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RU2372381C2 - Methods of producing crude product - Google Patents

Methods of producing crude product Download PDF

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Publication number
RU2372381C2
RU2372381C2 RU2006126084/04A RU2006126084A RU2372381C2 RU 2372381 C2 RU2372381 C2 RU 2372381C2 RU 2006126084/04 A RU2006126084/04 A RU 2006126084/04A RU 2006126084 A RU2006126084 A RU 2006126084A RU 2372381 C2 RU2372381 C2 RU 2372381C2
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Russia
Prior art keywords
crude product
crude
alkali metal
crude feed
total
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RU2006126084/04A
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Russian (ru)
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RU2006126084A (en
Inventor
Томас Фэйрчайлд БРАУНСКОМБ (US)
Томас Фэйрчайлд Браунскомб
Скотт Ли ВЕЛЛИНГТОН (US)
Скотт Ли Веллингтон
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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Publication of RU2006126084A publication Critical patent/RU2006126084A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/043—Sulfides with iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1074—Vacuum distillates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1096—Aromatics or polyaromatics
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/305—Octane number, e.g. motor octane number [MON], research octane number [RON]

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Lubricants (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

FIELD: physics. ^ SUBSTANCE: invention relates to a method of producing crude material. When crude material is brought into contact with one or more catalyst, a total product is obtained, which contains a crude product. Crude material has residue content of at least 0.2 grams per 1 gram of crude material. The crude product is a liquid mixture at 25C and 0.101 MPa. One or more properties of this crude product can be altered at least 10% from corresponding properties of the crude material. In some versions of the invention, gas is obtained after bringing crude material with one or more catalysts. These methods allow for obtaining crude material with improved characteristics. ^ EFFECT: invention also relates to a crude product or a mixture or a method of producing transport fuel. ^ 22 cl, 27 ex, 4 tbl, 12 dwg

Description

Текст описания приведен в факсимильном виде.

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Claims (22)

