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TW200413836A - Method for repairing mask by using multiple phase steps - Google Patents

Method for repairing mask by using multiple phase steps Download PDF

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Publication number
TW200413836A
TW200413836A TW92101644A TW92101644A TW200413836A TW 200413836 A TW200413836 A TW 200413836A TW 92101644 A TW92101644 A TW 92101644A TW 92101644 A TW92101644 A TW 92101644A TW 200413836 A TW200413836 A TW 200413836A
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light
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TW92101644A
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TW552470B (en
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Cheng-Ming Lin
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Taiwan Semiconductor Mfg
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  • Preparing Plates And Mask In Photomechanical Process (AREA)

Abstract

A method for repairing a mask by using multiple phase steps is disclosed. The method forms multiple phase steps beside a pit defect on a transparent substrate of a mask by removing part of the transparent substrate. With the multiple phase steps, the light destructive interference on the edge of the pit defect can be decreased, and the light intensity of the pit defect can be increased, thereby obtaining a purpose of effectively repairing the pit defect of the mask.

Description

200413836200413836

發明所屬之技術領域: 一種光罩修補方法’特別是有關於-種利 重相階Multlple Phase Steps)的方式來修補透光基 材上之凹陷(Pit)缺陷的方法。 先前技術: 一般,光罩之製造係先在由例如石英之平坦透光的玻璃絕 緣材質所構成之基材上覆蓋厚度約數百A之不透光薄膜,例 如鉻(Cr)。接著,形成一層光阻覆蓋此不透光薄膜,並以 例如電子束之尚解析度的曝光技術進行曝光,而將所需之 積體電路元件各層的圖案轉移至光阻上。再經顯影後,而聲 在此光阻中形成所需之電路圖案。然後,利用蝕刻方式將 此圖案轉移到上述之不透光薄膜,而在光罩上形成透光區 域與不透光區域。待所需之電路圖案轉移至不透光薄膜 後,甚至可另外在鉻膜的表面再加上一層厚度約2〇〇A的二 氧化鉻膜,以防止金屬鉻膜在曝光時產生反射而影響曰後 曝光步驟的進行。 在光罩的製造過程中,或者在光罩使用期間,極可能在光 罩上形成缺陷。因此,在利用光罩進行圖案複製時,通常 需先對光罩上之缺陷進行修補動作。一般之光罩缺陷大致籲 上有兩種,一種為透光缺陷(Transparent Defect),其產 生原因例如由於金屬鉻膜或相移層形成圖案之誤差,導致 原本應為不透光區的部分形成透光區。另一種則為不透光 缺陷(Opaque Defect),其發生原因例如由於塗佈過多的金 屬鉻膜而使光罩上原本應為透光區的部分形成不透光區所The technical field to which the invention belongs: A photomask repair method ', in particular, a method for repairing Pit defects on a light-transmitting substrate in a manner that benefits from Multlple Phase Steps. Prior art: Generally, a mask is manufactured by first covering a substrate made of a flat and transparent glass insulating material such as quartz with an opaque film having a thickness of about several hundred A, such as chromium (Cr). Next, a layer of photoresist is formed to cover the opaque film, and exposure is performed using, for example, an exposure technique with an electron beam resolution, and the pattern of each layer of the integrated circuit element is transferred to the photoresist. After development, the desired circuit pattern is formed in the photoresist. Then, the pattern is transferred to the above-mentioned opaque film by an etching method, and a light-transmitting area and an opaque area are formed on the photomask. After the required circuit pattern is transferred to the opaque film, an additional layer of chromium dioxide film with a thickness of about 200 A can be added to the surface of the chromium film to prevent the reflection of the metal chromium film during exposure. The post exposure step is performed. During the manufacture of the reticle, or during the use of the reticle, it is highly likely that defects will form on the reticle. Therefore, when using a photomask for pattern replication, it is usually necessary to perform repairs on defects on the photomask. There are generally two types of mask defects. One is Transparent Defect, which is caused by, for example, the formation of a pattern that is supposed to be an opaque area due to an error in the pattern formed by the metal chromium film or the phase shift layer. Light transmission area. The other is Opaque Defect, which is caused by, for example, excessive coating of the metal chromium film, so that the portion of the photomask that should be the light-transmitting area forms an opaque area.

然而’除了以 基材的損傷, 產生凹陷缺陷 其高度較未受 與未受損之正 與透光基材之 與正常表面之 進而產生相移 光率下降,更 破壞性干擾。 後,會成像在 案轉移品質。 上所述之 例如雷射 。此種位 損之透光 常基材表 正常表面 路徑不一 。因此, 由於相移 如此一來 晶圓上之 缺陷型 修補時 於光罩 基材的 面間產 間的高 致,而 凹陷缺 的產生 ,透光 光阻層 式以外,光 所引發之透 之透光基材 表面低,而 生高度落差 度差,使得 引發透射光 陷不僅會造 而在凹陷缺 基材上之凹 中,嚴重影 罩還可能因透光 光基材傷害,而 上的凹陷缺陷, 導致在凹陷缺陷 。由於凹陷缺陷 光通過凹陷缺陷 之相位的改變, 成透光基材之透 陷之邊緣造成光 陷缺陷經曝光 響微影製程之圖 目刖,大都使用氫氧化鈉(Na〇H)來修補光罩之透光基材上 的凹缺陷’其係將光罩浸入氫氧化鈉溶液中,利用氫氧 化納來腐钱透光基材,藉以移除凹陷缺陷,或者降低凹陷 缺陷與未受損之透光基材表面的高度差,而達到修補凹陷 缺陷之目的。然而,當凹陷缺陷的深度過大時,氫氧化鈉 溶液就無法有效移除透光基材上之凹陷缺陷。此時,凹陷 缺陷邊緣之相移現象仍舊存在,同樣會造成凹陷缺陷區域 之光強度下降。 舉例而言,當光罩之透光基材上的凹陷缺陷產生最糟的 度相移時,若凹陷缺陷之關鍵尺寸小於1· 2微米(em),可 透過此光罩進行曝光步驟後,會在晶圓之光阻層上產生一However, in addition to the damage to the substrate, pitting defects are generated. The height is lower than that of the untreated and undamaged positive and transparent substrates and the normal surface, which causes a phase shift. Later, the quality will be transferred on file. For example, the laser. This kind of loss of light transmission of the normal substrate table normal surface path is different. Therefore, due to the phase shift, the defect-type repair on the wafer is highly effective between the surfaces of the photomask substrate, and the generation of depressions is not the type of the light-transmitting photoresist layer. The surface of the light-transmitting substrate is low, and the height difference is poor, so that the induced light trap will not only create a depression in the recessed substrate, but also a serious shadow mask may be damaged by the light-transmitting substrate, and the upper depression Defects that lead to pitting defects. Due to the change of the phase of the recessed defect light through the recessed defect, the trapped edge of the light-transmitting substrate causes the trapped defect to pass through the photolithography process. Most of them use sodium hydroxide (NaOH) to repair the light. Concave defects on the light-transmitting substrate of the mask 'It is to immerse the photomask in a sodium hydroxide solution, and use sodium hydroxide to rot the light-transmitting substrate to remove the pitting defects or reduce the pitting defects and undamaged The height difference on the surface of the light-transmitting substrate can achieve the purpose of repairing the recessed defects. However, when the depth of the recessed defects is too large, the sodium hydroxide solution cannot effectively remove the recessed defects on the light-transmitting substrate. At this time, the phase shift phenomenon at the edge of the recessed defect still exists, which will also cause the light intensity of the recessed defect area to decrease. For example, when the recessed defects on the transparent substrate of the photomask produce the worst phase shift, if the critical size of the recessed defects is less than 1.2 micrometers (em), after the exposure step can be performed through this photomask, Will produce a photoresist layer on the wafer

