SU1521799A1 - Composition for shock washing of cellulose-containing fabric - Google Patents
Composition for shock washing of cellulose-containing fabric Download PDFInfo
- Publication number
- SU1521799A1 SU1521799A1 SU884371854A SU4371854A SU1521799A1 SU 1521799 A1 SU1521799 A1 SU 1521799A1 SU 884371854 A SU884371854 A SU 884371854A SU 4371854 A SU4371854 A SU 4371854A SU 1521799 A1 SU1521799 A1 SU 1521799A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- mixture
- fraction
- sodium
- composition
- cellulose
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 229920002678 cellulose Polymers 0.000 title claims abstract description 7
- 239000001913 cellulose Substances 0.000 title claims abstract description 7
- 230000035939 shock Effects 0.000 title claims 2
- 239000004744 fabric Substances 0.000 title abstract description 6
- 238000005406 washing Methods 0.000 title 1
- -1 polyoxyethylene Polymers 0.000 claims abstract description 12
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims abstract description 10
- 150000003138 primary alcohols Chemical class 0.000 claims abstract description 7
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 7
- 239000011734 sodium Substances 0.000 claims abstract description 7
- 238000007046 ethoxylation reaction Methods 0.000 claims abstract description 5
- 235000010265 sodium sulphite Nutrition 0.000 claims abstract description 5
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 5
- 239000012670 alkaline solution Substances 0.000 claims abstract description 3
- 238000009835 boiling Methods 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims abstract description 3
- 210000000540 fraction c Anatomy 0.000 claims description 7
- 150000002170 ethers Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims 1
- 239000001488 sodium phosphate Substances 0.000 claims 1
- 229910000162 sodium phosphate Inorganic materials 0.000 claims 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract description 3
- 238000012993 chemical processing Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 239000004753 textile Substances 0.000 abstract description 2
- 150000002334 glycols Chemical class 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical class OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Изобретение относитс к технологии химической обработки текстильных материалов, а именно к композици м дл щелочной обработки целлюлозосодержащих тканей. Изобретение обеспечивает повышение стабильности композиции в щелочных растворах, интенсификацию процесса отварки и повышение капилл рности целлюлозосодержащей ткани за счет того, что композици содержит 15-30 мас.% смеси полиоксиэтиленгликолевых эфиров синтетических первичных спиртов фракции С12-С14 со степенью оксиэтилировани 8-10The invention relates to the technology of chemical processing of textile materials, in particular, compositions for the alkaline treatment of cellulose-containing fabrics. The invention provides an increase in the stability of the composition in alkaline solutions, an intensification of the process of boiling and an increase in the capillary nature of the cellulose-containing tissue due to the fact that the composition contains 15-30 wt.% Mixture of polyoxyethylene glycol esters of synthetic primary alcohols of the C 12 -C 14 fraction with a degree of ethoxylation of 8-10
5-10 мас.% триполифосфата натри 5-10 wt.% Sodium tripolyphosphate
6-12 мас.% сульфита натри и до 100 мас.% смеси алкилбензолсульфонатов натри фракции С10-С12. 2 табл.6-12% by weight sodium sulfite and up to 100% by weight mixture of sodium alkyl benzene sulfonates of the C 10 -C 12 fraction. 2 tab.
Description
Изобретение относитс к технологии химической обработки текстильных материалов, а именно к составам дл щелочной обработки целлюлозосо- держащих тканей.The invention relates to the technology of chemical processing of textile materials, namely, compositions for the alkaline treatment of cellulose-containing fabrics.
Цель изобретени - повышение стабильности композиции в щелочных растворах, интенсификации процесса отварки и повьщзени капилл рности целлюлозосодержащей ткани.The purpose of the invention is to increase the stability of the composition in alkaline solutions, to intensify the process of boiling and increase the capillary nature of cellulose-containing tissue.
Пример 1 (сравнительный). Вещество сульфосид-31 готов т смешиванием 50 мас.% смеси алкилбензол- сульфонатов натри фракции и 50 мас.% смеси полиоксиэтиленгликолевых эфиров амидов синтетических жирных кислот фракции С,- С, со степенью оксиэтилировани 5-6 в при-- сутствии антивспенивател . .Example 1 (comparative). Sulfosid-31 is prepared by mixing 50% by weight of a mixture of sodium alkylbenzenesulfonates fraction and 50% by weight of a mixture of polyoxyethyleneglycol ethers of synthetic fatty acid amides of fraction C, -C, with an oxyethylation degree 5-6 in the presence of antifoam. .
