RU2346627C1 - Smoking mixture - Google Patents

Abstract

FIELD: smokables.

SUBSTANCE: low-nicotine products are manufactured applying medicated herbal raw materials and can be used for manufacturing smokables. Smoking mixture contains aromatic and skeletal raw tobacco, and redroot herb as addition agent in related ratio.

EFFECT: lower toxicity of tobacco smoke and risk of interstitial diseases.

4 tbl

Description

The invention relates to the tobacco industry and can be used in tobacco factories to produce low toxic cigarettes.

Cigarette smoke, especially the general array of particles in its main stream, contains several components that are harmful due to their carcinogenic properties, antagonistic and other negative effects on health. This conclusion is based on a comprehensive chemical study of the PTC resin, as well as subsequent animal studies. Without going into details about the components and mechanisms of their negative influence, harmful substances were found in the substrate of smoke condensate; however, it is generally accepted that they are also present in real tar of the main stream of smoke perceived by the smoker. [Foki A. Cigarette: The Way from the Laboratory to Packaging. Sensory testing of flavoring products and American cigarette bag manufacturing technology. - M .: "Russian tobacco", 2005. - 294 p.]

At the present stage of development of the tobacco industry, the consumer of smoking products must be protected from the harmful effects of tobacco smoke, which manifests itself in an increase of 20-30% in the risk of diseases associated with excessive acceleration of the reactions of free radical oxidation of lipids, and primarily damage to the ciliated epithelium of the bronchi, which causes interstitial lung disease in smokers. The state regulates the content of toxic substances - tar and nicotine - in cigarette smoke. Hygienic standards (GN 2.3.2.022-95) "Maximum allowable tar and nicotine levels in tobacco products" are: for cigarettes with a filter - resins 14 mg / cig, nicotine 1.2 mg / cig, for cigarettes without a filter - tar 16 mg / sig, nicotine 1.3 mg / sig. To achieve the specified level of nicotine in smoke, the nicotine content in tobacco raw materials should not exceed 1.4%.

Table 1 shows the components of the smoke condensate that affect the activity of ciliated cilia. [Tatatarchenko I.I., Mokhnachev I.G., Kasyanov G.I. Chemistry of subtropical and food flavoring products. - M.: Publishing Center "Academy", 2003. - 256 p.]

Table 1
Components of smoke condensate affecting the activity of ciliated cilia Substance The amount required to suppress 50% of the activity of cilia, mcg The approximate concentration in the gas phase of cigarette smoke, mcg / sig. Hydrocyanic acid twenty fifty Acrolein fifty twenty Acetaldehyde 1300 140 Ammonia 70 10 Carbon dioxide fifty twenty Phenol fifty 12

Thus, the introduction into the composition of smoking mixtures of sources of antioxidants and vitamins of natural origin will not only reduce the risk of these diseases, but also provide their necessary prevention.

An analysis of the chemical composition of tobacco raw materials supplied to tobacco factories from the CIS countries and grown in Russia showed that a significant part of tobacco raw materials is characterized by a relatively high content of nicotine - up to 4.5% and pyrolyzate (tar precursor in tobacco smoke) up to 130 mg / sig . At the same time, in order to ensure a nicotine content of not more than 1.3 mg / sig in cigarette smoke, it is necessary to have a nicotine content of not more than 1.4% in a tobacco bag. To reduce tar and nicotine in smoke in the manufacture of cigarettes, special measures must be taken.

Known methods for reducing tar and nicotine in smoke by changing the design of a cigarette, namely the use of filters, highly porous cigarette paper, perforated paper. [Tatatarchenko I.I., Mokhnachev I.G., Kasyanov G.I. Technology of subtropical and food flavoring products. - M.: Publishing Center "Academy", 2004. - 384 p.] All of these methods are quite effective, but are associated with significant additional material costs and do not reduce the risk of developing interstitial diseases.

Closest to the claimed technical solution is a method of manufacturing a smoking mixture (SU 1593617, A24D 1/18, A24B 15/00), which consists in the fact that the well-known mixture of leaf tobacco of various botanical, commercial varieties and growth areas that have undergone a steam-heat treatment known technology, additionally introduce a cheap carbohydrate-containing herbal supplement that changes the carbohydrate content of raw materials and reduces the nicotine content in the tobacco smoke of cigarettes made from the above mixture. As a carbohydrate-containing additive, beet pulp fiber is used that has previously undergone a steam-thermal treatment. The content of the pulp is from 3.0-15% of the total mass of the mixture, while cutting is carried out after the mixing process. It is noted that, in comparison with the control, the chemical composition of the tobacco smoke of cigarettes made from a mixture of tobacco and beet pulp additives changes towards a stable decrease in nicotine.

The main disadvantage of this method is that the effect of reducing nicotine in smoke is achieved by adding to the tobacco a herbal supplement - beet pulp containing residual diffusion juice. In addition, beet pulp has a specific smell, taste and taste. Therefore, the use of beet pulp forms an unpleasant aroma of tobacco smoke and leads to a deterioration in the consumer properties of cigarettes, and also increases the risk of interstitial diseases.

The objective of the invention is to create a smoking mixture with the following properties: reduced nicotine content in tobacco smoke of cigarettes; reduced risk of interstitial diseases; high-quality consumer properties.

The problem is solved in that the claimed formulation of the smoking mixture contains, along with aromatic and skeletal tobacco raw materials, an additive in the form of grass (a dried crushed mixture of vegetative organs, which is usually called grass with the exception of roots) of amaranth crimson in the following ratio of ingredients, wt.%:

Aromatic Tobacco 52-58 Amaranth crimson 5-15 Skeletal tobacco rest.