200413836200413836

條影像線;若凹陷缺陷之關鍵尺寸大於丨· 8微米,則透過此 光罩進行#光步料,可能會在晶圓之光阻層上產生兩條 影像線。如此一來,會導致微影製程之可靠产降低。 鑒於上述習知利用氫氧化鈉溶液來進行光罩之透光基材上 的凹陷缺陷的修補時,較深之凹陷無法有效地去除,而仍 會在透光基材之凹陷缺陷的邊緣產生光破壞性干擾,且難 以將凹陷缺陷區域之光強度提升至一定強度,進而無法有 效修補光罩之透光基材上的凹陷缺陷。 因此,本發明的主要目的之一就是在提供一種光罩之修補 方法,其係利用階梯狀之多重相位階,來減輕光罩之透光 基材上凹陷缺陷之邊緣與透光基材之無缺陷表面間的相位 差所造成之光破壞性干擾。如此一來,可有效提高凹陷缺 陷之光強度。 本發明之再一目的就是在提供一種利用多重相階之方式來 修補光罩之透光基材上的凹陷缺陷,其係去除凹陷缺陷周 圍之部分的透光基材,而與未經去除之透光基材以及凹陷 缺陷形成多重相位階。因此,可有效減輕凹陷缺陷邊緣之 相位差效應,並提高凹陷缺陷之光強度,而使凹陷缺陷難 以成像在晶圓之光阻上。 根據以上所述之目的,本發明更提供了一種多重相階之光 罩修補方法,其令上述之光罩至少包括一透光基材以及一 凹陷缺陷位於此透光基材之一表面上,且此透光基材之表 面具有一第一相位,而本發明之多重相階之光罩修補方法 200413836 五、發明說明(4) 至少包括下列步驟:測量透光基材上之凹陷缺陷的一第二 相位;以及去除上述之凹陷缺陷周圍之透光基材的一部 分,藉以在此透光基材中形成具有複數階層之一階梯狀凹 槽,其中每二個相鄰之階層間具有一預設相位差,且緊鄰 上述之凹陷缺陷之階層與此凹陷缺陷之間同樣具有此預設 相位差。此外,在這些階層中,其相位係從上述之凹陷缺 陷之第二相位朝透光基材之表面的第一相位遞減。 製作上述之階梯狀凹槽的每一個階層時,係利用微影以及 蝕刻製程分別定義凹陷缺陷周圍之透光基材而形成。其 中,每一個階層之高度係取決於此階層之相位,且在本發 明中,每二個相鄰之階層間之預設相位差較佳是小於6 〇 度,更佳則可為4 5度。此外,階梯狀凹槽之階層數量係取 決於透卑基材之表面與凹陷缺陷間之相位差以及所選定之 預設相位差。 藉由去除凹陷缺陷周圍之一部分的透光基材,可在透光基 材表面與凹陷缺陷之間形成相位階。因此,可以遞減的方 式緩和透光基材表面與凹陷缺陷間之相位差,而可減輕透 光基材表面與凹陷缺陷邊緣之光破壞性干擾,提升凹陷缺 1¾之光強度,進而達到修補透光基材之凹陷缺陷的目的。 實施方式: 本發明揭露一種多重相階之光罩修補方法,其係在光罩之 透光基材上的凹陷缺陷與周圍之無缺陷表面間形成階梯狀 相位,以減輕凹陷缺陷之邊緣的光干擾,提升凹陷缺陷之 光強度’而有效修補光罩之透光基材上的凹陷缺陷,進而Image lines; if the critical size of the recessed defect is greater than 丨 · 8 microns, #light stepping through this mask may result in two image lines on the photoresist layer of the wafer. As a result, the reliability of the lithography process will be reduced. In view of the above, when using the sodium hydroxide solution to repair the recessed defects on the light-transmitting substrate of the photomask, deeper recesses cannot be effectively removed, but light will still be generated on the edges of the recessed defects of the light-transmitting substrate. Destructive interference, and it is difficult to increase the light intensity of the recessed defect area to a certain intensity, so that the recessed defect on the transparent substrate of the photomask cannot be effectively repaired. Therefore, one of the main objects of the present invention is to provide a method for repairing a photomask, which uses step-like multiple phase steps to reduce the edges of the recessed defects on the transparent substrate of the photomask and the absence of the transparent substrate. Optically destructive interference caused by phase differences between defective surfaces. In this way, the light intensity of the depression can be effectively improved. Another object of the present invention is to provide a method for repairing a recessed defect on a light-transmitting substrate of a photomask by using multiple phase steps. The transparent substrate and the recessed defects form multiple phase steps. Therefore, the phase difference effect at the edges of the recessed defects can be effectively reduced, and the light intensity of the recessed defects can be improved, making it difficult to image the recessed defects on the photoresist of the wafer. According to the above-mentioned object, the present invention further provides a multi-phase step mask repair method, which enables the above-mentioned mask to include at least a light-transmitting substrate and a recess defect on one surface of the light-transmitting substrate. Moreover, the surface of the light-transmitting substrate has a first phase, and the multi-phase step mask repair method of the present invention 200413836 V. Description of the invention (4) At least includes the following steps: A second phase; and removing a portion of the light-transmitting substrate around the above-mentioned recessed defects, thereby forming a stepped groove having a plurality of layers in the light-transmitting substrate, wherein a pre- It is assumed that a phase difference is provided, and a layer immediately adjacent to the above-mentioned depression defect also has the preset phase difference between the depression defect and the depression defect. In addition, in these layers, the phase is gradually decreased from the second phase of the above-mentioned depressions to the first phase of the surface of the light-transmitting substrate. When making each step of the stepped groove described above, it is formed by using a photolithography and an etching process to define a light-transmitting substrate around a recessed defect, respectively. Among them, the height of each layer depends on the phase of the layer, and in the present invention, the preset phase difference between two adjacent layers is preferably less than 60 degrees, and more preferably 45 degrees. In addition, the number of levels of the stepped grooves depends on the phase difference between the surface of the transparent substrate and the recessed defect and the selected predetermined phase difference. By removing a part of the light-transmitting substrate around the recessed defect, a phase step can be formed between the surface of the light-transmitting substrate and the recessed defect. Therefore, the phase difference between the surface of the light-transmitting substrate and the recessed defects can be reduced in a decreasing manner, and the destructive interference of light between the surface of the light-transmitting substrate and the edges of the recessed defects can be reduced, and the light intensity of the recessed defects can be increased to achieve repair Purpose of pitting defects in light substrates. Embodiments: The present invention discloses a mask repair method with multiple phase steps, which forms a stepped phase between a recessed defect on a light-transmitting substrate of the mask and a surrounding non-defective surface to reduce light at the edges of the recessed defect. Interference, increase the light intensity of the recessed defects' and effectively repair the recessed defects on the transparent substrate of the photomask, and

