RU2677882C1 - Biologically active zeolite-containing additive, used as component of cosmetic means for hair coloring and cosmetic means for coloring hair on its basis - Google Patents

Abstract

FIELD: cosmetology.

SUBSTANCE: invention relates to the field of cosmetology and is a biologically active zeolite-containing additive used as a component of a cosmetic for hair dye and containing a zeolite previously ground to a particle size of 0.01–10 microns, characterized in that it contains a modified zeolite as a zeolite, which is additionally enriched in Na cations when immersed in a 5–12 % aqueous solution of sodium chloride, followed by the removal of chlorine anions by washing with water, filtration and drying, in one part of the dry ground mass of the modified zeolite, Na cations are replaced by silver or gold cations, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc or iron by treating with 10–20 % aqueous solution of inorganic salts of these metals, followed by removal of sodium salts, drying and grinding, and the rest of the dry ground mass of the modified zeolite, enriched in Na cations, is mixed in a ratio from 1:2 to 2:1 with the first part of the dry ground mass of a modified zeolite enriched in silver cations, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron.

EFFECT: invention provides an increase in the effectiveness of the cosmetic effect of a zeolite-containing additive on hair, skin and on plant components, enhancing their coloring and cosmetic properties for hair care, namely coloring and strengthening hair.

4 cl, 22 ex

Description

The invention relates to cosmetic additives that provide, when using herbal products for the care of the scalp and hair, good coloring properties and positive dermatological effects and can be used in cosmetics, as well as in the perfumery and cosmetic industry.

Known chemical means for dyeing hair, containing in a suitable dyeing medium, at least one direct cationic dye and at least one self-oxidizing dye (RF Patent No. 2168978, IPC A61K 7/13, published on 06/20/2001 [1]) . All of them, as a rule, consist of substances artificially synthesized. Chemical dyes, despite the fact that they require less time for dyeing, provide a natural hair color, have a large number of colors and shades that are resistant to water and shampoo, can lead to hair loss and brittleness.

Vegetable dyes are known (henna, basma, chamomile, etc.) (Friedman R. Cosmetics. 1959), the use of which favorably affects the scalp and hair.

The disadvantage of these funds is that they do not provide good coloring and positive dermatological properties, because after drying and grinding, the positive properties of plant materials are significantly reduced.

A known method of improving the coloring properties of herbal remedies, based on the fact that the plant material after drying is mixed with an additive consisting of soap pre-ground to a powder state and tea extract. Then the mixture is stirred for 10-15 minutes while heating to plus 95-100 ° C and sharply cooled to plus 20-25 ° C, stirred again for 3-5 minutes and tableted (USSR author's certificate No. 648226, IPC A61K 7 / 13, publ. 1972). The tablet preparation has good coloring properties.

The disadvantage of this method is the time-consuming technological process required of a large investment of time, energy and special technological equipment.

The closest technical solution (prototype) is the use of natural zeolite, previously crushed to a particle size of 0.01-10 microns as an additive to crushed and dried vegetable raw materials used as a hair dye (RF patent No. 2145841, IPC A61K 8/00, publ. 02/27/2000). Zeolite-containing additive is used in an amount of 30-50 wt. % by weight of the herbal remedy and provides an improvement in the coloring and therapeutic properties of herbal remedies for scalp and hair care in a simpler and more environmentally friendly way.

Typically, in a decoction of infusion or extract, large alkaloids - molecular formations responsible for the coloring properties, which are polymer molecules of active substances, turn into an inactive state, folded into a ball. Moreover, a significant part of their active centers does not come into contact with the object (skin, hair) of the exposure. In order to expand these molecules, either high temperatures (above 100 ° C) or special conditioners are needed, which play the role of catalysts that accelerate and enhance the biochemical effect.

The introduction of zeolite can improve the coloring and positive dermatological properties of plant products due to the fact that zeolites have selective adsorption properties (Tsitsishvili G.A., Adronikashvili T.G., Kirov G.N., Filizova L.D. Natural zeolites, M Chemistry, 1985 [3]) of positively charged ions, as well as ammonium ions and nitrogen-containing groups that make up plant alkaloids (T. Robinson. The biochemistry of alkaloid. Second edition. Springer, New York, 1981 [4]) . When zeolite particles are mixed with particles of herbal remedies, alkaloids are sorbed on the surface of zeolite crystals by their positively charged atomic groups, and thus their ordering and separation occurs. This process occurs at any humidity of the environment and mixed components. The process of ordering large molecules on the surface of clay minerals and zeolites, as is known (M. Calvin. Chemical evolution. Moscow, Moscow, 1971 [5]), modifies their chemical activity upward. This leads to an increase in the ability of alkaloids to act on the hair and scalp, which is manifested in the uniformity of hair color and in an increase in the therapeutic effect of medicinal herbs in the treatment of skin disorders.

