TW200536569A - Taurate formulated pigmented cosmetic composition exhibiting radiance with soft focus - Google Patents

Abstract

A cosmetic composition is provided which includes a crosslinked silicone elastomer, a zinc oxide or zirconium oxide of average particle size less than 300 nm and a taurate polymer, in a cosmetically acceptable carrier system. The composition achieves soft focus and radiance properties which improve the appearance of skin. Good coverage over imperfections such as pores and uneven skin tone is achieved while retaining a natural skin appearance.

Description

200536569 IX. Description of the invention: [Technical field to which Sheming belongs] The present invention relates to compositions that can improve the appearance of skin. These compositions can provide defects such as pores and uneven skin tone while maintaining a natural skin appearance. Good cover. [Prior art] All users of color cosmetics expect a matte effect. The matte finish # can overcome the shiny effects caused by oily skin, especially in hot and humid environments. Absorbent fillers such as talc, silica, kaolin and other inorganic particles have been used to achieve this effect by virtue of their optical properties. Defective skin can be masked in two ways by regulating light transmission. In the first way, the component of the color cosmetic can only reflect light back to the light source. An alternative method is called to achieve a soft focus effect. In this method, incident light is refracted by scattering (lensing). In this mechanism, the components of the colored cosmetics act as lenses to bend and twist the light into various directions. _ People expect to mask the defective skin by a delustering effect, and also hope to achieve a healthy skin radiance. An over-opaque cosmetic cover masks the skin under a paint-like coating. Although the defects were masked, they lost their luster. Where light transmission is not sufficiently impeded, the opposite occurs. At this time, a healthy luster may be displayed, but at the same time, it will also show the skin surface condition and color that are aesthetically unpleasant. US Patent No. 5,997,890 (Sine et al.), US Patent No. 5,972,359 (Sine et al.) And US Patent No. 6,174,533 B1 (SaNogneira, Jr.) are all about 98969 which can provide good skin defect coverage. doc 200536569 composition. The solutions proposed in these documents use a metal oxide having a refractive index of at least about 2 and a net primary particle size from about 100 to about 300 nanometers. Particulate-based titanium dioxide, zirconia, and zinc oxide are preferred. It has been found that stone oxo gelling agents (eg, cross-linked organopolysiloxane elastomers) are useful in cosmetic compositions due to their superior skin feel characteristics. For example, U.S. Patent No. 5,266,321 (Shukuzaki et al.) Discloses an oily cosmetic composition comprising a silicone gel crosslinked elastomer, titanium dioxide, mica, and iron oxide. Japanese Patent Application No. 61-194009 (Harashima) illustrates a cosmetic composition 'comprising a cured organopolysiloxane elastomer powder and may be selected from the group consisting of talc, titanium dioxide, zinc oxide, and iron oxide. pigment. One challenge that has not been fully achieved by known techniques is to provide a composition with suitable optical characteristics to achieve both soft focus and brilliance characteristics in a system and still provide superior skin feel. [Summary of the Invention] The present invention provides a cosmetic composition comprising: (1) a crosslinked silicone elastomer; (ii) a zinc oxide or an oxide with an average particle size of less than 300 nm; (iii) a cow Amine ester polymers; and (iv) —cosmetically acceptable carrier systems. [Embodiment] It has been found that a glorious soft focus effect can be achieved by one or ytterbium oxide floating-cross-linked polymerization of small particles of zinc oxide, which zinc oxide or ytterbium oxide must have. Without the elastomer or the oxide, the average particle size is not available. If the stomach produces a sufficient soft focus effect. 98969.doc -7- 200536569 The use of oxides alone will have no effect due to excessive loss of reflectance / brilliance. Crosslinked polysiloxane elastomer One component of the present invention is a crosslinked polysiloxane (organopolysiloxane) elastomer. There is no particular limitation on the type of curable organic polyoxygenase composition that can be used as a starting material for the crosslinked polyoxygenated elastomer. Examples in this regard are organic polysiloxane compositions which are cured by addition reactions, which are catalyzed by platinum metal by two organic polysiloxanes containing SiH and a vinyl group with bonded silicon The addition reaction between the two organopolysiloxanes achieves curing; the organopolysiloxane composition cured by the condensation reaction, these compositions are in the presence of an organotin compound by a hydroxyl-terminated two organic Polysilicone t-fired and the dechlorination reaction between SiSi-containing two polysilicone oxygen hospitals to achieve curing; organopolysiloxane composition cured by condensation reaction, these compositions are an organic tin compound or In the presence of a titanate, curing is achieved by a condensation reaction between a hydroxyl-terminated two organic polyoxane and a hydrolyzable organosiloxane (examples of the condensation reaction are dehydration, alcohol release, Reactions of amine release, amine release, carboxyl release, and ketone release); oxide-cured organopolysiloxane compositions that are thermally cured in the presence of an organic peroxide catalyst; and By high energy The radiation is, for example, an organopolysiloxane composition which is cured by 7 rays, ultraviolet radiation or electron beam. The silicone polysiloxane composition cured by the addition reaction is better because of its faster curing rate and excellent curing uniformity. A particularly good addition-cured organopolysiloxane composition is prepared from the following: (A)-98969.doc 200536569 organic polymer having at least two lower alkenyl groups in each molecule Siloxane; (B)-an organic polysiloxane having two silicon-bonded hydrogen atoms per fraction; and τ (C) a platinum-type catalyst. The crosslinked silicon oxygen enthalpy tickane bombs of the present invention may be an emulsified or non-emulsified crosslinked organic polymer shred elastomer or a combination thereof. As used herein, the term "non-emulsifying" is used in the context of crosslinked organopolysiloxane fired elastomers which do not contain polyoxyalkylene units. As used in this article, the term “Li Hem Lihua” refers to a cross-linked organic polysiloxane containing at least one polyoxyalkylene smoke (such as' polyoxyethylene or polyethylenimine rolled propylene). Elastomer. A particularly useful emulsified elastomeric system is a polyoxyalkylene-modified elastomer, which can be composed of a diethylammonium compound (especially a siloxane polymer with at least two free vinyl groups) and a polysiloxane base chain. Formed by ^ bonding reaction. Preferably, the elastic systems are dimethyl polysiloxane crosslinked by Si-H sites on a spherical molecular resin. The preferred siloxane elastic system can be dimethyl siloxane / vinyl dimethyl siloxane cross-linked polymer, dimethyl siloxane cross-linked polymer, and poly siloxane— "Organic poly siloxane obtained by ^ name Alkane composition. Usually these materials are provided as a 1-30% crosslinked silicone elastomer dissolved or suspended in a dimethylsilicone liquid (usually cyclomethylsiloxy). For the purpose of definition "" Crosslinked oxane elastomer "refers to the overall commercially available composition of the elastomer itself rather than also containing a solvent (for example, a monomethyloxyl) carrier. Monomethyl-oxygen / ethylene-monomethyl-oxygen cross-linked polymer and dimethyl secondary oxygen-crosslinked polymer are available from multiple suppliers, including Dow 98969.doc 200536569