200413836 五、發明說明(5) 達到改善微影製程之可靠度的目的。為了使本發明之敘述 更加詳盡與完備’可參照下列描述並配合fla圖至第6圖之 圖示0 β 請參照第la圖以及第lb圖,第la圖係繪示光罩之具有凹陷 缺陷的透光基材的上視圖,且第lb圖係繪示沿第&圖之『一 I剖面線所獲得之剖面圖。光罩1 〇 〇至少包括透光基材 102 ’其中此透光基材之材料可例如為石英等可透光玻璃材 質。在此透光基材102上具有凹陷缺陷1〇4,由第ib圖可 知’凹陷缺陷104與透光基材102之表面1〇3具有高度1〇5的 差距。 進行此透光基材102上之凹陷缺陷104的修補時,請一併參 照第2圖至第5圖’第2圖至第5圖係纷示本發明之一較佳實 施例之修補光罩之透光基材上的凹陷缺陷的製程剖面圖。 利用多重相階來修補此凹陷缺陷1 0 4時,首先假設透光基材 102之表面103的相位為〇度,再以透光基材1〇2之表面103的 相位為基準,測量凹陷缺陷1 〇 4之相位。待測得凹陷缺陷 104之相位後,進行計算步驟,將所測得之凹陷缺陷1〇4的 相位減去透光基材1 0 2之表面1 0 3的相位,而獲得相位差, 再選擇兩相鄰之相階的預定相位差。其中,亦可先選擇兩 相鄰之相階的預定相位差,再進行凹陷缺陷1 〇 4之相位的量 測以及凹陷缺陷104與透光基材102之表面103的相位差計 算,本發明並不在此限。在本發明中,兩相鄰之相階的預 定相位差較佳是小於60度,可例如為45度。然後,將所計 算出之凹陷缺陷104與透光基材102之表面103的相位差除以200413836 V. Description of the invention (5) The purpose of improving the reliability of the lithography process is achieved. In order to make the description of the present invention more detailed and complete, you can refer to the following description and cooperate with the diagrams of the fla chart to FIG. 6. 0 β Please refer to FIG. 1 and FIG. 1b, which shows that the photomask has a concave defect. A top view of the light-transmitting substrate, and FIG. 1b is a cross-sectional view obtained along the line “-I” of the & The photomask 100 includes at least a light-transmitting substrate 102 ', wherein the material of the light-transmitting substrate may be a light-transmissive glass material such as quartz. The light-transmitting substrate 102 has a recessed defect 104, and it can be seen from FIG. Ib that the 'dent-defect 104' and the surface 103 of the light-transmitting substrate 102 have a gap of 105. When repairing the recessed defect 104 on the light-transmitting substrate 102, please refer to FIG. 2 to FIG. 5 together. FIG. 2 to FIG. 5 are repair masks showing a preferred embodiment of the present invention. Process cross-sectional view of a recessed defect on a transparent substrate. When using multiple phase steps to repair this recessed defect 104, the phase of the surface 103 of the transparent substrate 102 is assumed to be 0 degrees, and then the phase of the surface 103 of the transparent substrate 102 is used as a reference to measure the recessed defect. 1 〇4 phase. After the phase of the recessed defect 104 is measured, a calculation step is performed, and the phase of the measured recessed defect 104 is subtracted from the phase of the surface 1 0 3 of the transparent substrate 102 to obtain a phase difference, and then selected. A predetermined phase difference between two adjacent phases. Among them, a predetermined phase difference between two adjacent phase steps may be selected first, and then the measurement of the phase of the recessed defect 104 and the calculation of the phase difference between the recessed defect 104 and the surface 103 of the transparent substrate 102 may be performed. Not in this limit. In the present invention, the predetermined phase difference between two adjacent phase steps is preferably less than 60 degrees, and may be, for example, 45 degrees. Then, the calculated phase difference between the recessed defect 104 and the surface 103 of the transparent substrate 102 is divided by

