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TR2024019598T2 - METHOD FOR CONTROLLING UNWANTED PLANTS AND PROMOTING THE GROWTH OF USEFUL PLANTS - Google Patents

METHOD FOR CONTROLLING UNWANTED PLANTS AND PROMOTING THE GROWTH OF USEFUL PLANTS Download PDF

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TR2024019598T2
TR2024019598T2 TR2024/019598 TR2024019598T2 TR 2024019598 T2 TR2024019598 T2 TR 2024019598T2 TR 2024/019598 TR2024/019598 TR 2024/019598 TR 2024019598 T2 TR2024019598 T2 TR 2024019598T2
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plants
tiafenacil
active ingredient
water
manufactured
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TR2024/019598
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Turkish (tr)
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Fukuda Shota
SUGANUMA Taketo
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Ishihara Sangyo Kaisha Ltd
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Publication of TR2024019598T2 publication Critical patent/TR2024019598T2/en

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Abstract

Zararlı bitkileri kontrol etmek ve faydalı bitkilerin büyümesini teşvik etmek için bir yöntem ve bir bileşim sağlamak. Etkili miktarda tiafenasil (a1) ve spesifikasyonda açıklanan A bileşik grubundan seçilen en az bir herbisit bileşiğin (a2) etkili bir miktarının istenmeyen bitkilere, istenmeyen bitkilerin yetiştiği bir yere veya yararlı bitkilerin yetiştirildiği bir yere uygulanmasını içeren, istenmeyen bitkileri kontrol etmek ve yararlı bitkilerin büyümesini teşvik etmek için bir yöntem.A method for controlling unwanted plants and promoting the growth of beneficial plants, comprising applying an effective amount of thiaphenacil (a1) and an effective amount of at least one herbicidal compound selected from compound group A disclosed in the specification (a2) to unwanted plants, a site where unwanted plants are growing, or a site where beneficial plants are growing.

Description

TARIFNAME ISTENMEYEN BITKILERIN KONTROL ALTINA ALINMASI VE FAYDALI BITKILERIN BÜYÜMESININ DESTEKLENMESI IçIN YÖNTEM TEKNIK ALAN Mevcut bulus, istenmeyen bitkileri kontrol etmek ve faydali bitkilerin büyümesini tesvik etmek için, etkili miktarda tiafenasil (a1) ve asagidaki bilesik grubu A'dan seçilen en az bir herbisit bilesigin (a2) etkili bir miktarinin istenmeyen bitkilere, istenmeyen bitkilerin yetistigi bir yere veya faydali bitkilerin yetistirildigi bir yere uygulanmasini içeren bir yöntemle ilgilidir. TEKNIGIN BILINEN DURUMU Patent Belgesi 1, aktif bilesenler olarak belirli bir formülle temsil edilen bir urasil bilesigi ve diger herbisidal olarak aktif bilesik içeren bir herbisidal bilesimi açiklamaktadir. Patent Disi Belge 1, tiafenasil ve metribuzin karisiminin glifosata dirençli at otu üzerindeki herbisidal etkilerini açiklamaktadir. Patent Belgesi 2, Tablo 1-17'de, flumioxazin ve tiafenacil içeren, tiafenacil/flumioxazin agirlik orani 1/1.000 veya daha az olan bir tarimsal bilesimi açiklamaktadir. Bununla birlikte, bu belgeler, mevcut bulusun istenmeyen bitkileri kontrol etmek ve yararli bitkilerin büyümesini tesvik etmek için daha sonra tarif edilen yöntemi özel olarak açiklamamaktadir. Patent Belgesi 3, PPO inhibitör aktivitesine sahip bir bilesik, VLCFA sentez inhibitör aktivitesine sahip bir bilesik veya bunlarin bir kombinasyonunu içeren bir çim büyüme destekleyicisini ve çimlerin büyümesini desteklemek için bir yöntemi açiklamaktadir. Ancak, Patent Belgesi 3 tiafenasili açiklamamaktadir. Patent Disi Belge 2 ve Patent Disi Belge 3'te, tiafenacil'in yararli bitkiler fasulye ve nane üzerinde tek basina kullanilmasiyla büyüme kontrolü veya bitki boyu üzerindeki etkileri dogrulanmistir, ancak bu belgeler tiafenacil ve diger herbisit bilesiklerinin birlikte kullanilmasiyla yararli bitkilerin büyümesini tesvik eden etkileri açiklamamaktadir. Önceki Teknik Belgeler Patent Belgeleri Patent Disi Belgeler PATENT Disi Belge 1: Weed Technology, 35, 817-823 PATENT Disi Belge 2: Weed Technology, 35, 991-994 PATENT Disi Belge 3: Weed Technology, 36, 729-732 BULUSUN KISA AÇIKLAMASI Teknik Problem Günümüzde, çesitli istenmeyen bitkileri kontrol etmek için çesitli herbisitlerin karisimi ve herbisitlerin kombinasyon halinde kullanimi kullanilmaktadir, ancak bazi herbisit kombinasyonlarinin istenmeyen bitkileri kontrol etmek için yeterli etkinin elde edilememesi, kombinasyondaki bilesenlerin birbirini zayiflatmasi ve ayrica kombinasyonun yararli bitkilere zarar vermesi ve yararli bitkilerin büyümesini veya kalitesini bozmasi gibi dezavantajlari vardir. Bu kosullar altinda, mevcut bulusun amaci, istenmeyen bitkileri kontrol etmek ve yararli bitkilerin büyümesini tesvik etmek için bir yöntem saglamaktir. Probleme Çözüm Mevcut bulus, istenmeyen bitkileri kontrol etmek ve faydali bitkilerin büyümesini tesvik etmek için, etkili miktarda tiafenasil (a1) ve asagidaki A bilesik grubundan seçilen en az bir herbisit bilesigin (a2) etkili bir miktarinin istenmeyen bitkilere, istenmeyen bitkilerin yetistigi bir yere veya faydali bitkilerin yetistirildigi bir yere uygulanmasini içeren bir yöntem sunmaktadir (bundan sonra bazen mevcut bulusun yöntemi olarak anilacaktir); bilesik grubu A: herbisit bilesikler S-metolachlor, metribuzin, piroksasülfon (piroksasülfon), pethoxamid, tri-allate ve dimethenamid-P. Mevcut bulus ayrica, aktif bilesenler olarak tiafenasil (a1) ve yukaridaki A bilesik grubundan seçilen en az bir herbisit bilesigi (a2) içeren, (a1) ila (a2) karisim agirlik orani 1:0.8 ila 1:1000 arasinda olan bir tarimsal bilesim saglar (bundan sonra bazen mevcut bulusun bilesimi olarak anilacaktir). Mevcut bulus ayrica tiafenasil (a1) ve yukaridaki A bilesik grubundan aktif bilesen olarak arasinda olan bir kombinasyonunu saglamaktadir. Bu tarifnamede, mevcut bulusun bilesimi yukaridaki kombinasyonu içerir. Bulusun Avantajli Etkileri Mevcut bulusun bilesimi, (a1) ve (a2)'nin tek basina kullanimindan beklenmeyen istenmeyen bitkilere karsi mükemmel herbisidal etkilere sahiptir ve yararli bitkilerin büyümesini tesvik edici etkilere sahiptir. Sonuç olarak, tiafenasil (a1) dozu ve/veya asagidaki A bilesik grubundan seçilen en az bir herbisit bilesigin (a2) dozu azaltilabilir ve böylece mevcut bulus gerçek kullanimda faydalidir. DETAYLI AÇIKLAMA Mevcut bulusa göre, istenmeyen bitkiler, etkili miktarda tiafenasil (a1) ve A bilesik grubundan seçilen en az bir herbisit bilesigin (a2) etkili miktarinin istenmeyen bitkilere, istenmeyen bitkilerin yetistigi bir yere veya yararli bitkilerin yetistirildigi bir yere uygulanmasiyla kontrol edilebilir. Ayrica, istenmeyen bitkiler, bu bulusun bilesiminin etkili bir miktarinin istenmeyen bitkilere, istenmeyen bitkilerin yetistigi bir yere veya yararli bitkilerin yetistirildigi bir yere uygulanmasiyla kontrol edilebilir. Mevcut bulusa göre, yararli bitkilerin büyümesi, etkili miktarda tiafenasil (a1) ve A bilesik grubundan seçilen en az bir herbisit bilesigin (a2) istenmeyen bitkilere, istenmeyen bitkilerin yetistigi bir yere veya yararli bitkilerin yetistirildigi bir yere etkili miktarda uygulanarak tesvik edilebilir. Ayrica, mevcut bulusun bilesiminin etkili bir miktari istenmeyen bitkilere, istenmeyen bitkilerin yetistigi bir yere veya yararli bitkilerin yetistirildigi bir yere uygulanarak yararli bitkilerin büyümesi tesvik edilebilir. Faydali bitkilerin büyümesini tesvik etmek için, etkili miktarda tiafenasil (a1), herbisit bilesigi (a2) veya bu bulusun bilesimi istenmeyen bitkilere, istenmeyen bitkilerin yetistigi bir yere veya faydali bitkilerin yetistirildigi bir yere, faydali bitkilerin yetistirilmesine baslanmadan önce, örnegin faydali bitkilerin tohumlarinin ekilmesinden veya faydali bitkilerin fidelerinin dikilmesinden önce uygulanabilir. Uygulamadan sonra tohumlarin ekilmesiyle veya fidelerin dikilmesiyle büyümeye baslayan faydali bitkilerin büyümesi tesvik edilir. Bu bulusun bilesimi, aktif bilesenler olarak tiafenasil (a1) ve asagidaki A bilesik grubundan seçilen en az bir herbisit bilesigi (a2) içerir. A bilesik grubu, S-metolachlor, metribuzin, piroksasülfon, pethoxamid, tri-allate ve dimethenamid-P herbisit bilesiklerinden (a2) olusan bir gruptur. Bunlar arasinda, herbisit bilesigi (a2) tercihen S-metolachlor, metribuzin, piroksasülfon veya tri-allate, daha tercihen S-metolachlor veya metribuzin veya daha tercihen S-metolachlor, piroksasülfon veya tri-allate'dir. Herbisit bilesigi (a2) ayrica tercihen S-metolachlor veya piroksasülfon veya daha fazla tercihen S-metolachlor veya tri-allate ve özellikle tercihen S- metolachlor'du r. Tiafenasil (a1) ve herbisit bilesigi (a2) bazen tuzlarina, alkil esterlerine, hidratlarina, farkli kristal formlarina, çesitli yapisal izomerlerine vb. sahip olabilir ve bunlar elbette mevcut bulusa dahildir. Tiafenacil'in (a1) mevcut bulustaki herbisit bilesige (a2) karisim agirlik orani, karistirilan aktif bilesen formülasyonunun türü, hava kosullari ve kontrol edilecek istenmeyen bitkilerin türü, büyüme durumu vb. gibi çesitli kosullara bagli olarak degistiginden genel olarak tanimlanamaz. Bununla birlikte, (a1):(a2) karisim agirlik orani genellikle 1:0.8 ila bir durumda, (a1):(a2) karisim agirlik orani daha tercihen 1:1 .2 ila 1:180, daha da tercihen metribuzin oldugu bir durumda, (a1):(a2) karisim agirlik orani daha çok tercihen 1:1.2 ila 1:88 arasindadir. Herbisit bilesigin (a2) piroksasülfon oldugu bir durumda, (a1):(a2) oldugu bir durumda, (a1):(a2) karisim agirlik orani daha çok tercihen 1:7 ila 1:200, daha (a2) pethoxamid oldugu bir durumda, (a1):(a2) karisim agirlik orani daha çok tercihen 1:8 Herbisit bilesigin (a2) dimetenamid-P oldugu bir durumda, (a1):(a2) karisim agirlik orani ila 1:120 arasindadir. Bu bulusun yönteminde, tiafenasil (a1) ve herbisit bilesik (a2) dozlari, karistirilan aktif bilesen formülasyonunun türü, hava kosullari ve kontrol edilecek istenmeyen bitkilerin türü, büyüme durumu vb. gibi çesitli kosullara bagli olarak degistiginden, genel olarak tanimlanamaz. Bununla birlikte, (a1) dozu genellikle hektar basina 0,01 ila 400 g, tercihen Herbisit bilesigin (a2) S-metolachlor oldugu bir durumda, dozu daha çok tercihen hektar Herbisit bilesigin (a2) metribuzin oldugu bir durumda, dozu hektar basina daha çok Herbisit bilesigin (a2) piroksasülfon oldugu bir durumda, dozu hektar basina daha çok Herbisit bilesigin (a2) tri-allat oldugu bir durumda, dozu hektar basina daha çok tercihen bilesigin (a2) pethoxamid oldugu bir durumda, dozu hektar basina daha çok tercihen 10 bilesigin (a2) dimetenamid-P oldugu bir durumda, dozu daha çok tercihen hektar basina arasindadir. Bu bulusun bilesimi, istenmeyen bitkilere, istenmeyen bitkilerin yetistigi bir yere veya yararli bitkilerin yetistirildigi bir yere uygulandiginda, istenmeyen bitkiler üzerinde mükemmel kontrol edici etkiler gösterir ve yararli bitkilerin büyümesini tesvik eder. Bu yer park alani, mezarliklar, yerlesim alanlari, setler, bahçeler, parklar, ormanlar, yollar, çiftlik yollari, araziler ve fabrika sahasi gibi çesitli tarim disi alanlari ve ekin bitkisi tarlalari, meyve bahçeleri, dut tarlalari ve çimler gibi tarimsal alanlari içerir. Özellikle, bu bulusun bilesimi tercihen bir tarim alanina veya gelecekte yararli bitkilerin yetistirilecegi bir yere uygulanir. Yetistirme, tohumun ekilmesinden, tohumun ekilmesinden veya yararli bitkilerin vejetatif üreme organinin ekilmesinden baslayarak yararli bitkilerin hasadini üretmek için bir dizi eylem anlamina gelir. Ayrica, söz konusu tohum, tohum veya fide anlamina gelmektedir. Mevcut bulusun bilesiminin uygulama yöntemi, toprak isleme, yaprak isleme, su isleme ve benzerlerinden uygun sekilde seçilir. Mevcut bulusun bilesiminin uygulama zamani, yararli bitkilerin hasadindan sonra bir sonraki ekimden önceye ve ekimden sonra yararli bitkilerin tomurcuklanmasindan önceye kadar uygun sekilde seçilir. Toprak uygulamasi durumunda, (a1) dozu tercihen hektar basina 0,01 ila 400 g, daha tercihen 1 ila 4000 g'dir. Yapraktan uygulama durumunda, (a1) dozu tercihen hektar Toprak isleme, mevcut bulusun bilesimini yararli bitkilerin veya istenmeyen bitkilerin tomurcuklanmasindan önce topraklara uygulama yöntemidir. Mevcut bulusun bilesiminin toprak islemiyle uygulanmasiyla, toprak yüzeyinde mevcut bulusun bilesimiyle islenmis bir tabaka olusturulur ve mevcut bulusun bilesiminin etkileri her bir bitkiye gösterilir. Yapraktan uygulama, mevcut bulusun bilesiminin, yararli bitkilerin veya istenmeyen bitkilerin tomurcuklanmasindan sonra, bitkilerin yapraklarina uygulanmasi için bir yöntemdir. Mevcut bulusun bilesiminin yapraktan uygulama yoluyla uygulanmasiyla, bilesenler yapraklardan emilir veya yapraklarla temas ettirilir ve mevcut bulusun bilesiminin etkileri her bir bitkiye gösterilir. Su aritimi, mevcut bulusun bilesiminin yararli bitkilerin yetistirildigi veya istenmeyen bitkilerin yetistigi su basmis bir çeltik tarlasina uygulanmasi yöntemidir. Mevcut bulusun bilesiminin su aritimi ile uygulanmasiyla, mevcut bulusun bilesiminin etkileri her bir bitkiye gösterilir. Yukaridaki uygulamalarin her birinde, mevcut bulusun bilesimi önceden belirlenmis bir konsantrasyona kadar örnegin su ile seyreltilir ve istenmeyen bitkilerin, istenmeyen bitkilerin yetistigi bir yerin veya yararli bitkilerin yetistirildigi bir yerin üzerine bir püskürtücü ile püskürtülür. Ayrica, otomatik helikopter veya drone gibi bir uçan cihaz, bir güç dagitici veya bir bom püskürtücü kullanilabilir. Yukaridaki uygulamalarin her birinde, mevcut bulusun bilesiminin dozu, tiafenasil (a1) ile herbisit bilesigin (a2) yukaridaki karisim orani veya ilgili bilesenlerin dozlari uygulanacak sekildedir. Mevcut bulusta "faydali bitkilerin büyümesini tesvik etmek" (bundan sonra bazen saglikli yaprak sayisinin artmasi, bitkinin boyunun artmasi, köklerin büyümesi veya kök yogunlugunun artmasi, tohum veya meyve sayisinin veya agirliginin artmasi veya çiçek sayisinin veya meyve sayisinin artmasi anlamina gelir. Mevcut bulusun bilesimi özellikle bitkinin agirliginin ve/veya tohumlarin agirliginin artirilmasi için uygundur. Büyüme tesviki asagidaki yöntemle ölçülebilir ve degerlendirilebilir. (1) Bitkinin agirligina göre degerlendirme Her yararli bitkinin toprak üstü kismi kesilir ve ham agirligi elde etmek için agirligi ölçülür veya kesilen numune kurutulur ve kuru agirligi elde etmek için agirligi ölçülür. (2) Yapraklarin alanina göre degerlendirme Her yararli bitkinin yapraklari toplanir ve yapraklarin toplam alani bir yaprak alani ölçer (3) Saglikli yaprak sayisina göre degerlendirme Her bir faydali bitkinin saglikli yaprak sayisi sayilir. (4) Bitki boyuna göre degerlendirme Her yararli bitkinin toprak üstü kismi dik tutulur ve toprak yüzeyinden en yüksek konuma kadar olan yükseklik ölçülür. (5) Köklerin büyümesi veya köklerin yogunluguna göre degerlendirme Her yararli bitkinin kökleri kazilir ve ham agirligi elde etmek için agirliklari ölçülür veya elde edilen örnek kökler kurutulur ve kuru agirligi elde etmek için agirliklari ölçülür. (6) Tohum veya meyve sayisi veya agirligina göre degerlendirme Her yararli bitkinin tohumlari veya meyveleri toplanir ve sayilari sayilir veya toplam agirligi veya ortalamayi elde etmek için agirliklari ölçülür. (7) Çiçek sayisi veya meyve sayisina göre degerlendirme Her faydali bitkinin çiçek sayisi veya meyve sayisi sayilir. Bu bulusun bilesimi, istenmeyen bitkileri kontrol etmek veya büyümelerini engellemek için kullanilabilir, örnegin ahir otu (Echinochloa crus-galli, Echinochloa oryzicola), güney yengeç otu (Digitaria ciliaris, Digitaria adscendens), büyük karabas otu (Digitaria sanguinalis), yumusak yengeç otu (Digitaria ischaemum), Dogu Hindistan yengeç otu (Digitaria microbachne), Jamaika yengeç otu (Digitaria horizontalis), yesil tilki kuyrugu (Setaria viridis), dev tilki kuyrugu (Setaria faberi), sari tilki kuyrugu (Setaria lutescens), kaz otu (Eleusine indica), yabani yulaf (Avena fatua), johnsong otu (Sorghum halepense), quackgrass (Agropyron repens), tüylü sinyal otu (Urochloa villosa), alexandergrass (Brachiaria plantaginea), guineagrass (Panicum maximum), paragrass (Panicum purpurascens), Chinese sprangletop (Leptochloa chinensis), red sprangletop (Leptochloa panicea), annual bluegrass (Poa annua), kisa tüylü tilki kuyrugu (Alopecurus aequalis), kara ot (Alopecurus myosuroides), cholorado bluestem (Agropyron tsukushiense), genis yaprakli sinyal otu (Brachiaria platyphylla), güney kum otu (Cenchrus echinatus), Italyan çimi (Lolium multiflorum), bermuda çimi (Cynodon dactylon), menekse yengeç otu (Digitaria violascens), dügüm otu (Paspalum distichum), küçük quakinggrass (Briza minor), tatli vernalgrass (Anthoxanthum odoratum), sonbahar panicum (Panicum dichotomiflorum), shattercane (Sorghum bicolor) ve Amerikan sloughgrass (Beckmannia syzigachne) gibi Poaceae yabani otlari; Pirinç yassi sazi (Cyperus iria), mor findik sazi (Cyperus rotundus), sari findik sazi (Cyperus esculentus), gelgit batakligi yassi sazi (Cyperus serotinus), küçük çiçekli semsiye sazi (Cyperus difformis), igne dikeni (Eleocharis acicularis), su kestanesi (Eleocharis kuroguwai), yesil kyllinga (Kyllinga brevifolia var. leiolepis), Schoenoplectus nipponicus, kozmopolit bulrush (Bolboschoenus koshevnikovii), amur cyperus (Cyperus microiria) ve kaya bulrush (Schoenoplectus juncoides) gibi Cyperaceae yabani otlari; .Japon serit waparo (Sagittaria pygmaea), ok basi (Sagittaria trifolia) ve kanalli su bitkisi (Alisma canaliculatum) gibi Alismataceae yabani otlari; Kalp seklinde yalanci tursu otu (Monochoria vaginalis) ve korsakow monochoria (Monochoria korsakowii) gibi Pontederiaceae yabani otlari; Hint disotu (Rotala indica) ve jerry-jerry (Ammannia multiflora) gibi Lythraceae yabani otlari; Uzun sapli su otu (Elatine triandra) gibi EIatinaceae yabani otlari; Kadife yapragi (Abutilon theophrasti), dikenli sida (Sida spinosa), gönüllü pamuk (Gossypium hirsutum), adi ebegümeci (Malva neglecta), küçük ebegümeci (Malva parviflora) ve Venedik ebegümeci (Hibiscus trionum) gibi Malvaceae yabani otlari; Horozibigi (Xanthium strumarium), kanarya otu (Ambrosia artemisiifolia), devedikeni (Breea setosa), tüylü galinsoga (Galinsoga ciliata), yabani papatya (Matricaria chamomilla), kokusuz papatya (Tripleurospermum maritimum), mayis papatyasi (Anthemis cotula), tüylü pire otu (Conyza bonariensis), uzun pire otu (Conyza sumatrensis), uzun altin basak (Solidago altissima), dikenli marul (Lactuca serriola), philadelphia pire otu (Erigeron philadelphicus), yillik pire otu (Erigeron annuus), adi yer otu (Senecio vulgaris), dev kanarya otu (Ambrosia trifida), at otu (Conyza canadensis), karahindiba (Taraxacum officinale), seytan otu (Bidens frondosa), dilenci otu (Bidens biternata), tüylü ot (Bidens pilosa), dar yaprakli sahin sakali (crepis tectorum), santa maria ates otu (Parthenium hysterophorus), dikenli devedikeni (Sonchus asper), yillik devedikeni (Sonchus oleraceus), gönüllü ayçiçegi (Helianthus annuus), Kanada devedikeni (Cirsium arvense) ve killi yildiz çiçegi (Acanthospermum hispidum) gibi Asteraceae yabani otlari; Siyah gece gölgesi (Solanum nigrum), jimsonweed (Datura stramonium), cutleaf groundcherry (Physalis angulate var. angulata), horsenettle (Solanum carolinense), cut- leaf nightshade (Solanum triflorum), eastern black nightshade (Solanum ptycanthum) ve hairy nightshade (Solanum sarrachoides) gibi Solanaceae yabani otlari; Ince amarant (Amaranthus viridis), kirmizi köklü domuz otu (Amaranthus retroflexus), canli amarant (Amaranthus blitum), .Japon saman çiçegi (Achyranthes bidentata var. japonica), palmer amaranth (Amaranthus palmeri), kochia (Bassia scoparia), smooth pigweed (Amaranthus hybridus), slender amaranth (Amaranthus viridis), powell's amaranth (Amaranthus powellii), spiny amaranth (Amaranthus spinosus), clammy goosefoot (Dysphania pumilio), common lambsquarters (Chenopodium album), fat hen (Chenopodium album var. centrorubrum), dar yaprakli kazayagi (Chenopodium pratericola), sarkik domuz otu (Amaranthus blitoides), Rus devedikeni (Salsola sp.) ve su keneviri (Amaranthus tuberculatus) gibi Amaranthaceae yabani otlari; Soluk akilli ot (Polygonum lapathifolium), ladysthumb (Polygonum persicaria), yabani karabugday (Polygonum convolvulus), knotweed (Polygonum aviculare), soluk akilli ot (Persicaria Iapathifolia var. Iapathifolia), .Japon knotweed (Fallopia japonica), oryantal lady's thumb (Persicaria longiseta), sheep sorrel (Rumex acetosella subsp. pyrenaicus), thunberg knotweed (Persicaria thunbergii), nepalese smartweed (Persicaria nepalensis), Japanese dock (Rumex japonicus) ve Pennsylvania smartweed (Persicaria pensylvanica) gibi Polygonaceae otlar; Esnek aci ot (Cardamine flexuosa), çoban çantasi (Capsella bursa-pastoris), Hint hardali (Brassica juncea), degisken yaprakli sari ot (Rorippa indica), bataklik sari otu (Rorippa palustris), gönüllü kanola (Brassica spp.), küçük tohumlu yalanci keten (Camelina microcarpa), flixweed (Descurainia sophia), siyah hardal (Brassica nigra), takla hardali (Sisymbrium altissimum), yabani hardal (Sinapis arvensis), tarla pennycress (Thlaspi arvense), Londra roketi (Sisymbrium irio) ve pinnate tansymustard (Descurainia pinnata) gibi Brassicaceae yabani otlari; Uzun sabahotu (lpomoea purpurea), tarla kahkahasi (Calystegia arvensis), sarmasik yaprakli sabahotu (lpomoea hederacea), bütün yaprakli sabahotu (lpomoea hederacea var. integriuscula), palmiye yaprakli sabahotu (lpomoea wrightii) ve çukurlu sabahotu (lpomoea lacunosa) gibi Convolvulaceae yabani otlari; Semizotu (Portulaca oleracea) gibi Portulacaceae yabani otlari; Orak otu (Cassia obtusifolia), kirmizi yonca (Trifolium pratense), dar yaprakli fig (Vicia sativa subsp. nigra var. segetalis), beyaz yonca (Trifolium repens), küçük fig (Vicia hirsuta), gönüllü yonca (Medicago sativa), kara ilaç (Medicago lupulina), yaygin lespedeza (Kummerowia striata), emziren yonca (Trifolium dubium), kus ayagi yoncasi (Lotus corniculatus var. japonicus), Florida begganNeed (Desmodium tortuosum) ve kenevir sesbania (Sesbania herbacea) gibi Fabaceae yabani otlari; Adi kus otu (Stellaria media), su kus otu (Stellaria aquatica), yapiskan kus otu (Cerastium glomeratum), .Japon inci otu (Sagina japonica), bataklik kus otu, bataklik yildiz otu (Stellaria uliginosa var. undulata), saksi kadife çiçegi (Calendula officinalis) ve sigirkuyrugu (Vaccaria hispanica) gibi Caryophyllaceae yabani otlari; Ballibabagiller (Lamium amplexicaule) ve mor isirgan otu (Lamium purpureum) gibi Lamiaceae yabani otlar; Yaki otu (Galium spurium), yaki otu (Galium aparine) ve Florida pusleyi (Richardia scabra) gibi Rubiaceae yabani otlari; Üç tohumlu bakir yapragi (Acalypha australis), benekli sütlegen (Euphorbia maculata), texasweed (Caperonia palustris) ve Virginia bakir yapragi (Acalypha virginica) gibi Euphorbiaceae yabani otlari; Asya günebakani (Commelina communis) gibi Commelinaceae yabani otlari; Linderniaceae yabanci otlari, örnegin yaygin yalanci pimpernel (Lindernia procumbens), yalanci pimpernel (Lindernia dubia subsp. major), yalanci pimpernel (Lindernia dubia subsp. dubia) ve (Lindernia micrantha); Dopatrium (Dopatrium junceum), Gratiola japonica), Asiatic plantain (Plantago asiatica), persian speedwell (Veronica persica) ve corn speedwell (Veronica arvensis) gibi Plantaginaceae yabani otlari; Hali otu (Mollugo verticillata) gibi Molluginaceae yabani otlari; Kesme yaprakli aksamsefasi (Oenothera Iaciniata) ve Amerikan sögüt otu (Epilobium ciliatum) gibi Onagraceae yabani otlari; Kirmizi sapli filaree (Erodium cicutarium) gibi Geraniaceae yabani otlari; Zehirli baldiran otu (Conium maculatum) gibi Apiaceae yabani otlari; lsirgan otu (Urtica urens) gibi Urticaceae yabani otlari; Puncturevine (Tribulus terrestris) gibi Zygophyllaceae yabani otlari; ve Burcucumber (Sicyos angulatus) gibi Cucurbitaceae yabani otlari. Mevcut bulusun bilesimi, istenmeyen bitkileri kontrol etmek veya büyümelerini engellemek için uygun sekilde kullanilabilir, örnegin, ahir otu (Echinochloa crus-galli, Echinochloa oryzicola) gibi Poaceae yabani otlari, güney yengeç otu (Digitaria ciliaris, Digitaria adscendens), büyük yengeç otu (Digitaria sanguinalis), yumusak yengeç otu (Digitaria ischaemum), Dogu Hint yengeç otu (Digitaria microbachne), Jamaika yengeç otu (Digitaria horizontalis), dev tilki kuyrugu (Setaria faberi), kaz otu (Eleusine indica), yabani yulaf (Avena fatua), Çin sprangletopu (Leptochloa chinensis), yillik mavi ot (Poa annua), kisa tüylü tilki kuyrugu (Alopecurus aequalis), kara ot (Alopecurus myosuroides), Italyan çimi (Lolium multiflorum), menekse yengeç otu (Digitaria violascens), güz panicumu (Panicum dichotomiflorum) ve Amerikan sloughgrass (Beckmannia syzigachne); Mor findik sazi (Cyperus rotundus), sari findik sazi (Cyperus esculentus) ve yesil kyllinga (Kyllinga brevifolia var. leiolepis) gibi Cyperaceae yabani otlari; Velvetleaf (Abutilon theophrasti) gibi Malvaceae yabani otlari; Asteraceae yabani otlari, örnegin yaygin kanarya