1. Способ получения неочищенного продукта, образующегося в процессе нефтепереработки, который заключается в том, что вводят в контакт неочищенное сырье с источником водорода в присутствии неорганического солевого катализатора, чтобы получить суммарный продукт, который содержит неочищенный продукт, представляющий собой жидкую смесь при 25°С и 0,101 МПа, причем неочищенное сырье имеет содержание остатка, по меньшей мере, 0,2 г остатка на 1 г неочищенного сырья; неорганический солевой катализатор содержит соли щелочных металлов, в котором, по меньшей мере, одна из солей щелочного металла представляет собой карбонат щелочного металла, и щелочной металл имеет атомный номер, по меньшей мере, 11 и атомное отношение, по меньшей мере, одного из щелочных металлов, имеющего атомный номер, по меньшей мере, 11, к щелочному металлу, имеющему атомный номер больше чем 11, находится в диапазоне от 0,1 до 10; и регулируют условия контактирования таким образом, что неочищенный продукт имеет содержание остатка, выраженное в граммах остатка на 1 г неочищенного продукта, менее чем 30% от содержания остатка в неочищенном сырье, где содержание остатка определяется по методу ASTM D5307.1. The method of obtaining the crude product formed during the oil refining process, which consists in contacting the crude feed with a hydrogen source in the presence of an inorganic salt catalyst to obtain a total product that contains the crude product, which is a liquid mixture at 25 ° C and 0.101 MPa, the crude feed having a residue content of at least 0.2 g of residue per 1 g of crude feed; the inorganic salt catalyst contains alkali metal salts in which at least one of the alkali metal salts is an alkali metal carbonate and the alkali metal has an atomic number of at least 11 and an atomic ratio of at least one of the alkali metals having an atomic number of at least 11 to an alkali metal having an atomic number greater than 11 is in the range from 0.1 to 10; and adjust the contact conditions so that the crude product has a residue content, expressed in grams of residue per 1 g of crude product, of less than 30% of the residue content in the crude feed, where the residue content is determined by ASTM D5307. 2. Способ по п.1, в котором, по меньшей мере, часть суммарного продукта образуется в виде паров, причем по меньшей мере часть паров конденсирует при 25°С и 0,101 МПа с образованием неочищенного продукта.2. The method according to claim 1, in which at least part of the total product is formed in the form of vapors, and at least part of the vapor condenses at 25 ° C and 0.101 MPa with the formation of the crude product. 3. Способ получения неочищенного продукта, который заключается в том, что вводят в контакт неочищенное сырье с источником водорода в присутствии неорганического солевого катализатора, чтобы получить суммарный продукт, причем неочищенное сырье имеет содержание остатка, по меньшей мере, 0,2 г остатка на 1 г неочищенного сырья; неорганический солевой катализатор содержит соли щелочных металлов, в котором, по меньшей мере, одна из солей щелочного металла представляет собой гидрид щелочного металла, и щелочной металл имеет атомный номер, по меньшей мере, 11 и атомное отношение, по меньшей мере, одного из щелочных металлов, имеющего атомный номер, по меньшей мере, 11, к щелочному металлу, имеющему атомный номер больше чем 11, находится в диапазоне от 0,1 до 10; получают, по меньшей мере, часть суммарного продукта в виде паров; конденсируют, по меньшей мере, часть паров при 25°С и 0,101 МПа; и образуется неочищенный продукт, который имеет содержание остатка менее чем 30% от содержания остатка для неочищенного сырья.3. A method of obtaining a crude product, which consists in the fact that the crude feed is brought into contact with a hydrogen source in the presence of an inorganic salt catalyst to obtain a total product, the crude feed having a residue content of at least 0.2 g of residue per 1 g of crude feed; the inorganic salt catalyst contains alkali metal salts in which at least one of the alkali metal salts is an alkali metal hydride and the alkali metal has an atomic number of at least 11 and an atomic ratio of at least one of the alkali metals having an atomic number of at least 11 to an alkali metal having an atomic number greater than 11 is in the range from 0.1 to 10; at least a portion of the total product is obtained in the form of vapors; at least part of the vapor is condensed at 25 ° C. and 0.101 MPa; and a crude product is formed that has a residue content of less than 30% of the residue content of the crude feed. 4. Способ по п.1 или 3, в котором атомное отношение щелочного металла, имеющего атомный номер, по меньшей мере, 11, к щелочному металлу, имеющему атомный номер больше чем 11, находится в диапазоне от 0,1 до 4.4. The method according to claim 1 or 3, in which the atomic ratio of an alkali metal having an atomic number of at least 11 to an alkali metal having an atomic number greater than 11 is in the range from 0.1 to 4. 