RU2207991C2 - Decorative glass - Google Patents
Decorative glass Download PDFInfo
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- RU2207991C2 RU2207991C2 RU2001115152A RU2001115152A RU2207991C2 RU 2207991 C2 RU2207991 C2 RU 2207991C2 RU 2001115152 A RU2001115152 A RU 2001115152A RU 2001115152 A RU2001115152 A RU 2001115152A RU 2207991 C2 RU2207991 C2 RU 2207991C2
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- 239000011521 glass Substances 0.000 title claims abstract description 21
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 7
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 6
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 6
- 238000010411 cooking Methods 0.000 claims description 4
- 229910021193 La 2 O 3 Inorganic materials 0.000 claims description 3
- 229910017493 Nd 2 O 3 Inorganic materials 0.000 claims description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002699 waste material Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 abstract 1
- 238000005272 metallurgy Methods 0.000 abstract 1
- 238000005065 mining Methods 0.000 abstract 1
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium oxide Inorganic materials [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 abstract 1
- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 238000001228 spectrum Methods 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000002893 slag Substances 0.000 description 4
- -1 Pr 2 O 3 Inorganic materials 0.000 description 2
- 229910052586 apatite Inorganic materials 0.000 description 2
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 241001104043 Syringa Species 0.000 description 1
- 235000004338 Syringa vulgaris Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000005354 aluminosilicate glass Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
- C03C3/068—Glass compositions containing silica with less than 40% silica by weight containing boron containing rare earths
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Glass Compositions (AREA)
Abstract
Description
Изобретение относится к стекольной промышленности, а именно к составам декоративных стекол, и может быть использовано для получения декоративных облицовочных материалов. The invention relates to the glass industry, and in particular to compositions of decorative glasses, and can be used to obtain decorative facing materials.
Известно стекло (1), включающее, мас.%: SiO2 - 42-50, Аl2О3 - 11,5-13, CaO - 25-30, MgO 0,1-0,5, МnО - 7-9, Fе2О3 - 5-9,7. Стекло имеет температуру варки 1300-1350oС, невысокие физико-механические свойства, черную цветовую гамму.Known glass (1), including, wt.%: SiO 2 - 42-50, Al 2 O 3 - 11.5-13, CaO - 25-30, MgO 0.1-0.5, MnO - 7-9 , Fe 2 O 3 - 5-9.7. Glass has a cooking temperature of 1300-1350 o C, low physical and mechanical properties, black color scheme.
Наиболее близким к предлагаемому является декоративное стекло (2), включающее, мас.%: SiO2 - 48,8-63,0; ТiO2 - 2,0-14,8; Аl2О3 - 0,03-14,8; Fе2О3 - 0,01-3,81; FeO - 0,01-4,3; MnO - 0,01-13,5; MgO - 0,01-3,14; CaO - 0,03-31,0; Na2O - 0,01-23,09; K2O - 0,03-13,5.Closest to the proposed is decorative glass (2), including, wt.%: SiO 2 - 48.8-63.0; TiO 2 - 2.0-14.8; Al 2 O 3 - 0.03-14.8; Fe 2 O 3 - 0.01-3.81; FeO - 0.01-4.3; MnO - 0.01-13.5; MgO - 0.01-3.14; CaO - 0.03-31.0; Na 2 O - 0.01-23.09; K 2 O - 0.03-13.5.
Недостатками указанного стекла являются невысокие физико-механические свойства, относительно высокая температура варки 1250-1320oС и использование дорогостоящих химических реактивов: КМnO4, MnO2, диоксида титана ТiO2, жидкого стекла.The disadvantages of this glass are low physical and mechanical properties, a relatively high cooking temperature of 1250-1320 o C and the use of expensive chemicals: KMnO 4 , MnO 2 , titanium dioxide TiO 2 , liquid glass.
Целью изобретения является уменьшение температуры варки, увеличение механической прочности, микротвердости, расширение цветовой гаммы, типизация отходов апатитового производства и металлургических шлаков. The aim of the invention is to reduce the cooking temperature, increase mechanical strength, microhardness, expand the color gamut, typify waste apatite production and metallurgical slag.
