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TR201720948A2 - DEVELOPMENT OF SOAP-BASED NATURAL ANTIBACTERIAL LIQUID SOAP FORMULA - Google Patents

DEVELOPMENT OF SOAP-BASED NATURAL ANTIBACTERIAL LIQUID SOAP FORMULA Download PDF

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Publication number
TR201720948A2
TR201720948A2 TR2017/20948A TR201720948A TR201720948A2 TR 201720948 A2 TR201720948 A2 TR 201720948A2 TR 2017/20948 A TR2017/20948 A TR 2017/20948A TR 201720948 A TR201720948 A TR 201720948A TR 201720948 A2 TR201720948 A2 TR 201720948A2
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Turkey
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soap
obtaining
antibacterial liquid
mass
based antibacterial
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TR2017/20948A
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Turkish (tr)
Inventor
Esen Özlem
Özge Avci Tuna Asli
Ünal Si̇nem
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Evyap Sabun Yag Gliserin Sanayi Ve Ticaret A S
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Priority to TR2017/20948A priority Critical patent/TR201720948A2/en
Publication of TR201720948A2 publication Critical patent/TR201720948A2/en
Priority to PCT/TR2018/050750 priority patent/WO2019199255A2/en

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/225Polymers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/08Liquid soap, e.g. for dispensers; capsuled
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/26Organic compounds, e.g. vitamins containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/26Organic compounds, e.g. vitamins containing oxygen
    • C11D9/262Organic compounds, e.g. vitamins containing oxygen containing carbohydrates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/30Organic compounds, e.g. vitamins containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/38Products in which the composition is not well defined

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Detergent Compositions (AREA)

Abstract

Bu buluş ile, bitkisel yağ asitlerinin yüksek pH?da bir zayıf ve/veya kuvvetli bir baz ile sabunlaştırılmasından sonra oluşan doğal sabun formuna; bilinen herhangi bir yan etkisi bulunmayan antibakteriyel etken madde ve antibakteriyel ajanın etkinliğini arttıran doğal hammadde, kıvamlaştırıcı, şelatlayıcı, parfüm, boya ve ekstrakt gibi diğer bileşenlerin ilavesi ile sentetik antibakteriyel sıvı sabunların yerine bitkisel ve doğal, biyosidal ürünler yönetmeliğinde yer alan dezenfektanların ve antiseptiklerin bakteriyolojik yönden etkinlik testi olan TS EN 1276 testinden başarıyla geçmiş, düşük ve yüksek sıcaklıklarda fiziksel olarak kararlı, viskozite ve jelleşme problemi gözlenmeyen, köpük ve yıkama performansı yüksek, çevre dostu doğal sabun bazlı antibakteriyel sıvı sabun formülü geliştirilmiştir.With the present invention, the natural soap form formed after saponification of vegetable fatty acids with a weak and / or strong base at high pH; With the addition of natural raw materials, thickeners, chelating agents, perfumes, dyes and extracts that increase the effectiveness of the antibacterial agent and antibacterial agent without any known side effects, instead of synthetic antibacterial liquid soaps, herbal and natural, disinfectants and antiseptics included in the regulation of biocidal products in terms of bacteriological aspects. An environmentally friendly natural soap-based antibacterial liquid soap formula with high foam and washing performance, physically stable at low and high temperatures, without viscosity and gelation problems, has been developed.

Description

TARIFNAME DOGAL SABUN BAZLI ANTIBAKTERIYEL SIVI SABUN FORMÜLÜNÜN GELISTIRILMESI Teknik Alan Bu bulus, mevcut surfaktan bazli antibakteriyel sivi sabunlarin insan ve çevre sagligina karsi potansiyel tüm olumsuz etkilerini ortadan kaldirabilmek amaciyla Gram pozitif ve Gram negatif mikroorganizmalara karsi gelistirilmis antibakteriyel etkinlige sahip Dogal ve Bitkisel olan Sabun Bazli Antibakteriyel Sivi Sabun formülünün gelistirilmesi ile ilgilidir. Önceki Teknik Ellerimizde çok sayida bakteri bulunmaktadir. Enfeksiyon hastaliklarinin en önemli sebebi bu bakterilerdir. El temizliginde amaç hastaliklara yol açan mikroorganizmalarin deriden uzaklastirilmasini saglamaktir. Ancak, eller sadece su ile yikandigi zaman zararli mikroorganizmalar mekanik etki ile uzaklastirilabilmekte ve bu nedenle temizlik tam olarak saglanamamaktadir. Özellikle kalabalik yerlerde kisisel temizlikte sivi sabunlarin kullanimi tercih edilmektedir. Antibakteriyel sivi sabunlar ise hijyenik sabunlarda antibakteriyel etkiye sahip özel bilesenler içermektedir. Bu bilesenler sayesinde bakteriyel enfeksiyonlarin azalmasi ve/veya önlenmesi saglanmaktadir. DESCRIPTION NATURAL SOAP BASED ANTIBACTERIAL LIQUID SOAP DEVELOPING THE FORMULA Technical Area This invention shows that existing surfactant-based antibacterial liquid soaps can be used in human and environmental in order to eliminate all potential negative effects against health Antibacterial developed against Gram-positive and Gram-negative microorganisms Natural and Herbal Soap Based Antibacterial Liquid Soap related to the development of the formula. Prior Art There are many bacteria on our hands. The most important infectious diseases The reason is these bacteria. The purpose of hand cleaning is to cause diseases. to ensure that microorganisms are removed from the skin. However, hands are just water. when washed with harmful microorganisms by mechanical effect can be removed and therefore cleaning cannot be provided completely. Especially in crowded places, the use of liquid soaps is preferred for personal cleaning. is being done. Antibacterial liquid soaps are antibacterial in hygienic soaps. contains special components that have an effect. Thanks to these components, bacterial reduction and/or prevention of infections.