otu (Ambrosia artemisiifolia), tüylü galinsoga (Galinsoga ciliata), uzun pire otu (Conyza sumatrensis), philadelphia pire otu (Erigeron philadelphicus) ve karahindiba (Taraxacum officinale); Kara itüzümü (Solanum nigrum) gibi Solanaceae yabani otlari; Kirmizi köklü domuz otu (Amaranthus retroflexus), powell's amaranth (Amaranthus powellii), livid amaranth (Amaranthus blitum), palmer amaranth (Amaranthus palmeri), yumusak domuz otu (Amaranthus hybridus), ince amarant (Amaranthus viridis), dikenli amarant (Amaranthus spinosus), kochia (Bassia scoparia), yaygin kuzu otu (Chenopodium album), yag tavugu (Chenopodium album var. centrorubrum) ve su keneviri (Amaranthus tuberculatus) gibi Amaranthaceae yabani otlari; Soluk akilli ot (Polygonum lapathifolium), soluk akilli ot (Persicaria Iapathifolia var. nepalensis) gibi Polygonaceae yabanci otlari; Esnek aci teresi (Cardamine flexuosa), çoban çantasi (Capsella bursa-pastoris) ve bataklik sari teresi (Rorippa palustris) gibi Brassicaceae yabani otlari; Uzun sabahotu (lpomoea purpurea), sarmasik yaprakli sabahotu (lpomoea hederacea), tarla kahkahasi (Convolvulus arvensis) ve çekirdeksiz sabahotu (lpomoea lacunosa) gibi Convolvulaceae yabani otlari; Semizotu (Portulaca oleracea) gibi Portulacaceae yabani otlari; Dar yaprakli fig (Vicia sativa subsp. nigra var. segetalis) ve yaygin Iespedeza (Kummerowia striata) gibi Fabaceae yabani otlari; Adi kus otu (Stellaria media) ve yapiskan kus otu (Cerastium glomeratum) gibi Ballibabagiller (Lamium amplexicaule) gibi Lamiaceae yabani otlar; Yaki otu (Galium spurium) gibi Rubiaceae yabani otlari; Asya günebakani (Commelina communis) gibi Commelinaceae yabani otlari; ve Persian speedwell (Veronica persica) gibi Plantaginaceae yabani otlari. Mevcut bulusun bilesimi, istenmeyen bitkileri kontrol etmek veya büyümelerini engellemek için yararlidir, örnegin Poaceae yabani otlari, Cyperaceae yabani otlari, Malvaceae yabani otlari, Asteraceae yabani otlari, Solanaceae yabani otlari, Amaranthaceae yabanci otlari, Polygonaceae yabanci otlari, Brassicaceae yabanci otlari, Convolvulaceae yabanci otlari, Fabaceae yabanci otlari, Caryophyllaceae yabanci otlari, Lamiaceae yabanci otlari, Rubiaceae yabanci otlari, Commelinaceae yabanci otlari ve Plantaginaceae yabanci otlari. Mevcut bulusun bilesimi, örnegin Poaceae yabani otlari, Asteraceae yabani otlari ve Amaranthaceae yabani otlari gibi istenmeyen bitkileri kontrol etmek veya büyümelerini engellemek için daha kullanislidir. Bu bulusun bilesimi özellikle Italyan çimi (Lolium multiflorum), kaz otu (Eleusine indica), su keneviri (Amaranthus tuberculatus) ve at otu (Conyza canadensis) gibi istenmeyen bitkileri kontrol etmek veya büyümelerini engellemek için kullanislidir. Bu bulusun bilesimi, su faydali bitkilerin yetistirilmesinde yukaridaki istenmeyen bitkileri kontrol etmek veya büyümelerini engellemek için kullanilir; örnegin çim, soya fasulyesi (Glycine max), yonca (Medicago sativa), nohut (Cicer arietinum), bezelye (Pisum sativum), mercimek (Lens culinaris), pamuk (Gossypium spp.) bugday (Triticum aestivum), pirinç (Oryza sativa), arpa (Hordeum vulgare), çavdar (Secale cereale), yulaf (Avena sativa), misir (Zea mays), sorgum (Sorghum spp.), Çin kolzasi (Brassica rapa var. nippo-oleifera), kanola (Brassica napus), ayçiçegi (Helianthus annuus), seker pancari (Beta vulgaris ssp. vulgaris, Beta vulgaris var. saccharifera, Beta vulgaris var. hortensis), seker kamisi (Saccharum officinarum), yer fistigi (Arachis hypogaea), keten (Linum usitatissimum), tabaco (Nicotiana tabacum) ve kahve (Coffea arabica). Bu nedenle, mevcut bulusun bilesimi tercihen yukaridaki faydali bitkilerin yetistigi bir yerde veya yukaridaki faydali bitkilerin yetistirildigi bir yerde kullanilir. Mevcut bulusun bilesimi özellikle çim, soya fasulyesi, pamuk, bugday, pirinç, misir, Çin kolzasi, kanola, ayçiçegi, seker pancari, seker kamisi, yer fistigi, keten, tabako veya kahve gibi yararli bitkilerin yetistigi veya yararli bitkilerin yetistirildigi bir yerde kullanilir. Mevcut bulusun bilesimi tercihen yararli bitkilerin yetistigi bir yerde veya çim, soya fasulyesi, bugday, pirinç veya misir gibi yararli bitkilerin yetistirildigi bir yerde kullanilir. Mevcut bulusun bilesimi daha çok tercihen soya fasulyesi, bugday, pirinç veya misir gibi faydali bitkilerin yetistigi veya faydali bitkilerin yetistirildigi bir yerde kullanilir. Faydali bitkiler, klasik islah yöntemleri ile bir herbisite, örnegin isoxaflutole gibi bir HPPD inhibitörüne, imazethapyr veya thifensulfuron-methyl gibi bir ALS inhibitörüne, glifosat gibi bir EPSP sentaz inhibitörüne, glufosinat gibi bir glutamin sentaz inhibitörüne, sethoxydim, bromoxynil, dicamba veya 2,4-D gibi bir asetil CoA karboksilaz inhibitörüne direnç kazandirilmis bitkileri içerir. Yararli bitkiler, örnegin, özellikle imidazolinon herbisite dirençli misir ve kanola çesidi (ticari adi: Clearfield) ve sülfonilüre ALS inhibitörü tipi herbisitlere dirençli STS soya fasulyesi olabilir. Yararli bitkiler, gen modifikasyonu ile üretilen transgenik bitkileri içerir. Transgenik bitkilere örnek olarak herbisite dirençli transgenik bitkiler, zararli böceklere dirençli transgenik bitkiler, bitki bilesenlerine iliskin transgenik bitkiler ve fitopatojenlere dirençli transgenik bitkiler verilebilir. Ayrica, faydali bitkiler, bu tür transgenik bitkilerin faydali karakterlerini bir arada bulunduran istiflenmis çesitleri içerir. Mevcut bulusun bilesimi, istenmeyen bitkileri seçici olarak kontrol etmek veya yukaridaki yararli bitkilerin (soya fasulyesi, pamuk, kolza tohumu ve misir gibi) çesitli transgenik bitkilerinin yetistirilmesinde büyümelerini engellemek için etkili bir sekilde kullanilabilir. Herbisite dirençli transgenik bitkiler arasinda glifosata dirençli misir, soya fasulyesi, pamuk, kanola (rapeseed) ve seker pancari, glufosinata dirençli misir, soya fasulyesi, pamuk ve kolza ve bromoksinile dirençli pamuk yer almaktadir. Zararli böceklere dirençli transgenik bitkiler, örnegin Bacillus cinsi tarafindan sentezlendigi bilinen toksinleri sentezleme yetenegi kazanmis bitkileri içerir. Transgenik bitkiler tarafindan sentezlenen toksinler, bitkilere özellikle Coleoptera böcekleri, Hemiptera böcekleri, Diptera böcekleri, Lepidoptera böcekleri ve nematodlara karsi direnç kazandirir. Yukaridaki toksinler Bacillus cereus ve Bacillus popilliae'den türetilen böcek öldürücü proteinleri; Bacillus thuringiensis'ten türetilen Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, CryBBb1 ve CryQC gibi ö-endotoksinleri içerir; VlP1, VlP2, VlP3 ve VlP3A gibi böcek öldürücü proteinler; nematodlardan elde edilen böcek öldürücü proteinler; akrep toksini, örümcek toksini, ari toksini ve böcege özgü nörotoksin gibi hayvanlar tarafindan üretilen toksinler; filamentli mantar toksini; bitki lektini; aglütinin; tripsin inhibitörü, serin proteaz inhibitörü, patatin, sistatin ve papain inhibitörü gibi proteaz inhibitörleri; risin, misir-RIP, abrin, luffin, saporin ve bryodin gibi ribozom inaktive edici proteinler (RlP); 3- hidroksisteroid oksidaz, ekdisteroid-UDP-glukoziltransferaz ve kolesterol oksidaz gibi steroid metabolize edici enzimler; ekdizon inhibitörü; HMG-CoA redüktaz; sodyum kanal blokeri ve kalsiyum kanal blokeri gibi iyon kanal blokerleri; juvenil hormon esteraz; diüretik hormon reseptörü; stilben sentaz; bibenzil sentaz; kitinaz; ve glukanaz. Ayrica, bu tür ve Cry35Ab gibi ö-endotoksin proteinlerinin hibrit toksinlerini ve VlP1, VlP2, VlP3 ve VlP3A gibi böcek öldürücü proteinleri, bunlarin bir kismini içermeyen toksinleri ve modifiye edilmis toksinleri içerir. Bitki bilesenlerine iliskin transgenik bitkiler, yag bileseni degistirilmis karakter veya amino asit içerigi artirilmis karakter kazandirilmis bitkileri içerir. Fitopatojene dirençli transgenik bitkiler, seçici etkiye sahip anti-patojen maddeler üretme yetenegi kazandirilmis bitkileri içerir. Transgenik bitkiler özellikle sinirli degildir ve örnegin glifosata dayanikli misir, soya fasulyesi, pamuk, kolza ve seker pancari çesitleri (ticari adi: RoundupReady, Agrisure, Gly-Tol); glufosinata dayanikli misir, soya fasulyesi, pamuk ve kolza çesitleri (ticari adi: LibertyLink); bromoksinile dayanikli pamuk çesidi (ticari adi: BXN); hem glifosata hem de ALS inhibitörlerine dayanikli misir ve soya fasulyesi çesitleri (ticari adi: Optimum, GAT) BXN); hem glifosat hem de ALS inhibitörlerine dayanikli misir ve soya fasulyesi çesitleri (ticari adi: Optimum, GAT); imidazolinon bilesigine dayanikli çesit (ticari adi: lMl); Cry1Ab toksini ifade eden misir çesidi (ticari adi: YieldGard); CryBBb1 toksini ifade eden misir çesidi (ticari adi: YieldGard Rootworm); Cry1Ab ve CryBBb1 toksinlerini ifade eden misir çesidi (ticari adi: YieldGard Plus); glufosinata direnç kazandirmak için Cry1Fa2 toksini ve fosfinotrisin N-asetiltransferaz (PAT) ifade eden misir çesidi (ticari adi: Herculex l); Cry1Ac toksini ifade eden pamuk çesidi (ticari adi: NuCOTNBBB, Bollgard l); Cry1Ac ve Cry2Ab toksini ifade eden pamuk çesidi (ticari adi: Bollgard ll); VlP toksini ifade eden pamuk çesidi (ticari adi: VlPCOT); glufosinata direnç kazandirmak için Cry1Fa2 toksini ve fosfinotrisin N-asetiltransferaz (PAT) ifade eden misir çesidi (Herculex l); GA21 glifosata dirençli karaktere sahip çesit (ticari adi: NatureGard Agrisure GT Advantage); Bt11 misir kurdu (CB) karakterine sahip çesit (ticari adi: Agrisure CB Advantage); linolenik asit içerigi azaltilmis düsük Iinolenik asit soya fasulyesi (ticari adi: VlSTlVE); ve lizin veya yag içerigi artirilmis misir çesidi. Tiafenacil (a1) ve herbisidal bilesigi (a2) birlikte içeren mevcut bulusun bilesimi, ilgili aktif bilesenlerin ayri ayri uygulandigi bir durumla karsilastirildiginda, daha sonra açiklanan Örneklerde gösterildigi gibi, uzun bir süre boyunca devam eden daha yüksek etkiler uygular. Bu nedenle, pratik uygulamada, örnegin tarimsal bilesimin etkilerinin uygulamadan sonra yagis veya sicakligin etkisi vb. ile azalabilecegi bir uygulamada çok kullanislidir. Mevcut bulusta, mevcut bulusun bilesimi duruma göre diger herbisit bilesiklerle de karistirilabilir. Bu tür diger herbisit bilesikler, mevcut bulusun bilesiminin uygulanmasi, kontrol edilecek istenmeyen bitkilerin türü ve büyüme durumu ve benzerleri dikkate alinarak, bilinen çesitli herbisit bilesikler arasindan uygun sekilde seçilebilir. Ayrica, mevcut bulusun bilesimi bir mantar ilaci, bir antibiyotik, bir bitki hormonu, bir böcek ilaci, bir gübre, bir koruyucu veya benzerleri ile karistirilabilir veya bunlarla birlikte kullanilabilir, böylece bazi durumlarda daha mükemmel etkiler veya islevler elde edilebilir. Bu tür diger herbisit bilesikler, örnegin asagidaki bilesikleri (ortak isimler) içerir ve bir bilesen veya iki veya daha fazla bilesen uygun sekilde seçilebilir. Burada, daha fazla karistirilacak diger herbisidal bilesik olarak, herbisidal bilesikten (a2) farkli bir herbisidal bilesik seçilir. Yani, herbisit bilesigin (a2) metribuzin oldugu bir durumda, daha fazla karistirilacak diger herbisit bilesik olarak, metribuzin disinda bir bilesik seçilir. DB-dimetilamonyum, 2,4-DB-izoktil, 2,4-DB-potasyum, 2,4-DB-sodyum, 2,4-D kolin tuzu, diklorprop, dichlorprop-butotyl, dichlorprop-dimethylammonium, dichlorprop-isoctyl, dichlorprop-potassium, dichlorprop-P, dichlorprop-P-dimethylammonium, dichlorprop-P- potassium, dichlorprop-P-sodium, MCPA, MCPA-butotyl, MCPA-dimethylammonium, MCPA-2-ethylhexyl, MCPA-potasyum, MCPA-sodyum, MCPA-tiyoetil, MCPB, MCPB- etil, MCPB-sodyum, mekoprop, mekoprop-butotil, mekoprop-sodyum, mekoprop-P, mekoprop-P-butotil, mekoprop-P-dimetilamonyum, mekoprop-P-2-etilheksil, mekoprop- P-potasyum, naproanilid, klomeprop ve HlA-1 gibi fenoksi bilesikleri gibi bitkilerin hormon aktivitelerini bozarak herbisit etki gösterdigine inanilan bilesikler ; 2,3,6-TBA, dicamba, dicamba-butotyl, dicamba-diglycolamine, dicamba-dimethylammonium, dicamba-diolamine, dicamba-izopropilamonyum, dicamba-potasyum, dicamba-sodyum, picloram, picloram-dimetilamonyum, picloram-izoktil, picloram-potasyum, picloram- triisopropanolamonyum, picloram-triisopropylammonium, picloram-trolamine, triclopyr, triclopyr-butotyl, triclopyr-triethylammonium, clopyralid, clopyralid-olamine, clopyralid- potassium, clopyralid-triisopropanolammonium, aminopyralid, aminocyclopyrachlor, halauxifen, halauxifen-methyl, indolauxipyr ve BAS-534 gibi aromatik karboksilik asit bilesikleri; ve naptalam, naptalam-sodyum, benazolin, benazolin-etil, quinclorac, quinmerac, diflufenzopyr, diflufenzopyr-sodyum, fluroxypyr, fluroxypyr-2-butoxy-1- methylethyl, fluroxypyr-meptyl, chlorflurenol, chlorflurenol-methyl, clacyfos ve fluchloraminopyr gibi diger bilesikler. (2) Klorotoluron, diuron, fluometuron, linuron, isoproturon, metobenzuron, tebuthiuron, dimefuron, isouron, karbutilate, methabenzthiazuron, metoxuron, metoburomuron, monolinuron, neburon ve siduron gibi üre bilesikleri; terbumeton, trietazine, simazine, atrazine, atratone, simetryn, prometryn, dimethametryn, terbuthylazine, cyanazine, ametryn, cybutryne, terbutryn, propazine, metamitron ve prometon gibi triazine bilesikleri; hekzazinon, metribuzin ve metamitron gibi triazinon bilesikleri; bromasil, bromasil-lityum, lenasil ve terbasil gibi urasil bilesikleri; propanil, cypromid, tetflupyrolimet ve pentanochlor gibi anilid bilesikleri; desmedipham ve phenmedipham gibi karbamat bilesikleri; bromoxynil, bromoxynil-octanoate, bromoxynil-heptanoate, ioxynil, ioxynil-octanoate, ioxynil-potassium ve ioxynil-sodium gibi hidroksibenzonitril bilesikleri; ve pyridate, bentazone, bentazone-sodium, amicarbazone, methazole ve chloridazon gibi diger bilesikler gibi bitkilerin fotosentezini inhibe ederek herbisit etki gösterdigine inanilan bilesikler. (3) Paraquat ve diquat gibi kuaterner amonyum tuzu bilesikleri, bitki gövdesinde aktif oksijen olusturmak için kendiliginden serbest radikallere dönüstügü ve hizli herbisit etkinligi gösterdigi düsünülmektedir. (4) Bitkilerin klorofil biyosentezini inhibe ederek ve bitki gövdesinde fotosensitize edici bir peroksit maddesini anormal sekilde biriktirerek herbisidal etki gösterdigine inanilan bilesikler, nitrofen, chlomethoxyfen, bifenox, acifluorfen, acifluorfen-sodium, fomesafen, fomesafen-sodium, oxyfluorfen, lactofen, aclonifen, ethoxyfen-ethyl, fluoroglycofen-ethyl ve fluoroglycofen gibi difenileter bilesikleri gibi; chlorphthalim, flumioxazin, flumiclorac, flumiclorac-pentyl, cinidon-ethyl, fluthiacet-methyl ve EK-5385 gibi siklik imid bilesikleri; ve oxadiargyl, oxadiazon, sulfentrazone, carfentrazone-ethyl, thidiazimin, pentoxazone, azafenidin, pyraflufen-ethyl, benzfendizone, butafenacil, saflufenacil, epyrifenacil, fluazolate, profluazol, flufenpyr-ethyl, bencarbazone, pyraclonil, cyclopyranil, trifludimoxazin ve flufenoximacil gibi diger bilesikler. (5) Norflurazon ve metflurazon gibi piridazinon bilesikleri; pirazolinat, pirazoksifen, benzofenap, topramezon, cypyrafluone, bipyrazone, tolpyralate ve pyraquinate gibi pirazol bilesikleri; ve amitrole, fluridone, flurtamone, diflufenican, methoxyphenone, clomazone, broclozone, bixlozone, mesotrione, tembotrione, tefuryltrione, fenquinotrione gibi diger bilesikler, cyclopyrimorate, difenzoquat, difenzoquat-methylsulfate, isoxachlortole, benzobicyclon, bicyclopyrone, picolinafen, beflubutamid, ketospiradox, ketospiradox-potassium ve flusulfinam gibi karotenoidler gibi bitkilerin kromogenezini inhibe ederek agartma aktiviteleri ile karakterize edilen herbisidal etki gösterdigine inanilan bilesikler. (6) Diklofop-metil, diklofop, pirifenop-sodyum, fluazifop-butil, fluazifop, fluazifop-P, fluazifop-P-butil, haloksifop-metil gibi ariloksifenoksipropiyonik asit bilesikleri, haloxyfop, haloxyfop-etotyl, haloxyfop-P, haloxyfop-P-methyl, quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, cyhalofop-butyl, fenoxaprop-ethyl, fenoxaprop- P, fenoxaprop-P-ethyl, clodinafop-propargyl, clodinafop, propaquizafop, HNPC-A8169 ve SYP-1924; alloxydim-sodium, alloxydim, clethodim, sethoxydim, tralkoxydim, butroxydim, tepraloxydim, profoxydim ve cycloxydim gibi cyclohexanedione bilesikleri; ve pinoxaden gibi phenylpyrazoline bilesikleri gibi yag asidi biyosentezini inhibe ederek bitkiler üzerinde herbisit etki gösterdigine inanilan bilesikler. (7) Bitkilerin bir amino asit biyosentezini inhibe ederek herbisit etki gösterdigine inanilan bilesikler, örnegin klorimuron-etil, klorimuron, sülfometuron-metil, sülfometuron, primisülfuron-metil, primisülfuron, bensülfuron-metil gibi sülfonilüre bilesikleri, bensulfuron, chlorsulfuron, metsulfuron-methyl, metsulfuron, cinosulfuron, pyrazosulfuron-ethyl, pyrazosulfuron flazasulfuron, rimsulfuron, nicosulfuron, imazosulfuron, flucetosulfuron, cyclosulfamuron, prosulfuron, flupyrsulfuron-methyl- sodium, flupyrsulfuron, triflusulfuron-methyl, triflusulfuron, halosulfuron-methyl, halosulfuron, thifensulfuron-methyl, thifensulfuron, ethoxysulfuron, oxasulfuron, ethametsulfuron, ethametsulfuron-methyl, iodosulfuron, iodosulfuron-methyl-sodium, sulfosulfuron, triasulfuron, tribenuron-methyl, tribenuron, tritosulfuron, foramsulfuron, trifloxysulfuron, trifloxysulfuron-sodium, mesosulfuron-methyl, mesosulfuron, orthosulfamuron, amidosulfuron, azimsulfuron, propyrisulfuron, metazosulfuron, methiopyrsulfuron, monosulfuron-methyl, iofensulfuron ve iofensulfuron-sodium; flumetsulam, metosulam, dimesulfazet, diclosulam, cloransulam-methyl, florasulam, penoxsulam ve pyroxsulam gibi triazolopyrimidinesulfonamide bilesikleri; imazapyr, imazapyr-isopropylammonium, imazethapyr, imazethapyr-ammonium, imazaquin, imazaquin-ammonium, imazamox, imazamox-ammonium, imazamethabenz, imazamethabenz-methyl ve imazapic gibi imidazolinon bilesikleri; pyrithiobac-sodium, bispyribac-sodium, pyriminobac-methyl, pyribenzoxim, pyriftalid ve pyriflubenzoxim gibi pirimidinilsalisilik asit bilesikleri; flucarbazone, flucarbazone-sodium, propoxycarbazone- sodium, propoxycarbazone ve thiencarbazone-methyl gibi sulfonylaminocarbonyltriazolinone bilesikleri; pyrimisulfan ve triafamone gibi sulfoneanilide bilesikleri; ve glyphosate, glyphosate-sodium, glyphosate-potassium, glyphosate-ammonium, glyphosate-diammonium, glyphosate-isopropylammonium, glyphosate-trimesium gibi diger bilesikler, glyphosate-sesquisodium, glufosinate, glufosinate-ammonium, glufosinate-P, glufosinate-P-ammonium, glufosinate-P-sodium, bilanafos, bilanafos-sodium ve cinmethylin. (8) Trifluralin, oryzalin, nitralin, pendimethalin, ethalfluralin, benfluralin, prodiamin, butralin ve dinitramin gibi dinitroanilin bilesikleri; bensulid, napropamid, napropamid-M, propyzamid, pronamid ve beflubutamid-M gibi amid bilesikleri; amiprofos-methyl, butamifos, anilofos ve piperophos gibi organik fosfor bilesikleri; propham, chlorpropham, barban ve carbetamide gibi fenil carbamate bilesikleri; daimuron, cumyluron, bromobutide ve methyldymron gibi cumylamine bilesikleri; ve dithiopyr, thiazopyr, chlorthal-dimethyl, chlorthal, diphenamid, flamprop-M-methyl, flamprop-M, flamprop-M-isopropyl ve swep gibi diger bilesikler gibi bitkilerin hücre mitozlarini inhibe ederek herbisidal etki gösterdigine inanilan bilesikler. (9) Alachlor, metazachlor, butachlor, pretilachlor, metolachlor, S-metolachlor, thenylchlor, pethoxamid, acetochlor, propachlor, dimethenamid, dimethenamid-P, propisochlor ve dimethachlor gibi kloroasetamid bilesikleri; molinate, dimepiperate, pyributicarb, EPTC, butylate, vernolate, pebulate, cycloate, prosulfocarb, esprocarb, thiobencarb, diallate, tri- allate ve orbencarb gibi tiyokarbamat bilesikleri ve etobenzanid, mefenacet, flufenacet, tridiphane, fentrazamide, oxaziclomefone, benfuresate, piroksasülfon, dalapon, dalapon- sodium, TCA-sodium ve trichloroacetic acid gibi diger bilesikler gibi bitkilerin protein biyosentezini veya lipid biyosentezini inhibe ederek herbisidal etki gösterdigine inanilan bilesikler. (10) Dichlobenil, triaziflam, indaziflam, flupoxam ve isoxaben gibi bitkilerin selüloz biyosentezini inhibe ederek herbisit etki gösterdigine inanilan bilesikler. (11) MSMA, DSMA, CMA, endothall, endothall-dipotasyum, endothall-sodyum, endothall- mono(N,N-dimetilalkilamonyum), ethofumesat, sodyum klorat, pelargonik asit, nonanoik asit, fosamin, fosamin-amonyum gibi diger herbisitler, ipfencarbazone, acrolein, ammonium sulfamate, borax, chloroacetic acid, sodium chloroacete, cyanamide, methylarsonic asit, dimethylarsinic asit, sodium dimethylarsinate, dinoterb, dinoterb- ammonium, dinoterb-diolamine, dinoterb-acetate, DNOC, demir sülfat, flupropanat, flupropanat-sodyum, mefluidid, mefluidid-diolamin, metam, metam-amonyum, metam- potasyum, metam-sodyum, metil izotiyosiyanat, pentaklorofenol, sodyum pentaklorofenoksit, pentaklorofenol laurat, kinoklamin, sülfürik asit, üre sülfat, ksantinozin, herbimisin, unguinol, metatyrosin, sarmentin, thaxtominA, mevalosidin, alfa- limonen, piribambenz-propil, piribambenz-izopropil, iptriazopirid, asulam, asulam- sodyum, icafolin, vb gibi diger herbisitler. (12) Xanthomonas campestris, Exserohilum monoceras veya Drechslera monoceras gibi bitkiler üzerinde parazit olarak herbisit etki gösterdigine inanilan mikroorganizmalar. Bir bilesik veya iki veya daha fazla bilesik, yukaridaki diger herbisit bilesikler arasindan uygun sekilde seçilebilir. Diger herbisit bilesik yukaridakilerle sinirli degildir. Bu bulusun bilesiminin uygulanmasina iliskin olarak, istenmeyen bitkilere uygulama, bitkilerin yetistigi bir yere uygulama (bitkilerin ortaya çikmasindan önce veya sonra) veya yararli bitkilerin yetistirildigi bir yere uygulama istege bagli olarak seçilebilir. Ayrica, tiafenasil (a1) ve herbisidal bilesik (a2) uygulama sirasinda kullanilmak üzere karistirilacak sekilde ayri ayri formüle edilebilir veya birlikte formüle edilebilir ve ardindan uygulama yapilabilir. Belirli bir uygulama yöntemine örnek olarak asagidakilerden bahsedilebilir. 1. Tiafenacil (a1) ve herbisidal bilesik (a2) karistirilarak formüle edilir ve formülasyon oldugu gibi uygulanir. 2. Tiafenacil (a1) ve herbisit bilesigi (a2) karistirilir ve birlikte formüle edilir ve formülasyon, örnegin su ile önceden belirlenmis bir konsantrasyona seyreltilir ve duruma göre, seyreltilmis çözeltiye bir tarimsal yayici (bir yüzey aktif madde, bir bitkisel yag veya bir mineral yag gibi) eklenir ve seyreltilmis çözelti uygulanir. 3. Tiafenasil (a1) ve herbisidal bilesik (a2) ayri ayri formüle edilir ve formülasyonlar oldugu gibi uygulanir. 