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TR201611238A2 - GLAZING GLASS CONTAINER AND PRODUCTION METHOD IN THE DARK - Google Patents

GLAZING GLASS CONTAINER AND PRODUCTION METHOD IN THE DARK Download PDF

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Publication number
TR201611238A2
TR201611238A2 TR2016/11238A TR201611238A TR201611238A2 TR 201611238 A2 TR201611238 A2 TR 201611238A2 TR 2016/11238 A TR2016/11238 A TR 2016/11238A TR 201611238 A TR201611238 A TR 201611238A TR 201611238 A2 TR201611238 A2 TR 201611238A2
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TR
Turkey
Prior art keywords
coating
pigment
paint
phosphorescent
dark
Prior art date
Application number
TR2016/11238A
Other languages
Turkish (tr)
Inventor
Gülşah Kahraman Hali̇de
Original Assignee
Tuerkiye Sise Ve Cam Fabrikalari Anonim Sirketi
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Application filed by Tuerkiye Sise Ve Cam Fabrikalari Anonim Sirketi filed Critical Tuerkiye Sise Ve Cam Fabrikalari Anonim Sirketi
Priority to TR2016/11238A priority Critical patent/TR201611238A2/en
Priority to PCT/TR2017/050383 priority patent/WO2018070960A2/en
Publication of TR201611238A2 publication Critical patent/TR201611238A2/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001General methods for coating; Devices therefor
    • C03C17/003General methods for coating; Devices therefor for hollow ware, e.g. containers
    • C03C17/005Coating the outside
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/007Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22Luminous paints
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer
    • C03C2217/43Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/44Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
    • C03C2217/445Organic continuous phases
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer
    • C03C2217/43Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/48Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific function
    • C03C2217/485Pigments

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Composite Materials (AREA)
  • Dispersion Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

Bu buluş, belirli bir süre ışık kaynağına maruz kaldıktan sonra karanlık ortamda veya siyah ışık (black light) altında ışıldama özelliğine sahip bir cam kap (1) ve bu kabın üretim yöntemi (100) ile ilgilidir.The present invention relates to a glass container (1) having the feature of luminescence in the dark environment or under black light after being exposed to a light source for a certain period of time and the production method (100) of this container.

Description

TARIFNAME KARANLIKTA ISILDAYAN CAM KAP VE ÜRETIM YÖNTEMI Teknik Alan Bu bulus, belirli bir süre isik kaynagina maruz kaldiktan sonra karanlik ortamda veya siyah isik (black light) altinda isildama özelligine sahip bir cam kap ve üretim yöntemi ile ilgilidir. Önceki Teknik Bir atom veya inolekülün elektronlarinin en düsük enerjili orbitallere yerlesimi ile atom veya molekülün temel enerji düzeyi veya temel hali olusmaktadir. DESCRIPTION HEAT-IN DARK GLASS CONTAINER AND MANUFACTURING METHOD Technical Area This invention can be found in a dark environment after being exposed to a light source for a certain period of time. or a glass container with the ability to glow under black light and production relates to method. Prior Art With the placement of the electrons of an atom or inolecule in the lowest energy orbitals the fundamental energy level or ground state of an atom or molecule.

Elektronlarin daha üst enerji düzeylerine yerlesmesi, atom veya molekülün uyarilmis hali olarak tanimlanmaktadir. Bazi maddeler bir isik kaynagi tarafindan uyarildiklarinda, üzerlerine düsen isinlari absorbe ederek uyarilmis hale geçmektedirler. Isinlama kesilince uyarilmis halden temel hale dönerken aradaki enerji farkini foton olarak yayimlamaktadirlar. (elektronun temel enerji düzeyine geri dönmesi için geçen süre) göre floresans ve fosforesans olarak ikiye ayrilmaktadir. The placement of electrons in higher energy levels, the atom or molecule known as the excited state. Some substances are destroyed by a light source. When excited, they become excited by absorbing the rays falling on them. they pass. When the irradiation is stopped, it returns from the excited state to the ground state. they radiate the energy difference as photons. fluorescence (the time it takes for the electron to return to its ground energy level) and phosphorescence is divided into two.

Bir atomun veya molekülün bir Çift elektronundan biri daha yüksek bir enerji seviyesine uyarilirsa ya bir singlet ya da bir triplet hal meydana gelmektedir. One of a pair of electrons of an atom or molecule has a higher energy If the level is excited, either a singlet or a triplet state occurs.

Uyarilmis singlet halde, uyarilmis elektronun spini hala temel haldeki elektron ile eslesmis durumdadir. Bununla beraber, triplet halde, iki elektronun spinleri eslesmemis durumda ve uyarilmis triplet haldeki bir molekülün özellikleri, uyarilmis singlet halindekinden önemli derecede farklidir. Uyarilmis triplet halden temel singlet hale geçmesiyle yayilan isiga fosforesans denir. Bir triplet -› singlet geçisi singlet -› singlet dönüsümüne göre çok daha az mümkündür; bu nedenle, uyarilmis triplet halin ortalama ömrü, singlet halin ömründen daha uzundur ve böyle bir geçisten kaynaklanan emisyon, isinlanma kesildikten sonra biraz daha sürebilir. F lüoresans isima daima sogurulan dalga boyundan daha uzun dalga boylu yani daha düsük enerjilidir. Fosforesans ise, iloresans ile iliskili bir çesit isildama sekli olarak tanimlanabilmektedir. Floresanstan farkli olarak fosforesans maddeler sogurduklari enerjiyi hizlica geri vermemektedirler. Ayrica, temel haldeki bir molekülün isinla, bir triplet hale uyarilmasi, düsük olasiliga sahiptir ve bu islem sonucu olusan absorpsiyon piklerinin siddeti, benzer sekilde singlet-singlet geçisine karsi gelenlerinkinden birkaç kat ondalik inertebesi daha düsüktür. In the excited singlet state, the spin of the excited electron is still with the electron in the ground state. is in a matched state. However, in the triplet state, the spins of the two electrons properties of a molecule in the unpaired and excited triplet state, significantly different from the excited singlet state. from excited triplet state The light emitted by the transition to the basic singlet state is called phosphorescence. a triplet -› singlet singlet -› much less possible than singlet conversion; because, The average lifetime of the excited triplet state is longer than the lifetime of the singlet state, and The emission from such a transition is slightly higher after the irradiation has ceased. it may take. Fluorescence is always longer wavelength than the absorbed wavelength. that is, it has lower energy. Phosphorescence, on the other hand, is a type of luminescence associated with fluorescence. can be defined as a form. Unlike fluorescence, phosphorescent substances they do not quickly return the energy they have absorbed. In addition, a basic Excitation of the molecule to a triplet state by radiation has a low probability, and this process The intensity of the absorption peaks that occur as a result of this, similarly depends on the singlet-singlet transition. it has several decimal inertia lower than that of its counterparts.

Fosforesans özellige sahip malzemeler basta plastik ve boya olinak üzere birçok alanda kullanilmaktadirlar. Fosforesans özellige sahip kimyasal malzemeler pigment olarak tedarik edilmekte ve kullanim alanina göre tasarlanmis boya sistemlerinde kullanilarak uygulandiklari yüzeye karanlik ortamda parlama özelligi kazandirmaktadirlar. Cam; boya uygulanabilirligi açisindan metal, ahsap, kâgit, kompozit, plastik ve beton gibi birçok yüzeye göre daha zordur. Mevcut fosforesans boya sistemleri cam yüzeyine uygulandiginda mekanik mukavemet ve etki açisindan yetersiz kalmaktadirlar. Cama fosforesans etkiye sahip pigmentler ilave edilerek karanlikta isildama özelligi de kazandirilabilmektedir. Ancak bu yöntemde cam kompozisyonunda ilgili pigmentler homojen olarak dagitilamamaktadirlar. Materials with phosphorescence feature, especially plastic and paint, many are used in the field. Chemical materials with phosphorescence It is supplied as a pigment and is a paint designed according to the area of use. Glow feature in dark environment to the surface on which they are applied by using they are gaining. Pine; in terms of paint applicability, metal, wood, paper, It is harder than many surfaces such as composite, plastic and concrete. Current phosphorescence mechanical strength and impact when paint systems are applied to the glass surface they are insufficient in terms of Adding pigments with a phosphorescent effect to the glass It can also gain the ability to glow in the dark. However, in this method Related pigments cannot be distributed homogeneously in the glass composition.