Bir sivi sabunun antibakteriyel olarak iddia edilebilmesi için Biyosidal Yönetmeligfnde yer alan antibakteriyel etken maddelerden en az bir tanesini içermesi ve TS EN 1276 testini basarili olarak tamamlamasi gerekmektedir. Biocidal for a liquid soap to be claimed as antibacterial At least one of the antibacterial active substances in the regulation and must successfully complete the TS EN 1276 test.

Antibakteriyel özellik tasiyan sivi sabunlarin forrnülasyonunda bulunan aktif maddelerin (Triclosan, Triclocarban vb.) bir bölümü gerçeklestirilen bilimsel çalismalar neticesinde hem hormonlar üzerindeki zararli etkileri hem de 2154.13 kanalizasyon sularinda ve baliklarda bulunmasi sonucu çevreye verdigi zarar nedeniyle birçok ülkede yasaklanmis, diger birçok ülkede de yasaklanma durumu ile karsi karsiya kalmistir. Active ingredient in the formulation of antibacterial liquid soaps some of the substances (Triclosan, Triclocarban, etc.) As a result of studies, both its harmful effects on hormones and 2154.13 damage to the environment as a result of its presence in sewage waters and fish banned in many countries due to is faced with.

Baudouin ve arkadaslari tarafindan, 2010 yilinda yeni bir antibakteriyel ajan arayisina girilmis ve mevcut kullanilan antibakteriyel sivi sabunlardaki etken madde olan Benzalkonyum Klorür kullanimi gündeme gelmistir. Ancak, yapilan çalismalarda Benzalkonyum Klorür, ün asindirici ve tahris edici özelliklerinin oldugunun ortaya çikmasi gelecekte de bu hammaddenin yasaklanabilecegi süphesini dogurmustur. A new antibacterial agent was discovered in 2010 by Baudouin et al. The factor in antibacterial liquid soaps that have been searched for and currently used The use of Benzalkonium Chloride, which is a substance, has come to the fore. However, made Studies have shown that Benzalkonium Chloride has a reputation for its corrosive and irritating properties. It is revealed that this raw material may be banned in the future. aroused suspicion.

Bilinen tüm tekniklerde sentetik surfaktan bazli yüzey aktifler kullanilmistir. Uzun süre surfaktanlara maruz kalan cildin sürtünmeye neden olarak hücreleri koruyan lipit yapiyi bozdugu bilinmektedir. C. L. Yuan ve arkadaslari tarafindan 2014 yilinda yapilan diger çalismalarda ise yüzey aktif maddelerin konsantrasyonunun belirli bir seviyeyi astiginda çamur nitrifikasyonunu ve diger pek çok prosesle beraber atik su aritiminin zorlugunu arttiracagi bildirilmistir. Synthetic surfactant-based surfactants have been used in all known techniques. Long The skin, which is exposed to surfactants for a long time, causes friction and protects the cells. It is known to disrupt the lipid structure. 2014 by C. L. Yuan et al. In other studies conducted in When it exceeds a certain level, it can undergo sludge nitrification and many other processes. It has been reported that together with this, it will increase the difficulty of wastewater treatment.

Yukarida bahsedilen tüm nedenlerden ötürü günümüzde insanlarin daha az sentetik bilesen ve antibakteriyel ajan olarak insan sagligini tehdit etmeyecek etken maddeleri içeren ürünleri kullanmasini yayginlastirmak ve böylece ileride olusabilecek insan ve çevre sagligi tehdidini minimuma indirmek amaciyla yeni çalismalarin gerekliligi ortaya çikmistir. de kati formda kararli olan yag asitleriyle olusturulmus, Gram pozitif ve Gram negatif bakterilere karsi etkili bir formül gelistirildiginden bahsedilmektedir. Bu bilesimde bakterileri öldürmek amaciyla gümüs iyonlari veya bilesikleri kullanilmistir. Saglik Bakanligi”nin yayinladigi yönetmeliklerin ürün tipi 1; insan hijyeni için kullanilan biyosidal ürünler listesinde gümüs iyonlari bulunmadigindan elde edilen nihai ürün antibakteriyel iddiasini tasiyamamaktadir. Bununla birlikte, 2154.13 yapilan çalismada formüle sentetik yüzey aktif maddeler eklendiginden nihai formül bitkisel ve dogal bir ürün degildir. For all the reasons mentioned above, people nowadays have less synthetic factor that will not threaten human health as a component and antibacterial agent to popularize the use of products containing substances and thus in the future In order to minimize the threat to human and environmental health that may occur, new the necessity of the work has emerged. formed with fatty acids that are stable in solid form, Gram positive and Gram It is mentioned that an effective formula has been developed against negative bacteria. This silver ions or compounds in the composition to kill bacteria used. Product type 1 of the regulations published by the Ministry of Health; human Since there are no silver ions in the list of biocidal products used for hygiene The final product obtained cannot carry the antibacterial claim. With this, 2154.13 Since synthetic surfactants were added to the formula in the study, the final The formula is not a herbal and natural product.

Bu bulus ile birlikte yapisinda insan sagligina herhangi bir zararli etkisi olmayan antibakteriyel ajanlarin kullanildigi, surfaktan bazli antibakteriyel sabunlar yerine dogal olan, durulanma, temizleme ve köpük performansi yüksek, viskozite (300 - 7000 cp) ve jellesme problemi gözlenmeyen, düsük ve yüksek sicakliklarda (5 - 50°C) fiziksel olarak kararli olan bitkisel sabun bazli antibakteriyel bir sivi sabun formülü gelistirilmistir. With this invention, it does not have any harmful effects on human health in its structure. Instead of surfactant-based antibacterial soaps using antibacterial agents natural, high rinsing, cleaning and foaming performance, viscosity (300 - 7000 cp) and at low and high temperatures (5 - 50°C) is an antibacterial liquid soap based on herbal soap that is physically stable. formula has been developed.

