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RU2321562C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2321562C1
RU2321562C1 RU2006130154/03A RU2006130154A RU2321562C1 RU 2321562 C1 RU2321562 C1 RU 2321562C1 RU 2006130154/03 A RU2006130154/03 A RU 2006130154/03A RU 2006130154 A RU2006130154 A RU 2006130154A RU 2321562 C1 RU2321562 C1 RU 2321562C1
Authority
RU
Russia
Prior art keywords
glaze
tio
sio
cao
zno
Prior art date
Application number
RU2006130154/03A
Other languages
Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
Original Assignee
Юлия Алексеевна Щепочкина
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006130154/03A priority Critical patent/RU2321562C1/en
Application granted granted Critical
Publication of RU2321562C1 publication Critical patent/RU2321562C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: manufacture of tiles and domestic ceramic articles.
SUBSTANCE: proposed glaze contains the following components, mass-%: SiO2, 60.0-68.0; Al2O3, 1.0-2.0; CaO, 4.0-7.0; ZnO, 1.0-2.0; K2O, 2.0-4.0; Na2O, 2.0-4.0; TiO2, 8.0-10.0; Co2O3, 1.0-2.0; B2O3, 5.0-7.0; BaO, 4.0-6.0.
EFFECT: enhanced heat resistance and luster of glaze.
1 tbl

Description

Изобретение относится к составам фриттованных глазурей, которые могут быть использованы в производстве облицовочной плитки, изделий бытовой керамики.The invention relates to compositions of fritted glazes that can be used in the manufacture of facing tiles, household ceramics.

Известна глазурь, содержащая, мас.%: SiO2 56,93-62,92; Al2O3 3,77-7,63; K2O 1,34-2,62; Na2O 7,34-6,43; TiO2 3,5-5,94; B2O3 15,62-28,67 /1/.Known glaze containing, in wt.%: SiO 2 56.93-62.92; Al 2 O 3 3.77-7.63; K 2 O 1.34-2.62; Na 2 O, 7.34-6.43; TiO 2 3.5-5.94; B 2 O 3 15.62-28.67 / 1 /.

Известна глазурь, содержащая, мас.%: SiO2 66,64-68,02; Al2O3 7,01-7,15; CaO 0,62-0,63; ZnO 1,66-1,74; K2O 2,48-2,51; Na2O 5,68-5,79; TiO2 8,29-8,47; Co2O3 2,0-4,0; B2O3 3,62-3,69 /2/.Known glaze containing, in wt.%: SiO 2 66.64-68.02; Al 2 O 3 7.01-7.15; CaO 0.62-0.63; ZnO 1.66-1.74; K 2 O 2.48-2.51; Na 2 O 5.68-5.79; TiO 2 8.29-8.47; Co 2 O 3 2.0-4.0; B 2 O 3 3.62-3.69 / 2 /.

Целью изобретения является повышение термостойкости и блеска глазури.The aim of the invention is to increase the heat resistance and gloss of the glaze.

Цель достигается тем, что в состав глазури дополнительно вводят BaO, при следующем соотношении компонентов, мас.%: SiO2 60,0-68,0; Al2O3 1,0-2,0; CaO 4,0-7,0; ZnO 1,0-2,0; K2O 2,0-4,0; Na2O 2,0-4,0; TiO2 8,0-10,0; Co2O3 1,0-2,0; B2O3 5,0-7,0; BaO 4,0-6,0.The goal is achieved by the fact that BaO is additionally introduced into the glaze composition, in the following ratio of components, wt.%: SiO 2 60.0-68.0; Al 2 O 3 1.0-2.0; CaO 4.0-7.0; ZnO 1.0-2.0; K 2 O 2.0-4.0; Na 2 O 2,0-4,0; TiO 2 8.0-10.0; Co 2 O 3 1.0-2.0; B 2 O 3 5.0-7.0; BaO 4.0-6.0.

В таблице приведены составы глазури.The table shows the glaze compositions.

