[go: up one dir, main page]

RU96118472A - METHOD FOR PROCESSING HIGH-ENRICHED URANIUM - Google Patents

METHOD FOR PROCESSING HIGH-ENRICHED URANIUM

Info

Publication number
RU96118472A
RU96118472A RU96118472/25A RU96118472A RU96118472A RU 96118472 A RU96118472 A RU 96118472A RU 96118472/25 A RU96118472/25 A RU 96118472/25A RU 96118472 A RU96118472 A RU 96118472A RU 96118472 A RU96118472 A RU 96118472A
Authority
RU
Russia
Prior art keywords
uranium
hexafluoride
fluorination
oxides
purification
Prior art date
Application number
RU96118472/25A
Other languages
Russian (ru)
Other versions
RU2112744C1 (en
Inventor
Г.П. Хандорин
А.С. Буйновский
Е.Ф. Веревкин
А.А. Гущин
А.А. Деменко
А.Н. Жиганов
А.И. Карелин
Ю.Ф. Кобзарь
В.М. Кондаков
А.М. Кораблев
В.В. Лазарчук
А.К. Ледовских
Е.П. Мариненко
В.А. Хохлов
Г.Г. Шадрин
В.И. Щелканов
Original Assignee
Сибирский химический комбинат
Filing date
Publication date
Application filed by Сибирский химический комбинат filed Critical Сибирский химический комбинат
Priority to RU96118472A priority Critical patent/RU2112744C1/en
Priority claimed from RU96118472A external-priority patent/RU2112744C1/en
Application granted granted Critical
Publication of RU2112744C1 publication Critical patent/RU2112744C1/en
Publication of RU96118472A publication Critical patent/RU96118472A/en

Links

Claims (2)

1. Способ переработки высокообогащенного урана, включающий окисление металлического урана, получение раствора уранилнитрата, его экстракционно-сорбционную очистку, денитрацию с получением оксидов урана, фторирование оксидов до гексафторида урана, пригодного для получения низкообогащенного урана, и возврат оксидов, полученных от переработки огарков, на стадию фторирования, отличающийся тем, что на фторирование направляют оксиды, полученные непосредственно на стадии окисления металлического урана, процесс фторирования ведут до остаточного содержания в огарках 10 - 25 % U от поданного на фторирование, а полученный гексафторид высокообогащенного урана направляют на доочистку от гексафторида плутония селективной сорбцией последнего на фториде натрия, при этом время контакта и температуру процесса выбирают из условий, определяемых уравнением
Figure 00000001

где Co, C - концентрация плутония в гексафториде урана до и после очистки, соответственно;
τ - время контакта гексафторида урана с сорбентом, с;
T - температура сорбента, K.
1. A method of processing highly enriched uranium, including the oxidation of metallic uranium, obtaining a solution of uranyl nitrate, its extraction and sorption purification, denitration to obtain uranium oxides, fluorination of oxides to uranium hexafluoride suitable for producing low enriched uranium, and the return of oxides obtained from processing cinder to a fluorination stage, characterized in that the oxides obtained directly from the oxidation stage of uranium metal are directed to fluorination, the fluorination process is carried out to the content in the cinders 10 - 25% U of the fluorination feed, and the obtained highly enriched uranium hexafluoride is sent to purification of plutonium hexafluoride by selective sorption of the latter on sodium fluoride, while the contact time and process temperature are selected from the conditions determined by the equation
Figure 00000001

where Co, C is the concentration of plutonium in uranium hexafluoride before and after purification, respectively;
τ is the contact time of uranium hexafluoride with the sorbent, s;
T is the temperature of the sorbent, K.
2. Способ по п.1, отличающийся тем, что сорбцию гексафторида плутония ведут при температуре 653 - 773 K. 2. The method according to claim 1, characterized in that the sorption of plutonium hexafluoride is carried out at a temperature of 653 - 773 K.
RU96118472A 1996-09-17 1996-09-17 Method of processing high-concentration uranium RU2112744C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU96118472A RU2112744C1 (en) 1996-09-17 1996-09-17 Method of processing high-concentration uranium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU96118472A RU2112744C1 (en) 1996-09-17 1996-09-17 Method of processing high-concentration uranium