Bulusun Kisa Açiklamasi Bulusumuz bitkisel yag ve/veya yag asitlerinin kuvvetli ve/veya zayif bir baz ile yüksek pH'da sabunlastirilmasindan sonra olusturulan dogal sivi sabun formülasyonuna Biyosidal Ürünler Yönetmeligine göre izin verilen aktif maddeler listesinde (Liste 1) yer alan-antibakteriyel ajan ilavesi yapilarak el dezenfeksiyonu amaçli kullanilabilen dogal bitkisel sabun bazli antibakteriyel sivi sabun üretilmesi ile ilgilidir. Bulus ile kullanilan mevcut sentetik, surfaktan bazli antibakteriyel sivi sabunlarin yerine kimyasal reaksiyon elde edilen sabunun formu sivilastirilarak biyobozunur olan, 5 - 50°C sicaklik araliklarinda fiziksel olarak kararli, eldeki zararli bakterileri öldüren, 7 - 32 Fransiz Sertlikleri gibi farkli su sertliklerinde yüksek yikama ve köpürme performansina sahip bitkisel ve dogal olan antibakteriyel bir sivi sabun formülü gelistirilmistir. Brief Description of the Invention Our invention is a mixture of vegetable oil and/or fatty acids with a strong and/or weak base. Natural liquid soap created after saponification at high pH active substances allowed for formulation according to the Biocidal Products Regulation hand disinfection by adding antibacterial agent Production of antibacterial liquid soap based on natural herbal soap that can be used for It is related to. The available synthetic surfactant-based antibacterial liquid used with the invention Instead of soaps, the form of the soap obtained from the chemical reaction is liquefied. biodegradable, physically stable in the temperature range of 5 - 50°C, in different water hardnesses, such as 7 - 32 French Hardnesses, which kill harmful bacteria. herbal and natural with high washing and foaming performance An antibacterial liquid soap formula has been developed.

Bulusun Ayrintili Açiklamasi Bulus konusu sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi, biyobozunur olan, 5°C - 50°C sicaklik araliklarinda fiziksel olarak kararli olan, 7 - 32 Fransiz Sertliginde yüksek yikama performansina sahip, bitkisel olan ve i. bitkisel yag asidi çözeltisi, baz çözeltisi/bazik materyal ve tuz 2154.13 çözeltisinin hazirlanmasi, ii. sabunlasma reaksiyonunun gerçeklestirilmesi için bitkisel yag asidi çözeltisi ile baz ve tuz çözeltisinin 80°C,de karistinlmasi, iii. bitkisel yag asidi çözeltisi ile baz ve tuz çözeltisinin karistirilmasiyla olusan çözeltiye kivamlastirici, selatlayici, antibakteriyel ajan ve antibakteriyel ajanin etkinligini arttiran dogal hammadde eklenmesi, iv. ortaya çikan ürünün 35°C,nin altindaki sicakliga sogutulmasi adimlarini içermektedir. Detailed Description of the Invention The method of obtaining a soap-based antibacterial liquid soap, which is the subject of the invention, biodegradable, physically stable in the temperature range of 5°C to 50°C, 7 - 32 French Hardness with high washing performance, herbal and I. vegetable fatty acid solution, base solution/basic material and salt 2154.13 preparation of the solution ii. vegetable fatty acid to carry out the saponification reaction mixing the solution of base and salt at 80°C, iii. by mixing the vegetable fatty acid solution with the base and salt solution. thickener, chelator, antibacterial agent and adding natural raw materials that increase the effectiveness of the antibacterial agent, iv. the steps of cooling the resulting product to a temperature below 35°C. contains.

Bulusun bir uygulamasinda bitkisel yag asidi çözeltisinde yer alan yag asidi olarak; C8 - Cl8 arasindaki bitkisel yag asidi zincirleri kullanilmaktadir. Tercihen bu araliktaki yag asitlerinden C12 - C18 arasindaki bitkisel yag asidi zincirleri kullanilmaktadir. Bu baglamda, kullanilabilecek olan yag asitleri olarak; kaprilik linoleik asit (CigH3202) veya linolenik asit (CigH3002) yag asitlerinden olusan bir gruptan seçilen en az bir yag asidi bulus kapsaminda kullanilmaktadir. Bunlarin arasindan tercihen bitkisel doymus yag asitlerinden laurik asit (C12H2402), miristik gruptan seçilen yag asidi kullanilmaktadir. Laurik asit (Ci2H2402), miristik asit araliginda, %4,0 - 8,0 araliginda olmaktadir. Kullanilan bir diger karisim olan laurik asit ve miristik asit karisiminda kütlece karisim oranlari, sirasiyla: %10,0 - ,0 araliginda ve %3,0 - 10,0 araliginda olmaktadir. Kullanilan bir diger karisim olan laurik asit ve palmitik asit karisiminda kütlece karisim oranlari, sirasiyla: Bulusun bir uygulamasinda, potasyum hidroksit (KOH), sodyum hidroksit (NaOH), monoetanolamin (HzNCHzCHzOH), dietanolamin (HN(CH2CH20H)2), 2154.13 trietanolamin (N(CH2CH20H)3), amonyak (NH3) ve bunlarin karisimlarindan olusan bir gruptan seçilen en az biri baz çözeltisi/bazik materyal olarak kullanilmaktadir. Tercihen bu bazik materyal olarak potasyum hidroksit (KOH) kullanilmaktadir. Kullanilan bazik materyal miktarinin toplam karisima göre orani Bulusun bir uygulamasinda, tuz çözeltisi olarak, sodyum klorür (NaCl), sodyum sülfat (NaSO4) ve potasyum klorür (KCl) tuzlarinin çözeltilerinden en az biri tuz çözeltisi olarak kullanilmaktadir. Tercihen tuz çözeltisi olarak sodyum klorür (NaCl) kullanilmaktadir. In an application of the invention, as the fatty acid in the vegetable fatty acid solution; Vegetable fatty acid chains between C8 and Cl8 are used. Preferably this vegetable fatty acid chains between C12 - C18 from fatty acids in the range is used. In this context, as fatty acids that can be used; caprylic linoleic acid (CigH3202) or linolenic acid (CigH3002) fatty acids. At least one fatty acid selected from the group is used within the scope of the invention. These Among them, preferably vegetable saturated fatty acids, lauric acid (C12H2402), myristic Fatty acid selected from the group is used. Lauric acid (Ci2H2402), myristic acid in the range of 4.0 - 8.0%. Another mixture used Mixture ratios by mass in the mixture of lauric acid and myristic acid, respectively: 10.0% - It is in the range of .0 and between 3.0% and 10.0%. Another mix used Mixture ratios by mass of lauric acid and palmitic acid mixture, respectively: In one embodiment of the invention, potassium hydroxide (KOH), sodium hydroxide (NaOH), monoethanolamine (HzNCHzCH2OH), diethanolamine (HN(CH2CH2OH)2), 2154.13 triethanolamine (N(CH2CH2OH)3), ammonia (NH3) and their mixtures as a base solution/basic material selected from a group consisting of is used. Preferably potassium hydroxide (KOH) as this basic material is used. The ratio of the amount of basic material used to the total mixture In one embodiment of the invention, sodium chloride (NaCl) is used as salt solution. At least one of the solutions of sulfate (NaSO4) and potassium chloride (KCl) salts is salt. used as solution. Preferably sodium chloride as salt solution (NaCl) is used.