5. Способ по п.1 или 3, в котором, по меньшей мере, один щелочной металл представляет собой калий.5. The method according to claim 1 or 3, in which at least one alkali metal is potassium. 6. Способ по п.1 или 3, в котором щелочными металлами являются калий, цезий, рубидий или их смеси.6. The method according to claim 1 or 3, in which the alkali metals are potassium, cesium, rubidium, or mixtures thereof. 7. Способ по п.1 или 3, в котором, по меньшей мере, два щелочных металла представляют собой калий и рубидий, и атомное отношение калия к рубидию находится в диапазоне от 0,1 до 5; по меньшей мере, два щелочных металла представляют собой калий и цезий, и атомное отношение калия к цезию находится в диапазоне от 0,1 до 5; по меньшей мере, три щелочных металла представляют собой калий, цезий, рубидий, и каждое из атомных отношений калия к цезию, калия к рубидию, и цезия к рубидию находится в диапазоне от 0,1 до 5.7. The method according to claim 1 or 3, in which at least two alkali metals are potassium and rubidium, and the atomic ratio of potassium to rubidium is in the range from 0.1 to 5; at least two alkali metals are potassium and cesium, and the atomic ratio of potassium to cesium is in the range from 0.1 to 5; at least three alkali metals are potassium, cesium, rubidium, and each of the atomic ratios of potassium to cesium, potassium to rubidium, and cesium to rubidium is in the range from 0.1 to 5. 8. Способ получения неочищенного продукта, который заключается в том, что вводят в контакт неочищенное сырье с источником водорода в присутствии неорганического солевого катализатора, чтобы получить суммарный продукт, который содержит неочищенный продукт, который представляет собой жидкую смесь при 25°С и 0,101 МПа, причем неочищенное сырье имеет содержание остатка, по меньшей мере, 0,2 г остатка на 1 г неочищенного сырья; неорганический солевой катализатор содержит соли щелочных металлов, соли щелочноземельных металлов, или их смеси;
регулируют условия контактирования таким образом, что неочищенный продукт имеет содержание остатка менее чем 30% от содержания остатка в неочищенном сырье, где содержание остатка определяется по методу ASTM D5307; и
нагревают смесь остаточного неочищенного сырья и отработанного неорганического солевого катализатора до температуры, по меньшей мере, 800°С в присутствии реакционноспособного газа, чтобы получить газовый поток и/или жидкий поток, являющийся дополнительным неочищенным продуктом из смеси остаточного неочищенного сырья и отработанного неорганического солевого катализатора.8. The method of obtaining the crude product, which consists in the fact that the crude raw material is brought into contact with a hydrogen source in the presence of an inorganic salt catalyst to obtain a total product that contains the crude product, which is a liquid mixture at 25 ° C and 0.101 MPa, moreover, the crude feed has a residue content of at least 0.2 g of residue per 1 g of crude feed; inorganic salt catalyst contains alkali metal salts, alkaline earth metal salts, or mixtures thereof;
adjust the contact conditions so that the crude product has a residue content of less than 30% of the residue content of the crude feed, where the residue content is determined according to ASTM D5307; and
heat the mixture of residual crude feed and spent inorganic salt catalyst to a temperature of at least 800 ° C in the presence of reactive gas to obtain a gas stream and / or liquid stream, which is an additional crude product from a mixture of residual crude feed and spent inorganic salt catalyst. 9. Способ по п.8, в котором реакционноспособный газ содержит водород, водяной пар, азот, диоксид углерода, легкие углеводороды или их смеси.9. The method of claim 8, in which the reactive gas contains hydrogen, water vapor, nitrogen, carbon dioxide, light hydrocarbons, or mixtures thereof. 10. Способ по п.8 или 9, в котором газовый поток имеет от 0,2 до 0,99 моль водорода и/или диоксида углерода на 1 моль реакционноспособного газа и жидкий поток имеет больше чем 0,9 г или больше чем 0,99 г воды на 1 г жидкости.10. The method according to claim 8 or 9, in which the gas stream has from 0.2 to 0.99 mol of hydrogen and / or carbon dioxide per 1 mol of reactive gas and the liquid stream has more than 0.9 g or more than 0, 99 g of water per 1 g of liquid. 