SE545966C2 - Method for obtaining a coated fiber-based product comprising cellulose fibers - Google Patents
Method for obtaining a coated fiber-based product comprising cellulose fibersInfo
- Publication number
- SE545966C2 SE545966C2 SE2151158A SE2151158A SE545966C2 SE 545966 C2 SE545966 C2 SE 545966C2 SE 2151158 A SE2151158 A SE 2151158A SE 2151158 A SE2151158 A SE 2151158A SE 545966 C2 SE545966 C2 SE 545966C2
- Authority
- SE
- Sweden
- Prior art keywords
- fiber
- based product
- previous
- recess
- liquid material
- Prior art date
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 117
- 238000000034 method Methods 0.000 title claims abstract description 67
- 229920003043 Cellulose fiber Polymers 0.000 title claims abstract description 16
- 238000007639 printing Methods 0.000 claims abstract description 98
- 239000011344 liquid material Substances 0.000 claims abstract description 53
- 239000011247 coating layer Substances 0.000 claims abstract description 22
- 230000004888 barrier function Effects 0.000 claims description 34
- 239000000463 material Substances 0.000 claims description 31
- 239000007788 liquid Substances 0.000 claims description 28
- 239000010410 layer Substances 0.000 claims description 26
- 238000000576 coating method Methods 0.000 claims description 21
- 239000011248 coating agent Substances 0.000 claims description 17
- 238000001035 drying Methods 0.000 claims description 13
- 238000004140 cleaning Methods 0.000 claims description 11
- 229920001131 Pulp (paper) Polymers 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 102100031260 Acyl-coenzyme A thioesterase THEM4 Human genes 0.000 claims description 6
- 101000638510 Homo sapiens Acyl-coenzyme A thioesterase THEM4 Proteins 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 5
- 241000218657 Picea Species 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- 239000002966 varnish Substances 0.000 claims description 4
- 238000007598 dipping method Methods 0.000 claims description 3
- 239000002657 fibrous material Substances 0.000 claims description 3
- 239000000123 paper Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 241000609240 Ambelania acida Species 0.000 claims description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 2
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 2
- 229920000875 Dissolving pulp Polymers 0.000 claims description 2
- 244000166124 Eucalyptus globulus Species 0.000 claims description 2
- 244000082204 Phyllostachys viridis Species 0.000 claims description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 239000010905 bagasse Substances 0.000 claims description 2
- 239000011425 bamboo Substances 0.000 claims description 2
- 238000003618 dip coating Methods 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 239000002655 kraft paper Substances 0.000 claims description 2
- 239000010902 straw Substances 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 2
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 2
- 238000005259 measurement Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 description 11
- 238000012384 transportation and delivery Methods 0.000 description 10
- 238000007649 pad printing Methods 0.000 description 9
- 238000004347 surface barrier Methods 0.000 description 8
- 238000000465 moulding Methods 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 239000008204 material by function Substances 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 239000011105 molded pulp Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 229920001600 hydrophobic polymer Polymers 0.000 description 2
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- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- -1 alkyl ketene dimer Chemical compound 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
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- 238000007602 hot air drying Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 238000010329 laser etching Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000020939 nutritional additive Nutrition 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000012460 protein solution Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/0005—Processes or apparatus specially adapted for applying liquids or other fluent materials to finished paper or board, e.g. impregnating, coating
- D21H5/0025—Processes or apparatus specially adapted for applying liquids or other fluent materials to finished paper or board, e.g. impregnating, coating by contact with a device carrying the treating material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/0046—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by constructional aspects of the apparatus
- B32B2037/0069—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by constructional aspects of the apparatus the apparatus being originally designed for another function, e.g. printer, photocopier
Landscapes
- Laminated Bodies (AREA)
- Materials For Medical Uses (AREA)
Abstract
A method for obtaining a coated fiber-based product comprising cellulose fibers, said method comprising the steps of providing a fiber-based product (1) comprising cellulose fibers; providing a printing plate (2) comprising at least one recess (3); providing a volume (40) of a liquid material (4) to said recess of said printing plate; applying a printing pad (6) into said recess; allowing said liquid material comprised in the recess to adhere to an outside surface (60) of said printing pad, moving the printing pad comprising said adhered liquid material on said outside surface of said printing pad from the recess; and contacting a surface of said fiber-based product with said printing pad and allowing the adhered liquid material to leave said outside surface of the printing pad and to instead adhere to a surface (10; 100) of said fiber-based product thereby creating a coating layer (8).
Description
Technical field
The present invention relates to a method for obtaining a
coated fiber-based product comprising cellulose fibers.
