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RU2318753C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2318753C1
RU2318753C1 RU2006135707/03A RU2006135707A RU2318753C1 RU 2318753 C1 RU2318753 C1 RU 2318753C1 RU 2006135707/03 A RU2006135707/03 A RU 2006135707/03A RU 2006135707 A RU2006135707 A RU 2006135707A RU 2318753 C1 RU2318753 C1 RU 2318753C1
Authority
RU
Russia
Prior art keywords
glaze
cao
mgo
sio
seo
Prior art date
Application number
RU2006135707/03A
Other languages
Russian (ru)
Inventor
Юлия Алексеевна Щепочкина
Original Assignee
Юлия Алексеевна Щепочкина
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006135707/03A priority Critical patent/RU2318753C1/en
Application granted granted Critical
Publication of RU2318753C1 publication Critical patent/RU2318753C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: technology of silicates; composition of glazes used in manufacture of decorative tiles.
SUBSTANCE: proposed glaze contains the following components, mass-%: SiO2, 50.0-54.0; Al2O3, 2.0-4.0; CaO, 13.0-17.0; MgO, 1.0-2.0; B2O3, 6.0-7.0; Fe2O3, 0.5-1.0; K2O, 3.5-4.5; SeO2, 1.5-2.5; ZnO, 8.0-10.0; TiO2, 5.0-7.0.
EFFECT: enhanced freeze resistance of glaze.
1 tbl

Description

Изобретение относится к области технологии силикатов, в частности к составам глазурей, используемых в производстве облицовочной плитки.The invention relates to the field of technology of silicates, in particular to compositions of glazes used in the manufacture of tiles.

Известна глазурь, содержащая, мас.%: SiO2 49,79-54,3; MgO 0,25-0,28; Fe2O3 1,62-2,05; Al2O3 11,71-13,6; Na2O 2,13-3,0; B2O3 7,11-8,19; CaO 18,68-22,4; K2O 2,22-2,58; SO3 0,03-0,05 /1/.Known glaze containing, wt.%: SiO 2 49,79-54,3; MgO 0.25-0.28; Fe 2 O 3 1.62-2.05; Al 2 O 3 11.71-13.6; Na 2 O 2,13-3,0; B 2 O 3 7.11-8.19; CaO 18.68-22.4; K 2 O 2.22-2.58; SO 3 0.03-0.05 / 1 /.

Известна глазурь, содержащая, мас.%: SiO2 49,08-53,51; Al2O3 8,84-10,86; CaO 16,39-19,96; MgO 0,66-1,64; B2O3 7,6-8,34; Fe2O3 0,5-0,75; K2O 0,37-1,05; Na2O 7,08-9,34; SeO2 1,29-2,56; F' 0,69-1,42 /2/.Known glaze containing, wt.%: SiO 2 49,08-53,51; Al 2 O 3 8.84-10.86; CaO 16.39-19.96; MgO 0.66-1.64; B 2 O 3 7.6-8.34; Fe 2 O 3 0.5-0.75; K 2 O 0.37-1.05; Na 2 O 7.08-9.34; SeO 2 1.29-2.56; F '0.69-1.42 / 2 /.

Цель изобретения - повышение морозостойкости глазури.The purpose of the invention is to increase frost resistance of glaze.

Цель достигается тем, что в состав глазури дополнительно вводят ZnO и TiO2 при следующем соотношении компонентов, мас.%: SiO2 50,0-54,0; Al2O3 2,0-4,0; CaO 13,0-17,0; MgO 1,0-2,0; B2O3 6,0-7,0; Fe2O3 0,5-1,0; K2O 3,5-4,5; SeO2 1,5-2,5; ZnO 8,0-10,0; TiO2 5,0-7,0.The object is achieved in that the glaze composition is further administered ZnO and TiO 2, with the following component ratio, wt%: SiO 2 50,0-54,0;. Al 2 O 3 2.0-4.0; CaO 13.0-17.0; MgO 1.0-2.0; B 2 O 3 6.0-7.0; Fe 2 O 3 0.5-1.0; K 2 O 3.5-4.5; SeO 2 1.5-2.5; ZnO 8.0-10.0; TiO 2 5.0-7.0.

