SU630225A1 - Method of purifying aqueous solution of sodium sulfate from metal ions and organic admixtures - Google Patents
Method of purifying aqueous solution of sodium sulfate from metal ions and organic admixturesInfo
- Publication number
- SU630225A1 SU630225A1 SU742045056A SU2045056A SU630225A1 SU 630225 A1 SU630225 A1 SU 630225A1 SU 742045056 A SU742045056 A SU 742045056A SU 2045056 A SU2045056 A SU 2045056A SU 630225 A1 SU630225 A1 SU 630225A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- aqueous solution
- metal ions
- sodium sulfate
- purifying aqueous
- organic admixtures
- Prior art date
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 101150114464 ATRN gene Proteins 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 241001455617 Sula Species 0.000 description 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 1
- 241000256856 Vespidae Species 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 244000144980 herd Species 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000009856 non-ferrous metallurgy Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Removal Of Specific Substances (AREA)
Description
33
к о н ц бМт р а ц и с у л ь ф а т аto about nts bmt r and c and s u lf f a t a
«атрн , г:л1 Ь"Atrn, g: l1 b
КОИцеИТ-раци железа, г/,10,02KOITsIT-iron of iron, g /, 10.02
чонцеитрацл марганца. г-.;0.02 Концентраци органическихmanganese chonzeitrazl. Mr. - .0.02 Concentration of organic
сосди-нений, г/л2sundry, g / l2
Начальное значение рН5Initial pH5
подают насосем (0,5 л:ч} в лологрезател;,, где темнературу воды ноднилипот до 250 С. Вода с темнературон 250° С лроходнг через смеситс,ль, куда нодают воздух в количестве 25 лч. Врем пребыва.ни газожидксстiiofi смеси i автоклаве 1 ч. Жидкость :-:е 1рерЫ (В:Но вывод т из автоклава через дросселирующее устройство и теллообмеки ;. з рсзерзуар-сгустите.ть. ВОЗДУХ вывод т через дроеселирую цее устройство з атмосф еру . Далее зоду фильтруют.they are pumped (0.5 l: h} to a lolo-cutter ;, where the temperature of the water is up to 250 ° C. Water with the temperature of 250 ° C is distributed through the mixture, or where the air is supplied in the amount of 25 hl. The residence time and gas-liquid mixture i autoclave 1 hour. Liquid: -: e 1Repy (B: But withdrawn from the autoclave through a throttling device and body smear; z rzzerzuar-thicken. AIR is output through the air dowel circuit device from the atmosphere. Then the zod is filtered.
После фильтрации вода имеет следую1Ц ло характеристик}:After filtration, the water has the following characteristics:
Концепт-ради сулы)атConcept for sula) at
и а три , г/л158 Содержатше железа Отс тстлуегand a three, g / l 158 Contains iron Ots tstlueg
Содержание марга нца. г .:О.ООС.. Концентраци органическихThe content of marga natz. G.: O.O.S .. Concentration of organic
соединений, г/лIcompounds g / l
Конечное значение рН6Final pH6
Концентраци су.тьфатаConcentration of succinate
натри , г/лsodium, g / l
Концентраци железа, г/л Концентраци марганца, гл Конце1гпраци органическихIron concentration, g / l Concentration of manganese, hl Concentration of organic
нри.месей, г/л З начеиие рНNom.mesey, g / l 3 Nacheee rn
иодают иасосом в иодогреватель, где темиературу воды иодним.ают до . Под воздействием температуры в ирисутстзин растворимого кислорода основна часть лтета ,ллов пере.ходит з окислы. Воду зывОлТ, гIodine and pump into the iodine heater, where the temoturture of water is iodim. Under the influence of temperature, soluble oxygen irisststzin forms the main part of the summer, but it transfers from oxides. Cold water, g
4four
:; i нодогреватс.т ;: ох,1:жлают епед гюдачеи ,; .|5-с:устител:,.:; i nodogrevats.t;: oh, 1: they want to eat this,; . | 5-s: tired:,.
llcc/ie фильтрации те: л С-о5работа:-На зода ИМеет следующую характеристику:llcc / ie filtering those: l C-o5work: -On the zod IMEet the following characteristics:
К С: i це н тр ац и с ,i ь ф а т аK C: i cce n tr a c u s i i f a t а
натри , г л5Ssodium, g l5S
Содержание же.теза, г/л0,002Content same.tez, g / l0,002
Содержа«1 е маргаи-ца. г/л0,С02 Кондентраци опганичс::-;ихContaining "1 e margai-tsa. g / l0, C02 Concentration opganichs :: -;
соединений, гл1.7compounds, ch1.7
Значен 1е рН8Value 1e pH8
Сток;, нрошедш ;е термообработку, ис: ользуюте дл выделени сульфата каТрИЯ .Stoke; not hot; e heat treated, use: Use to give off KATRIUM sulphate.