The present invention also relates to a three-dimensional
molded pulp structure made by means of the method.
Background There is a growing interest for producing cellulose-based
products for use as packaging applications for foodstuff, tableware, trays, technical products, electronic equipment and/or consumer goods. Several advantages are associated with the use of natural fibers (such as cellulose fibers) for manufacturing packages. Being a renewable resource, natural fibers provide a sustainable alternative to other packaging materials such as aluminum and plastics, and furthermore natural fibers are both recyclable and biodegradable. Natural fibers include cellulose fibers of any natural
origin, such as derived from wood pulp and/or plants.
Molding of cellulose fiber materials provides a way of achieving renewable articles with various three-dimensional shapes, which may be used to differentiate products available for sale in a
given market place.Manufacturing molded fiber products can be done by wet forming, wherein a forming tool is dipped into an aqueous pulp composition followed by compression-molding performed under heat, resulting in a dried fiber product having a shape complementary to the shape of the mold. Typically, said tool is perforated or porous so that water can be removed from the suspension or wet pulp during forming during a dewatering/drying step.
It is also possible to dry mold products such as trays from a cellulose fiber sheet or web. Dry molding can be done in various ways, e.g. by press-forming a wetted sheet combined with applied
heat using a forming tool.
While there is a demand for environmentally friendly packaging products, especially single-use food packaging products, a known problem with moulded pulp products is it has proven difficult to provide barrier properties. Packages for food requires adequate grease resistance, or water repellence properties, or both. To impart such properties to a moulded article of cellulose, a surface treatment or coating method is often required. In addition, the coating should preferably have properties that not only improves the properties but also facilitates the manufacturing of the moulded articles without compromising repulpability and recyclability. Prior art discloses ideas to provide desired properties to the moulded products, e.g. post-coating the moulded product
with barrier coating layer.
An example is disclosed in WO11/O65911 wherein a resilient pad is submerged into a bath containing a liquid surface barrier
material for uptake of said liquid surface barrier material onto theresilient pad whereafter the pad is pressed against the surface of a fiber product for creating a barrier layer. The fiber product is placed inside of and supported by a porous mold during the application of the liquid surface barrier material. A suction is applied through the pores of the mold during the application of the liquid surface barrier material. However, there are several disadvantages with this technology for creating a barrier. For instance, using a bath with a large excess of liquid surface barrier material leads to an extensive waste of liquid surface barrier material. The amount of liquid surface barrier material applied to the fibrous product cannot be controlled meaning that no proper controlthe amount of the surface barrier layer is possible during the production and further that optimization of the application is not possible. Moreover, the coating barrier material could be sucked into the formed product, either destroying the functional coating layer on the surface or Wasting more barrier materials going into the bulk. Therefore, this is not a sustainable and economical way of applying barrier
properties to fibrous products.
There is a remaining need for cellulose-based, surface treated or coated products where the coating preferably has properties that not only improves the product properties but also facilitates the manufacturing of the articles as well as sustainability, repulpability and recycling. There is also a need of reducing the total amount usage of coating chemicals, leading to a more reusable and
environmentally friendly products.
Obiect of the inventionIt is an object of the present invention, to provide an improved method for obtaining a coated fiber-based product
comprising cellulose fibers.
Summary The object of the invention is at least partially obtained by
means of a method for obtaining a coated fiber-based product comprising cellulose fibers according to c|aim 1. Said method comprises at least the steps of:
-providing a fiber-based product comprising cellulose fibers;
-providing a printing plate comprising at least one recess;
-providing a volume of a liquid material to said recess of said printing plate;
-applying a printing pad into said recess;
-allowing said liquid material comprised in the recess to adhere to an outside surface of said printing pad,
-moving the printing pad comprising said adhered liquid material on said outside surface of said printing pad from the recess;
-contacting a surface of said fiber-based product with said printing pad and allowing the adhered liquid barrier material to leave said outside surface of the printing pad and to instead adhere to the surface of said fiber-based product thereby creating a coating
layer.
Thanks to the inventive method, there is achieved a very accurate way of creating a coating layer due to that the volume of the liquid material provided to the recess is directly proportional to
the thickness of the coating layer. That is, by controlling/adjustingthe volume of liquid material provided to the recess, the thickness
of the coating layer may also be controlled/adjusted.
Furthermore, the method results in a surprisingly even thickness of the obtained coating layer, aiming for the bottom and side wall parts, also effective at difficult parts of the fiber-based material, e.g. at edges, corners, on both smooth and rough
su rfaces.
These are all great improvements as compared to the coating
methods described in the background prior art.