In addition, for the effective ordering of molecules, it is necessary to increase the surface or reduce the particle size of the introduced zeolite, but the particle size must remain much larger than the size of the alkaloids. This is achieved by grinding zeolite in powder, the grinding fraction of 0.01-10 microns.

The most effective and cheap zeolite can be well-known and used in industry natural heylandite-clinoptilolite tuffs (heylandite, clinoptillolite-zeolites).

Another closest analogue (prototype) is a cosmetic mask (RF patent No. 2192845, IPC A61K 7/48, publ. November 20, 2002) containing mechanochemically ground medicinal plant material, cosmetic bactericidal zeolite-containing additive, rye and wheat bran powder in the following the ratio of components per 100 g of dry matter, g:

Zeolite-containing bactericidal cosmetic additive - 40

Rye bran - 20

Wheat bran - 20

Herbal Medicine Powder - 20

However, in the known analogues (the above prototypes), the action of the zeolite-containing additives and cosmetic plant components for the care of the scalp and hair are not effective enough.

The technical result of the claimed invention is to increase the effectiveness of cosmetic herbal ingredients for scalp and hair care and a zeolite-containing additive due to the preliminary enrichment of the Na-form zeolite of this additive with Na ⁺ ions, which ensures higher activation of the zeolite due to an increase in its exchange capacity due to an increase in the total the amount of Na ⁺ ions capable of further ion exchange, as well as due to the content of other metal ions in the additive, providing greater its high bioactivity.

The specified technical result is achieved by the fact that in a biologically active zeolite-containing additive that improves the action of cosmetic plant components for scalp and hair care and contains zeolite, previously crushed to a particle size of 0.01-10 microns, according to the invention, it contains as zeolite modified zeolite, additionally enriched with Na cations when immersed in a 5-12% aqueous solution of sodium chloride, followed by removal of chlorine anions by washing with water, filtration and drying which, moreover, in one part of the dry ground mass of the modified zeolite, Na cations are replaced by cations of silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron by treatment with a 10-20% aqueous solution of inorganic salts of these metals, followed by removal of sodium salts, drying and grinding, and the other remaining part of the dry ground mass of the modified zeolite enriched with Na cations is mixed in a ratio of 1: 2 to 2: 1 with the first part of the dry ground mass of the modified cet an olite enriched in cations of silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron.

In addition, silver nitrate, or gold chloride, or platinum chloride, or copper sulfate, or calcium chloride, or magnesium chloride, or potassium chloride, or zinc chloride, or iron chloride are used as inorganic salts.

The specified technical result is also achieved by the fact that in a cosmetic product for dyeing hair of the head containing vegetable dye, a zeolite-containing additive and a powder of coloring tinted plant materials, according to the invention, as a zeolite-containing additive, the product contains a biologically active modified zeolite-containing additive according to 1, 2 formulas in the following quantitative content of components (wt.%):

biologically active zeolite-containing PP supplement 1, 2 formulas 10.0-20.0 vegetable paint 25.0-70.0 tinting powder vegetable raw materials the rest is up to 100%.

As a vegetable paint, the cosmetic product contains lavanzia leaf powder (henna), and as a powder of coloring tinted vegetable raw materials, an indigofer (basma) leaf, or coffee powder, or cocoa powder, or chamomile powder.

The specified technical result is also achieved by the fact that in a cosmetic product in the form of a mask for facial skin care, containing mechanochemically ground vegetable raw materials and an additive in the form of zeolite powder, according to the invention, the agent further comprises guar or xanthan gum, and as a zeolite powder - modified zeolite by pp 1, 2 formulas with the following content of components, mass. %:

modified zeolite by item 1, 2 formulas 10.0-40.0 guar or xanthan gum 0.5-1.0 mechanochemically ground vegetable raw materials the rest is up to 100%.