4. Tiafenacil (a1) ve herbisit bilesigi (a2) ayri ayri formüle edilir ve formülasyonlar ayri ayri örnegin su ile önceden belirlenmis konsantrasyonlara seyreltilir ve duruma göre seyreltilmis çözeltilere bir tarimsal yayici (örnegin bir yüzey aktif madde, bir bitkisel yag veya bir mineral yag) eklenir ve seyreltilmis çözeltiler uygulanir. . Tiafenacil (a1) ve herbisidal bilesik (a2) ayri ayri formüle edilir ve formülasyonlar, örnegin su ile önceden belirlenmis bir konsantrasyona seyreltildiginde karistirilir ve duruma göre, seyreltilmis çözeltiye bir tarimsal yayici (bir yüzey aktif madde, bir bitkisel yag veya bir mineral yag gibi) eklenir ve seyreltilmis çözelti uygulanir. Bu bulusun bilesimi, tiafenasil (a1) ve herbisit bilesigi (a2), aktif bilesenler olarak, tarim kimyasallari için geleneksel formülasyon yöntemlerine uygun olarak çesitli katki maddeleri ile karistirilarak hazirlanabilir ve tozlar gibi çesitli formülasyonlar seklinde uygulanabilir, granüller, suda dagilabilen granüller, islanabilir tozlar, tabletler, haplar, kapsüller (suda çözünür bir filmle paketlenmis bir formülasyon dahil), su bazli süspansiyonlar, yag bazli süspansiyonlar, mikroemülsiyonlar, suspoemülsiyonlar, suda çözünür tozlar, emülsifiye edilebilir konsantreler, çözünür konsantreler veya macunlar. Mevcut bulusun bilesimi, mevcut bulusun amaci karsilandigi sürece, bu alanda yaygin olarak kullanilan herhangi bir formülasyon haline getirilebilir. Formülasyon sirasinda tiafenasil (a1) ve herbisit bilesigi (a2) birlikte formüle edilebilir veya ayri ayri formüle edilebilir. Formülasyon için kullanilacak katki maddeleri arasinda örnegin diyatomlu toprak, sönmüs kireç, kalsiyum karbonat, talk, beyaz karbon, kaolin, bentonit, kaolinit, serisit, kil, sodyum karbonat, sodyum bikarbonat, mirabilit, zeolit, nisasta veya sakkaritler gibi kati bir tasiyici yer alir; su, toluen, ksilen, solvent nafta, dioksan, aseton, izoforon, metil izobütil keton, klorobenzen, sikloheksan, dimetil sülfoksit, dimetilformamit, dimetilasetamit, N-metil-2- pirolidon veya bir alkol (propilen glikol gibi) gibi bir çözücü; bir yag asidi tuzu, bir benzoat, bir alkilsülfosüksinat, bir dialkilsülfosüksinat, bir polikarboksilat, bir alkilsülfürik asit esteri tuzu, bir alkil sülfat, bir alkillaril sülfat, bir alkil diglikol eter sülfat, bir alkol sülfürik asit esteri tuzu, bir alkil sülfonat, bir alkilaril sülfonat, bir aril sülfonat, bir lignin sülfonat, bir alkildifenil eter disülfonat, bir polistiren sülfonat, bir alkilfosforik asit esteri tuzu, bir alkilaril fosfat, bir stirilaril fosfat, bir polioksietilen alkil eter sülfürik asit ester tuzu, bir polioksietilen alkilaril eter sülfat, bir polioksietilen alkilaril eter sülfürik asit ester tuzu, bir polioksietilen alkil eter fosfat, polioksietilen alkilaril fosforik asit esterinin bir tuzu, polioksietilen aril eter fosforik asit esterinin bir tuzu, formaldehit ile yogunlastirilmis bir naftalin sülfonat veya formaldehit ile yogunlastirilmis bir alkilnaftalin sülfonat gibi bir anyonik yüzey aktif madde veya bir anyonik yayici; bir sorbitan yag asidi esteri, bir gliserin yag asidi esteri, bir yag asidi poligliseridi, bir yag asidi alkol poliglikol eteri, asetilen glikol, asetilen alkol, bir oksialkilen blok polimer, bir polioksietilen alkil eter, bir polioksietilen alkillaril eter, bir polioksietilen stirilaril eter, bir polioksietilen glikol alkil eter, bir polietilen glikol, bir polioksietilen yag asidi esteri, bir polioksietilen sorbitan yag asidi esteri, bir polioksietilen gliserin yag asidi esteri, bir polioksietilen hidrojenize hint yagi veya bir polioksipropilen yag asidi esteri gibi bir noniyonik yüzey aktif madde veya bir noniyonik yayici; ve zeytinyagi, kapok yagi, hint yagi, palm yagi, kameIya yagi, hindistan cevizi yagi, susam yagi, misir yagi, pirinç kepegi yagi, yer fistigi yagi, pamuk tohumu yagi, soya yagi, kolza yagi, keten tohumu yagi, tung yagi veya sivi parafinler gibi bir bitkisel yag veya mineral yag. Bu katki maddeleri, mevcut bulusun amaci karsilandigi sürece, tek baslarina veya iki veya daha fazlasinin karisimi olarak kombinasyon halinde kullanilmak üzere uygun sekilde seçilebilir. Ayrica, bir dolgu maddesi, bir koyulastirici, bir çökelme önleyici madde, bir donma önleyici madde, bir dagilim stabilizatörü, bir saflastirici, bir kalip önleyici madde, bir sisirme maddesi, bir parçalayici ve bir baglayici gibi yaygin olarak kullanilan çesitli katki maddeleri kullanilabilir. Katki maddelerinin tiafenasil (a1) ve herbisit bilesiginin (a2) her birine veya bunlarin karisimina karisim orani, agirlik oranina göre, yaklasik 0.1 :99.9 Mevcut bulusun tercih edilen düzenlemelerine iliskin örnekler asagida verilecektir, ancak mevcut bulusun hiçbir sekilde bunlarla sinirli olmadigi anlasilmalidir. etmek için etkili miktarda tiafenasil (a1) ve asagidaki A bilesik grubundan seçilen en az bir herbisit bilesigin (a2) etkili bir miktarinin istenmeyen bitkilere, istenmeyen bitkilerin yetistigi bir yere veya faydali bitkilerin yetistirildigi bir yere uygulanmasini içeren bir yöntem; bilesik grubu A: herbisit bilesikler S-metolachlor, metribuzin, piroksasülfon, pethoxamid, tri-allate ve dimethenamid-P. pethoxamid, tri-allate ve dimethenamid-P arasindan seçilen en az bir üyedir. piroksasülfon ve tri-allate arasindan seçilen en az bir üyedir. allate arasindan seçilen en az bir üyedir. arasindan seçilen en az bir üyedir. arasindan seçilen en az bir üyedir. piroksasülfon'du r. seçilen en az bir üyedir. bir dozda uygulanir ve (a2) 0,1 ila 5000 g/ha arasinda bir dozda uygulanir. uygulanir ve (a2) 1 ila 4000 g/ha dozunda uygulanir. arasinda olan bir tarimsal bilesim. 1:200 arasindadir. bir kombinasyonu. piroksasülfon, pethoxamid, tri-allate ve dimethenamid-P arasindan seçilen en az bir üyedir. metribuzin, piroksasülfon ve tri-allate arasindan seçilen en az bir üyedir. piroksasülfon ve tri-allate arasindan seçilen en az bir üyedir. oldugu [16] veya [17]'ye göre tarimsal bilesim. tarimsal bilesim. ve piroksasülfon arasindan seçilen en az bir üyedir. göre tarimsal bilesim. ve tri-allate arasindan seçilen en az bir üyedir. veya tri-allattir. baslanmadan önce, istenmeyen bitkilere, istenmeyen bitkilerin yetistigi bir yere veya yararli bitkilerin yetistirildigi bir yere etkili miktarda tiafenasil (a1) ve asagidaki A bilesik grubundan seçilen en az bir herbisit bilesigin (a2) etkili bir miktarinin uygulanmasini içeren bir yöntem: bilesik grubu A; herbisit bilesikler S-metolachlor, metribuzin, piroksasülfon, pethoxamid, tri-allate ve dimethenamid-P. (a2) S-metolaklor'dur. bilesik grubundan seçilen en az bir herbisit bilesigin (a2) etkili miktarinin istenmeyen bitkilere, istenmeyen bitkilerin yetistigi bir yere veya yararli bitkilerin yetistirildigi bir yere uygulanmasini içeren bir yöntem; bilesik grubu A: herbisit bilesikler S-metolachlor, metribuzin, piroksasülfon, pethoxamid, tri-allate ve dimethenamid-P. istenmeyen bitkilerin yetistigi bir yere veya yararli bitkilerin yetistirildigi bir yere etkili miktarda tiafenasil (a1) ve asagidaki bilesik grubu A'dan seçilen en az bir herbisit bilesigin (a2) etkili bir miktarinin uygulanmasini içerir; bilesik grubu A: herbisit bilesikler S-metolachlor, metribuzin, piroksasülfon, pethoxamid, tri-allate ve dimethenamid-P. ÖRNEKLER Mevcut bulusun Örnekleri açiklanacaktir, ancak mevcut bulus hiçbir sekilde bunlarla sinirli degildir. Ilk olarak, mevcut bulusun bilesiminin istenmeyen bitkiler üzerindeki herbisidal etkisine iliskin testler açiklanacaktir. (1) Herbisidal etki testi (Italyan çimi (Lolium multiflorum)) Arazi topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 2.3 ila 3.0 yaprak asamasina ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak S-metolaklor içeren emülsifiye edilebilir bir konsantre (ticari adi: Dual Gold, Syngenta tarafindan üretilmistir), tarafindan üretilmistir) içeren su ile (hektar basina 200 litreye karsilik gelen bir miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132G, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Püskürtmeden sonraki 6. günde, Italyan çavdarinin büyüme durumu görsel olarak gözlemlenmis ve büyüme inhibisyon orani (%) asagidaki standartlara göre elde edilmis ve sonuçlar Tablo 1'de gösterilmistir. Degerlendirme standartlari: Büyüme engelleme orani (%) = 0 (islem görmemis alana esdeger) ila 100 (tamamen öldürme) Ayrica, büyüme inhibisyon oraninin beklenen degeri (%) asagidaki Colby formülüne göre gösterilmistir. Colby'nin formülü: X: oi (g/ha) bilesik A ile muamele edildiginde büyüme inhibisyon orani, Y: [3 (g/ha) B bilesigi ile muamele edildiginde büyüme inhibisyon orani, E: oi (g/ha) A bilesigi ve B (g/ha) B bilesigi ile muamele edildiginde beklenen büyüme inhibisyon orani (beklenen deger). Yani, mevcut bulusun bilesiminin büyüme inhibisyon orani, yukaridaki formülle hesaplanan E'den (büyüme inhibisyon oraninin beklenen degeri) daha yüksek oldugunda, kombinasyonun sinerjik bir etkiye sahip oldugu kabul edilebilir. Tablo 1'den, tiafenacil (a1) ve S-metolachlor'un (a2) birlikte kullaniminin, her bir bilesenin tek basina kullanimina kiyasla Italyan çimi üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tüm doz kombinasyonlarinda tiafenacil (a1) ve S-metolachlor'un (a2) birlikte kullaniminin büyümeyi engelleme oranlari beklenen degerlerden daha yüksektir ve bu nedenle birlikte kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) Ölçülen deger (beklenen S-metolaklor 25+750 99(84) +375 99(84) +250 98(83) tiafenasil 25 83 12,5 75 S-metolaklor 3000 5 1500 5 (2) Herbisidal etki testi ( Italyan çimi (Lolium multiflorum)) Arazi topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 2,5 ila 3,0 yaprak asamasina ulastiginda, su bazli süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak S-metolaklor içeren emülsifiye edilebilir bir konsantre (ticari adi: Dual Gold, Syngenta tarafindan üretilmistir), tarafindan üretilmistir) içeren su ile (hektar basina 200 litreye karsilik gelen bir miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132G, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Püskürtmeden sonraki 16. günde, Italyan çavdarinin büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 2'de gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri, yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne uygun olarak hesaplanmis ve sonuçlar da Tablo 2'de gösterilmistir. Tablo 2'den, tiafenacil (a1) ve S-metolachlor'un (a2) birlikte kullaniminin, her bir bilesenin tek basina kullanimina kiyasla Italyan çimi üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tiafenacil (a1) ve S-metolachlor'un (a2) kombinasyon halinde kullaniminin tüm doz kombinasyonlarinda büyümeyi engelleme oranlari beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) tiafenasil 12,5 30 S-metolaklor 3000 73 1500 55 62,5 0 (3) Herbisidal etki testi (Italyan çimi (Lolium multiflorum)) Arazi topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 2,8 ila 3,2 yaprak asamasina ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak S-metolaklor içeren emülsifiye edilebilir bir konsantre (ticari adi: Dual Gold, Syngenta tarafindan üretilmistir), tarafindan üretilmistir) içeren su ile (hektar basina 200 litreye karsilik gelen bir miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132Câ, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Püskürtmeden sonraki 7. günde, Italyan çavdarinin büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 3'te gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri, yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne uygun olarak hesaplanmis ve sonuçlar da Tablo 3'te gösterilmistir. Tablo 3'ten, tiafenacil (a1) ve S-metolachlor'un (a2) belirli dozlarda kombinasyon halinde kullaniminin, her bir bilesenin tek basina kullanimina kiyasla Italyan çimi üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tiafenacil (a1) ve S-metolachlor'un (a2) belirli bir doz kombinasyonunda birlikte kullaniminin büyüme inhibisyon oranlari beklenen degerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) tiafenasil+ S-metolaklor tiafenasil 12,5 53 S-metolaklor 15,6 0 (4) Herbisidal etki testi (Italyan çimi (Lolium multiflorum)) Arazi topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 2,5 ila 3,0 yaprak asamasina ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak metribuzin içeren islanabilir bir toz (ticari adi: SENCOR islanabilir toz, Bayer Crop Science tarafindan üretilmistir), %0,5 hacimde tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren su ile (hektar basina 200 litreye karsilik gelen bir miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132Câ, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Püskürtmeden sonraki 7. günde, Italyan çavdarinin büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 4'te gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri, yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne uygun olarak hesaplanmis ve sonuçlar da Tablo 4'te gösterilmistir. Tablo 4'ten tiafenacil (a1) ve metribuzinin (a2) birlikte kullaniminin, her bir bilesenin tek basina kullanimina kiyasla Italyan çimi üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tüm doz kombinasyonlarinda tiafenacil (a1) ve metribuzin (a2) kombinasyonunun büyüme inhibisyon oranlari beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) tiafenasil 6,25 30 metribuzin 1100 88 550 57 275 45 9,38 0 (5) Herbisidal etki testi (Italyan çimi (Lolium multiflorum)) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 3,0 ila 3,3 yaprak asamasina ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak metribuzin içeren islanabilir bir toz (ticari adi: SENCOR islanabilir toz, Bayer Crop Science tarafindan üretilmistir), aktif bilesen olarak piroksasülfon içeren suda dagilabilir granüller (ticari adi: Sakura, Bayer Crop Science tarafindan üretilmistir) veya islanabilir bir toz hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tri-allat içeren islanabilir bir toz, üretilmistir) içeren suyla (hektar basina 200 litreye karsilik gelen bir miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132Câ, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Püskürtmeden sonraki 6. günde, Italyan çavdarinin büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 5'te gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri, yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne uygun olarak hesaplanmis ve sonuçlar da Tablo 5'te gösterilmistir. Tablo 5'ten, tiafenacil (a1) ve metribuzin, piroksasülfon veya tri-allate (a2) kombinasyonunun, her bir bilesenin tek basina kullanimina kiyasla Italyan çimi üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tiafenacil (a1) ve metribuzin, piroksasülfon veya tri-allate (a2) kombinasyonunun tüm kombinasyonlarda kullanilmasiyla elde edilen büyüme inhibisyon oranlari beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) 12,5+15 77(61) Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) 6,25+15 63(35) 6,25+7,5 58(33) 6,25+75 52(33) tiafenasil 12,5 60 6,25 33 3,13 17 metribuzin 550 30 275 30 137,5 20 piroksasülfon 250 23 125 17 62,5 8 Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) tri-allate 1250 5 (6) Herbisidal etki testi (Italyan çimi (Lolium multiflorum)) Arazi topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 2,5 ila 3,0 yaprak asamasina ulastiginda, su bazli süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak piroksasülfon içeren suda dagilabilir granüller (ticari adi: Sakura, Bayer Crop Science tarafindan üretilmistir), %0,5 hacimde bir tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren suyla (hektar basina 200 litreye karsilik gelen bir miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132Câ, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Püskürtmeden sonraki 14. günde, Italyan çimi büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 6'da gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri, yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne uygun olarak hesaplanmis ve sonuçlar da Tablo 6'da gösterilmistir. Tablo 6'dan, tiafenacil (a1) ve piroksasülfon'un (a2) birlikte kullaniminin, her bir bilesenin tek basina kullanimina kiyasla Italyan çimi üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tüm doz kombinasyonlarinda tiafenacil (a1) ve piroksasülfon (a2)'nin birlikte kullanimi ile büyüme inhibisyon oranlari beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) 12,5+30 97(65) 12,5+15 95(63) tiafenasil 12,5 63 piroksasülfon 1000 72 500 67 250 42 125 35 (7) Herbisidal etki testi (Italyan çimi (Lolium multiflorum)) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 2,8 ila 3,0 yaprak asamasina ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak pethoxamid içeren emülsifiye edilebilir bir konsantre (ticari adi: Successor 600, Stahler Suisse SA tarafindan üretilmistir) veya aktif bilesen olarak dimethenamid-P içeren emülsifiye edilebilir bir konsantre (ticari adi: Fieldstar P emülsifiye edilebilir konsantre, BASF tarafindan üretilmistir), %0,5 hacimde tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren suyla (hektar basina 200 litreye karsilik gelen bir miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132Câ, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Püskürtmeden sonraki 7. günde, Italyan çiminin büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 7'de gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri, yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne göre hesaplanmis ve sonuçlar da Tablo 7'de gösterilmistir. Tablo 7'den tiafenacil (a1) ve pethoxamid veya dimethenamid-P'nin (a2) birlikte kullaniminin, her bir bilesenin tek basina kullanimina kiyasla Italyan çimi üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tüm kombinasyonlarda tiafenacil (a1) ve pethoxamid veya dimethenamid-P (a2)'nin birlikte kullanimi ile büyüme inhibisyon oranlari beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) 6,25+60 55(15) tiafenasil 25 33 12,5 37 6,25 15 pethoxamid 1500 12 187,5 0 93,75 0 dimetenamid-P 1500 15 750 12 Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) (8) Herbisidal etki testi (Italyan çimi (Lolium multiflorum)) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 3,0 ila 3,1 yaprak asamasina ulastiginda, su bazli süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak S-metolaklor içeren emülsifiye edilebilir bir konsantre (ticari adi: Dual Gold, Syngenta tarafindan üretilmistir), aktif bilesen olarak metribuzin içeren islanabilir bir toz (ticari adi: SENCOR islatilabilir toz, Bayer Crop Science tarafindan üretilmistir) veya aktif bilesen olarak piroksasülfon içeren suda dagilabilir granüller (ticari adi: Sakura, Bayer Crop Science tarafindan üretilmistir), tarafindan üretilmistir) içeren su ile (hektar basina 200 litreye karsilik gelen miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132Câ, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Püskürtmeden sonraki 4. günde, Italyan çiminin büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 8'de gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri, yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne uygun olarak hesaplanmis ve sonuçlar da Tablo 8'de gösterilmistir. Tablo 8'den tiafenacil (a1) ve S-metolachlor, metribuzin veya piroksasülfon'un (a2) birlikte kullaniminin, her bir bilesenin tek basina kullanimina kiyasla Italyan çimi üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tiafenacil (a1) ve S-metolachlor, metribuzin veya piroksasülfon'un (a2) kombinasyon halinde kullaniminin büyüme inhibisyon oranlari, tüm kombinasyonlarda, beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) Ölçülen deger (beklenen tiafenasil 6,25 20 S-metolaklor 625 13 500 10 metribuzin 938 33 750 20 438 10 piroksasülfon 375 20 188 10 (9) Herbisit etki testi (Italyan çimi (Lolium multiflorum)) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 3,2 ila 4,0 yaprak asamasina ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan, aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak tri-allat içeren islanabilir bir toz, islanabilir bir toz hazirlamak için geleneksel bir yöntemle hazirlanan, aktif bilesen olarak pethoxamid içeren emülsifiye edilebilir bir konsantre (ticari adi: Successor 600, Stahler Suisse SA tarafindan üretilmistir) veya aktif bilesen olarak dimethenamid-P içeren emülsifiye edilebilir bir konsantre (ticari adi: Fieldstar P emülsifiye edilebilir konsantre, BASF tarafindan üretilmistir), %0,5 hacimde bir tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren su ile (hektar basina 200 litreye karsilik gelen bir miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W- ile püskürtülmüstür. Püskürtmeden sonraki 6. günde, Italyan çiminin büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 9'da gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri, yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne göre hesaplanmis ve sonuçlar da Tablo 9'da gösterilmistir. Tablo 9'dan, tiafenacil (a1) ve tri-allate, pethoxamid veya dimethenamid-P (a2)'nin birlikte kullaniminin, her bir bilesenin tek basina kullanimina kiyasla Italyan çimi üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tiafenacil (a1) ve tri-allate, pethoxamid veya dimethenamid-P (a2)'nin kombinasyon halinde kullanilmasiyla elde edilen büyüme inhibisyon oranlari, tüm kombinasyonlarda, beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) Ölçülen deger (beklenen tri-aIIate tiafenasil 6,25 30 tri-allate 937,5 3 pethoxamid 625 8 437,5 3 312,5 5 dimetenamid-P 625 40 500 33 (10) Herbisidal etki testi (kaz otu (Eleusine indica)) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve kaz çimi (Eleusine indica) tohumlari ekilmistir. Kaz çimi (goosegrass) 6,5 iIa 7,8 yaprak asamasina ulastiginda, su bazli süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak S-metolaklor içeren emülsifiye edilebilir bir konsantre (ticari adi: Dual Gold, Syngenta tarafindan üretilmistir), aktif bilesen olarak metribuzin içeren islanabilir bir toz (ticari adi: SENCOR islatilabilir toz, Bayer Crop Science tarafindan üretilmistir) veya aktif bilesen olarak piroksasülfon içeren suda dagilabilir granüller (ticari adi: Sakura, Bayer Crop Science tarafindan üretilmistir), tarafindan üretilmistir) içeren su ile (hektar basina 200 litreye karsilik gelen miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132Câ, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Püskürtmeden sonraki 13. günde, kaz otunun büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 10'da gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri, yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne göre hesaplanmis ve sonuçlar da Tablo 10'da gösterilmistir. Tablo 10'dan tiafenacil (a1) ve S-metolachlor, metribuzin veya piroksasülfon'un (a2) birlikte kullaniminin, her bir bilesenin tek basina kullanimina kiyasla kaz otu üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tiafenacil (a1) ve S-metolachlor, metribuzin veya piroksasülfon'un (a2) kombinasyon halinde kullaniminin büyüme inhibisyon oranlari, tüm kombinasyonlarda, beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) Ölçülen deger (beklenen Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) Ölçülen deger (beklenen 6,25+7,5 96(35) 6,25+7,5 96(30) tiafenasil 6,25 30 S-metolaklor 750 7 metribuzin 1100 72 550 68 9,38 7 piroksasülfon 500 2 (11) Herbisidal etki testi (kaz otu (Eleusine indica)) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve kaz çimi (Eleusine indica) tohumlari ekilmistir. Kaz çimi 7,0 ila 8,3 yaprak asamasina ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan, aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak tri-allat içeren islanabilir bir toz, islanabilir bir toz hazirlamak için geleneksel bir yöntemle hazirlanan, aktif bilesen olarak pethoxamid içeren emülsifiye edilebilir bir konsantre (ticari adi: Successor 600, Stahler Suisse SA tarafindan üretilmistir) veya aktif bilesen olarak dimethenamid-P içeren emülsifiye edilebilir bir konsantre (ticari adi: Fieldstar P emülsifiye edilebilir konsantre, BASF tarafindan üretilmistir), %0,5 hacimde bir tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren su (hektar basina 200 litreye karsilik gelen bir miktarda) ile seyreltilmistir ve küçük bir püskürtme tabancasi (model: W- ile püskürtülmüstür. Püskürtmeden sonraki 3. günde, kaz otunun büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 11'de gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri, yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne göre hesaplanmis ve sonuçlar da Tablo 11'de gösterilmistir. Tablo 11'den, tiafenacil (a1) ve tri-allate, pethoxamid veya dimethenamid-P (a2)'nin birlikte kullaniminin, her bir bilesenin tek basina kullanimina kiyasla kaz otu üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tiafenacil (a1) ve tri-allate, pethoxamid veya dimethenamid-P (a2)'nin kombinasyon halinde kullanilmasiyla elde edilen büyüme inhibisyon oranlari, tüm kombinasyonlarda, beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) Ölçülen deger (beklenen 6,25+75 93(77) 6,25+60 95(77) tiafenasil 6,25 77 tri-allate 1250 5 pethoxamid 750 0 93,8 0 dimetenamid-P 750 0 (12) Herbisit etki testi (su keneviri (Amaranthus tuberculatus)) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve su keneviri (Amaranthus tuberculatus) tohumlari ekilmistir. Su keneviri 6,0 ila 8,5 yaprak asamasina ulastiginda, su bazli süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak S-metolaklor içeren emülsifiye edilebilir bir konsantre (ticari adi: Dual Gold, Syngenta tarafindan üretilmistir), aktif bilesen olarak metribuzin içeren islanabilir bir toz (ticari adi: SENCOR islatilabilir toz, Bayer Crop Science tarafindan üretilmistir) veya aktif bilesen olarak piroksasülfon içeren suda dagilabilir granüller (ticari adi: Sakura, Bayer Crop Science tarafindan üretilmistir), tarafindan üretilmistir) içeren su ile (hektar basina 200 litreye karsilik gelen miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132Câ, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Püskürtmeden sonraki 13. günde, su kenevirinin büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 12'de gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri, yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne göre hesaplanmis ve sonuçlar da Tablo 12'de gösterilmistir. Tablo 12'den tiafenacil (a1) ve S-metolachlor, metribuzin veya piroksasülfon'un (a2) birlikte kullaniminin, her bir bilesenin tek basina kullanimina kiyasla su keneviri üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tiafenacil (a1) ve S-metolachlor, metribuzin veya piroksasülfon'un (a2) kombinasyon halinde kullaniminin büyüme inhibisyon oranlari, tüm kombinasyonlarda, beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) Ölçülen deger (beklenen 6,25+7,5 93(33) 6,25+7,5 97(40) tiafenasil 6,25 33 S-metolaklor 750 0 metribuzin 1100 50 550 37 9,38 5 piroksasülfon 500 13 250 17 7,5 10 (13) Herbisit etki testi (su keneviri (Amaranthus tuberculatus)) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve su keneviri (Amaranthus tuberculatus) tohumlari ekilmistir. Su kenevirleri 5,0 ila 8,0 yaprak asamasina ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan, aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak tri-allat içeren islanabilir bir toz, islanabilir bir toz hazirlamak için geleneksel bir yöntemle hazirlanan, aktif bilesen olarak pethoxamid içeren emülsifiye edilebilir bir konsantre (ticari adi: Successor 600, Stahler Suisse SA tarafindan üretilmistir) veya aktif bilesen olarak dimethenamid-P