Ilave olarak bu yöntem oldukça maliyetlidir. Piyasada bulunan fosforesans özellikli boyalar farkli yüzeylere uygulamakta olup, cam yüzeyi ile yeteri ve etkin adezyon saglanamamaktadir. Cam yüzeyi ile uyumlu pigmentsiz (renksiz) boya sistemlerine, fosforesans pigment dâhil edildiginde, boya sisteminde çökme (faz ayrimi) problemleri yasanmaktadir. Cama fosforesans özelligi kazandirmak harmanda renklendirme ile de mümkündür. Ancak bu yöntemde de pigmentin cam kompozisyonu içerisinde homojen olarak dagilmasi saglanamamakta ve tüm cam yüzeyinde etki görünememektedir. Genellikle ucuz olmalarindan dolayi ZnS:Cu tipi fosforlar tercih edilmektedirler ancak pek çok uygulama için yeteri kadar parlak ve uzun ömürlü degillerdir. In addition, this method is quite costly. Phosphorescent feature available in the market paints are applied on different surfaces, sufficient and effective adhesion with the glass surface. cannot be provided. Pigmentless (colorless) paint compatible with the glass surface When phosphorescent pigment is included in the paint systems, the paint system collapses (phase separation) problems are experienced. To give phosphorescence property to glass It is also possible with coloring in the blend. However, in this method, the pigment It cannot be distributed homogeneously in its composition and all glass No effect is visible on the surface. Usually ZnS:Cu because they are cheap type phosphors are preferred, but they are sufficient for most applications. They are not bright and long-lasting.

Teknigin bilinen durumunda yer alan Dl: USZOO sayili Birlesik Devletler dokümaninda, fosforesans isik yayan bir kaptan bahsedilmektedir. Bu kap, konserve sisesi, cam veya plastik Sise, karton ve daha birçok inateryalden elde edilebilmektedir. Kabin dis yüzeyi üzerinde, isik kaynagi yoklugunda fosforesans isima yapan bir kaplama bulunmaktadir. Söz konusu dokümanda isik kaynaginin yoklugunda etrafa isik yayma özelligi fosforesans pigmentler ile saglanmaktadir. Dl: USZOO, which is in the state of the art, In the States document, a vessel emitting phosphorescent light is mentioned. This can be obtained from containers, cans, glass or plastic bottles, cardboard and many other materials can be achieved. Phosphorescence on cabinet outer surface in absence of light source It has a naming coating. In the document in question, the light source In the absence of light, the feature of emitting light is provided by phosphorescent pigments.

Ancak, basvuru konusu bulusta fosforesans pigmentler seçilen bir boya içerisine karistirilmakta ve bir kaplama karisimi elde edilmektedir ve elde edilen karisim cam yüzeye çesitli yöntemlerde kaplanmaktadir. Söz konusu Dl dokümaninda kullanilan pigment, boya çesidi ve boya performansi hakkinda bilgi bulunmamaktadir. However, in the subject invention, phosphorescent pigments are incorporated into a selected dye. is mixed and a coating mixture is obtained, and the resulting mixture is glass It is coated on the surface in various methods. In the DL document in question Information about the pigment used, type of paint and paint performance does not exist.

Teknigin bilinen durumunda yer alan US6123872 sayili Birlesik Devletler dokümaninda uzun süreli afterglow ve isikla uyarilmis lüminesans özelligine sahip floresans veya fosforesans oksit cam açiklanmaktadir. Bahsi geçen dokümanda enerji, isima ile uyarilarak depolanmaktadir. Bu isimalara, Gama-ray, X-ray ve UV- ray isinlari vb. örnek verilebilir. Söz konusu dokümanda geçen cam, uzun süreli sonradan isildayan (afterglow) ve isikla uyarilmis lüminesans özelliklerini sergileyen fosforesans camdir ve camin kimyasal bilesimi açiklanmaktadir. United States numbered US6123872 in the state of the art It has long-term afterglow and light-stimulated luminescence. fluorescence or phosphorescence oxide glass is described. In the aforementioned document energy is stored by being excited by heat. These names are Gamma-ray, X-ray and UV- ray rays etc. example can be given. The glass mentioned in the document in question is a long-term afterglow and light-evoked luminescence properties It is phosphorescent glass that exhibits, and the chemical composition of the glass is described.

Basvuru konusu bulusta ise bir cam yüzeyi üzerinde uygulama yapilmaktadir. In the invention, which is the subject of the application, the application is made on a glass surface.

Teknigin bilinen durumunda yer alan dokümanda alternatif olarak cam yüzey üzerine kaplama yapilabilecegi söylenmistir ancak yapilan kaplamada pullanarak soyulma (peeling off) problemi gözlenmektedir. Basvuru konusu bulusta ise cam yüzey üzerine yapilan kaplamanin dayanimi yüksektir ve herhangi bir soyulma sorunu yasanmamaktadir. As an alternative in the document in the state of the art, the glass surface It has been said that coating can be applied on it, but it will be flaked on the coating. peeling off problem is observed. If the subject of the application is the invention, the glass The coating on the surface has high strength and any peeling problem does not occur.

Teknigin bilinen durumunda yer alan U sayili Birlesik Devletler dokümaninda, karanlikta isildama özelligine sahip yiyecek ve içecek saklama kaplari açiklanmaktadir. Söz konusu dokümanda bahsedilen kap, üfleme yolu ile (blow molded) sekillendirilmis, isiltili, polietilen saklama kabi veya siselerdir. Söz konusu kaplara karanlikta isildama özelligi, polietilen reçineye kütlece yüzde 0.075-l.2 araliginda çinko sülfür lüminesans pigment karistirilarak elde edilmektedir. Dokümanda açiklanan kaplar plastik özellikte kaplar olup, kaplara fosforesans isildama özelligi kazandiran pigment çinko sülfür temellidir. Basvuru konusu bulusta ise fosforesans pigment olarak daha uzun isima süresine sahip olan stronsiyum alüminat kullanilmakta ve fosforesans etki cam yüzeyler üzerine yapilan kaplama ile saglanmaktadir. The United States with the number U in the state of the art food and beverage storage with glow-in-the-dark feature containers are described. The container mentioned in the aforementioned document is blown. (blow molded) shaped, glowing, polyethylene storage containers or bottles. Promise The glow-in-the-dark property of the containers in question is attached to polyethylene resin in percent by mass. It is obtained by mixing zinc sulfide luminescence pigment in the range of 0.075-l.2. is being done. The containers described in the document are plastic containers. The pigment that gives phosphorescence luminescence is zinc sulfide based. Application In the present invention, it is a phosphorescent pigment with a longer heating time. strontium aluminate is used and the phosphorescence effect is on glass surfaces. It is provided with the coating made.

Teknigin bilinen durumunda yer alan NL sayili Hollanda dokümaninda, serigrafi baski veya sprey kaplama ile cam yüzeyi üzerine fosforesans pigment uygulanmasi açiklanmaktadir. Isik yayan cam üzerine uygulanan fosforesans pigmentlerin kimyasal formüllerinden biri SrAl204:Eu,Dy olarak verilmektedir. Ancak stronsiyum alüminat pigment seramik veya baska bir mürekkep sistemine karistirilmaktadir. Basvuru konusu bulusta fosforesans pigment bir boya sistemine karistirilmakta ve cam yüzey elde edilen karisim ile kaplanmaktadir. Ek olarak teknigin bilinen durumunda yer alan dokümanda, üzerine uygulama yapilan cam, düz camdir. Basvuru konusu bulusta ise uygulama silindirik yüzeyler üzerine yapilmaktadir. Netherlands numbered NL, which is in the state of the art on the glass surface by screen printing or spray coating. The application of phosphorescent pigment is explained. on light emitting glass One of the chemical formulas of applied phosphorescent pigments is SrAl204:Eu,Dy are given as. However, the strontium aluminate pigment is made of ceramic or other mixed into the ink system. Phosphorescence in the subject invention The pigment is mixed into a paint system and the glass surface is mixed with the resulting mixture. is covered. In addition, in the document in the state of the art, The glass on which the application is made is flat glass. If the subject of the application is the invention, the application made on cylindrical surfaces.

Teknigin bilinen durumunda yer alan JP sayili Japon dokümaninda bir fosforesans kompozisyon açiklanmaktadir. Kompozisyon, inorganik fosforesans pigment, Ilüoresans boya ve baglayici (binder) içermektedir. Söz konusu dokümanda açiklanan kompozisyonda bulunan pigmentin kimyasal formülü SrA1204:Eu,Dy olarak verilmektedir ve karanlik ortamda mavi-yesil isilti elde edilmektedir. Ancak elde edilen karisimin hangi yüzeyler üzerine, ne sekilde uygulandigina dair bir ögreticilik bulunmamaktadir. Basvuru konusu bulus, siyah isik (black light) altinda sonsuz isildama özelligine sahiptir. Teknigin bilinen durumunda yer alan dokümanda ise bulusun siyah isik altindaki performansina dair bir bilgi bulunmamaktadir. Ayni zamanda teknigin bilinen durumunda yer alan dokümanda dayanim ve yüzey özelliklerine dair de bir açiklama yer almamaktadir. In the Japanese document no. JP, which is in the state of the art, A phosphorescent composition is disclosed. Composition, inorganic It contains phosphorescent pigment, Iluorescence dye and binder. Promise chemical composition of the pigment in the composition described in the document in question. Its formula is given as SrA1204:Eu,Dy and gives a blue-green glow in the dark. is obtained. However, on which surfaces and in what form the mixture obtained There is no instruction about its implementation. Subject invention, black It has the ability to shine infinitely under black light. known technique In the document in the case of there is no information. At the same time, in the state of the art, There is no explanation in the document about strength and surface properties.

