TW200504103A - Supported metallocene catalysts - Google Patents
Supported metallocene catalystsInfo
- Publication number
- TW200504103A TW200504103A TW093109750A TW93109750A TW200504103A TW 200504103 A TW200504103 A TW 200504103A TW 093109750 A TW093109750 A TW 093109750A TW 93109750 A TW93109750 A TW 93109750A TW 200504103 A TW200504103 A TW 200504103A
- Authority
- TW
- Taiwan
- Prior art keywords
- alumoxane
- support
- silica
- catalysts
- metallocene
- Prior art date
Links
- 239000012968 metallocene catalyst Substances 0.000 title abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 6
- 239000000377 silicon dioxide Substances 0.000 abstract 3
- 125000001424 substituent group Chemical group 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 abstract 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/412,372 US6855783B2 (en) | 2003-04-11 | 2003-04-11 | Supported metallocene catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200504103A true TW200504103A (en) | 2005-02-01 |
Family
ID=33131194
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW093109750A TW200504103A (en) | 2003-04-11 | 2004-04-08 | Supported metallocene catalysts |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6855783B2 (zh) |
| EP (1) | EP1613665A4 (zh) |
| JP (1) | JP2007524721A (zh) |
| KR (1) | KR20060006920A (zh) |
| CN (1) | CN1795211A (zh) |
| CA (1) | CA2521652A1 (zh) |
| TW (1) | TW200504103A (zh) |
| WO (1) | WO2004092225A1 (zh) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1988104B1 (en) * | 2003-03-28 | 2010-03-03 | Mitsui Chemicals, Inc. | Propylene copolymer, polypropylene composition, use thereof, transition metal compounds, and catalysts for olefin polymerization |
| US7667238B2 (en) * | 2003-04-15 | 2010-02-23 | Luminus Devices, Inc. | Light emitting devices for liquid crystal displays |
| EP1493759A1 (en) * | 2003-07-04 | 2005-01-05 | Total Petrochemicals Research Feluy | Polymerisation process |
| EP1496070A1 (en) * | 2003-07-09 | 2005-01-12 | Total Petrochemicals Research Feluy | A polyolefin having internal double bonds and a method for making the same |
| ATE369386T1 (de) * | 2003-10-07 | 2007-08-15 | Dow Global Technologies Inc | Polypropylenzusammensetzung für luftgekühlte blasfolien |
| EP1533102A1 (en) * | 2003-11-14 | 2005-05-25 | Total Petrochemicals Research Feluy | Polypropylene processing with reduced cycle time in injection-stretch-blow moulding. |
| US7220806B2 (en) * | 2005-04-29 | 2007-05-22 | Fina Technology, Inc. | Process for increasing ethylene incorporation into random copolymers |
| EP1734058A1 (en) * | 2005-06-13 | 2006-12-20 | Total Petrochemicals Research Feluy | Ethylene and alpha-olefins polymerisation catalyst system based on fluorenyl ligand |
| EP1762577A1 (en) * | 2005-09-02 | 2007-03-14 | Total Petrochemicals Research Feluy | Impact copolymer of propylene prepared in single reactor |
| JP4784279B2 (ja) * | 2005-11-17 | 2011-10-05 | 王子製紙株式会社 | コンデンサーフィルム |
| US20070299222A1 (en) * | 2006-04-04 | 2007-12-27 | Fina Technology, Inc. | Transition metal catalysts and formation thereof |
| US7683002B2 (en) * | 2006-04-04 | 2010-03-23 | Fina Technology, Inc. | Transition metal catalyst and formation thereof |
| US7514510B2 (en) * | 2006-07-25 | 2009-04-07 | Fina Technology, Inc. | Fluorenyl catalyst compositions and olefin polymerization process |