Corning (9040, 9041, 9045, 9506, and 9509), General Electric (SFE 839), Shin £ 411, 80-15, 16, 18 [Dimethylsilyloxy / phenylethoxydimethyl dimethylsulfite Cross-linked polymer]) and Grant Industries (GransilTM series # material), and lauryl dimethyl siloxy / vinyl dimethyl stone cross-linked polymer (for example, KSG-3 1, KSG-32, KSG-41, KSG-42, KSG-43, and KSG-44). Other suitable commercially available silicone elastomer powders include vinyl monomethyllithium oxide sold by Shin_Etsu as KSP-100, KSP-101, KSP-102, KSP-103, KSP-104, and KSP-105. Methyllithium sesquioxane fired cross-linked polymer, and Shin-Etsiz are sold as KSP-200 and KSP-300, respectively, a mixed silica powder containing a fluorocarbon group or a phenyl group. The concentration of the crosslinked silicone elastomer of the present invention may range from about 0.01 to about 30% by weight of the cosmetic composition, preferably from about 0 "to about 10%, and most preferably from about 0.5 to about 2%. These weight values do not include any solvents, such as urethane methyl oxanite in commercially available "elastomeric" siloxanes (eg, Dow Corning's products 904 and 905). For example, in 9_ and 9045, the amount of cross-linked sparoxane elastomer is between 12 and π weight ❹ /. between. The oxygen-soluble volume of D5 cyclomethyl stone and the optimal siloxane elastic system 9045 according to spherical particles have an expanded elastomer particle size (based on volume calculation) of about 38 microns on average, and the particle The diameter can range from about 25 to about 55 microns. Micronized zinc oxide or oxide

Less than 85 nanometers is a component consisting of micronized zinc oxide or zirconia having a diameter of less than 300, more preferably less than 100 nanometers, and most preferably less than 85 nanometers. 98969.doc 10 200536569 Often the range of these particle sizes can be from about o.omw to rice, more preferably from about ^ to about 200 nm, even more preferably from about 10 to 95 nm, and the best since 25 to 75 nanometers. The average particle size of the oxide or zirconia is assumed to be spherical and is defined as the particle diameter obtained by averaging a plurality of particles. This average is a numerical average. For spherical particles such as zinc oxide, laser light scattering is used to determine individual particle sizes and generate a particle size distribution map. Based on this profile, the average particle size can be determined. In more mathematical terms, the average particle diameter is a diameter obtained from the conversion of the specific surface area of the interstitial pores determined by the method of the Buffet method (particle size conversion does not include the specific surface area of micropores smaller than 20 angstroms). In detail, assuming that the particles are spherical 2 ′, the average particle diameter D can be obtained by the following equation: D = 6 / pS, where H (m2 / g) represents the interstitial pore specific surface area and p (g / cm3) is the density . The range of the cosmetic composition may range from about 0.1 to about 20% by weight of the cosmetic composition, from about 0.05 to about 5%, and most preferably from about 1 to about 5%. "Zinc oxide or hafnium oxide particles are applied to the skin, so they are expected to be free of toxic trace metal contaminants. A particularly good oxidant has only a trace concentration of lead (less than 20 PPm), Shishen (less than 3 PPm), recording (less than i 5 ppm), and mercury (less than 2 rigid). This material can be Z heart te HP i Its trade name was purchased from BASF. Granules are best used in formulations as a 5 to 80% by weight premix suspended in an organic matrix. Zinc oxide or zirconia particles are preferred but need not be substantially spherical. The refractive index of the particles preferably ranges from about U to about 2.3. Refractive index

Dean > Ed? Lange, s Handb〇〇k 〇f

Chemistry, 14th ·, McGraw Hill, New York 1992, Section 98969.doc -11-200536569 9, Refractometry ", which is incorporated herein by reference. Tauric acid S polymer Another important component of the present invention is a combined polymer. Particularly preferred are taurine homopolymers and copolymers. These copolymers are particularly useful when the taurine repeating monomer unit is acryl dimethyl taurine xanthate, which can be in the form of a free acid or salt. Copolymers that can form copolymers with taurine • Monomers can include styrene, acrylic, methacrylic, vinyl chloride, vinyl acetate, vinyl pyrrolidone, isoprene, vinyl alcohol, ethylene Methyl ether, chlorostyrene, dialkylaminostyrene, maleic acid, acrylic acid, methyl acrylic acid, and mixtures thereof. When the term "acid" appears, the term refers not only to the free acid but also to Cl-Cw alkyl esters, anhydrides, and salts thereof. Preferably, but not exclusively, the salts may be ammonium, alkanolammonium, alkali metal and alkaline earth metal salts. The best are ammonium salts and alkanol ammonium salts. Examples of suitable taurine polymers are those listed in the table below. Supplier name INCI name Clariant Aristoflex AVC Acrylic acid dimethyl taurine salt / VP copolymer Clariant Aristoflex HMB Acrylic acid dimethyl taurine ammonium salt / Beheneth-25 methacrylate crosslinked polymer Clariant Hostacerin AMP5 Polypropylene ammonium dimethyl taurine ammonium salt RITA Viscolam Sodium acrylate / acryl fluorenyl difluorenyl taurine 98969.doc -12- 200536569 SMC 20 Sodium salt copolymer and C13-C14 isochain burning Hydrocarbons and Laureth-8 SEPPIC Simulgel 600 Propyleneamine / Propanyl Difluorenyl Tauryl Sodium Salt Copolymer; Isohexadecane; Polysorbate 80 SEPPIC Simulgel 800 Polypropylene Dimethyl Dimethyl Cattle Sodium sulfonate; isooctadecaine; sorbitan oleate SEPPIC Simulgel EG sodium acrylate / acrylomethyldimethyltaurine xanthate copolymer and isohexadecane and polysorbate 80 SEPPIC Simulgel EPG acrylic acid Sodium / acrylfluorenyl dimethyl taurate copolymer and polyisobutylene and octyl / octylglucoside SEPPIC Simulgel NS acrylic acid ester / acrylfluorenyl dimethyl taurate sodium salt copolymer and horn Squalene and Polysorbate 60 The best copolymer is acryl dimethyl taurine / vinylpyrrolidone copolymer. This is the INCI name of a material supplied by Clariant under the trade name Aristoflex® AVC and has the following general formula: :