Хлопчатобумажную ткань (б зь) пропитывают при 20-25 с водным раствором гидроокиси натри (180 г/л), содержащими 1 г/л вещества сульфосид-31 , отжимают до 80% влажности, запаривают 10 мин при 140°С, промывают гор чей и холодной водой, обрабатывают раствором серной- кислоты 5 г/л, промьшают, сушат.Cotton fabric (bz) is impregnated at 20-25 with an aqueous solution of sodium hydroxide (180 g / l), containing 1 g / l of sulfoside-31 substance, pressed to 80% humidity, steamed for 10 minutes at 140 ° C, washed hot and with cold water, treated with a solution of sulfuric acid 5 g / l, rinsed, dried.
Пример 2. В трехгорлую колбу емкостью 200 мл, снабженную термометром и мешалкой, загружают 57 г смеси алкилбензолсульфонатов натри фракции С,р- С,. Д° 45-50 С в течение 20 мин. При перемешивании постепенно добавл ют 25 г смеси полиоксиэтиленгликолевых эфиров синтетических первичных спиртов фракции С,- . со степенью оксиэтилировани 8 и продолжают перемешивать в течение 30 мин, после чего последовательно внос т 8 г триполифосфа- та натри , 10 г сульфита натри . Полученную массу перемешивают в течение 60 мин при 45-50°С. Полученна композици по внешнему виду представл ет собой пастообразную массу светло-желтого цвета, хорошо раство- :римую в воде, концентраци водород- 1НЫХ ионов (рН) 1%-ного водного раствора 7-8, поверхностное нат жение водного раствора в концентрации З г/л - 35 10- Н/м.Example 2. In a three-neck flask with a capacity of 200 ml, equipped with a thermometer and a stirrer, 57 g of a mixture of sodium alkylbenzenesulfonate fraction C, p-C, is charged. D ° 45-50 C for 20 minutes. Under stirring, 25 g of a mixture of polyoxyethylene glycol ethers of synthetic primary alcohols of fraction C, - are gradually added. with a degree of ethoxylation of 8 and continue to mix for 30 minutes, after which 8 g of sodium tripolyphosphate and 10 g of sodium sulfite are successively introduced. The resulting mass is stirred for 60 minutes at 45-50 ° C. The resulting composition in appearance is a pasty mass of light yellow color, well soluble in water, the concentration of hydrogen ions (pH) of a 1% aqueous solution is 7-8, the surface tension of an aqueous solution in a concentration of 3 g / l - 35 10-N / m.
Полученный препарат имеет следующий состав, мас.%;The resulting preparation has the following composition, wt.%;
Смесь полиоксиэтилен- гликолевьк эфиров синтетических первичных спиртов фракции С со степенью оксиэтили- ровани 825A mixture of polyoxyethylene glycol ether esters of synthetic primary alcohols fraction C with a degree of ethoxylation 825
Триполифосфат натри 8 Сульфат натри 10Sodium tripolyphosphate 8 sodium sulfate 10
Смесь алкилбензол- сульфонатов натри фракции С,о- .57 Услови обработки ткани провод т по примеру 1.A mixture of sodium alkyl benzene sulphonates of fraction C, o - .57 The conditions for treating the fabric are as in Example 1.
Примеры 3-11. Услови получени композиции аналогичны примеру 2. Обработку ткани провод т как в примере 1.Examples 3-11. The conditions for the preparation of the composition are the same as in Example 2. The fabric is treated as in Example 1.
00
5five
Состав компонентов приведен в табл. 1, а свойства представлены в табл. 2.IThe composition of the components is given in table. 1, and the properties are presented in table. 2.I
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU884371854A SU1521799A1 (en) | 1988-01-26 | 1988-01-26 | Composition for shock washing of cellulose-containing fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU884371854A SU1521799A1 (en) | 1988-01-26 | 1988-01-26 | Composition for shock washing of cellulose-containing fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1521799A1 true SU1521799A1 (en) | 1989-11-15 |
Family
ID=21352980
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU884371854A SU1521799A1 (en) | 1988-01-26 | 1988-01-26 | Composition for shock washing of cellulose-containing fabric |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU1521799A1 (en) |
-
1988
- 1988-01-26 SU SU884371854A patent/SU1521799A1/en active
Non-Patent Citations (1)
| Title |
|---|
| Авторское свидетельство GCCP № 713891, кл. С 08 L 83/04, 1977. Текстильно-вспомогательные вещества: Технические услови 6-14-487-79. Черкассы, 1980, с. 139-141. * |
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