SU538005A1 - The method of surface treatment products - Google Patents
The method of surface treatment productsInfo
- Publication number
- SU538005A1 SU538005A1 SU2054169A SU2054169A SU538005A1 SU 538005 A1 SU538005 A1 SU 538005A1 SU 2054169 A SU2054169 A SU 2054169A SU 2054169 A SU2054169 A SU 2054169A SU 538005 A1 SU538005 A1 SU 538005A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- solutions
- surface treatment
- metal salts
- products
- treatment products
- Prior art date
Links
- 238000000034 method Methods 0.000 title description 5
- 238000004381 surface treatment Methods 0.000 title description 4
- 239000000243 solution Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 2
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 230000002542 deteriorative effect Effects 0.000 claims 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims 1
- 235000021419 vinegar Nutrition 0.000 claims 1
- 239000000052 vinegar Substances 0.000 claims 1
- 229920003023 plastic Polymers 0.000 description 8
- 239000004033 plastic Substances 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- SVMCDCBHSKARBQ-UHFFFAOYSA-N acetic acid;cobalt Chemical compound [Co].CC(O)=O SVMCDCBHSKARBQ-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910000462 iron(III) oxide hydroxide Inorganic materials 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- WVULZDFWPQCPPJ-UHFFFAOYSA-N potassium;hydrochloride Chemical compound Cl.[K] WVULZDFWPQCPPJ-UHFFFAOYSA-N 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Treatments Of Macromolecular Shaped Articles (AREA)
Description
1one
Изобретение относитс к технологии обработки поверхности пластмассовых изделий ДЛЯ получени окрашенной поверхности и придани поверхности пластмассовых изделий необходимых оптических свойств.The invention relates to the technology of surface treatment of plastic products for obtaining a painted surface and imparting optical properties to the surface of plastic products.
Известен способ обработки поверхности изделий из акрипонитрилбутадиенстирольных пластиков (АБС), включающий обработку поверхности концентрированной серной кислотой и обработку водными растворами солей металлов, например хлористым палладием и затем хлористым никелем, при температуре 20-800С в течение 0,5-10 мин 1.There is a method of surface treatment of products from acryponitrile butadiene styrene plastics (ABS), including surface treatment with concentrated sulfuric acid and treatment with aqueous solutions of metal salts, such as palladium chloride and then nickel chloride, at a temperature of 20-800С for 0.5-10 min 1.
По известному способу на поверхности пластмассового издели образуетс слойметалпа . Однако вещества, примен емые при металлизации, не могут использоватьс дл окрашивани пластмасс.By a known method, a metal layer is formed on the surface of the plastic product. However, the substances used in the metallization cannot be used for painting plastics.
Цель изобретени состоит в получении поверхностно-окрашенных изделий без ухудшени их физико-механических и химических свойств. Поставленна цепь достигаетс тем что поверхность издели из АБС-пластика, фенопластов или аминопластов обрабатывают парами водных растворов солей металлов, The purpose of the invention is to obtain surface-colored products without compromising their physico-mechanical and chemical properties. The delivered chain is achieved by the fact that the surface of an ABS plastic product, phenolic plastics or amino plastics is treated with vapors of aqueous solutions of metal salts,
выбранных из групп, содержащих медь сернокислую и калий железистосинеродистый, свинец уксуснокислый и натрий углекислый, железо хлорное и калий железистосинеродистый , свинец уксуснокислый и калий двухромовокислый , кобальт уксуснокислый и калий марганцевокислый, железо хлорное и аммоний роданистый, никель хлористый и натрий сернистый.selected from the groups containing copper sulphate and potassium zhelezistosinerodisty, lead acetic acid and optics optics, oxycarbonate oxygene, iron chloric and potassium zhelezystoynosynodisty, lead acetic acid and potassium dichromate, cobalt acetic acid and potassium permanganate, ferric acid, potassium hydrochloride and potassium acetate
Интенсивность окраски определ етс толщиной модифицированного сло , а также концентрацией реагирующих растворов и температурно-временными режимами обработки пластмасс в этих растворах. Получение необходимого цвета достигают выбором соответствующих неорганических веществ, при взаимодействии которых образуютс пигменты .The color intensity is determined by the thickness of the modified layer, as well as by the concentration of the reactive solutions and the temperature-time regimes of processing plastics in these solutions. Obtaining the desired color is achieved by selecting the appropriate inorganic substances, the interaction of which produces pigments.
Пример. Производ т поверхностное окрашивание изделий из АБО-пластика. Химическое модифицирование поверхности осуществл ют способом сульфировани путем обработки в концентрированной серной кисло34Example. Surface coloring of products made of ABO-plastic. Chemical surface modification is carried out by the method of sulfonation by treatment in concentrated sulfuric acid.
те {уд. вес 1,84) при температуре 70°См обработки в каждом из указанных раств течение 1-2 мин. После промывки водойворов 5 мин при комнатной температуре,those {beats. weight 1.84) at a temperature of 70 ° C. Processing in each of these solutions for 1-2 minutes. After washing with water for 5 minutes at room temperature,
издели обрабатывают последовательно вСоставы растворов и данные об окранщварастворе N° 1, промывают водой и послеаии поверхности изделий приведены в табthe products are processed sequentially in the composition of the solutions and data on the octane solution N ° 1, washed with water and after the surface of the products are given in the table
этого обрабатывают в растворе № 2. Вре-5 иде.this process in solution number 2. Time-5 ide.
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Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU2054169A SU538005A1 (en) | 1974-08-20 | 1974-08-20 | The method of surface treatment products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU2054169A SU538005A1 (en) | 1974-08-20 | 1974-08-20 | The method of surface treatment products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU538005A1 true SU538005A1 (en) | 1976-12-05 |
Family
ID=20594272
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU2054169A SU538005A1 (en) | 1974-08-20 | 1974-08-20 | The method of surface treatment products |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU538005A1 (en) |
-
1974
- 1974-08-20 SU SU2054169A patent/SU538005A1/en active
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