RU2018138784A - Блочные вспениваемые полимерные композиции - Google Patents
Блочные вспениваемые полимерные композиции Download PDFInfo
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- RU2018138784A RU2018138784A RU2018138784A RU2018138784A RU2018138784A RU 2018138784 A RU2018138784 A RU 2018138784A RU 2018138784 A RU2018138784 A RU 2018138784A RU 2018138784 A RU2018138784 A RU 2018138784A RU 2018138784 A RU2018138784 A RU 2018138784A
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- Prior art keywords
- polymer composition
- mass
- vinyl aromatic
- paragraphs
- expandable polymer
- Prior art date
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- 229920000642 polymer Polymers 0.000 title claims 20
- 239000000203 mixture Substances 0.000 title claims 19
- 229920002554 vinyl polymer Polymers 0.000 claims 11
- 229920001400 block copolymer Polymers 0.000 claims 9
- 125000004432 carbon atom Chemical group C* 0.000 claims 5
- 229920001577 copolymer Polymers 0.000 claims 5
- 150000001993 dienes Chemical class 0.000 claims 5
- 239000000178 monomer Substances 0.000 claims 5
- 239000004604 Blowing Agent Substances 0.000 claims 3
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 claims 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 2
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 claims 2
- 238000004806 packaging method and process Methods 0.000 claims 2
- -1 styrene-ethylene-butylene-styrene Chemical group 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 claims 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical class ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 claims 1
- VCWDAHMQCOZVQD-UHFFFAOYSA-N 2-chloroprop-1-enylbenzene Chemical class CC(Cl)=CC1=CC=CC=C1 VCWDAHMQCOZVQD-UHFFFAOYSA-N 0.000 claims 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 claims 1
- 239000006260 foam Substances 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical group 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 1
- 239000000155 melt Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- KHMYONNPZWOTKW-UHFFFAOYSA-N pent-1-enylbenzene Chemical class CCCC=CC1=CC=CC=C1 KHMYONNPZWOTKW-UHFFFAOYSA-N 0.000 claims 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 claims 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical class C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims 1
- 229920006132 styrene block copolymer Polymers 0.000 claims 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/224—Surface treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/228—Forming foamed products
- C08J9/232—Forming foamed products by sintering expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/06—Polystyrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/03—Extrusion of the foamable blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/036—Use of an organic, non-polymeric compound to impregnate, bind or coat a foam, e.g. fatty acid ester
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2207/00—Foams characterised by their intended use
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2453/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2453/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Claims (23)
1. Вспениваемая полимерная композиция, содержащая
a) от 60 масс. % до 88 масс. % винилароматического полимера и/или сополимера в расчете на (а)+(b),
b) от 12 масс. % до 40 масс. % блок-сополимера, содержащего по меньшей мере один винилароматический полимер и/или сополимер и по меньшей мере один гидрированный диеновый полимер, в расчете на (а)+(b),
c) от 3 масс. частей до 10 масс. частей вспенивателя в расчете на 100 частей (а)+(b).
2. Вспениваемая полимерная композиция, состоящая из:
a) от 60 масс. % до 88 масс. % винилароматического полимера и/или сополимера в расчете на (а)+(b),
b) от 12 масс. % до 40 масс. % блок-сополимера, содержащего по меньшей мере один винилароматический полимер и/или сополимер и по меньшей мере один гидрированный диеновый полимер, в расчете на (а)+(b),
c) от 3 масс. частей до 10 масс. частей вспенивателя в расчете на 100 частей (а)+(b).
3. Вспениваемая полимерная композиция по п. 1 или 2, в которой блок-сополимер представляет собой блок-сополимер типа стирол-этилен-бутилен-стирол.
4. Вспениваемая полимерная композиция по любому из пп. 1-3, в которой винилароматический полимер и/или сополимер получен из винилароматического мономера формулы (I)
в чистом виде, из смесей указанных мономеров или смесей, в которых присутствует до 35 масс. % сополимеризуемых виниловых мономеров, в которой R является водородом или метильной группой, n является нулем или целым числом от 1 до 3, Y выбран из галогена, предпочтительно хлора или брома, хлорметила, алкильной группы или алкоксигруппы, содержащей от 1 до 3 атомов углерода.
5. Вспениваемая полимерная композиция по п. 4, в которой винилароматический мономер выбран из стирола, α-метилстирола, метилстирола, этилстирола, изомеров винилтолуола, изомеров этилстирола, изомеров пропилстирола, изомеров хлорстирола, изомеров метилхлорстирола, изомеров метоксистирола, изомеров ацетоксистирола, изомеров гидроксистирола, изомеров метилгидроксистирола и их смесей.