Teknigin bilinen durumunda yer alan TW sayili Tayvan dokümaninda fosforesans boya açiklanmaktadir. Söz konusu dokümanda geçen boyada boyutu 15 mikrondan küçük toz fosforesans ve saydam vernik içermektedir. Taiwan with the number TW in the state of the art document describes the phosphorescent dye. mentioned in the document The paint contains powder phosphorescence and transparent varnish smaller than 15 microns in size.

D6 dokümaninda yer alan boyada bulunan pigmentlerin vernige orani 0.9~l.l:l olacak sekildedir. Elde edilen karisim, cam dâhil olmak üzere birçok yüzeye uygulanabilmektedir ancak karisimin UV ile kürlenebilen serigrafik baski ile cam yüzeyine aktarmasina dair bir bilgi bulunmamaktadir. The ratio of the pigments in the paint in the D6 document to the varnish is 0.9 ~ l.l:l will be the way it is. The resulting mixture can be applied to many surfaces, including glass. However, the mixture can be applied to glass with UV-curable silk-screen printing. There is no information about its transfer to the surface.

Mevcut teknikte, stronsiyum alüminat temelli fosforesans pigmentlerin, etkilerini minimum düzeyde azaltan bir tasiyici boya sistemi ile birlestirilerek elde edilen bir karisimin cam yüzeylere sprey, serigrati ve tampon baski yöntemleri ile kaplandigi bir uygulama bulunmamaktadir. Fosforesans pigmentlerin kaplama yöntemine göre tercih edilen boya sistemine ilavesiyle elde edilen karisim, cam yüzeyi üzerine saglam bir sekilde tutunmakta ve uygulandiklari yüzeyin karanlik oitamda ve siyah isik altinda tercih edilen pigment rengine göre isildamasini saglamaktadir. In the current art, the effects of strontium aluminate-based phosphorescent pigments obtained by combining it with a carrier paint system that minimizes the mixture is coated on glass surfaces by spray, serigraphy and pad printing methods. There is no application. According to the coating method of phosphorescent pigments The mixture obtained by adding it to the preferred paint system is applied to the glass surface. They are firmly attached and the surface on which they are applied is dark and black. It makes it shine according to the preferred pigment color under the light.

Bulusun Amaçlari Bu bulusun amaci, fosforesans pigment içeren bir boya ile kaplanmis bir cam kap ve bu kabin üretim yöntemini gerçeklestirmektir. Objectives of the Invention The object of this invention is a glass container coated with a dye containing phosphorescent pigment. and this is to realize the cabinet production method.

Bu bulusun amaci, fosforesans pigmentlerin etkisini engellemeyen, cam yüzeyi ile uyumlu olan bir kaplamaya sahip bir cam kap ve bu kabin üretim yöntemini gerçeklestirmektir. The aim of this invention is to work with glass surface, which does not interfere with the effect of phosphorescent pigments. a glass container with a coating that is compatible with this cabinet is to perform.

Bu bulusun amaci, bir isik kaynagina maruz kaldiktan sonra karanlik ortamda yüksek siddette, uzun süreli isima yapan bir kaplamaya sahip bir cam kap ve bu kabin üretim yöntemini gerçeklestirmektir. The purpose of this invention is to use it in the dark after exposure to a light source. a glass vessel with a high-intensity, long-term heating coating, and to realize the cabin production method.

Bu bulusun amaci, siyah isik altinda sonsuz isildama özelligine sahip bir cam kap ve bu kabin üretim yöntemini gerçeklestinnektir, Bu bulusun amaci, yüzey geometrisinden bagimsiz homojen bir kaplamaya sahip bir cam kap ve bu kabin üretim yöntemini gerçeklestirmektir. The aim of this invention is to create a glass container with infinite luminescence under black light. and this is to realize the cabinet production method, The aim of this invention is to have a homogeneous coating independent of surface geometry. a glass container and this cabinet is to realize the production method.

Bu bulusun bir diger amaci, UV ve/Veya isi ile kürlenebilen boya sistemleri ile sprey boyama, serigrafi ve tampon baski gibi birçok kaplama yöntemi ile uygulanabilen bir kaplamaya sahip bir cam kap ve bu kabin üretim yöntemini gerçeklestirmektir. Another object of this invention is to work with UV and/or heat curable paint systems. with many coating methods such as spray painting, screen printing and pad printing. a glass container with an applicable coating and this cabinet manufacturing method is to perform.

Bulusun Kisa Açiklamasi Bu bulusun amacina ulasmak için gerçeklestirilen ilk istem ve bu isteme bagli diger istemlerde tanimlanan karanlikta isildayan cam kap, bir hazne içermektedir. Hazne, tercih edilen sicaklikta maddenin dolduruldugu, içerisine doldurulan maddeyi çevreleyen hacimdir. Haznenin kullaniciya bakan ve belirli bir süre isik kaynagina maruz kaldiktan sonra karanlik ortamda isildayan veya siyah isik kaynagi altinda sonsuz isildayabilen kaplamanin yapildigi kisim dis yüzeydir. Dis yüzey, dogrudan haznenin kullaniciya bakan cam kismi olabilecegi gibi bir veya daha fazla kaplamadan olusan bir katman da olabilmektedir. Dis yüzeyin üzerinde, belirli bir süre isik kaynagina maruz kaldiktan sonra karanlikta isildayan veya siyah isik kaynagi altinda sonsuz isima yapan fosforesans kaplama bulunmaktadir. Brief Description of the Invention The first request made in order to achieve the purpose of this invention and other related requests. The glow-in-the-dark glass container as defined in the claims includes a reservoir. Receptacle, the substance in which the substance is filled at the preferred temperature, is the surrounding volume. The chamber is facing the user and to the light source for a certain period of time. glowing in the dark after exposure or under a black light source The part where the infinitely radiant coating is made is the outer surface. outer surface, directly The chamber may be the glass part facing the user, as well as one or more It can also be a layer of coating. On the outer surface, a certain glow-in-the-dark or black light after exposure to a light source for a period of time Under the source, there is a phosphorescent coating that makes infinite heat.

Fosforesans kaplama, dis yüzeyin tamamini veya bir kismini kaplamaktadir. The phosphorescent coating covers all or part of the outer surface.

Fosforesans kaplama, tercih edilen tasiyici boya ve stronsiyum alüminat temelli fosforesans pigmentin karistirilarak dis yüzey üzerine uygulanmasi ile elde edilmektedir. Boya, içerisine karistirilan fosforesans pigmenti dis yüzeye aktarmakta ve pigmenti dis etkilerden korumaktadir. Pigment ise karanlik ortamda fosforesans kaplamanin isildamasini saglayan unsurdur. Based on phosphorescent coating, preferred carrier paint and strontium aluminate It is obtained by mixing the phosphorescent pigment and applying it on the outer surface. is being done. The paint, the phosphorescent pigment mixed into it, is applied to the outer surface. transfers and protects the pigment from external effects. The pigment is in the dark environment. It is the element that makes the phosphorescent coating glow.

Bu bulusun amacina ulasmak için gerçeklestirilen, ikinci bagimsiz istem ve bu isteme bagli diger istemlerde tanimlanan belirli bir süre isik kaynagina maruz kaldiktan sonra karanlikta isildayan cam kap üretim yönteminde ilk olarak dis yüzeyin temizlenmesi ve aktiflestirilmesi için bir ön islem uygulanmaktadir. Dis yüzeye uygulanan ön islem fiziksel veya kimyasal olabilmektedir. Ön islemden sonra, tercih edilen baski özelliklerine göre boya/pigment karisim oranlari belirlenmektedir. Oran belirlenmesinin ardindan fosforesans pigmentlerin karistirilacagi boya sistemi hazirlanmaktadir. Boya sisteminin hazirlanmasi ile birlikte pigmentler boyaya karistirilmakta ve kaplama islemi gerçeklestirilmektedir. The second independent claim, carried out to achieve the purpose of this invention, and this exposed to a light source for a certain period of time as defined in other optional claims. In the glass container production method that glows in the dark after A pre-treatment is applied to clean and activate the surface. External The pretreatment applied to the surface can be physical or chemical. from pretreatment then, dye/pigment mixture ratios according to preferred printing properties is determined. After determining the ratio, phosphorescent pigments The paint system to be mixed is being prepared. With the preparation of the paint system Together, the pigments are mixed with the paint and the coating process is carried out.

