TW200613253A - Catalysts for maleic acid hydrogenation to 1,4-butanediol - Google Patents
Catalysts for maleic acid hydrogenation to 1,4-butanediolInfo
- Publication number
- TW200613253A TW200613253A TW094122105A TW94122105A TW200613253A TW 200613253 A TW200613253 A TW 200613253A TW 094122105 A TW094122105 A TW 094122105A TW 94122105 A TW94122105 A TW 94122105A TW 200613253 A TW200613253 A TW 200613253A
- Authority
- TW
- Taiwan
- Prior art keywords
- butanediol
- catalysts
- maleic acid
- acid hydrogenation
- hydrogenation catalyst
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6567—Rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8986—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/34—Mechanical properties
- B01J35/37—Crush or impact strength
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
- C07C29/172—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with the obtention of a fully saturated alcohol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/06—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
- C07D307/08—Preparation of tetrahydrofuran
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Furan Compounds (AREA)
Abstract
This invention relates to a process for catalytically hydrogenating a hydrogenatable precursor in contact with a hydrogen-containing gas and a hydrogenation catalyst comprising one or more active hydrogenation catalyst components on a support comprising titanium dioxide in the rutile crystalline phase to produce 1,4-butanediol (BDO) and, optionally, gamma-butyrolactone (GBL) and/or tetrahydrofuran (THF).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/883,106 US7935834B2 (en) | 2004-07-01 | 2004-07-01 | Catalysts for maleic acid hydrogenation to 1,4-butanediol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200613253A true TW200613253A (en) | 2006-05-01 |
| TWI362376B TWI362376B (en) | 2012-04-21 |
Family
ID=35448019
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW094122105A TWI362376B (en) | 2004-07-01 | 2005-06-30 | Catalysts for maleic acid hydrogenation to 1,4-butanediol |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7935834B2 (en) |
| EP (1) | EP1773746B1 (en) |
| JP (1) | JP2008505103A (en) |
| KR (1) | KR101281219B1 (en) |
| CN (1) | CN101163656B (en) |
| AU (1) | AU2005262405B8 (en) |
| MX (1) | MX2007000197A (en) |
| MY (1) | MY150675A (en) |
| TW (1) | TWI362376B (en) |
| WO (1) | WO2006007523A1 (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10252281A1 (en) * | 2002-11-11 | 2004-05-27 | Basf Ag | Supported rhenium catalyst, useful for the production of tetrahydrofuran and gamma-butyrolactone by reduction of carbonyl compounds, contains a further Group 8 or 1b metal and is prepared using a bimetallic precursor compound |
| GB0719191D0 (en) | 2007-10-02 | 2007-11-07 | Cadbury Schweppes Plc | Packaging of a stack of confectionary pellets and the like |
| ES2432642T3 (en) * | 2010-02-12 | 2013-12-04 | Purac Biochem Bv | Succinic acid production process |
| CN103044365B (en) * | 2011-10-17 | 2015-06-17 | 中国石油化工股份有限公司 | Production method of tetrahydrofuran |
| CN102417445B (en) * | 2011-11-05 | 2013-11-13 | 中国科学院山西煤炭化学研究所 | Method for synthesizing succinic acid from maleic acid |
| WO2014035654A1 (en) | 2012-08-31 | 2014-03-06 | Rohm And Haas Company | Method to produce alcohols from organic acids |
| JP6318479B2 (en) * | 2013-06-21 | 2018-05-09 | 宇部興産株式会社 | Catalyst, catalyst production method, and polyol compound production method using the same |
| RU2679639C2 (en) * | 2014-12-04 | 2019-02-12 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Method for producing 1,4-butanediol and tetrahydrofuran from furan |
| US10377727B2 (en) | 2015-10-06 | 2019-08-13 | Synvina C.V. | Process for the preparation of gamma-valerolactone |
| CN108329943B (en) * | 2018-03-12 | 2019-11-05 | 江苏华达化工集团有限公司 | A kind of processing method of heavy benzol naphtalene oil |
| CN108409522B (en) * | 2018-03-12 | 2021-10-29 | 江苏华达化工集团有限公司 | A kind of heavy benzene naphthalene produces refined naphthalene method |
| JP7372815B2 (en) * | 2018-12-25 | 2023-11-01 | 出光興産株式会社 | Method for producing C5+ compound and catalyst used therein |
| TWI786326B (en) * | 2019-08-29 | 2022-12-11 | 大連化學工業股份有限公司 | A method for producing tetrahydrofuran |
| CN110396072B (en) * | 2019-09-02 | 2022-09-13 | 上海欣海健伟实业有限公司 | Method for producing(s) -3-hydroxytetrahydrofuran |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3344721A (en) | 1965-08-13 | 1967-10-03 | Chevron Res | Pneumatic compaction of asphalt compositions |