The introduction of modified zeolite allows to improve the coloring and positive dermatological properties of plant products to a greater extent due to the fact that the modified zeolite in the inventive additive has higher selective properties for the adsorption of positively charged ions, as well as ammonium ions and nitrogen-containing groups that are part of plant alkaloids. When particles of a modified zeolite are mixed with particles of plant products, alkaloids are sorbed on the surface of zeolite crystals by their positively charged atomic groups, and thereby their higher ordering and separation. Moreover, the modified zeolite increases to a greater extent the chemical activity of plant alkaloids. This leads to an increase in the ability of alkaloids to act on the hair and scalp, which is manifested in a higher uniformity of hair color and an increase in the therapeutic effect of medicinal herbs in the treatment of skin disorders.

The increase in the effectiveness of cosmetic effects on the skin and hair coloring is due to the higher ability of the claimed modified zeolite-containing additives to bind on its surface biochemically active organic cations - plant alkaloids, traditionally used in cosmetology. These include nettle, chamomile, sage, etc., as well as natural dyes - henna, basma, coffee and cocoa. The cosmetic bactericidal zeolite-containing additive uses the property of active alkaloids to be distributed in an oriented layer on the surface of the zeolite ion exchanger. Under the influence of the surface potential of the zeolite, the molecules of active substances pass from twisted disordering to expanded, oriented, and ordered. In this case, the maximum (higher) degree of chemical activity of oriented molecules is achieved, and their positive effect on the skin and hair is significantly enhanced. The bactericidal effect of the additive is provided by trace elements - copper, silver, zinc, gold, platinum, calcium, potassium, magnesium, iron.

In addition, a modified cyolite-containing additive increases the degree of skin cleansing from ions harmful to it, such as lead, cesium and other heavy metal ions (including radioactive isotopes), as well as ammonium ions and other ammonium bases responsible for the existence of a specific smell of human skin, improving its nutrition through the delivery of macro- and microelements, as well as hygienic processing of the skin by increasing the biocidal properties of the lithocomplex and cosmetics based on it.

A method of preparing a biologically active zeolite-containing additives and cosmetics based on it for dyeing scalp hair and for cleaning and hygienic treatment of the skin. To prepare a biologically active zeolite-containing additive, the zeolite in the sodium form of heylandite or clinoptilolite k is pre-modified. To do this, the indicated zeolite, for example, in an amount of 50 g is poured with a 5-12% aqueous NaCl solution, kept in this solution for 18 hours, thereby additionally enriching the zeolite with sodium ions. Then, repeated washing is performed to remove chlorine ions and subsequent filtration through a “white tape” filter. The resulting semi-finished product is dried. Next, the mass of the modified zeolite is divided into two parts.

In one (first) part of the dry ground mass of the modified zeolite, Na cations are replaced by cations of silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron by treatment with a 10-20% aqueous solution of inorganic salts specified metals. As inorganic salts, silver nitrate, or gold chloride, or platinum chloride, or copper sulfate, or calcium chloride, or magnesium chloride, or potassium chloride, or zinc chloride, or ferric chloride are used. The process of repeated modification of the zeolite was carried out by exposure to an aqueous solution of metal salts for 20 hours. The modification process was carried out at elevated temperature, preferably at 60 ° C. The obtained retrofitted semi-finished product was repeatedly washed to remove sodium salts, filtered and dried at a temperature of 70-80 ° C. The consumption of aqueous solutions for processing 50 g of modified zeolite was: zeolite: aqueous solution as 1:20. After drying, the product was subjected to dispersion grinding using a ball mill. Examination of particles by electron microscope showed a dispersion of their size from 10 nm to 1 μm.

Next, the second remaining part of the dry ground mass of the modified zeolite enriched in Na cations is mixed in a ratio of 1: 2 to 2: 1 with the first part of the dry ground mass of the modified zeolite enriched in cations of silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron.

Below are examples of 1-3 compositions of dry powdered modified zeolite-containing additives with a particle size of 0.01 to 10 microns.