B таблице приведены составы глазури.The table shows the compositions of the glaze.

ТаблицаTable СоставStructure Компоненты, мас.%:Components, wt.%: Морозостойкость, циклыFrost resistance cycles SiO2 SiO 2 Al2O3 Al 2 O 3 CaOCao MgOMgO B2O3 B 2 O 3 Fe2O3 Fe 2 O 3 K2OK 2 O SeO2 Seo 2 ZnOZno TiO2 TiO 2 1one 50,050,0 4,04.0 17,017.0 1,01,0 7,07.0 1,01,0 3,53,5 1,51,5 8,08.0 7,07.0 200-230200-230 22 52,052.0 3,03.0 15,515,5 1,71.7 6,06.0 0,80.8 4,04.0 2,02.0 9,09.0 6,06.0 200-230200-230 33 54,054.0 2,02.0 13,013.0 2,02.0 6,56.5 0,50.5 4,54,5 2,52,5 10,010.0 5,05,0 200-230200-230

Компоненты глазури сплавляют при 1300°С, расплат гранулируют в воду. Фритту размалывают мокрым способом с добавкой 3-4% глины и 0,1-0,2% электролита (калиевое жидкое стекло). Полученную суспензию наносят на изделия и закрепляют обжигом при 950°С.The components of the glaze are fused at 1300 ° С; The frit is ground wet with the addition of 3-4% clay and 0.1-0.2% electrolyte (potassium water glass). The resulting suspension is applied to the products and fixed by firing at 950 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №1025677, С03С 9/00, 1983.1. USSR copyright certificate No. 1025677, С03С 9/00, 1983.

2. Авторское свидетельство СССР №1154230, С03С 8/06, 1985.2. USSR author's certificate No. 1154230, С03С 8/06, 1985.

Claims (1)

Глазурь, содержащая SiO2, Al2O3, CaO, MgO, B2O3, Fe2O3, K2O, SeO2, отличающаяся тем, что дополнительно содержит ZnO и TiO2 при следующем соотношении компонентов, мас.%:Glaze containing SiO 2 , Al 2 O 3 , CaO, MgO, B 2 O 3 , Fe 2 O 3 , K 2 O, SeO 2 , characterized in that it additionally contains ZnO and TiO 2 in the following ratio of components, wt.% : SiO2 SiO 2 50,0-54,050.0-54.0 Al2O3 Al 2 O 3 2,0-4,02.0-4.0 CaOCao 13,0-17,013.0-17.0 MgOMgO 1,0-2,01.0-2.0 B2O3 B 2 O 3 6,0-7,06.0-7.0 Fe2O3 Fe 2 O 3 0,5-1,00.5-1.0 K2OK 2 O 3,5-4,53.5-4.5 SeO2 Seo 2 1,5-2,51.5-2.5 ZnOZno 8,0-10,08.0-10.0 TiO2 TiO 2 5,0-7,05.0-7.0
RU2006135707/03A 2006-10-09 2006-10-09 Glaze RU2318753C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006135707/03A RU2318753C1 (en) 2006-10-09 2006-10-09 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006135707/03A RU2318753C1 (en) 2006-10-09 2006-10-09 Glaze

Publications (1)

Publication Number Publication Date
RU2318753C1 true RU2318753C1 (en) 2008-03-10

Family

ID=39280846

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2006135707/03A RU2318753C1 (en) 2006-10-09 2006-10-09 Glaze

Country Status (1)

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RU (1) RU2318753C1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6525300B1 (en) * 1999-07-30 2003-02-25 Schott Glas Cooking surface for cooking food having a glass ceramic surface with a glass coating thereon
RU2225372C1 (en) * 2002-07-01 2004-03-10 ОАО "Тольяттиазот" Glaze
RU2259327C1 (en) * 2004-03-01 2005-08-27 ОАО "Тольяттиазот" Glaze

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6525300B1 (en) * 1999-07-30 2003-02-25 Schott Glas Cooking surface for cooking food having a glass ceramic surface with a glass coating thereon
RU2225372C1 (en) * 2002-07-01 2004-03-10 ОАО "Тольяттиазот" Glaze
RU2259327C1 (en) * 2004-03-01 2005-08-27 ОАО "Тольяттиазот" Glaze

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