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RU2642608C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2642608C1
RU2642608C1 RU2017103802A RU2017103802A RU2642608C1 RU 2642608 C1 RU2642608 C1 RU 2642608C1 RU 2017103802 A RU2017103802 A RU 2017103802A RU 2017103802 A RU2017103802 A RU 2017103802A RU 2642608 C1 RU2642608 C1 RU 2642608C1
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RU
Russia
Prior art keywords
glaze
sno
zno
sio
coating
Prior art date
Application number
RU2017103802A
Other languages
Russian (ru)
Inventor
Юлия Алексеевна Щепочкина
Original Assignee
Юлия Алексеевна Щепочкина
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2017103802A priority Critical patent/RU2642608C1/en
Application granted granted Critical
Publication of RU2642608C1 publication Critical patent/RU2642608C1/en

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/4505Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
    • C04B41/4523Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application applied from the molten state ; Thermal spraying, e.g. plasma spraying
    • C04B41/4527Plasma spraying
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • C04B41/5023Glass-ceramics
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5031Alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5033Chromium oxide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/87Ceramics

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  • Glass Compositions (AREA)

Abstract

FIELD: construction.
SUBSTANCE: invention relates to the technology of silicates, in particular to glaze compounds that can be used for applying to articles made of faience, majolica. Glaze contains the following, wt %: SiO2 3.0–4.0; Al2O3 52.5–53.4; K2O 5.0–6.0; B2O3 7.0–8.5; Cr2O3 15.0–20.0; SnO2 4.0–5.0; ZnO 7.0–10.0. Finely dispersed components weighed in the required ratios (residue on sieve No. 008 is not more than 5 %) are mixed. Resulting mixture is sprayed onto the surface of ceramic products in a stream of low-temperature plasma, and a glass-crystalline coating with small structure defects (micropores, gas inclusions) is formed.
EFFECT: technical result is higher heat resistance of coating.
1 cl, 1 tbl

Description

Изобретение относится к технологии силикатов, в частности к составам глазурей, которые могут быть использованы для нанесения на изделия из фаянса, майолики.The invention relates to the technology of silicates, in particular to compositions of glazes that can be used for application to faience, majolica.

Известна глазурь, содержащая, мас. %: SiO2 54,98-56,7; Al2O3 9,4-10,45; Fe2O3 0,05-0,2; СаО 10,0-10,75; MgO 0,01-0,1; Na2O 0,05-0,2; K2O 6,71-7,0; B2O3 10,9-11,3; Cr2O3 0,9-1,3; SnO2 4,5-5,0 [1].Known glaze containing, by weight. %: SiO 2 54.98-56.7; Al 2 O 3 9.4-10.45; Fe 2 O 3 0.05-0.2; CaO 10.0-10.75; MgO 0.01-0.1; Na 2 O 0.05-0.2; K 2 O 6.71-7.0; B 2 O 3 10,9-11,3; Cr 2 O 3 0.9-1.3; SnO 2 4.5-5.0 [1].

Задачей изобретения является повышение термостойкости глазури.The objective of the invention is to increase the heat resistance of the glaze.

Технический результат достигается тем, что глазурь, включающая SiO2, Al2O3, K2O, B2O3, Cr2O3, SnO2, дополнительно содержит ZnO, при следующем соотношении компонентов, мас. %: SiO2 3,0-4,0; Al2O3 52,5-53,4; K2O 5,0-6,0; B2O3 7,0-8,5; Cr2O3 15,0-20;0;SnO2 4,0-5,0; ZnO 7,0-10,0.The technical result is achieved in that the glaze, including SiO 2 , Al 2 O 3 , K 2 O, B 2 O 3 , Cr 2 O 3 , SnO 2 , additionally contains ZnO, in the following ratio, wt. %: SiO 2 3.0-4.0; Al 2 O 3 52.5-53.4; K 2 O 5.0-6.0; B 2 O 3 7.0-8.5; Cr 2 O 3 15.0-20; 0; SnO 2 4.0-5.0; ZnO 7.0-10.0.

В таблице приведены составы глазури.The table shows the glaze compositions.