第9頁 200413836 五、發明說明(6) 所選定之兩相鄰相階的預定相位差後,將所得到之數值減 掉1,即可獲得相階之數量。 舉例而言,若所測得之凹陷缺陷1 〇 4的相位為1 8 0度,曝光 光線之波長為248公尺,凹陷缺陷1〇4與透光基材102之表面 103的高度差距高度1〇5為238.5奈米(nm),且兩相鄰相階的 預定相位差為45度時,凹陷缺陷1〇4與透光基材102之表面 1 0 3的相位差為1 8 0度減去〇度而得到1 8 〇度的相位差。將相 位差180度除以預定相位差45度,得到數值4,此時,以數 值4減掉1,所得到之數值3即代表相階之數量,也就是說, 需在介於凹陷缺陷104與透光基材1〇2之表面1〇3間的透光基 材102中額外加入3個相階,如第5圖所示之階層1〇8、階層 112、以及階層116。而由於介於凹陷缺陷1〇4與透光基材 102之表:面103間額外加入3個相階,因此凹陷缺陷丨〇4與透 光基材102之表面103間的180度相位差共由4個相位落差所 分攤,即第5圖所示之凹陷缺陷1〇4與階層1〇8之間、階層 108與階層112之間、階層112與階層116之間、以及階層116 與表面130之間。因此,兩相鄰之階層的高度差為凹陷缺陷 104與表面^103之高度差距238· 5奈米除以4,而得到兩相鄰 之階層的咼度差約為5 9 · 6奈米。此時即可依所計算出來之 兩相鄰之階層的高度差以及階層數量在透光基材1〇2中製作 多重相階。 請一併參照第lb圖以及第2圖,首先以例如塗佈(c〇atin 的方式形成光阻層1〇6覆蓋在第11}圖之透光基材1〇2以及 陷缺陷UH上,再利例如光曝光方式、離子束(⑹Page 9 200413836 V. Description of the invention (6) After selecting the predetermined phase difference between two adjacent phase steps, subtract the value obtained by 1 to obtain the number of phase steps. For example, if the measured phase of the recessed defect 104 is 180 degrees, the wavelength of the exposure light is 248 meters, and the height difference between the recessed defect 104 and the surface 103 of the transparent substrate 102 is 1 〇5 is 238.5 nanometers (nm), and the predetermined phase difference between two adjacent phase steps is 45 degrees, the phase difference between the recessed defect 104 and the surface 103 of the transparent substrate 102 is 180 degrees minus A degree difference of 180 degrees is obtained by removing 0 degrees. Divide the phase difference of 180 degrees by the predetermined phase difference of 45 degrees to get the value 4. At this time, subtract 1 from the value 4, and the obtained value 3 represents the number of phase orders, that is, it needs to be between the recessed defect 104 The light-transmitting substrate 102 between the surface 10 and the surface 10 of the light-transmitting substrate 102 is additionally provided with three phase steps, as shown in FIG. 5, a layer 108, a layer 112, and a layer 116. Since 3 additional phase steps are added between the concave defect 104 and the surface 103 of the light-transmitting substrate 102, the 180-degree phase difference between the concave defect 104 and the surface 103 of the light-transmitting substrate 102 is common. It is shared by 4 phase differences, that is, the depression defects 104 and 108 as shown in FIG. 5, between the level 108 and the level 112, between the level 112 and the level 116, and between the level 116 and the surface 130. between. Therefore, the difference in height between two adjacent layers is the height difference between the recessed defect 104 and the surface ^ 103 by 2385 nm divided by 4, and the difference in the degrees between the two adjacent layers is approximately 59.6 nm. At this time, multiple phase steps can be made in the transparent substrate 10 according to the calculated height difference between two adjacent layers and the number of layers. Please refer to FIG. 1b and FIG. 2 together. First, for example, a photoresist layer 10 is formed by coating (c0atin) to cover the light-transmitting substrate 102 and the defect UH in FIG. 11}. For example, light exposure methods, ion beams (⑹