The dependent claims are related to preferred embodiments. They may be combined freely unless the context clearly indicates
otherwise.
Brief description of the drawincls
The foregoing aspects and many of the attendant advantages of this invention will become more readily appreciated as the same become better understood by reference to the following detailed description, when taken in conjunction with the accompanying
drawings, wherein:
Fig. 1a is a schematic view of technical parts comprised in a pad printing device for performing the inventive method for obtaining a coated fiber-based product;
Fig. 1b shows, in a schematic way, a fiber-based product ready to undergo the inventive method;
Figs. 2a-2f schematically show a number of steps comprised
in the inventive method.
Detailed description
Before the invention is disclosed and described in detail, it is to be understood that the terminology employed herein is used for the purpose of describing particular embodiments only and is not intended to be limiting since the scope of the present invention is
limited only by the appended claims and equivalents thereof.
"Printing plate" is in its broadest sense a flat surface comprising a recess. The printing plate typically offers a smooth and flat, most often horizontal, surface into which a cavity has been created. In this context the cavity is termed a recess, in other contexts the recess is often denoted a relief. The printing plate may typically be made from steel or polymers, but other materials are conceivable too, and the invention is not limited to the choice of
material of the plate.
"Recess" is used herein to denote a three-dimensional space having a volume in the plate. Said volume is defined by a bottom surface and one or more wall surface/-s, the number of walls depending on the shape of the recess, which can be of an irregular shape, or a more well-defined shape, e.g. rectangular, square, cylindrical etc. The shape may further comprise concave and/or convex parts. Said volume is an open volume having no upper
ceiling closing the volume.
"Printing pad" or "pad" is used herein to denote a cushion, which is made of a resilient and flexible material, typically of, but not limited to, silicone. Thanks to the flexible material the pad can
easily adapt its shape to a surrounding shape of a recess whenbeing pressed/applied/submerged into the recess. The hardness of the pad may be determined by the amount of silicon oil used when the pad is manufactured, i.e. the harder the pad, the less silicone
oil was added during manufacture.
"Pad printing" is used herein to denote a process for printing of two- or three-dimensional objects by making use of a flexible printing pad. Pad printing is an indirect offset printing process. Conventionally, the pad printing process is used for transferring an image from a printing plate (often termed cliché) via a printing pad
onto a substrate.
"Liquid material" is used herein to denote a material in liquid form. The liquid material is applied to a surface of fiber-based products such as paper or board to form a solid, non-porous film after drying covering essentially the whole surface, i.e. covering more than 900/0, preferably 95% or more and most preferred 98% or more of the surface to be covered (coated) by the applied liquid
material.
"Coating" and "coating layer" as used herein denotes covering more than 900/0, preferably 95% or more and most preferred 98% or more of a surface with a continuous layer of a coating, i.e. a
coating layer.
Fig. 1a is a schematic view of a pad printing device D. Said pad printing device D comprises a printing plate 2 and a printing pad 6 held by a holderThe printing plate 2 may in its simplest form be any flat surface which preferably is also a horizontal surface. Said printing plate 2 may be a surface of a table or a plate resting on a table or a stand. The printing plate 2 comprises a recess 3 having a well- defined volume 30, said volume 30 may be a variable volume or a fixed volume. In embodiments where the volume 30 is a variable volume, a bottom surface and/or a wall surface of the volume 30 may preferably be arranged to be adjustable. The recess 3 is
arranged to comprise a volume 40 of a liquid material
The recess 3 is typically created in the printing plate 2 by any therefore appropriate process, e.g. laser etching or acid etching. The inventive idea is not limited to the kind of process of creating
the recess.
Preferably the bottom surface and the wall surfaces of the
recess 3 are smooth.
Embodiments are however conceivable where said surfaces of
the recess 3 are textured.
Preferably, the printing pad 6 is a resilient and flexible pad having a vertical center axis A. Said vertical center axis A is preferably coinciding with a vertical center axis of said recess 3,
and preferably also with a vertical center axis of the holder
The printing pad 6 has an outside surface
In Fig. 1A, said printing pad 6 is arranged in a position such
that said printing pad 6 is ready to be dipped or pressed (dependingon a relation between a size of the printing pad 6 and the volume 30 of said recess 3) into the recess 3 comprising the volume 40 of
the liquid material
Fig. 1b is a schematic view of a fiber-based product 1 comprising cellulose fibers. As can be seen the fiber-based product 1 shown in Fig. 1b has a convex shape and is an example of a
three-dimensional (3D) fiber-based product.
