SU1351983A1 - Method of oil-poison-protective finishing of textile cotton materials - Google Patents
Method of oil-poison-protective finishing of textile cotton materials Download PDFInfo
- Publication number
- SU1351983A1 SU1351983A1 SU853961626A SU3961626A SU1351983A1 SU 1351983 A1 SU1351983 A1 SU 1351983A1 SU 853961626 A SU853961626 A SU 853961626A SU 3961626 A SU3961626 A SU 3961626A SU 1351983 A1 SU1351983 A1 SU 1351983A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- oil
- poison
- cotton materials
- textile
- textile cotton
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims abstract description 8
- 239000004753 textile Substances 0.000 title claims abstract description 8
- 229920000742 Cotton Polymers 0.000 title claims description 7
- 238000000034 method Methods 0.000 title description 3
- 239000006185 dispersion Substances 0.000 claims abstract description 9
- 229920001577 copolymer Polymers 0.000 claims abstract description 8
- 230000001681 protective effect Effects 0.000 claims abstract description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000011575 calcium Substances 0.000 claims abstract 2
- 229910052731 fluorine Inorganic materials 0.000 claims abstract 2
- 239000011737 fluorine Substances 0.000 claims abstract 2
- 238000003825 pressing Methods 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- 150000002688 maleic acid derivatives Chemical class 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- 238000009417 prefabrication Methods 0.000 abstract 1
- 229920001187 thermosetting polymer Polymers 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 10
- 239000000575 pesticide Substances 0.000 description 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 230000003712 anti-aging effect Effects 0.000 description 1
- HDRTWMBOUSPQON-ODZAUARKSA-L calcium;(z)-but-2-enedioate Chemical compound [Ca+2].[O-]C(=O)\C=C/C([O-])=O HDRTWMBOUSPQON-ODZAUARKSA-L 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Изобретение относитс к текстильному производству, а именно к маслооттапкивающей и дозащитной отделке текстильных материалов, используемых дл изготовлени спецодежды дл работников сельского хоз йства, и позвол ет повысить эффективность дозащитных свойств целлкшозосодержа- щих текстильных материалов пропиткой их водной дисперсией сополимера фтор- содержащего эфира и кальциевой соли малеиновой кислоты общей формулы - сн-сн,„- сн-сн m 0 т 11 OCH2.(CF2)5CF5 0 0 Са где п 3937, m 659, при концентрации дисперсии 30-50 г/л с последующим отжимом, сушкой и термофиксацией. (Л оо елThe invention relates to textile production, namely, oil removal and prefabrication finishing of textile materials used for the manufacture of overalls for agricultural workers, and improves the effectiveness of the protective properties of cellulose-containing textile materials by impregnating them with an aqueous dispersion of fluorine-containing ether and calcium salt copolymer. maleic acid of the general formula - LH, L - LH m 0 t 11 OCH2. (CF2) 5CF5 0 0 Ca where n 3937, m 659, at a dispersion concentration of 30-50 g / l, followed by pressing, s shkoy and thermoset. (L oo ate
Description
Изобретение относитс к текстильному отделочному производству, а именно к масло- и доотталкивающей отделке текстильных материалов, ис- пользуемых дл изготовлени спецодежды дл работников сельского хоз йства .The invention relates to textile finishing, in particular, oil and anti-aging finishing of textile materials used for the manufacture of working clothes for agricultural workers.
Цель изобретени - повьгашние до- защитных свойств текстильных матери- алев.The purpose of the invention is to reduce the protective properties of textile materials.
Пример 1. Хлопчатобумажную ткань (артикул 3165) пропитывают на двухвальной плюсовке водной дисперсией сополимера 1,l -дигидроперфторгеп- тилакрилата и кальциевой соли малеи- новой кислоты общей формулыExample 1. Cotton fabric (article 3165) is impregnated on a two-shaft padding with an aqueous dispersion of copolymer of 1, l-dihydroperfluorpeptylacrylate and maleic acid calcium salt of the general formula
CH-CH,(fH,,,CH-CH, (fH ,,,
- -
ОСН(СР)5СРз о.DOS (CP) 5SRz about.
.0.0
саsa
где пwhere n
mm
3937 6593937 659
Состав сополимера., 7,The composition of the copolymer., 7,
-Te-Q i-Te-Q i
teop teop
СаSa
теорtheor
29,8 1,205 57,3 1,56 29.8 1,205 57,3 1,56
най| найА nay | naiA
Hutl((,Hutl ((,
СаSa
чоидchoid
29,8 1,23 57,5 1,629.8 1.23 57.5 1.6
Доказана структура методом ИК- пектроскопии,Proved structure by IR pectroscopy,
.2.2
сwith
0-Са-(|) -С -С0-Sa- (|) -C-C
. OCHi( Н И. OCHi (HI
1760 см - полоса поглощени во фрагменте1760 cm - absorption band in the fragment
1870 см - полоса поглощени фрагменте1870 cm - absorption band fragment
-снч-snch
ОСН2(СР2ЪСГзOCH2 (SR2GSGz
сwith
с оwith about
сwith
оabout
СаSa
Далее данную хлопчатобумажную ткань, пропитанную водной дисперсиейNext, this cotton fabric soaked in water dispersion
5 five
00
5five
00
5five
сополимера ГЛ-СЛ-hfK с концентрацией 30 г/л, отжимают со степенью 80-85%, высушивают при 100 С и подвергаютa copolymer of GL-SL-hfK with a concentration of 30 g / l, wring out with a degree of 80-85%, dried at 100 ° C and subjected to
лl
термообработке при 160-170 С в течение 40-45 с.heat treatment at 160-170 C for 40-45 s.