Dis yüzey üzerine kaplama karisimi aktarilana kadar pigmentlerin dibe çökmesinin engellenmesi amaciyla karisim sürekli olarak karistirilmakta, karistirilirken ayni zamanda boyanin bulundugu karistirma kabinin dip kismindan üst kismina dogru devir daim olmaktadir. Boya/pigment karisimi dis yüzeye aktarildiktan sonra fosforesans kaplamanin olusmasi için kürleme islemi yapilmaktadir. Son olarak dis yüzey üzerinde tercih edilen sekilde fosforesans kaplamanin elde edilip edilmediginin belirlenmesi amaci ile siyah isik kaynagi kullanilarak kontrol islemi gerçeklestirilmektedir. Until the coating mixture is transferred onto the outer surface, the pigments should settle to the bottom. The mixture is mixed continuously in order to prevent from the bottom to the upper part of the mixing cabinet where the paint is is perpetual. After the paint/pigment mixture is transferred to the outer surface The curing process is carried out to form the phosphorescent coating. Lastly, dis whether a phosphorescent coating is obtained on the surface in a preferred way. Control process using a black light source to determine whether is carried out.

Bulusun Ayrintili Açiklamasi Bu bulusun amacina ulasmak için gerçeklestirilen, belirli bir süre isik kaynagina maruz kaldiktan sonra karanlikta isildayan cam kap ve bu kabin üretim yöntemi ekli sekillerde gösterilmis olup bu sekiller; Sekil 1. Cam kabin önden görünüsüdür. Detailed Description of the Invention light source for a certain period of time, carried out to achieve the purpose of this invention. attached glass container that glows in the dark after exposure, and the manufacturing method of this cabinet shown in the figures and these figures; Figure 1. Front view of the glass cabin.

Sekil 2. Kaplamali cam kabin kesitten sematik görünüsüdür. Figure 2. The sematic view of the coated glass cabinet from the cross-section.

Sekil 3. Fosforesans kaplamanin kesitten sematik görünüsüdür. Figure 3. The sematic view of the phosphorescent coating from the cross-section.

Sekil 4. Karanlikta isildayan cam kap üretim yöntemi adimlarinin sematik görünüsüdür. Figure 4. Schematic of the steps of the glow-in-the-dark glass container production method is the view.

Sekillerdeki parçalar tek tek numaralandirilmis olup, bu numaralarin karsiligi asagida verilmistir. 1. Cam kap 2. Hazne Dis yüzey Fosforesans kaplama Tasiyici boya Pigment 100. Karanlikta isildayan cam kap üretim yöntemi Belirli bir süre isik kaynagina maruz kaldiktan sonra karanlik ortamda veya dogrudan siyah isik altinda isildama özelligine sahip bir cam kap (1) en temel halinde, sivi veya kati maddenin dolduruldugu en az bir hazne (2), cam kabin (l) kullaniciya bakan yüzü olan en az bir dis yüzey (3), dis yüzeyin (3) tamamina veya bir kismina uygulanan, tasiyici boya (5) ve pigment (6) içeren, siyah isik altinda ve belirli bir süre isik kaynagina maruz kaldiktan sonra karanlik ortamda isildama saglayan en az bir fosforesans içerisine pigment (6) karistirilarak pigmentin (6) kaplamanin yapilacagi yüzeye tasinmasini saglayan en az bir tasiyici boya (5), bir isik kaynagina maruz kaldiginda, atomlarinin veya moleküllerinin elektronlarinin uyarilarak bir üst enerji seviyelerine geçtigi, isik kaynaginin olmadigi bir ortamda ise üst enerji seviyesindeki elektronlarin daha düsük enerjili alt seviyeye geçerken fazla enerjilerini bir foton olarak yaymasi ile etrafa isilti yayan en bir az bir pigment (6) içermektedir. The parts in the figures are numbered one by one and the corresponding numbers are given below. 1. Glass container 2. Hopper Exterior surface Phosphorescent coating carrier paint Pigment 100. Glow-in-the-dark glass container production method In the dark after being exposed to a light source for a certain period of time, or A glass container (1) that can glow under direct black light is the most basic in case of, at least one chamber (2) filled with liquid or solid matter, glass cabinet (l) at least one outer surface (3) with a user-facing side, Carrier paint (5) applied to all or part of the outer surface (3) and containing pigment (6), under black light and exposed to a light source for a certain period of time. at least one phosphorescence that provides luminescence in the dark after the pigment (6) to be coated by mixing the pigment (6) into it. at least one carrier paint (5) that allows it to be carried to the surface, when exposed to a light source, its atoms or molecules of the light source, in which the electrons of the light source are excited and move to a higher energy level. In an environment where there is no electrons in the upper energy level, by emitting their excess energy as a photon while passing to the lower energy level. it contains at least one pigment (6) that emits a glow around.

Bulusun bir uygulainasinda hazne (2) bulunmaktadir. Hazne (2), sivi veya kati maddenin doldumldugu hacimdir. Haznenin (2) geometrisi, cam kabin (1) geometrisine göre degisiklik gösterebilmektedir. In one embodiment of the invention, the chamber (2) is provided. Reservoir (2), liquid or solid is the volume in which the substance is filled. Geometry of the chamber (2), glass cabinet (1) may vary depending on the geometry.

Bulusun bir uygulamasinda dis yüzey (3) bulunmaktadir. Dis yüzey (3), haznenin (2) kullaniciya bakan kisminda bulunmakta ve cam kabin (1) haznesinin (2) dis bölümünü olusturmaktadir. Dis yüzey (3) cam kabin (l) kaplama yapilan yüzeyidir. In one embodiment of the invention, there is the outer surface (3). The outer surface (3) is (2) is located on the part facing the user and is located outside the glass cabinet (1) chamber (2). forms the section. The outer surface (3) is the surface of the glass cabinet (l) on which the coating is made.

Dis yüzey (3) olarak kimyasal ve/veya fiziksel islem görmüs yüzeyler veya herhangi bir islem görmemis yüzeyler kullanilabilmektedir. Dis yüzey (3) düz veya girintili çikintili bir yapiya sahip olabilmektedir. Dis yüzey (3) renkli saydam, yari saydam, renksiz saydam ve opak olabilmektedir. Bulusun alternatif bir uygulamasinda dis yüzey (3) opak beyaz veya beyaz kaplamali bir yüzeydir. Dis yüzeyin (3) opak beyaz veya beyaz kaplamali olmasi, üzerine uygulanan fosforesans kaplamanin (4) isima süresini ve isima siddetini arttirrnaktaclir. Surfaces that have been chemically and/or physically treated as external surfaces (3), or Untreated surfaces can be used. The outer surface (3) is flat or It can have an indented structure. Outer surface (3) colored transparent, semi-transparent It can be transparent, colorless, transparent and opaque. Find an alternative In its application, the outer surface (3) is an opaque white or white coated surface. External whether the surface (3) is opaque white or white coated, increases the heating time and intensity of the phosphorescence coating (4).

Bulusun bir uygulamasinda dis yüzey (3) üzerinde fosforesans kaplama (4) bulunmaktadir. Fosforesans kaplama (4), belirli bir süre isik kaynagina maruz kaldiktan sonra karanlik bir ortamda yüzeyinde bulundugu cismin ortama isilti yaymasini saglayan yapidir. Fosforesans kaplamanin (4) etki siddeti, tasiyici boya (5) içerisine karistirilan pigmentin (6) parçacik boyutlari ile dogru orantilidir. In one embodiment of the invention, phosphorescent coating (4) on the outer surface (3) are available. The phosphorescent coating (4) is exposed to a light source for a certain period of time. After staying in a dark environment, the object on its surface is illuminated. It is the structure that allows it to spread. The intensity of the phosphorescent coating (4), the carrier paint (5) is directly proportional to the particle size of the pigment (6) mixed into it.