Wherein η and m are integers and can be independently changed in the range of 1 to 100,000. 98969.doc 13 200536569 The number average molecular weight of the taurine sulfonate of the present invention may range from about 1, _ to about 3, _, _ ', preferably from about 3, _ to about i () G, _, most preferably From about 10,000 to about 80,000. The amount of the taurine S polymer can be from about 0.001 to about 10% by weight of the composition, preferably from about ㈣ to about 8%, more preferably between about Q, and most preferably between about 0. -2 to about 10/0. Optional Particles • Another desirable component of the composition of the present invention is a component composed of light reflecting flake particles. The particles have an average particle size d5 from about i 0,000 to about 30,000 nanometers. . The refractive index of these particles is preferably at least about 18, usually from about 1.9 to about 4 ', more preferably from about 2 to about 3, and most preferably between about 2.5 to 28. Illustrative but non-limiting examples of light reflecting particles are bismuth oxychloride (single crystal flakes) and hafnium dioxide-coated mica. Suitable aerosol silver crystals can be quoted. Named Biron® NLY-L-2X CO and Biron® Silver CO (where the flakes are dispersed in onion sesame oil), Biron (g) Uquid (where these particles are dispersed in monostearic acid ®) and Nailsyn® IGO, Nailsyn® Π C2X, and Nailsyn⑧H Piatinum 25 (where the flakes are dispersed in stone shokey fiber ^) were purchased from EMInd_ies. The best is a system in which bismuth oxide is dispersed in a c2-c40 alkyl ester such as Biron @ Uquid SiWer. Suitable titanium dioxide-coated mica flakes include materials known from EM Industries. These include Ding ^ ⑽⑧ Μρ · ι〇 (particle size range of 10,000 to 30,000 nanometers), Ding 11 ^ 〇1 ^] ^ -14 (particle size range of 5,000 to 30,000 Nanometers), Ding ㈤ ⑽⑧ Μρ_3〇 (particle size range 2,000 20,000 nanometers), Timir ⑽⑧Μρ-1〇1 (particle size range 98969.doc -14- 200536569

Timiron® MP-111 (particle size range k Timiron® MP-1001 (particle size range, Timiron® MP-155 (particle size range, Timiron® MP-175 (particle size range, Timiron® MP-115 (Particle size range is Timiron® MP-127 (The best particle size range is Timiron® MP-111. The range of weight ratio of dioxide can be from about 1: 1 to about • by weight from about 1: 1 to about 1: 6, more preferably from about 1: 3 to about 1: 4. Preferably, these preferred compositions are generally substantially free of titanium dioxide except as required for coating mica. Titanium dioxide may also be suitable for use Mica coatings other than silica coatings are the choice. The amount of light-reflecting flake-shaped particles ranges from about to about 5%, preferably from about 0.5 to about 3% by weight of the composition. More preferably from about 08% to about 2%, most preferably from about 1 to about 1.5%. Preferably, the composition of the present invention has a range from 14 to 170 KW-nm when measured at an angle of 30. / cm reflection intensity. Preferably, the light transmission intensity is at 10 ° from 4 to 7 MW-nm / cm2 at the angle; at 10. angle is a transmission intensity from i to 2 MW-nm / cm2 at the angle ; From 300 to 140KW-nm / cm2 at 300 ° Light transmission intensity; a light transmission intensity from 60 to 80 KW-nm / cm2 at a 40 ° angle; and a light transmission intensity from 40 to 60 KW-nm / cm2 at a 50 ° angle Strength. Preferably, the weight ratio of zinc oxide and hafnium oxide to light reflecting flake-shaped particles is 98969.doc -15-200536569. The range may be from about 4: 1 to about 1: 1, preferably from about 3: ι by weight. Up to about i Η, most preferably about 2: 1. In a preferred but non-limiting example, the ratio of the presence of Shi Xi oxygen elastomer and ㈣be particles relative to the light reflecting flake-shaped particles can be from about um by weight To about 1: preferably from about 6: 1 to about ι: ι, more preferably from about $ "to about 3: 1, most preferably about 4: 1. Preferably, the composition of the present invention may comprise Coated mica. Mica particles can also be flake-shaped, but should have a thinner and smaller particle size than the coated mica described above. Particularly good ones are calendered mica, which can be obtained from your heart. You can easily remove all the excessive gloss imparted by the light scattering tablets. Preferably, the particle size of the uncoated mica is not greater than 15,000 nanometers, and the range of its average (volume) particle size is 1, _ to 10, _ nanometer , Preferably from 5,000 to 8,000 nanometers. The amount of uncoated mica occupies about 2% of the composition by weight, preferably from about (M to about h5%). To about 0. Preferably, 'water-insoluble organic materials in the form of polymeric porous spherical particles may also be present. The term "porous" refers to an open or closed cell structure. Preferably, the particles are not in the central office. Τ