П р и м е р 2. Хлопчатобумажную ткань (арт. 3165) пропитывают как в примере 1 водной дисперсией сополимера ГА-Са МК с концентрацией 40 г/л, отжимают, высушивают и термофиксиру- ют.PRI mme R 2. Cotton fabric (art. 3165) is impregnated as in Example 1 with a water dispersion of a GA-Ca MK copolymer with a concentration of 40 g / l, squeezed, dried and heat-set.
ПримерЗ. Хлопчатобумажную ткань (арт. 3165) пропитывают как в примере 1 водной дисперсией сополимера ГА-Са МК с концентрацией 50 г/л, отжимают, высушивают и термофиксиру- ют.Example Cotton fabric (item no. 3165) is impregnated as in example 1 with a water dispersion of a copolymer of GA-Ca MK with a concentration of 50 g / l, pressed, dried and heat-fixed.
п р и м е р 4 (сравнительный по известному способу).PRI me R 4 (comparative by a known method).
Хлопчатобумажную ткань (арт.3165) пропитывают как в примерах 1-3 водной дисперсией латекса ГФ с концентрацией 50 г/л, сушат и фиксируют.Cotton fabric (art. 3165) is impregnated as in Examples 1-3 with a water dispersion of GF latex with a concentration of 50 g / l, dried and fixed.
Данные, характеризующие масло- и доотталкивающие свойства обработанной ткани представлены в табл. 1.The data characterizing the oil and anti-repellency properties of the treated fabric are presented in table. one.
Ядоудал емость в-процессе дес ти стирок определ ют следующим образом.The toxicity in the process of ten washes is determined as follows.
На образец ткани микрошприцем нанос т 500 мкг препарата карбофоса. После 4 ч выдержки образцы заливают гор чим раствором мьша и соды и сти-: рают по ГОСТ 12.4049-78. Образцы после стирки и двух промывок сушат. Оставшийс на ткани пестицид экстрагируют гексаном и определ ют количество его в экстракте с применением хроматографа Цвет-106.500 µg of the drug of karbofos was applied to a tissue sample with a microsyringe. After 4 hours of exposure, the samples are poured with a hot solution of soda and soda and stored: according to GOST 12.4049-78. Samples after washing and two washes are dried. The pesticide remaining on the fabric is extracted with hexane and its amount in the extract is determined using a Tsvet-106 chromatograph.
С (1 , C (1,
-(- (
5five
где а - количество пестицида на ткани после стирки; количество пестицида, наносимого на образец; количество пестицида на ни в предыдущем цикле,where a is the amount of pesticide on the fabric after washing; the amount of pesticide applied to the sample; the amount of pesticide on the previous cycle,
а„ ткаa „tka
Показатели доудал емости приведены в табл. 2.Dose rates are given in table. 2
Обработка текстильного материала предложенным сополимером позвол ет получить ткань, котора сорбирует токсичных веществ (пестицидов) в 2- 3 раза меньше, чем ткани, обработанные известным составом. Данные представлены в табл. 3.The treatment of a textile material with the proposed copolymer makes it possible to obtain a fabric that absorbs toxic substances (pesticides) 2 to 3 times less than fabrics treated with a known composition. The data presented in Table. 3
-(fH-CH,- CH-CH- (fH-CH, - CH-CH
OCH2(CF)5CF3 00OCH2 (CF) 5CF3 00
1351983 1351983
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU853961626A SU1351983A1 (en) | 1985-09-11 | 1985-09-11 | Method of oil-poison-protective finishing of textile cotton materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU853961626A SU1351983A1 (en) | 1985-09-11 | 1985-09-11 | Method of oil-poison-protective finishing of textile cotton materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1351983A1 true SU1351983A1 (en) | 1987-11-15 |
Family
ID=21200150
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU853961626A SU1351983A1 (en) | 1985-09-11 | 1985-09-11 | Method of oil-poison-protective finishing of textile cotton materials |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU1351983A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6544594B2 (en) * | 1999-09-10 | 2003-04-08 | Nano-Tex, Llc | Water-repellent and soil-resistant finish for textiles |
-
1985
- 1985-09-11 SU SU853961626A patent/SU1351983A1/en active
Non-Patent Citations (1)
| Title |
|---|
| Киркина Л.И. и др. Производственные испытани фторорганических препаратов. - Текстильна промьшшен- ность, 1974, № 5, с .58,ав. Авторское свидетельство СССР № 804648, кл. С 08 F 220/24, 1982. Козлова С.Е. и др. Отделка хлопчатобумажных тканей дл одежды рабочих сельского хоз йства. - Текстильна промышленность, № 4, 1983. * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6544594B2 (en) * | 1999-09-10 | 2003-04-08 | Nano-Tex, Llc | Water-repellent and soil-resistant finish for textiles |
| US6855772B2 (en) | 1999-09-10 | 2005-02-15 | Nano-Tex, Llc | Water-repellent and soil-resistant finish for textiles |
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