Fosforesans kaplama (4), belirli bir süre bir isik kaynagina maruz kaldiktan sonra karanlikta 0-2 saat arasinda isildayabilmektedir. Fosforesans kaplama (4), siyah isik (black light) kaynagi altinda ise süresiz isildama özelligine sahiptir. Dis yüzey (3) üzerinde bulunan fosfore sans kaplama (4), normal isik altinda renksiz buzlu mat bir görünüme sahiptir, Renksiz buzlu mat görünüm, karanlik ortamda renkli hale gelmektedir. Bulusun alteriiatif bir uygulamasinda fosforesans kaplama (4) üzerine renksiz, seffaf özellikte bir baska kaplama daha yapilmaktadir. Yapilan seffaf kaplama, fosforesans kaplamanin (4) dis etkenlere (örnegin, bulasik makinasi ortami, kimyasallar Vb.) karsi dayanimini arttirmaktadir. Phosphorescent coating (4) after exposure to a light source for a certain period of time. It can glow between 0-2 hours in the dark. Phosphorescent coating (4), black light Under the (black light) source, it has an indefinite glow feature. Outer surface (3) The phosphorescent yellow coating (4) on it is a colorless frosted matte under normal light. It has the appearance of colorless frosted matte appearance, becomes colored in the dark environment. is coming. In an alternative embodiment of the invention, on the phosphorescent coating (4) Another colorless, transparent coating is being made. made transparent coating, the phosphorescent coating (4) is resistant to external factors (for example, dishwasher environment, chemicals etc.) increases its resistance.

Bulusun bir uygulamasinda tasiyici boya (5) bulunmaktadir. Tasiyici boya (5), içerisine belirli bir süre isik kaynagina maruz kaldiktan sonra karanlikta isildama özelligi saglayan pigmentlerin (6) karistirildigi sistemdir. Tasiyici boya (5) ayni zamanda pigmentleri (6) tercih edilen yüzey üzerine aktaran tasiyicidir. Bulusun bu uygulamasinda tasiyici boya (5), cam yüzeyi ile uyumlu bir tasiyici boyadir (5). In one embodiment of the invention, carrier paint (5) is present. Carrier paint (5), glow in the dark after being exposed to a light source for a certain period of time. It is the system in which the pigments (6) that provide this feature are mixed. Carrier paint (5) in-kind It is also the carrier that transfers the pigments (6) onto the preferred surface. find this In its application, the carrier paint (5) is a carrier paint that is compatible with the glass surface (5).

Tasiyici boya (5) olarak su veya solvent bazli sprey, UV ve/Veya isi ile kürlenebilen serigrafik baski veya tampon baski boyalari kullanilabilmektedir. As carrier paint (5), water or solvent based spray, UV and/or heat curable serigraphic printing or pad printing inks can be used.

Bulusun bir uygulamasinda tasiyici boya (5); reçine, sertlestirici ve çözücü içermektedir. Bulusun bir diger uygulamasinda tasiyici boya (5); reçine, aktivatör ve çözücü içermektedir. Bu durumlarda tasiyici boya (5) ile fosforesans pigmentler (6) karistirilarak elde edilen kaplama karisimi, tabanca robotuyla veya elektrostatik diskle veya elektrostatik çanla sprey boyama yöntemleri ile camin kullaniciya bakan dis yüzeyine (3) uygulanmaktadir. In one embodiment of the invention, carrier paint (5); resin, hardener and solvent contains. In another embodiment of the invention, carrier paint (5); resin, activator and solvent. In these cases, the carrier dye (5) and phosphorescent pigments (6) The coating mixture obtained by mixing can be applied with a gun robot or electrostatic the glass to the user by spray painting methods with disc or electrostatic bell. It is applied to the facing outer surface (3).

Bulusun alternatif bir uygulamasinda tasiyici boya (5); UV ile kürlenebilen reçine ve aktivatör içermektedir. Bu durumda tasiyici boya (5) ile pigment (6) karistirilarak elde edilen kaplama karisimi serigrafik baski yöntemi ile camin kullaniciya bakan dis yüzeyine (3) uygulanmaktadir. In an alternative embodiment of the invention, carrier paint (5); UV curable resin and activator. In this case, the carrier dye (5) and the pigment (6) The coating mixture obtained by mixing is applied to the glass by silk-screen printing method. It is applied to the outer surface (3) facing the user.

Bulusun alternatif bir uygulamasinda tasiyici boya (5); isi ile kürlenebilen reçine ve aktivatör içermektedir. Bu durumda tasiyici boya (5) ile pigment (6) karistirilarak elde edilen kaplama karisimi tampon baski yöntemi ile camin kullaniciya bakan dis yüzeyine (3) uygulanmaktadir. In an alternative embodiment of the invention, carrier paint (5); heat-curable resin and Contains activator. In this case, the carrier dye (5) is mixed with the pigment (6). The obtained coating mixture was applied to the outer surface of the glass facing the user with the pad printing method. applied to the surface (3).

Bulusun bu uygulamasinda, tercih edilen tasiyici boya (5) sisteminin içerisine pigment (6) karistirilrnaktadir. Tasiyici boyaya (5) karistirilan pigment (6), belirli bir süre isik kaynagina maruz kaldiktan sonra karanlik ortamda isildama yapan bir pigment (6) çesididir. Pigment (6), floresan ve/veya fosforesans pigment (6) olabilmektedir. Bulusun tercih edilen uygulamasinda, karanlik ortamda isildama süresinin daha uzun olmasi sebebi ile fosforesans pigment (6) kullanilmaktadir. Bir atom veya molekülde elektronlarin en düsük enerjili orbitallere yerlesimi ile atom veya molekülün temel enerji düzeyi veya temel hali olusturmaktadir. Elektronlarin daha üst enerji düzeylerine yerlesmesi ile atom veya molekülün uyarilmis hali olusmaktadir. Uyarilmis bir atom veya molekül kararsiz yapidadir ve fazla enerjisini atarak temel hale dönmek istemektedir. Atom veya molekül temel enerji düzeyine dönerken fazla enerjisinin bir kismini veya tamamini emisyon seklinde atabilir ve böylece sistemden bir isik emisyonu gözlenmektedir. Fosforesans pigmentlerde (6) uyarilmis bir triplet sistemden temel haldeki bir singlet sisteme geçis gerçeklesmektedir. Pigment (6) tasiyici boyaya (5) tercihen toz formda karistirilmaktadir. Tasiyici boyaya (5) karistirilan pigmentin (6) parçacik boyutlari 0-100 mikron arasindadir. Bulusun tercih edilen uygulamasinda ortalama pigment (6) tane boyutu 2-40 mikron araliginda olacak sekilde optimize edilmistir. Tasiyici boya (5) ve pigment (6) içeren fosforesans kaplamaya (4) fosforesans özellik, birçok fosforesans pigment (6) ile kazandirilabilmektedir. Bulusun tercih edilen uygulamasinda kullanilan pigment (6) stronsiyum alüminat temelli olup kimyasal formülü SrAlzO4zEu,Dy seklindedir. Uyarilmalar sonucu ortama yayilan isigin dalga boyu 450-550 nm arasindadir. In this embodiment of the invention, the preferred carrier paint (5) is inserted into the system. pigment (6) is mixed. The pigment (6) mixed with the carrier paint (5) a light that glows in the dark after being exposed to a light source for a while. type of pigment (6). Pigment (6), fluorescent and/or phosphorescent pigment (6) can happen. In the preferred embodiment of the invention, luminescence in the dark Phosphorescent pigment (6) is used due to its longer duration. A Atom with the placement of electrons in the lowest energy orbitals in the atom or molecule or the fundamental energy level or ground state of the molecule. your electrons The excited state of an atom or molecule with its placement in higher energy levels is formed. An excited atom or molecule is unstable and He wants to throw away his energy and return to the basic state. Atom or molecule fundamental energy some or all of its excess energy in the form of emission when returning to the level so that a light emission from the system is observed. phosphorescence from an excited triplet system to a ground-state singlet system in pigments (6) transition is taking place. The pigment (6) is added to the carrier paint (5), preferably in powder form. are mixed. Particle dimensions of the pigment (6) mixed into the carrier paint (5) It is between 0-100 microns. Average pigment in the preferred embodiment of the invention (6) the grain size is optimized to be in the range of 2-40 microns. Carrier phosphorescent coating (4) containing paint (5) and pigment (6), It can be imparted with many phosphorescent pigments (6). Invention preferred The pigment (6) used in its application is strontium aluminate based and chemical Its formula is SrAlzO4zEu,Dy. The wave of light emitted into the environment as a result of excitations Its length is between 450-550 nm.

Bulusun konusu olan cam kap (1) bir cam eV esyasi olabilmektedir. The glass container (1) which is the subject of the invention can be a glassware.