For three-dimensional (3D) fiber-based products, it may be an advantage if the shape of the printing pad 6 has a complementary shape to a shape of a surface 10 of the fiber-based product 1, as shown in Figs. 1a and 1b. Adapting the shape of the printing pad 6 to the shape of the 3D fiber-based product 1 may result in a more uniform adherence of the liquid material 4 from the outside surface 60 of the printing pad 6 to the surface 10 of the fiber-based product
For 3D fiber-based products 1 it may further be preferred that also the recess 3 has a shape that is essentially of the same shape as the shape of the surface 10 of the 3D fiber-based product 1, or at least similar to the shape of the surface 10 of the 3D fiber-based product 1. A shape of the recess 3 adapted to the shape of the 3D fiber-based product 1 may result in a more uniform adherence of the liquid material 4, first to the outside surface 60 of the printing pad 6, and then to the surface 10 of the 3D fiber-based product 1, thereby resulting in a more even coating layer on the surface 10 of the 3D fiber-based product
From reading the above it is understood that for 3D fiber-
based products 1 it is preferred that all of the shapes, i.e. of the
recess 3, printing pad 6, and the fiber-based product 1, may be the
same or at least similar with regards to their dimensions.
For the 3D fiber-based product as shown in Fig. 1b, the surface 10 of the fiber-based product 1 to be contacted with the printing pad 6 is preferably an inside surface 100 of said fiber-
based product 1, i.e. herein the concave surface.
In other embodiments, not shown, said fiber-based productmay be a two-dimensional (2D) fiber-based product.
Figs. 2a-2f schematically show the main steps of the method
according to the invention.
In Fig. 2a the printing pad 6 is arranged by the holder 7 in a starting position above the recess 3 comprised in the printing plate 2 (the same position as shown in Fig. 1a). The liquid material 4 preferably occupies 90 vol-O/o or more of said volume 30 of the recess 3, and most preferred at least 98 vol-O/o or more. Said liquid material 4 preferably fills the total volume 30 of said recess 3. In embodiments where the volume 30 of the recess 3 is completely filled with liquid material 4, the volume 40 of the liquid material
equals the volume of the recess
Fig. 2b shows that a movement of the printing pad 6 in a downwardly direction towards the recess 3 occurs. The printing pad 6 is pressed into said recess 3 and a step of applying the printing
pad 6 into the recess 3 has thereby been performed.The printing pad 6 is, as already discussed, preferably made of a flexible material and due to this flexibility, said printing pad 6 adapts its shape to the shape of the recess 3 when being pressed into the recess 3, i.e. it deforms to some extent during pressing into the recess. When the printing pad 6 is pressed into the recess 3, the liquid material 4 kept in the recess 3 adheres to the outside
surface 60 of the printing pad
Preferably 90 vol-O/o or more, more preferred 95 vol-O/o or more, and most preferred 98 vol-% or more, of the volume 40 of liquid material 4 comprised in the recess 3 is adhered to said
outside surface 60 of said printing pad
Fig. 2c illustrates an upward movement of the printing pad 6, now comprising said adhered liquid material 4 on its outside surface 60. The holder 7 vertically lifts the printing pad 6 up from the recess 3. Preferably the movement is at least initially performed
along the center axis A of the printing pad 6 / holder
After having lifted the printing pad 6 upwardly, the holder 7 moves the printing pad 6 and positions the printing pad 6 in a position above the fiber-based product 1, as shown in Fig. 2d. Preferably the vertical center axis A of the printing pad 6 coincides with a vertical center axis of the fiber-based product 1. (The skilled person understands the fiber-based product 1 may be moved to the
printing pad 6 instead of the other way around.)
An adhered layer of liquid material 4 on the surface 60 of the
printing pad 60 is shown in Fig. 2d. An area of the liquid materialon the surface 60 preferably corresponds essentially to an area of
the surface 10 of the fiber-based product 1 intended to be coated.