11. Способ по любому из пп.1-3 и 8-9, в котором неорганический солевой катализатор дополнительно содержит щелочноземельный металл.11. The method according to any one of claims 1 to 3 and 8-9, in which the inorganic salt catalyst further comprises an alkaline earth metal. 12. Способ по любому из пп.1-3 и 8-9, в котором источник водорода представляет собой водород, легкие углеводороды, воду или их смеси.12. The method according to any one of claims 1 to 3 and 8-9, in which the hydrogen source is hydrogen, light hydrocarbons, water, or mixtures thereof. 13. Способ по любому из пп.1-3 и 8-9, в котором условия контактирования регулируют таким образом, что в ходе контактирования на 1 г неочищенного сырья образуется менее чем 0,2 г, по большей мере 0,15 г, менее чем 0,1 г, или менее чем 0,05 г углеводородов, которые не конденсируются при 25°С и 0,101 МПа, что определяется с помощью материального баланса.13. The method according to any one of claims 1 to 3 and 8-9, in which the contacting conditions are controlled in such a way that less than 0.2 g, at least 0.15 g, less than than 0.1 g, or less than 0.05 g of hydrocarbons that do not condense at 25 ° C and 0.101 MPa, which is determined using the material balance. 14. Способ по любому из пп.1-3 и 8-9, в котором неочищенный продукт имеет от 0,00001 до 0,03 г или от 0,0001 до 0,01 г кокса на 1 г неочищенного продукта.14. The method according to any one of claims 1 to 3 and 8-9, in which the crude product has from 0.00001 to 0.03 g or from 0.0001 to 0.01 g of coke per 1 g of crude product. 15. Способ по любому из пп.1-3 и 8-9, в котором неочищенное сырье имеет суммарное кислотное число (СКЧ), суммарное содержание Ni/V/Fe, суммарное содержание гетероатомов, выраженные в граммах Ni/V/Fe, или граммах гетероатомов на 1 г сырья, и условия контактирования регулируются таким образом, что неочищенный продукт имеет СКЧ, суммарное содержание Ni/V/Fe, и/или суммарное содержание гетероатомов по большей мере 90% от величин СКЧ, суммарного содержания Ni/V/Fe, и/или суммарного содержания гетероатомов в неочищенном сырье.15. The method according to any one of claims 1 to 3 and 8-9, in which the crude feed has a total acid number (SKH), the total content of Ni / V / Fe, the total content of heteroatoms, expressed in grams of Ni / V / Fe, or grams of heteroatoms per 1 g of raw material, and the contact conditions are regulated in such a way that the crude product has an SCH, the total Ni / V / Fe content, and / or a total heteroatom content of at most 90% of the SCH, the total Ni / V / Fe content , and / or the total content of heteroatoms in the crude feed. 16. Способ по любому из пп.1-3 и 8-9, в котором неочищенный продукт также имеет на 1 г неочищенного продукта от 0,00001 до 0,2 г нафты, от 0,0001 до 0,9 г дистиллята, от 0,0001 до 0,99 г вакуумного газойля или их смесей.16. The method according to any one of claims 1 to 3 and 8-9, in which the crude product also has, per gram of crude product, from 0.00001 to 0.2 g of naphtha, from 0.0001 to 0.9 g of distillate, from 0.0001 to 0.99 g of vacuum gas oil or mixtures thereof. 17. Способ по любому из пп.1-3 и 8-9, в котором неочищенное сырье имеет от 0,2 до 0,99 г или от 0,3 до 0,8 г остатка на 1 г неочищенного сырья.17. The method according to any one of claims 1 to 3 and 8-9, in which the crude feed has from 0.2 to 0.99 g or from 0.3 to 0.8 g of residue per 1 g of crude feed. 18. Способ по любому из пп.1-3 и 8-9, в котором смешивают неочищенный продукт с сырьем, являющимся таким же или отличающимся от неочищенного сырья с получением смеси.18. The method according to any one of claims 1 to 3 and 8-9, in which the crude product is mixed with a raw material that is the same or different from the crude raw material to obtain a mixture. 19. Неочищенный продукт или смесь, которые получают способом по любому из пп.1-18.19. The crude product or mixture, which is obtained by the method according to any one of claims 1 to 18. 20. Способ получения транспортного топлива, котельного топлива, смазочных средств или химикалий, который включает переработку неочищенного продукта или смеси, по п.19.20. The method of producing transport fuel, boiler fuel, lubricants or chemicals, which includes the processing of the crude product or mixture, according to claim 19. 21. Способ по п.20, в котором переработка включает дистилляцию неочищенного продукта или смеси, чтобы получить одну или несколько дистиллятных фракций.21. The method according to claim 20, in which the processing includes distillation of the crude product or mixture to obtain one or more distillate fractions. 22. Способ по п.20 или 21, в котором переработка представляет собой гидроочистку. 22. The method according to claim 20 or 21, in which the processing is hydrotreating.
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