6. Вспениваемая полимерная композиция по п. 4, в которой сополимеризуемые виниловые мономеры выбраны из (мет)акриловой кислоты, малеинового ангидрида, сложных алкиловых эфиров (мет)акриловой кислоты, содержащих от 1 до 18 атомов углерода, амидов и нитрилов (мет)акриловой кислоты.
7. Вспениваемая полимерная композиция по любому из пп. 1-6, в которой блок-сополимеры выбраны из блок-сополимеров типа полистирол-поли(этилен-бутилен)-полистирол или блок-сополимеров типа полистирол-поли(этилен-пропилен)-полистирол.
8. Вспениваемая полимерная композиция по любому из пп. 1-7, в которой сопряженные диены, которые можно использовать для получения блок-сополимеров (b), являются диенами, которые содержат от 4 до 8 атомов углерода.
9. Вспениваемая полимерная композиция по п. 8, в которой сопряженные диены выбраны из 1,3-бутадиена, изопрена, 2,3-диметил-1,3-бутадиена, пиперилена и их смесей.
10. Вспениваемая полимерная композиция по любому из пп. 1-9, в которой содержание винилароматического компонента в блок-сополимере (b) составляет от 20 масс. % до 45 масс. %.
11. Вспениваемая полимерная композиция по любому из пп. 1-10, в которой показатель текучести расплава (ПТР) винилароматического компонента в блок-сополимере больше или равен 1 г/10 мин, при измерении с помощью способа ASTM D1238, 5 кг, 200°С.
12. Вспениваемая полимерная композиция по любому из пп. 1-11, в которой вспениватель выбран из алифатических или циклоалифатических углеводородов, содержащих от 3 до 6 атомов углерода, и галогенированных производных алифатических углеводородов, содержащих от 1 до 3 атомов углерода.
13. Вспененные шарики, которые содержат композиции по любому из пп. 1-12.
14. Упаковка, содержащая вспененные шарики по п. 13.
15. Упаковка, содержащая композиции по любому из пп. 1-12.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT102016000080035A IT201600080035A1 (it) | 2016-07-29 | 2016-07-29 | Composizioni polimeriche espandibili a blocchi |
| IT102016000080035 | 2016-07-29 | ||
| PCT/EP2017/069166 WO2018019995A1 (en) | 2016-07-29 | 2017-07-28 | Block expandable polymeric compositions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2018138784A true RU2018138784A (ru) | 2020-08-28 |
| RU2018138784A3 RU2018138784A3 (ru) | 2020-10-26 |
| RU2745224C2 RU2745224C2 (ru) | 2021-03-22 |
Family
ID=58159227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2018138784A RU2745224C2 (ru) | 2016-07-29 | 2017-07-28 | Блочные вспениваемые полимерные композиции |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US11078342B2 (ru) |
| EP (1) | EP3491061B1 (ru) |
| JP (1) | JP7004670B2 (ru) |
| CN (1) | CN109476894B (ru) |
| BR (1) | BR112019001544B1 (ru) |
| ES (1) | ES2917614T3 (ru) |
| HU (1) | HUE059299T2 (ru) |
| IT (1) | IT201600080035A1 (ru) |
| MX (1) | MX2018013329A (ru) |
| MY (1) | MY198505A (ru) |
| PL (1) | PL3491061T3 (ru) |
| RU (1) | RU2745224C2 (ru) |
| WO (1) | WO2018019995A1 (ru) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT201800008073A1 (it) * | 2018-08-13 | 2020-02-13 | Versalis Spa | Composizione polimerica vinilaromatica espandibile a migliorate proprieta’ meccaniche e isolanti |
| DE102021104713A1 (de) | 2021-02-26 | 2022-09-01 | Sunpor Kunststoff Gmbh | Elastischer Partikelschaum |
| TWI798784B (zh) * | 2021-08-05 | 2023-04-11 | 財團法人工業技術研究院 | 耐衝擊聚苯乙烯樹脂 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA149002A (en) | 1913-05-22 | 1913-07-01 | Theron B. Bushnell | Drain valve for cooking vessels |
| US3595942A (en) | 1968-12-24 | 1971-07-27 | Shell Oil Co | Partially hydrogenated block copolymers |