五、發明說明(7) 曝光方式、4、胃, #,難^ 子束(ara)曝光方式進行光阻層106之曝 ^ ^以將階層1〇8之圖案轉移至光阻 方式去除部分之光阻細,而將階二之; ΗΠ。轉移至光阻層106中,並暴露出部分之表面 後,利用剩餘之光阻層1〇6為罩幕,以例如蝕刻的 & I® 卩分之透光基材102,而在緊鄰凹陷缺陷104處形 ,如第2圖所示。其中,階層108與凹陷缺陷之高 ^约為59· 6奈米,而使得階層1〇8與凹陷缺陷之相位差為 1 θ如同先前所計算出之數值。此外,上述之透光基材 # $ 7刻可採用例如電漿之乾式蝕刻(Dry Etchind方式 離子束(F〇CUS I〇n Beani ;F〖B)的方式進行。完成階 ^ 8後,即可將剩下之光阻層1〇6予以剝除,而暴露出透 ^ 土材102之表面103、凹陷缺陷1〇4、以及所形成之階層 10 8 ° 接著,可同樣利用塗佈的方式形成光阻層11()覆蓋在透光基 材1〇2之表面1〇3、凹陷缺陷1〇4、以及階層1〇8上。再以例 如光曝光方式、離子束曝光方式、或者電子束曝光方式對 光阻層110進行曝光,而將階層112之圖案轉移至光阻層11〇 ^。之後’利用例如顯影的方式,去除部分之光阻層丨i 〇, 藉以將階層112之圖案轉移至光阻層11()中,並暴露出透光 基材102之表面1〇3的一部分。再利用其餘之光阻層11〇為罩 幕’並藉由例如蝕刻的方式去除部分之透光基材丨〇 2,藉以 在階層108周圍形成階層112,如第3圖所示。其中,階層 11 2與階層1 〇 8之高度差同樣約為5 9 · 6奈米,亦使得階層112 200413836 五、發明說明(8) 與階層108之相位差為45度,如同先前所計算出之數值。如 同上述’钱刻透光基材丨〇 2時,可選用例如運用電漿之乾式 姓刻技術或聚焦離子束技術進行。待階層丨丨2形成後,可將 剩餘之光阻層11〇剝除,而暴露出透光基材1〇2之表面1〇3、 凹陷缺陷104、階層1〇8、以及階層112。 階層11 2完成後’同樣可藉由例如塗佈的方式形成光阻層 114覆蓋在透光基材1〇2之表面1〇3、凹陷缺陷1〇4、階層 108、以及階層1丨2上。並利用例如光曝光技術、離子束曝 光技術、或者是電子束曝光技術曝光光阻層114,將階層 11 6之圖案轉移至光阻層i丨4上。再利用例如顯影技術,移 除部分之光阻層114,以將階層116之圖案轉移至光阻層114 中,而暴露出牝部分之光阻層114下方之透光基材1〇2的表 面1 03。:此時,即可利用其餘之光阻層丨丨4作為罩幕,以例 如蝕刻的方式去除部分之透光基材1〇2,而在階層丨12周圍 形成階層>11 6 ’如第4圖所示之結構。同樣地,階層丨丨6與階 層11 2之同度差亦約為5 9 · 6奈米,以使得階層丨丨6與階層丨i 2 之相位差為45度,如同先前所計算出之數值。其中,可選 用例如乾式蝕刻技術或聚焦離子束技術來進行透光基材1〇2 之蝕刻,而乾式蝕刻技術可利用電漿來進行。 值得注意的是,上述在去除凹陷缺陷1〇4周圍之透光基材 ’亦可不須塗佈光阻,而可直接利用 具有準確疋位此力之蝕刻技術來製作各個階層,本發明之 相階的形成並不限於以上所述之方法。 然後,可剝除剩餘之光阻層114,並將透光基材⑽之表面V. Description of the invention (7) Exposure method, 4, stomach, #, difficult ^ Exposure of the photoresist layer 106 in the sub-beam (ara) exposure method ^ ^ Transferring the pattern of layer 108 to the photoresist method to remove a part The photoresist is fine, and the second one will be; ΗΠ. After transferring to the photoresist layer 106 and exposing a part of the surface, the remaining photoresist layer 10 is used as a mask, such as an etched & I® half-light-transmitting substrate 102, and is immediately adjacent to the recess Defect 104 is formed, as shown in FIG. 2. Among them, the height of the level 108 and the recessed defect is about 59.6 nm, so that the phase difference between the level 108 and the recessed defect is 1 θ as the value calculated previously. In addition, the above-mentioned light-transmitting substrate # 7 can be performed by, for example, dry etching of a plasma (Dry Etchind ion beam (FOCUS Ion Beani; F 〖B). After completing step ^ 8, The remaining photoresist layer 10 may be peeled off to expose the surface 103 of the earth material 102, the depression defect 104, and the formed layer 10 8 °. Then, the coating method may be used in the same manner. A photoresist layer 11 () is formed to cover the surface 103 of the light-transmitting substrate 102, the recessed defect 104, and the layer 108. Then, for example, a light exposure method, an ion beam exposure method, or an electron beam is used. The exposure method exposes the photoresist layer 110 and transfers the pattern of the layer 112 to the photoresist layer 11 ^. Then, 'for example, the development method is used to remove a part of the photoresist layer 丨 i 〇, thereby transferring the pattern of the layer 112 Into the photoresist layer 11 (), and expose a part of the surface 103 of the light-transmitting substrate 102. The remaining photoresist layer 11 is used as a mask, and part of the light is removed by, for example, etching. The substrate 丨 02 is used to form a layer 112 around the layer 108, as shown in Fig. 3. Among them, the step The height difference between 11 2 and stratum 1 008 is also about 5 9 · 6 nanometers, which also makes stratum 112 200413836. V. Description of invention (8) The phase difference between stratum 108 and 45 is 45 degrees, as the value calculated previously. As with the above-mentioned “money-cutting light-transmitting substrate” 〇2, for example, dry plasma engraving technology or focused ion beam technology using plasma can be selected. After the layer 丨 2 is formed, the remaining photoresist layer 11 can be peeled In addition, the surface 10 of the light-transmitting substrate 10, the depression defect 104, the layer 108, and the layer 112 are exposed. After the layer 112 is completed, the photoresist layer can also be formed by, for example, coating. 114 is covered on the surface 10 of the light-transmitting substrate 10, the recessed defect 104, the layer 108, and the layer 1 and 2. For example, light exposure technology, ion beam exposure technology, or electron beam exposure technology is used. The photoresist layer 114 is exposed, and the pattern of the layer 116 is transferred to the photoresist layer i. 4. Then, for example, a developing technology is used to remove a part of the photoresist layer 114 to transfer the pattern of the layer 116 to the photoresist layer 114. The surface of the light-transmitting substrate 10 below the photoresist layer 114 of the hafnium portion is exposed. Surface 103: At this time, the remaining photoresist layer 丨 4 can be used as a mask to remove part of the light-transmitting substrate 10 by, for example, etching, and form a layer around the layer 12 6 'as shown in Figure 4. Similarly, the same degree difference between layer 丨 丨 6 and layer 11 2 is about 5 9 · 6 nm, so that the phase difference between layer 丨 丨 6 and layer 丨 i 2 It is 45 degrees, as calculated previously. Among them, dry etching technology or focused ion beam technology can be used to etch the transparent substrate 10, and dry etching technology can be performed using plasma. It is worth noting that the above-mentioned light-transmitting substrates around the pit defect 104 can be removed without coating a photoresist, and each layer can be directly fabricated by using an etching technique with accurate positioning force. Formation of steps is not limited to the method described above. Then, the remaining photoresist layer 114 can be peeled off, and the surface of the transparent substrate can be peeled off.