Bulusun bir uygulamasinda, kivamlastirici olarak; hidroksietil selüloz, hidroksimetil selüloz, hidroksietilmetil selüloz, hidroksipropil selüloz, hidroksipropil metil selüloz, ksantan gam, guar gam, akrilat kopolimer emülsiyonlari ve diger tüm kivamlastiricilardan arasindan en az bin` kullanilmaktadir. Bunlarin arasindan tercihen hidroksietil selüloz, ve ksantan gam kullanilmaktadir. Hidroksietil selüloziun kütlece karisima orani %0,01 - 10,0 araliginda, %O,1 - 5,0 araliginda ve tercihen %0,1 - 3,0 araliginda, Ksantan gam°in Bulusun bir uygulamasinda, selatlayici olarak, EDTA türevleri veya tetrasodyum glutamate diasetat selatlayicilarindan en az biri kullanilmaktadir. Tercihen bir EDTA türevi olan tetrasodyum EDTA kullanilmaktadir. In one embodiment of the invention, as a thickener; hydroxyethyl cellulose, hydroxymethyl cellulose, hydroxyethylmethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, xanthan gum, guar gum, acrylate copolymer emulsions and at least one thousand of all other thickeners. is used. Among them, preferably hydroxyethyl cellulose, and xanthan gum is used. Mixture ratio by mass of hydroxyethyl cellulose 0.01 - 10.0% in the range of 0.1 - 5.0%, preferably between 0.1 - 3.0%, Xanthan gum In one embodiment of the invention, EDTA derivatives or tetrasodium are used as chelators. At least one of the glutamate diacetate chelators is used. Preferably a Tetrasodium EDTA, which is an EDTA derivative, is used.

Bulusun bir uygulamasinda, antibakteriyel ajan olarak fenoksietanol ile antibakteriyel ajanin etkinligini arttiran dogal hammadde olarak çay agaci yagi kullanilmaktadir. Kullanilan fenoksietanol”un kütlece karisima orani %0,01 - 1,0 araliginda, %0,05 - 0,8 araliginda ve tercihen %0,I - 0,6 araliginda, çay agaci 2154.13 tercihen %0,1 - 1,0 araliginda olmaktadir. In one embodiment of the invention, with phenoxyethanol as an antibacterial agent. Tea tree oil as a natural raw material that increases the effectiveness of antibacterial agent is used. Mixing ratio by mass of phenoxyethanol used 0.01% - 1.0% in the range of 0.05% - 0.8% and preferably between 0.1% - 0.6%, tea tree 2154.13 preferably in the range of 0.1 - 1.0%.

Bulusun bir uygulamasinda, “ortaya çikan ürünün sogutulmasi” adimindan sonra, sogutulmus ürüne parfüm ilavesi edilmektedir. Bulusun bir uygulamasinda, “ortaya çikan ürünün sogutulmasi” adimindan sonra sogutulmus ürüne renklendirici ilavesi edilmektedir. Bulusun bir uygulamasinda, “ortaya çikan ürünün sogutulmasi” adimindan sonra sogutulmus ürüne ekstrakt ilavesi edilmektedir. In one embodiment of the invention, after the "cooling of the resulting product" step, Perfume is added to the cooled product. In one embodiment of the invention, Adding colorant to the cooled product after the “cooling the output product” step is being done. In one embodiment of the invention, "cooling of the resulting product" After the step, extract is added to the cooled product.

Bu bulus, amacina ulasmak için gerçeklestirilen sabun bazli antibakteriyel sivi sabun olup; yag asitlerinin en az biri kullanilarak bir bitkisel yag asidi çözeltisinin ve potasyum hidroksit (KOH), sodyum hidroksit (NaOH), monoetanolamin (HzNCHzCHzOH), dietanolamin (HN(CH2CH20H)2), trietanolamin (N(CH2CH20H)3) veya amonyak (N H3) bazlari arasindan seçilen en az biri ile, sodyum klorür (NaCl), sodyum sülfat (NaSO4) ve potasyum klorür (KCl) tuzlarindan en az biri seçilerek bir baz ve tuz sulu çözeltisinin hazirlanmasi, - sabunlasma reaksiyonunun gerçeklestirilmesi için bitkisel yag asidi çözeltisi ile baz ve tuz çözeltisinin 80°Cide kanstirilmasi, - karistirilan çözeltiye kivamlastirici olarak hidroksietil selüloz, hidroksimetil selüloz, hidroksietilmetil selüloz, hidroksipropil selüloz, hidroksipropil metil selüloz, ksantan gam, guar gam, akrilat kopolimer emülsiyonlari ve diger tüm kivamlastiricilar arasindan seçilen bir veya birkaçi ile; selatlayici olarak EDTA türevleri veya Tetrasodyum Glutamat Diasetat eklenmesi, - selatlayici ve kivamlastiricinin eklendigi çözeltiye antibakteriyel ajan olarak fenoksietanol ve antibakteriyel ajanin etkinligini arttiran dogal hammadde olarak çay agaci yagi eklenmesi. 2154.13 elde edilen nihai ürünün 35°Csnin altina sogutulmasi, sogutulmus ürün içerisine tercihen parfüm, renklendirici veya ekstrakt gibi bilesenlerin ilavesi edilmesi adimlari ile üretilmektedir. This invention is a soap-based antibacterial liquid made to achieve its purpose. is soap; of a vegetable fatty acid solution using at least one of the fatty acids and potassium hydroxide (KOH), sodium hydroxide (NaOH), monoethanolamine (HzNCHzCH2OH), diethanolamine (HN(CH2CH2OH)2), triethanolamine at least one selected from (N(CH2CH2OH)3) or ammonia (N H3) bases with sodium chloride (NaCl), sodium sulfate (NaSO4) and potassium chloride By choosing at least one of the (KCl) salts, a base and salt aqueous solution preparation, - vegetable fatty acid to carry out the saponification reaction mixing the solution with the base and salt solution at 80°C, - hydroxyethyl cellulose, hydroxymethyl as a thickener into the stirred solution cellulose, hydroxyethylmethyl cellulose, hydroxypropyl cellulose, hydroxypropyl emulsions of methyl cellulose, xanthan gum, guar gum, acrylate copolymer and with one or more selected among all other thickeners; stimulant Addition of EDTA derivatives or Tetrasodium Glutamate Diacetate as - antibacterial agent to the solution to which the chelator and thickener are added as a natural product that increases the effectiveness of phenoxyethanol and antibacterial agent. adding tea tree oil as raw material. 2154.13 cooling the final product below 35°C, Preferably perfume, colorant or extract into the cooled product. It is produced by the steps of adding components.

Bitkisel yaglarin ve/veya yag asitlerinin yüksek pH degerlerinde (pH 8,0 - 11,0) zayif ve/veya kuvvetli bir baz ile sabunlastirilmasindan sonra olusan dogal sabun formunun kivamlastirici, selatlayici, antibakteriyel ajan, antibakteriyel ajanin etkinligini arttiran dogal madde, parfüm, boya ve ekstrakt gibi diger bilesenlerin ilavesi ile el temizliginde kullanilabilecek antibakteriyel bitkisel sabun bazli sivi sabun üretilmistir. At high pH values of vegetable oils and/or fatty acids (pH 8.0 - 11,0) natural soap formed after saponification with a weak and/or strong base form of thickener, chelating agent, antibacterial agent, antibacterial agent of other components such as natural substances, perfumes, dyes and extracts that increase its effectiveness. Antibacterial herbal soap-based liquid that can be used for hand cleaning with the addition of soap is produced.

Bulus konusu üretim yöntemi sirasi ile asagidaki basamaklardan olusmaktadir: Bitkisel yag asidi çözeltisinin hazirlanmasi. The production method which is the subject of the invention consists of the following steps, respectively: Preparation of vegetable fatty acid solution.

Ilk adimda belirtilen bitkisel yag asitleri tercihen Kaprilik asit (CsHmOz), Baz ve tuz çözeltisinin hazirlanmasi. Üçüncü adimda belirtilen baz çözeltisi tercihen Potasyum Hidroksit (KOH), Sodyum Hidroksit (NaOH), Monoethanolamin (HzNCHzCHzOH), Diethanolamin (HN(CH2CH20H)2), Triethanolamin (N(CH2CH20H)3), Amonyak (NH3),dir. Tuz çözeltisi tercihen: Sodyum Klorür (NaCl), Sodyum Sülfat (NaSO4), Potasyum Klorür(KC1)'dir. Vegetable fatty acids mentioned in the first step, preferably Caprylic acid (CsHmOz), Preparation of base and salt solution. The base solution specified in the third step is preferably Potassium Hydroxide (KOH), Sodium Hydroxide (NaOH), Monoethanolamine (HzNCHzCHzOH), Diethanolamine (HN(CH2CH2OH)2), Triethanolamine (N(CH2CH2OH)3), Ammonia (NH3). Salt solution preferably: Sodium Chloride (NaCl), Sodium Sulphate (NaSO4) is Potassium Chloride (KC1).

Bitkisel yag asidi çözeltisi ile baz ve tuz çözeltisinin 80°C,de karistirilmasi ile sabunlasma reaksiyonunun gerçeklestirilmesi. Mixing the vegetable fatty acid solution with the base and salt solution at 80°C carrying out the saponification reaction with

Kivamlastirici ve selatlayici ajanlarin ilavesi. Addition of thickening and chelating agents.

Altinci adimda belirtilen kivamlastiricilar tercihen Hidroksietil Selüloz, Hidroksimetil Selüloz, Hidroksietilmetil Selüloz, Hidroksipropil Selüloz, Hidroksipropil Metil Selüloz, Ksantan Gam, Guar Gam, Akrilat Kopolimer Emülsiyonlari ve diger tüm kivamlastiricilardir. Selatlayici olarak tercihen EDTA türevleri, Tetrasodyum Glutamat Diasetafdir. 2154.13 - Antibakteriyel ajan ve antibakteriyel ajanin etkinligini arttiran dogal hammadde ilavesi. The thickeners mentioned in the sixth step are preferably Hydroxyethyl Cellulose, Hydroxymethyl Cellulose, Hydroxyethylmethyl Cellulose, Hydroxypropyl Cellulose, Hydroxypropyl Methyl Cellulose, Xanthan Gum, Guar Gum, Acrylate Copolymer Emulsions and all other thickeners. Preferably as a chelator EDTA derivatives are Tetrasodium Glutamate Diacetaph. 2154.13 - Antibacterial agent and natural agent that increases the effectiveness of antibacterial agents addition of raw materials.

- Sekizinci adimda belirtilen antibakteriyel ajan tercihen fenoksietanol, antibakteriyel ajanin etkinligini arttiran dogal hammadde tercihen çay agaci yagidir. - The antibacterial agent mentioned in step eight, preferably phenoxyethanol, Natural raw material that increases the effectiveness of the antibacterial agent, preferably tea tree it is oil.

- Nihai formülün sogutularak içerisine parfüm, boya, gibi diger bilesenlerin ilavesi edilmesi. 2154.13 REFERANSLAR (PATENT DISI) 0 Baudouin, C., Labbé, A., Liang, H., Pauly, A. ve Brignole-Baudouin, F., (2010), “Preservatives in eyedrops: the good, the bad and the ugly”, Progress in Retinal and Eye Research, 29, (4), 312-334. 0 Yuan, C.L., Xu, Z.Z., Fan, M.X., Liu, H.Y., Xie, Y.H. ve Zhu, T., (2014), 0 Kurt Kosswig, (2005), "Surfactants" in Ullmann's Encyclopedia of 0 Public Consultation on the SCCS Preliminary Opinion on the Antimicrobial - The final formula is cooled and other components such as perfume, paint, etc. to be added. 2154.13 REFERENCES (NOT PATENT) 0 Baudouin, C., Labbé, A., Liang, H., Pauly, A., and Brignole-Baudouin, F., (2010), “Preservatives in eyedrops: the good, the bad and the ugly”, Progress in Retinal and Eye Research, 29, (4), 312-334. 0 Yuan, C.L., Xu, Z.Z., Fan, M.X., Liu, H.Y., Xie, Y.H. and Zhu, T., (2014), 0 Kurt Kosswig, (2005), "Surfactants" in Ullmann's Encyclopedia of 0 Public Consultation on the SCCS Preliminary Opinion on the Antimicrobial

Claims (2)

ISTEMLERREQUESTS 1. Biyobozunur olan, 5°C - 50°C sicaklik araliklarinda fiziksel olarak kararli olan, 7 - 32 Fransiz Sertliginde yüksek yikama performansina sahip, bitkisel olan ve i. bitkisel yag asidi çözeltisi, baz çözeltisi/bazik materyal ve tuz çözeltisinin hazirlanmasi, ii. sabunlasma reaksiyonunun gerçeklestirilmesi için bitkisel yag asidi çözeltisi ile baz ve tuz çözeltisinin 80°C,de karistirilmasi, iii. bitkisel yag asidi çözeltisi ile baz ve tuz çözeltisinin karistirilmasiyla olusan çözeltiye kivamlastirici, selatlayici, antibakteriyel ajan ve antibakteriyel ajanin etkinligini arttiran dogal hammadde eklenmesi iv. ortaya çikan ürünün 35°C5nin altindaki sicakliga sogutulmasi adimlari ile sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi.1. Biodegradable, physically stable in the temperature range of 5°C - 50°C, having high washing performance in French Hardness 7 - 32, vegetal and i. preparation of vegetable fatty acid solution, base solution/basic material and salt solution, ii. mixing the vegetable fatty acid solution with the base and salt solution at 80°C to carry out the saponification reaction, iii. Adding natural raw materials that increase the efficacy of thickening, chelating, antibacterial agent and antibacterial agent to the solution formed by mixing vegetable fatty acid solution with base and salt solution iv. A method of obtaining a soap-based antibacterial liquid soap by the steps of cooling the resulting product to a temperature below 35°C. 2. Bitkisel yag asidi çözeltisinde yer alan yag asidi olarak; C8 - C18 arasindaki bitkisel yag asidi zincirlerinin kullanildigi Istem l,deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. . Bitkisel yag asidi çözeltisinde yer alan yag asidi olarak; Cl2 - C18 arasindaki bitkisel yag asidi zincirlerinin kullanildigi Istem 2,deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. . Bitkisel yag asidi çözeltisinde yer alan yag asidi olarak; kaprilik asit asitlerinden ve bunlarin karisimlarindan olusan bir gruptan seçilen en az bir yag asidinin kullanildigi Istem I veya 2'deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Bitkisel yag asidi çözeltisinde yer alan yag asidi olarak; bitkisel doymus yag (C 16H3202) ve bunlarin karisimindan olusan bir gruptan seçilen en az biri yag asidinin kullanildigi Istem 4iteki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Bitkisel doymus yag asitlerinden laurik asit oraninin kütlece %1,0 - 50,0 araliginda, miristik asit oraninin kütlece %1,0 - 20,0 araliginda ve palmitik asit oraninin kütlece %1,0 - 20,0 araliginda oldugu bir karisimin kullanildigi Istem 5,teki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Bitkisel doymus yag asitlerinden laurik asit oraninin kütlece %5,0 - 40,0 araliginda, miristik asit oraninin kütlece %3,0 - 15,0 araliginda ve palmitik asit oraninin kütlece %3,0 - 10,0 araliginda oldugu bir karisimin kullanildigi Istem 6ldaki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Bitkisel doymus yag asitlerinden laurik asit oraninin kütlece %10,0 - 30,0 araliginda, miristik asit oraninin kütlece %3,0 - 10,0 araliginda ve palmitik asit oraninin kütlece %4,0 - 8,0 araliginda oldugu bir karisimin kullanildigi Istem Tdeki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Bitkisel doymus yag asitlerinden laurik asit oraninin kütlece %10,0 - 30,0 araliginda, miristik asit oraninin kütlece %3,0 - 10,0 araliginda oldugu Istem 5,teki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Bitkisel doymus yag asitlerinden laurik asit oraninin kütlece %10,0 - 30,0 araliginda, palmitik asit oraninin kütlece %3,0 - 10,0 araliginda oldugu Istem 5,teki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Potasyum hidroksit (KOH), sodyum hidroksit (NaOH), monoetanolamin (HzNCHzCHzOH), dietanolamin (HN(CH2CH20H)2), trietanolamin (N(CH2CH20H)3) veya amonyak (NH3) bazlari arasindan seçilen en az birinin baz çözeltisi/bazik materyal olarak kullanildigi Istem l,deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Bazik materyal olarak potasyum hidroksitin (KOH) kullanildigi Istem ”deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Bazik materyal miktarinin kütlece %1,0 - 30,0 oranlari araliginda oldugu Istem 1 veya 12,deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Bazik materyal miktarinin kütlece %5,0 - 20,0 oranlari araliginda oldugu Istem 13,teki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Bazik materyal miktarinin kütlece %7,0 - 10,0 oranlari araliginda oldugu Istem 14”teki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Sodyum klorür (NaCl), sodyum sülfat (N aSO4) ve potasyum klorür (KCl) tuz çözeltileri arasindan en az birinin tuz çözeltisi olarak kullanildigi Istem lideki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Tuz çözeltisi olarak sodyum klorür (NaCl) tuz çözeltisinin kullanildigi Istem 16,daki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Kivamlastirici olarak; hidroksietil selüloz, hidroksimetil selüloz, hidroksietilmetil selüloz, hidroksipropil selüloz, hidroksipropil metil selüloz, ksantan gum, guar gam, akrilat kopolimer emülsiyonlari ve diger tüm kivamlastiricilar arasindan en az birinin kullanildigi Istem l,deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Kivamlastiricilardan hidroksietil selüloz veya ksantan gam”in kullanildigi Istem l8ideki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Kivamlastiricilardan hidroksietil selüloz miktarinin kütlece %0,01 - 10,0 araliginda, ksantan gam miktarinin kütlece %0,01 - 20,0 oldugu Istem 19,daki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Kivamlastiricilardan hidroksietil selüloz miktarinin kütlece %0,1 - 5,0 araliginda, ksantan gam miktarinin kütlece %0,1 - 10,0 oldugu Istem 20,deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Kivamlastiricilardan hidroksietil selüloz miktarinin kütlece % 1,0 - 3,0 araliginda, ksantan gam miktarinin kütlece %0,2 - 5,0 oldugu Istem 21 ”deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. EDTA türevleri veya tetrasodyum glutamate diasetat selatlayicilarindan en az birinin selatlayici olarak kullanildigi Istem 1,deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Selatlayici olarak tetrasodyum EDTA'nin kullanildigi Istem 235teki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Antibakteriyel ajan olarak fenoksietanol'un kullanildigi Istem l,deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi Fenoksietanol miktarinin kütlece %0,01 - 1,0 oranlari araliginda oldugu Istem 255teki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Fenoksietanol miktarinin kütlece %0,05 - 0,8 oranlari araliginda oldugu Istem 26idaki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Fenoksietanol miktarinin kütlece %0,l - 0,6 oranlari araliginda oldugu Istem 279deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Antibakteriyel ajanin etkinligini arttiran dogal hammadde olarak çay agaci yaginin kullanildigi Istem l,deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Çay agaci yagi miktarinin kütlece %0,01 - 5,0 oranlari araliginda oldugu Istem 29idaki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Çay agaci yagi miktarinin kütlece %0,05 - 3,0 oranlari araliginda oldugu Istem 30,daki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Çay agaci yagi miktarinin kütlece %0,l - 1,0 oranlari araliginda oldugu Istem 319deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. parfüm ilavesi edilmesi adimini içeren Istem l,deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. renklendirici ilavesi edilmesi adimini içeren Istem l,deki gibi sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi. Yukaridaki istemlerden herhangi birindeki gibi bir yöntemle elde edilen ve biyobozunur, 5°C - 50°C sicaklik araliklarinda fiziksel olarak kararli olan ve 7 - 32 Fransiz Sertliginde yüksek yikama performansina sahip, Istem l,deki gibi bir sabun bazli antibakteriyel bir sivi sabun elde edilmesi yöntemi.2. As the fatty acid in the vegetable fatty acid solution; The method of obtaining a soap-based antibacterial liquid soap as in claim 1, in which vegetable fatty acid chains between C8 and C18 are used. . As the fatty acid in the vegetable fatty acid solution; The method of obtaining a soap-based antibacterial liquid soap as in Claim 2, in which vegetable fatty acid chains between Cl2 - C18 are used. . As the fatty acid in the vegetable fatty acid solution; The method of obtaining a soap-based antibacterial liquid soap as in claim I or 2, wherein at least one fatty acid selected from the group consisting of caprylic acid acids and mixtures thereof is used. As the fatty acid in the vegetable fatty acid solution; The method of obtaining a soap-based antibacterial liquid soap as in claim 4, in which at least one fatty acid selected from a group consisting of vegetable saturated oil (C 16H3202) and a mixture thereof is used. Claim that a mixture of vegetable saturated fatty acids with a ratio of lauric acid in the range of 1.0 - 50.0 by mass, myristic acid between 1.0 - 20.0 by mass, and palmitic acid in the range of 1.0 - 20.0 by mass, is used. 5, a method of obtaining a soap-based antibacterial liquid soap. A mixture of vegetable saturated fatty acids in which the ratio of lauric acid is between 5.0% and 40.0% by mass, the ratio of myristic acid is between 3.0% and 15.0% by mass, and the ratio of palmitic acid is between 3.0% and 10.0% by mass. Method of obtaining a soap-based antibacterial liquid soap as in 6. Claim that a mixture of vegetable saturated fatty acids with a ratio of lauric acid in the range of 10.0 - 30.0 mass%, myristic acid ratio in the range of 3.0 - 10.0% by mass and palmitic acid ratio in the range of 4.0 - 8.0% by mass is used. A method of obtaining a soap-based antibacterial liquid soap as in T. The method of obtaining a soap-based antibacterial liquid soap as in Claim 5, where the ratio of lauric acid from vegetable saturated fatty acids is in the range of 10.0 - 30.0% by mass, and the ratio of myristic acid is between 3.0 - 10.0% by mass. The method of obtaining a soap-based antibacterial liquid soap as in Claim 5, where the ratio of lauric acid from vegetable saturated fatty acids is between 10.0 - 30.0% by mass, and the ratio of palmitic acid is between 3.0 - 10.0% by mass. Base solution/basic material of at least one selected from potassium hydroxide (KOH), sodium hydroxide (NaOH), monoethanolamine (HzNCHzCH2OH), diethanolamine (HN(CH2CH2OH)2), triethanolamine (N(CH2CH2OH)3) or ammonia (NH3) bases Method of obtaining a soap-based antibacterial liquid soap as in Claim 1, where it is used as Method of obtaining a soap-based antibacterial liquid soap as in Claim, in which potassium hydroxide (KOH) is used as the basic material. The method of obtaining a soap-based antibacterial liquid soap as in Claim 1 or 12, where the amount of basic material is between 1.0% and 30.0% by mass. The method of obtaining a soap-based antibacterial liquid soap as in Claim 13, where the amount of basic material is in the range of 5.0-20.0% by mass. The method of obtaining a soap-based antibacterial liquid soap as in Claim 14, where the amount of basic material is in the range of 7.0 - 10.0% by mass. The method of obtaining a soap-based antibacterial liquid soap as in Request, in which at least one of the sodium chloride (NaCl), sodium sulfate (N aSO4) and potassium chloride (KCl) salt solutions is used as a salt solution. The method of obtaining a soap-based antibacterial liquid soap as in Claim 16, in which sodium chloride (NaCl) salt solution is used as the salt solution. As a thickener; The method of obtaining a soap-based antibacterial liquid soap as in Claim 1, where at least one of hydroxyethyl cellulose, hydroxymethyl cellulose, hydroxyethylmethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, xanthan gum, guar gum, acrylate copolymer emulsions and all other thickeners is used. Method of obtaining a soap-based antibacterial liquid soap as in claim 1, in which hydroxyethyl cellulose or xanthan gum is used as a thickener. The method of obtaining a soap-based antibacterial liquid soap as in Claim 19, where the amount of hydroxyethyl cellulose from the thickeners is in the range of 0.01 - 10.0% by mass, and the amount of xanthan gum is 0.01 - 20.0% by mass. The method of obtaining a soap-based antibacterial liquid soap as in Claim 20, where the amount of hydroxyethyl cellulose from the thickeners is in the range of 0.1 - 5.0% by mass and the amount of xanthan gum is 0.1 - 10.0% by mass. The method of obtaining a soap-based antibacterial liquid soap as in Claim 21, where the amount of hydroxyethyl cellulose from the thickeners is in the range of 1.0 - 3.0% by mass and the amount of xanthan gum is 0.2 - 5.0% by mass. The method of obtaining a soap-based antibacterial liquid soap as in claim 1, wherein at least one of the EDTA derivatives or tetrasodium glutamate diacetate chelators is used as the chelator. The method of obtaining a soap-based antibacterial liquid soap as in claim 235 using tetrasodium EDTA as the chelator. Method of obtaining a soap-based antibacterial liquid soap as in Claim 1 where phenoxyethanol is used as an antibacterial agent. The method of obtaining a soap-based antibacterial liquid soap as in Claim 26, where the amount of phenoxyethanol is in the range of 0.05% - 0.8% by mass. The method of obtaining a soap-based antibacterial liquid soap as in Claim 279, where the amount of phenoxyethanol is in the range of 0.1% - 0.6% by mass. Method of obtaining a soap-based antibacterial liquid soap as in Claim 1, in which tea tree oil is used as a natural raw material that increases the effectiveness of the antibacterial agent. The method of obtaining a soap-based antibacterial liquid soap as in claim 29, where the amount of tea tree oil is in the range of 0.01 - 5.0% by mass. The method of obtaining a soap-based antibacterial liquid soap as in Claim 30, where the amount of tea tree oil is in the range of 0.05 - 3.0% by mass. The method of obtaining a soap-based antibacterial liquid soap as in Claim 319, where the amount of tea tree oil is in the range of 0,1 - 1,0% by mass. The method of obtaining a soap-based antibacterial liquid soap as in claim 1 comprising the step of adding perfume. The method of obtaining a soap-based antibacterial liquid soap as in claim 1, comprising the step of adding colorant. Obtaining a soap-based antibacterial liquid soap as in claim 1, obtained by a method according to any one of the above claims and which is biodegradable, physically stable in the temperature range of 5°C to 50°C, and having high washing performance at a French Hardness of 7 - 32. method.
TR2017/20948A 2017-12-20 2017-12-20 DEVELOPMENT OF SOAP-BASED NATURAL ANTIBACTERIAL LIQUID SOAP FORMULA TR201720948A2 (en)

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PCT/TR2018/050750 WO2019199255A2 (en) 2017-12-20 2018-11-30 Developing natural soap based antibacterial liquid soap formula

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CN114736747A (en) * 2022-03-18 2022-07-12 山东利尔康医疗科技股份有限公司 Antibacterial soap solution containing natural plant components and preparation method thereof

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US4663070A (en) * 1985-01-25 1987-05-05 Lever Brothers Company Process for preparing soap-acyl isethionate toilet bars
US6730642B1 (en) * 2003-01-10 2004-05-04 Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. Extruded multiphase bars exhibiting artisan-crafted appearance
JP5977433B2 (en) * 2012-03-26 2016-08-24 ザ プロクター アンド ギャンブル カンパニー Cleaning composition comprising pH-switchable amine surfactant
CN106591011B (en) * 2016-10-21 2018-03-27 威莱(广州)日用品有限公司 A kind of antibacterial soap and preparation method thereof
CN106833986A (en) * 2016-12-25 2017-06-13 池州市建东生物科技有限公司 The antibacterial special soap of one kind analgesic

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