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SG10201907001WA - Process to prepare paraffin wax - Google Patents

Process to prepare paraffin wax

Info

Publication number
SG10201907001WA
SG10201907001WA SG10201907001WA SG10201907001WA SG10201907001WA SG 10201907001W A SG10201907001W A SG 10201907001WA SG 10201907001W A SG10201907001W A SG 10201907001WA SG 10201907001W A SG10201907001W A SG 10201907001WA SG 10201907001W A SG10201907001W A SG 10201907001WA
Authority
SG
Singapore
Prior art keywords
carbon atoms
obtaining
range
product stream
fischer
Prior art date
Application number
SG10201907001WA
Inventor
Arend Hoek
Antonius Roovers
Kaushik Majumder
Hélène Toledano
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of SG10201907001WA publication Critical patent/SG10201907001WA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06Waxes
    • C08L91/08Mineral waxes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00Recovery or refining of mineral waxes, e.g. montan wax
    • C10G73/36Recovery of petroleum waxes from other compositions containing oil in minor proportions, from concentrates or from residues; De-oiling, sweating
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00Recovery or refining of mineral waxes, e.g. montan wax
    • C10G73/42Refining of petroleum waxes
    • C10G73/44Refining of petroleum waxes in the presence of hydrogen or hydrogen-generating compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1022Fischer-Tropsch products
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/30Physical properties of feedstocks or products

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PROCESS TO PREPARE PARAFFIN WAX The present invention provides a process to prepare paraffins and waxes, the process at least comprising the following steps: (a) providing a Fischer-Tropsch product stream comprising paraffins having from 10 to 300 carbon atoms; (b) subjecting the Fischer-Tropsch product stream of step (a) to a hydrogenation step, thereby obtaining a hydrogenated Fischer- Tropsch product stream comprising 10 to 300 carbon atoms; (c) separating the hydrogenated Fischer-Tropsch product stream of step (b), thereby obtaining at least a fraction comprising 10 to 17 carbon atoms and a fraction comprising 18 to 300 carbon atoms; (d) separating the hydrogenated fraction comprising 18 to 300 carbon atoms of step (c), thereby obtaining one or more first light waxes having a congealing point in the range of 30 to 75°C and a second heavy wax having a congealing point in the range of 75 to 120°C; e) hydrofinishing one or more wax fractions having a congealing point in the range of 30 to 75°C of step (d) thereby obtaining one or more hydrofinished wax fractions having a congealing point in the range of 30 to 75°C. (Figure 1)
SG10201907001WA 2014-12-31 2015-12-29 Process to prepare paraffin wax SG10201907001WA (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP14200717 2014-12-31

Publications (1)

Publication Number Publication Date
SG10201907001WA true SG10201907001WA (en) 2019-09-27

Family

ID=52272972

Family Applications (2)

Application Number Title Priority Date Filing Date
SG10201907001WA SG10201907001WA (en) 2014-12-31 2015-12-29 Process to prepare paraffin wax
SG11201705160YA SG11201705160YA (en) 2014-12-31 2015-12-29 Process to prepare paraffin wax

Family Applications After (1)

Application Number Title Priority Date Filing Date
SG11201705160YA SG11201705160YA (en) 2014-12-31 2015-12-29 Process to prepare paraffin wax

Country Status (8)

Country Link
US (1) US10774277B2 (en)
EP (1) EP3240873B1 (en)
CN (1) CN107109248A (en)
AU (1) AU2015373391B2 (en)
MY (1) MY186862A (en)
SG (2) SG10201907001WA (en)
WO (1) WO2016107864A1 (en)
ZA (1) ZA201704224B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107922852B (en) * 2015-09-04 2020-11-10 国际壳牌研究有限公司 Process for preparing paraffins and waxes
WO2018083143A1 (en) 2016-11-07 2018-05-11 Shell Internationale Research Maatschappij B.V. Process to prepare normal paraffins
WO2018083149A1 (en) 2016-11-07 2018-05-11 Shell Internationale Research Maatschappij B.V. Process to prepare normal paraffins
BR112019008964A2 (en) 2016-11-07 2019-07-09 Shell Int Research preparing a normal paraffin composition, and process for preparing linear alkyl benzene sulfonate
WO2018087277A1 (en) 2016-11-11 2018-05-17 Shell Internationale Research Maatschappij B.V. Polyvinylchloride compositions comprising a fischer-tropsch wax
CN109988608B (en) * 2017-12-29 2021-07-09 中国石油化工股份有限公司 Flexible liquid phase paraffin hydrogenation process
CN114174474B (en) 2019-08-08 2024-09-20 国际壳牌研究有限公司 Microcrystalline wax

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2692835A (en) 1950-06-07 1954-10-26 Gulf Research Development Co Paraffin wax compositions
MY108946A (en) 1992-07-14 1996-11-30 Shell Int Research Process for the distillation of fischer-tropsch products
MY115180A (en) * 1994-10-24 2003-04-30 Shell Int Research Synthetic wax for food applications
ZA99253B (en) * 1998-01-27 2000-07-14 Schuemann Sasol South Africa P Treatment of waxes.
CN1150299C (en) 1998-08-21 2004-05-19 舒曼-萨索尔(南非)(控股)有限公司 Method for distillation of paraffins obtained by Fischer-Tropsch process
DK1412459T3 (en) 2001-03-05 2007-11-26 Shell Int Research Process for making intermediate distillates
ES2271296T3 (en) 2001-06-15 2007-04-16 Shell Internationale Research Maatschappij B.V. PROCEDURE TO PREPARE A MICROCRYSTAL WAX.
EP1487942B2 (en) 2002-02-25 2011-08-24 Shell Internationale Research Maatschappij B.V. Process to prepare a catalytically dewaxed gas oil or gas oil blending component
BR0312667B1 (en) 2002-07-18 2012-11-27 process for preparing a microcrystalline wax and medium distillate fuel.
WO2007082589A1 (en) * 2006-01-23 2007-07-26 Shell Internationale Research Maatschappij B.V. Hydrogenation catalyst and use thereof for hdrogenating fischer-tropsch endproducts
US20100189674A1 (en) * 2007-05-11 2010-07-29 Sonneborn Inc. Petrolatum Having Silicone-Like Properties
DE102010044319A1 (en) * 2010-09-03 2012-03-08 Sasol Wax Gmbh Wax blends comprising long-chain hydrocarbons and alcohols, printing ink compositions and thermal transfer ribbons containing such wax blends and use of wax blends
RU2621685C2 (en) * 2011-11-01 2017-06-07 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Paraffin wax
IN2015DN01502A (en) * 2012-08-02 2015-07-03 Sasol Tech Pty Ltd

Also Published As

Publication number Publication date
CN107109248A (en) 2017-08-29
SG11201705160YA (en) 2017-07-28
EP3240873A1 (en) 2017-11-08
WO2016107864A1 (en) 2016-07-07
US20170369799A1 (en) 2017-12-28
AU2015373391B2 (en) 2019-03-21
MY186862A (en) 2021-08-26
EP3240873B1 (en) 2023-08-16
AU2015373391A1 (en) 2017-07-13
ZA201704224B (en) 2018-08-29
US10774277B2 (en) 2020-09-15

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