КомпонентыComponents Содержание, мас. % в составахContent, wt. % in the compositions 1one 22 33 Si02 Si0 2 4,04.0 3,53,5 3,03.0 Al2O3 Al 2 O 3 53,053.0 53,453,4 52,552,5 K2OK 2 O 6,06.0 5,55.5 5,05,0 B2O3 B 2 O 3 7,07.0 7,87.8 8,58.5 Cr2O3 Cr 2 O 3 15,015.0 17,017.0 20,020,0 SnO2 Sno 2 5,05,0 4,54,5 4,04.0 ZnOZno 10,010.0 8,38.3 7,07.0 Термостойкость, теплосмены (нагрев до 125°C → охлаждение до 20°C)Heat resistance, heat exchange (heating to 125 ° C → cooling to 20 ° C) 30-3530-35 30-3530-35 30-3530-35

Взвешенные в требуемых соотношениях тонкодисперсные (остаток на сите №008 не более 5%) компоненты смешивают. Полученную смесь напыляют на поверхность керамических изделий в струе низкотемпературной плазмы, при этом образуется стеклокристаллическое покрытие с незначительными дефектами структуры (микропоры, газовые включения). Weighed in the required proportions, finely dispersed (residue on sieve No. 008 no more than 5%), the components are mixed. The resulting mixture is sprayed onto the surface of ceramic products in a low-temperature plasma jet, and a glass-crystal coating is formed with minor structural defects (micropores, gas inclusions).

Методика нанесения подобных покрытий, происходящие при этом процессы и необходимое оборудование подробно описаны нами в [2].The technique of applying such coatings, the processes that occur during this, and the necessary equipment are described in detail in [2].

Источники информацииInformation sources

1. SU 1275013, С03С 8/02, 1986. 1. SU 1275013, C03C 8/02, 1986.

2. Федосов С.В., Акулова М.В., Щепочкина Ю.А., Подлозный Э.Д., Науменко Н.Н. «Плазменное оплавление строительных композитов». Москва, Изд-во АСВ, Иваново, ИГАСУ, 2009, c. 131-144.2. Fedosov S.V., Akulova M.V., Schepochkina Yu.A., Podlozny E.D., Naumenko N.N. "Plasma fusion of building composites." Moscow, DIA Publishing House, Ivanovo, IGASU, 2009, p. 131-144.

Claims (1)

Глазурь, включающая SiO2, Al2O3, K2O, B2O3, Cr2O3, SnO2, отличающаяся тем, что дополнительно содержит ZnO при следующем соотношении компонентов, мас. %: SiO2 3,0-4,0; Al2O3 52,5-53,4; K2O 5,0-6,0; B2O3 7,0-8,5; Cr2O3 15,0-20,0; SnO2 4,0-5,0; ZnO 7,0-10,0.Glaze, including SiO 2 , Al 2 O 3 , K 2 O, B 2 O 3 , Cr 2 O 3 , SnO 2 , characterized in that it additionally contains ZnO in the following ratio of components, wt. %: SiO 2 3.0-4.0; Al 2 O 3 52.5-53.4; K 2 O 5.0-6.0; B 2 O 3 7.0-8.5; Cr 2 O 3 15.0-20.0; SnO 2 4.0-5.0; ZnO 7.0-10.0.
RU2017103802A 2017-02-06 2017-02-06 Glaze RU2642608C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2017103802A RU2642608C1 (en) 2017-02-06 2017-02-06 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2017103802A RU2642608C1 (en) 2017-02-06 2017-02-06 Glaze

Publications (1)

Publication Number Publication Date
RU2642608C1 true RU2642608C1 (en) 2018-01-25

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1275013A1 (en) * 1983-10-05 1986-12-07 Украинский Научно-Исследовательский Институт Стекольной И Фарфоро-Фаянсовой Промышленности Coloured glaze
EP0672632B1 (en) * 1994-03-16 1997-12-17 AEROSPATIALE Société Nationale Industrielle High temperature monolayer coating on ceramic substrate and its production
DE19622522C1 (en) * 1996-06-05 1998-01-22 Schott Glaswerke Production of sealed sintered glass ceramic for household equipment
RU2255076C1 (en) * 2003-11-26 2005-06-27 Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт авиационных материалов" (ФГУП "ВИАМ") Heat-resistant coating
RU2398746C1 (en) * 2009-08-03 2010-09-10 Российская Федерация в лице Министерства промышленности и торговли Российской Федерации (Минпромторг России) Ceramic pigment

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1275013A1 (en) * 1983-10-05 1986-12-07 Украинский Научно-Исследовательский Институт Стекольной И Фарфоро-Фаянсовой Промышленности Coloured glaze
EP0672632B1 (en) * 1994-03-16 1997-12-17 AEROSPATIALE Société Nationale Industrielle High temperature monolayer coating on ceramic substrate and its production
DE19622522C1 (en) * 1996-06-05 1998-01-22 Schott Glaswerke Production of sealed sintered glass ceramic for household equipment
RU2255076C1 (en) * 2003-11-26 2005-06-27 Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт авиационных материалов" (ФГУП "ВИАМ") Heat-resistant coating
RU2398746C1 (en) * 2009-08-03 2010-09-10 Российская Федерация в лице Министерства промышленности и торговли Российской Федерации (Минпромторг России) Ceramic pigment

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