SG11201906757PA - Acrylate-based monomers for use as reactive diluents in printing formulations - Google Patents

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 16 August 2018 (16.08.2018) WIP0 I PCT omit IIl °nolo iflo oimIE (10) International Publication Number WO 2018/146259 Al (51) International Patent Classification: C09D 11/101 (2014.01) C09D 4/00 (2006.01) B41M 7/00 (2006.01) CO9D 11/30 (2014.01) (21) International Application Number: PCT/EP2018/053304 (22) International Filing Date: 09 February 2018 (09.02.2018) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 17155623.6 10 February 2017 (10.02.2017) EP (71) Applicant: BASF SE [DE/DE]; Carl-Bosch-Str. 38, 67056 Ludwigshafen am Rhein (DE). (72) Inventors: FLECKENSTEIN, Christoph; Carl-Bosch- Str. 38, 67056 Ludwigshafen (DE). BARO, Juergen; Carl- Bosch-Str. 38, 67056 Ludwigshafen (DE). BECK, Erich; Carl-Bosch-Str. 38, 67056 Ludwigshafen (DE). KALLER, Martin; Carl-Bosch-Str. 38, 67056 Ludwigshafen (DE). MISSKE, Andrea; Carl-Bosch-Str. 38, 67056 Lud- wigshafen (DE). FLEISCHHAKER, Friederike; Carl- Bosch-Str. 38, 67056 Ludwigshafen (DE). = (74) Agent: RIPPEL, Hans Christoph; Isenbruck Bosl Horschler LLP Patentanwalte, EASTSITE ONE, Secken- heimer LandstraBe 4, 68163 Mannheim (DE). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Declarations under Rule 4.17: as to applicant's entitlement to apply for and be granted a patent (Rule 4.17(ii)) of inventorship (Rule 4.17(iv)) Published: with international search report (Art. 21(3)) W O 20 18/ 146 25 9 Al (54) Title: ACRYLATE-BASED MONOMERS FOR USE AS REACTIVE DILUENTS IN PRINTING FORMULATIONS (57) : The invention relates to compositions, comprising. a)1.00 to 65.00% by weight of at least one compound of formula (I), wherein R 1 , R 2 , 0 R 3 , R 4 are each independently H, C1-C6-alkyl, C1-C6-alkoxy, or C1-C6-alkoxy- (I) Ci-C6-alkyl; R is H or Ci-C6-alkyl; Xis CR6R7, 0, or NR 8 ; R 6 R are each in- 7 dependently H, C1-C6-alkyl, Ci-C6-alkoxy, or C1-C6-alkoxy-Ci-C6-alkyl; R8 0 R 5 is H, C1-C6-alkyl, or C1-C6-alkoxy-C1-C6-alkyl; k is 1, 2, 3, 4 or 5, as com- ponent A; b) 1.00 to 60.00% by weight of at least one monomer having two (meth)acrylate groups and having a molecular weight of no more than 500 Dal- ton, as component B; c) 0 to 25% by weight of at least one monomer having at least three (meth)acrylate groups and having a molecular weight of no more than 600 Dalton, as component C; and d) 1.00 to 30.00% by weight of at least one polymer having at least two (meth)acrylate groups and having a molecular weight of at least 700 Dalton, as component D; with the proviso that the amount of components A + B is at least 50% by weight, as well as the use of these compositions as printing inks, in particular inkjet printing inks. R1 R2 R:R4 X N