Поставленная цель достигается за счет того, что декоративное стекло, включающее SiO2, ТiO2, Аl2О3, Fе2О3, FeO, CaO, MgO, MnO, Na2O, K2O дополнительно содержит P2O5, В2О3 оксиды РЗЭ La2О3, Рr2О3, Nd2O3 при следующем соотношении компонентов, мас.%:
SiO2 - 36,125 - 49,745
ТiO2 - 8,300 - 20,000
Аl2О3 - 2,900 - 7,900
Fе2О3 - 2,850 - 5,140
FeO - 0,010 - 0,930
CaO - 15,700 - 17,100
MgO - 1,100 - 8,000
МnО - 0,150 - 3,300
Na2O - 4,000 - 6,000
К2О - 1,000 - 3,000
В2О3 - 0,100 - 0,200
P2O5 - 0,430 - 0,860
La2O3 - 0,005 - 0,010
Рr2О3 - 0,001 - 0,005
Nd2O3 - 0,002 - 0,010
В качестве сырья используются полевошпатовые минералы, продукты переработки и отходы апатитового производства, ваграночные шлаки, гранулированные доменные шлаки, конвертерные шлаки.This goal is achieved due to the fact that the decorative glass, including SiO 2 , TiO 2 , Al 2 O 3 , Fe 2 O 3 , FeO, CaO, MgO, MnO, Na 2 O, K 2 O additionally contains P 2 O 5 , In 2 O 3 REE oxides La 2 O 3 , Pr 2 O 3 , Nd 2 O 3 in the following ratio of components, wt.%:
SiO 2 - 36.125 - 49.745
TiO 2 - 8,300 - 20,000
Al 2 O 3 - 2,900 - 7,900
Fe 2 O 3 - 2,850 - 5,140
FeO - 0.010 - 0.930
CaO - 15,700 - 17,100
MgO - 1,100 - 8,000
MnO - 0.150 - 3.300
Na 2 O - 4,000 - 6,000
K 2 O - 1,000 - 3,000
In 2 About 3 - 0,100 - 0,200
P 2 O 5 - 0.430 - 0.860
La 2 O 3 - 0.005 - 0.010
Pr 2 O 3 - 0.001 - 0.005
Nd 2 O 3 - 0.002 - 0.010
Feldspar minerals, processed products and apatite waste, cupola slag, granulated blast furnace slag, and converter slag are used as raw materials.
Стекло изготавливают по обычной технологии: шихту плавят в течение 0,5 - 0,7 часа при 1180 - 1200oC, отжиг стекла ведут при 500 - 550oC в течение 0,5 часа. Составы конкретных стекол приведены в таблице 1:
Из данных табл. 1 следует, что стекла составов 1-3 имеют обширные области метастабильной ликвации вследствие несовместимости титана и его комплексов типа (TiO4/2)2- R2 +1 или (TiO6/2)2-R2 + с алюмосиликатным каркасом стекла (3). За счет введения элементов с крупными катионами, таких как Р2O5, оксидов РЗЭ при избытке ТiO2, В2О3, возникает эффект разноцветного окрашивания областей кристаллизации стекла.Glass is made by conventional technology: the mixture is melted for 0.5 - 0.7 hours at 1180 - 1200 o C, the glass is annealed at 500 - 550 o C for 0.5 hours. The compositions of specific glasses are shown in table 1:
From the data table. 1 it follows that glasses of compositions 1-3 have extensive regions of metastable segregation due to the incompatibility of titanium and its complexes of the type (TiO 4/2 ) 2- R 2 +1 or (TiO 6/2 ) 2- R 2 + with an aluminosilicate glass framework ( 3). Due to the introduction of elements with large cations, such as P 2 O 5 , REE oxides with an excess of TiO 2 , B 2 O 3 , the effect of multi-colored coloring of glass crystallization areas occurs.
Полученные стекла имеют огненно-полированную поверхность и красивый рисунок с окраской в темно-коричневых, синих, сиреневых, бежевых, зеленых, фиолетовых тонах. Присутствие В2О3 и оксидов РЗЭ обусловливает высокую микротвердость и прочность стекол, что предполагает их использование в строительно-отделочной промышленности. Свойства приведены в таблице 2.The resulting glass has a fiery polished surface and a beautiful pattern with a color in dark brown, blue, lilac, beige, green, purple. The presence of B 2 O 3 and REE oxides determines the high microhardness and strength of the glasses, which suggests their use in the construction and finishing industry. The properties are shown in table 2.
Источники информации
1. А. с. 692784, С 03 С 3/04; С 03 С 33/22. В.С. Суварева, В.Ф. Лясин, Г.П. Тимонина, С.С. Руделев, А.П. Платонов, Ю.А. Гришенков.Sources of information
1. A. p. 692784, C 03
2. Пат. 2034804, 6 С 03 С 3/087, 4/02. Г.А. Лебедева, Г.П. Озерова. 2. Pat. 2034804, 6 C 03
3. Н.М. Павлушкин. Физика и химия стекла, т. 2, 3, 1976 г., Наука, Лен. отд. 3. N.M. Pavlushkin. Physics and Chemistry of Glass, Vol. 2, 3, 1976, Science, Len. Dep.