içeren emülsifiye edilebilir bir konsantre (ticari adi: Fieldstar P emülsifiye edilebilir konsantre, BASF tarafindan üretilmistir), %0,5 hacimde bir tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren su (hektar basina 200 litreye karsilik gelen bir miktarda) ile seyreltilmistir ve küçük bir püskürtme tabancasi (model: W- ile püskürtülmüstür. Püskürtmeden sonraki 4. günde, su kenevirinin büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 13'te gösterilmistir. Ayrica, büyüme inhibisyon oraninin beklenen degeri (%) yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne uygun olarak hesaplanmis ve sonuçlar da Tablo 13'te gösterilmistir. Tablo 13'ten tiafenacil (a1) ve tri-allate, pethoxamid veya dimethenamid-P'nin (a2) birlikte kullaniminin, her bir bilesenin tek basina kullanimina kiyasla su keneviri üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tiafenacil (a1) ve tri-allate, pethoxamid veya dimethenamid-P (a2)'nin kombinasyon halinde kullanilmasiyla elde edilen büyüme inhibisyon oranlari, tüm kombinasyonlarda, beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) 6,25+75 90(73) 6,25+60 92(73) tiafenasil 6,25 73 tri-allate 1250 0 pethoxamid 750 0 93,8 0 dimetenamid-P 750 0 (14) Herbisit etki testi (at otu (Conyza canadensis)) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve at otu (Conyza canadensis) tohumlari ekilmistir. At otu 12 ila 17 cm çapa ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak S-metolaklor içeren emülsifiye edilebilir bir konsantre (ticari adi: Dual Gold, Syngenta tarafindan üretilmistir), aktif bilesen olarak metribuzin içeren islanabilir toz (ticari adi: SENCOR islanabilir toz, Bayer Crop Science tarafindan üretilmistir) veya aktif bilesen olarak piroksasülfon içeren suda dagilabilir granüller (ticari adi: Sakura, Bayer Crop Science tarafindan üretilmistir), %0.5 hacimde bir tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren suyla (hektar basina 200 litreye karsilik gelen bir miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132Câ, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Püskürtmeden sonraki 6. günde, at otunun büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 14'te gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne uygun olarak hesaplanmis ve sonuçlar da Tablo 14'te gösterilmistir. Tablo 14'ten tiafenacil (a1) ve S-metolachlor, metribuzin veya piroksasülfon'un (a2) birlikte kullaniminin, her bir bilesenin tek basina kullanimina kiyasla at otu üzerindeki kontrol edici etkilerinin daha iyi oldugu bulunmustur. Tiafenacil (a1) ve S-metolachlor, metribuzin veya piroksasülfon'un (a2) kombinasyon halinde kullaniminin büyüme inhibisyon oranlari, tüm kombinasyonlarda, beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) Ölçülen deger (beklenen 6,25+7,5 48(23) 6,25+7,5 63(23) tiafenasil 6,25 23 S-metolaklor 750 0 metribuzin 1100 5 9,38 0 piroksasülfon 500 0 (15) Herbisit etki testi (at otu (Conyza canadensis)) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve at otu (Conyza canadensis) tohumlari ekilmistir. At otu 13 ila 19 cm çapa ulastiginda, su bazli süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan, aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak tri-allat içeren islanabilir bir toz, islanabilir bir toz hazirlamak için geleneksel bir yöntemle hazirlanan, aktif bilesen olarak pethoxamid içeren emülsifiye edilebilir bir konsantre (ticari adi: Successor 600, Stahler Suisse SA tarafindan üretilmistir) veya aktif bilesen olarak dimethenamid-P içeren emülsifiye edilebilir bir konsantre (ticari adi: Fieldstar P emülsifiye edilebilir konsantre, BASF tarafindan üretilmistir), %0,5 hacimde bir tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren su (hektar basina 200 litreye karsilik gelen bir miktarda) ile seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132Câ, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Püskürtmeden sonraki 3. günde, at otunun büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 15'te gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri, yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne göre hesaplanmis ve sonuçlar da Tablo 15'te gösterilmistir. Tablo 15'ten, tiafenacil (a1) ve tri-allate, pethoxamid veya dimethenamid-P (a2)'nin birlikte kullaniminin, her bir bilesenin tek basina kullanimina kiyasla at otu üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tiyafenasil (a1) ve tri-allat, pethoxamid veya dimethenamid-P (a2)'nin kombinasyon halinde kullaniminin büyüme inhibisyon oranlari, tüm kombinasyonlarda, beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Test Bilesigi Doz (g/ha) Büyüme inhibisyon orani (%) Ölçülen deger (beklenen 6,25+75 43(17) 6,25+60 50(17) tiafenasil 6,25 17 tri-allate 1250 3 pethoxamid 750 0 93,8 0 dimetenamid-P 750 0 Asagida, mevcut bulusun bilesimi ile tiafenasil yerine baska bir herbisit bilesigi içeren bir bilesim arasindaki karsilastirmali bir test açiklanacaktir. (16) Herbisidal etki testi (karsilastirmali test) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 2,5 ila 3,0 yaprak asamasina ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon, aktif bilesen olarak saflufenasil içeren su bazli bir süspansiyon (ticari adi: Sharpen, BASF tarafindan üretilmistir), aktif bilesen olarak fomesafen içeren islanabilir bir toz, islanabilir bir toz hazirlamak için geleneksel bir yöntemle hazirlanmis, aktif bilesen olarak fluthiacet-methyl içeren emülsifiye edilebilir bir konsantre (ticari adi: Attackshot emülsifiye edilebilir konsantre, MARUWA Biochemical Co., Ltd. tarafindan üretilen), aktif bilesen olarak karfentrazon-etil içeren kuru bir akiskan (ticari adi: Task DF, lSHlHARA SANGYO KAlSHA, LTD. tarafindan üretilen) veya aktif bilesen olarak pyraflufen-etil içeren su bazli bir süspansiyon (ticari adi: ECOPART akiskan, NlHON NOHYAKU CO, LTD. tarafindan üretilmistir) ve aktif bilesen olarak 8- metolachlor içeren emülsifiye edilebilir bir konsantre (ticari adi: Dual Gold, Syngenta tarafindan üretilmistir) veya aktif bilesen olarak metribuzin içeren islatilabilir bir toz (ticari adi: SENCOR islatilabilir toz, Bayer Crop Science tarafindan üretilmistir), %0,5 hacimde bir tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren suyla (hektar basina 200 litreye karsilik gelen miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132Câ, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Püskürtmeden sonraki 4. günde, Italyan çiminin büyüme durumu görsel olarak gözlemlenmis ve yukarida (1) herbisidal etki testinde açiklanan degerlendirme standartlarina uygun olarak büyüme inhibisyon orani (%) elde edilmis ve sonuçlar Tablo 16'da gösterilmistir. Ayrica, büyüme inhibisyon oraninin (%) beklenen degeri yukaridaki (1) herbisidal etki testinde açiklanan Colby formülüne uygun olarak hesaplanmis ve sonuçlar da Tablo 16'da gösterilmistir. Tablo 16'dan, tiafenacil (a1) ve S-metolachlor veya metribuzin (a2) kombinasyonunun, her bir bilesenin tek basina kullanimina kiyasla Italyan çimi üzerinde daha iyi kontrol edici etkilere sahip oldugu bulunmustur. Tiafenacil (a1) ve S-metolachlor veya metribuzin (a2) kombinasyonunun büyüme inhibisyon oranlari beklenen degerlerden daha yüksektir ve bu nedenle kombinasyon halinde kullanimin sinerjik bir etkiye sahip oldugu bulunmustur. Ve tiafenasil (a1) ve S-metolaklor veya metribuzin (a2) kombinasyonu, ki bu bulusun bilesimidir, tiafenasil ve S-metolaklor veya metribuzin disindaki bir test bilesiginin kombinasyonlarindan daha yüksek bir büyüme inhibisyon orani sergilemistir. Oysa tiafenasil disindaki test bilesiklerinin ve S-metolaklor veya metribuzinin kombinasyon halinde kullanilmasiyla Italyan çimi üzerindeki kontrol etkisinde, her bir bilesigin tek basina kullanimina kiyasla herhangi bir iyilesme görülmemistir. Ayrica, bu tür kombinasyonlarin büyüme inhibisyon oranlari beklenen degerlerden daha yüksek degildi, bu nedenle bu kombinasyonlarin sinerjik bir etkiye sahip olmadigini göstermektedir. Test Bilesigi Doz Büyüme inhibisyon orani Ölçülen deger (beklenen Mevcut bulus tiafenasil+ S-metolaklor tiafenasil+ metribuzin Karsilastirmal saflufenasil+ saflufenasil+ metribuzin Test Bilesigi Doz Büyüme inhibisyon orani Ölçülen deger (beklenen fomesafen + 12,5+750 8(11) S-metolaklor fomesafen + metribuzin fluthiacet-methyl+ S-metolaklor fluthiacet-methyl+ metribuzin karfentrazon-etil+ S-metolaklor karfentrazon-etil+ metribuzin piraflufen-etil+ S-metolaklor piraflufen-etil+ metribuzin tiafenasil 12,5 38 saflufenasil 12,5 33 fomesafen 12,5 8 fluthiacet-methyl 12,5 12 Test Bilesigi Doz Büyüme inhibisyon orani Ölçülen deger (beklenen karfentrazon-etil 12,5 12 piraflufen-etil 12,5 25 S-metolaklor 750 3 metribuzin 18,75 7 Asagida, mevcut bulusun bilesiminin yararli bitkiler üzerindeki büyümeyi tesvik edici etkisine iliskin bir test (bundan böyle bitki büyümesini tesvik edici etki testi olarak anilacaktir) açiklanacaktir. Ilk olarak, istenmeyen bitkilerin yetistigi kosullar altinda bitki büyümesini tesvik edici etki testi açiklanacaktir. (17) Bitki büyümesini tesvik edici etki testi (misir) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 2,5 ila 3,0 yaprak asamasina ulastiginda, su bazli süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak S-metolaklor içeren emülsifiye edilebilir bir konsantre (ticari adi: Dual Gold, Syngenta tarafindan üretilmistir) veya aktif bilesen olarak metribuzin içeren islatilabilir bir toz (ticari adi: SENCOR islatilabilir toz, Bayer Crop Science tarafindan üretilmistir), %0,5 hacimde bir tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren su (hektar basina 200 litreye karsilik gelen miktarda) ile seyreltilmistir ve küçük bir püskürtme tabancasi (model: W- ile püskürtülmüstür. Yemlik misir tohumlari (çesit: SNOW DENT OTOHA, SNOW BRAND SEED Co., Ltd. tarafindan üretilmistir) ilaçlamadan sonra saksiya ekilmistir. Ekimden sonraki 20. günde, yemlik misirin toprak üstü kismi biçilmis ve ham agirligi elde etmek için agirligi ölçülmüstür. Sonuçlar Tablo 17'de gösterilmistir. Tablo 17'den, tiafenacil (a1) ve S-metolachlor veya metribuzin (a2) kombinasyonunun kullanilmasinin, islenmemis alan ve her bir bilesenin tek basina kullanimina kiyasla yemlik misirin ham agirligini artirdigi bulunmustur. Test Bilesigi Doz Yemlik misirin ham agirligi (g) tiafenasil+ 12,5+750 17,1 S-metolaklor metribuzin tiafenasil 12,5 8,5 S-metolaklor 750 5,1 metribuzin 18,75 6,2 (Islem görmemis alan) - 6,6 (18) Bitki büyümesini tesvik edici etki testi (misir) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 2,7 ila 3,1 yaprak asamasina ulastiginda, su bazli süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak S-metolaklor içeren emülsifiye edilebilir bir konsantre (ticari adi: Dual Gold, Syngenta tarafindan üretilmistir), aktif bilesen olarak metribuzin içeren islanabilir bir toz (ticari adi: SENCOR islatilabilir toz, Bayer Crop Science tarafindan üretilmistir) veya aktif bilesen olarak piroksasülfon içeren suda dagilabilir granüller (ticari adi: Sakura, Bayer Crop Science tarafindan üretilmistir), tarafindan üretilmistir) içeren su ile (hektar basina 200 litreye karsilik gelen miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132G, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Yemlik misir tohumlari (çesit: SNOW DENT OTOHA, SNOW BRAND SEED Co., Ltd. tarafindan üretilmistir) ilaçlamadan sonra saksiya ekilmistir. Ekimden sonraki 21. günde, yemlik misirin toprak üstü kismi biçilmis ve ham agirligi elde etmek için agirligi ölçülmüstür. Sonuçlar Tablo 18'de gösterilmistir. Tablo 18'den, tiafenacil (a1) ve S-metolachlor, metribuzin veya piroksasülfon'un (a2) birlikte kullaniminin, islenmemis alan ve her bir bilesenin tek basina kullanimi ile karsilastirildiginda yemlik misirin ham agirligini artirdigi bulunmustur. Test Bilesigi Doz Yemlik misirin ham agirligi (g) tiafenasil+ 6,25+750 6,9 S-metolaklor 6,25+7,5 8,7 tiafenasil+ 6,25+550 6,7 metribuzin 6,25+225 6,6 tiafenasil+ 6,25+250 8,2 piroksasülfon 6,25+125 6,5 6,25+7,5 9,5 tiafenasil 6,25 3,2 Test Bilesigi Doz Yemlik misirin ham agirligi (g) S-metolaklor 750 3,1 7,5 3,5 metribuzin 550 5,6 225 4,7 piroksasülfon 250 3,8 125 3,3 7,5 5,8 (Islem görmemis alan) - 5,1 (19) Bitki büyümesini tesvik edici etki testi (misir) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 3,2 ila 3,7 yaprak asamasina ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan, aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak tri-allat içeren, islanabilir bir toz hazirlamak için geleneksel bir yöntemle hazirlanan islanabilir bir toz veya aktif bilesen olarak pethoxamid içeren emülsifiye edilebilir bir konsantre (ticari adi: Successor 600, Stahler Suisse SA tarafindan üretilmistir), %0,5 hacimde bir tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren suyla (hektar basina 200 litreye karsilik gelen bir miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132G, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Yemlik misir tohumlari (çesit: SNOW DENT OTOHA, SNOW BRAND SEED Co., Ltd. tarafindan üretilmistir) ilaçlamadan sonra saksiya ekilmistir. Ekimden sonraki 21. günde, yemlik misirin toprak üstü kismi biçilmis ve ham agirligi elde etmek için agirligi ölçülmüstür. Sonuçlar Tablo 19'da gösterilmistir. Tablo 19'dan tiafenacil (a1) ve tri-allate veya pethoxamid'in (a2) birlikte kullaniminin, islenmemis alan ve her bir bilesenin tek basina kullanimi ile karsilastirildiginda yemlik misirin ham agirligini artirdigi bulunmustur. Test Bilesigi Doz Yemlik misirin ham agirligi (9) tiafenasil+ 6,25+1250 5,8 tri-allate 6,25+625 5,3 6,25+75 5,7 tiafenasil+ 6,25+750 4,4 pethoxamid 6,25+375 5,2 6,25+93,8 6,0 tiafenasil 6,25 3,9 tri-allate 1250 2,5 625 2,2 75 2,6 pethoxamid 750 3,6 375 2,2 93,8 3,4 (Islem görmemis alan) - 2,3 (20) Bitki büyümesini tesvik edici etki testi (misir) Arazi topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 2,7 ila 3,0 yaprak asamasina ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak dimetenamid-P içeren emülsifiye edilebilir bir konsantre (ticari adi: Fieldstar P emülsifiye edilebilir konsantre, BASF tarafindan üretilmistir), %0,5 hacimde bir tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren su ile (hektar basina 200 litreye karsilik gelen bir miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W- ile püskürtülmüstür. Yemlik misir tohumlari (çesit: SNOW DENT OTOHA, SNOW BRAND SEED Co., Ltd. tarafindan üretilmistir) ilaçlamadan sonra saksiya ekilmistir. Ekimden sonraki 33. günde, yemlik misirin toprak üstü kismi biçilmis ve ham agirligi elde etmek için agirligi ölçülmüstür. Sonuçlar Tablo 20'de gösterilmistir. Tablo 20'den, tiafenacil (a1) ve dimethenamid-P'nin (a2) birlikte kullaniminin, islenmemis alan ve her bir bilesenin tek basina kullanimina kiyasla yemlik misirin ham agirligini artirdigi bulunmustur. Test Bilesigi Doz Yemlik misirin ham agirligi (g) tiafenasil+ 6,25+750 19,0 dimetenamid-P 6,25+375 21,9 6,25+60 15,5 tiafenasil 6,25 12,1 dimetenamid-P 750 8,0 375 12,5 60 9,8 (Islem görmemis alan) - 2,7 (21) Bitki büyümesini tesvik edici etki testi (bugday) Yayla topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 3,3 ila 3,8 yaprak asamasina ulastiginda, su bazli süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan, aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak metribuzin içeren islanabilir bir toz (ticari adi: SENCOR islanabilir toz, Bayer Crop Science tarafindan üretilmistir) veya aktif bilesen olarak piroksasülfon içeren suda dagilabilir granüller (ticari adi: Sakura, Bayer Crop Science tarafindan üretilmistir), %0,5 hacimde bir tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren suyla (hektar basina 200 litreye karsilik gelen bir miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-13ZG, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Bugday tohumlari (çesit: Norin 61, Asahi Noen Seed Co., Ltd. tarafindan üretilmistir) ilaçlamadan sonra saksiya ekilmistir. Ekimden sonraki 22. günde bugdayin toprak üstü kismi biçilmis ve ham agirligi elde etmek için agirligi ölçülmüstür. Sonuçlar Tablo 21 ide gösterilmistir. Tablo 21 iden tiafenacil (a1) ve metribuzin veya piroksasülfon'un (a2) birlikte kullaniminin, islem görmemis alan ve her bir bilesenin tek basina kullanimi ile karsilastirildiginda bugdayin ham agirligini artirdigi görülmektedir. Test Bilesigi Doz Bugdayin ham agirligi (g) tiafenasil+ 3+150 4,5 metribuzin tiafenasil+ 3+37,5 4,0 piroksasülfon tiafenasil 3 2,3 Test Bilesigi Doz Bugdayin ham agirligi (g) metribuzin 150 2,5 piroksasülfon 37,5 1,2 (Islem görmemis alan) - 1,2 (22) Bitki büyümesini tesvik edici etki testi (bugday) Arazi topragi 1/1.000.000 hektarlik bir saksiya konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 2,5 ila 2,8 yaprak asamasina ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve islatilabilir bir toz hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tri-allat içeren islatilabilir bir toz, tarafindan üretilmistir) içeren suyla (hektar basina 200 litreye karsilik gelen bir miktarda) seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132G, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Bugday tohumlari (çesit: Norin 61, Asahi Noen Seed Co., Ltd. tarafindan üretilmistir) ilaçlamadan sonra saksiya ekilmistir. Ekimden sonraki 21. günde bugdayin toprak üstü kismi biçilmis ve ham agirligi elde etmek için agirligi ölçülmüstür. Sonuçlar Tablo 22'de gösterilmistir. Tablo 22'den, tiafenasil (a1) ve tri-allat'in (a2) birlikte kullaniminin, islem görmemis alan ve her bir bilesenin tek basina kullanimi ile karsilastirildiginda bugdayin ham agirligini artirdigi görülmektedir. Test Bilesigi Doz Bugdayin ham agirligi (g) tiafenasil+ 3+200 2,7 tri-allate tiafenasil 3 2,2 tri-allate 200 2,3 (Islem görmemis alan) - 2,3 (23) Bitki büyümesini tesvik edici etki testi (soya fasulyesi) 1/200.000 hektarlik bir saksiya yayla topragi konmus ve Italyan çimi (Lolium multiflorum) tohumlari ekilmistir. Italyan çimi 2,5 ila 3,0 yaprak asamasina ulastiginda, su bazli bir süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenasil içeren su bazli bir süspansiyon ve aktif bilesen olarak S-metolaklor içeren emülsifiye edilebilir bir konsantre (ticari adi: Dual Gold, Syngenta tarafindan üretilmistir), aktif bilesen olarak metribuzin içeren islanabilir bir toz (ticari adi: SENCOR islanabilir toz, Bayer Crop Science tarafindan üretilmistir), aktif bilesen olarak piroksasülfon içeren suda dagilabilir granüller (ticari adi: Sakura, Bayer Crop Science tarafindan üretilmistir), islanabilir bir toz hazirlamak için geleneksel bir yöntemle hazirlanan, aktif bilesen olarak tri-allat içeren islanabilir bir toz, aktif bilesen olarak pethoxamid içeren emülsifiye edilebilir bir konsantre (ticari adi: Successor 600, Stahler Suisse SA tarafindan üretilmistir) veya aktif bilesen olarak dimethenamid-P içeren emülsifiye edilebilir bir konsantre (ticari adi: Fieldstar P emülsifiye edilebilir konsantre, BASF tarafindan üretilmistir), %0,5 hacimde bir tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren su (hektar basina 200 litreye karsilik gelen bir miktarda) ile seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132G, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Soya fasulyesi tohumlari (çesit: Enrei, Asahi Noen Seed Co., Ltd. tarafindan üretilmistir) ilaçlamadan sonra saksiya ekilmis ve soya fasulyesi yetistirilmistir. Ekimden sonraki 97. günde, yetistirilen soya fasulyesinden tohumlar toplanmis ve toplam agirligi elde etmek için agirliklari ölçülmüstür. Sonuçlar Tablo 23'te gösterilmistir. Tablo 23'ten, tiafenacil (a1) ve S-metolachlor, metribuzin, piroksasülfon, tri-allate, pethoxamid veya dimethenamid-P'nin (a2) birlikte kullaniminin, islem görmemis alan ve her bir bilesenin tek basina kullanimi ile karsilastirildiginda soya fasulyesi tohumlarinin toplam agirligini artirdigi bulunmustur. Test Bilesigi Doz Soya fasulyesi tohumlarinin toplam agirligi (g) tiafenasil+ 12,5+750 34,5 S-metolaklor metribuzin tiafenasil+ 12,5+125 43,4 piroksasülfon tiafenasil+ 12,5+625 45,2 tri-allate Test Bilesigi Doz Soya fasulyesi tohumlarinin toplam agirligi (9) tiafenasil+ 12,5+750 45,2 pethoxamid tiafenasil+ 12,5+750 50,0 dimetenamid-P tiafenasil 12,5 14,3 S-metolaklor 750 12,7 metribuzin 18,75 14,2 piroksasülfon 125 15,6 tri-allate 625 17,0 pethoxamid 750 1 1 ,0 dimetenamid-P 750 14,1 (Islem görmemis alan) - 11,0 Bitki büyümesini tesvik edici etki testlerinin (17) ila (23) yukaridaki sonuçlarindan, mevcut bulusun bilesiminin faydali bitkiler üzerindeki büyümeyi tesvik edici etkileri dogrulanmistir. Bitki büyümesini tesvik edici etki testleri (17) ila (23) istenmeyen bitkilerin tohumlarinin ekildigi kosullar altinda gerçeklestirilmistir ve bu nedenle istenmeyen bitkilerin mevcut bulusun bilesimi tarafindan kontrol edilmesiyle, istenmeyen bitkilerin yararli bitkilerle etkilesimi azaltilmistir, bu da mevcut bulusun bilesiminin yararli bitkiler üzerindeki büyümeyi tesvik edici etkilerinde en az bir faktör olarak kabul edilmektedir. Bu nedenle, asagida, istenmeyen bitkilerin tohumlarinin ekilmedigi kosullar altinda yürütülen, mevcut bulusun bilesiminin yararli bitkiler üzerindeki bitki büyümesini tesvik edici etkisi üzerine bir test açiklanacaktir. (24) Bitki büyümesini tesvik edici etki testi (soya fasulyesi) Upland topragi 1/500.000 hektarlik bir saksiya konmus ve su bazli süspansiyon hazirlamak için geleneksel bir yöntemle hazirlanan aktif bilesen olarak tiafenacil içeren su bazli bir süspansiyon ve aktif bilesen olarak S-metolachlor içeren emülsifiye edilebilir bir konsantre (ticari adi: Dual Gold, Syngenta tarafindan üretilmistir), aktif bilesen olarak metribuzin içeren islanabilir bir toz (ticari adi: SENCOR islanabilir toz, Bayer Crop Science tarafindan üretilmistir), aktif bilesen olarak piroksasülfon içeren suda dagilabilir granüller (ticari adi: Sakura, Bayer Crop Science tarafindan üretilmistir), islanabilir bir toz hazirlamak için geleneksel bir yöntemle hazirlanan, aktif bilesen olarak tri-allat içeren islanabilir bir toz, aktif bilesen olarak pethoxamid içeren emülsifiye edilebilir bir konsantre (ticari adi: Successor 600, Stahler Suisse SA tarafindan üretilmistir) veya aktif bilesen olarak dimethenamid-P içeren emülsifiye edilebilir bir konsantre (ticari adi: Fieldstar P emülsifiye edilebilir konsantre, BASF tarafindan üretilmistir), %0,5 hacimde bir tarimsal yayici (ticari adi: Destiny HC, Winfield Solutions, LLC. tarafindan üretilmistir) içeren su (hektar basina 200 litreye karsilik gelen bir miktarda) ile seyreltilmistir ve küçük bir püskürtme tabancasi (model: W-101-132Câ, ANEST lWATA Corporation tarafindan üretilmistir) ile püskürtülmüstür. Soya fasulyesi tohumlari (çesit: Enrei, Asahi Noen Seed Co., Ltd. tarafindan üretilmistir) ilaçlamadan sonra saksiya ekilmistir. Ekimden sonraki 48. günde, soya fasulyesinin toprak üstü kismi biçilmis ve toplam agirligi elde etmek için agirligi ölçülmüstür. Sonuçlar Tablo 24'te gösterilmistir. Tablo 24'ten tiafenacil (a1) ve S-metolachlor, metribuzin, piroksasülfon, tri-allate, pethoxamid veya dimethenamid-P'nin (a2) birlikte kullaniminin, islenmemis alan ve her bir bilesenin tek basina kullanimi ile karsilastirildiginda soya fasulyesinin ham agirligini arttirdigi bulunmustur. Böylece, mevcut bulusun bilesiminin, istenmeyen bitkilerin ekilmedigi kosullar altinda soya fasulyesi üzerinde büyümeyi tesvik edici etkilere sahip oldugu dogrulanmistir. Test Bilesigi Doz Soya fasulyesinin ham agirligi tiafenasil+ 3+75 47,7 S-metolaklor tiafenasil+ 3+150 53,5 metribuzin tiafenasil+ 3+37,5 40,0 piroksasülfon tiafenasil+ 3+200 53,8 tri-allate tiafenasil+ 3+200 38,5 pethoxamid tiafenasil+ 3+150 38,0 dimetenamid-P tiafenasil 3 28,3 S-metolaklor 75 27,1 metribuzin 150 16,1 piroksasülfon 37,5 30,0 tri-allate 200 18,2 Test Bilesigi Doz Soya fasulyesinin ham agirligi pethoxamid 200 26,7 dimetenamid-P 150 28,9 (Islem görmemis alan) - 23,2 Yukaridaki herbisidal etki testlerinin ve bitki büyümesini tesvik edici etki testlerinin sonuçlarindan, mevcut bulusun bilesiminin istenmeyen bitkileri kontrol etme ve yararli bitkilerin büyümesini tesvik etme etkilerine sahip oldugu bulunmustur. Tarifname, istemler ve özet de dahil olmak üzere 29 Temmuz 2022 tarihinde dosyalanan olarak yer verilmistir. TR TR TR TR TR TR TRDESCRIPTION METHOD FOR CONTROLING UNWANTED PLANTS AND PROMOTING THE GROWTH OF BENEFICIAL PLANTS TECHNICAL FIELD The present invention relates to a method for controlling unwanted plants and promoting the growth of beneficial plants, comprising applying an effective amount of tiafenacil (a1) and an effective amount of at least one herbicidal compound (a2) selected from compound group A below to unwanted plants, to a place where unwanted plants grow, or to a place where beneficial plants grow. STATE OF THE ART Patent Document 1 discloses a herbicidal composition comprising a uracil compound and other herbicidally active compound represented by a certain formula as active ingredients. Non-Patent Document 1 describes the herbicidal