| DE2519817A1 (en) * | 1975-05-03 | 1976-11-11 | Hoechst Ag | PROCESS FOR THE PRODUCTION OF BUTANDIOL- (1.4) |
| JPS5248582A (en) * | 1975-10-15 | 1977-04-18 | Sakai Chem Ind Co Ltd | Carrier |
| DE2553761A1 (en) * | 1975-11-29 | 1977-06-02 | Hoechst Ag | METHOD FOR THE CATALYTIC PRODUCTION OF GAMMA-BUTYROLACTONE |
| US4446073A (en) * | 1981-08-05 | 1984-05-01 | Uop Inc. | Process for the reduction of unsaturated carboxylic acids |
| US4524225A (en) * | 1983-12-14 | 1985-06-18 | Uop Inc. | Acid resistant catalyst supports; reduction of fatty acids to fatty alcohols |
| US4609636A (en) * | 1983-12-22 | 1986-09-02 | E. I. Du Pont De Nemours And Company | Pd/Re hydrogenation catalyst for making tetrahydrofuran and 1,4-butanediol |
| US4550185A (en) * | 1983-12-22 | 1985-10-29 | E. I. Du Pont De Nemours And Company | Process for making tetrahydrofuran and 1,4-butanediol using Pd/Re hydrogenation catalyst |
| US4782167A (en) | 1987-01-23 | 1988-11-01 | E. I. Du Pont De Nemours And Company | Process for preparing butyrolactones and butanediols |
| GB8707595D0 (en) * | 1987-03-31 | 1987-05-07 | British Petroleum Co Plc | Chemical process |
| GB8917157D0 (en) | 1989-07-27 | 1989-09-13 | Bp Chem Int Ltd | Chemical process |
| JP3238456B2 (en) * | 1991-05-22 | 2001-12-17 | 花王株式会社 | Method for producing catalyst precursor for hydrogenation reaction, and method for producing alcohol using said catalyst precursor |
| US5362908A (en) * | 1993-03-10 | 1994-11-08 | Amoco Corporation | Catalyst and method for purifying crude terephthalic acid, isophthalic acid or naphthalene dicarboxylic acid |
| US5354898A (en) * | 1993-06-17 | 1994-10-11 | Amoco Corporation | Method for purifying crude aromatic carboxylic acids |
| JPH0782189A (en) | 1993-09-14 | 1995-03-28 | Tosoh Corp | Method for producing 1,4-butanediol |
| US5473086A (en) * | 1995-01-17 | 1995-12-05 | The Standard Oil Co. | Process for the hydrogenation of maleic acid to 1,4-butanediol |
| US5698749A (en) * | 1995-09-06 | 1997-12-16 | The Standard Oil Company | Catalysts for the hydrogenation of aqueous maleic acid to 1,4-butanediol |
| US5616792A (en) * | 1996-02-01 | 1997-04-01 | Amoco Corporation | Catalytic purification of dicarboxylic aromatic acid |
| US5756833A (en) * | 1996-02-01 | 1998-05-26 | Amoco Corporation | Catalytic purification and recovery of dicarboxylic aromatic acids |
| US5969164A (en) * | 1996-12-20 | 1999-10-19 | The Standard Oil Company | Catalysts for the hydrogenation of maleic acid to 1,4-butanediol |
| US5985789A (en) * | 1997-03-27 | 1999-11-16 | E. I. Du Pont De Nemours And Company | Ru, Sn/oxide catalyst and process for hydrogenation in acidic aqueous solution |
| US6486367B1 (en) * | 1997-12-01 | 2002-11-26 | The Standard Oil Company | Process for the hydrogenation of maleic acid to 1,4-butanediol |
| JP2000135440A (en) * | 1998-10-30 | 2000-05-16 | Catalysts & Chem Ind Co Ltd | Hydrotreating catalyst and method for producing the same |
| DE10252282A1 (en) | 2002-11-11 | 2004-05-27 | Basf Ag | Supported rhenium catalyst, e.g. for production of alcohols by catalytic hydrogenation of carbonyl compounds in liquid phase, comprises titanium dioxide of defined maximum sulfate content and surface area |
-
2004
- 2004-07-01 US US10/883,106 patent/US7935834B2/en active Active
-
2005
- 2005-06-30 AU AU2005262405A patent/AU2005262405B8/en not_active Ceased
- 2005-06-30 TW TW094122105A patent/TWI362376B/en not_active IP Right Cessation
- 2005-06-30 EP EP05763765.4A patent/EP1773746B1/en not_active Expired - Lifetime
- 2005-06-30 MX MX2007000197A patent/MX2007000197A/en active IP Right Grant
- 2005-06-30 JP JP2007519439A patent/JP2008505103A/en active Pending
- 2005-06-30 KR KR1020077002339A patent/KR101281219B1/en not_active Expired - Fee Related
- 2005-06-30 WO PCT/US2005/023306 patent/WO2006007523A1/en not_active Ceased
- 2005-06-30 CN CN200580028533XA patent/CN101163656B/en not_active Expired - Fee Related
- 2005-06-30 MY MYPI20052994 patent/MY150675A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20060004212A1 (en) | 2006-01-05 |
| MX2007000197A (en) | 2008-03-25 |
| WO2006007523A1 (en) | 2006-01-19 |
| KR20080024103A (en) | 2008-03-17 |
| AU2005262405B2 (en) | 2011-03-24 |
| EP1773746A1 (en) | 2007-04-18 |
| AU2005262405B8 (en) | 2011-04-14 |
| US7935834B2 (en) | 2011-05-03 |
| AU2005262405A1 (en) | 2006-01-19 |
| MY150675A (en) | 2014-02-28 |
| EP1773746B1 (en) | 2017-08-09 |
| KR101281219B1 (en) | 2013-07-02 |
| TWI362376B (en) | 2012-04-21 |
| JP2008505103A (en) | 2008-02-21 |
| CN101163656B (en) | 2011-07-13 |
| CN101163656A (en) | 2008-04-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |