SU105759A1 - Method for determining minimum copper sulfate consumption to activate zinc blende - Google Patents
Method for determining minimum copper sulfate consumption to activate zinc blendeInfo
- Publication number
- SU105759A1 SU105759A1 SU454491A SU454491A SU105759A1 SU 105759 A1 SU105759 A1 SU 105759A1 SU 454491 A SU454491 A SU 454491A SU 454491 A SU454491 A SU 454491A SU 105759 A1 SU105759 A1 SU 105759A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- copper sulfate
- zinc blende
- consumption
- zinc
- determining minimum
- Prior art date
Links
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 title description 14
- 229910000365 copper sulfate Inorganic materials 0.000 title description 8
- WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical compound [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 title description 5
- 229910052984 zinc sulfide Inorganic materials 0.000 title description 5
- 238000000034 method Methods 0.000 title description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 9
- 229910052725 zinc Inorganic materials 0.000 description 9
- 239000011701 zinc Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000005188 flotation Methods 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 101100160997 Mus musculus Rchy1 gene Proteins 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 235000005811 Viola adunca Nutrition 0.000 description 1
- 235000013487 Viola odorata Nutrition 0.000 description 1
- 240000009038 Viola odorata Species 0.000 description 1
- 235000002254 Viola papilionacea Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- ZURAKLKIKYCUJU-UHFFFAOYSA-N copper;azane Chemical compound N.[Cu+2] ZURAKLKIKYCUJU-UHFFFAOYSA-N 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 235000013522 vodka Nutrition 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
Landscapes
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
Description
Определение расхода медного купороса , примен емого дл активацин цинковой обнанкн, нмеет су1цественпое значенне дл результатов г:оследуюн1,ей цинковой флотацин. Известно, что нри недостатке медного купороса чрезвычайно возрастают потери цинка в хвостах флотации . Весьма вреден и избыток купороса: помимо активации пирита, избыток медного купороса затрудн ет пенообразовапие, вызывает перерасход собирател и пенообразовател и ухудн)ает качество получаемого цинкового концентрата.Determining the consumption of copper sulphate used for activating zinc is important for the results of the following: followed by zinc flocacin. It is known that, due to the lack of copper sulfate, zinc losses in the flotation tails are extremely increased. Excessive vitriol is also very harmful: in addition to the activation of pyrite, excess copper sulfate impedes foaming, causes over-consumption of the collector and foaming agent and degrades the quality of the zinc concentrate.
Особенностью пред.тагаемого способа онределе1Н1 миннма.льного расхода медного купороса вл етс применение в качестве индикатора этого расхода водно-аммиачного раствора медно1 о купороса известной конце1гграцин, добав.ч емого к аэрируемой нульпе до резкого возрастани нагружеиности пены цинковой об Манкой, после чего но количеству затраченного раствора вычисл ют удельный расход медного купороса.A specific feature of the proposed onlinele1H1 method of minerum copper sulfate consumption is the use of copper ammonium solution of vitriol from the ammonium water solution used as an indicator of this consumption of ammonium sulfate known to the end of 1 gracine, adding to the aerated zinc loading of Mancoy, after which The spent solution is used to calculate the specific consumption of copper sulphate.
Пробу пульны питани цииковой флотации или хвостов свинцовой флотации загружают в лабораторную флотомашину при вращающемс импеллере; туда же ввод т известь и ксантогенат в ко.личестве обычном д.т цинковой флоганни данной руды (пенообразователь не вводитс ). Затем, при аэрации пульны , в машинку из бюретки постепенно добавл ют водио-аммиачпый раствор медпого купороса известной концентрации. Когда его ко.тичество становитс достаточным дл активации цинковой обманки, цвет пены во флотомаингне мен етс , пена нагружаетс обманкой, высота непы )езко уменьн1аетс и д. больнпнгства руд ней а частично и.тн полностью нреврацаогс в (иперализованную пленк .A sample of pulverized feed flotation or lead flotation tailings is loaded into a laboratory flotation machine with a rotating impeller; lime and xanthate are also added thereto in the usual form of zinc floganium ore of this ore (no frother is introduced). Then, when aerating is pulverized, a water-ammonia solution of copper sulfate of known concentration is gradually added to the machine from the burette. When its quality becomes sufficient to activate zinc blende, the color of the foam in the flotomaing does not change, the foam is loaded with blende, the height of the foam is slightly reduced, and the village ore is partially i.e. fully nrevravogogs (with an impregnated film.