| KR100968704B1 (ko) * | 2006-12-01 | 2010-07-06 | 주식회사 엘지화학 | 페닐렌 브릿지를 가지는 전이 금속 촉매 화합물을 이용한올레핀 중합용 담지촉매, 이의 제조방법, 상기 올레핀중합용 담지촉매를 이용한 올레핀계 중합체의 제조방법, 및이에 의해 제조된 올레핀계 중합체 |
| CN101600743B (zh) * | 2007-01-18 | 2012-08-29 | 普瑞曼聚合物株式会社 | 应力耐久成型体用丙烯均聚物和包含该聚合物的组合物、以及由它们得到的应力耐久成型体 |
| US8299188B2 (en) * | 2007-05-18 | 2012-10-30 | Fina Technology, Inc. | Supported metallocene catalysts |
| US20080287619A1 (en) * | 2007-05-18 | 2008-11-20 | William Gauthier | Supported metallocene catalysts |
| EP2006011A1 (en) * | 2007-06-22 | 2008-12-24 | Total Petrochemicals Research Feluy | Process for reducing carbon monoxide in olefin-containing hydrocarbon feedstocks |
| EP2006012A1 (en) * | 2007-06-22 | 2008-12-24 | Total Petrochemicals Research Feluy | Process for the polymerisation of olefins |
| KR101084677B1 (ko) * | 2008-05-14 | 2011-11-22 | 주식회사 엘지화학 | 올레핀 중합체의 제조방법 |
| US8288495B2 (en) * | 2009-01-27 | 2012-10-16 | Mitsui Chemicals, Inc. | Propylene homopolymer for capacitors |
| JP5906702B2 (ja) * | 2010-12-14 | 2016-04-20 | 日本ポリエチレン株式会社 | オレフィン重合触媒の製造方法、オレフィン重合触媒およびオレフィンの重合方法 |
| CN105658686A (zh) * | 2013-06-24 | 2016-06-08 | 沙特基础工业公司 | 基于钛酸化的铬的催化剂以制备高密度聚乙烯 |
| US10072107B2 (en) * | 2013-12-06 | 2018-09-11 | Total Research & Technology Feluy | Long chain branched polypropylene |
| JP6199731B2 (ja) * | 2013-12-26 | 2017-09-20 | 旭化成株式会社 | ポリエチレンの製造方法 |
| US9738779B2 (en) * | 2015-06-05 | 2017-08-22 | Exxonmobil Chemical Patents Inc. | Heterophasic copolymers and sequential polymerization |
| US10329360B2 (en) | 2015-06-05 | 2019-06-25 | Exxonmobil Chemical Patents Inc. | Catalyst system comprising supported alumoxane and unsupported alumoxane particles |
| US10280235B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers |
| EP3303423A1 (en) | 2015-06-05 | 2018-04-11 | ExxonMobil Chemical Patents Inc. | Single reactor production of polymers in gas or slurry phase |
| US9809664B2 (en) * | 2015-06-05 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Bimodal propylene polymers and sequential polymerization |
| US10077325B2 (en) * | 2015-06-05 | 2018-09-18 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
| US10294316B2 (en) * | 2015-06-05 | 2019-05-21 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
| US9920176B2 (en) * | 2015-06-05 | 2018-03-20 | Exxonmobil Chemical Patents Inc. | Single site catalyst supportation |
| US9725537B2 (en) * | 2015-06-05 | 2017-08-08 | Exxonmobil Chemical Patents Inc. | High activity catalyst supportation |
| US9725569B2 (en) | 2015-06-05 | 2017-08-08 | Exxonmobil Chemical Patents Inc. | Porous propylene polymers |
| US10280233B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst systems and methods of making and using the same |
| EP3303418A4 (en) * | 2015-06-05 | 2018-06-20 | ExxonMobil Chemical Patents Inc. | Bimodal propylene polymers and sequential polymerization |
| US10723821B2 (en) | 2015-06-05 | 2020-07-28 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems for polymerization |
| WO2016196339A2 (en) | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Production of heterophasic polymers in gas or slurry phase |
| WO2017155211A1 (ko) * | 2016-03-11 | 2017-09-14 | 주식회사 엘지화학 | 에틸렌 슬러리 중합용 혼성 담지 촉매 시스템 및 이를 이용한 에틸렌 중합체의 제조 방법 |
| KR102064990B1 (ko) | 2016-03-11 | 2020-03-02 | 주식회사 엘지화학 | 에틸렌 슬러리 중합용 혼성 담지 촉매 시스템 및 이를 이용한 에틸렌 중합체의 제조 방법 |
| WO2017204830A1 (en) | 2016-05-27 | 2017-11-30 | Exxonmobil Chemical Patents, Inc. | Metallocene catalyst compositions and polymerization process therewith |