Mf Τ two beads. The average particle size may be from about 0.1 to about 100, preferably from about 1 to about 50, more preferably greater than 5 and even more preferably from about 5 to about 15: most preferably from about 6 to about 10 microns. Organic polymers or copolymers are preferred materials and can be composed of acrylic acid and methacrylic acid, methyl acrylic acid, ethyl acrylic acid, ethyl methacrylate, acrylic acid Dilute, acryl, maleic acid, ethyl. Monomer formation of croaker, styrene, butadiene and their mixtures. Crosslinked forms of these polymers are particularly useful. The cells of multiple particles can be filled with-gas, which can be air, nitrogen or — 98969.doc -16- 200536569 anaerobic port. The oil absorption rate (10,000 sesame oil) is a measure of porosity and in a preferred but non-limiting example, it can range from about 900 to an optimum from about 100 milligrams. G. In the two examples, the particle density may be from about 55 to about 55, preferably from about 0 μ to 0.48 g / cm3. + Exemplary porous polymers include polymethyl methacrylate and cross-linked polystyrene. The best one is polymethyl methanoate, which is commercially available from PlSCataWay, New Jersey under the trade name Ganzpearl® GMP 820. Its INCI name is methyl methacrylate cross-linked polymerization The amount of the water-insoluble polymeric porous particles ranges from about 0.001 to about 10% by weight of the composition, preferably from about 01 to about 5%, and most preferably from about 0.3% to about 2 % 〇 Carrier system and optional components Preferably, a crystalline structurant may be present in the composition of the present invention. The structurant may include a surfactant and a co-surfactant. The surfactant The nature of the co-surfactant will depend on whether the crystal structurant is anionic or non-ionic. For anionic structurants, the preferred surfactant is C. G-C22 fatty acids and their salts (ie, soap). And particularly preferably, it is a combination of these materials. It can form the typical counter ion of the fatty acid salt, such as ammonium salt, sodium salt, potassium salt, lithium salt, trialkyl alcohol ammonium (such as triethyl ammonium), and other ions. A combination of fatty acids and fatty acids when both fatty acids and fatty acid salts are present The amount ratio may be from about 100: 1 to about 1: 100 by weight, preferably from about 50: 1 to about 1:50 'and most preferably from about 3: 1 to about 1: 3. Exemplary fatty acids include mandrill Acid, stearic acid, isostearic acid, myristic acid, lauric acid, linoleic acid, 98969.doc-π-200536569 oil =, stearic acid and combinations thereof. The best is stearic acid. Among the fatty acid salts, the best is sodium stearate. The co-surfactant of the dianionic crystal structurant is usually an "a " C22 fatty acid of 0 丨 _ <: 2 esters, and especially these materials. combination. When both the purpose and the alcohol are present, the relative dosage ratio is from about 1 to about 100 by weight, preferably from about 50: 1 to about 1:50, and most preferably from about 31 to about 0.5%. 3. Fatty alcohols for suspension include behenyl alcohol, stearyl alcohol, cetyl alcohol, tetradecyl alcohol ... Preferred fatty acid vinegar polyol polyol vinegars, oxidized alcohol esters. In addition, it also includes polyethoxylate, polypropoxylate, and Ganecho / polypropoxylate. The best ones are such as PEG. Stearate, PEG-20 stearate, peg_80 laurel vinegar, coffee, laurel vinegar, PEG. 10G palmitate, PEG_2 standard acid vinegar, etc. combination. The relative amount of the surfactant and co-surfactant of the anionic structurant may be from about 50: 1 to about 1:50, preferably from about ㈣ to about! 10, and most preferably from about 3: 1 To about 1: 3. Non-ionic crystal structurants should have—unlike surfactants and co-surfactants used in anionic systems. The preferred nonionic surfactant is C 丨. -. Ci_C2— of 2 fatty acids. Fatty acid is preferably a polyhydric alcohol vinegar, such as (: 2 _ (: 3 esters of oxylated alcohol or sorbitol. In addition, it also includes polyethoxylated, polypropoxylated, and block polyethoxylated / polypropoxylated vinegar. You poly sorbitol, poly sorbitol vinegar 60, ca_100 stearic acid, PEG, stearic acid, PEG-80 lauryl ester, η laurel, PEG-2 laurel, PEG_1〇〇 Under-ester, PEG-20 palmitate, and other esters and their combinations. -Co-surfactants of non-ionic structurants can usually be _ Ciπ% lipid 98969.doc -18- 200536569 fatty alcohols, -c, .-c22 A combination of fatty acid glycerides and a Ci0_c22 fatty acid that has not been vinegarized. The relative amount of the ester dish is θ, and the relative amount of the ® may be from about 100: 1 to about ι ·· ι〇〇, preferably from about 50: 1 to about 1:50 'and most preferably from about 3: 1 to about 3. The relative ratio of the combination of glycerol: ester and fatty alcohol to the unesterified fatty acid Dosage can be from about 100.1 to about, preferably from about H, and most preferably from about 3: 1 to about 1: 3. Tang Xian 0 Diao Qi Qi _ ^ t ^ Φ Behenyl alcohol, stearyl alcohol, cetyl alcohol, myristyl alcohol, lauryl alcohol, oleyl alcohol A combination thereof.

The relative amount of surfactant and co-surfactant in the non-ionic structurant can be from about ㈣ to about ㈣, preferably from about ΐ (M to about 1.10 'and most preferably from about 3: 1 by weight). To about 1: 3.-Crystal structure agent is formed by surfactant and co-surfactant. In fact, the combination of surfactant and co-surfactant according to its relative proportion and material type combination is defined by a This range is from about 2 to about 15, preferably from about 2.5 to about 12, and most preferably from about 3.5 to about 8 joules / gram, which is measured by differential scanning calorimetry. Moreover, the refinement point of the crystal structurant system may preferably be from about 30 to about 70 t, more preferably from about ^ to ㈣C, and most preferably from about 50 to about 60 ° C.-Its value is a positive number The normal force can reflect the smooth skin feel of the formulation. It has been confirmed that the negative value has a stagnation sensation that is unpleasant to many consumers. The normal force is measured in the following way. Use one with all the moduli of modulus and one method. Toward the transmission of the force, L worry instrument to measure the high shear normal force. These devices can be

Rheometric Scientific ARES, TA Instruments AR2000, and paar were purchased as MCR. The samples were compacted between concentric parallel plates with a diameter of 25 mm and a distance of 100 mm (the vertical distance between the two plates). The same amount 98969.doc -19- 200536569 The measurement system is implemented in a continuous logarithmic shear scan mode, and the shear rate ranges from ι to 10, _1. Each scan time is b minutes and is applied under ambient conditions (20-25 C). Calculate the normal force by subtracting the reference value (defined as the normal force at or near _ 1) from the highest normal force value measured between 1000 and ι, _. When the product When the normal force of the material is + 5 grams and especially 10 grams or more, the products / materials have a smooth feel when rubbing is applied. The higher the positive normal force, the better the soft focus effect. Generally, the soft focus effect can be enhanced when the normal force is about +5 to about + Gang. The best is when the normal force is from about +1 (> to about +6 (). From about +25 to about +40 g. The composition of the present invention can be # 人 夕 甘 + other ingredients. The most important thing is water, which acts as a carrier in a two-carrier system. The amount of water is by weight It can account for 80% of the composition. To about 9G%, preferably from about 50% to about 50%, and most preferably from about 50 to about 50% of the material can be included as a carrier in the composition of the present invention. These materials; Synthetic vinegar, hydrocarbons, etc. The amount of emollient used is by weight = about G.1% to about 95% of the composition 'preferably between about 1% to about 50% I.' The knife can be volatile and Non-volatile two. The term " The material for steaming Qing. (20-25. 0 has a measurable steaming content containing 4 to 5 gal, and the volatile silicone oil is selected from the group containing 3 to 9 (compared to oxygen burning. The ring of silicon atoms ( Cyclomethylsilicone) or linear polydimethylsilicone can be used as emollients. M β > Alkane, polym Non-volatile silicone oils include polyalkylsilicone earth claysilicone and polyether silicone Alkane copolymer. The substantially non-volatile polyalkylsiloxane used in the present invention 98969.doc-20 · 200536569 includes, for example, a viscosity of about 5x10.6 to 0.1 at 25 ° C m2 / s of polydimethylsiloxane. Among the preferred non-volatile emollients that can be used by the present inventors are those at 25. (: have from about ΙχΙΟ · 5 to about 4xl0 · Polydimethylsiloxane with a viscosity of 4 m2 / s. Esters emollients include: Alkenyl or alkyl esters of fatty acids containing 10 to 20 carbon atoms. Examples include isoarachidyl pivalate, isopropyl Isononanoyl nonanoate, oleyl myristate, oleyl stearate, and oleyl oleate. Ether vinegar, for example, fatty acid esters of ethoxylated fatty alcohols. Polyol esters. Ethylene glycol Single and double fat Acid esters, mono- and di-fatty acid esters of diethylene glycol, mono- and di-fatty acid esters of polyethylene glycol (200-6000), mono- and di-fatty acid esters of propylene glycol, and mono-oleate of polypropylene glycol 2000 Acid ester, polypropylene glycol 2000 monostearate, ethoxylated propylene glycol monostearate, glycerol mono and di fatty acid vinegar, polyglycerol polyfatty acid ester, ethoxylated glycerol monostearate, 1,3-butanediol monostearate, 1,3-butanediol distearate, polyoxyethylene polyol fatty acid ester, sorbitan fatty acid ester, and polyoxyethylene sorbitan Fatty acid esters are all satisfactory polyhydric alcohol esters. Particularly useful are iso-tetraol, trishydroxymethylpropane, and neopentyl glycol esters of Ci-Cw alcohols.躐 S purpose, for example, beeswax, whale wax and three camellia wax. W alcohol is an example of a cholesteryl fatty acid. Fatty acid esters of sugar, for example, polybehenate of cane bran and polyraffinate of sucrose. Hydrocarbons as suitable carriers acceptable for cosmetics include petroleum jelly, mineral oil, Cn-C! 3 isoparaffin, polyalphaolefins, and especially isohexadecane, 98969.doc -21-200536569 which can be Permethyl The trade name of 010A was purchased from Presperse. Polyol type humectants can be used as cosmetically acceptable carriers. Commonly used polyols include ... polyalkylene glycols and better alkylene polyols and their derivatives, including propylene glycol, dipropylene glycol, polypropylene glycol, polyethylene glycol and its derivatives, sorbitol, hydroxypropyl sorbitan Furfuryl alcohol, hexanediol, 13-butanediol, isoprenediol, 1,2,6-hexanetriol, ethoxylated glycerol, propoxylated glycerol, and mixtures thereof. The amount of the humectant may be from 0% to φ50% of the composition by weight, preferably between 1 to 15%. The best is glycerin. The amount of glycerol may be from about 10% to about 50% by weight of the composition, preferably from 12 to 35%, and most preferably from 15 to 30%. Sunscreen agents may also be included in the compositions of the present invention. These sunscreen agents may be organic compounds having at least one chromophore that absorbs ultraviolet light ranging from 29 to 4 nanometers. Hair coloring organic sunscreens can be divided into the following categories (and specific examples) 'including: p-aminobenzoic acid, its salts and its derivatives (ethyl, isopropyl, glyceryl esters; p-dimethylaminobenzoic acid) ); Ampicillin (o-aminobenzoic acid esters; methyl, menthyl, phenyl, benzyl, phenethyl, agar, terpine and cyclohexenyl esters); salicylate (Octyl, pentyl, phenyl, benzyl, menthyl, glyceryl, and dipropylene glycol esters); cinnamic acid derivatives (menthyl and benzyl), α-benzyl cinnamonitrile; cinnamylpyruvate Esters); diacid cinnamic acid derivatives (umbelliferone, methylumbelliferone, methylacetamylumbelliferone); trihydroxycinnamic acid derivatives (aescinate, methyl Aesculetin, daphsin, and the glucosides, aescin and daphsin); hydrocarbons (diphenylbutadiene, stilbene); dibenzylacetone and benzylacetophenone; 2-naphthol-3, sodium mono-acid and sodium salt of 2-napan-6,8-dipic acid); dinaphthyl naphthoic acid and its 98969.doc -22- 200536569 salt; Biphenyl Dixanthovate ((salt); I legulin derivative fluorenyl, 7-methyl, 3-phenyl); Diazole (2-gene bromoindazole, phenylbenzoxazole, methylnaphthalene Azole, various aryl benzothiazoles); quinine salts (bisulfate, sulfate, gaseous, oleate, and tannate); quinoline derivatives (8-hydroxyquinoline salt, 2-phenyl Quinoline); benzophenones substituted with hydroxy or methoxy; uric acid and vilouricacids; tannic acid and its derivatives (for example, hexaethyl ether);

(Butylcarbitol) (6-propylpiperidyl) ether; hydroquinone; benzophenones (hydroxybenzophenone, sulisbenzone), benzophenone, Phenylhydrazone resorcinol, 2,2 ', 4,4'-tetrahydrobenzophenone, 2,2, _dihydroxy_4,4, dimethoxybenzophenone, otaphenone ( 〇ctabenzone); 4-isopropylbiphenylmethylmethane; butylmethoxybiphenylmethylmethane; Etocrylene; and 4-isopropylbiphenylmethylmethane). Particularly useful are: 2-ethylhexyl p-methoxycinnamate, 4,4, -tert-butylmethoxybibenzylidenemethane, 2-hydroxy-4-methoxybenzophenone, dimethyl Octyl p-aminobenzoate, difluorenyl trioleate, 2,2-dihydroxymethoxydibenzophenamidine '4- [bis (hydroxypropyl)] aminobenzoic acid ethyl ester, 2-Cyano · 3,3-diphenylacrylic acid 2-ethylhexyl ester, salicylic acid 2-ethylhexyl ester, p-aminobenzoic acid glycerol acetate 'salicylic acid 3,3,5-trimethyl Cyclohexyl ester, methyl o-aminobenzoate, p-dimethylaminobenzoic acid or aminobenzoate, p-dimethylaminobenzoic acid 2-ethylhexyl ester, 2-phenylbenzo Imidazole-5_sulfonic acid, 2- (p-dimethylaminophenyl) -5-fluorenylbenzoxazole acid and mixtures thereof. Particularly preferred are such as ethylhexyl p-methoxycinnamate (commercially known as Parsol MCX®), Avobenzene (commercially available under the trade name Parsol 1789®), and Dermablock OS® (salix Acid octyl ester) and other materials. 98969.doc -23- 200536569 Organic sunscreens are used in an amount of about 0.00 to about 5% of the composition, preferably from about 0.5 to about 10%, and most preferably from about 1 to about 80 /. . If necessary, a preservative can also be incorporated into the cosmetic composition of the present invention to prevent the growth of potentially harmful microorganisms. A conventional preservative suitable for the composition of the present invention is an alkyl p-benzoate. Other preservatives commonly used recently include caprolactam derivatives, propionates and various quaternary ammonium compounds. Cosmetic chemists are familiar with suitable preservatives, and can choose preservatives according to customary methods.

Meets preservative screening test requirements and provides product stability. Particularly preferred preservatives are phenoxyethanol, methylparaben, glyoxybenzamide, sodium dehydroacetate and phenylethanol. Preservatives should be selected taking into account the application of the composition and possible incompatibilities between the preservative and other ingredients in the emulsion. The amount of the preservative is preferably 0.01% to 2% by weight of the composition. The composition of the invention may also contain vitamins. Examples of water-soluble vitamins include nicotinamide, vitamin I, vitamin β, vitamin c, and biotin. Available water-soluble vitamins include vitamins (retinol), vitamin A palmitate, ascorbic acid tetraisopalmitate, vitamins (tocopherol), vitamin e acetate, and DL-panthenol. The total amount of vitamins used in the composition of the present invention may be between 0.001% and 10% by weight of the composition, preferably from 0.01% to 1%, and most preferably from 0.1% to 0.5%. Peeling agents are an optional ingredient for another. Examples are alpha-menic acid and mesitylene and salts of these acids. The former includes the salts of glycolic acid, lactic acid, and pomelic acid. Salicylic acid is the representative of hydroxycarboxylic acid. These materials may be used in an amount of from about 0.10 / 0 to about 15/0 by weight of the composition. 98969.doc -24- 200536569: As needed, various herbal extracts can be incorporated into the composition of the present invention. ′, Examples are pomegranate, betula alba, green tea, chamomile, licorice extract and combinations thereof. These extracts may be water-soluble or water-insoluble, which are contained in each-hydrophilic or hydrophobic. Water and ethanol are the preferred extraction solvents. Except in operational and comparative real money or other clearly specified places, the numbers used in this specification to indicate the amount of material used shall be understood as modified by the word § 我 “约”. The term "comprising" does not mean limited to the following elements, and j is intended to cover unspecified elements that are functionally important or unimportant. The listed steps, elements, and options need not be exhaustive. When When the words "including" or "having" are used, these terms have an equivalent meaning to "compring" as defined above. The entire contents of all documents referred to herein (including all patents, patent applications, and printed publications) are incorporated herein by reference. The following examples will more fully illustrate the embodiments of the present invention. Unless otherwise stated, all parts, percentages and ratios referred to herein and in the scope of the accompanying patent application are by weight. Example 1 A series of formulations were studied to evaluate the optical properties contribution of Shixi oxygen elastomer, zinc oxide and taurine polymer. These are recorded in Table j below. 98969.doc -25-200536569 Table i Sample number (% by weight) Component INCI / Chemical name 1 2 3 4 5 6 7 Surfactant gel Tween 40® Polysorbate 40 1.62 1.62 1.62 1.62 1.62 1.62 1.62 Lanette® 16 Cetyl alcohol 1.55 1.55 1.55 1.55 1.55 1.55 1.55 Cutina® GMS glycerol monostearate 0.78 0.78 0.78 0.78 0.78 0.78 0.78 Emersol® 315 linoleic acid 0.10 0.10 0.10 0.10 0.10 0.10 0.10 Pristerene® 9559 stearic acid 0.25 0.25 0.25 0.25 0.25 0.25 0.25 Cholesterol NF Cholesterol 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Moisturizer / emollient glycerin 9.00 9.00 9.00 9.00 9.00 9.00 9.00 9.00 Sunscreen Dermablock® OS Ethyl Salicylate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Parsol® MCX Ethylhexyl methoxycinnamate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Oil phase 98969.doc -26- 200536569

Dow Coming 200 (50 cSt) Dimethyloxyl 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Dow Coming 245 Isopentasil 20.00 Dow Coming 5225C Formulation Aid 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Dow Coming 9045 Silicone Elastomer 20.00 20.00 20.00 20.00 20.00 20.00 Polymer Aristoflex® AVC Taurine copolymer 0.80 0.80 0.80 0.80 0.80 0.40 0.60 Granular Z-Cote® HP1 Dispersion (65% ZnO) Zinc oxide 3.08 3.08 3.08 3.08 3.08 3.08 Ganzpearl® GMP-0820 polymer Methyl Acrylate 0.50 0.50 0.50 0.50 0.50 0.50 Calendered mica mica 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Timiron® MP 111 Titanium dioxide-coated mica 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Water 53.12 53.12 56.20 53.62 53.62 53.52 53.32 Opaque optical measurement Property is an index of the degree of attenuation of the intensity of a transmitted beam perpendicular to a medium or film. The higher the degree of attenuation of the direct light beam, the stronger the opacity. 98969.doc -27- 200536569 The attenuation of the beam comes from two aspects: A) Part of the initial light is reflected back from the film / medium. This gives the film / medium a white / opaque appearance with strong hiding power. The use of pigment-grade Ti02 in a formulation will provide this effect ^ b) Part of the light deviates from the direct beam path control, but still passes through the film / medium. In fact, the film / vehicle is between transparent and translucent and produces a "blurred" image. Another term used to describe this phenomenon is soft focus. Procedure: Use a stretch rod to apply (or stretch) a 3-mil (76 2 micron) formulation film to a plastic top transparent sheet. The film was dried at room temperature for two hours. The coated top transparent sheet was removed and placed in a mstrument Systems angle spectrophotometer. The light source and the debt detector are arranged so that they are aligned in a line perpendicular to the coated transparent sheet. Turn on the light source (set to 209 MW-nm / cm2, which serves as a reference value for all light transmission intensity values reported in this article) and measure the light transmission intensity. Other measurements are performed by moving the debt detector away from the direct transmission normals 1G, 3G, 4G, and 5G degrees. This equivalent value shows the degree of soft-focus light scattering. —Product reflectance or “gloss” is determined in the same way as opacity / soft-focus light scattering, except that the position of the light source and sensor is different. The detector is located at% degrees on one side of the normal / vertical line, and the light source is located at 20 degrees on the other side. For degrees, the strength value can be compared with an uncoated top transparent sheet. The difference between these two values is the degree of attenuation or opacity. Results: The effect of certain components on the optical properties of these compositions was evaluated by testing formulations from which their components had been removed. The results are reported in Table ^. 98969.doc -28- 200536569 Table II Sample No. (W-nm / cm2) Transmission angle (degrees) 1 2 3 4 5 6 7 Acceptable transmission intensity (W-nm / cm2) 0 5.5M 10M 10M 5.1M 7.9M 10M 7.2M 4 to 7 MU 10 1.1M 1.0M 1.6M 1.1M 1.2M 1.1M 1.1M 1 to 2M 30 128K 98K 104K 143K 131K 110K 116K 120 to 140K 40 73K 56K 46K 80 K 71K 63K 61K 60 to 80 Κ 50 48K 37K 25K 52 K 45K 41K 45K 40 to 60 KK Reflection angle (degrees) 30 154K 160K 195K 160K 131K 160K 155K 140 to 170K Note: Values in bold indicate an acceptable range. Sample 1 is a preferred embodiment of the present invention. For this formulation, the light transmission intensity (opacity) and reflection intensity at various angles are within the range of parameter values required to achieve soft focus and brilliance effects. Cyclopentanol (Dow Corning 245) was used instead of Dox Corning Elastomer (Dow Corning 9045) in Sample 2. As a result, the transmitted light intensity exceeded the acceptable range at all four angles. Zinc oxide was omitted from sample 3. The light transmission intensity here also exceeds 4 acceptable ranges, which shows the necessity of zinc oxide to achieve soft focus. The removal of Ganzpearl® GMP-0820 consisting of polymethyl methacrylate beads in Sample 4 had virtually no effect on opacity. In sample 5, the calendered mica was removed as desired, showing a larger light transmittance, but the reflection intensity was zero. The light transmission intensity at the corners is beyond the acceptable range. In Sample 6, the amount of Aristoflex AVC® (taurine copolymer) was halved. As a result, 〇. The light transmission intensity values at the angles of 30 ° and 30 ° are outside the acceptable range, which indicates that the copolymer can affect 98969.doc -29- 200536569 and help achieve a soft focus effect. In Sample 7, Aristoflex AVC® was formulated in an amount between those of Samples 1 and 6, and this example further demonstrates the functional importance of the copolymer for soft focus effects. Example 2 In this example, we studied the effect of zinc oxide on titanium dioxide, which has a similar average particle size. The results are reported in Table IV.

Table III Sample number (% by weight) Component INCI / Chemical Name 8 9 10 11 Surfactant Gel Tween® 40 Polysorbate 40 1.62 1.62 1.62 1.62 Lanette® 16 Hexadecanol 1.55 1.55 1.55 1.55 Cutina® GMS Glycerin Monostearate 0.78 0.78 0.78 0.78 Emersol® 315 Linoleic acid 0.10 0.1 0.1 0.1 Pristerene® 9559 Stearic acid 0.25 0.25 0.25 0.25 Cholesterol NF Cholesterol 0.20 0.2 0.2 0.2 Moisturizer / emollient glycerin 9.00 9.0 9.0 9.0 Sunscreen Dermablock® OS Ethylhexyl Salicylate 2.00 2.0 2.0 2.0 Parsol® MCX Ethylhexyl Methoxycinnamate 4.00 4.0 4.0 4.0 Oil Phase Dow Coming 200 (50 cSt) Dimethicone 1.00 1.0 1.0 1.0 Dow Coming 245 Cyclopentasiloxane Dow Coming 5225C Formulation Aid 0.50 0.50 0.50 0.50 Dow Coming 9040 Silicone Elastomer 20.00 98969.doc -30- 200536569

Dow Coming 9045 Silicone Elastomer 20.00 20.00 20.00 Polymer Aristoflex® AVC Taurine copolymer 0.80 0.80 0.80 0.80 Soft Focus Z-Cote® HP1 Dispersion (65% ZnO) Zinc Oxide 3.08 Ti02 (UV 'Grade) Titanium Dioxide 3.08 1.5 0.4 Ganzpearl® GMP-0820 Polymethyl methacrylate 0.50 0.50 0.50 0.50 Calcined mica mica Timiron® MP 111 Titanium dioxide-coated mica 0.50 0.50 0.50 0.50 Water 53.12 53.12 54.7 55.80

Table IV Sample No. Light transmission intensity (MW-nm / cm2) at 0 degree angle 8 5.1 9 2.3 10 3.5 11 9.0 Based on a sample of equal weight 8 provides a transmission intensity that is within the acceptable range. By comparison, the titanium dioxide-prepared samples 9, 10, and 11 showed light transmission intensity values outside the acceptable range. Example 3 A series of experiments were performed to evaluate the soft focus effect of a number of different thickening polymers. These evaluated formulations are recorded in Table V. 98969.doc -31-200536569 Table v Sample number (% by weight) Component INCI / Chemical name 12 13 14 15 16 17 18 Surfactant gel Tween 40® Polysorbate 40 1.62 1.62 1.62 1.62 1.62 1.62 1.62 Lanette® 16 Cetyl alcohol 1.55 1.55 1.55 1.55 1.55 1.55 1.55 Cutina® GMS glycerol monostearate 0.78 0.78 0.78 0.78 0.78 0.78 0.78 0.78 Emersol® 315 linoleic acid 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 Pristerene® 9559 stearic acid 0.25 0.25 0.25 0.25 0.25 0.25 0.25 Cholesterol NF Cholesterol 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Moisturizer / Emollient Glycerin 9.00 9.00 9.00 9.00 9.00 9.00 9.00 9.00 Sunscreen Dermablock® OS Ethyl Salicylate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Parsol® MCX Ethylhexyl Methoxycinnamate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Oil phase Dow Coming 200 (50 cSt) dimethylsiloxy 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Dow Coming 245 cyclopentasiloxane 20.00 Dow Coming 5225C Formulation Aid 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Dow Coming 9045 Silicone Elastomer 20.00 20.00 20.00 20.00 2 0.00 20.00 Polymer Aristoflex® AVC Acrylic acid dimethyl ammonium taurate 0.80 98969.doc -32- 200536569

Carbopol ETD 2020 Polycarboxylate — 0.80 — — — — — Rhodopol 23 Xanthan Gum — — 0.80 — — — — Viscolam AT 100 / P Sodium Acrylate / Sodium Acrylic Acid Dimethytaurate 2.00 Salcare SC96 Quaternary Ammonium Salt Preservative 37 and Propylene 1.50 Natrosol Plus 330 CS Cetyl Hydroxyethyl Cellulose 0.80 Pemulen TR-1 Acrylic Acid Purpose / C10-30 Acrylic Acid Purpose 0.80 Granules Z-Cote® Dispersion (65% ZnO) Zinc oxide 3.08 3.08 3.08 3.08 3.08 3.08 3.08 3.08 Ganzpearl® GMP-0820 Polymethylmethacrylate 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Calendered mica mica 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Timiron® MP 111 titanium dioxide coated Covered mica 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Water 53.12 53.12 53.12 51.92 52.42 53.12 53.12 Samples 13, 16 and 18 are unstable, and their initial phases can be separated at 75 ° C (between oil and water) or cooled When showing separation. Therefore, unstable polymers include Carbomer, Salcare SC96®, and Pemulen TR-1. 98969.doc -33-200536569 Table ν Sample No. y —------- Normal Force @ 10,000 S · 1 (g) Stability of formulation 12 70.6 Stable 13 61.5 Unstable 14 33.5 Stable 15 77.0 Stable 16 76.4 Unstable 17 43.7 Stable 18 34.0 Unstable Samples 12, 14, 15 and 17 are stable when Aristoflex AVC®, Xanthan Gum, and Viscolam AT 100 / P are used. However, when xanthan gum (sample 14) was used, the light transmission intensity was outside the acceptable range. See Table VII. Viscolam AT® 100 / P (Sodium Acrylate / Sodium Acrylic Acid Dimethyl Taurine Copolymer) in Sample 15 showed better light transmission opacity and reflection intensity at soft focus at all angles And glory within the required parameter value range.

Table VII

Sample No. (W-nm / cm2) Transmission angle (degrees) 12 14 15 17 * Acceptable transmission intensity (W-nm / cm2) 0 5.5M 9.5M 5.1M 14.6M 4 to 7 Μ 10 1.1M 1.0 M 1.1M 1.2M 1 to 2 Μ 30 128K 107K 124K 84K 120 to 140 KK 40 73K 59K 68K 49K 60 to 80 KK 50 48K 39K 48K 34K Wide 40 to 60 KI Reflection angle (degrees) 30 T54K 169K 162K 151K 140 to 170 K Note · ^ Starred formulations can provide a non-uniform / non-compatible film. Values in bold indicate values outside the acceptable range of 0. 98969.doc -34-

Claims (1)

200536569 10. Scope of patent application: 1. A cosmetic composition comprising: (i) a crosslinked silicone elastomer; (ii) a zinc oxide or hafnium oxide having an average particle size of less than 300 nm; (i) a Taurine polymer; and Gv) a cosmetically acceptable carrier system. 2. The composition as claimed in claim 1, wherein the taurine polymer is an acryl dimethyl taurine and a polymer selected from the group consisting of styrene, acrylic acid, methyl propylene isL, ethylene gas, and acetic acid Vinyl ester, ethylene η-pylonolone, isoprene, vinyl alcohol, vinyl methyl ether, gas styrene, dialkylaminobenzyl ethylene, maleic acid, acrylamide, acrylamine Copolymers of monomers consisting of a mixture thereof. The composition is called the composition of claim 2, wherein the taurine copolymer is acrylene monomethyltaurine / vinylpyrrolidone copolymer. The composition of claim 1, further comprising a light-reflective inorganic flake-shaped particle having an average particle diameter of 10,000 to 30,000 nanometers. ρ The composition according to item 1, wherein the light-reflecting inorganic lamellar particles are from titanium dioxide-coated mica or bismuth oxychloride. 6. The composition of claim 1, further comprising a crystal structurant, the crystal and the "structural agent" are formed from a surfactant and a co-surfactant, wherein the 矣 χ 八 ^ surfactant and The relative weight ratio and material type of the co-surfactant are defined by an enthalpy, which is from 2 to 15 Joules / gram and measured by differential calorimetry. The composition of the month term 1, which has a normal force from +5 to +100 grams. 98969.doc 200536569 8. The composition according to claim 7, which has the normal force. 9. The claim! A combination of *, which further comprises from to 40. Poly (methyl methacrylate) hollow particles. 0% to 1%. : The composition of claim 2, further comprising a self-manufactured average (volume) particle diameter from 005 to 10,000, and a master of 10,000 to 100,000 nanometers. ,... N. The composition according to claim 1, which has-in 〇. Angular amount; transmission intensity of 4 to 7 MW-nm / cm2; one at 10. &Amp; Light transmission intensity of MW-nmW;-at 30. The angle is measured as the light transmission intensity from ⑽ to just KW-nm / cm2; one is measured as the light transmission intensity from 60 to 80 KW_nm / Cm2 at a 400 angle; and one is measured as 50. The angular measurement is a light transmission intensity of 40 to 60 KW-nm / cm2. 12. The composition as claimed in claim 1, wherein the composition has a value of 30. The angular measurement is a light transmission intensity of 140 to 170 KW-nm / cm2. 13. A cosmetic composition, comprising: (1) 0.01 to 30% by weight of the composition, a cross-linked sparoxane elastomer; (ii) accounting for ⑴ to "% by weight of the composition" Zinc oxide having an average particle size of less than 300 nanometers; (ill) a taurine polymer of 0.001 to 10% by weight of the composition; and (iv) —Cosmetically acceptable carrier system; and wherein the composition has a light transmission intensity of 4 to 7 MW-nm / cm2 when measured at an angle of 1 to 10. The angle is measured at 1 to 2 MW. -nm / cm2 transmission intensity; one at 30. Angle measurement is 120 to 14〇1 ^ -11111 / (^ transmission intensity; one at 40. Angle s: 60 to 80 KW-nm / cm2 And the transmission intensity at 50. The angle is measured at the transmission intensity of 40 to 60 KW-nm / cm2. 98969.doc 200536569 VII. Designated Representative Charts · (1) The designated representative maps in this case are: (none) (2) Brief description of the component symbols in this representative figure: φ 8. If there is a chemical formula in this case, please disclose the chemical formula that can best show the characteristics of the invention: 98969.doc