Bulusun bir uygulamasinda cam kap (1) bir kadehtir. Kadehte bir hazne (2) bulunmaktadir. Kadehin haznesinin (2) dis yüzeyinin (3) bir kismina veya tamamina fosforesans kaplama (4) yapilabilmektedir. Üzerinde fosforesans kaplama (4) olan kadeh, bir isik kaynagi altinda üzerine düsen isigin enerjisini depolamakta ve isik kaynagi ortadan kalktiginda, pigmentin (6) yapisinda bulunan enerji seviyeleri arasinda meydana gelen elektron geçisleri ile depoladigi enerjiyi isima olarak serbest birakmakta bu sayede; karanlik ortamda isildayan bir ürün elde edilmektedir, Bulusun bir uygulamasinda cam kap (1) bir kâsedir. Kâsede bir hazne (2) bulunmaktadir. Kâsenin haznesinin (2) dis yüzeyinin (3) bir kismina veya tamamina fosforesans kaplama (4) yapilabilmektedir. Üzerinde fosforesans kaplama (4) olan kâse, bir isik kaynagi altinda üzerine düsen isigin enerjisini depolamakta ve isik kaynagi ortadan kalktiginda, pigmentin (6) yapisinda bulunan enerji seviyeleri arasinda meydana gelen elektron geçisleri ile depoladigi enerjiyi isima olarak serbest birakmakta; bu sayede karanlik ortamda isildayan bir ürün elde edilmektedir. In one embodiment of the invention, the glass container 1 is a goblet. A bowl (2) are available. on a part of the outer surface (3) of the bowl (2) or phosphorescence coating (4) can be made completely. Phosphorescence on The goblet with the coating (4) absorbs the energy of the light falling on it under a light source. it stores and when the light source disappears, the present in the structure of the pigment (6) the energy stored by electron transitions between energy levels. thereby releasing it as a name; obtain a product that glows in the dark. is being done, In one embodiment of the invention, the glass container 1 is a bowl. A bowl (2) in the bowl are available. part or all of the outer surface (3) of the bowl (2). phosphorescence coating (4) can be made. with phosphorescent coating (4) The bowl stores the energy of the light falling on it under a light source and when its source disappears, the energy levels in the structure of the pigment (6) as heat, the energy stored by the electron transitions between releasing; In this way, a product that glows in the dark environment is obtained. is being done.

Bulusun konusu olan cam kap (1) bir cam ambalaj ürünü olabilmektedir. The glass container (1), which is the subject of the invention, can be a glass packaging product.

Bulusun bir uygulamasinda cam kap (l ) bir sisedir. Bir sise olan cam ambalaj ürünü zeytinyagi, su, yüksek alkol, gazli içecek, gazsiz içecek, enerji içecegi, sarap vb. sivilarin ambalaji olarak kullanilabilmektedir. In one embodiment of the invention, the glass container (l) is a bottle. Glass packaging product with a bottle olive oil, water, high alcohol, carbonated beverage, non-carbonated beverage, energy drink, wine etc. It can be used as the packaging of liquids.

Bulus konusu cam kap (1) ile isik kaynaginin bulunmadigi bir ortamda, önceden belirli bir süre isik kaynaginda kalarak depoladigi enerjiyi isima olarak serbest birakmasi sayesinde ortama isilti veren ve karanlikta görünür hale gelen bir ürün elde edilmektedir. With the inventive glass container (1), in an environment where there is no light source, It releases the energy it has stored by staying in the light source for a certain period of time as heat. A product that gives a glow to the environment and becomes visible in the dark thanks to its release. is obtained.

Bir cam kabin (l) dis yüzeyine (3) karanlik bir ortamda renkli ve parlak bir ürün elde edilmesini saglayan, karanlikta isildayan cam kap üretim yöntemi (100), - dis yüzeyin (3) ön islem görmesi (101), - tasiyici boya (5)/pigment (6) oraninin fosforesans kaplamayi (4) olusturan tasiyici boya (5) ve fosforesans pigment (6) agirliklari yüzdesel olarak, tercihen pigment (6) oraninin, tasiyici boya (5) agirliginin %0-50°si (w/w) - tasiyici boyanin (5) hazirlanmasi (103), - boya karistirma kabinda fosforesans pigment (6) ilave edilmis tasiyici boyanin (5) bir karistirici ile dipten siyirilarak ve karistirma kabinin dibinden üstüne dogru devir daim yaptirilarak karistirilmasi ve kaplama karisiminin elde edilmesi (104), - kaplama karisiminin dis yüzeye (3) uygulanmasi (105), - fosforesans kaplamanin (4) kürlenmesi (106) - kontrol testlerinin yapilmasi (107) adimlarini içermektedir. A colored and bright product on the outer surface of a glass cabinet (l) (3) in a dark environment. Glow-in-the-dark glass container production method, which allows to obtain - pre-treatment of the outer surface (3) (101), - the ratio of carrier paint (5)/pigment (6) forming the phosphorescent coating (4) weights of carrier paint (5) and phosphorescent pigment (6) in percent, preferably 0-50° (w/w) of the pigment (6) rate, the weight of the carrier paint (5) - preparation of the carrier paint (5) (103), - carrier with added phosphorescent pigment (6) in the paint mixing cabinet by scraping the paint (5) from the bottom with a mixer and mixing and coating by circulating from bottom to top obtaining the mixture (104), - applying the coating mixture to the outer surface (3) (105), - curing of the phosphorescent coating (4) (106) - performing the control tests (107).

Yüzey üzerine yapilan kaplamanin, yüzeye tutunumunun artmasi ve daha dayanikli hale gelmesi için yüzey temizligi oldukça önemlidir. Bu nedenle, fosforesans kaplamanin (4) olusturulacagi dis yüzey (3) ön islem görmektedir (101). Dis yüzey (3), fiziksel veya kimyasal bir ön isleme tabii tutulabilmektedir. Increasing the adhesion of the coating on the surface to the surface and making it more durable. Surface cleanliness is very important. Therefore, the phosphorescence The outer surface (3) on which the coating (4) will be formed is pre-treated (101). Exterior surface (3) may be subjected to a physical or chemical pretreatment.

Dis yüzey (3) üzerinde elde edilmek istenen fosforesans kaplamanin (4) tercih edilen yapida olabilmesi için fosforesans kaplamayi (4) olusturan tasiyici boya (5) / fosforesans pigment (6) orani toplam karisim agirligina göre belirlenmektedir (102). Bu islem adiminda fosforesans kaplamayi (4) olusturan tasiyici boya (5) ve fosforesans pigment (6) agirliklari yüzdesel olarak belirlenmektedir. Bulusun bir uygulamasinda, pigmenti (6) orani, tasiyici boya (5) agirliginin %0-50”si (W/w) araligindadir. Örnegin, 100 gram tasiyici boya (5) için çerçevesinde elde edilen kaplama karisiminin agirligi 130 gramdir. The phosphorescence coating (4) desired to be obtained on the outer surface (3) the carrier forming the phosphorescent coating (4) so that it can be of the preferred structure. the ratio of dye (5) / phosphorescent pigment (6) according to the total weight of the mixture determined (102). In this process step, the phosphorescence coating (4) is formed. Carrier paint (5) and phosphorescent pigment (6) weights in percent is determined. In one embodiment of the invention, the ratio of pigment (6), carrier dye (5) It is in the range of 0-50% (W/w) of its weight. For example, for 100 grams of carrier paint (5) The weight of the coating mixture obtained in the frame is 130 grams.

Tasiyici boya (5) / pigment (6) orani belirlendikten sonra, pigmentin (6) içerisine eklenip karistirilacagi boya sistemi hazirlanmaktadir (103). Kullanilacak boya, tercih edilen uygulama çeside göre farkli bilesenler içerebilmektedir. Tasiyici boya (5), reçine, aktivatör ve sertlestirici gibi bilesenler ile katki maddelerini içerebilmektedir. Tasiyici boyanin (5) kullanima hazirlanmasinda (103), reçine ve reçineye ilave edilecek aktivatör veya sertlestirici vb. bilesenler ile katki maddeleri oransal olarak karistirilmaktadir. Fosforesans kaplamayi (4) olusturan bilesenlerden biri olan tasiyici boya (5), hem dis yüzey (3) üzerine tutunmayi saglamakta hem de içerisine karistirilan pigmentiri (6) dayanimini arttirmaktadir. After determining the ratio of carrier dye (5) / pigment (6), it is put into the pigment (6). The paint system to which it will be added and mixed is being prepared (103). paint to be used, it may contain different components depending on the preferred application type. carrier paint (5), additives and components such as resin, activator and hardener. may contain. In the preparation of the carrier paint (5) for use (103), resin and activator or hardener etc. to be added to the resin. ingredients and additives proportionally mixed. Of the components that make up the phosphorescent coating (4) Carrier paint (5), which is one of them, both ensures adhesion on the outer surface (3) and The pigment (6) mixed into it increases its strength.