In Fig. 2e a downward, and preferably vertical, movement of the printing pad 6 is performed by the holder 7 such that the printing pad 6 comes into a direct contact with the surface 10, 100 of said fiber-based product 1 thereby allowing the adhered liquid material 4 to leave said outside surface 60 of the printing pad 6 and to instead adhere to the surface 10, 100 of said fiber-based product 1. Upon contacting the surface 10, 100 of the fiber-based product, the printing pad 6 is pressed towards said surface such that it is at least slightly deformed, securing that the liquid material 4 is properly transferred from the pad 6 to the fiber-based product 1, i.e. the liquid material 4 is transferred from the pad 6 to the surface 10, 100 of said fiber-based product under applied pressure. Thereby, a creating coating layer 8 is created on the surface 10, 100 of said fiber-based product
Fig. 2f schematically shows the vertical movement of the printing pad 6 upwardly and away from the fiber-based productnow comprising the coating layer
Preferably, 90 vol-O/o or more of the volume 40 of said liquid material 4 adhered to said outside surface 60 of said printing pad 6 will in the direct contact with the surface 10, 100 of the fiber-based product 1 adhere to said surface 10, 100 of the fiber-based product 1. More preferred, 98 vol-O/o or more of the volume 40 of said liquid material 4 adhered to said outside surface 60 of said printing padwill instead adhere to said surface 10,Preferably 90 %, and more preferred 95 % or more of the area of the surface 10, 100 of said fiber-based product 1 has now been covered by said adhered liquid material 40 resulting in one layer 8 of a continuously coating on said fiber-based product 1, i.e. one layer 8 of coating has been applied to the fiber-based product
For fiber-based products comprising only one coating layer 8, the method for obtaining a coated fiber-based product is completed after the step shown in Fig. 2f. A coated fiber-based product
comprising cellulose fibers has hereby been obtained.
However, it is conceivable, most often a reality, that the fiber- based product 1 may have two or more layers of coatings. The cycle of the method for obtaining a coated fiber-based product as shown in the Figs. 2a-2f may then repeated as many times as the
number of coating layers 8 needed.
Preferably, one layer of coating will have a dry weight in an interval of 1-20 gsm, more preferred 5-15 gsm and most preferred
9-11 gsm.
Said pad printing device D comprises at least one container comprising liquid material 4. Said container is preferably arranged in a sealing contact with the printing plate 2 such that the container is moveable over a surface of the printing plate 2 while still keeping the sealed contact. The container delivers liquid material 4 to the recess 3 before immersion of the printing pad 6 into the recess 3. The container may preferably be closed and performs a doctoring
function over the printing plate 2 during operation. Delivery of theliquid material 4 to the recess 3 takes place when the container has moved from a starting position and is positioned in a delivery position above the recess 3. Scraping off of any delivered excess liquid material 4 to the recess 3 occurs when the container moves from the delivery position back to the starting position thereby securing delivery of a controlled and exact volume 40 of the liquid
material 4 to the volume 30 of the recess
It is conceivable that the container, in some embodiments, does not move, but instead the printing plate 3 moves under the container. Irrespective which of the printing plate 3 or the container is moveable, the end result is that the surface of the printing plate 2 is cleaned up and the recess 3 has been filled with a controlled
volume 40 of the liquid material
In some embodiments the pad printing device may comprise two containers. A first container may comprise a liquid precoating material, e.g. a varnish, and a second container may comprise a
liquid barrier material.
It is conceivable that the pad printing device further
comprises a third container comprising e.g. a post-coating liquid.
The working operation of the moveable container will not be described in more detail here since that operation may be
performed in any conventional and known way.
Preferably, the inventive method for obtaining a coated fiber- based product further comprises at least one cleaning step. This
cleaning step may be performed by a cleaning station comprised in
or outside the printing device D. In said cleaning step the outside surface 60 of the printing pad 6 may be cleaned. Preferably said cleaning step is performed after the printing pad 6 has contacted the surface 10, 100 of the said fiber-based product 1 and the adhered liquid barrier material has left the outside surface 60 of the printing pad 6 and instead adhered to the surface 10, 100 of said fiber-based product 1. During the cleaning step any rest of liquid material (4) that may still remain on the outside surface 60 of the printing pad 6 after the contact with the surface 10, 100 of the fiber-based product 1, i.e. that has not adhered to the surface 10, 100 of the fiber-based product 1, will be removed from the outside surface 60. After the performed cleaning step the outside surface 60 of the printing pad 6 is free, or at least essentially free, from
liquid material 4 and ready to undergo a next cycle of the method.
In some embodiments it is conceivable that the cleaning step of the outside surface 60 of the printing pad 6 may not be performed after every delivery of liquid material 4 to the surface 10, 100 of the fiber-based product 1, but only when there is a
change of a chemical composition of the liquid material
Embodiments are conceivable wherein the fiber-based product 1 is supported/held by a mold during contacting the surface 10, 100 of said fiber-based product 1 with said printing pad
The method preferably comprises at least one drying step for drying of the of the fiber-based product comprising one or more coating layer/-s and/or the coated fiber-based product. Said drying step may comprise hot air drying, microwave and/or IR drying but
other drying techniques are however conceivable.The method may comprise additional method steps without
departing from the scope of the invention.
