhaust gas conversion becomes process for making hydrogen unstripped gas
CN104609369B (en) * 2015-01-30 2015-11-18 山东益丰生化环保股份有限公司 A kind ofly petroleum refinery is resolved the method that exhaust gas conversion becomes process for making hydrogen unstripped gas
CN106556668B (en) * 2015-09-30 2020-07-10 中国石油化工股份有限公司 Movable hydrocarbon steam conversion hydrogen production catalyst test platform and test method
JP6944349B2 (en) * 2017-11-09 2021-10-06 エア・ウォーター株式会社 Hydrogen generator
KR102094646B1 (en) 2019-10-14 2020-03-30 주식회사 트리신 Highly efficient steam reforming hydrogen production apparatus with hydrodesulfurization
EP4178936A4 (en) * 2020-07-07 2025-07-02 Proteum Energy Llc Process and system for converting non-methane hydrocarbons to recover hydrogen gas and/or methane gas therefrom

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4909808A (en) * 1987-10-14 1990-03-20 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Steam reformer with catalytic combustor
JPH05253436A (en) * 1992-03-16 1993-10-05 Mitsui Eng & Shipbuild Co Ltd Production of co gas free from ch4
JP2001151502A (en) * 1999-11-26 2001-06-05 Daikin Ind Ltd Fuel reformer
US6485853B1 (en) * 2000-06-27 2002-11-26 General Motors Corporation Fuel cell system having thermally integrated, isothermal co-cleansing subsystem
JP2002050386A (en) * 2000-08-04 2002-02-15 Babcock Hitachi Kk Hydrogen producing device for fuel cell
JP4968984B2 (en) * 2001-01-12 2012-07-04 三洋電機株式会社 Fuel cell reformer
JP2002274805A (en) * 2001-01-12 2002-09-25 Toyota Motor Corp Control of reformer with heat exchanger using reforming raw material as refrigerant
JP2002293510A (en) * 2001-03-28 2002-10-09 Osaka Gas Co Ltd Carbon monoxide converter
JP2003103171A (en) * 2001-09-28 2003-04-08 Nippon Oil Corp Autothermal reforming catalyst and method, hydrogen production apparatus, and fuel cell system
JP2003212508A (en) * 2002-01-24 2003-07-30 Honda Motor Co Ltd Water supply control method for reforming system
US20030192251A1 (en) * 2002-04-12 2003-10-16 Edlund David J. Steam reforming fuel processor
JP4175921B2 (en) * 2003-03-12 2008-11-05 東京瓦斯株式会社 Heat recovery system in hydrogen production equipment

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI617508B (en) * 2016-11-21 2018-03-11 Huang Heng Xin Biogas catalyst cogeneration unit and operation method thereof

Also Published As

Publication number Publication date
KR101241848B1 (en) 2013-03-11
CN101111452A (en) 2008-01-23
KR20070099644A (en) 2007-10-09
CN101111452B (en) 2012-09-05
JP5165832B2 (en) 2013-03-21
WO2006080544A1 (en) 2006-08-03
JP2006206382A (en) 2006-08-10
TWI394710B (en) 2013-05-01

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