SU728687A3 - Weeds fighting method - Google Patents
Weeds fighting method Download PDFInfo
- Publication number
- SU728687A3 SU728687A3 SU731921921A SU1921921A SU728687A3 SU 728687 A3 SU728687 A3 SU 728687A3 SU 731921921 A SU731921921 A SU 731921921A SU 1921921 A SU1921921 A SU 1921921A SU 728687 A3 SU728687 A3 SU 728687A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- triazin
- reacting
- phenyl
- compound
- ethyl ester
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract description 5
- 241000196324 Embryophyta Species 0.000 title description 7
- 230000002363 herbicidal effect Effects 0.000 abstract description 7
- 150000001875 compounds Chemical class 0.000 abstract description 6
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 abstract 2
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 abstract 2
- BFNNILAMSKQDRN-UHFFFAOYSA-N 2h-1,2,4-triazin-5-one Chemical class O=C1C=NNC=N1 BFNNILAMSKQDRN-UHFFFAOYSA-N 0.000 abstract 1
- MYRZHMIBRIKWDO-UHFFFAOYSA-N 4h-triazin-5-one Chemical compound O=C1CN=NN=C1 MYRZHMIBRIKWDO-UHFFFAOYSA-N 0.000 abstract 1
- OFLXLNCGODUUOT-UHFFFAOYSA-N acetohydrazide Chemical compound C\C(O)=N\N OFLXLNCGODUUOT-UHFFFAOYSA-N 0.000 abstract 1
- LZVLIYQNBYTEFN-UHFFFAOYSA-N ethyl 2-(1-chloroethylidenehydrazinylidene)-2-phenylacetate Chemical compound C1(=CC=CC=C1)C(=NN=C(C)Cl)C(=O)OCC LZVLIYQNBYTEFN-UHFFFAOYSA-N 0.000 abstract 1
- QKLCQKPAECHXCQ-UHFFFAOYSA-N ethyl phenylglyoxylate Chemical compound CCOC(=O)C(=O)C1=CC=CC=C1 QKLCQKPAECHXCQ-UHFFFAOYSA-N 0.000 abstract 1
- VHCNQEUWZYOAEV-UHFFFAOYSA-N metamitron Chemical compound O=C1N(N)C(C)=NN=C1C1=CC=CC=C1 VHCNQEUWZYOAEV-UHFFFAOYSA-N 0.000 abstract 1
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 description 6
- -1 3-methoxy-4-methyl-5H-6-phenyl-1, 2,4-triazin-5-one Chemical compound 0.000 description 4
- 235000016068 Berberis vulgaris Nutrition 0.000 description 2
- 241000335053 Beta vulgaris Species 0.000 description 2
- 229940126062 Compound A Drugs 0.000 description 2
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- MVAQKCBXFGRWER-UHFFFAOYSA-N 6-phenyl-2h-1,2,4-triazin-5-one Chemical class O=C1N=CNN=C1C1=CC=CC=C1 MVAQKCBXFGRWER-UHFFFAOYSA-N 0.000 description 1
- 231100000674 Phytotoxicity Toxicity 0.000 description 1
- 240000006394 Sorghum bicolor Species 0.000 description 1
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 1
- 244000274883 Urtica dioica Species 0.000 description 1
- 235000009108 Urtica dioica Nutrition 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 230000009528 severe injury Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/72—Hydrazones
- C07C251/88—Hydrazones having also the other nitrogen atom doubly-bound to a carbon atom, e.g. azines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/72—Hydrazones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D253/00—Heterocyclic compounds containing six-membered rings having three nitrogen atoms as the only ring hetero atoms, not provided for by group C07D251/00
- C07D253/02—Heterocyclic compounds containing six-membered rings having three nitrogen atoms as the only ring hetero atoms, not provided for by group C07D251/00 not condensed with other rings
- C07D253/06—1,2,4-Triazines
- C07D253/065—1,2,4-Triazines having three double bonds between ring members or between ring members and non-ring members
- C07D253/07—1,2,4-Triazines having three double bonds between ring members or between ring members and non-ring members with hetero atoms, or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Description
