SU496237A1 - The method of purification of zinc sulphate solutions from chlorine - Google Patents
The method of purification of zinc sulphate solutions from chlorineInfo
- Publication number
- SU496237A1 SU496237A1 SU2015391A SU2015391A SU496237A1 SU 496237 A1 SU496237 A1 SU 496237A1 SU 2015391 A SU2015391 A SU 2015391A SU 2015391 A SU2015391 A SU 2015391A SU 496237 A1 SU496237 A1 SU 496237A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- purification
- chlorine
- zinc sulphate
- sulphate solutions
- zinc
- Prior art date
Links
- 229910052801 chlorine Inorganic materials 0.000 title claims description 5
- 239000000460 chlorine Substances 0.000 title claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 title claims description 4
- 238000000746 purification Methods 0.000 title claims 3
- 235000009529 zinc sulphate Nutrition 0.000 title description 2
- 239000011686 zinc sulphate Substances 0.000 title description 2
- 239000000243 solution Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Extraction Or Liquid Replacement (AREA)
Description
(54) СПОСОБ ОЧИСТКИ СУЛЬФАТНЫХ ОТ ХЛОРА ЦИНКОВЫХ РАСТВОРОВ(54) METHOD FOR CLEANING SULPHATE ZINC SOLUTIONS WITH CHLORINE
кой 1-2 н.Гводныкга,растворами бисульфата шелочного металла или аммони , серной кислоты или стехиометрической смеси серной кислоты и сульфата шелочного металла или аммони .Coke 1-2 N. Gvodnykga, solutions of the silk sulfate metal or ammonium, sulfuric acid or a stoichiometric mixture of sulfuric acid and silk sulfate metal or ammonium.
Пример 1. Промышленный раствор слабокислого выщелачивани вельиокислов и шлаковоэгонов, содержащий (в г/л) цинка 125 ,5, меди - 3,94; талли - 0,О04, сурьмы 0,14; мышь ка - 0,83; инди 0 ,008; свлГниа - 0,051; хлора - 1,18; фтора -0,15, при рН 1,2 и соотношении объемов фаз , обрабатывают 0,15 М раствором сульфата триалкилбензиламмони Example 1. An industrial solution of the weakly acid leaching of velichlorides and slag carpets containing (in g / l) zinc 125, 5, copper - 3.94; tally - 0, O04, antimony 0.14; mouse ka - 0.83; indie 0, 008; svlGnia - 0.051; chlorine - 1.18; fluorine -0.15, at a pH of 1.2 and the ratio of the volumes of the phases, is treated with a 0.15 M solution of trialkylbenzylammonium sulfate
е три-нЦ бутнпфосфате. Врем встр хивани 5 .мин. .Состав рафввата (в г/л): цинк 125,5; медь-3,94; таллий О,ОО4; сурьма 0,14; мь1шь к 0,93; индий О,ОО8; свинец О,О51; хлор 0,025 ; фтор 0,01. .e three-NC butnphosphate. Shake time 5 .min. . Composition of rafvvat (in g / l): zinc 125.5; copper-3.94; thallium O, OO4; antimony 0.14; mish1 to 0.93; indium o, OO8; lead Oh, O51; chlorine 0.025; fluorine 0.01. .
В остальных примерах услови проведени экстракции идентичны описанным в примере 1,In the other examples, the extraction conditions are identical to those described in example 1,
Пример 2, Экстракци хлоридионов 0,15 М растворами сульфата триапкилбензиламмони в три-н бутилфосфате из сульфатных цинковых растворов, содер жаших 75 г/л цинка за один контакт. Результаты опыта представлены в табл, 1.Example 2, Chloridion Extraction with 0.15 M solutions of tripkylbenzylammonium sulphate in tri-n-butyl phosphate from zinc sulphate solutions containing 75 g / l of zinc per contact. The results of the experiment are presented in table. 1.
Концентраци хлорид-ионов, г/лChloride ion concentration, g / l
П р и М е р 3. Экстракци фториЯ-,; ионов О,15 М раствором сульфата триалкилбензиламмони в три-н-бутилфосфатеPRI me R 3. Extraction of fluoride; O ions, 15 M solution of trialkylbenzylammonium sulfate in tri-n-butyl phosphate
Пример 4. Раствор хлорида триалкилбензиламмони в смеси 7О% керосина и ЗО% октацола, содержаший 7,668 г/л хлорид-ионов, последовательно встр хиваютExample 4 A solution of trialkylbenzylammonium chloride in a mixture of 7O% kerosene and ZO% octacola, containing 7.668 g / l of chloride ions, is subsequently shaken
ТаблицаTable
при концентрации цинка ЮО г/л. Результаты опыта представлены в табл. 2.when the concentration of zinc SO is g / l. The results of the experiment are presented in table. 2
Т а б л и ц а 2Table 2
с водным раствором бисульфата натри в течение 5 мин. Соотношение объемов фаз О:В 1:1. Содержание хлорид-конов в вод-; ной и органической фазах представлено з табл. 3.with an aqueous solution of sodium bisulfate for 5 minutes. The ratio of the volume of the phase of O: 1: 1. The content of chloride-horses in water; Noah and organic phases are presented in Table. 3
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU2015391A SU496237A1 (en) | 1974-04-18 | 1974-04-18 | The method of purification of zinc sulphate solutions from chlorine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU2015391A SU496237A1 (en) | 1974-04-18 | 1974-04-18 | The method of purification of zinc sulphate solutions from chlorine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU496237A1 true SU496237A1 (en) | 1975-12-25 |
Family
ID=20581764
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU2015391A SU496237A1 (en) | 1974-04-18 | 1974-04-18 | The method of purification of zinc sulphate solutions from chlorine |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU496237A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4156711A (en) * | 1975-06-19 | 1979-05-29 | Societe Des Mines Et Fonderies De Zinc De La Vieille Montagne, S.A. | Process for the removal of impurities contained in a zinc and cadmium sulfate solution |
| FR2593829A1 (en) * | 1985-10-02 | 1987-08-07 | Nat Tank Co | PROCESS FOR SELECTIVELY EXTRACTING ZINC FROM AQUEOUS SALMON |
| US7037482B2 (en) | 2003-03-10 | 2006-05-02 | Teck Cominco Metals Ltd. | Solvent extraction of a halide from a aqueous sulphate solution |
-
1974
- 1974-04-18 SU SU2015391A patent/SU496237A1/en active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4156711A (en) * | 1975-06-19 | 1979-05-29 | Societe Des Mines Et Fonderies De Zinc De La Vieille Montagne, S.A. | Process for the removal of impurities contained in a zinc and cadmium sulfate solution |
| FR2593829A1 (en) * | 1985-10-02 | 1987-08-07 | Nat Tank Co | PROCESS FOR SELECTIVELY EXTRACTING ZINC FROM AQUEOUS SALMON |
| US7037482B2 (en) | 2003-03-10 | 2006-05-02 | Teck Cominco Metals Ltd. | Solvent extraction of a halide from a aqueous sulphate solution |
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