ТаблицаTable СоставStructure Компоненты, мас.%:Components, wt.%: Термостойкость, теплосменыHeat resistance, heat exchange Блеск,%Gloss,% SiO2 SiO 2 Al2O3 Al 2 O 3 CaOCao ZnOZno K2OK 2 O Na2ONa 2 O TiO2 TiO 2 Co2O3 Co 2 O 3 B2O3 B 2 O 3 BaOBao 1one 60,060.0 2,02.0 7,07.0 2,02.0 2,02.0 4,04.0 10,010.0 2,02.0 7,07.0 4,04.0 ~20~ 20 ~75~ 75 22 64,064.0 1,51,5 5,55.5 1,51,5 3,03.0 3,03.0 10,010.0 1,51,5 6,06.0 5,05,0 ~20~ 20 ~75~ 75 33 66,066.0 1,01,0 4,04.0 1,01,0 4,04.0 2,02.0 6,06.0 1,01,0 5,05,0 6,06.0 ~20~ 20 ~75~ 75

Компоненты глазури сплавляют при 1300°С, расплав гранулируют в воду. Фритту размалывают с добавкой 1-2% глины, 0,1-0,2% электролита 45-50% воды до остатка 0,2-0,5% на сетке №005. Глазурную суспензию наносят на изделия и закрепляют обжигом при 1000°С.Glaze components are fused at 1300 ° С, the melt is granulated into water. The frit is ground with the addition of 1-2% clay, 0.1-0.2% electrolyte 45-50% water to a residue of 0.2-0.5% on mesh No. 005. The glaze suspension is applied to the products and fixed by firing at 1000 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №1004265, С03С 9/00, 1982.1. USSR copyright certificate No. 1004265, С03С 9/00, 1982.

2. Авторское свидетельство СССР №1491624, С03С 8/04, 1989.2. USSR Author's Certificate No. 1491624, С03С 8/04, 1989.

Claims (1)

Глазурь, содержащая SiO2, Al2О3, СаО, ZnO, K2O, Na2O, TiO2, Со2О3, В2О3, отличающаяся тем, что дополнительно содержит ВаО при следующем соотношении компонентов, мас.%: SiO2 60,0-68,0; Al2О3 1,0-2,0; СаО 4,0-7,0; ZnO 1,0-2,0; К2O 2,0-4,0; Na2O 2,0-4,0; TiO2 8,0-10,0; Со2O3 1,0-2,0; В2O3 5,0-7,0; ВаО 4,0-6,0.Glaze containing SiO 2 , Al 2 O 3 , CaO, ZnO, K 2 O, Na 2 O, TiO 2 , Co 2 O 3 , B 2 O 3 , characterized in that it additionally contains BaO in the following ratio of components, wt. %: SiO 2 60.0-68.0; Al 2 O 3 1.0-2.0; CaO 4.0-7.0; ZnO 1.0-2.0; K 2 O 2.0-4.0; Na 2 O 2,0-4,0; TiO 2 8.0-10.0; Co 2 O 3 1.0-2.0; B 2 O 3 5.0-7.0; BaO 4.0-6.0.
RU2006130154/03A 2006-08-21 2006-08-21 Glaze RU2321562C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006130154/03A RU2321562C1 (en) 2006-08-21 2006-08-21 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006130154/03A RU2321562C1 (en) 2006-08-21 2006-08-21 Glaze

Publications (1)

Publication Number Publication Date
RU2321562C1 true RU2321562C1 (en) 2008-04-10

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2006130154/03A RU2321562C1 (en) 2006-08-21 2006-08-21 Glaze

Country Status (1)

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RU (1) RU2321562C1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4282035A (en) * 1980-02-15 1981-08-04 Corning Glass Works Lead-free and cadmium-free frits
SU1491824A1 (en) * 1987-01-05 1989-07-07 Институт Химии Ан Узсср Glaze
JP2005350327A (en) * 2004-06-14 2005-12-22 Inax Corp Decorated ceramic body, its production method, and glaze preparation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4282035A (en) * 1980-02-15 1981-08-04 Corning Glass Works Lead-free and cadmium-free frits
SU1491824A1 (en) * 1987-01-05 1989-07-07 Институт Химии Ан Узсср Glaze
JP2005350327A (en) * 2004-06-14 2005-12-22 Inax Corp Decorated ceramic body, its production method, and glaze preparation

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