Tasiyici boya (5) / fosforesans pigment (6) orani belirlendikten (102) ve tasiyici boya (5) hazirlandiktan (103) sonra fosforesans pigmentler (6) tasiyici boyaya (5) karistirilarak kaplama karisimi elde edilmektedir (104). Fosforesans özellikte olan pigmentlerin (6) yogunluklari, yapilacak uygulamaya göre tercih edilen tasiyici boyalara (5) göre oldukça yüksektir. Bu nedenle, Özellikle yogunlugu düsük sprey boya sistemlerinde fosforesans pigmentler (6) dibe çökme egilimindedirler. After determining the carrier dye (5) / phosphorescent pigment (6) ratio (102) and the carrier phosphorescent pigments (6) after the paint (5) has been prepared (103) to the carrier paint (5) coating mixture is obtained by mixing (104). phosphorescent The densities of the pigments (6) are the preferred carrier according to the application to be made. It is considerably higher than the dyes (5). Therefore, especially low density spray phosphorescent pigments (6) tend to settle to the bottom in paint systems.

Pigmentlerin (6) tasiyici boya (5) içerisinde dibe çökmelerini önlemek ve karisimin homojen yapisini devam ettirebilmesi için uygulama süresince karistirma islemi yapilmaktadir. Tasiyici boyaya (5) pigment (6) ilavesi yapildiktan sonra gerçeklestirilen karistirma islemi sürekli olup ayni anda iki farkli yöntem ile yapilmaktadir. Fosforesans pigment (6) ilave edilmis tasiyici boya (5) bir boya karistirma kabina alinir. Boya karistirma kabinda fosforesans pigment (6) ilave edilmis tasiyici boya (5) bir karistirici ile dipten siyirilarak karistirilirken; karisan boya ayni anda karistirma kabinin dibinden üstüne dogru devir daim yaptirilir. To prevent the pigments (6) from sinking in the carrier paint (5) and to prevent the mixture mixing process during the application in order to maintain its homogeneous structure. is being done. After adding pigment (6) to the carrier paint (5) The mixing process carried out is continuous and it is carried out simultaneously with two different methods. is being done. Carrier paint (5) with added phosphorescent pigment (6) is a paint the mixing cabinet is taken. Adding phosphorescent pigment (6) in the paint mixing cabinet while mixing the carrier paint (5) by scraping it from the bottom with an agitator; interfering the paint is circulated from the bottom of the mixing cabinet to the top at the same time.

Pigmentlerinin (6) tasiyici boyaya (5) karistirilmasi ve kaplama karisiminin elde edilmesi (104) tercihen oda sicakliginda, atmosfer basincinda gerçeklestirilmektedir. Karistirma islemi, kaplama islemi tamamlanana dek sürmektedir. Mixing the pigments (6) into the carrier paint (5) and obtaining the coating mixture (104) preferably at room temperature, atmospheric pressure is carried out. Mixing process until coating process is complete. in progress.

Kaplama karisimi elde edildikten sonra dis yüzeye (3) uygulanmaktadir (105). After the coating mixture is obtained, it is applied to the outer surface (3) (105).

Kaplama karisimi, tabanca robotu, elektrostatik disk veya elektrostatik çan kullanilarak çesitli sprey boyama teknikleri ile dis yüzeyin (3) tamamina veya bir kismina; desenli dekorlama yapilmasi tercih edildiginde ise serigrafik baski, tampon baski gibi teknikler ile dis yüzeye (3) uygulanabilmektedir. Coating mix, gun robot, electrostatic disc or electrostatic bell Using various spray painting techniques, the entire outer surface (3) or a partly; silkscreen printing, when patterned decoration is preferred, It can be applied to the outer surface (3) with techniques such as pad printing.

Kaplama karisimi dis yüzeye (3) uygulandiktan (105) sonra, fosforesans kaplamanin (4) dis yüzey (3) üzerinde kalici bir film tabakasi olusturmasi için fosforesans kaplamanin (4) kürlenme ( 106) islemi gerçeklestirilmektedir. After the coating mixture is applied to the outer surface (3) (105), the phosphorescence for the coating (4) to form a permanent film on the outer surface (3) The curing (106) process of the phosphorescent coating (4) is carried out.

Fosforesans kaplamanin (4) kürlenme ( 106) islemi, tercih edilen tasiyici boya (5) çesidine bagli olarak UV veya isil islem ile gerçeklesmektedir. .Fosforesans kaplamanin (4) kürlenme (106) adiminda; vernik olarak tabir edilen reçine sistemi, yapisinda bulunan fonksiyonel uçlarin UV ve/Veya isil islein ile aktif hale gelerek kimyasal bag yapmasi ile sertlesmekte ve dis yüzey (3) üzerinde kalici bir fosforesans kaplama (4) olusturmaktadir. Curing (106) of the phosphorescent coating (4), the preferred carrier paint (5) Depending on the type, it takes place with UV or heat treatment. .Phosphorescence in the curing (106) step of the coating (4); resin system called varnish, by activating the functional ends in its structure with UV and/or heat treatment. It hardens by chemical bonding and forms a permanent bond on the outer surface (3). phosphorescence coating (4).

Boyanin kürlenme islemi (106) tamamlandiktan sonra, elde edilen ürünün fosforesans özellige sahip olup olmadiginin belirlenmesi airiaci ile kontrol testleri yapilmaktadir (107). Dis yüzeyinde (3) fosforesans kaplama (4) bulunan cam kap (1) ilkin manuel olarak isiga tutulmaktadir. Isik kaynagina maruz birakilan cam kap (l) fosforesans etkinin açiga çikabilmesi için karanlik bir ortama alinmaktadir. After the curing process (106) of the paint is completed, the resulting product Determination of whether it has phosphorescence property control tests with pesticides being done (107). Glass container with phosphorescent coating (4) on outer surface (3) (1) is first manually irradiated. Glass container exposed to light source (l) It is taken into a dark environment so that the phosphorescence effect can be revealed.

Alternatif olarak; dis yüzeyinde (3) fosforesans kaplama (4) bulunan cam kap (1) siyah isik (black light) kaynagi altina alinarak, siyah isik kaynagi altinda isima yapip yapmadigi kontrol edilmektedir. Tercih edilen fosforesans etki elde edilirse cam kap (l) bulasik makinasi, çizilme ve kalem testlerine maruz birakilmaktadir.As an alternaive; glass vessel (1) with phosphorescent coating (4) on outer surface (3) by being placed under a black light source, it is heated under a black light source. It is checked whether it does or not. If the preferred phosphorescent effect is achieved The glass container (l) is subjected to dishwasher, scratch and pencil tests.

Claims (2)

