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RU94026996A - Method of sorbent production - Google Patents

Method of sorbent production

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Publication number
RU94026996A
RU94026996A RU94026996/26A RU94026996A RU94026996A RU 94026996 A RU94026996 A RU 94026996A RU 94026996/26 A RU94026996/26 A RU 94026996/26A RU 94026996 A RU94026996 A RU 94026996A RU 94026996 A RU94026996 A RU 94026996A
Authority
RU
Russia
Prior art keywords
oxyhydrate
sorbents
bichromate
potassium
iron
Prior art date
Application number
RU94026996/26A
Other languages
Russian (ru)
Other versions
RU2082494C1 (en
Inventor
Ю.И. Сухарев
И.Ю. Сухарева
Я.Н. Лепп
Original Assignee
Ассоциация "Институт химических проблем промышленной экологии АЕН РФ"
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ассоциация "Институт химических проблем промышленной экологии АЕН РФ" filed Critical Ассоциация "Институт химических проблем промышленной экологии АЕН РФ"
Priority to RU94026996A priority Critical patent/RU2082494C1/en
Publication of RU94026996A publication Critical patent/RU94026996A/en
Application granted granted Critical
Publication of RU2082494C1 publication Critical patent/RU2082494C1/en

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  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

FIELD: inorganic chemistry, methods to produce sorbents, that are used in hydraulic metallurgy of non-ferrous and rare-earth metals and for purification of corresponding works industrial waters in particular, that is for production of oxyhydrate sorbents. SUBSTANCE: method to produce sorbent, that has metal oxyhydrate, provides for its settling in the form of hydrogel using interaction of metal salt with alkaline in presence of organic substance, its holding and filtering with following drying and granulating of ready-made product. Water soluble trivalent iron salt reacts with alkaline. Reaction between initial substances is carried out in low concentration alkaline solution. Then bichromate of potassium is added. Bichromate of potassium is taken in molar ratio to iron equal to (0.1 - 0.125) : 1. As organic substance nitryltrimethylphosphonic acid is used with molar ratio to iron equal to (0.01 - 0.07) : 1. After addition of nitryltrimethylphosphonic acid value of pH is raised to 3.5 - 4.5 with following washing potassium bichromate out using ammonia solution. EFFECT: improved process. 1 tbl

Claims (1)

Изобретение относится к неорганической химии, в частности к способам получения сорбентов, которые могут быть использованы в гидрометаллургии цветных и редких металлов, а также при очистке сточных вод соответствующих заводов, а именно к способам получения оксигидратных сорбентов. Способ получения сорбента, содержащего оксигидрат металла, включает его осаждение в виде гидрогеля путем взаимодействия соли металла со щелочью в присутствии органического вещества, его выдержку и фильтрацию с последующей сушкой и гранулированием готового продукта. Во взаимодействие со щелочью вступает растворимая в воде соль трехвалентного железа, реакцию между исходными веществами ведут в слабощелочной среде, затем добавляют калий двухромовокислый в молярном отношении хрома к железу, равном 0,1-0,125:1, в качестве органического вещества используют нитрилтриметилфосфоновую кислоту при молярном отношении к железу, равном 0,01-0,07:1, а после добавления нитрилтриметилфосфоновой кислоты доводят рН до 3,5-4,5 с последующим вымыванием бихромата калия раствором аммиака.The invention relates to inorganic chemistry, in particular to methods for producing sorbents that can be used in the hydrometallurgy of non-ferrous and rare metals, as well as in wastewater treatment of the corresponding plants, and in particular to methods for producing oxyhydrate sorbents. A method of obtaining a sorbent containing metal oxyhydrate, includes its precipitation in the form of a hydrogel by reacting a metal salt with an alkali in the presence of organic matter, its exposure and filtration, followed by drying and granulation of the finished product. A water-soluble ferric salt enters into interaction with alkali, the reaction between the starting materials is carried out in a slightly alkaline medium, then potassium dichromate is added in a molar ratio of chromium to iron equal to 0.1-0.125: 1, nitrile trimethylphosphonic acid is used as an organic substance in molar the ratio to iron, equal to 0.01-0.07: 1, and after adding nitrile trimethylphosphonic acid, the pH is adjusted to 3.5-4.5, followed by leaching of potassium dichromate with ammonia solution.
RU94026996A 1994-07-18 1994-07-18 Method of preparing sorbent RU2082494C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU94026996A RU2082494C1 (en) 1994-07-18 1994-07-18 Method of preparing sorbent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU94026996A RU2082494C1 (en) 1994-07-18 1994-07-18 Method of preparing sorbent

Publications (2)

Publication Number Publication Date
RU94026996A true RU94026996A (en) 1996-07-10
RU2082494C1 RU2082494C1 (en) 1997-06-27

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU94026996A RU2082494C1 (en) 1994-07-18 1994-07-18 Method of preparing sorbent

Country Status (1)

Country Link
RU (1) RU2082494C1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115646427A (en) * 2022-10-27 2023-01-31 江西鑫泰功能材料科技有限公司 Preparation method of hydrated rare earth oxide adsorbent for arsenic removal

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2255801C1 (en) * 2003-12-22 2005-07-10 Государственное образовательное учреждение высшего профессионального образования "Пермский государственный технический университет" Sorbent for separating heavy metal ions from drinking water and a method for preparation thereof
RU2261757C1 (en) * 2004-08-20 2005-10-10 Общество с ограниченной ответственностью Научно-производственная экологическая фирма "ЭКО-технология" Method of production of granulated inorganic sorbents on base of oxyhydrates of metals
RU2289474C1 (en) * 2005-08-31 2006-12-20 Государственное образовательное учреждение высшего профессионального образования "Южно-Уральский государственный университет" Process of preparing sorbents based on metal oxyhydrate gels

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115646427A (en) * 2022-10-27 2023-01-31 江西鑫泰功能材料科技有限公司 Preparation method of hydrated rare earth oxide adsorbent for arsenic removal
CN115646427B (en) * 2022-10-27 2024-06-04 江西鑫泰功能材料科技有限公司 Preparation method of hydrous rare earth oxide adsorbent for removing arsenic

Also Published As

Publication number Publication date
RU2082494C1 (en) 1997-06-27

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