Example 1. (wt.%):

dry ground mass of modified enriched zeolite Na cations 33,4 dry ground mass modified zeolite, enriched with silver cations, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron 66.6

Example 2. (wt.%):

dry ground mass of modified enriched zeolite Na cations 50,0 dry ground mass modified zeolite, enriched with silver cations, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron 50,0

Example 3. (wt.%):

dry ground mass of modified enriched zeolite Na cations 66.6 dry ground mass modified zeolite, enriched with silver cations, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron 33,4

A method of obtaining a cosmetic product for dyeing scalp hair. For this, vegetable paint is mixed in a reactor in an amount of 25.0-70.0 wt. %, powder coloring tinted plant materials - 10.0-65.0 wt. % and dry powdered modified biologically active zeolite-containing additive (clinoptillolite or heilandite) with a particle size of 0.01-10 microns, enriched with cations of sodium, silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc , or iron in an amount of 10.0-20.0 wt. % As a vegetable paint, the cosmetic product contains lavanzia leaf powder (henna), and as a powder of coloring tinted vegetable raw materials, an indigofer (basma) leaf, or coffee powder, or cocoa powder, or chamomile powder.

Below are examples of 4-10 formulations of a cosmetic product based on a modified zeolite-containing hair dye supplement. The proposed composition for dyeing hair of the head can be used to obtain seven types of shades of hair: red-red, bronze, chestnut, black, mahogany, reddish-brown, bright golden.

Example 4. Color red-red (wt.%):

vegetable paint (lavzania leaf powder) 70.0 modified biologically active zeolite-containing additive (example 1), enriched cations of sodium, silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron 20,0 tinting powder plant materials (leaf powder of indigofer) 10.0

Example 5. The color of bronze (wt.%):

vegetable paint (lavzania leaf powder) 50,0 modified biologically active zeolite-containing additive (example 2), enriched cations of sodium, silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron 20,0 tinting powder plant materials (leaf powder of indigofer) 30,0

Example 6. The color of chestnut (wt.%):

vegetable paint (lavzania leaf powder) 40,0 modified biologically active zeolite-containing additive (example 3), enriched cations of sodium, silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron 20,0 tinting powder plant materials (leaf powder of indigofer) 40,0

Example 7. Color black (wt.%):

vegetable paint (lavzania leaf powder) 25.0 modified biologically active zeolite-containing additive (example 2), enriched cations of sodium, silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron 15.0 tinting powder plant materials (leaf powder of indigofer) 60.0

Example 8. Color mahogany (wt.%):

vegetable paint (lavzania leaf powder) 68.0 modified biologically active zeolite-containing additive (example 2), enriched cations of sodium, silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron 20,0 tinting powder plant materials (cocoa powder) 12.0

Example 9. The color is reddish-brown (wt.%):

vegetable paint (lavzania leaf powder) 68.0 modified biologically active zeolite-containing additive (example 2), enriched cations of sodium, silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron 20,0 tinting powder vegetable raw materials (coffee powder) 12.0

Example 10. The color is bright golden (wt.%):

vegetable paint (lavzania leaf powder) 68.0 modified biologically active zeolite-containing additive (example 2), enriched cations of sodium, silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron 20,0 tinting powder plant materials (chamomile inflorescences) 12.0

Example. 11. The method of applying the composition for dyeing hair with any composition according to example 4-10.

Before dyeing, the hair must be washed, dried with a towel, combed thoroughly. Dilute the required amount of paint with hot water at a temperature not exceeding 80 ° C and mix thoroughly to the state of liquid slurry. Color the strand after strand with quick movements so that the pulp does not cool. The composition is applied first to the hair roots with a thin layer, and then to all hair. After applying the paint to the scalp and hair, tie the hair with plastic wrap or parchment paper dampened with hot water, wrap the head in a towel and give the desired temporary exposure. After that, the hair should be washed well with warm water without the use of detergents and finally rinsed with water, acidified with vinegar, citric acid or lemon juice.

The required amount of composition for dyeing depends on the length and density of the hair and 25 to 100 g of paint is required.

The exposure time depends on the desired color, as well as on the structure of the hair, its original color. Blonde hair can withstand from 5 to 10 minutes, dark from 30-40 minutes, black from 1 to 1.5 hours. The proposed composition is a natural (100%) product, so the exposure time can be increased if desired to obtain an intense color to 4 -7 hours

It is recommended to dye your hair at least 1 time per month. When dyeing gray hair, to obtain good dyeing, you need to repeat the procedure 1 time per week for a month, and then dye your hair 1 time per month.