200413836 五、發明說明(9) 1 0 3、凹陷缺陷1 0 4、階層1 〇 8、階層11 2、以及階層11 6暴露 出來’而階層108、階層112、以及階層116在透光基材1〇2 中形成階梯狀凹槽,如第5圖所示之結構。其中,階層丨〇 8 之相位、階層11 2之相位、以及階層11 6之相位以預定相位 差而呈階梯狀順次遞減,進而在透光基材1〇2之表面103與 凹陷缺陷1 04之間構成多重相階。另外,請參照第6圖,第6 圖係緣示本發明之一較佳實施例之光罩的透光基材經修補 後的上視圖’也就是第5圖所示之剖面圖的上視圖。在第6 圖中可看出’凹陷缺陷1〇4為階層1()8所圍繞,階層1〇8為階 層112所圍繞,階層11 2為階層丨丨6所圍繞,而階層11 6則鄰 接於透光基材102之表面1〇3。也就是說,凹陷缺陷104的每 一個方位皆依序由階層丨〇8、階層丨1 2、以及階層11 6所構成 之多重_階所環繞,而凹陷缺陷1〇4與透光基材102之表面 1 03間皆有階層1 〇8、階層丨丨2、以及階層11 6所構成之多重 相階來緩和表面1 〇 3與凹陷缺陷丨〇 4間的相位差。 在上述之較佳實施例中,凹陷缺陷1〇4與透光基材1〇2之表 面1 0 3間的相位差為丨8 〇度,可為兩相鄰之階層間所採用的 預定相位差45度所整除。因此,凹陷缺陷1〇4與階層1〇8之 間的相位差、階層1 〇 8與階層丨丨2之間的相位差、階層11 2與 階層11 6之間的相位差、以及階層丨丨6與透光基材丨〇 2之表面 1 03間的相位差可均為相等之45度,亦即相位呈現階梯狀之 0度-45度-90度-135度-180度。然而,凹陷缺陷104與表面 103之間的階層數量係取決於凹陷缺陷1〇4與透光基材1〇2之 表面1 03間的相位差以及所採用之兩相鄰階層間的預定相位 Μ200413836 V. Description of the invention (9) 1 0 3, Defect defect 1 0 4, Level 1 008, Level 11 2, and Level 1 16 are exposed ', and Level 108, Level 112, and Level 116 are on the transparent substrate 1 〇2 is formed in a stepped groove, as shown in Figure 5. Among them, the phase of the layer 〇0, the phase of the layer 11 2 and the phase of the layer 116 are gradually decreased in a stepwise manner with a predetermined phase difference, and then the surface 103 of the transparent substrate 10 and the recessed defect 104 There are multiple phases. In addition, please refer to FIG. 6. FIG. 6 is a top view of the transparent substrate of the photomask after repairing according to a preferred embodiment of the present invention, that is, a top view of the cross-sectional view shown in FIG. 5. . In Figure 6, it can be seen that 'depression defect 104 is surrounded by level 1 () 8, level 108 is surrounded by level 112, level 112 is surrounded by level 丨 丨 6, and level 116 is adjacent. On the surface of the transparent substrate 102, 103. That is to say, each position of the recessed defect 104 is surrounded by a multi-order consisting of a layer 丨 〇8, a layer 丨 1 2, and a layer 116 in order, and the pit defect 104 and the light-transmitting substrate 102 Among the surfaces 103, there are multiple phase steps composed of layers 108, 2, and 11, and 11 to alleviate the phase difference between the surfaces 103 and the recessed defects 04. In the above-mentioned preferred embodiment, the phase difference between the recessed defect 104 and the surface 103 of the light-transmitting substrate 10 is 80 degrees, which may be a predetermined phase adopted between two adjacent layers. Divided by 45 degrees. Therefore, the phase difference between the recessed defect 104 and the level 108, the phase difference between the level 108 and the level 丨 2, the phase difference between the level 112 and the level 116, and the level 丨 丨The phase difference between 6 and the surface 103 of the light-transmitting substrate 〇 02 can be equal to 45 degrees, that is, the phase appears stepwise from 0 degrees to 45 degrees to 90 degrees to 135 degrees to 180 degrees. However, the number of levels between the recessed defect 104 and the surface 103 depends on the phase difference between the recessed defect 104 and the surface 103 of the light-transmitting substrate 10 and the predetermined phase between two adjacent levels used.

第13頁 200413836 五、發明說明(ίο) 差。因此,若凹陷缺陷104與透光基材102之表面103間的相 位差不能為兩相鄰階層間的預定相位差所整除時,凹陷缺 陷1 04與階層1 08之間的相位差、階層1 〇8與階層11 2之間的 相位差、以及階層11 2與階層11 6之間的相位差較佳還是保 持相等,而階層11 6與透光基材1 0 2之表面1 〇 3間的相仇差就 會根據實際的製程產生變化。 由於階層108、階層112、以及階層116所構成之多重相階的 加入,可使得凹陷缺陷104與透光基材102之表面103間之相 位呈階梯狀而朝表面103的方向遞減。因此,可有效減輕凹 陷缺陷104邊緣與透光基材102之表面103間之光破壞性干 擾,而使凹陷缺陷104之光強度獲得提升,甚至可將凹陷缺 陷104之光強度從相當低之〇· 1大幅提升至〇· 9的程度。如此 一來,可達到修補透光基材102上之凹陷缺陷1〇4的目的。 綜合以上所述,本發明之一優點就是因為利用階梯狀之多 重相位階,可減輕光罩之透光基材上之凹陷缺陷邊緣所產 生之光破壞性干擾。因此,可達到提高凹陷缺陷之光強度 的目的。 本發明之又一優點就是因為藉由在無缺陷之透光基材表面 以及凹陷缺陷間利用蝕刻技術加入多重相位階可大幅地提 高凹陷缺陷之光強度,因此可避免凹陷缺陷成像在晶圓之 光阻上,而有效修補光罩之透光基材的凹陷缺陷,進而達 到提升圖案轉移之可靠度的目的。 如熟悉此技術之人員所瞭解的,以上所述僅為本發明之較 佳實施例而已,並非用以限定本發明之申請專利範圍;凡Page 13 200413836 V. Description of the Invention (ίο) Poor. Therefore, if the phase difference between the recessed defect 104 and the surface 103 of the light-transmitting substrate 102 cannot be divisible by a predetermined phase difference between two adjacent levels, the phase difference between the recessed defect 104 and the level 1 08, the level 1 The phase difference between 〇8 and layer 11 2 and the phase difference between layer 11 2 and layer 116 is preferably kept the same, while the phase difference between layer 11 6 and the surface 1 0 3 of the transparent substrate 1 0 Resentment will change according to the actual process. Due to the addition of multiple phase steps composed of the stratum 108, the stratum 112, and the stratum 116, the phase between the recessed defect 104 and the surface 103 of the light-transmitting substrate 102 is stepped and gradually decreases toward the surface 103. Therefore, the light destructive interference between the edge of the recessed defect 104 and the surface 103 of the light-transmitting substrate 102 can be effectively reduced, and the light intensity of the recessed defect 104 can be improved, and the light intensity of the recessed defect 104 can be even reduced from a relatively low level · 1 increased to a level of 0.9. In this way, the purpose of repairing the concave defect 104 on the light-transmitting substrate 102 can be achieved. In summary, one of the advantages of the present invention is that the use of the stepped multiple phase steps can alleviate the light-damaging interference caused by the concave defect edges on the transparent substrate of the photomask. Therefore, the purpose of increasing the light intensity of the recessed defects can be achieved. Another advantage of the present invention is that by adding multiple phase steps by using etching technology between the surface of the non-defective light-transmitting substrate and the recessed defects, the light intensity of the recessed defects can be greatly improved, so that the recessed defects can be prevented from being imaged on the wafer. On the photoresist, it can effectively repair the concave defects of the light-transmitting substrate of the photomask, thereby achieving the purpose of improving the reliability of pattern transfer. As will be understood by those familiar with this technology, the above are only preferred embodiments of the present invention and are not intended to limit the scope of patent application for the present invention;

