SE501158C2 - Ways to clean flue gases with a deficit of oxygen and formed soot - Google Patents
Ways to clean flue gases with a deficit of oxygen and formed sootInfo
- Publication number
- SE501158C2 SE501158C2 SE9201232A SE9201232A SE501158C2 SE 501158 C2 SE501158 C2 SE 501158C2 SE 9201232 A SE9201232 A SE 9201232A SE 9201232 A SE9201232 A SE 9201232A SE 501158 C2 SE501158 C2 SE 501158C2
- Authority
- SE
- Sweden
- Prior art keywords
- soot
- flue gases
- oxygen
- deficit
- flue gas
- Prior art date
Links
- 239000003546 flue gas Substances 0.000 title claims abstract description 20
- 239000004071 soot Substances 0.000 title claims abstract description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 4
- 239000001301 oxygen Substances 0.000 title claims abstract description 4
- 230000006735 deficit Effects 0.000 title claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 6
- 239000000446 fuel Substances 0.000 claims abstract description 4
- 238000002485 combustion reaction Methods 0.000 claims description 7
- 150000002013 dioxins Chemical class 0.000 claims description 5
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 4
- 239000003344 environmental pollutant Substances 0.000 claims description 3
- 231100000719 pollutant Toxicity 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 abstract 1
- 230000007812 deficiency Effects 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 238000009434 installation Methods 0.000 abstract 1
- 239000000428 dust Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
- B01D53/70—Organic halogen compounds
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/006—Layout of treatment plant
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Treating Waste Gases (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
Abstract
Description
501 10 15 20 25 30 35 158 2 innehåller dioxiner och kvicksilver. Föreliggande uppfin- ning är särskilt inriktad på avskiljningen av just dioxi- ner och kvicksilver. 501 10 15 20 25 30 35 158 2 contains dioxins and mercury. The present invention is particularly focused on the separation of just dioxins and mercury.
Rökgaserna ledes från förbränningsugnen 1 via en rök- gasledning 2 till en anläggning 3 för avskiljning av gas- formiga föroreningar, såsom svaveldioxid och klorväte, och därefter till en anläggning 4 för avskiljning av partikel- formiga föroreningar (stoft). Anläggningen 3 är här en våtskrubber men kan också vara en kontaktreaktor av annat slag. Anläggningen 4 är här en spärrfilterenhet i form av ett slangfilter med textila filterslangar men kan exempel- vis också vara en elektrostatisk stoftavskiljare. Arbets- temperaturen i spärrfilterenheten är lämpligen 60-150°C.The flue gases are led from the incinerator 1 via a flue gas line 2 to a plant 3 for the separation of gaseous pollutants, such as sulfur dioxide and hydrogen chloride, and then to a plant 4 for the separation of particulate pollutants (dust). The plant 3 here is a wet scrubber but can also be a contact reactor of another kind. The system 4 here is a blocking filter unit in the form of a hose filter with textile filter hoses, but can also be an electrostatic dust collector, for example. The operating temperature in the barrier filter unit is suitably 60-150 ° C.
Från anläggningen 4 ledes rökgaserna eventuellt vidare till ytterligare behandlingsanläggningar innan de slutli- gen utsläppes i atmosfären via en skorsten (icke visad).From plant 4, the flue gases may be passed on to additional treatment plants before they are finally released into the atmosphere via a chimney (not shown).
I en förbränningsenhet 5 utföres en sotbildande för- bränning av ett bränsle med ett underskott av syre. De härvid bildade, sotbemängda rökgaserna inledes i rökgas- ledningen 2 mellan gasavskiljaren 3 och stoftavskiljaren 4. Sotpartiklarna adsorberar dioxiner och kvicksilver innan de avskiljes i stoftavskiljaren 4.In a combustion unit 5, a soot-forming combustion of a fuel with a deficit of oxygen is performed. The soot-laden flue gases thus formed are introduced into the flue gas line 2 between the gas separator 3 and the dust collector 4. The soot particles adsorb dioxins and mercury before they are separated in the dust trap 4.
Att i enlighet med uppfinningen på detta vis utföra en sotbildande förbränning och utnyttja det bildade sotet för att adsorbera dioxiner och kvicksilver är enklare och avsevärt billigare än att för detta ändamål utnyttja aktivt kol eller aktivt koks i enlighet med den ovan be- skrivna kända tekniken.According to the invention, in this way carrying out a soot-forming combustion and using the soot formed to adsorb dioxins and mercury is simpler and considerably cheaper than using activated carbon or activated coke for this purpose in accordance with the known technique described above.