The proposed composition for dyeing scalp hair was used by 60 women aged 25 to 60 years 1 time per week for 30 days. In this case, none of the subjects had an irritating or allergic effect.

The tests showed that when adding a modified zeolite-containing additive (clinoptilolite tuff) to a herbal remedy - henna, the coloring properties are significantly improved. The dyed hair acquires a darker, brilliant, chestnut hue, a higher density of the dyed hair is visible on the electron microscopic images, there are no effects of surface damage and splitting of the ends of the hair, which occurs during normal chemical coloring. The use of a complex of chamomile with zeolite gives the hair a darker, shiny, yellow shade.

Studies have shown that the proposed composition for dyeing hair gives the hair a natural shine, improves the structure, strengthens the roots and adds volume, paints over the gray hair and does not wash off for a long time. Effective for dry, brittle hair, peeling, loss and dandruff, cure hair and relieve irritation. Composition for dyeing the hair of the head envelops the upper layers of the hair, therefore, does not change or violate their structure during dyeing, making it soft and safe.

A method of obtaining a cosmetic product in the form of a mask for facial skin care. To do this, mechanochemically ground vegetable raw materials are mixed in a reactor in an amount of 59.0-89.5 wt.%; guar or xanthan gum - 0.5-1.0 wt. % and dry powdered biologically active zeolite-containing additive (clinoptillolite) with a particle size of 0.01 - 10 microns, enriched with cations of sodium, silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron in the amount of 10.0-40.0 wt. %

Example 12. A mask to restore aging skin and prevent the formation of wrinkles. The raw plant powder contains wheat and rye bran, hanging birch leaves, medicinal dandelion leaves, odoriferous inflorescences, dioecious nettle leaves, hop cones, mountain arnica inflorescences, peppermint grass, rose petals, white lily petals, white acacia flowers, lily of the valley flowers at the following content of all components of the product, wt. %:

Dry powder of a modified zeolite-containing additive,

enriched with sodium and calcium ions - 30.0

guar gum - 0.5

Rye bran - 25.0

Wheat bran - 24.5

Collection of medicinal herbs - 20.0

of them:

Drooping birch leaves - 1.5

Leaves of dandelion officinalis - 1.5

Odorous chamomile inflorescences - 1.5

Stinging nettle leaves - 1.5

Hop Cones - 1.5

Inflorescences of mountain arnica - 0.5

Peppermint herb - 0.5

Rose Petals - 0.3

White Lily Petals - 0.4

White Acacia Flowers - 0.4

May lily of the valley flowers - 0.4

Example 13. Mask for skin restoration of the eyelids. The plant raw material powder contains wheat and rye bran, linden blossom, pharmacy chamomile, parsley, dill, sage, blue cornflower flowers, hop cones in the following contents of all components of the product, wt. %:

Dry powder of a modified zeolite-containing additive,

enriched with sodium and gold ions - 10.0

guar gum - 0.5

Rye bran - 35.0

Wheat bran - 34.5

Collection of medicinal herbs - 20.0

of them:

Lime blossom - 0.2

Chamomile pharmacy - 0.2

Parsley - 1.5

Dill - 1.5

Sage - 1.0

Cornflower Blue Flowers - 1.0

Hop Cones - 1.0

Example 14. A mask for improving complexion. The raw vegetable powder contains: wheat and rye bran, rose hips, nettle leaves, hypericum, linden flowers, thyme leaves, fireweed leaves, blackcurrant leaves, carrot seeds, blackberry leaves, wild strawberry leaves, raspberry leaves, rowan fruits in the following components of the tool, wt. %:

Dry powder of a modified zeolite-containing additive,

enriched with sodium and platinum ions - 20.0

Xanthan Gum - 1.0

Rye bran - 30.0

Wheat bran - 29.0

Herb picking - 20.0

of them:

Rosehip, fruits - 1.0

Nettle Leaves - 1.0

Hypericum leaves - 1.0

Linden flowers - 1.0

Thyme Leaves - 1.0

Fireweed Leaves - 1.0

Blackcurrant leaves - 1.0

Carrot Seeds - 0.6

Blackberry Leaves - 0.6

Strawberry Leaves - 0.6

Raspberry leaves - 0.6

Rowan fruits - 0.6

Example 15. A mask against wilting and aging of the skin and for the rehabilitation of the skin after cosmetic injuries. The raw plant powder contains wheat and rye bran, St. John's wort perforated, mountain arnica inflorescences, large plantain leaves, pharmaceutical chamomile inflorescences, peppermint leaves, rose petals, ordinary flax seeds, dioecious nettle leaves, common thyme grass, all eucalyptus means, wt. %:

Dry powder of a modified zeolite-containing additive,

enriched with sodium and copper ions - 20.0

Xanthan Gum - 1.0

Rye bran - 30.0

Wheat bran - 29.0

Herb picking - 20.0

of them:

Hypericum perforatum, grass - 2.0

Arnica mountain, inflorescences - 2.0

Large plantain, leaves - 2.0

Chamomile pharmaceutical, inflorescences - 2.0

Peppermint, leaves - 2.0

Rose, petals - 2.0

Flax ordinary, seeds - 2.0

Stinging nettle, leaves - 2.0

Thyme, grass - 2.0

Rod Eucalyptus - 2.0

Example 16. Mask for the regeneration of the skin of any type. Powder of plant materials contains wheat and rye bran, chamomile, yarrow, horsetail, peppermint, sage with the following content of all components of the product, wt. %:

Dry powder of a modified zeolite-containing additive,

enriched with sodium and magnesium ions - 20.0

Xanthan Gum - 1.0

Rye bran - 30.0

Wheat bran - 29.0

Herb picking - 20.0

of them:

Chamomile pharmacy - 2.0

Yarrow - 2.0

Horsetail -1.5

Peppermint - 1.5

Sage - 1.5

Example 17. A mask for nourishing porous and sagging skin. The raw plant powder contains wheat and rye bran, perforated St. John's wort grass, leaves of coltsfoot ordinary, wormwood grass, common dandelion grass, yarrow grass, fruits and leaves of mountain ash with the following contents of all components of the product, wt. %:

Dry powder of a modified zeolite-containing additive,

enriched with sodium and zinc ions - 20.0

Xanthan Gum - 1.0

Rye bran - 30.0

Wheat bran - 29.0

Herb picking - 20 g

of them:

Hypericum perforatum herb - 2.0

Leaves of coltsfoot - 2.0

Common wormwood, grass - 1.5

Common dandelion, grass - 1.5

Yarrow, grass - 1.5

Fruits and leaves of mountain ash - 1.5

Example 18. Mask for hair restoration. The plant material powder contains wheat and rye bran, burdock root, calamus root, marigold flowers, hop cones in the following contents of all components of the product, wt. %:

Dry powder of a modified zeolite-containing additive,

enriched with sodium and iron ions - 20.0

Xanthan Gum - 1.0

Rye bran - 30.0

Wheat bran - 29.0

Herb picking - 20.0

of them:

Burdock Root - 3.0

Calamus root - 3.0

Marigold flowers - 1.5

Hop cones - 2.5

Example 19. Mask for the whitening effect of the skin. Powder of plant materials contains wheat and rye bran, hop cones in the following contents of all components of the product, wt. %:

Dry powder of a modified zeolite-containing additive,

enriched with sodium and potassium ions - 40.0

Guar gum - 0.5

Rye bran - 20.0

Wheat bran - 19.5

Herb picking - 20.0

of them:

Hop cones - 20.0

Example 20. Anti-inflammatory mask. The raw plant powder contains wheat and rye bran, hanging birch leaves, medicinal dandelion leaves, odoriferous inflorescences, dioecious nettle leaves, hop cones, mountain arnica inflorescences, peppermint grass, rose petals, white lily petals, white acacia flowers, lily of the valley flowers at the following content of all components of the product, wt. %:

Dry powder of a modified zeolite-containing additive,

enriched with sodium and silver ions - 40.0

guar gum - 0.5

Rye bran - 20.0

Wheat bran - 19.5

Collection of medicinal herbs - 20.0

of them:

Drooping birch leaves - 1.5

Leaves of dandelion officinalis - 1.5

Odorous chamomile inflorescences - 1.5

Stinging nettle leaves -1.5

Hop Cones - 1.5

Inflorescences of mountain arnica - 0.5

Peppermint herb - 0.5

Rose Petals - 0.3

White Lily Petals - 0.4

White Acacia Flowers - 0.4

May lily of the valley flowers - 0.4

Studies have shown that masks activate metabolism and oxygen, accelerate tissue regeneration. Masks nourish, moisturize, disinfect the skin, tighten pores and have a high cleansing effect, dissolving and adsorbing impurities. Masks are easy to use.