ISTEMLER . Belirli bir süre isik kaynagina maruz kaldiktan sonra karanlik ortamda isildaina özelligine sahip, sivi veya kati maddenin dolduruldugu en az bir hazne (2), - cam kabin (1) kullaniciya bakan yüzü olan en az bir dis yüzey (3) içeren, - dis yüzeyin (3) tamamina veya bir kismina uygulanan, tasiyici boya (5) ve pigment (6) içeren, siyah isik altinda sürekli ve karanlik ortamda belirli bir süre isildama saglayan en az bir fosforesans kaplama (4), - içerisine pigment (6) karistirilarak, pigmentin (6) kaplamanin yapilacagi yüzeye tasinmasini saglayan en az bir tasiyici boya (5), - bir isik kaynagina maruz kaldiginda, atomlarinin veya moleküllerinin elektronlarinin uyarilarak bir üst enerji seviyelerine geçtigi, isik kaynagi ortadan kalktiginda ise isik enerjisini depolayan üst enerji seviyesindeki elektronlarin daha düsük enerjili alt seviyeye geçerken depoladiklari enerjilerini bir foton olarak yaymasi ile etrafa isilti yayan en bir az bir pigment (6) ile karakterize edilen bir cam kap (1) . Üzerine kaplama yapilan, kimyasal ve/veya fiziksel islem görmüs olan veya herhangi bir islem görmemis olan, düz veya girintili çikintili olan, renkli saydam veya yari saydam veya renksiz saydam veya opak olan dis yüzey (3) ile karakterize edilen istem ?deki gibi bir cam kap (1). . Opak beyaz veya beyaz kaplamaya sahip olan ve bu sayede üzerine uygulanan fosforesans kaplamanin (4) isima süresini ve isima siddetini arttiran dis yüzey (3) ile karakterize edilen istem 27deki gibi bir cam kap (l). . Dis yüzey (3) üzerinde bulunan, belirli bir süre isik kaynagina maruz kaldiktan sonra karanlik bir ortamda üzerinde bulundugu cismin ortama isilti yaymasini saglayan; etki siddeti, tasiyici boya (5) içerisine karistirilan pigmentin (6) tanecik boyutu ile dogru orantili olan; gün isigi altinda renksiz, buzlu ve mat bir görünüme sahip olup karanlik ortamda ise parlak ve renkli hale gelen fosforesans kaplama (4) ile karakterize edilen istem l°deki gibi bir cain kap Bir isik kaynagina maruz kaldiktan sonra karanlikta 0-2 saat süre ile isima özelligine sahip olan fosforesans kaplama (4) ile karakterize edilen istem 4'deki gibi bir cam kap (1) Siyah isik (black light) kaynagi altinda süresiz isildama özelligine sahip olan fosforesans kaplama (4) ile karakterize edilen istem 43deki gibi bir cam kap Içerisine pigmentlerin (6) karistirildigi, pigmentleri (6) tercih edilen yüzey üzerine tasiyan, cam ile uyumlu olan tasiyici boya (5) ile karakterize edilen istem 1`deki gibi bir cam kap (l) UV veya isil islem ile kürlenebilen reçine veya aktivatör içeren tasiyici boya (5) ile karakterize edilen istem 7°deki gibi cam kap (1), Tasiyici boya (5) içerisine karistirilan, belirli bir süre isik kaynagina maruz kaldiktan sonra karanlik ortamda isildama yapan, fosforesans özellikte pigment (6) ile karakterize edilen istem lideki gibi cam kap (1). Toz formda olan, parçacik boyutu 0- 100 mikron olan, optimize parçacik boyutuREQUESTS . At least one chamber (2) filled with liquid or solid material, which has the property of glowing in the dark after being exposed to a light source for a certain period of time, - the glass cabinet (1) containing at least one outer surface (3) with a user-facing side, - the outer surface (3) at least one phosphorescent coating (4), which is applied wholly or partially, containing carrier paint (5) and pigment (6), which provides luminescence continuously under black light and in a dark environment for a certain period of time, - by mixing the pigment (6) into it, at least one carrier paint (5) that enables the pigment (6) to be carried to the surface where the coating will be made, - when exposed to a light source, the electrons of its atoms or molecules are excited and transferred to higher energy levels, and when the light source disappears, the electrons at the higher energy level, which store the light energy, are lowered. a glass vessel (1) characterized by at least one pigment (6) that emits the stored energy as a photon when passing to the lower energetic level. A glass as in claim 3, characterized by an outer surface (3) that is coated, chemically and/or physically treated or not, smooth or recessed, colored transparent or translucent or colorless, transparent or opaque. container (1). . A glass container (1) as in Claim 27, characterized by the outer surface (3) having an opaque white or white coating and thus increasing the heating time and heating intensity of the phosphorescent coating (4) applied on it. . Located on the outer surface (3), which, after being exposed to a light source for a certain period of time, allows the object on which it is on to emit light in a dark environment; the intensity of the effect is directly proportional to the particle size of the pigment (6) mixed into the carrier paint (5); A ceramic pot as in claim 1, which is characterized by a phosphorescent coating (4) that has a colorless, frosted and matte appearance under daylight and becomes bright and colorful in the dark environment. After being exposed to a light source, it is heated for 0-2 hours in the dark A glass container (1) as in claim 4, characterized by a phosphorescent coating (4) that has the feature of A glass container (1) as in claim 1, characterized by a carrier paint (5) compatible with glass, in which pigments (6) are mixed, carrying the pigments (6) on the preferred surface, and a carrier containing resin or activator that can be cured by UV or heat treatment. Glass container (1) as in claim 7, characterized by paint (5), phosphorescent special paint mixed into the carrier paint (5), which glows in the dark after being exposed to a light source for a certain period of time. Glass container (1) as in claim li, characterized by a pigment (6) along with it. Optimized particle size in powder form, particle size 0-100 microns 2-40 mikron arasinda olan pigment (6) ile karakterize edilen istem 9”daki gibi olan pigment (6) ile karakterize edilen istem 9°daki gibi cam kap (1). Cam kabin (l) dis yüzeyine (3) karanlik bir ortamda veya siyah isik altinda fosforesans kaplama (4) ile renkli ve parlak bir ürün elde edilmesini saglayan, - dis yüzeyin (3) ön islem görmesi (101), - tasiyici boya (5)/pigment (6) oraninin fosforesans kaplainayi (4) olusturan tasiyici boya (5) ve fosforesans pigment (6) agirliklari yüzdesel olarak, tercihen pigment (6) oraninin, tasiyici boya (5) agirliginin %0-50*si (w/w) - tasiyici boyanin (5) hazirlanmasi (103), - boya karistirma kabinda fosforesans pigment (6) ilave edilmis tasiyici boyanin (5) bir karistirici ile dipten siyirilarak ve karistirma kabinin dibinden üstüne dogru devir daim yaptirilarak karistirilmasi ve kaplama karisiminin elde edilmesi (104), - kaplama karisiminin dis yüzeye (3) uygulanmasi (105), - fosforesans kaplamanin (4) kürlenmesi (106) ile karakterize edilen karanlikta isildayan cam kap üretim yöntemi (100). Tasiyici boyanin (5) hazirlanmasi (103) islem adiminda, reçine ve reçineye ilave edilecek aktivatör veya sertlestirici bilesenler ile katki maddelerinin oransal olarak karistirilarak fosforesans kaplamanin (4) matrisinin Olusturulmasi ile karakterize edilen istem l2ldeki gibi karanlikta isildayan cam kap üretim yöntemi (100). Pigmentlerin (6) tasiyici boyaya (5) karistirilinasi ve kaplama karisiminin elde edilmesi (104) islem adiminda, tercihen oda sicakliginda, atmosfer basincinda ve kaplama islemi tamamlanana dek süren karistirma islemi ile karakterize edilen istem 12`deki gibi karanlikta isildayan cam kap üretim yöntemi (100). Kaplama karisiminin dis yüzeye (3) uygulanmasi (105) islem adiminda, kaplama karisiminin tabanca robotu veya elektrostatik disk veya elektrostatik çan kullanilarak çesitli sprey boyama teknikleri ile dis yüzeyin (3) tamamina veya bir kismina; desenli dekorlama yapilmasi tercih edildiginde ise serigrafik baski, tampon baski gibi teknikler ile uygulanmasi ile karakterize edilen istem 12ideki gibi karanlikta isildayan cam kap üretim yöntemi (100). 16. Fosforesans kaplamanin (4) kürlenmesi (106) islem adiminda, reçine sistemi yapisinda bulunan fonksiyonel uçlarin UV ve/Veya isil islem ile aktif hale gelerek kimyasal bag yapmasi ile sertlesmesi ve dis yüzey (3) üzerinde kalici bir fosforesans kaplama (4) olusturmasi ile karakterize edilen istem 12”deki gibi karanlikta isildayan cam kap üretim yöntemi (100).Glass container (1) as in claim 9, characterized by the pigment (6) as in claim 9, characterized by pigment (6) between 2-40 microns. - Pre-treatment of the outer surface (3) (101), - Carrier paint (5 )/pigment (6) ratio of the carrier paint (5) and phosphorescent pigment (6) forming the phosphorescent coating (4) as percent, preferably 0-50% of the weight of the carrier paint (5), of the pigment (6) ratio (w/ w) - preparation of the carrier paint (5) (103), - mixing the carrier paint (5) with added phosphorescent pigment (6) in the paint mixing cabinet by scraping it from the bottom with a mixer and circulating it from the bottom of the mixing cabinet to the top and obtaining the coating mixture ( 104), - the application of the coating mixture to the outer surface (3) (105), - the curing (106) of the phosphorescent coating (4), the production method of a glow-in-the-dark glass vessel (100). Glass container production method (100) that glows in the dark as in claim 12, characterized by the formation of the matrix of the phosphorescent coating (4) by mixing the additives with the resin and the activator or hardening components to be added to the resin in the process step (103) of preparing the carrier paint (5). Glow-in-the-dark glass container production method, as in claim 12, characterized by mixing the pigments (6) with the carrier paint (5) and obtaining the coating mixture (104) in the process step, preferably at room temperature, at atmospheric pressure, and by the mixing process that continues until the coating process is completed ( one hundred). In the process step of applying the coating mixture to the outer surface (3) (105), the coating mixture is completely or partially applied to the outer surface (3) with various spray painting techniques using a gun robot or an electrostatic disc or an electrostatic bell; when patterned decoration is preferred, it is a glass container production method (100) that glows in the dark as in claim 12, which is characterized by the application of techniques such as screen printing and pad printing. 16. In the curing (106) process step of the phosphorescent coating (4), the functional ends of the resin system are activated by UV and/or heat treatment and harden by chemical bonding and a permanent phosphorescent coating (4) is formed on the outer surface (3). Glass container production method that glows in the dark as in claim 12, characterized by (100).
TR2016/11238A 2016-08-10 2016-08-10 GLAZING GLASS CONTAINER AND PRODUCTION METHOD IN THE DARK TR201611238A2 (en)

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FR3056327B1 (en) * 2016-09-20 2020-11-06 Stoelzle Masnieres Parfumerie ARTICLE COVERED AT LEAST PARTIALLY BY AT LEAST ONE LUMINESCENT COATING

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