effects of a mixture of tiafenacil and metribuzin on glyphosate-resistant horseweed. Patent Document 2, Table 1-17, containing flumioxazin and tiafenacil, with a tiafenacil/flumioxazin weight ratio of 1/1. Describes an agricultural composition of 000 or less. However, these documents do not specifically disclose the method later described for controlling undesirable plants and promoting the growth of beneficial plants using the present invention. Patent Document 3 discloses a grass growth promoter comprising a compound having PPO inhibitory activity, a compound having VLCFA synthesis inhibitory activity, or a combination thereof, and a method for promoting the growth of grass. However, Patent Document 3 does not disclose tiafenacyl. In Non-Patent Document 2 and Non-Patent Document 3, the effects of tiafenacil on growth control or plant height when used alone on the beneficial plants bean and mint were confirmed, but these documents do not describe the growth-promoting effects of tiafenacil and other herbicide compounds when used together. Prior Art Documents Patent Documents Non-Patent Documents Non-PATENT Document 1: Weed Technology, 35, 817-823 Non-PATENT Document 2: Weed Technology, 35, 991-994 Non-PATENT Document 3: Weed Technology, 36, 729-732 BRIEF DESCRIPTION OF THE INVENTION Technical Problem Nowadays, mixture of various herbicides and use of herbicides in combination are used to control various undesirable plants, but some herbicide combinations have disadvantages such as not obtaining sufficient effect to control undesirable plants, the components in the combination weaken each other, and also the combination harms useful plants and deteriorates the growth or quality of useful plants. Under these circumstances, the object of the present invention is to provide a method for controlling undesirable plants and promoting the growth of beneficial plants. Solution to the Problem The present invention provides a method for controlling unwanted plants and promoting the growth of beneficial plants, comprising applying to unwanted plants, a place where unwanted plants grow, or a place where beneficial plants grow, an effective amount of thiafenacil (a1) and at least one herbicidal compound (a2) selected from the following compound group A: herbicidal compounds S-metolachlor, metribuzin, pyroxasulfone (pyroxasulfone), pethoxamid, tri-allate, and dimethenamid-P. The present invention also provides a mixture containing thiafenacyl (a1) and at least one herbicide compound (a2) selected from the above compound group A as active ingredients, with a weight ratio of (a1) to (a2) of 1:0. It provides an agricultural composition of between 8 and 1:1000 (hereinafter sometimes referred to as the composition of the present invention). The present invention also provides a combination of tiafenacil (a1) and the above compound group A as the active ingredient. In this specification, the composition of the present invention includes the above combination. Advantageous Effects of the Invention The composition of the present invention has excellent herbicidal effects against undesirable plants and growth-promoting effects on useful plants, which are not expected from the use of (a1) and (a2) alone. As a result, the dose of tiafenacil (a1) and/or the dose of at least one herbicidal compound (a2) selected from the following compound group A can be reduced, and thus the present invention is useful in actual use. DETAILED DESCRIPTION According to the present invention, unwanted plants can be controlled by applying an effective amount of thiafenacil (a1) and at least one herbicidal compound selected from the compound group A (a2) to unwanted plants, to a place where unwanted plants grow, or to a place where beneficial plants grow. Additionally, undesirable plants can be controlled by applying an effective amount of the composition of the present invention to undesirable plants, to a place where undesirable plants are growing, or to a place where beneficial plants are growing. According to the present invention, the growth of beneficial plants can be promoted by applying an effective amount of thiafenacil (a1) and at least one herbicidal compound selected from compound group A (a2) to unwanted plants, to a place where unwanted plants grow, or to a place where beneficial plants grow. Additionally, an effective amount of the composition of the present invention can be applied to unwanted plants, to a place where unwanted plants grow, or to a place where useful plants grow, to promote the growth of beneficial plants. To promote the growth of beneficial plants, an effective amount of tiafenacil (a1), the herbicide compound (a2) or the composition of the present invention can be applied to unwanted plants, to a place where unwanted plants grow, or to a place where beneficial plants are grown, before starting the cultivation of beneficial plants, such as before sowing seeds of beneficial plants or planting seedlings of beneficial plants. After application, the growth of beneficial plants is encouraged by sowing seeds or planting seedlings. The composition of the present invention contains thiafenacyl (a1) and at least one herbicidal compound (a2) selected from the following compound group A as active ingredients. Compound group A is a group consisting of S-metolachlor, metribuzin, pyroxasulfone, pethoxamide, tri-allate and dimethenamide-P herbicide compounds (a2). Among these, the herbicidal compound (a2) is preferably S-metolachlor, metribuzin, pyroxasulfone or tri-allate, more preferably S-metolachlor or metribuzin, or more preferably S-metolachlor, pyroxasulfone or tri-allate. The herbicide compound (a2) is also preferably S-metolachlor or pyroxasulfone or more preferably S-metolachlor or tri-allate and particularly preferably S-metolachlor. Thiafenacil (a1) and the herbicide compound (a2) are sometimes referred to as their salts, alkyl esters, hydrates, different crystal forms, various structural isomers, etc. may have and these are of course included in the present invention. The mixing weight ratio of Tiafenacil (a1) to the herbicidal compound (a2) of the present invention depends on the type of active ingredient formulation mixed, weather conditions and the type of undesirable plants to be controlled, their growth status, etc. It cannot be defined generally because it changes depending on various conditions such as. However, the (a1):(a2) mix weight ratio is usually 1:0. In one case of 8, the (a1):(a2) mixture weight ratio is more preferably 1:1. 2 to 1:180, more preferably in the case of metribuzin, the (a1):(a2) mix weight ratio is more preferably 1:1. It is between 2 and 1:88. In a case where the herbicide compound (a2) is pyroxasulfone, in a case where it is (a1):(a2), the (a1):(a2) mixture weight ratio is more preferably from 1:7 to 1:200, in a case where it is (a2) pethoxamid, the (a1):(a2) mixture weight ratio is more preferably from 1:8. In a case where the herbicide compound (a2) is dimethenamid-P, the (a1):(a2) mixture weight ratio is from 1:120 to 1:120. In the method of this invention, the doses of thiafenacil (a1) and herbicide compound (a2) are determined by various factors such as the type of active ingredient formulation mixed, weather conditions and the type of undesirable plants to be controlled, their growth status, etc. Since it varies depending on various conditions such as, it cannot be defined in general. However, the dose of (a1) is generally between 0.01 and 400 g per hectare, preferably in a case where the herbicidal compound (a2) is S-metolachlor, the dose is more preferably in the range of 0.01 to 400 g per hectare. In a case where the herbicidal compound (a2) is metribuzin, the dose is more preferably in the range of 0.01 to 400 g per hectare. In a case where the herbicidal compound (a2) is pyroxasulfone, the dose is more preferably in the range of 0.01 to 400 g per hectare. In a case where the herbicidal compound (a2) is tri-allate, the dose is more preferably in the range of 10 g per hectare. In a case where the compound (a2) is dimethenamid-P, the dose is more preferably in the range of 0.01 to 400 g per hectare. When the composition of the present invention is applied to unwanted plants, a place where unwanted plants grow, or a place where useful plants grow, it shows excellent controlling effects on unwanted plants and promotes the growth of useful plants. This includes various non-agricultural areas such as parkland, cemeteries, residential areas, embankments, gardens, parks, forests, roads, farm roads, fields and factory sites, and agricultural areas such as crop fields, orchards, berry fields and lawns. In particular, the composition of the present invention is preferably applied to an agricultural field or a place where useful plants will be grown in the future. Cultivation means a series of actions starting from planting the seed, sowing the seed or planting the vegetative reproductive organ of useful plants to produce a harvest of useful plants. It also means the seed, seed or seedling in question. The application method of the composition of the present invention is appropriately selected from soil tillage, leaf tillage, water tillage, and the like. The application time of the composition of the present invention is appropriately selected from after harvesting the useful plants to before the next planting and after planting to before the budding of the useful plants. In case of soil application, the dose (a1) is preferably 0.01 to 400 g per hectare, more preferably 1 to 4000 g. In case of foliar application, the dose (a1) is preferably applied to hectares. Soil tillage is a method of applying the composition of the present invention to soils before the budding of useful plants or undesirable plants. By applying the composition of the present invention through soil treatment, a layer treated with the composition of the present invention is formed on the soil surface, and the effects of the composition of the present invention are demonstrated to each plant. Foliar application is a method of applying the composition of the present invention to the leaves of plants after the beneficial plants or undesirable plants have budded. By applying the composition of the present invention via foliar application, the ingredients are absorbed from or brought into contact with the leaves, and the effects of the composition of the present invention are exerted on each plant. Water treatment is the method of applying the composition of the present invention to a flooded paddy field where beneficial plants are growing or undesirable plants are growing. By applying the composition of the present invention to water treatment, the effects of the composition of the present invention are demonstrated to each plant. In each of the above embodiments, the composition of the present invention is diluted to a predetermined concentration, for example with water, and sprayed with a sprayer onto unwanted plants, a place where unwanted plants grow, or a place where beneficial plants grow. Additionally, a flying device such as an automated helicopter or drone, a power dispersant, or a boom sprayer may be used. In each of the above embodiments, the dosage of the composition of the present invention is such that the above mixing ratio of tiafenacil (a1) and the herbicide compound (a2) or the dosages of the respective components are applied. In the present invention, "promoting the growth of useful plants" (hereinafter sometimes means increasing the number of healthy leaves, increasing the height of the plant, increasing the growth of roots or root density, increasing the number or weight of seeds or fruits, or increasing the number of flowers or number of fruits. The composition of the present invention is particularly suitable for increasing the weight of the plant and/or the weight of the seeds. Growth promotion can be measured and evaluated by the following method. (1) Evaluation by weight of plant The above-ground part of each useful plant is cut and its weight is measured to obtain the raw weight, or the cut sample is dried and its weight is measured to obtain the dry weight. (2) Evaluation according to the area of leaves The leaves of each useful plant are collected and the total area of leaves measures one leaf area (3) Evaluation according to the number of healthy leaves The number of healthy leaves of each useful plant is counted. (4) Evaluation according to plant height The above-ground part of each useful plant is held vertically and the height from the soil surface to the highest position is measured. (5) Evaluation according to root growth or root density The roots of each useful plant are dug and their weight is measured to obtain the raw weight, or the obtained sample roots are dried and their weight is measured to obtain the dry weight. (6) Evaluation by number or weight of seeds or fruits Seeds or fruits of each useful plant are collected and their number is counted or their weight is measured to obtain the total weight or average. (7) Evaluation according to the number of flowers or number of fruits The number of flowers or number of fruits of each useful plant is counted. The composition of the present invention can be used to control or inhibit the growth of undesirable plants, such as barnyard grass (Echinochloa crus-galli, Echinochloa oryzicola), southern crabgrass (Digitaria ciliaris, Digitaria adscendens), large black bastgrass (Digitaria sanguinalis), smooth crabgrass (Digitaria ischaemum), East India crabgrass (Digitaria microbachne), Jamaican crabgrass (Digitaria horizontalis), green foxtail (Setaria viridis), giant foxtail (Setaria faberi), yellow foxtail (Setaria lutescens), goose grass (Eleusine indica), wild oats (Avena fatua), johnsongrass (Sorghum halepense), quackgrass (Agropyron repens), feathery signal grass (Urochloa villosa), alexandergrass (Brachiaria plantaginea), guineagrass. (Panicum maximum), paragrass (Panicum purpurascens), Chinese sprangletop (Leptochloa chinensis), red sprangletop (Leptochloa panicea), annual bluegrass (Poa annua), short-haired foxtail (Alopecurus aequalis), black grass (Alopecurus myosuroides), cholorado bluestem (Agropyron tsukushiense), broad-leaved signal grass. (Brachiaria platyphylla), southern dune grass (Cenchrus echinatus), Italian grass (Lolium multiflorum), bermuda grass (Cynodon dactylon), violet crabgrass (Digitaria violascens), knotweed (Paspalum distichum), little quakinggrass (Briza minor), sweet vernalgrass (Anthoxanthum odoratum), autumn panicum (Panicum). dichotomiflorum), shattercane (Sorghum bicolor) and American Poaceae weeds such as sloughgrass (Beckmannia syzigachne); Brass sedge (Cyperus iria), purple sedge (Cyperus rotundus), yellow sedge (Cyperus esculentus), tidal marsh sedge (Cyperus serotinus), small-flowered umbrella sedge (Cyperus difformis), needle thistle (Eleocharis acicularis), water chestnut (Eleocharis). kuroguwai), green kyllinga (Kyllinga brevifolia var. leiolepis), Schoenoplectus nipponicus, cosmopolitan bulrush (Bolboschoenus koshevnikovii), amur cyperus (Cyperus microiria) and rock bulrush (Schoenoplectus juncoides); . Alismataceae weeds such as Japanese ribbon waparo (Sagittaria pygmaea), arrowhead (Sagittaria trifolia), and channel waterweed (Alisma canaliculatum); Pontederiaceae weeds such as heart-shaped false pickle (Monochoria vaginalis) and korsakow monochoria (Monochoria korsakowii); Lythraceae weeds such as Indian disot (Rotala indica) and jerry-jerry (Ammannia multiflora); Elatinaceae weeds such as long-stemmed waterweed (Elatine triandra); Malvaceae weeds such as velvetleaf (Abutilon theophrasti), prickly sida (Sida spinosa), volunteer cotton (Gossypium hirsutum), common mallow (Malva neglecta), small mallow (Malva parviflora) and Venice mallow (Hibiscus trionum); Horsetail (Xanthium strumarium), ragweed (Ambrosia artemisiifolia), thistle (Breea setosa), downy galinsoga (Galinsoga ciliata), wild chamomile (Matricaria chamomilla), scentless chamomile (Tripleurospermum maritimum), may chamomile (Anthemis cotula), downy pyrethrum (Conyza). bonariensis), tall pyrethrum (Conyza sumatrensis), tall goldenrod (Solidago altissima), prickly lettuce (Lactuca serriola), philadelphia pyrethrum (Erigeron philadelphicus), annual pyrethrum (Erigeron annuus), common ground grass (Senecio vulgaris), giant ragweed (Ambrosia trifida), horseweed (Conyza canadensis), dandelion (Taraxacum officinale), devil's herb Asteraceae weeds, such as (Bidens frondosa), beggar's weed (Bidens biternata), feathery fescue (Bidens pilosa), narrow-leaved hawksbeard (Crepis tectorum), Santa Maria fireweed (Parthenium hysterophorus), prickly thistle (Sonchus asper), annual thistle (Sonchus oleraceus), volunteer sunflower (Helianthus annuus), Canada thistle (Cirsium arvense), and clayey aster (Acanthospermum hispidum); black nightshade (Solanum nigrum), jimsonweed (Datura stramonium), cutleaf groundcherry (Physalis angulate var. angulata), horsenettle (Solanum carolinense), cut-leaf nightshade (Solanum triflorum), eastern black nightshade (Solanum ptycanthum), and hairy nightshade (Solanum sarrachoides); slender amaranth (Amaranthus viridis), redroot pigweed (Amaranthus retroflexus), live amaranth (Amaranthus blitum). Japanese strawflower (Achyranthes bidentata var. japonica), palmer amaranth (Amaranthus palmeri), kochia (Bassia scoparia), smooth pigweed (Amaranthus hybridus), slender amaranth (Amaranthus viridis), powell's amaranth (Amaranthus powellii), spiny amaranth (Amaranthus spinosus), clammy goosefoot (Dysphania pumilio), common lambsquarters (Chenopodium album), fat hen (Chenopodium album var. centrorubrum), narrow-leaved goosefoot (Chenopodium pratericola), hanging pigweed (Amaranthus blitoides), Russian thistle (Salsola sp. ) and Amaranthaceae weeds such as waterhemp (Amaranthus tuberculatus); pale wisent (Polygonum lapathifolium), ladysthumb (Polygonum persicaria), wild buckthorn (Polygonum convolvulus), knotweed (Polygonum aviculare), pale wisent (Persicaria Iapathifolia var. Iapathifolia), . Japanese knotweed (Fallopia japonica), oriental lady's thumb (Persicaria longiseta), sheep sorrel (Rumex acetosella subsp. pyrenaicus), Thunberg knotweed (Persicaria thunbergii), Nepalese smartweed (Persicaria nepalensis), Japanese dock (Rumex japonicus), and Pennsylvania smartweed (Persicaria pensylvanica); flexible bitterweed (Cardamine flexuosa), shepherd's purse (Capsella bursa-pastoris), Indian mustard (Brassica juncea), variable-leaf yellowweed (Rorippa indica), swamp yellowweed (Rorippa palustris), volunteer canola (Brassica spp. ), small-seeded false flax (Camelina microcarpa), flixweed (Descurainia sophia), black mustard (Brassica nigra), tumble mustard (Sisymbrium altissimum), wild mustard (Sinapis arvensis), field pennycress (Thlaspi arvense), London rocket (Sisymbrium irio), and pinnate tansymustard (Descurainia pinnata); Brassicaceae weeds such as tall morning glory (Lpomoea purpurea), field bindweed (Calystegia arvensis), ivy-leaved morning glory (Lpomoea hederacea), whole-leaved morning glory (Lpomoea hederacea var. integriuscula), Convolvulaceae weeds such as palmate morning glory (Ipomoea wrightii) and cupped morning glory (Ipomoea lacunosa); Portulacaceae weeds such as purslane (Portulaca oleracea); sickleaf weed (Cassia obtusifolia), red clover (Trifolium pratense), narrow-leaved fig (Vicia sativa subsp. nigra is present. segetalis), white clover (Trifolium repens), small fig (Vicia hirsuta), volunteer clover (Medicago sativa), black clover (Medicago lupulina), common lespedeza (Kummerowia striata), suckling clover (Trifolium dubium), bird's foot clover (Lotus corniculatus var. japonicus), Florida begganNeed (Desmodium tortuosum) and hemp sesbania (Sesbania herbacea); Common chickweed (Stellaria media), water chickweed (Stellaria aquatica), sticky chickweed (Cerastium glomeratum), . Japanese pearl grass (Sagina japonica), marsh bird grass, marsh star grass (Stellaria uliginosa var. undulata), pot marigold (Calendula officinalis) and mullein (Vaccaria hispanica); Lamiaceae weeds such as Balliaceae (Lamium amplexicaule) and purple nettle (Lamium purpureum); Rubiaceae weeds such as ragweed (Galium spurium), yaki weed (Galium aparine) and Florida hazelnut (Richardia scabra); Euphorbiaceae weeds such as three-seeded copperleaf (Acalypha australis), spotted euphorbia (Euphorbia maculata), texasweed (Caperonia palustris) and Virginia copperleaf (Acalypha virginica); Commelinaceae weeds such as Asian sunflower (Commelina communis); Linderniaceae weeds, such as common false pimpernel (Lindernia procumbens), false pimpernel (Lindernia dubia subsp. major), false pimpernel (Lindernia dubia subsp. dubia) and (Lindernia micrantha); Plantaginaceae weeds such as Dopatrium (Dopatrium junceum), Gratiola japonica), Asiatic plantain (Plantago asiatica), Persian speedwell (Veronica persica), and corn speedwell (Veronica arvensis); Molluginaceae weeds such as halibut (Mollugo verticillata); Onagraceae weeds such as cutleaf axecephala (Oenothera iaciniata) and American willow (Epilobium ciliatum); Geraniaceae weeds such as red-stemmed filaree (Erodium cicutarium); Apiaceae weeds such as poison hemlock (Conium maculatum); Urticaceae weeds such as nettle (Urtica urens); Zygophyllaceae weeds such as puncturevine (Tribulus terrestris); and Cucurbitaceae weeds such as Burcucumber (Sicyos angulatus). The composition of the present invention can be suitably used to control or inhibit the growth of undesirable plants, for example, Poaceae weeds such as barnyard grass (Echinochloa crus-galli, Echinochloa oryzicola), southern crabgrass (Digitaria ciliaris, Digitaria adscendens), large crabgrass (Digitaria sanguinalis), smooth crabgrass (Digitaria ischaemum), East Indian crabgrass (Digitaria microbachne), Jamaican crabgrass (Digitaria horizontalis), giant foxtail (Setaria faberi), goosegrass (Eleusine indica), wild oats (Avena fatua), Chinese sprangleball (Leptochloa chinensis), annual bluegrass (Poa annua), shorthair foxtail (Alopecurus aequalis), blackgrass (Alopecurus myosuroides), Italian ryegrass (Lolium multiflorum), violet crabgrass (Digitaria violascens), autumn panicum (Panicum dichotomiflorum) and American sloughgrass (Beckmannia syzigachne); Purple sedge (Cyperus rotundus), yellow sedge (Cyperus esculentus) and green kyllinga (Kyllinga brevifolia var. Cyperaceae weeds such as leiolepis); Malvaceae weeds such as Velvetleaf (Abutilon theophrasti); Asteraceae weeds, such as common ragweed (Ambrosia artemisiifolia), downy galinsoga (Galinsoga ciliata), tall pyrethrum (Conyza sumatrensis), philadelphia pyrethrum (Erigeron philadelphicus) and dandelion (Taraxacum officinale); Solanaceae weeds such as black nightshade (Solanum nigrum); Redroot pigweed (Amaranthus retroflexus), Powell's amaranth (Amaranthus powellii), livid amaranth (Amaranthus blitum), palmer amaranth (Amaranthus palmeri), tender pigweed (Amaranthus hybridus), slender amaranth (Amaranthus viridis), prickly amaranth (Amaranthus spinosus), kochia (Bassia scoparia), common lamb's lettuce (Chenopodium album), fat grouse (Chenopodium album var. centrorubrum) and Amaranthaceae weeds such as waterhemp (Amaranthus tuberculatus); pale wisent (Polygonum lapathifolium), pale wisent (Persicaria Iapathifolia var. nepalensis); Brassicaceae weeds such as flexible bittercress (Cardamine flexuosa), shepherd's purse (Capsella bursa-pastoris) and swamp yellow cress (Rorippa palustris); Convolvulaceae weeds such as tall morning glory (Lpomoea purpurea), ivy-leaved morning glory (Lpomoea hederacea), field bindweed (Convolvulus arvensis) and seedless morning glory (Lpomoea lacunosa); Portulacaceae weeds such as purslane (Portulaca oleracea); Narrow-leaved fig (Vicia sativa subsp. nigra is present. segetalis) and common Iespedeza (Kummerowia striata); Lamiaceae weeds such as common chickweed (Stellaria media) and sticky chickweed (Cerastium glomeratum); Rubiaceae weeds such as yaki weed (Galium spurium); Commelinaceae weeds such as Asian sunflower (Commelina communis); and Plantaginaceae weeds such as Persian speedwell (Veronica persica). The composition of the present invention is useful for controlling or inhibiting the growth of undesirable plants, such as Poaceae weeds, Cyperaceae weeds, Malvaceae weeds, Asteraceae weeds, Solanaceae weeds, Amaranthaceae weeds, Polygonaceae weeds, Brassicaceae weeds, Convolvulaceae weeds, Fabaceae weeds, Caryophyllaceae weeds, Lamiaceae weeds, Rubiaceae weeds, Commelinaceae weeds and Plantaginaceae weeds. The composition of the present invention is more useful for controlling or inhibiting the growth of unwanted plants, such as Poaceae weeds, Asteraceae weeds and Amaranthaceae weeds. The composition of the present invention is particularly useful for controlling or inhibiting the growth of undesirable plants such as Italian ryegrass (Lolium multiflorum), goose grass (Eleusine indica), waterhemp (Amaranthus tuberculatus) and horse grass (Conyza canadensis). The composition of the present invention is used in growing water utilizing plants to control or inhibit the growth of the above undesirable plants, e.g. grass, soybean (Glycine max), alfalfa (Medicago sativa), chickpea (Cicer arietinum), pea (Pisum sativum), lentil (Lens culinaris), cotton (Gossypium spp. ) wheat (Triticum aestivum), rice (Oryza sativa), barley (Hordeum vulgare), rye (Secale cereale), oats (Avena sativa), corn (Zea mays), sorghum (Sorghum spp.). ), Chinese rapeseed (Brassica rapa var. nippo-oleifera), canola (Brassica napus), sunflower (Helianthus annuus), sugar beet (Beta vulgaris ssp. vulgaris, Beta vulgaris var. saccharifera, Beta vulgaris var. hortensis), sugar cane (Saccharum officinarum), peanut (Arachis hypogaea), flax (Linum usitatissimum), tabaco (Nicotiana tabacum) and coffee (Coffea arabica). Therefore, the composition of the present invention is preferably used in a place where the above beneficial plants grow or in a place where the above beneficial plants are cultivated. The composition of the present invention is particularly used where useful plants such as grass, soybean, cotton, wheat, rice, corn, Chinese rapeseed, canola, sunflower, sugar beet, sugar cane, peanut, flax, tabasco or coffee grow or where useful plants are cultivated. The composition of the present invention is preferably used in a place where useful plants grow or in a place where useful plants such as grass, soybeans, wheat, rice or corn are grown. The composition of the present invention is more preferably used in a place where beneficial plants such as soybeans, wheat, rice or corn grow or where beneficial plants are cultivated. Beneficial plants include plants that have been developed to resist a herbicide by conventional breeding methods, for example, an HPPD inhibitor such as isoxaflutole, an ALS inhibitor such as imazethapyr or thifensulfuron-methyl, an EPSP synthase inhibitor such as glyphosate, a glutamine synthase inhibitor such as glufosinate, an acetyl CoA carboxylase inhibitor such as sethoxydim, bromoxynil, dicamba, or 2,4-D. Beneficial plants may be, for example, particularly imidazolinone herbicide-resistant corn and canola varieties (trade name: Clearfield) and STS soybeans resistant to sulfonylurea ALS inhibitor-type herbicides. Useful plants include transgenic plants produced by gene modification. Examples of transgenic plants include herbicide-resistant transgenic plants, pest-resistant transgenic plants, plant component-related transgenic plants, and phytopathogen-resistant transgenic plants. Additionally, useful plants include stacked varieties that incorporate the useful characters of such transgenic plants. The composition of the present invention can be effectively used to selectively control undesirable plants or inhibit their growth in the cultivation of various transgenic plants of the above useful plants (such as soybean, cotton, rapeseed, and corn). Herbicide-resistant transgenic plants include glyphosate-resistant maize, soybean, cotton, canola (rapeseed) and sugar beet; glufosinate-resistant maize, soybean, cotton and rapeseed; and bromoxynil-resistant cotton. Transgenic plants resistant to pests include, for example, plants that have acquired the ability to synthesize toxins known to be synthesized by the genus Bacillus. Toxins synthesized by transgenic plants confer resistance to plants, particularly against Coleoptera insects, Hemiptera insects, Diptera insects, Lepidoptera insects and nematodes. The above toxins include insecticidal proteins derived from Bacillus cereus and Bacillus popilliae; β-endotoxins such as Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, CryBBb1, and CryQC derived from Bacillus thuringiensis; insecticidal proteins such as VlP1, VlP2, VlP3, and VlP3A; insecticidal proteins from nematodes; animal-produced toxins such as scorpion toxin, spider toxin, bee toxin, and insect-specific neurotoxin; filamentous fungal toxin; plant lectin; agglutinin; protease inhibitors such as trypsin inhibitor, serine protease inhibitor, patatin, cystatin, and papain inhibitor; Ribosome-inactivating proteins (RIP) such as ricin, misir-RIP, abrin, luffin, saporin, and bryodin; steroid-metabolizing enzymes such as 3-hydroxysteroid oxidase, ecdysteroid-UDP-glucosyltransferase, and cholesterol oxidase; ecdysone inhibitor; HMG-CoA reductase; ion channel blockers such as sodium channel blocker and calcium channel blocker; juvenile hormone esterase; diuretic hormone receptor; stilbene synthase; bibenzyl synthase; chitinase; and glucanase. They also include hybrid toxins of β-endotoxin proteins such as Cry35Ab and insecticidal proteins such as VlP1, VlP2, VlP3 and VlP3A, toxins lacking some of these, and modified toxins. Transgenic plants related to plant components include plants with altered oil components or increased amino acid content. Phytopathogen-resistant transgenic plants include plants that have been endowed with the ability to produce anti-pathogenic substances with selective action. The transgenic plants are not particularly limited and include, for example, glyphosate-resistant maize, soybean, cotton, rapeseed and sugar beet varieties (trade name: RoundupReady, Agrisure, Gly-Tol); glufosinate-resistant maize, soybean, cotton and rapeseed varieties (trade name: LibertyLink); bromoxynil-resistant cotton variety (trade name: BXN); maize and soybean varieties resistant to both glyphosate and ALS inhibitors (trade name: Optimum, GAT) BXN); maize and soybean varieties resistant to both glyphosate and ALS inhibitors (trade name: Optimum, GAT); imidazolinone compound-resistant variety (trade name: lMl); Maize variety expressing Cry1Ab toxin (commercial name: YieldGard); Maize variety expressing CryBBb1 toxin (commercial name: YieldGard Rootworm); Maize variety expressing Cry1Ab and CryBBb1 toxins (commercial name: YieldGard Plus); Maize variety expressing Cry1Fa2 toxin and phosphinothricin N-acetyltransferase (PAT) to confer resistance to glufosinate (commercial name: Herculex I); Cotton variety expressing Cry1Ac toxin (commercial name: NuCOTNBBB, Bollgard I); Cotton variety expressing Cry1Ac and Cry2Ab toxins (commercial name: Bollgard II); Cotton variety expressing VlP toxin (commercial name: VlPCOT); a maize variety (Herculex I) expressing the Cry1Fa2 toxin and phosphinothricin N-acetyltransferase (PAT) to confer resistance to glufosinate; a variety with the GA21 glyphosate-resistant trait (trade name: NatureGard Agrisure GT Advantage); a variety with the Bt11 corn borer (CB) trait (trade name: Agrisure CB Advantage); a low-linolenic acid soybean variety with reduced linolenic acid content (trade name: VlSTlVE); and a maize variety with increased lysine or oil content. The composition of the present invention containing tiafenacil (a1) and the herbicidal compound (a2) together exerts higher effects that persist for a long period of time, as shown in the Examples described later, compared to a case where the respective active ingredients are applied separately. Therefore, in practical application, for example, the effects of agricultural composition, the effect of rainfall or temperature after application, etc. It is very useful in an application where it can be reduced with . In the present invention, the composition of the present invention can also be mixed with other herbicide compounds as the case may be. Such other herbicidal compounds can be appropriately selected from various known herbicidal compounds, taking into consideration the application of the composition of the present invention, the type and growth state of undesirable plants to be controlled, and the like. Moreover, the composition of the present invention can be mixed or used with a fungicide, an antibiotic, a plant hormone, an insecticide, a fertilizer, a preservative or the like, so that more excellent effects or functions can be obtained in some cases. Such other herbicidal compounds include, for example, the following compounds (common names), and one component or two or more components can be selected appropriately. Here, a different herbicidal compound from herbicidal compound (a2) is selected as the other herbicidal compound to be further mixed. That is, in a case where the herbicide compound (a2) is metribuzin, a compound other than metribuzin is selected as the other herbicide compound to be further mixed. DB-dimethylammonium, 2,4-DB-isoctyl, 2,4-DB-potassium, 2,4-DB-sodium, 2,4-D choline salt, dichlorprop, dichlorprop-butotyl, dichlorprop-dimethylammonium, dichlorprop-isoctyl, dichlorprop-potassium, dichlorprop-P, dichlorprop-P-dimethylammonium, dichlorprop-P- potassium, dichlorprop-P-sodium, MCPA, MCPA-butotyl, MCPA-dimethylammonium, MCPA-2-ethylhexyl, MCPA-potassium, MCPA-sodium, MCPA-thioethyl, MCPB, MCPB- ethyl, MCPB-sodium, mecoprop, mecoprop-butotyl, mecoprop-sodium, mecoprop-P, mecoprop-P-butotyl, compounds that are believed to have herbicidal effects by disrupting the hormone activities of plants, such as mecoprop-P-dimethylammonium, mecoprop-P-2-ethylhexyl, mecoprop-P-potassium, naproanilide, clomeprop and phenoxy compounds such as HlA-1; 2,3,6-TBA, dicamba, dicamba-butotyl, dicamba-diglycolamine, dicamba-dimethylammonium, dicamba-diolamine, dicamba-isopropylammonium, dicamba-potassium, dicamba-sodium, picloram, picloram-dimethylammonium, picloram-isoctyl, picloram-potassium, picloram- triisopropanolammonium, picloram-triisopropylammonium, picloram-trolamine, triclopyr, triclopyr-butotyl, triclopyr-triethylammonium, clopyralid, clopyralid-olamine, clopyralid-potassium, clopyralid-triisopropanolammonium, aminopyralid, aminocyclopyrachlor, halauxifen, halauxifen-methyl, aromatic carboxylic acid compounds such as indolauxipyr and BAS-534; and others such as naptalam, naptalam-sodium, benazoline, benazoline-ethyl, quinclorac, quinmerac, diflufenzopyr, diflufenzopyr-sodium, fluroxypyr, fluroxypyr-2-butoxy-1-methylethyl, fluroxypyr-meptyl, chlorflurenol, chlorflurenol-methyl, clacyfos and fluchloraminopyr. compounds. (2) Urea compounds such as chlorotoluron, diuron, fluometuron, linuron, isoproturon, metobenzuron, tebuthiuron, dimefuron, isouron, carbutylate, methabenzthiazuron, metoxuron, metoburomuron, monolinuron, neburon, and siduron; triazine compounds such as terbumeton, trietazine, simazine, atrazine, atratone, simetryn, prometryn, dimethametryn, terbuthylazine, cyanazine, ametryn, cybutryne, terbutryn, propazine, metamitron, and prometon; triazinone compounds such as hexazinone, metribuzin, and metamitron; uracil compounds such as bromacil, bromacil-lithium, lenasil, and terbacil; anilide compounds such as propanil, cypromid, tetflupyrolimet, and pentanochlor; carbamate compounds such as desmedipham and phenmedipham; hydroxybenzonitrile compounds such as bromoxynil, bromoxynil-octanoate, bromoxynil-heptanoate, ioxynil, ioxynil-octanoate, ioxynil-potassium, and ioxynil-sodium; and other compounds such as pyridate, bentazone, bentazone-sodium, amicarbazone, methazole, and chloridazon, which are believed to exert herbicidal effects by inhibiting plant photosynthesis. (3) Quaternary ammonium salt compounds such as paraquat and diquat are thought to spontaneously transform into free radicals to form active oxygen in the plant body and exhibit rapid herbicide activity. (4) Compounds believed to exhibit herbicidal effects by inhibiting the chlorophyll biosynthesis of plants and abnormally accumulating a photosensitizing peroxide substance in the plant body, such as diphenylether compounds such as nitrofen, chlomethoxyfen, bifenox, acifluorfen, acifluorfen-sodium, fomesafen, fomesafen-sodium, oxyfluorfen, lactofen, aclonifen, ethoxyfen-ethyl, fluoroglycofen-ethyl, and fluoroglycofen; cyclic imide compounds such as chlorphthalim, flumioxazin, flumiclorac, flumiclorac-pentyl, cinidon-ethyl, fluthiacet-methyl, and EK-5385; and oxadiargyl, oxadiazon, sulfentrazone, carfentrazone-ethyl, thidiazimin, pentoxazone, azafenidine, pyraflufen-ethyl, benzfendizone, butafenacil, saflufenacil, epyrifenacil, fluazolate, profluazole, flufenpyr-ethyl, bencarbazone, pyraclonil, cyclopyranil, trifludimoxazine and other compounds such as flufenoximacil. (5) Pyridazinone compounds such as norflurazone and metflurazone; pyrazole compounds such as pyrazolinate, pyrazoxyfen, benzofenap, topramezone, cypyrafluone, bipyrazone, tolpyralate and pyraquinate; and other compounds such as amitrole, fluridone, flurtamone, diflufenican, methoxyphenone, clomazone, broclozone, bixlozone, mesotrione, tembotrione, tefuryltrione, fenquinotrione, compounds characterized by bleaching activity by inhibiting the chromogenesis of plants such as cyclopyrimorate, difenzoquat, difenzoquat-methylsulfate, isoxachlortole, benzobicyclon, bicyclopyrone, picolinafen, beflubutamide, ketospiradox, ketospiradox-potassium and flusulfinam, and carotenoids such as cyclopyrimorate, difenzoquat, difenzoquat-methylsulfate, isoxachlortole, benzobicyclon, bicyclopyrone, picolinafen, beflubutamide, ketospiradox, ketospiradox-potassium, and flusulfinam, which are believed to exert herbicidal effects. (6) Aryloxyphenoxypropionic acid compounds such as diclofop-methyl, diclofop, pirifenop-sodium, fluazifop-butyl, fluazifop, fluazifop-P, fluazifop-P-butyl, haloxyfop-methyl, haloxyfop, haloxyfop-ethotyl, haloxyfop-P, haloxyfop-P-methyl, quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, cyhalofop-butyl, fenoxaprop-ethyl, fenoxaprop- P, fenoxaprop-P-ethyl, clodinafop-propargyl, clodinafop, propaquizafop, HNPC-A8169 and SYP-1924; Compounds believed to exert herbicidal effects on plants by inhibiting fatty acid biosynthesis, such as cyclohexanedione compounds, such as alloxydim-sodium, alloxydim, clethodim, sethoxydim, tralkoxydim, butroxydim, tepraloxydim, profoxydim, and cycloxydim; and phenylpyrazoline compounds, such as pinoxaden. (7) Compounds believed to have herbicidal effects by inhibiting the biosynthesis of an amino acid in plants, such as sulfonylurea compounds such as chlorimuron-ethyl, chlorimuron, sulfometuron-methyl, sulfometuron, primisulfuron-methyl, primisulfuron, bensulfuron-methyl, bensulfuron, chlorsulfuron, metsulfuron-methyl, metsulfuron, cinosulfuron, pyrazosulfuron-ethyl, pyrazosulfuron, flazasulfuron, rimsulfuron, nicosulfuron, imazosulfuron, flucetosulfuron, cyclosulfamuron, prosulfuron, flupyrsulfuron-methyl-sodium, flupyrsulfuron, triflusulfuron-methyl, triflusulfuron, halosulfuron-methyl, halosulfuron, thifensulfuron-methyl, thifensulfuron, ethoxysulfuron, oxasulfuron, ethametsulfuron, ethametsulfuron-methyl, iodosulfuron, iodosulfuron-methyl-sodium, sulfosulfuron, triasulfuron, tribenuron-methyl, tribenuron, tritosulfuron, foramsulfuron, trifloxysulfuron, trifloxysulfuron-sodium, mesosulfuron-methyl, mesosulfuron, orthosulfamuron, amidosulfuron, azimsulfuron, propyrisulfuron, metasulfuron, methiopyrsulfuron, monosulfuron-methyl, iofensulfuron and iofensulfuron-sodium; triazolopyrimidinesulfonamide compounds such as flumetsulam, metosulam, dimesulfazet, diclosulam, cloransulam-methyl, florasulam, penoxsulam and pyroxsulam; imidazolinone compounds such as imazapyr, imazapyr-isopropylammonium, imazethapyr, imazethapyr-ammonium, imazaquin, imazaquin-ammonium, imazamox, imazamox-ammonium, imazamethabenz, imazamethabenz-methyl and imazapic; pyrimidinylsalicylic acid compounds such as pyrithiobac-sodium, bispyribac-sodium, pyriminobac-methyl, pyribenzoxim, pyriftalide and pyriflubenzoxim; sulfonylaminocarbonyltriazolinone compounds such as flucarbazone, flucarbazone-sodium, propoxycarbazone-sodium, propoxycarbazone and thiencarbazone-methyl; sulfoneanilide compounds such as pyrimisulfan and triafamone; and other compounds such as glyphosate, glyphosate-sodium, glyphosate-potassium, glyphosate-ammonium, glyphosate-diammonium, glyphosate-isopropylammonium, glyphosate-trimesium, glyphosate-sesquisodium, glufosinate, glufosinate-ammonium, glufosinate-P, glufosinate-P-ammonium, glufosinate-P-sodium, bilanafos, bilanafos-sodium and cinmethylin. (8) Dinitroaniline compounds such as trifluralin, oryzalin, nitralin, pendimethalin, ethalfluralin, benfluralin, prodiamine, butralin, and dinitramine; amide compounds such as bensulide, napropamide, napropamide-M, propyzamide, pronamide, and beflubutamide-M; organic phosphorus compounds such as amiprophos-methyl, butamifos, anilofos, and piperophos; phenyl carbamate compounds such as propham, chlorpropham, barban, and carbetamide; cumylamine compounds such as daimuron, cumyluron, bromobutide, and methyldymron; and other compounds such as dithiopyr, thiazopyr, chlorthal-dimethyl, chlorthal, diphenamid, flamprop-M-methyl, flamprop-M, flamprop-M-isopropyl, and swep, which are believed to exert herbicidal effects by inhibiting plant cell mitosis. (9) Chloroacetamide compounds such as alachlor, metazachlor, butachlor, pretilachlor, metolachlor, S-metolachlor, thenylchlor, pethoxamid, acetochlor, propachlor, dimethenamide, dimethenamide-P, propisochlor and dimethachlor; Compounds that are believed to exert herbicidal effects by inhibiting plant protein biosynthesis or lipid biosynthesis, such as thiocarbamate compounds such as molinate, dimepiperate, pyributicarb, EPTC, butylate, vernolate, pebulate, cycloate, prosulfocarb, esprocarb, thiobencarb, diallate, tri-allate, and orbencarb, and other compounds such as etobenzanid, mefenacet, flufenacet, tridiphane, fentrazamide, oxaziclomefone, benfuresate, pyroxasulfone, dalapon, dalapon-sodium, TCA-sodium, and trichloroacetic acid. (10) Compounds such as dichlobenil, triaziflam, indaziflam, flupoxam and isoxaben are believed to have herbicidal effects by inhibiting cellulose biosynthesis in plants. (11) Other herbicides such as MSMA, DSMA, CMA, endothall, endothall-dipotassium, endothall-sodium, endothall-mono(N,N-dimethylalkylammonium), ethofumesate, sodium chlorate, pelargonic acid, nonanoic acid, fosamine, fosamine-ammonium, ipfencarbazone, acrolein, ammonium sulfamate, borax, chloroacetic acid, sodium chloroacete, cyanamide, methylarsonic acid, dimethylarsinic acid, sodium dimethylarsinate, dinoterb, dinoterb-ammonium, dinoterb-diolamine, dinoterb-acetate, DNOC, ferrous sulfate, flupropanate, flupropanate-sodium, mefluidid, mefluidid-diolamine, metam, metam-ammonium, metam-potassium, metam-sodium, methyl Other herbicides such as isothiocyanate, pentachlorophenol, sodium pentachlorophenoxide, pentachlorophenol laurate, quinoclamin, sulfuric acid, urea sulfate, xanthinosine, herbimycin, unguinol, metatyrosin, sarmentin, thaxtominA, mevalosidine, alpha-limonene, piribambenz-propyl, piribambenz-isopropyl, iptriazopyrid, asulam, asulam- sodium, icafolin, etc. (12) Microorganisms believed to have herbicidal effects as parasites on plants, such as Xanthomonas campestris, Exserohilum monoceras or Drechslera monoceras. One compound or two or more compounds can be appropriately selected from the above other herbicidal compounds. Other herbicide compounds are not limited to the above. As regards the application of the composition of the present invention, application to unwanted plants, application to a place where plants grow (before or after emergence of plants), or application to a place where useful plants grow can be optionally selected. Additionally, tiafenacil (a1) and the herbicidal compound (a2) can be formulated separately to be mixed for use at the time of application or formulated together and then applied. The following can be mentioned as examples of a specific application method. 1. It is formulated by mixing tiafenacil (a1) and herbicidal compound (a2) and the formulation is applied as is. 2. Tiafenacil (a1) and the herbicide compound (a2) are mixed and formulated together, and the formulation is diluted to a predetermined concentration, for example, with water, and, as the case may be, an agricultural spreader (such as a surfactant, a vegetable oil, or a mineral oil) is added to the diluted solution, and the diluted solution is applied. 3. Thiafenacil (a1) and the herbicidal compound (a2) are formulated separately and the formulations are applied as is. 4. Tiafenacil (a1) and the herbicide compound (a2) are formulated separately and the formulations are diluted separately, for example with water, to predetermined concentrations, and an agricultural spreader (for example a surfactant, a vegetable oil or a mineral oil) is added to the diluted solutions as the case may be, and the diluted solutions are applied. . Tiafenacil (a1) and the herbicidal compound (a2) are formulated separately and the formulations are mixed, for example diluted with water to a predetermined concentration, and, as the case may be, an agricultural spreader (such as a surfactant, a vegetable oil or a mineral oil) is added to the diluted solution and the diluted solution is applied. The composition of the present invention can be prepared by mixing thiafenacil (a1) and herbicide compound (a2), as active ingredients, with various additives in accordance with conventional formulation methods for agricultural chemicals, and can be applied in the form of various formulations such as powders, granules, water-dispersible granules, wettable powders, tablets, pills, capsules (including a formulation packaged in a water-soluble film), water-based suspensions, oil-based suspensions, microemulsions, suspoemulsions, water-soluble powders, emulsifiable concentrates, soluble concentrates or pastes. The composition of the present invention can be made into any formulation commonly used in the field, as long as the purpose of the present invention is met. During formulation, tiafenacil (a1) and the herbicide compound (a2) can be formulated together or formulated separately. Additives to be used for the formulation include, for example, a solid carrier such as diatomaceous earth, slaked lime, calcium carbonate, talc, white carbon, kaolin, bentonite, kaolinite, sericite, clay, sodium carbonate, sodium bicarbonate, mirabilite, zeolite, starch or saccharides; a solvent such as water, toluene, xylene, solvent naphtha, dioxane, acetone, isophorone, methyl isobutyl ketone, chlorobenzene, cyclohexane, dimethyl sulfoxide, dimethylformamide, dimethylacetamide, N-methyl-2- pyrrolidone or an alcohol (such as propylene glycol); a fatty acid salt, a benzoate, an alkylsulfosuccinate, a dialkylsulfosuccinate, a polycarboxylate, an alkylsulfuric acid ester salt, an alkyl sulfate, an alkyllaryl sulfate, an alkyl diglycol ether sulfate, an alcohol sulfuric acid ester salt, an alkyl sulfonate, an alkylaryl sulfonate, an aryl sulfonate, a lignin sulfonate, an alkyldiphenyl ether disulfonate, a polystyrene sulfonate, an alkylphosphoric acid ester salt, an alkylaryl phosphate, a styryl phosphate, a polyoxyethylene alkyl ether sulfuric acid ester salt, a polyoxyethylene alkylaryl ether sulfate, a polyoxyethylene alkylaryl ether sulfuric acid ester salt, a polyoxyethylene alkyl ether phosphate, polyoxyethylene alkylaryl phosphoric an anionic surfactant or an anionic dispersant, such as a salt of the acid ester, a salt of the polyoxyethylene aryl ether phosphoric acid ester, a formaldehyde-condensed naphthalene sulfonate or a formaldehyde-condensed alkylnaphthalene sulfonate; a nonionic surfactant or a nonionic spreader, such as a sorbitan fatty acid ester, a glycerin fatty acid ester, a fatty acid polyglyceride, a fatty acid alcohol polyglycol ether, acetylene glycol, acetylene alcohol, an oxyalkylene block polymer, a polyoxyethylene alkyl ether, a polyoxyethylene alkyllaryl ether, a polyoxyethylene styryl ether, a polyoxyethylene glycol alkyl ether, a polyethylene glycol, a polyoxyethylene fatty acid ester, a polyoxyethylene sorbitan fatty acid ester, a polyoxyethylene glycerin fatty acid ester, a polyoxyethylene hydrogenated castor oil, or a polyoxypropylene fatty acid ester; and a vegetable oil or mineral oil such as olive oil, kapok oil, castor oil, palm oil, camellia oil, coconut oil, sesame oil, corn oil, rice bran oil, peanut oil, cottonseed oil, soybean oil, rapeseed oil, linseed oil, tung oil, or liquid paraffins. These additives may be appropriately selected for use alone or in combination as a mixture of two or more, as long as the purpose of the present invention is met. Additionally, various commonly used additives such as a filler, a thickener, an anti-settling agent, an anti-freezing agent, a dispersion stabilizer, a purifier, a mold inhibitor, a blowing agent, a disintegrant, and a binder may be used. The mixing ratio of the additives tiafenacil (a1) and the herbicide compound (a2) to each or their mixture, by weight, is approximately 0. 1:99. 9 Examples of preferred embodiments of the present invention will be given below, but it should be understood that the present invention is by no means limited to these. A method comprising applying to unwanted plants, to a place where unwanted plants grow or to a place where beneficial plants grow an effective amount of thiafenacil (a1) and at least one herbicidal compound (a2) selected from the following compound group A: compound group A: herbicidal compounds S-metolachlor, metribuzin, pyroxasulfone, pethoxamid, tri-allate and dimethenamid-P. is at least one member selected from pethoxamid, tri-allate and dimethenamid-P. is at least one member selected from pyroxasulfone and tri-allate. At least one member is chosen from among the allate. At least one member is elected from among At least one member is elected from among pyroxasulfone. at least one member is elected. applied at a dose of (a2) 0.1 to 5000 g/ha. and (a2) is applied at a dose of 1 to 4000 g/ha. An agricultural combination between It is between 1:200. a combination. at least one member selected from pyroxasulfone, pethoxamide, tri-allate and dimethenamide-P. at least one member selected from metribuzin, pyroxasulfone and tri-allate. is at least one member selected from pyroxasulfone and tri-allate. agricultural composition according to [16] or [17]. agricultural composition. and at least one member selected from pyroxasulfone. agricultural composition according to. and at least one member elected from the tri-allate. or tri-allattir. A method comprising applying, before starting the application, to unwanted plants, to a place where unwanted plants are growing or to a place where beneficial plants are growing, an effective amount of tiafenacil (a1) and at least one herbicidal compound (a2) selected from the following compound group A: compound group A; herbicidal compounds S-metolachlor, metribuzin, pyroxasulfone, pethoxamid, tri-allate and dimethenamid-P. (a2) S-metolachlor. a method comprising applying an effective amount of at least one herbicidal compound (a2) selected from compound group A to unwanted plants, to a place where unwanted plants grow or to a place where beneficial plants grow; compound group A: herbicidal compounds S-metolachlor, metribuzin, pyroxasulfone, pethoxamid, tri-allate and dimethenamid-P. It comprises applying to a place where unwanted plants are growing or to a place where useful plants are growing an effective amount of tiafenacil (a1) and at least one herbicidal compound (a2) selected from the following compound group A; compound group A: herbicidal compounds S-metolachlor, metribuzin, pyroxasulfone, pethoxamid, tri-allate and dimethenamid-P. EXAMPLES Examples of the present invention will be described, but the present invention is by no means limited thereto. First, tests on the herbicidal effect of the composition of the present invention on undesirable plants will be described. (1) Herbicidal effect test (Italian ryegrass (Lolium multiflorum)) Field soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. Italian grass 2. 3 to 3. When it reached the 0 leaf stage, a water-based suspension containing tiafenacil as the active ingredient and an emulsifiable concentrate containing S-metolachlor as the active ingredient (trade name: Dual Gold, manufactured by Syngenta) prepared by a conventional method for preparing a water-based suspension was diluted with water (in an amount corresponding to 200 liters per hectare) and sprayed with a small spray gun (model: W-101-132G, manufactured by ANEST IWATA Corporation). 6 after spraying. On the 10th day, the growth status of Italian rye was observed visually and the growth inhibition rate (%) was obtained according to the following standards and the results are shown in Table 1. Evaluation standards: Growth inhibition rate (%) = 0 (equivalent to untreated area) to 100 (complete killing) In addition, the expected value of growth inhibition rate (%) is shown according to the following Colby formula. Colby's formula: X: growth inhibition rate when treated with compound A (g/ha), Y: growth inhibition rate when treated with compound B (g/ha), E: expected growth inhibition rate (expected value) when treated with compound A (g/ha) and compound B (g/ha). That is, when the growth inhibition rate of the composition of the present invention is higher than E (expected value of growth inhibition rate) calculated by the above formula, the combination can be considered to have a synergistic effect. From Table 1, it was found that the combined use of tiafenacil (a1) and S-metolachlor (a2) had better controlling effects on Italian ryegrass than the use of each component alone. The growth inhibition rates of combined use of tiafenacil (a1) and S-metolachlor (a2) were higher than expected values in all dose combinations and therefore, the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) Measured value (expected S-metolachlor 25+750 99(84) +375 99(84) +250 98(83) thifenacil 25 83 12.5 75 S-metolachlor 3000 5 1500 5 (2) Herbicidal effect test ( Italian grass (Lolium multiflorum)) Land soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reached the 2.5 to 3.0 leaf stage, a water-based suspension containing tiafenacil as the active ingredient and an emulsifiable concentrate containing S-metolachlor as the active ingredient (trade name: Dual Gold, manufactured by Syngenta) prepared by a conventional method for preparing water-based suspension was diluted with water (in an amount corresponding to 200 liters per hectare) and sprayed with a small spray gun (model: W-101-132G, manufactured by ANEST IWATA Corporation). 16 days after spraying On the 10th day, the growth status of Italian rye was visually observed and the growth inhibition rate (%) was obtained in accordance with the evaluation standards described in the herbicidal effect test above (1) and the results are shown in Table 2. In addition, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1) and the results are also shown in Table 2. From Table 2, it was found that the combined use of tiafenacil (a1) and S-metolachlor (a2) had better controlling effects on Italian ryegrass than the use of each component alone. The growth inhibition rates of the combined use of tiafenacil (a1) and S-metolachlor (a2) were higher than expected values at all dose combinations and therefore the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) tiafenacil 12.5 30 S-metolachlor 3000 73 1500 55 62.5 0 (3) Herbicidal effect test (Italian ryegrass (Lolium multiflorum)) Field soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reached the 2.8 to 3.2 leaf stage, a water-based suspension containing tiafenacil as the active ingredient, prepared by a conventional method for preparing a water-based suspension, and an emulsifiable concentrate containing S-metolachlor as the active ingredient (trade name: Dual Gold, manufactured by Syngenta), was diluted with water (in an amount corresponding to 200 litres per hectare) and sprayed with a small spray gun (model: W-101-132Câ, manufactured by ANEST IWATA Corporation). 7 days after spraying On the 10th day, the growth status of Italian rye was visually observed and the growth inhibition rate (%) was obtained in accordance with the evaluation standards described in the herbicidal effect test above (1) and the results are shown in Table 3. In addition, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1) and the results are also shown in Table 3. From Table 3, it was found that the use of tiafenacil (a1) and S-metolachlor (a2) in combination at certain doses had better controlling effects on Italian ryegrass than the use of each component alone. The growth inhibition rates of combined use of tiafenacil (a1) and S-metolachlor (a2) at a given dose combination were higher than expected and therefore, the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) thifenacil+ S-metolachlor thifenacil 12.5 53 S-metolachlor 15.6 0 (4) Herbicidal effect test (Italian grass (Lolium multiflorum)) Field soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reaches the 2.5 to 3.0 leaf stage, a water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing a water-based suspension and a wettable powder containing metribuzin as the active ingredient (trade name: SENCOR wettable powder, manufactured by Bayer Crop Science), 0.5% by volume agricultural spreader (trade name: Destiny HC, Winfield Solutions, LLC). It was diluted with water containing 200 litres of water per hectare (manufactured by ANEST IWATA Corporation) and sprayed with a small spray gun (model: W-101-132Câ, manufactured by ANEST IWATA Corporation). 7 days after spraying On the 10th day, the growth status of Italian rye was visually observed and the growth inhibition rate (%) was obtained in accordance with the evaluation standards described in the herbicidal effect test above (1) and the results are shown in Table 4. In addition, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1) and the results are also shown in Table 4. From Table 4, it was found that the combined use of tiafenacil (a1) and metribuzin (a2) had better controlling effects on Italian ryegrass than the use of each component alone. The growth inhibition rates of the combination of tiafenacil (a1) and metribuzin (a2) were higher than expected values in all dose combinations and therefore the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) tiafenacil 6.25 30 metribuzin 1100 88 550 57 275 45 9.38 0 (5) Herbicidal effect test (Italian ryegrass (Lolium multiflorum)) Plateau soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reached the 3.0 to 3.3 leaf stage, a water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing a water-based suspension and a wettable powder containing metribuzin as the active ingredient (trade name: SENCOR wettable powder, manufactured by Bayer Crop Science), water-dispersible granules containing pyroxasulfone as the active ingredient (trade name: Sakura, manufactured by Bayer Crop Science) or a wettable powder containing tri-allate as the active ingredient prepared by a conventional method for preparing a wettable powder (manufactured by Bayer Crop Science) were diluted in water (in an amount corresponding to 200 liters per hectare) and sprayed with a small spray gun (model: W-101-132Câ, manufactured by ANEST IWATA Corporation). 6 after spraying. On the 10th day, the growth status of Italian rye was visually observed and the growth inhibition rate (%) was obtained in accordance with the evaluation standards described in the herbicidal effect test above (1) and the results are shown in Table 5. In addition, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1) and the results are also shown in Table 5. From Table 5, it was found that the combination of tiafenacil (a1) and metribuzin, pyroxasulfone or tri-allate (a2) had better controlling effects on Italian ryegrass compared to the use of each component alone. The growth inhibition rates obtained by using the combination of tiafenacil (a1) and metribuzin, pyroxasulfone or tri-allate (a2) in all combinations were higher than expected values and therefore the use in combination was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) 12.5+15 77(61) Test Compound Dose (g/ha) Growth inhibition rate (%) 6.25+15 63(35) 6.25+7.5 58(33) 6.25+75 52(33) tiafenacil 12.5 60 6.25 33 3.13 17 metribuzin 550 30 275 30 137.5 20 pyroxasulfone 250 23 125 17 62.5 8 Test Compound Dose (g/ha) Growth inhibition rate (%) tri-allate 1250 5 (6) Herbicidal effect test (Italian ryegrass (Lolium multiflorum)) Field soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reaches the 2.5 to 3.0 leaf stage, a water-based suspension containing tiafenacil as the active ingredient and water-dispersible granules containing pyroxasulfone as the active ingredient (trade name: Sakura, manufactured by Bayer Crop Science) prepared by a conventional method for preparing water-based suspension are applied with an agricultural spreader (trade name: Destiny HC, manufactured by Winfield Solutions, LLC) at 0.5% vol. It was diluted with water containing 200 litres of water per hectare (manufactured by ANEST IWATA Corporation) and sprayed with a small spray gun (model: W-101-132Câ, manufactured by ANEST IWATA Corporation). 14 days after spraying On the day, the growth status of Italian ryegrass was visually observed and the growth inhibition rate (%) was obtained in accordance with the evaluation standards described in the herbicidal effect test above (1) and the results are shown in Table 6. In addition, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1) and the results are also shown in Table 6. From Table 6, it was found that the combined use of tiafenacil (a1) and pyroxasulfone (a2) had better controlling effects on Italian ryegrass than the use of each component alone. Growth inhibition rates with the combined use of tiafenacil (a1) and pyroxasulfone (a2) were higher than expected values in all dose combinations and therefore the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) 12.5+30 97(65) 12.5+15 95(63) tiafenacil 12.5 63 pyroxasulfone 1000 72 500 67 250 42 125 35 (7) Herbicidal effect test (Italian ryegrass (Lolium multiflorum)) Plateau soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reaches the 2.8 to 3.0 leaf stage, a water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing a water-based suspension and an emulsifiable concentrate containing pethoxamide as the active ingredient (trade name: Successor 600, manufactured by Stahler Suisse SA) or an emulsifiable concentrate containing dimethenamide-P as the active ingredient (trade name: Fieldstar P emulsifiable concentrate, manufactured by BASF), 0.5% by volume of agricultural spreader (trade name: Destiny HC, Winfield Solutions, LLC). It was diluted with water containing 200 litres of water per hectare (manufactured by ANEST IWATA Corporation) and sprayed with a small spray gun (model: W-101-132Câ, manufactured by ANEST IWATA Corporation). 7 days after spraying On the 10th day, the growth status of Italian ryegrass was visually observed and the growth inhibition rate (%) was obtained in accordance with the evaluation standards described in the herbicidal effect test above (1) and the results are shown in Table 7. Moreover, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1) and the results are also shown in Table 7. From Table 7, it was found that the combined use of tiafenacil (a1) and pethoxamid or dimethenamid-P (a2) had better controlling effects on Italian ryegrass than the use of each component alone. In all combinations, growth inhibition rates with the combined use of tiafenacil (a1) and pethoxamid or dimethenamid-P (a2) were higher than expected values and therefore the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) Test Compound Dose (g/ha) Growth inhibition rate (%) 6.25+60 55(15) tiafenacil 25 33 12.5 37 6.25 15 pethoxamid 1500 12 187.5 0 93.75 0 dimethenamid-P 1500 15 750 12 Test Compound Dose (g/ha) Growth inhibition rate (%) (8) Herbicidal effect test (Italian ryegrass (Lolium multiflorum)) Plateau soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reaches the 3.0 to 3.1 leaf stage, a water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing water-based suspension and an emulsifiable concentrate containing S-metolachlor as the active ingredient (trade name: Dual Gold, manufactured by Syngenta), a wettable powder containing metribuzin as the active ingredient (trade name: SENCOR wettable powder, manufactured by Bayer Crop Science) or water-dispersible granules containing pyroxasulfone as the active ingredient (trade name: Sakura, manufactured by Bayer Crop Science) was diluted with water (in an amount corresponding to 200 litres per hectare) and sprayed with a small spray gun (model: W-101-132Câ, manufactured by ANEST IWATA Corporation). 4th day after spraying On the 10th day, the growth status of Italian ryegrass was visually observed and the growth inhibition rate (%) was obtained in accordance with the evaluation standards described in the herbicidal effect test above (1) and the results are shown in Table 8. In addition, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1) and the results are shown in Table 8. From Table 8, it was found that the combined use of tiafenacil (a1) and S-metolachlor, metribuzin or pyroxasulfone (a2) had better controlling effects on Italian ryegrass than the use of each component alone. The growth inhibition rates of the combined use of tiafenacil (a1) and S-metolachlor, metribuzin or pyroxasulfone (a2) were higher than the expected values in all combinations and therefore the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) Measured value (expected thiefenacil 6.25 20 S-metolachlor 625 13 500 10 metribuzin 938 33 750 20 438 10 pyroxasulfone 375 20 188 10 (9) Herbicide potency test (Italian grass (Lolium multiflorum)) Plateau soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reaches the 3.2 to 4.0 leaf stage, a water-based suspension containing thiafenacyl as the active ingredient and a wettable powder containing tri-allate as the active ingredient, prepared by a conventional method for preparing a water-based suspension, an emulsifiable concentrate containing pethoxamide as the active ingredient (trade name: Successor 600, manufactured by Stahler Suisse SA) or an emulsifiable concentrate containing dimethenamide-P as the active ingredient (trade name: Fieldstar P emulsifiable concentrate, manufactured by BASF), at 0.5% vol. (produced by ) was diluted with water containing (in an amount corresponding to 200 litres per hectare) and sprayed with a small spray gun (model: W-. 6 after spraying. On the 1st day, the growth status of Italian ryegrass was visually observed and the growth inhibition rate (%) was obtained in accordance with the evaluation standards described in the herbicidal effect test above (1) and the results are shown in Table 9. Moreover, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1) and the results are also shown in Table 9. From Table 9, it was found that the combined use of tiafenacil (a1) and tri-allate, pethoxamid or dimethenamid-P (a2) had better controlling effects on Italian ryegrass compared to the use of each component alone. The growth inhibition rates obtained by using tiafenacil (a1) and tri-allate, pethoxamid or dimethenamid-P (a2) in combination were higher than expected values in all combinations and therefore the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) Measured value (expected tri-allate tiafenacil 6.25 30 tri-allate 937.5 3 pethoxamid 625 8 437.5 3 312.5 5 dimethenamid-P 625 40 500 33 (10) Herbicidal effect test (goose grass (Eleusine indica)) Yayla soil 1/1. 000. A pot of 000 hectares was placed and goose grass (Eleusine indica) seeds were planted. When goosegrass reaches the 6.5 to 7.8 leaf stage, a water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing water-based suspension and an emulsifiable concentrate containing S-metolachlor as the active ingredient (trade name: Dual Gold, manufactured by Syngenta), a wettable powder containing metribuzin as the active ingredient (trade name: SENCOR wettable powder, manufactured by Bayer Crop Science), or water-dispersible granules containing pyroxasulfone as the active ingredient (trade name: Sakura, manufactured by Bayer Crop Science) are diluted with water (in an amount corresponding to 200 liters per hectare) and applied with a small spray gun (model: W-101-132Câ, manufactured by ANEST IWATA Corporation). has been sprayed. 13th after spraying On the day, the growth status of goose grass was observed visually and the growth inhibition rate (%) was obtained in accordance with the evaluation standards explained in the herbicidal effect test above (1) and the results are shown in Table 10. Moreover, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1), and the results are also shown in Table 10. From Table 10, it was found that the combined use of tiafenacil (a1) and S-metolachlor, metribuzin or pyroxasulfone (a2) had better controlling effects on goosegrass than the use of each component alone. The growth inhibition rates of the combined use of tiafenacil (a1) and S-metolachlor, metribuzin or pyroxasulfone (a2) were higher than the expected values in all combinations and therefore the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) Measured value (expected Test Compound Dose (g/ha) Growth inhibition rate (%) Measured value (expected 6.25+7.5 96(35) 6.25+7.5 96(30) tiafenacil 6.25 30 S-metolachlor 750 7 metribuzin 1100 72 550 68 9.38 7 pyroxasulfone 500 2 (11) Herbicidal effect test (goose grass (Eleusine indica)) Yayla soil 1/1. 000. A pot of 000 hectares was placed and goose grass (Eleusine indica) seeds were planted. When goose grass reaches the 7.0 to 8.3 leaf stage, a water-based suspension containing thiafenacyl as the active ingredient and a wettable powder containing tri-allate as the active ingredient, prepared by a conventional method for preparing a water-based suspension, an emulsifiable concentrate containing pethoxamide as the active ingredient (trade name: Successor 600, manufactured by Stahler Suisse SA) or an emulsifiable concentrate containing dimethenamide-P as the active ingredient (trade name: Fieldstar P emulsifiable concentrate, manufactured by BASF), at 0.5% vol. ) was diluted with water (in an amount corresponding to 200 litres per hectare) and sprayed with a small spray gun (model: W-. 3 after spraying. On the 10th day, the growth status of goose grass was observed visually and the growth inhibition rate (%) was obtained in accordance with the evaluation standards explained in the herbicidal effect test above (1) and the results are shown in Table 11. Moreover, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1), and the results are also shown in Table 11. From Table 11, it was found that the combined use of tiafenacil (a1) and tri-allate, pethoxamid or dimethenamid-P (a2) had better controlling effects on goosegrass than the use of each component alone. The growth inhibition rates obtained by using tiafenacil (a1) and tri-allate, pethoxamid or dimethenamid-P (a2) in combination were higher than expected values in all combinations and therefore the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) Measured value (expected 6.25+75 93(77) 6.25+60 95(77) tiafenacil 6.25 77 tri-allate 1250 5 pethoxamid 750 0 93.8 0 dimethenamid-P 750 0 (12) Herbiside effect test (water hemp (Amaranthus tuberculatus)) Yayla soil 1/1. 000. A pot of 000 hectares was placed and water hemp (Amaranthus tuberculatus) seeds were planted. When waterhemp reached the 6.0 to 8.5 leaf stage, a water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing water-based suspension and an emulsifiable concentrate containing S-metolachlor as the active ingredient (trade name: Dual Gold, manufactured by Syngenta), a wettable powder containing metribuzin as the active ingredient (trade name: SENCOR wettable powder, manufactured by Bayer Crop Science) or water-dispersible granules containing pyroxasulfone as the active ingredient (trade name: Sakura, manufactured by Bayer Crop Science) were diluted with water (in an amount corresponding to 200 liters per hectare) and sprayed with a small spray gun (model: W-101-132Câ, manufactured by ANEST IWATA Corporation). 13th after spraying On the day, the growth status of waterhemp was observed visually and the growth inhibition rate (%) was obtained in accordance with the evaluation standards described in the herbicidal effect test above (1) and the results are shown in Table 12. Moreover, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1), and the results are also shown in Table 12. From Table 12, it was found that the combined use of tiafenacil (a1) and S-metolachlor, metribuzin or pyroxasulfone (a2) had better controlling effects on waterhemp compared to the use of each component alone. The growth inhibition rates of the combined use of tiafenacil (a1) and S-metolachlor, metribuzin or pyroxasulfone (a2) were higher than the expected values in all combinations and therefore the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) Measured value (expected 6.25+7.5 93(33) 6.25+7.5 97(40) tiafenacil 6.25 33 S-metolachlor 750 0 metribuzin 1100 50 550 37 9.38 5 pyroxasulfone 500 13 250 17 7.5 10 (13) Herbicide effect test (water hemp (Amaranthus tuberculatus)) Yayla soil 1/1. 000. A pot of 000 hectares was placed and water hemp (Amaranthus tuberculatus) seeds were planted. When waterhemp reaches the 5.0 to 8.0 leaf stage, a water-based suspension containing thiafenacyl as the active ingredient and a wettable powder containing tri-allate as the active ingredient, prepared by a conventional method for preparing a water-based suspension, an emulsifiable concentrate containing pethoxamide as the active ingredient (trade name: Successor 600, manufactured by Stahler Suisse SA), or an emulsifiable concentrate containing dimethenamide-P as the active ingredient (trade name: Fieldstar P emulsifiable concentrate, manufactured by BASF), at 0.5% vol. ) was diluted with water (in an amount corresponding to 200 litres per hectare) and sprayed with a small spray gun (model: W-. 