Claims (1)
SiO2 - 35,125-49,735
TiO2 - 8,300-20,000
Al2O3 - 2,900-7,900
Fe2O3 - 2,850-5,140
FeO - 0,010-0,930
CaO - 15,700-17,100
MgO - 1,100-8,000
MnO - 0,150-3,300
Na2O - 4,000-6,000
K2O - 1,000-3,000
В2О3 - 0,100-0,200
P2О5 - 0,430-0,860
ZrO2 - 0,010-2,000
La2O3 - 0,005-0,010
Pr2О3 - 0,001-0,005
Nd2O3 - 0,002-0,010зDecorative glass, including SiO 2 , TiO 2 , Al 2 O 3 , CaO, MgO, Fe 2 O 3 , FeO, MnO, Na 2 O, K 2 O, characterized in that to reduce the cooking temperature, increase mechanical strength, microhardness , expanding the color gamut, it additionally contains P 2 O 5 , ZrO 2 , B 2 O 3 , rare earth oxides in the following ratio of components, wt.%:
SiO 2 - 35.125-49.735
TiO 2 - 8,300-20,000
Al 2 O 3 - 2,900-7,900
Fe 2 O 3 - 2,850-5,140
FeO - 0.010-0.930
CaO - 15,700-17,100
MgO - 1,100-8,000
MnO - 0.150-3.300
Na 2 O - 4,000-6,000
K 2 O - 1,000-3,000
In 2 About 3 - 0,100-0,200
P 2 O 5 - 0.430-0.860
ZrO 2 - 0.010-2.000
La 2 O 3 - 0.005-0.010
Pr 2 O 3 - 0.001-0.005
Nd 2 O 3 - 0.002-0.010 s
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2001115152A RU2207991C2 (en) | 2001-06-04 | 2001-06-04 | Decorative glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2001115152A RU2207991C2 (en) | 2001-06-04 | 2001-06-04 | Decorative glass |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2001115152A RU2001115152A (en) | 2003-05-27 |
| RU2207991C2 true RU2207991C2 (en) | 2003-07-10 |
Family
ID=29209737
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2001115152A RU2207991C2 (en) | 2001-06-04 | 2001-06-04 | Decorative glass |
Country Status (1)
| Country | Link |
|---|---|
| RU (1) | RU2207991C2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2316488C1 (en) * | 2006-08-21 | 2008-02-10 | Юлия Алексеевна Щепочкина | Glass |
| RU2320557C1 (en) * | 2006-07-31 | 2008-03-27 | Юлия Алексеевна Щепочкина | Glass |
| CN106458712A (en) * | 2014-08-27 | 2017-02-22 | 施华洛世奇股份有限公司 | Luminescent glass composition |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1993002019A1 (en) * | 1991-07-22 | 1993-02-04 | Schott Glass Technologies, Inc. | Constrat enhancement in glass |
| US5242869A (en) * | 1991-07-11 | 1993-09-07 | Isuzu Glass Co., Ltd. | Colored glass |
| RU2020135C1 (en) * | 1991-04-10 | 1994-09-30 | Государственный научно-исследовательский и проектный институт азотной промышленности и продуктов органического синтеза | Aventurine glass |
| RU2034804C1 (en) * | 1992-08-10 | 1995-05-10 | Институт геологии Карельского научного центра РАН | Decorative glass |
| WO2002059053A1 (en) * | 2001-01-05 | 2002-08-01 | Schott Glass Technologies, Inc. | Interference filter having a glass substrate |
-
2001
- 2001-06-04 RU RU2001115152A patent/RU2207991C2/en not_active IP Right Cessation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2020135C1 (en) * | 1991-04-10 | 1994-09-30 | Государственный научно-исследовательский и проектный институт азотной промышленности и продуктов органического синтеза | Aventurine glass |
| US5242869A (en) * | 1991-07-11 | 1993-09-07 | Isuzu Glass Co., Ltd. | Colored glass |
| WO1993002019A1 (en) * | 1991-07-22 | 1993-02-04 | Schott Glass Technologies, Inc. | Constrat enhancement in glass |
| RU2034804C1 (en) * | 1992-08-10 | 1995-05-10 | Институт геологии Карельского научного центра РАН | Decorative glass |
| WO2002059053A1 (en) * | 2001-01-05 | 2002-08-01 | Schott Glass Technologies, Inc. | Interference filter having a glass substrate |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2320557C1 (en) * | 2006-07-31 | 2008-03-27 | Юлия Алексеевна Щепочкина | Glass |
| RU2316488C1 (en) * | 2006-08-21 | 2008-02-10 | Юлия Алексеевна Щепочкина | Glass |
| CN106458712A (en) * | 2014-08-27 | 2017-02-22 | 施华洛世奇股份有限公司 | Luminescent glass composition |
| US10414686B2 (en) * | 2014-08-27 | 2019-09-17 | D. Swarovski Kg | Luminescent glass composition |
| RU2717594C2 (en) * | 2014-08-27 | 2020-03-24 | Д. Сваровски Кг | Luminescent glass composition |
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| Date | Code | Title | Description |
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| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20140605 |