For example, said method for obtaining a coated fiber-based product may further comprise a spraying step for spray coating and /or a dipping step for dip coating one or more parts of said fiber- based product wherein said one or more parts may be chosen from any of edges and /or corners and / or flat parts of said fiber-based
product.
According to one aspect of the invention, the fiber-based product is a molded fiber-based product. In the following, an example of a wet molding method for manufacturing a 3D molded fiber-based product will be described, which manufactured 3D molded fiber-based product will obtain a coating layer according to
the inventive method.
An aqueous pulp suspension (also referred to as “composition”) is provided with the consistency of O.O5-1Owt°/0. The pulp may be any one of wood pulps, non-wood pulps, unbleached chemical pulp, defibrated fiber material, bagasse, straws, bamboo, spruce CTMP, eucalyptus CTMP, spruce HT CTMP, kraft pulp, sulphate, sulphite, PGW, GW, DIP, recycled paper and board, broke, RMP, TMP, CMP, CSP NSSC nanopulp, dissolving pulp, and regenerated fibers or mixtures thereof. A 3D shaped forming tool comprising a forming portion is brought into contact with the pulp suspension, for instance by dipping or immersing said tool into the slurry bath. Said forming portion is arranged to represent a 3D
mirror image of the article to be formed. Pulp is drawn onto theforming portion e.g. by means of vacuum suction until a layer of desired thickness has been formed, whereupon the forming tool is removed from the slurry. At this stage, the forming portion is covered with a wet layer of pulp, said wet layer comprising between 5-150 gsm (g/m2) in dry weight. Next, the wet layer of pulp is dewatered to a dry content of at least 70 wt°/0. Dewatering and/or drying can be done in various ways. In a wet curing procedure, the wet layer is pressed under elevated temperatures to be compressed and dried to a certain thickness, thereby yielding a smooth external surface for the end structure. In a dry curing process, the wet layer is subjected to heated air thereby removing moisture, which results in an end structure with a more textured finish. This way, a single
layer molded fiber product is formed.
Manufacturing multilayered molded fiber products can be accomplished for instance by applying more than one fibrous layer on top of each other in consecutive molding production steps. For instance, a layer of metal salt-containing pulp can be molded onto a pre-molded pulp layer already present on the forming tool. The various layers of a multilayered product may hereby provide
different functions, such as rigidity, barrier properties, etc.
According to the invention, the hot press temperature range for a wet molded procedure is around 150-220 degrees C, with a
press range around 1-10 bar.
A dry grammage of the molded product is preferably 100-500 gsm or more preferably 200-400 gsm, and a dry density is between 100-1200 kg/m3, preferably 200-1000 kg/m3 or most preferably 400-800 kg/mOnce the 3D molded fiber-based product has been dried to a desired dryness, said 3D molded fiber-based product will undergo the method according to the invention as defined in claim 1 and any one of the dependent claims so as to obtain a coating layer on an
inside of the 3D molded fiber-based product.
The coated fiber-based products made by means of the method of the present invention may be referred to as packages and/or packaging material, and include in a non-limiting way bowls,
cups, capsule, pots, containers, trays and packages.
Examples of fiber-based products suitable for the inventive method are fiber-based products having irregular surfaces and/or
surfaces characterized by high surface roughness.
The invention is not limited to any special kind of manufacturing method of the fiber-based product comprising
cellulose fibers.
The skilled person appreciates that the invention may contemplate any fiber-based manufacturing method, including conventional wet forming procedures and dry forming procedures, wet molding procedures, dry molding procedures, three-
dimensional (3D) printing techniques and air laid techniques.
The invention is not limited to the chemical composition of the liquid material. The liquid material may be chosen from a variety of chemical compositions and the choice depends on the properties
wanted for the specific application/product.In some embodiments, the fiber-based product may be intended to contain foodstuff in which case the liquid material is a liquid barrier material, and the obtained coating layer is a barrier layer preferably arranged at the food-contacting side of the
product, for instance on the inside of a tray.
Commonly, there is a most often a need to improve the barrier properties of the surface (inside and/or outside surface) of the fiber-based product against grease, oil, liquid, moisture and/or oxygen. It is advantageous that the formed barrier layer is impervious, or at least resistant, to grease, oil, liquid, moisture,
aroma and/or oxygen.
When barrier properties are desirable for the fiber-based product, the liquid barrier material may preferably be a dispersion barrier material, an emulsion barrier material or any other kind of liquid barrier material that provides barrier properties to the fiber- based product when applied to a surface of said fiber-based
product.