第14頁 200413836 五、發明說明(11) 其它未脫離本發明所揭示之精神下所完成之等效改變或修 飾,均應包含在下述之申請專利範圍内。 200413836 圖式簡單說明 " 本發明的較佳實施例已於前述之說明文字中輔以下列圖形 做更詳細的闡述,其中·· 第la圖係繪示光罩之具有凹陷缺陷的透光基材的上視圖,· 第lb圖係繪示沿第la圖之I — I剖面線所獲得之剖面圖,· 第2圖至第5圖係繪示本發明之一較佳實施例之修補光罩之 透光基材上_的凹陷缺陷的製程剖面圖;以及 第6圖係緣示本發明之一較佳實施例之光罩的透光基材經修 補後的上視圖。 圖號對照說明: 100 光 罩102 透 光 基 材 103 表 面104 凹 陷 缺 陷 105 高度106 光 阻 層 108 階 層110 光 阻 層 112 階 層114 光 阻 層 116 階 層Page 14 200413836 V. Description of the invention (11) Other equivalent changes or modifications made without departing from the spirit disclosed in the present invention shall be included in the scope of patent application described below. 200413836 Brief description of the drawings " The preferred embodiment of the present invention has been described in more detail in the foregoing explanatory text with the following figures, in which: Fig. La shows the light-transmitting base with recessed defects of the photomask The top view of the material, Figure lb is a cross-sectional view taken along the line I-I of Figure la, and Figures 2 to 5 are the repair light of a preferred embodiment of the present invention. A process cross-sectional view of a recessed defect on the transparent substrate of the mask; and FIG. 6 is a top view of the transparent substrate of the mask after repairing according to a preferred embodiment of the present invention. Comparative description of drawing numbers: 100 mask 102 light-transmitting base material 103 surface 104 depressions 105 height 106 photoresist layer 108 step layer 110 photoresist layer 112 step layer 114 photoresist layer 116 step layer

Claims (1)