Crimson amaranth (A. cruentus) is an annual herbaceous plant with erect panicle, blood-red inflorescences. The leaves are alternate, whole, without stipules, dark green in color with intensely red venation. The surface area of the leaf reaches 5.5 thousand square centimeters per plant. The shape of the leaf blade is ovoid-rhombic. Upper leaves have shorter petioles than lower leaves.

The stalk is straight, furrowed, rounded, 1.5-2.2 m high.

A. cruentus is a multi-use plant. From A. cruentus grain you can get flour, starch, bran, oil. Broad-leaved forms are used as vegetable plants, mainly for the preparation of salads rich in vitamin C, iron, calcium and some trace elements. Due to the large number of biologically active substances (rutin, amaranthine, vitamins C and E), amaranth exhibits antioxidant properties. Flavonoid compounds of amaranth leaves are presented in table 2.

table 2
Flavonoid compounds of amaranth leaves (% on absolutely dry weight) Connections Quartzine 0.31 Quarcetin-3-0-Glycositis 0.85 Quarcetin-3-0-galactoside 0.42 Quarcetin-3-0-rhamnoside 0.54 Routine 1.75 Apinegin-7-0-Glucoside 0.34 Σ flavonoids 4.21

For introduction into the smoking mixture, crushed vegetative organs of the plant (inflorescences and leaves) are used, dried to a moisture content of 15-17%.

Samples of tobacco raw materials are evaluated by smoking properties, technological properties, chemical composition and cost price and determine how much it is necessary to introduce crimson amaranth grass, aromatic and skeletal tobaccos into the formula of the smoking mixture. When developing the formulation of the smoking mixture, it focuses on the compliance of the cigarettes with the requirements of clause 4.1. GOST 3935-2000 "Cigarettes. Specifications" on the tar and nicotine content in the smoke declared on the package, on the smoking properties of the brand and the cost of products.

As a known base mixture, a first-class mixture (bag) is used according to the recipe (RC 10-04-09 / 01-88), which includes aromatic and skeletal raw materials (eastern bag). In this case, five types of tobacco raw materials are used having a rather high content of nicotine and pyrolyzate (tar precursor in tobacco smoke). To reduce the amount of nicotine in the tobacco mixture, high nicotine raw materials - Trapezond Kubanets or Yubileiny of the Krasnodar Territory are completely or partially replaced with amaranth grass.

The formulations of the base, prototype and experimental mixtures are given in table 3.

Table 3
Formulations of smoking mixtures, wt.% No. Type of raw material Basic Prototype Experimental mixtures one 2 3 four 5 one Dubek Central Asian 46 46 46 46 40 46 46 2 Samsun Abkhazian 12 12 12 12 12 12 12 3 Trapezond 219 of the Krasnodar Territory 9 9 9 9 fifteen 9 9 four Trapezond Kubanets of Krasnodar Territory 8 8 - 8 8 - 8 5 Anniversary of Krasnodar Territory fifteen fifteen 28 fifteen 10 23 twenty 6 Beet pulp - 10 - - - - - 7 Crimson amaranth grass - - 5 10 fifteen 10 5

Table 4 shows the chemical composition of mixtures of tobacco raw materials and smoke of filterless cigarettes made from these mixtures.

Table 4
The chemical composition of mixtures of tobacco raw materials and smoke-free cigarettes made from these mixtures The chemical composition of cigarette smoke, mg / sig. Basic Prototype Experimental mixtures one 2 3 four 5 Nicotine 1.40 1,11 1.10 1.00 0.90 1.00 1.10 Resin 15,80 13.6 13.00 12.90 13.30 13.10 13,20 Routine - - 0.09 0.23 0.32 0.24 0.09 Quartzine - - - - - - - Quarcetin-3-0-Glycositis - - 0,07 0.20 0.27 0.19 0,07 Quarcetin-3-0-galactoside - - - - - - - Kvarpetin-3-0-rhamnoside - - 0.05 0.12 0.20 0.11 0.04 Apinegin-7-0-Glucoside - - - - - - - Hydrocyanic acid 0.0080 0.0065 0.0046 0.0048 0.0035 0.0041 0.0047 Acrolein 0.0045 0.0038 0.0022 0.0020 0.0012 0.0020 0.0019 Acetaldehyde 0.0160 0.0150 0.0145 0.0130 0.0128 0.0145 0.0130 Ammonia 0.0037 0.0028 0.0014 0.0012 0.0012 0.0011 0.0012 Carbon dioxide 0.0042 0.0035 0.0015 0.0024 0.0020 0.0023 0.0016 Phenol 0.0031 0.0022 0.0012 0.0016 0,0008 0.0016 0.0012

The data presented in table 4 show that the use of amaranth raw materials can reduce the nicotine content in cigarette tobacco smoke and enrich tobacco smoke with flavonoid compounds that reduce the risk of interstitial diseases.

In order to compare the smoking properties of cigarettes made from the prototype and the proposed mixtures, their organoleptic characterization was performed by tasting.

It was found that the experimental mixtures 2 and 4 have better smoking properties compared to the prototype. In all experimental batches, a decrease in strength and a decrease in taste defects were noted.

When comparing the smoking properties of cigarettes according to the recipe of the prototype and made from a mixture of 3 revealed a sharp decrease in strength and void taste.

When comparing the smoking properties of cigarettes made according to formulations 1 and 5 and the mixture from the prototype, no significant differences were found.

The proposed smoking mixture with a low nicotine content in the smoke of cigarettes does not violate the known technology for the production of smoking products, does not require special expensive equipment.

Claims (1)

A smoking mixture comprising aromatic and skeletal tobacco raw materials and an additive, characterized in that as an additive it contains crimson amaranth grass in the following ratio of ingredients, wt.%:
Aromatic Tobacco 52-58 Amaranth crimson 5-15 Skeletal tobacco rest