Example 21. The method of applying a nourishing mask for the skin of the face and neck with any plant set 12-17, 19 and 20.

A mask weighing 3 g is placed in a bowl and poured with an equal volume of hot water (60-70 ° C), mix thoroughly to a pulp consistency and a still warm mask (38-40 ° C) is applied to the face and neck. After drying, which is an average of 15 minutes, the mask is washed off with warm water, after which the face is softened with a soft cloth.

The proposed masks were used by 40 women aged 20 to 55 years 1 time per week for 30 days. In this case, none of the subjects had an irritating or allergic effect. Masks cleansed the skin, eliminated peeling, and had an anti-inflammatory effect. After applying the masks, the skin became smooth, supple, fresh. After 2-3 procedures, the grease of the skin decreased, small wrinkles were slightly smoothed out. It is recommended to use the proposed mask 1 time in 5-6 days for a course of 25 masks.

Example 22. The method of applying a nourishing mask for hair restoration with a herbal set according to example 18.

A mask weighing 25 g is placed in a bowl and poured with an equal volume of hot water (60-70 ° C), mix thoroughly to a pulp consistency and a still warm mask (38-40 ° C) is applied to the hair roots on the head. The soft movements of the fingers rub the mask into the scalp and spread it over the entire surface of the head and hair. They cover their heads with a waterproof and heat-insulating bag and are in this state for at least 15 minutes. Then the hair is washed with warm water. It is recommended to use the proposed mask once every 6-7 days for a course of 25 masks.

The proposed mask was used by 30 women aged 30-40 years 1 time per week for 30 days. Hair acquired a darker, brilliant shade. Electron microscopic images did not reveal the effects of damage to the surface of the hair.

In the process of cheap processing of raw materials using mechanical mills, biologically active substances are almost completely preserved in the final product, their bioavailability and consumer qualities increase. The fraction of mechanochemically ground plant material obtained using mechanical mills is determined in the range of 10-20 microns. The addition of a modified zeolite-containing additive leads to an improvement in the dermatological properties of herbal remedies due to the fact that the modified zeolite has higher selective adsorption properties. Modification of the additive by the method gives the cosmetic mask higher bactericidal properties.

Claims (5)

1. A biologically active zeolite-containing additive used as a component of a hair dye cosmetic product and containing a zeolite preliminarily ground to a particle size of 0.01-10 μm, characterized in that it contains a modified zeolite as a zeolite, enriched additionally with Na cations by immersion in a 5-12% aqueous solution of sodium chloride, followed by removal of chlorine anions by washing with water, filtration and drying, and in one part of the dry ground mass of the modified zeolite cation Na s are replaced by cations of silver, or gold, or platinum, or copper, or calcium, or potassium, or magnesium, or zinc, or iron by treatment with a 10-20% aqueous solution of inorganic salts of these metals, followed by removal of sodium salts, drying and grinding and the other remaining part of the dry ground mass of the modified zeolite enriched in Na cations is mixed in a ratio of 1: 2 to 2: 1 with the first part of the dry ground mass of the modified zeolite enriched in cations of silver, or gold, or platinum, or copper, or calcium , Whether the potassium or magnesium, or zinc, or iron. 2. The additive according to claim 1, characterized in that as inorganic salts use silver nitrate, or gold chloride, or platinum chloride, or copper sulfate, or calcium chloride, or magnesium chloride, or potassium chloride, or zinc chloride, or chloride gland. 3. Cosmetic hair dye containing vegetable dye, zeolite-containing additive and powder coloring dyeing plant materials, characterized in that as a zeolite-containing additive it contains a biologically active modified zeolite-containing additive in the following quantitative content of components, wt. %: biologically active modified zeolite-containing additive 10.0-20.0 vegetable paint 25.0-70.0 tinting powder vegetable raw materials the rest is up to 100% 4. The tool according to p. 3, characterized in that it contains henna leaf powder as a vegetable paint, and indigofer (basma) leaf, or coffee powder, or cocoa powder, or chamomile powder as a coloring powder of plant raw materials.