200413836200413836 六、申請專利範圍 1· 一種多重相階(Multiple Phase Steps)之光罩修補方 法’其中該光罩至少包括一透光基材、以及一凹陷缺陷位 於該透光基材之一表面上,且該透光基材之該表面具 第一相位’該多重相階之光罩修補方法至少包括·· 測量該凹陷缺陷之一第二相位;以及 形成複數個相位階位於該凹陷缺陷周圍之該透光基材中 其中該些相位階之相位從該透光基材之該表面的該第一相 位朝該凹陷缺陷的該第二相位遞增,且每二個相鄰之誃= 相位階之間具有一預設相位差,而緊鄰該凹陷缺陷之^二 相位階與該凹陷缺陷之間具有該預設相位差。 Λ二 2·如申請專利’範圍第J項所述之多重相階之光罩修補 其中該透光基材之材質為石英。 所度述之”㈣…修補方法 方法 4其度所述之…階之光單修補 I申广專利圍第!項所述之多重相階之‘光罩修補方法 2形成該些相位階之步驟,至少包括去除該凹陷缺陷月 之該透光基材的一部分,藉以在該透光基材中形成具』6. Scope of Patent Application 1. A mask repair method of multiple phase steps' wherein the mask includes at least a light-transmitting substrate and a recessed defect is located on a surface of the light-transmitting substrate, and The mask repair method for the surface of the light-transmitting substrate with a first phase 'the multiple phase steps at least includes measuring a second phase of the recessed defect; and forming a plurality of phase steps of the transparent layer around the recessed defect The phase of the phase steps in the light substrate increases from the first phase of the surface of the transparent substrate to the second phase of the recessed defect, and every two adjacent 誃 = between the phase steps A predetermined phase difference, and the predetermined phase difference is between the second phase step adjacent to the recessed defect and the recessed defect. Λ2. The mask repair of multiple phase steps as described in item J of the scope of the patent application, wherein the material of the transparent substrate is quartz. The described "㈣ ... repairing method and method 4 of the above-mentioned ... order of light single repair I Shenguang patent encirclement! The multiple phase order of the" mask repair method 2 "steps to form these phase steps Including at least a portion of the light-transmitting substrate from which the recessed defect is removed, thereby forming a tool in the light-transmitting substrate. " 200413836 六、申請專利範圍 低階層 複數個階層之一階梯狀凹槽,而該階梯狀凹 緊鄰該凹陷缺陷。 玲义取 6.如申請專利範圍第5項所述之多重相階之光 其中形成每一該些階層之步驟,至少包括: >補方法, 形成一光阻層覆蓋在該透光基材之該表面上; 曝光步驟,心將每一該些階層之圖 阻層中;以及 王通光 進行一姓刻步驟。 7·如申請專利範圍第6項所述之多重相階之光罩修 其中進行該曝光步驟係利用光照射曝光方式^ ’ 4 * 8·如申請專利範圍第6項所述之多重相階之光罩修補方法 其中進行該曝光步驟係利用離子束(i〇n_beam)曝光方式 9·如申請專利範圍第6項所述之多重相階之光罩修補方法 其中進行該曝光步驟係利用電子束(E-beam)曝光方式。 1 〇·如申請專利範圍第6項所述之多重相階之光罩修補方 法,其中進行該蝕刻步驟係利用一乾式蝕刻法(Dry Etching) 〇 11 ·如申請專利範圍第1 〇項所述之多重相階之光罩修補方200413836 VI. Scope of patent application Low-level One of a plurality of levels is a stepped groove, and the stepped depression is next to the depression defect. Lingyi take 6. The step of forming multiple layers of light as described in item 5 of the scope of the patent application, wherein the steps of forming each of these layers include at least: > a method of forming a photoresist layer to cover the transparent substrate On the surface; the exposure step, in which the layers of each of the layers are resisted; and Wang Tongguang performs a surname engraving step. 7. The mask repair of multiple phase steps as described in item 6 of the scope of patent application, wherein the exposure step is performed using light exposure exposure method ^ '4 * 8. The multiple phase steps as described in item 6 of scope of patent application Photomask repair method, in which the exposure step is performed using an ion beam (ion-beam) exposure method 9. The multi-phase mask repair method in accordance with item 6 of the patent application scope, wherein the exposure step is performed using an electron beam ( E-beam) exposure method. 1 〇 The multi-phase mask repair method according to item 6 of the scope of patent application, wherein the etching step is performed by using a dry etching method (Dry Etching) 〇 11 Multi-phase mask repair 200413836 六、申請專利範圍 法’其令進行該姓刻步騾係利用電漿。 專利範圍第6項所述之多重相階之光罩修補方 =j八中進仃該蝕刻步驟係利用一聚焦離子束(FIB)蝕刻 1 3·如申請專利範圍第5項所述之多重相階之光罩修補方 法,其中該些階層之數量係將該第二相位減去該^ 一相 位,並將該第二相位減去該第一相位之相位差除以 相位差後再減掉1而獲得。 14· 一種多重相階之光罩修補方法,其中該光罩至少包括一 透光基材以及一凹陷缺陷位於該透光基材之一表面上,且 該透光基材之該表面具有一第一相位,該多重相階之光罩 修補方法至少包括: 測量該凹陷缺陷之一第二相位;以及 去除該凹陷缺陷周圍之該透光基材的一部分,藉以在該透 光基材中形成具有複數個階層之一階梯狀凹槽,其中每二 個相鄰之該些階層之間具有一預設相位差,且緊鄰該凹陷 缺陷之該些階層與該凹陷缺陷之間具有該預設相位差,而 該些階層之相位係從該凹陷缺陷之該第二相位朝該透光基 材之該表面的該第一相位遞減。 1 5 ·如申請專利範圍第14項所述之多重相階之光罩修補方 第19頁 200413836200413836 VI. Scope of Patent Application Law 'The order to carry out the engraving of the last name does not use plasma. The mask repair method of multiple phase steps described in item 6 of the patent scope = j 八 中 进 This etching step is etched using a focused ion beam (FIB) 1 3 · The multiple phases described in item 5 of the scope of patent application Step mask repair method, wherein the number of layers is subtracted from the second phase by the second phase, and the phase difference of the second phase minus the first phase is divided by the phase difference and then subtracted by 1. And get. 14. A method for repairing a photomask with multiple phases, wherein the photomask includes at least a light-transmitting substrate and a recessed defect on a surface of the light-transmitting substrate, and the surface of the light-transmitting substrate has a first A phase, the multi-phase mask repair method includes at least: measuring a second phase of the recessed defect; and removing a portion of the light-transmitting substrate around the recessed defect, thereby forming a layer having A stepped groove of a plurality of layers, wherein each two adjacent layers have a preset phase difference, and the steps adjacent to the concave defect and the concave defect have a predetermined phase difference. And the phases of the layers are decreasing from the second phase of the recessed defect toward the first phase of the surface of the transparent substrate. 1 5 · Multi-phase mask repair method as described in item 14 of the patent application page 19 200413836 六、申請專利範圍 法,其中該透光基材之材質為石英 1 6 ·如申請專利範圍第1 4項所述之多重相階之光罩修補方 法,其中該預設相位差小於6 0度。 1 7 ·如申請專利範圍第14項所述之多重相階之光罩修補方 法,其中該預設相位差為45度。 18·如申請專利範圍第14項所述之多重相階之光罩修補方 法,其中形成每一該些階層之步驟,至少包括·· 形成一光阻層覆蓋在該透光基材之該表面上; 進行一曝光步驟,藉以將每一該些階層之圖案轉移至該光 阻層中;、以及 進行一蝕刻步驟。 1 9.如申請專利範圍第丨8項所述之多重相階之光罩修補方 法,其中進行該曝光步驟係利用光照射曝光方式。 20·如申請專利範園第18項所述之多重相階之光罩修補方 法’其中進行該曝光步驟係利用離子束曝光方式。 21.如申請專利範圍第丨8項所述之多重相階之光罩修補方 法’其中進行該曝光步驟係利用電子束曝光方式。6. The scope of patent application method, wherein the material of the light-transmitting substrate is quartz 16. The multi-phase mask repair method as described in item 14 of the scope of patent application, wherein the preset phase difference is less than 60 degrees . 17 • The multi-phase mask repair method according to item 14 of the scope of patent application, wherein the preset phase difference is 45 degrees. 18. The multi-phase step mask repair method as described in item 14 of the scope of the patent application, wherein the steps of forming each of these layers include at least ... forming a photoresist layer covering the surface of the light-transmitting substrate Above; performing an exposure step to transfer the patterns of each of the layers into the photoresist layer; and performing an etching step. 1 9. The multi-phase step mask repair method according to item 8 of the scope of the patent application, wherein performing the exposure step uses a light irradiation exposure method. 20. The multiple-phase mask repair method according to item 18 of the patent application park, wherein the exposure step is performed using an ion beam exposure method. 21. The multi-phase mask repair method according to item 8 of the patent application range, wherein the exposure step is performed using an electron beam exposure method. 第20頁 200413836 六、申請專利範圍 ""^ ---- 2 2 ·如申請專利範圍第1 8項所述之多重相階之光罩修、、 法,其中進行該蝕刻步驟係利用一乾式蝕刻法。 補方 23·如申請專利範圍第22項所述之多重相階之光罩修、、 法,其中進行該蝕刻步驟係利用電漿。 -補方 2 4 _如申請專利範圍第1 §項所述之多重相階之光罩修補 法’其中進行該蝕刻步驟係利用一聚焦離子束蝕刻法。 25·如申請專利範圍第14項所述之多重相階之光罩方修補 法’其中該些階層之數量係將該第二相位減去該第一相 位並將該第一相位減去該第一相位之相位差除以該預設 相位差後再減掉1而獲得。Page 20 200413836 VI. Scope of Patent Application " " ^ ---- 2 2 · As for the multi-phase mask repair method according to item 18 of the scope of patent application, the etching step is performed by using A dry etching method. Supplement 23: The multiple phase step mask repair method as described in item 22 of the scope of patent application, wherein the etching step is performed using a plasma. -Supplement 2 4 _ The mask repair method of multiple phases as described in the first patent application scope item ′, wherein the etching step is performed by a focused ion beam etching method. 25. The multi-phase step photomask repair method described in item 14 of the scope of the patent application, wherein the number of layers is the second phase minus the first phase and the first phase minus the first phase The phase difference of a phase is divided by the preset phase difference and then subtracted by 1 to obtain. 第21頁Page 21
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