Способ осуществлен i-:a опытной установке производительностью 40 л1ч. Очищагма зода тгр а ктичеоки не содержит ионов металлов, возраетает скорость фильтрации, у 1рощаетс технологи очистки зоды за счет сокращени числа стадий.The method is implemented i-: a pilot plant with a capacity of 40 l1h. The purification system of the zodiac does not contain metal ions, the filtration rate is restored, and the cleaning technology of the zod is reduced by reducing the number of stages.
Фор М у л а и 3 о б р е т е н н Vor M u l a and 3 o b e te n n
1.Снособ очисткп водного раствора сульф:1та натри от ИОНОЗ метал.тов и орга ничес: нх тгримесе, включающий HciVioa.:i;3au;; O :; фНльтраиию раствора, о т л и ч а ю щ и iс тем. что. с целью упрощени ироцессз С)ч;;ст1 и путем 1:с: лючс; ;:;: стад;:;: -тстаиван; и , перед ф гльтрацне : ;гСт:ю1 .гюдзе а К) т I е:} м о с:) б р а б о т к е.1. The method of purification of an aqueous solution of sulfon: 1 t sodium from IONOS metal.t and organic: nx term, including HciVioa.:ii3au ;; O:; fnltraiyu solution, about tl and h a y i and i with those. what. in order to simplify the processes C) h ;; st1 and by 1: s: luchs; ;::: herd;:;: -staivan; and, in front of the footer,: gSt: S1. Gyudze and K) t I e:} m o s :) b a b o to k.
2.C:ioco6 но ::. 1. от л и ч а ю Hi и и с 1ем, что термообработку ос и;ест1;;-т::о: гпи температуре 170-250° С.2.C: ioco6 but ::. 1. from Hi and Hi and and with 1, that the heat treatment of wasps and; est1 ;; - t :: o: gpi temperature 170-250 ° C.
Источники инфор.маЦИ ;, :прин тые во п:1имание при экспертизе:Sources informatsi;;: accepted in p: 1 name for examination:
1.Масл ницкий 11. Н. Авток.ла зньге процессы в цветной металлургии. М., 1969, с. 78-85.1. Oil Nikitsky 11. N. Avtok.la znge processes in non-ferrous metallurgy. M., 1969, p. 78-85.
2.Солодовников В. В. и др. Обеззрежиза1;ие сульфатных сточ.кых в-эд ироиз:юдства СЖК. М., «ЦНП ТЭНе:ЬтеХИМ, 1970, с. 40.2. Solodovnikov, V.V., et al. Decontamina1; no sulphate wastewater sources: the waters of SLC. M., “TSNP TENe: Laborer, 1970, p. 40
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU742045056A SU630225A1 (en) | 1974-07-17 | 1974-07-17 | Method of purifying aqueous solution of sodium sulfate from metal ions and organic admixtures |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU742045056A SU630225A1 (en) | 1974-07-17 | 1974-07-17 | Method of purifying aqueous solution of sodium sulfate from metal ions and organic admixtures |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU630225A1 true SU630225A1 (en) | 1978-10-30 |
Family
ID=20591329
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU742045056A SU630225A1 (en) | 1974-07-17 | 1974-07-17 | Method of purifying aqueous solution of sodium sulfate from metal ions and organic admixtures |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU630225A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012065731A1 (en) * | 2010-11-16 | 2012-05-24 | Remondis Assets & Services Gmbh & Co. Kg | Method for recovering potassium sulphate from biodiesel production |
| CN110759570A (en) * | 2019-10-31 | 2020-02-07 | 广东闻扬环境科技有限公司 | Treatment method and treatment system for dye intermediate wastewater |
-
1974
- 1974-07-17 SU SU742045056A patent/SU630225A1/en active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012065731A1 (en) * | 2010-11-16 | 2012-05-24 | Remondis Assets & Services Gmbh & Co. Kg | Method for recovering potassium sulphate from biodiesel production |
| US8968689B2 (en) | 2010-11-16 | 2015-03-03 | Remondis Production Gmbh | Method for recovering potassium sulphate from biodiesel production |
| CN110759570A (en) * | 2019-10-31 | 2020-02-07 | 广东闻扬环境科技有限公司 | Treatment method and treatment system for dye intermediate wastewater |
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