Изобретение относитс к химическим средствам борьбы с нежелательной растительностью, а именно к способам борьбы с сорной растительностью путем обработки ее или ее биотопа гер- бицидом на основе производных 3-метил-4-амино-5Н-6-фенил-1 ,2,4-триазин-5-она . Известны способы борьбы с сорной растительностью путем обработки посе ВОВ гербицидом на основе 3-метилтио-4-метил-5Н-6-фенил-1 ,2,4-триаэин-5-она 1 . или З-метокси-4-метил-5Н-6-фенил-1 ,2,4-триазин-5-она 2. Наиболее близким к предлагаемому действующим веществом гербицида, которым ведут обработку посевов, вл етс 3-метилтио-4-амино-5Н-6-фенил-1 ,2,4-триазин-5-он 13. Однако известные гербициды на основе производных 6-фенил-1,2,4-триазин-5-она про вл ют фитотоксичность к возделываемым культурам и в силу низкой избирательности действи не могут быть использованы в посевах свеклы. Целью изобретени вл етс повышение эффективности способа борьбы с сорной растительностью путем изыскани гербицидного средства путем обр -3-5где тил пол ств на или хар ве мул аботки ее или ее биотопа 6-фенилметил-4-амино-5Н-1 ,2,4-триазиноном общей формулы I . X - водород, метил, трифтормев количестве 0,0001 - 10%. Предлагаемые соединени могут быть учены известным способом посредом взаимодействи ацетилгидразис сС-кетокарбоновой кислотой с ее сложным эфиром. В табл.1 дана физико-химическа актеристика примен емых в качестгербицида соединений обшей форы I. Таблица 1The invention relates to chemical means of controlling undesirable vegetation, and in particular to methods of controlling weeds by treating her or her biotope with a herbicide based on 3-methyl-4-amino-5H-6-phenyl-1, 2,4- triazin-5-she. There are known methods for controlling weeds by treating a BOB plant with a herbicide based on 3-methylthio-4-methyl-5H-6-phenyl-1, 2,4-triaine-5-one 1. or 3-methoxy-4-methyl-5H-6-phenyl-1, 2,4-triazin-5-one 2. Closest to that proposed by the active ingredient of the herbicide, which is treated crops, is 3-methylthio-4-amino -5H-6-phenyl-1, 2,4-triazin-5-one 13. However, known herbicides based on 6-phenyl-1,2,4-triazin-5-one derivatives exhibit phytotoxicity to cultivated crops and in because of the low selectivity of the action can not be used in crops of beets. The aim of the invention is to increase the efficiency of the method of weed control by searching for a herbicidal agent by means of -3-5 where the field has been harvested or harvested by her or her biotope 6-phenylmethyl-4-amino-5H-1, 2,4- triazinone General formula I. X - hydrogen, methyl, trifluorine in amounts of 0.0001 - 10%. The proposed compounds can be studied in a known manner by reacting acetyl hydrazis with a C-ketocarboxylic acid with its ester. Table 1 gives the physicochemical actuality of the common ground form I compounds used as a quality herbicide. Table 1
Соединение А (известно)s 3-метилтио-4-амино-5Н-б-фенил-1 ,2,4-триазин-5-он ,° соединение В (известно); {3 метоксикарбониламинофенил)-N- (3-метилфенил )-карбамат .Compound A (known) s 3-methylthio-4-amino-5H-b-phenyl-1, 2,4-triazin-5-one, ° compound B (known); {3 methoxycarbonylaminophenyl) -N- (3-methylphenyl) carbamate.
Пример 1„ Довсходова обработка .Example 1: Dovskhodovaya processing.
Семена свеклы, галинсоги, poMaiii;KH звездчатки, крапивы, м тлика высевали в почву, которую, спуст 1 сут, обрабатывали в дозе 2,5-5 кг/га иThe seeds of beet, galinsog, poMaiii; KH of sprocket, nettle, and m tlyka were sown in the soil, which, after 1 day, was treated at a dose of 2.5-5 kg / ha and
Довсходова обработкаPre-emergence treatment
спуст 3 над.проводили учет гербицидной активности по п тибалльной шкале О - нет повреждений; 1 -замечание роста растений; 2 - заметные повреждени ; 3 - сильные повреждени и только 50% всходов; 4 - только 25% всходов; 5 - полна гибель растенийlater, 3 nad.were accounting of the herbicidal activity on a scale of 0 on a scale of 0 — no damage; 1 - notice plant growth; 2 - noticeable damage; 3 - severe damage and only 50% of shoots; 4 - only 25% of shoots; 5 - full of death of plants
Результаты исшлтаний представлены в табл.2.The results of the results are presented in table 2.