4th day after spraying On the 10th day, the growth status of waterhemp was visually observed and the growth inhibition rate (%) was obtained in accordance with the evaluation standards described in the herbicidal effect test above (1) and the results are shown in Table 13. In addition, the expected value (%) of growth inhibition rate was calculated according to the Colby formula explained in the herbicidal effect test above (1) and the results are shown in Table 13. From Table 13, it was found that the combined use of tiafenacil (a1) and tri-allate, pethoxamid or dimethenamid-P (a2) had better controlling effects on waterhemp compared to the use of each component alone. The growth inhibition rates obtained by using tiafenacil (a1) and tri-allate, pethoxamid or dimethenamid-P (a2) in combination were higher than expected values in all combinations and therefore the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) 6.25+75 90(73) 6.25+60 92(73) thifenacil 6.25 73 tri-allate 1250 0 pethoxamide 750 0 93.8 0 dimetenamide-P 750 0 (14) Herbicide potency test (horseweed (Conyza canadensis)) Plateau soil 1/1. 000. A pot of 000 hectares was placed and horse grass (Conyza canadensis) seeds were planted. When horsegrass reaches a diameter of 12 to 17 cm, a water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing a water-based suspension and an emulsifiable concentrate containing S-metolachlor as the active ingredient (trade name: Dual Gold, manufactured by Syngenta), wettable powder containing metribuzin as the active ingredient (trade name: SENCOR wettable powder, manufactured by Bayer Crop Science) or water-dispersible granules containing pyroxasulfone as the active ingredient (trade name: Sakura, manufactured by Bayer Crop Science), 0%. A 5 volume agricultural spreader (trade name: Destiny HC, Winfield Solutions, LLC. It was diluted with water containing 200 litres of water per hectare (manufactured by ANEST IWATA Corporation) and sprayed with a small spray gun (model: W-101-132Câ, manufactured by ANEST IWATA Corporation). 6 after spraying. On the 10th day, the growth status of horseweed was observed visually and the growth inhibition rate (%) was obtained in accordance with the evaluation standards described in the herbicidal effect test above (1) and the results are shown in Table 14. In addition, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1) and the results are shown in Table 14. From Table 14, it was found that the combined use of tiafenacil (a1) and S-metolachlor, metribuzin or pyroxasulfone (a2) had better controlling effects on horseweed than the use of each component alone. The growth inhibition rates of the combined use of tiafenacil (a1) and S-metolachlor, metribuzin or pyroxasulfone (a2) were higher than the expected values in all combinations and therefore the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) Measured value (expected 6.25+7.5 48(23) 6.25+7.5 63(23) thifenacil 6.25 23 S-metolachlor 750 0 metribuzin 1100 5 9.38 0 pyroxasulfone 500 0 (15) Herbicide effect test (horse grass (Conyza canadensis)) Highland soil 1/1. 000. A pot of 000 hectares was placed and horse grass (Conyza canadensis) seeds were planted. When horsegrass reaches a diameter of 13 to 19 cm, a water-based suspension containing thiafenacyl as the active ingredient and a wettable powder containing tri-allate as the active ingredient, prepared by a conventional method for preparing a water-based suspension, an emulsifiable concentrate containing pethoxamide as the active ingredient (trade name: Successor 600, manufactured by Stahler Suisse SA) or an emulsifiable concentrate containing dimethenamide-P as the active ingredient (trade name: Fieldstar P emulsifiable concentrate, manufactured by BASF), 0.5% vol. (manufactured by ANEST IWATA Corporation) was diluted with water containing 200 litres per hectare of land and sprayed with a small spray gun (model: W-101-132Câ, manufactured by ANEST IWATA Corporation). 3 after spraying. On the 10th day, the growth status of horseweed was visually observed and the growth inhibition rate (%) was obtained in accordance with the evaluation standards described in the herbicidal effect test above (1) and the results are shown in Table 15. Moreover, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1), and the results are also shown in Table 15. From Table 15, it was found that the combined use of tiafenacil (a1) and tri-allate, pethoxamid or dimethenamid-P (a2) had better controlling effects on horseweed compared to the use of each component alone. The growth inhibition rates of the combined use of thiaphenacil (a1) and tri-allate, pethoxamide or dimethenamid-P (a2) were higher than the expected values in all combinations and therefore the combined use was found to have a synergistic effect. Test Compound Dose (g/ha) Growth inhibition rate (%) Measured value (expected 6.25+75 43(17) 6.25+60 50(17) tiafenacil 6.25 17 tri-allate 1250 3 pethoxamid 750 0 93.8 0 dimethenamid-P 750 0 Below, a comparative test between the composition of the present invention and a composition containing another herbicidal compound instead of tiafenacil will be described. (16) Herbicidal effect test (comparative test) Highland soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reaches the 2.5 to 3.0 leaf stage, a water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing a water-based suspension, a water-based suspension containing saflufenacil as the active ingredient (trade name: Sharpen, manufactured by BASF), a wettable powder containing fomesafen as the active ingredient, an emulsifiable concentrate containing fluthiacet-methyl as the active ingredient prepared by a conventional method for preparing a wettable powder (trade name: Attackshot emulsifiable concentrate, manufactured by MARUWA Biochemical Co. , Ltd. ), a dry fluid containing carfentrazone-ethyl as the active ingredient (trade name: Task DF, manufactured by lSHlHARA SANGYO KAlSHA, LTD. ) or an aqueous suspension containing pyraflufen-ethyl as the active ingredient (trade name: ECOPART fluid, NlHON NOHYAKU CO, LTD. manufactured by Syngenta) and an emulsifiable concentrate containing 8-metolachlor as the active ingredient (trade name: Dual Gold, manufactured by Syngenta) or a wettable powder containing metribuzin as the active ingredient (trade name: SENCOR wettable powder, manufactured by Bayer Crop Science) at 0.5% vol. as an agricultural spreader (trade name: Destiny HC, manufactured by Winfield Solutions, LLC. (manufactured by ANEST IWATA Corporation) was diluted with water containing 200 liters per hectare of land and sprayed with a small spray gun (model: W-101-132Câ, manufactured by ANEST IWATA Corporation). 4th day after spraying On the 1st day, the growth status of Italian ryegrass was visually observed and the growth inhibition rate (%) was obtained in accordance with the evaluation standards described in the herbicidal effect test above (1) and the results are shown in Table 16. In addition, the expected value of growth inhibition rate (%) was calculated according to the Colby formula explained in the herbicidal effect test above (1) and the results are shown in Table 16. From Table 16, it was found that the combination of tiafenacil (a1) and S-metolachlor or metribuzin (a2) had better controlling effects on Italian ryegrass compared to the use of each component alone. The growth inhibition rates of the combination of tiafenacil (a1) and S-metolachlor or metribuzin (a2) were higher than expected values and therefore the combined use was found to have a synergistic effect. And the combination of tiafenacil (a1) and S-metolachlor or metribuzin (a2), which is the composition of the present invention, exhibited a higher growth inhibition rate than combinations of tiafenacil and a test compound other than S-metolachlor or metribuzin. However, no improvement in the control effect on Italian ryegrass was observed when test compounds, except tiafenacil, were used in combination with S-metolachlor or metribuzin compared to either compound used alone. Furthermore, the growth inhibition rates of such combinations were not higher than the expected values, thus indicating that these combinations did not have a synergistic effect. Test Compound Dose Growth inhibition rate Measured value (expected) Present invention tiafenacil+ S-metolachlor tiafenacil+ metribuzin Comparative saflufenacil+ saflufenacil+ metribuzin Test Compound Dose Growth inhibition rate Measured value (expected) fomesafen + 12.5+750 8(11) S-metolachlor fomesafen + metribuzin fluthiacet-methyl+ S-metolachlor fluthiacet-methyl+ metribuzin carfentrazone-ethyl+ S-metolachlor carfentrazone-ethyl+ metribuzin pyraflufen-ethyl+ S-metolachlor pyraflufen-ethyl+ metribuzin tiafenacil 12.5 38 saflufenacil 12.5 33 fomesafen 12.5 8 fluthiacet-methyl 12.5 12 Test Compound Dose Growth inhibition rate Measured value (expected carfentrazone-ethyl 12.5 12 pyraflufen-ethyl 12.5 25 S-metolachlor 750 3 metribuzin 18.75 7 Below, a test on the growth-promoting effect of the compound of the present invention on useful plants (hereinafter referred to as the plant growth-promoting effect test) will be described. First, the test for plant growth promoting effect under conditions where undesirable plants grow will be explained. (17) Plant growth promoting effect test (corn) Highland soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reaches the 2.5 to 3.0 leaf stage, a water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing a water-based suspension and an emulsifiable concentrate containing S-metolachlor as the active ingredient (trade name: Dual Gold, manufactured by Syngenta) or a wettable powder containing metribuzin as the active ingredient (trade name: SENCOR wettable powder, manufactured by Bayer Crop Science) at 0.5% vol. is applied with an agricultural spreader (trade name: Destiny HC, Winfield Solutions, LLC). ) was diluted with water (corresponding to 200 litres per hectare) and sprayed with a small spray gun (model: W-. Feed corn seeds (variety: SNOW DENT OTOHA, SNOW BRAND SEED Co. , Ltd. ) was planted in pots after spraying. 20th after October. On the first day, the above-ground portion of the feed corn was harvested and its weight was measured to obtain the raw weight. The results are shown in Table 17. From Table 17, it was found that the use of combination of tiafenacil (a1) and S-metolachlor or metribuzin (a2) increased the crude weight of feed maize compared to untreated area and use of each component alone. Test Compound Dose Raw weight of feed corn (g) thifenacil+ 12.5+750 17.1 S-metolachlor metribuzin thifenacil 12.5 8.5 S-metolachlor 750 5.1 metribuzin 18.75 6.2 (Untreated area) - 6.6 (18) Plant growth promoting effect test (corn) Plateau soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reached the 2.7 to 3.1 leaf stage, a water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing water-based suspension and an emulsifiable concentrate containing S-metolachlor as the active ingredient (trade name: Dual Gold, manufactured by Syngenta), a wettable powder containing metribuzin as the active ingredient (trade name: SENCOR wettable powder, manufactured by Bayer Crop Science) or water-dispersible granules containing pyroxasulfone as the active ingredient (trade name: Sakura, manufactured by Bayer Crop Science) was diluted with water (in an amount corresponding to 200 liters per hectare) and sprayed with a small spray gun (model: W-101-132G, manufactured by ANEST IWATA Corporation). Feed corn seeds (variety: SNOW DENT OTOHA, SNOW BRAND SEED Co. , Ltd. ) was planted in pots after spraying. 21st after October. On the first day, the above-ground portion of the feed corn was harvested and its weight was measured to obtain the raw weight. The results are shown in Table 18. From Table 18, it was found that the combined use of tiafenacil (a1) and S-metolachlor, metribuzin or pyroxasulfone (a2) increased the crude weight of feed maize compared to the untreated area and the use of each component alone. Test Compound Dose Crude weight of feed corn (g) thifenacil+ 6.25+750 6.9 S-metolachlor 6.25+7.5 8.7 thifenacil+ 6.25+550 6.7 metribuzin 6.25+225 6.6 thifenacil+ 6.25+250 8.2 pyroxasulfone 6.25+125 6.5 6.25+7.5 9.5 thiefenacil 6.25 3.2 Test Compound Dose Raw weight of feed corn (g) S-metolachlor 750 3.1 7.5 3.5 metribuzin 550 5.6 225 4.7 pyroxasulfone 250 3.8 125 3.3 7.5 5.8 (Untreated area) - 5.1 (19) Plant growth promoting effect test (corn) Highland soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reaches the 3.2 to 3.7 leaf stage, a water-based suspension containing thiafenacyl as the active ingredient and tri-allate as the active ingredient, prepared by a conventional method for preparing a water-based suspension, a wettable powder prepared by a conventional method for preparing a wettable powder or an emulsifiable concentrate containing pethoxamide as the active ingredient (trade name: Successor 600, manufactured by Stahler Suisse SA), 0.5% by volume, an agricultural spreader (trade name: Destiny HC, manufactured by Winfield Solutions, LLC). (manufactured by ANEST IWATA Corporation) was diluted with water containing (in an amount corresponding to 200 litres per hectare) and sprayed with a small spray gun (model: W-101-132G, manufactured by ANEST IWATA Corporation). Feed corn seeds (variety: SNOW DENT OTOHA, SNOW BRAND SEED Co. , Ltd. ) was planted in pots after spraying. 21st after October. On the first day, the above-ground portion of the feed corn was harvested and its weight was measured to obtain the raw weight. The results are shown in Table 19. From Table 19, it was found that the combined use of tiafenacil (a1) and tri-allate or pethoxamid (a2) increased the crude weight of feed maize compared to the untreated area and the use of each component alone. Test Compound Dose Crude weight of feed corn (9) thifenacil+ 6.25+1250 5.8 tri-allate 6.25+625 5.3 6.25+75 5.7 thifenacil+ 6.25+750 4.4 pethoxamide 6.25+375 5.2 6.25+93.8 6.0 thiafenacil 6.25 3.9 tri-allate 1250 2.5 625 2.2 75 2.6 pethoxamide 750 3.6 375 2.2 93.8 3.4 (Untreated area) - 2.3 (20) Plant growth promoting effect test (maize) Field soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reaches the 2.7 to 3.0 leaf stage, a water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing a water-based suspension and an emulsifiable concentrate containing dimethenamide-P as the active ingredient (trade name: Fieldstar P emulsifiable concentrate, manufactured by BASF), an agricultural spreader at 0.5% vol. (trade name: Destiny HC, Winfield Solutions, LLC. (produced by ) was diluted with water containing (in an amount corresponding to 200 litres per hectare) and sprayed with a small spray gun (model: W-. Feed corn seeds (variety: SNOW DENT OTOHA, SNOW BRAND SEED Co. , Ltd. ) was planted in pots after spraying. 33rd after October. On the first day, the above-ground portion of the feed corn was harvested and its weight was measured to obtain the raw weight. The results are shown in Table 20. From Table 20, it was found that the combined use of tiafenacil (a1) and dimethenamid-P (a2) increased the crude weight of feed maize compared to the untreated area and the use of each component alone. Test Compound Dose Crude weight of feed corn (g) tiafenacil+ 6.25+750 19.0 dimethenamid-P 6.25+375 21.9 6.25+60 15.5 tiafenacil 6.25 12.1 dimethenamid-P 750 8.0 375 12.5 60 9.8 (Untreated area) - 2.7 (21) Plant growth promoting effect test (wheat) Highland soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reaches the 3.3 to 3.8 leaf stage, a water-based suspension containing thiafenacyl as the active ingredient and a wettable powder containing metribuzin as the active ingredient (trade name: SENCOR wettable powder, manufactured by Bayer Crop Science) or water-dispersible granules containing pyroxasulfone as the active ingredient (trade name: Sakura, manufactured by Bayer Crop Science) prepared by a conventional method for preparing water-based suspension are applied with an agricultural spreader (trade name: Destiny HC, Winfield Solutions, LLC) at 0.5% by volume. (manufactured by ANEST IWATA Corporation) was diluted with water containing (in an amount corresponding to 200 litres per hectare) and sprayed with a small spray gun (model: W-101-13ZG, manufactured by ANEST IWATA Corporation). Wheat seeds (variety: Norin 61, Asahi Noen Seed Co. , Ltd. ) was planted in pots after spraying. 22nd after October. On the day, the above-ground part of the wheat was harvested and its weight was measured to obtain the raw weight. The results are shown in Table 21. Table 21 shows that the combined use of tiafenacil (a1) and metribuzin or pyroxasulfone (a2) increased the crude weight of wheat compared to the untreated area and the use of each component alone. Test Compound Dose Crude weight of wheat (g) thiafenacil+ 3+150 4.5 metribuzin thiafenacil+ 3+37.5 4.0 pyroxasulfone thiafenacil 3 2.3 Test Compound Dose Crude weight of wheat (g) metribuzin 150 2.5 pyroxasulfone 37.5 1.2 (Untreated area) - 1.2 (22) Plant growth promoting effect test (wheat) Field soil 1/1. 000. A pot of 000 hectares was placed and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reached the 2.5 to 2.8 leaf stage, a water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing a water-based suspension and a wettable powder containing tri-allate as the active ingredient prepared by a conventional method for preparing a wettable powder were diluted with water (in an amount corresponding to 200 liters per hectare) and sprayed with a small spray gun (model: W-101-132G, manufactured by ANEST IWATA Corporation). Wheat seeds (variety: Norin 61, Asahi Noen Seed Co. , Ltd. ) was planted in pots after spraying. 21st after October. On the day, the above-ground part of the wheat was harvested and its weight was measured to obtain the raw weight. The results are shown in Table 22. From Table 22, it is seen that the combined use of tiafenacil (a1) and tri-allate (a2) increased the crude weight of wheat compared to the untreated area and the use of each component alone. Test Compound Dose Crude weight of wheat (g) thifenacil+ 3+200 2.7 tri-allate thifenacil 3 2.2 tri-allate 200 2.3 (Untreated area) - 2.3 (23) Plant growth promoting effect test (soybean) 1/200. 000 hectares of highland soil was placed in a pot and Italian ryegrass (Lolium multiflorum) seeds were planted. When Italian ryegrass reaches the 2.5 to 3.0 leaf stage, it can be treated with a water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing a water-based suspension and an emulsifiable concentrate containing S-metolachlor as the active ingredient (trade name: Dual Gold, manufactured by Syngenta), a wettable powder containing metribuzin as the active ingredient (trade name: SENCOR wettable powder, manufactured by Bayer Crop Science), water-dispersible granules containing pyroxasulfone as the active ingredient (trade name: Sakura, manufactured by Bayer Crop Science), a wettable powder containing tri-allate as the active ingredient prepared by a conventional method for preparing a wettable powder, an emulsifiable concentrate containing pethoxamide as the active ingredient (trade name: Successor 600, manufactured by Stahler Suisse SA) or a water-based suspension containing thiafenac as the active ingredient (trade name: S-metolachlor) ... an emulsifiable concentrate containing dimethenamide-P (trade name: Fieldstar P emulsifiable concentrate, manufactured by BASF), an agricultural spreader at 0.5% vol (trade name: Destiny HC, manufactured by Winfield Solutions, LLC. (manufactured by ANEST IWATA Corporation) was diluted with water containing 200 liters per hectare of land and sprayed with a small spray gun (model: W-101-132G, manufactured by ANEST IWATA Corporation). Soybean seeds (variety: Enrei, Asahi Noen Seed Co. , Ltd. ) was planted in pots after spraying and soybeans were grown. 97 after October. On the 10th day, seeds were collected from the cultivated soybeans and their weights were measured to obtain the total weight. The results are shown in Table 23. From Table 23, it was found that the combined use of tiafenacil (a1) and S-metolachlor, metribuzin, pyroxasulfone, tri-allate, pethoxamid or dimethenamid-P (a2) increased the total weight of soybean seeds compared to the untreated area and the use of each component alone. Test Compound Dose Total weight of soybean seeds (g) thifenacil+ 12.5+750 34.5 S-metolachlor metribuzin thifenacil+ 12.5+125 43.4 pyroxasulfone thifenacil+ 12.5+625 45.2 tri-allate Test Compound Dose Total weight of soybean seeds weight (9) thiafenacil+ 12.5+750 45.2 pethoxamide thiafenacil+ 12.5+750 50.0 dimethenamide-P thiafenacil 12.5 14.3 S-metolachlor 750 12.7 metribuzin 18.75 14.2 pyroxasulfone 125 15.6 tri-allate 625 17.0 pethoxamide 750 1 1 .0 dimethenamid-P 750 14.1 (Untreated area) - 11.0 From the above results of plant growth promoting effect tests (17) to (23), the growth promoting effects of the composition of the present invention on useful plants were confirmed. The plant growth promoting effect tests (17) to (23) were carried out under conditions where seeds of undesirable plants were sown and therefore by controlling the undesirable plants by the composition of the present invention, the interaction of the undesirable plants with the beneficial plants was reduced, which is considered to be at least one factor in the growth promoting effects of the composition of the present invention on beneficial plants. Therefore, below will be described a test on the plant growth promoting effect of the composition of the present invention on useful plants, which was conducted under conditions where seeds of undesirable plants were not sown. (24) Plant growth promoting effect test (soybean) Upland soil 1/500. A water-based suspension containing tiafenacil as the active ingredient prepared by a conventional method for preparing a water-based suspension and an emulsifiable concentrate containing S-metolachlor as the active ingredient (trade name: Dual Gold, manufactured by Syngenta), a wettable powder containing metribuzin as the active ingredient (trade name: SENCOR wettable powder, manufactured by Bayer Crop Science), water-dispersible granules containing pyroxasulfone as the active ingredient (trade name: Sakura, manufactured by Bayer Crop Science), a wettable powder containing tri-allate as the active ingredient prepared by a conventional method for preparing a wettable powder, an emulsifiable concentrate containing pethoxamide as the active ingredient (trade name: Successor 600, manufactured by Stahler Suisse SA) or an emulsifiable concentrate containing dimethenamide-P as the active ingredient an emulsifiable concentrate (trade name: Fieldstar P emulsifiable concentrate, manufactured by BASF), an agricultural spreader at 0.5% vol (trade name: Destiny HC, manufactured by Winfield Solutions, LLC. (manufactured by ANEST IWATA Corporation) was diluted with water containing 200 litres per hectare of land and sprayed with a small spray gun (model: W-101-132Câ, manufactured by ANEST IWATA Corporation). Soybean seeds (variety: Enrei, Asahi Noen Seed Co. , Ltd. ) was planted in pots after spraying. 48 after October. On the 1st day, the aboveground part of the soybean was harvested and its weight was measured to obtain the total weight. The results are shown in Table 24. From Table 24, it was found that the combined use of tiafenacil (a1) and S-metolachlor, metribuzin, pyroxasulfone, tri-allate, pethoxamid or dimethenamid-P (a2) increased the crude weight of soybeans compared to the untreated area and the use of each component alone. Thus, it has been confirmed that the composition of the present invention has growth promoting effects on soybean under the condition that no undesirable plants are planted. Test Compound Dose Crude weight of soybeans thifenacil+ 3+75 47.7 S-metolachlor thifenacil+ 3+150 53.5 metribuzin thifenacil+ 3+37.5 40.0 pyroxasulfone thifenacil+ 3+200 53.8 tri-allate thifenacil+ 3+200 38.5 pethoxamide thiafenacil+ 3+150 38.0 dimethenamid-P thiafenacil 3 28.3 S-metolachlor 75 27.1 metribuzin 150 16.1 pyroxasulfone 37.5 30.0 tri-allate 200 18.2 Test Compound Dose Crude weight of soybeans pethoxamide 200 26.7 dimethenamide-P 150 28.9 (Untreated area) - 23.2 From the results of the above herbicidal effect tests and plant growth promoting effect tests, it was found that the composition of the present invention has the effects of controlling undesirable plants and promoting the growth of useful plants. The specification, including claims and summary, is filed as of July 29, 2022. TR TR TR TR TR TR TR

TR2024/019598 2023-07-11 METHOD FOR CONTROLLING UNWANTED PLANTS AND PROMOTING THE GROWTH OF USEFUL PLANTS TR2024019598T2 (en)

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