The dispersion barrier material may comprise fine polymer particles, such as latex and optionally pigments. Alternatively, the dispersion barrier material may comprise starch and hydrophobic polymers such as Wax, styrene maleic anhydride (SMA) and/or or an alkyl ketene dimer (AKD) or a copolymer of ethylene and PVOH further including optionally hydrophobic polymers. Such a dispersion coating applied on the surface of the fiber-based product may serve as a sufficiently efficient barrier against moisture arising
from condensation. In addition, the barrier layer provides good
optical properties resulting in a surface of a thereof formed
packaging suitable for printing.
The liquid barrier material may preferably have a Brookfield viscosity in a range of 100 - 2000 mpa.s, more preferred 200-1200 mpa.s, and most preferred 350 - 800 mpa.s using spindle 4, atFpm meaSUFement.
It may further be advantageous that the formed barrier is
biodegradable.
The liquid material may further be chosen from a pigment coating liquid material, a varnish, e.g. a food-contacting varnish,
and/ or a Wax in liquid form.
The present invention has been described with regard to preferred embodiments. However, it will be obvious to a person skilled in the art that a number of variations and modifications can be made without departing from the scope of the invention as
described herein.
The printing pad may be used not only for delivery of barrier layers but also for delivery of functional materials, such as, but not limited to, conductive inks, adhesives, dyes, flavours, nutritional additives, conservatives, and lubricants, to the surface of the fiber-
based product.
The method may further be used also for delivery of aqueous starch solution, protein solution, styrene-based polymers, styrene
acrylate-based polymers, styrene butadiene polymers, non-ionicacryl polymers, ammonia salt of modified acrylic polymers, proteins, and/or cellulose derivatives to the surface of the fiber-
based product.
It is conceivable to firstly deliver liquid functional materials to the surface of the fiber-based product followed by delivery of one or more liquid barrier materials on top of the delivered liquid functional materials. Any drying step may be performed between and/or after the deliveries. It is also conceivable to deliver liquid functional materials as a middle-layer or a finishing layer on an already barrier coated fiber-based product.
Claims (19)
1. A method for obtaining a coated fiber-based product comprising cellulose fibers, said method -~__providing a fiber-based product (1) comprising cellulose fibers; -providing a printing plate (2) comprising at least one recess (3); -providing a volume (40) of a liquid material (4) to said recess (3) of said printing plate (2); -applying a printing pad (6) into said recess (3); -allowing said liquid material (4) comprised in the recess (3) to adhere to an outside surface (60) of said printing pad (6), -moving the printing pad (6) comprising said adhered liquid material (4) on said outside surface (60) of said printing pad (6) from the recess (3); -contacting a surface of said fiber-based product (1) with said printing pad (6) and allowing the adhered liquid material (4) to leave said outside surface (60) of the printing pad (6) and to instead adhere to a surface (10; 100) of said fiber-based product (1), thereby creating a coating layer (8).
2. A method according to claim 1, Wherein the printing pad (6), upon contacting the surface of said fiber-based product (1), is pressed against said surface such that it is deformed, for transferring said liquid material (4) from the pad (6) to the surface (10; 100) of said fiber-based product (1).
3. A method according to claim 1 or 2, wherein 90 vol-O/o or more of said volume (40) of liquid material (4) comprised in the recess (3) is adhered to said outside surface (60) of said printing pad (6).
4. A method according to any one of the previous claims, wherein 90 vol-O/o or more of the volume (40) of said liquid material (4) adhered to said outside surface (60) of said printing pad (6) will, in contact with the surface (10; 100) of the fiber-based product (1), adhere to said surface (10; 100) of the fiber-based product (1).
5. A method according to any one of the previous claims, wherein 90 % or more of an area of the surface (10; 100) of said fiber-based product (1) is being covered by said adhered liquid material (4) resulting in one layer of coating (8) on said fiber-based product (1).
6. A method according to any one of the previous claims, wherein one layer of coating (8) preferably will have a dry weight in an interval of 1-20 gsm.
7. A method according to any one of the previous claims, wherein the method is repeated for one and the same fiber-based product (1) such that the surface (10; 100) of the fiber-based product (1) will have two or more coating layers (8).
8. A method according to any one of the previous claims, wherein a cleaning step is arranged for cleaning said outside surface (60) of said printing pad (6), preferably said cleaning stepis arranged after the printing pad (6) has been in contact with said surface (10; 100) of said fiber-based product (1).
9. A method according to any one of the previous claims, wherein the method further comprises a spraying step for spray coating one or more parts of said fiber-based product (1); said one or more parts is/ are chosen from any of edges and /or corners and/ or flat parts of said fiber-based product.