| WO2018212852A1 (en) | 2017-05-19 | 2018-11-22 | Exxonmobil Chemical Patents Inc. | Catalyst systems and polymerization processes for using the same |
| CN117756967A (zh) * | 2023-12-21 | 2024-03-26 | 上海化工研究院有限公司 | 一种硅桥连茂金属催化剂及其应用 |
| WO2025157819A1 (en) * | 2024-01-22 | 2025-07-31 | Sabic Global Technologies B.V. | Catalyst system for multi-stage olefin polymerisation |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3007725A1 (de) | 1980-02-29 | 1981-09-17 | Hansjörg Prof. Dr. 2000 Hamburg Sinn | Verfahren zur herstellung von polyethylen, polypropylen und copolymeren |
| US4522982A (en) | 1983-06-06 | 1985-06-11 | Exxon Research & Engineering Co. | Isotactic-stereoblock polymers of alpha-olefins and process for producing the same |
| US4767735A (en) | 1987-02-02 | 1988-08-30 | Cosden Technology, Inc. | Catalyst pretreatment process |
| US4794096A (en) | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
| US4892851A (en) | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US5155080A (en) | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US5036034A (en) | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
| US5146228A (en) | 1990-01-24 | 1992-09-08 | The Johns Hopkins University | Coherent correlation addition for increasing match information in scene matching navigation systems |
| US5451649A (en) | 1991-05-09 | 1995-09-19 | Phillips Petroleum Company | Organometallic fluorenyl compounds, preparation, and use |
| US5416228A (en) | 1991-10-07 | 1995-05-16 | Fina Technology, Inc. | Process and catalyst for producing isotactic polyolefins |
| US5459117A (en) | 1993-08-27 | 1995-10-17 | Ewen; John A. | Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers |
| US5945365A (en) | 1996-05-20 | 1999-08-31 | Fina Technology, Inc. | Stereorigid bis-fluorenyl metallocenes |
| US5968864A (en) | 1996-12-20 | 1999-10-19 | Fina Technology, Inc. | Catalyst efficiency for supported metallocene catalyst |
| EP0881236A1 (en) * | 1997-05-26 | 1998-12-02 | Fina Research S.A. | Metallocene catalyst component for use in producing isotactic polyolefins |
| US6515086B1 (en) * | 1999-02-19 | 2003-02-04 | Fina Research, S.A. | Polyolefin production |
| US6414095B1 (en) | 2000-06-30 | 2002-07-02 | Exxon Mobil Chemical Patents Inc. | Metallocene compositions |
| US6777366B2 (en) | 2001-02-13 | 2004-08-17 | Fina Technology, Inc. | Method for the preparation of metallocene catalysts |
-
2003
- 2003-04-11 US US10/412,372 patent/US6855783B2/en not_active Expired - Lifetime
-
2004
- 2004-04-07 KR KR1020057019362A patent/KR20060006920A/ko not_active Withdrawn
- 2004-04-07 EP EP04759233A patent/EP1613665A4/en not_active Withdrawn
- 2004-04-07 CN CNA2004800145560A patent/CN1795211A/zh active Pending
- 2004-04-07 CA CA002521652A patent/CA2521652A1/en not_active Abandoned
- 2004-04-07 JP JP2006509787A patent/JP2007524721A/ja active Pending
- 2004-04-07 WO PCT/US2004/010725 patent/WO2004092225A1/en not_active Ceased
- 2004-04-08 TW TW093109750A patent/TW200504103A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004092225A1 (en) | 2004-10-28 |
| EP1613665A1 (en) | 2006-01-11 |
| CA2521652A1 (en) | 2004-10-28 |
| CN1795211A (zh) | 2006-06-28 |
| US6855783B2 (en) | 2005-02-15 |
| US20040204310A1 (en) | 2004-10-14 |
| EP1613665A4 (en) | 2011-08-03 |
| JP2007524721A (ja) | 2007-08-30 |
| KR20060006920A (ko) | 2006-01-20 |
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