Det ovan beskrivna förfarandet kan modifieras på olika sätt inom ramen för uppfinningen. Sålunda kan exem- pelvis de sotbemängda rökgaserna från enheten 5 inledas i rökgasledningen 2 mellan förbränningsugnen l och gasav- skiljaren 3. Enheten 5 kan vid speciella tillämpningar er- sättas med en i rökgasledningen 2 mellan gasavskiljaren 3 och stoftavskiljaren 4 placerad brännare, som förbränner ett därtill matat bränsle på sotbildande vis. Brännaren höjer då temperaturen i rökgasledningen 2, vilket ger den 10 15 20 25 30 35 501 158 3 fördelen att en avskiljningsgraden ökande sänkning av temperaturen i gasavskiljaren 3 kan utföras.The method described above can be modified in various ways within the scope of the invention. Thus, for example, the soot-laden flue gases from the unit 5 can be introduced into the flue gas line 2 between the incinerator 1 and the gas separator 3. The unit 5 can in special applications be replaced by a burner placed in the flue gas line 2 between the gas separator 3 and the dust separator 4, which burns a in addition, fuel is fed in a soot-forming manner. The burner then raises the temperature in the flue gas line 2, which gives it the advantage that a degree of lowering increasing the temperature in the gas separator 3 can be performed.
Claims (3)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9201232A SE501158C2 (en) | 1992-04-16 | 1992-04-16 | Ways to clean flue gases with a deficit of oxygen and formed soot |
| PCT/SE1993/000163 WO1993020926A1 (en) | 1992-04-16 | 1993-02-26 | Method for cleaning flue gases |
| AU39104/93A AU3910493A (en) | 1992-04-16 | 1993-02-26 | Method for cleaning flue gases |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9201232A SE501158C2 (en) | 1992-04-16 | 1992-04-16 | Ways to clean flue gases with a deficit of oxygen and formed soot |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE9201232D0 SE9201232D0 (en) | 1992-04-16 |
| SE9201232L SE9201232L (en) | 1993-10-17 |
| SE501158C2 true SE501158C2 (en) | 1994-11-28 |
Family
ID=20385997
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE9201232A SE501158C2 (en) | 1992-04-16 | 1992-04-16 | Ways to clean flue gases with a deficit of oxygen and formed soot |
Country Status (3)
| Country | Link |
|---|---|
| AU (1) | AU3910493A (en) |
| SE (1) | SE501158C2 (en) |
| WO (1) | WO1993020926A1 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5843205A (en) * | 1996-12-06 | 1998-12-01 | Kabushiki Kaisha Kawasaki Giken | Method of removing dioxins in a waste incineration plant |
| US8069797B2 (en) | 2003-06-03 | 2011-12-06 | Alstom Technology Ltd. | Control of mercury emissions from solid fuel combustion |
| US6848374B2 (en) | 2003-06-03 | 2005-02-01 | Alstom Technology Ltd | Control of mercury emissions from solid fuel combustion |
| US9321002B2 (en) | 2003-06-03 | 2016-04-26 | Alstom Technology Ltd | Removal of mercury emissions |
| US7766997B2 (en) | 2007-12-21 | 2010-08-03 | Alstom Technology Ltd | Method of reducing an amount of mercury in a flue gas |
| US8828341B1 (en) | 2013-07-18 | 2014-09-09 | Alstom Technology Ltd | Sulfite control to reduce mercury re-emission |
| US9120055B2 (en) | 2014-01-27 | 2015-09-01 | Alstom Technology Ltd | Mercury re-emission control |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT390206B (en) * | 1988-04-22 | 1990-04-10 | Howorka Franz | DEVICE FOR THE THERMAL DISASSEMBLY OF FLUID POLLUTANTS |
| SE466814B (en) * | 1989-06-01 | 1992-04-06 | Kvaerner Generator Ab | DEVICE FOR DEGRADATION OF GASES GENERATED FOR PRESENT BURNING AT UNGEFER 850 DEGREES C OF THE SOLID BROWN IN A LIQUID BED |
-
1992
- 1992-04-16 SE SE9201232A patent/SE501158C2/en unknown
-
1993
- 1993-02-26 WO PCT/SE1993/000163 patent/WO1993020926A1/en not_active Ceased
- 1993-02-26 AU AU39104/93A patent/AU3910493A/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO1993020926A1 (en) | 1993-10-28 |
| AU3910493A (en) | 1993-11-18 |
| SE9201232L (en) | 1993-10-17 |
| SE9201232D0 (en) | 1992-04-16 |
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