10. A method according to any one of the previous claims, wherein said method further comprises a dipping step for dip coating one or more parts of said fiber-based product; said one or more parts is/ are chosen from any of edges and /or corners and / or flat parts of said fiber-based product.
11. A method according to any one of the previous claims, wherein at least one drying step is arranged for drying said fiber- based product comprising one or more coating layer/-s.
12. A method according to any one of the previous claims, wherein at least one drying step is arranged for drying said coated fiber-based product.
13. A method according to any one of the previous claims, wherein said liquid material is chosen from dispersion barriers, emulsion barriers, suspension barriers, pigment coatings, varnishes, pre-coating liquids, post-coating liquids.
14. A method according to any one of the previous claims, wherein said fiber-based product is a three-dimensional molded fiber-based product.
15. A method according to any one of the previous claims, wherein the steps of the method are being performed on an inside surface of said three-dimensional molded fiber-based product.
16. A method according to any one of the previous claims, wherein said fiber-based product comprises ce||u|ose pulp selected from the group comprising: wood pulps, non-wood pulps, unbleached chemical pulp, defibrated fiber material, bagasse, straws, bamboo, spruce CTMP, eucalyptus CTMP, spruce HT CTMP, kraft pulp, sulphate, sulphite, PGW, GW, DIP, recycled paper and board, broke, RMP, TMP, CMP, CSP NSSC nanopulp, dissolving pulp, and regenerated fibers and mixtures thereof.
17. A method according to any one of the previous claims, wherein the grammage of the molded product is
18. A method according to any one of the previous claims, wherein said molded product comprises a density between 100- 1200 kg/m3, preferably 200-1000 kg/m3 or most preferably 400- 800 kg/m
19. A method according to any one of the previous claims, wherein a viscosity of a liquid barrier material is Within the range of 100-2000 mpa.s using spindle 4, at 100 rpm measurement.
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| SE2151158A SE545966C2 (en) | 2021-09-22 | 2021-09-22 | Method for obtaining a coated fiber-based product comprising cellulose fibers |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE2151158A SE545966C2 (en) | 2021-09-22 | 2021-09-22 | Method for obtaining a coated fiber-based product comprising cellulose fibers |
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|---|---|---|---|---|
| JPH0834424A (en) * | 1994-07-21 | 1996-02-06 | Sony Corp | Packaging containers |
| WO1996029205A1 (en) * | 1995-03-21 | 1996-09-26 | Lundgren Claes G L | Coating in connection with printing and coating composition with barrier properties |
| US5818016A (en) * | 1992-05-27 | 1998-10-06 | Conagra, Inc. | Food trays and the like having press-applied coatings |
| US20100221449A1 (en) * | 2007-07-24 | 2010-09-02 | Schmid Rhyner Ag | Method and apparatus for applying plastic coatings |
| WO2011065911A1 (en) * | 2009-11-27 | 2011-06-03 | Pakit International Trading Company Inc. | A method for applying a barrier on moulded fibrous product and a product produced by said method |
| JP2018108654A (en) * | 2016-12-28 | 2018-07-12 | 出光ユニテック株式会社 | Antifogging sheet, molded article, container, and method for producing molded article |
| JP2020125140A (en) * | 2019-02-05 | 2020-08-20 | 内山工業株式会社 | Manufacturing method of cork stopper and cork stopper |
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2021
- 2021-09-22 SE SE2151158A patent/SE545966C2/en unknown
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|---|---|---|---|---|
| US5818016A (en) * | 1992-05-27 | 1998-10-06 | Conagra, Inc. | Food trays and the like having press-applied coatings |
| JPH0834424A (en) * | 1994-07-21 | 1996-02-06 | Sony Corp | Packaging containers |
| WO1996029205A1 (en) * | 1995-03-21 | 1996-09-26 | Lundgren Claes G L | Coating in connection with printing and coating composition with barrier properties |
| US20100221449A1 (en) * | 2007-07-24 | 2010-09-02 | Schmid Rhyner Ag | Method and apparatus for applying plastic coatings |
| WO2011065911A1 (en) * | 2009-11-27 | 2011-06-03 | Pakit International Trading Company Inc. | A method for applying a barrier on moulded fibrous product and a product produced by said method |
| JP2018108654A (en) * | 2016-12-28 | 2018-07-12 | 出光ユニテック株式会社 | Antifogging sheet, molded article, container, and method for producing molded article |
| JP2020125140A (en) * | 2019-02-05 | 2020-08-20 | 内山工業株式会社 | Manufacturing method of cork stopper and cork stopper |
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| Publication number | Publication date |
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| SE2151158A1 (en) | 2023-03-23 |
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