SU692825A1 - Method of preparing cresols - Google Patents
Method of preparing cresolsInfo
- Publication number
- SU692825A1 SU692825A1 SU782623969A SU2623969A SU692825A1 SU 692825 A1 SU692825 A1 SU 692825A1 SU 782623969 A SU782623969 A SU 782623969A SU 2623969 A SU2623969 A SU 2623969A SU 692825 A1 SU692825 A1 SU 692825A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- cresols
- yield
- phenol
- selectivity
- preparing
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 13
- 150000001896 cresols Chemical class 0.000 title claims description 11
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 8
- YUWFEBAXEOLKSG-UHFFFAOYSA-N hexamethylbenzene Chemical compound CC1=C(C)C(C)=C(C)C(C)=C1C YUWFEBAXEOLKSG-UHFFFAOYSA-N 0.000 claims description 5
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 235000009499 Vanilla fragrans Nutrition 0.000 claims 1
- 244000263375 Vanilla tahitensis Species 0.000 claims 1
- 235000012036 Vanilla tahitensis Nutrition 0.000 claims 1
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 230000029936 alkylation Effects 0.000 description 2
- 238000005804 alkylation reaction Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000005199 trimethylbenzenes Chemical class 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
(54) СПОСОБ ПОЛУЧЕНИЯ КРЕЗОЛОВ(54) METHOD FOR OBTAINING CRESOLS
II
Изобретение относитс к основному органическому синтезу, а именно к способам получени крезолов.This invention relates to a basic organic synthesis, in particular to methods for producing cresols.
Известен способ получени крезолов путем алкилировани фенола триметилбензолами при 200-500°С в присутствии алюмосиликатного катализатора 1}. Процесс ведут при мольном соотношении фенол: триметилбензол 1-2:1, выход крезолов 31%, селективность по фенолу 50%, по триметилбензолу 57%.A known method for producing cresols by alkylation of phenol with trimethylbenzenes at 200-500 ° C in the presence of an aluminosilicate catalyst 1}. The process is carried out at a molar ratio of phenol: trimethylbenzene of 1-2: 1, the yield of cresols is 31%, the selectivity for phenol is 50%, for trimethylbenzene is 57%.
Однако дл этого способа характерны недостаточно высокий выход крезолов и низка селективность процесса.However, this method is characterized by an insufficiently high yield of cresols and a low selectivity of the process.
Целью изобретени йвл етс повышение выхода целевых продуктов и селективности процесса .The aim of the invention is to increase the yield of target products and the selectivity of the process.
Поставленна цель достигаетс способом получени крезолов путем алкилировани фенола гексаметилбензолом при 400-425 С в присутствии алюмосиликатного катализатора и при мольном отношении фенол :гексаметилбензол 3-10:1.This goal is achieved by the method of obtaining cresols by alkylation of phenol with hexamethylbenzene at 400-425 ° C in the presence of an aluminosilicate catalyst and at a molar ratio of phenol: hexamethylbenzene of 3-10: 1.
Предлагаемый способ позвол ет повысить выход крезолов до 48-84% и селективность доThe proposed method allows to increase the yield of cresols to 48-84% and selectivity to
.90%. . ,.90%. . ,
П р и м е р. Во вращающийс автоклав объемом 250 см загружают 5,18 г смеси фенола и гексаметилбензола в мол рном соотно-шении 5,25:1 и 1,13 г (22,5 вес.%) промышленного шарикового алюмосиликата (фракци 1,6-2,5 мм), подают водород до давлени 7ат и реакционную смесь нагревают до 400-425 С (максимальное Давление в автоклаве 29 аТ(). Реакцию ведут в течение 1ч, после чего реакционную смесь охлаждают, снижают давление в автоклаве До атмосферного и отфильтровывают катализатор. Выход катализата 5,06 г ,(97,6%), выход крезолов 78,3%, селективность по фенолу 80,8%, по гексаметилбензолу 90,3%.PRI me R. A rotary autoclave with a volume of 250 cm was charged with 5.18 g of a mixture of phenol and hexamethylbenzene in a molar ratio of 5.25: 1 and 1.13 g (22.5 wt.%) Of industrial ball silica-alumina (fraction 1.6-2, 5 mm), hydrogen is supplied to a pressure of 7 at and the reaction mixture is heated to 400-425 ° C (the maximum pressure in the autoclave is 29 atT (). The reaction is carried out for 1 h, after which the reaction mixture is cooled, the pressure is reduced in the autoclave) The catalyst is filtered off. The yield of catalyzate 5.06 g, (97.6%), the yield of cresols is 78.3%, the selectivity for phenol is 80.8%, and for hexamethyl benzene is 90.3%.
В таблице приведены выход крезолов, конверси реагентов и селективность процесса, проведенного а аналогичных услови х.The table shows the yield of cresols, the conversion of the reagents and the selectivity of the process carried out under similar conditions.
692825692825
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.-1 Ч.-1 H
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Ю1Л1ЛЮU1L1LYU
Tf rt Tf rt
r- -r- -
5692825656928256
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU782623969A SU692825A1 (en) | 1978-06-02 | 1978-06-02 | Method of preparing cresols |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU782623969A SU692825A1 (en) | 1978-06-02 | 1978-06-02 | Method of preparing cresols |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU692825A1 true SU692825A1 (en) | 1979-10-25 |
Family
ID=20768174
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU782623969A SU692825A1 (en) | 1978-06-02 | 1978-06-02 | Method of preparing cresols |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU692825A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4532368A (en) * | 1984-02-01 | 1985-07-30 | Ethyl Corporation | Process for making meta- and para-alkylphenols |
| US4927979A (en) * | 1987-12-18 | 1990-05-22 | Maruzen Petrochemical Co., Ltd. | Process for the preparation of p-ethylphenol |
-
1978
- 1978-06-02 SU SU782623969A patent/SU692825A1/en active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4532368A (en) * | 1984-02-01 | 1985-07-30 | Ethyl Corporation | Process for making meta- and para-alkylphenols |
| US4927979A (en) * | 1987-12-18 | 1990-05-22 | Maruzen Petrochemical Co., Ltd. | Process for the preparation of p-ethylphenol |
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