Если в руде нмеетс несколько разновидностей цинковой обманки, например, светла с малым содержа1Н1ем железа и темна с повышенным содержанием железа, то первой ожнвл етс и по вл етс в иене евет.ча малолселезиста цинкова обманка; после этого нужно гфодолжать добавление водно-амкиачного раствора медного купороса до по влени в пене и темной цинковой обманки с повьштеинымIf there are several varieties of zinc blende in the ore, for example, light with a low content of iron and dark with a high content of iron, then the first one appears and appears in the yen as a low-selling zinc blende; after this, one should additionally add a water-ammonia solution of copper sulphate until it appears in the foam and dark zinc blende with higher
содержанием железа, так чтобыiron content so that
цвет пены-пленки был примерно таким же, как при цинковой флотации данной руды. ..the color of the foam film was about the same as that of the zinc flotation of this ore. ..
Минимальное количество медного купороса, которое необходимо дл подобно1о изменени характера йены , т. е. перехода от полупустой пены хвостов свинцовой флотации к интенсивноми11ералнзова пюй цинковой обмапкой пене-пленке, и вл етс минима.чьпо-пеобходкмым дл активации.The minimum amount of copper sulphate, which is necessary for a similar change in the nature of the yen, i.e., a transition from a half-empty foam tailing lead flotation to an intense foaming zinc foaming film, is minimal chimp-activated for activation.
Дл выпо.тнепп с лототитровани требуетс 3-5 минут.It takes 3-5 minutes to complete a lotto titration.
Водпо-аммиачный расчвор медного купороса можно готовить, например , слсдуюпщм образом: 2 г медного купороса помещают в мерную колбу () 200 мл, до.тивают туда иебо;1ыное ко.пичество воды, взбалтыва раствор ют модный купорос в долитой воде; затем по капл м добавл ют копцептрировапный раствор аммиака до тех пор, покаA ammonia vodka of copper sulfate can be prepared, for example, in the following way: 2 g of copper sulphate is placed in a volumetric flask () 200 ml, added to the bottle; 1 is the usual amount of water, the fashionable vitriol is dissolved in chilled water; then an ammonia coprecipitate solution is added dropwise until
первоначально выпавпшй голубой осадок пе растворитс полностью с образованием сиие-фиолетово1о раствора , поа-те чего колбу доливают до метки водой и перемешивают. Полученный раствор используют д,:( осуществлени предлагаемого способа; I мл этого раствора соде)жит 10 мг медного купороса.The initially precipitated blue precipitate does not completely dissolve to form a blue-violet solution, after which the flask is filled to the mark with water and stirred. The resulting solution is used d,: (implementation of the proposed method; I ml of this solution of soda) contains 10 mg of copper sulphate.
Предмет изобретени Способ определепи мипимальиого расхода медного купороса, необходимого дл активации цинковой обмапки, о т л и ч а ю nt и и с тем, что в качестве иидикатора этого расхода примен )от водно-аммиачный раствор медного купороса известной концентрации, добавл емый к аэрируемой пульпе до резкого возрастани нагруженности пеиы цииковой обманкой, после чего но ко.тичеству затраченного раствора вычислиюг удельный расход медпого купороса.The subject of the invention. The method for determining the minimum consumption of copper sulfate, necessary for activating a zinc coating, is also required so that a water-ammonia solution of copper sulfate of a known concentration added to aerated liquid is used as an indicator of this consumption. the pulp to a sharp increase in the loading of the soil deodorization, after which the specific consumption of the medic vitriol was calculated on the cost of the spent solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU454491A SU105759A1 (en) | 1955-07-02 | 1955-07-02 | Method for determining minimum copper sulfate consumption to activate zinc blende |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU454491A SU105759A1 (en) | 1955-07-02 | 1955-07-02 | Method for determining minimum copper sulfate consumption to activate zinc blende |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU105759A1 true SU105759A1 (en) | 1956-11-30 |
Family
ID=48379131
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU454491A SU105759A1 (en) | 1955-07-02 | 1955-07-02 | Method for determining minimum copper sulfate consumption to activate zinc blende |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU105759A1 (en) |
-
1955
- 1955-07-02 SU SU454491A patent/SU105759A1/en active
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