| US3810957A (en) | 1970-08-10 | 1974-05-14 | Shell Oil Co | Selectively hydrogenated block copolymer-polystyrene blends |
| JPS54152069A (en) * | 1978-05-20 | 1979-11-29 | Asahi Chem Ind Co Ltd | Granular expandable styrene resin composition |
| JPH07119306B2 (ja) * | 1988-01-13 | 1995-12-20 | 出光興産株式会社 | 熱可塑性樹脂発泡体とその製造方法 |
| JP2841303B2 (ja) * | 1989-12-12 | 1998-12-24 | 旭化成工業株式会社 | 発泡用樹脂組成物とその発泡成形体 |
| JPH0489846A (ja) * | 1990-08-01 | 1992-03-24 | Sumitomo Chem Co Ltd | ポリスチレン系予備発泡粒子及びビーズ発泡成形品 |
| JP2795079B2 (ja) * | 1992-08-03 | 1998-09-10 | 住友化学工業株式会社 | ポリスチレン系樹脂発泡体 |
| DE4416862A1 (de) | 1994-05-13 | 1996-02-22 | Basf Ag | Expandierbare Styrolpolymerisate |
| DE19710442B4 (de) | 1997-03-13 | 2008-02-07 | Basf Ag | Expandierbare Styrolpolymerisate, Verfahren zu ihrer Herstellung sowie daraus hergestellte elastische Schaumstoffe |
| ITMI20012708A1 (it) | 2001-12-20 | 2003-06-20 | Enichem Spa | Dispositivo per la granulazione a caldo di polimeri termolastici |
| ITMI20020584A1 (it) * | 2002-03-20 | 2003-09-22 | Polimeri Europa Spa | Composizioni a base di polimeri vinilaromatici espandibili a migliorata espandibilita' |
| JP2007084744A (ja) | 2005-09-26 | 2007-04-05 | Sekisui Plastics Co Ltd | スチレン系樹脂発泡性粒子とその製造方法及びスチレン系樹脂発泡成形体 |
| CA2681782C (en) | 2007-04-11 | 2015-07-14 | Basf Se | Elastic particle foam based on polyolefin/styrene polymer mixtures |
| JP5248630B2 (ja) | 2008-03-13 | 2013-07-31 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリオレフィン／スチレンポリマー混合物に基づく弾性成形フォームビーズ |
| WO2010076213A1 (de) * | 2008-12-30 | 2010-07-08 | Basf Se | Elastischer partikelschaumstoff auf basis von polyolefin/styrolpolymer-mischungen |
| US8729143B2 (en) | 2008-12-30 | 2014-05-20 | Basf Se | Elastic particle foam based on polyolefin/styrene polymer mixtures |
| JP5523283B2 (ja) | 2010-11-02 | 2014-06-18 | 積水化成品工業株式会社 | ポリスチレン系樹脂発泡シート及びこれを用いてなる果菜包装容器 |
-
2016
- 2016-07-29 IT IT102016000080035A patent/IT201600080035A1/it unknown
-
2017
- 2017-07-28 CN CN201780045418.6A patent/CN109476894B/zh active Active
- 2017-07-28 PL PL17742780T patent/PL3491061T3/pl unknown
- 2017-07-28 BR BR112019001544-2A patent/BR112019001544B1/pt active IP Right Grant
- 2017-07-28 ES ES17742780T patent/ES2917614T3/es active Active
- 2017-07-28 MX MX2018013329A patent/MX2018013329A/es unknown
- 2017-07-28 JP JP2018557000A patent/JP7004670B2/ja active Active
- 2017-07-28 US US16/314,098 patent/US11078342B2/en active Active
- 2017-07-28 HU HUE17742780A patent/HUE059299T2/hu unknown
- 2017-07-28 MY MYPI2018001844A patent/MY198505A/en unknown
- 2017-07-28 RU RU2018138784A patent/RU2745224C2/ru active
- 2017-07-28 WO PCT/EP2017/069166 patent/WO2018019995A1/en not_active Ceased
- 2017-07-28 EP EP17742780.4A patent/EP3491061B1/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| IT201600080035A1 (it) | 2018-01-29 |
| PL3491061T3 (pl) | 2022-06-27 |
| ES2917614T3 (es) | 2022-07-11 |
| WO2018019995A1 (en) | 2018-02-01 |
| EP3491061A1 (en) | 2019-06-05 |
| CN109476894A (zh) | 2019-03-15 |
| US11078342B2 (en) | 2021-08-03 |
| US20190309138A1 (en) | 2019-10-10 |
| EP3491061B1 (en) | 2022-04-27 |
| JP7004670B2 (ja) | 2022-01-21 |
| HUE059299T2 (hu) | 2022-11-28 |
| BR112019001544A2 (pt) | 2019-05-14 |
| RU2745224C2 (ru) | 2021-03-22 |
| MY198505A (en) | 2023-09-01 |
| CN109476894B (zh) | 2021-05-25 |
| JP2019523310A (ja) | 2019-08-22 |
| BR112019001544B1 (pt) | 2024-01-16 |
| MX2018013329A (es) | 2019-05-02 |
| RU2018138784A3 (ru) | 2020-10-26 |
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