Publications (2)

Publication Number Publication Date
RU2112744C1 RU2112744C1 (en) 1998-06-10
RU96118472A true RU96118472A (en) 1998-12-10

Family

ID=20185486

Family Applications (1)

Application Number Title Priority Date Filing Date
RU96118472A RU2112744C1 (en) 1996-09-17 1996-09-17 Method of processing high-concentration uranium

Country Status (1)

Country Link
RU (1) RU2112744C1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2230704C2 (en) * 2002-09-27 2004-06-20 Федеральное государственное унитарное предприятие "УРАЛЬСКИЙ ЭЛЕКТРОХИМИЧЕСКИЙ КОМБИНАТ" Method of determining impurities in solid uranium compounds and device for implementation thereof
RU2371792C2 (en) * 2007-08-20 2009-10-27 Леонид Георгиевич Бабиков Method and plant for recycling of spent nuclear fuel
RU2355641C1 (en) * 2007-12-19 2009-05-20 Открытое акционерное общество "Сибирский химический комбинат" Method of uranium hexafluoride production
RU2451639C1 (en) * 2010-09-22 2012-05-27 Открытое акционерное общество "Сибирский химический комбинат" Method of dissolving mox fuel
RU2537581C1 (en) * 2013-07-23 2015-01-10 Открытое акционерное общество "Сибирский химический комбинат" Method of processing fluorination cinder
CN113023783B (en) * 2019-12-24 2023-04-14 中核新能核工业工程有限责任公司 Method for purifying trace impurities in uranium after stacking

Similar Documents

Publication Publication Date Title
JPS5317566A (en) Denitration method for of exhaust gas
RU96118472A (en) METHOD FOR PROCESSING HIGH-ENRICHED URANIUM
RU2112588C1 (en) Method of recovering microquantities of osmium from gas phase
JPS5415496A (en) Method of improving in roasting waste hydrochloric acid
JPS5310375A (en) Treating method for exhaust gas containing nox
JPS5554532A (en) Ammonia recovering method
SE8203955D0 (en) PROCESS FOR THE REMOVAL OF POTASSIUM FROM USED ETHYLENE OXIDE CATALYSTS
JPS5423068A (en) Removing method for nitrogen oxides in exhaust gas
JPS51136595A (en) Method of clarifing exhaust gas of dry type
RU97114503A (en) METHOD OF FRACTIONAL CLEANING OF GASES FROM HARMFUL CHEMICAL AND RADIOACTIVE SUBSTANCES FORMED BY DISSOLVING SNF
RU97100297A (en) METHOD FOR CHEMICAL SEPARATION OF URANIUM ISOTOPES
JPS53113761A (en) Removing method for sulfur oxides and nitrogen oxides in exhaust gas
JPS5631427A (en) Treatment of waste gas
RU93036348A (en) METHOD FOR REMOVING SILVER / I / FROM NITRIC ACID AND THIOSULPHATE SOLUTIONS
JPS53137892A (en) Catalyzer for purifying nitrogen oxide
JPS5229467A (en) Method of removing nox
JPS53106382A (en) Simultaneous desulfurization and denitration method for exhaust gas
JPS5425262A (en) Wet system simultaneous desulfurization/denitration process
JPS5439368A (en) Method of removing nitrogen oxides from acid-atmospheric exhaust gas
JPS5358486A (en) Simultaneous treating method for desulfurization and denitration of flue gas
BG43237A1 (en) Apparatus for performing conversion of ammonium sulphite- bisulphite solutions with nitric acid in ammonia- acid method for purifying of flue gases
JPS5378998A (en) Gypsum recovering method in exhaust gas desulfurization process
JPS5328567A (en) Desulfurization and denitration method by wet process
JPS54128975A (en) Removing method for nitrogen oxides
JPS53115686A (en) Process for producing highly activated denitrating catalyst