Эталон - соединение А.Reference - compound A.
Т а б л и ц а T a b l and c a
Пример 2. Послевсходова обработка. Растени Ьвсюга, стовника, щетинника , м тлика, сорго, горца и Ецирицы высотой 5-15 см обрабатывали в дозеExample 2. Post-harvest processing. Plants of Bwsyuga, Stovnik, Bristles, Glyce, Sorghum, Highlander, and Eziritsa 5–15 cm high were treated in a dose
Послевсходова обработкаPost-harvest processing
Таблица 1,2,4 кг/га соединением 1,2,3 и эталоном - соединением В. Спуст 3 нед. проводили учет гербицидной активности .по п тибалльной Шкале. j Результаты испытаний представлены в табл.3,.Table 1,2,4 kg / ha with compound 1,2,3 and standard - compound B. After 3 weeks. an account of herbicidal activity was carried out. On a scale. j The test results are presented in table 3 ,.
Claims (3)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2224161A DE2224161A1 (en) | 1972-05-18 | 1972-05-18 | SELECTIVE HERBICIDAL AGENTS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU728687A3 true SU728687A3 (en) | 1980-04-15 |
Family
ID=5845170
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU731921921A SU728687A3 (en) | 1972-05-18 | 1973-05-16 | Weeds fighting method |
Country Status (19)
| Country | Link |
|---|---|
| JP (1) | JPS5626644B2 (en) |
| AT (2) | AT327607B (en) |
| BE (1) | BE799584A (en) |
| CH (1) | CH581951A5 (en) |
| CS (1) | CS174882B2 (en) |
| DD (1) | DD104019A5 (en) |
| DE (1) | DE2224161A1 (en) |
| ES (1) | ES414824A1 (en) |
| FR (1) | FR2185034B1 (en) |
| GB (1) | GB1368416A (en) |
| HU (1) | HU166183B (en) |
| IE (1) | IE37643B1 (en) |
| IL (1) | IL42271A (en) |
| IT (1) | IT987656B (en) |
| NL (1) | NL177461C (en) |
| PL (1) | PL89244B1 (en) |
| SU (1) | SU728687A3 (en) |
| TR (1) | TR17273A (en) |
| YU (1) | YU39297B (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2346936C2 (en) * | 1973-09-18 | 1982-05-06 | Bayer Ag, 5090 Leverkusen | Process for the preparation of new 3,4-dihydro-1,2,4-triazines and three compounds of this type and their use |
| DE2537290A1 (en) * | 1975-08-21 | 1977-03-03 | Bayer Ag | Means for selective weed control in turnips |
| FR2482421B1 (en) * | 1980-05-19 | 1985-08-02 | Slovenska Akademia Vied | AGENT FOR INCREASING THE HARVEST OF AGRICULTURAL PRODUCTS |
| DE3102318A1 (en) | 1981-01-24 | 1982-08-26 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING 3,6-DISUBSTITUTED 4-AMINO-1,2,4-TRIAZINE-5-ONES |
| DE3206234A1 (en) * | 1982-02-20 | 1983-09-29 | Bayer Ag, 5090 Leverkusen | SELECTIVE BEET HERBICIDE CONTAINING METAMITRON IN COMBINATION WITH A NAPHTHOCHINONE DERIVATIVE |
| JPS6076640U (en) * | 1983-10-31 | 1985-05-29 | 中央パツケージング工業株式会社 | laundry storage bag |
| JPS60120908U (en) * | 1984-01-26 | 1985-08-15 | 株式会社 サンアイ | Hanging tool for bag adsorption |
| EP0549531A1 (en) * | 1991-12-20 | 1993-06-30 | Säurefabrik Schweizerhall | Process for preparing acid anhydrides |
| DE4313093C2 (en) * | 1993-04-22 | 1996-01-11 | Stefes Pflanzenschutz Gmbh | Suspension concentrates containing metamitron based on water as the only carrier |
| DE4329974A1 (en) | 1993-09-04 | 1995-03-09 | Stefes Pflanzenschutz Gmbh | Aqueous herbicidal suspension concentrates |
| DE19605786A1 (en) | 1996-02-16 | 1997-08-21 | Hoechst Schering Agrevo Gmbh | Oil suspension concentrates |
| DE10143084A1 (en) | 2001-09-03 | 2003-03-20 | Bayer Cropscience Ag | Fruit thinning process |
| EP2052610A1 (en) | 2007-10-24 | 2009-04-29 | Bayer CropScience AG | Herbicide combination |
| DE102008037630A1 (en) | 2008-08-14 | 2010-02-18 | Bayer Cropscience Ag | Herbicidal combination, useful to control undesired plant growth in plant culture e.g. wheat, comprises dimethoxytriazinyl-substituted difluoromethanesulfonyl anilide compounds and herbicides comprising triazine compounds e.g. ametryn |
| EP2238834A1 (en) * | 2009-04-07 | 2010-10-13 | Bayer CropScience Aktiengesellschaft | Defoliant based on thidiazuron and 1,2,4-triazinones |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2107757C3 (en) * | 1971-02-18 | 1980-02-28 | Bayer Ag, 5090 Leverkusen | 4-Amino-1,2,4-triazin-5-ones, process for their preparation and their use as herbicides |
| BE786840A (en) * | 1971-07-29 | 1973-01-29 | Bayer Ag | PROCESS FOR PREPARING 1,2,4-TRIAZINE -5-ONES |
-
1972
- 1972-05-18 DE DE2224161A patent/DE2224161A1/en active Pending
-
1973
- 1973-05-09 DD DD170729A patent/DD104019A5/xx unknown
- 1973-05-15 TR TR17273A patent/TR17273A/en unknown
- 1973-05-15 IL IL42271A patent/IL42271A/en unknown
- 1973-05-15 YU YU1283/75A patent/YU39297B/en unknown
- 1973-05-16 SU SU731921921A patent/SU728687A3/en active
- 1973-05-16 IT IT24202/73A patent/IT987656B/en active
- 1973-05-16 CH CH700473A patent/CH581951A5/xx not_active IP Right Cessation
- 1973-05-16 BE BE131153A patent/BE799584A/en not_active IP Right Cessation
- 1973-05-17 ES ES414824A patent/ES414824A1/en not_active Expired
- 1973-05-17 IE IE788/73A patent/IE37643B1/en unknown
- 1973-05-17 GB GB2355273A patent/GB1368416A/en not_active Expired
- 1973-05-17 CS CS3539A patent/CS174882B2/cs unknown
- 1973-05-17 PL PL1973162625A patent/PL89244B1/pl unknown
- 1973-05-18 NL NLAANVRAGE7307004,A patent/NL177461C/en not_active IP Right Cessation
- 1973-05-18 AT AT820174*7A patent/AT327607B/en not_active IP Right Cessation
- 1973-05-18 AT AT438673A patent/AT325341B/en not_active IP Right Cessation
- 1973-05-18 HU HUBA2929A patent/HU166183B/hu unknown
- 1973-05-18 JP JP5481173A patent/JPS5626644B2/ja not_active Expired
- 1973-05-18 FR FR7318105A patent/FR2185034B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IT987656B (en) | 1975-03-20 |
| IL42271A0 (en) | 1973-07-30 |
| TR17273A (en) | 1975-03-24 |
| FR2185034A1 (en) | 1973-12-28 |
| JPS4954537A (en) | 1974-05-27 |
| CH581951A5 (en) | 1976-11-30 |
| PL89244B1 (en) | 1976-11-30 |
| FR2185034B1 (en) | 1977-02-11 |
| ES414824A1 (en) | 1976-02-01 |
| YU39297B (en) | 1984-10-31 |
| AT327607B (en) | 1976-02-10 |
| CS174882B2 (en) | 1977-04-29 |
| DE2224161A1 (en) | 1973-11-29 |
| NL177461B (en) | 1985-05-01 |
| JPS5626644B2 (en) | 1981-06-19 |
| HU166183B (en) | 1975-02-28 |
| IE37643B1 (en) | 1977-09-14 |
| YU128373A (en) | 1982-05-31 |
| ATA820174A (en) | 1975-04-15 |
| GB1368416A (en) | 1974-09-25 |
| BE799584A (en) | 1973-11-16 |
| DD104019A5 (en) | 1974-02-20 |
| NL7307004A (en) | 1973-11-20 |
| AT325341B (en) | 1975-10-10 |
| NL177461C (en) | 1985-10-01 |
| IL42271A (en) | 1976-10-31 |
| IE37643L (en) | 1973-11-18 |
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