RU2018125648A - Композиция полипропилена с малой массой, армированная волокном - Google Patents
Композиция полипропилена с малой массой, армированная волокном Download PDFInfo
- Publication number
- RU2018125648A RU2018125648A RU2018125648A RU2018125648A RU2018125648A RU 2018125648 A RU2018125648 A RU 2018125648A RU 2018125648 A RU2018125648 A RU 2018125648A RU 2018125648 A RU2018125648 A RU 2018125648A RU 2018125648 A RU2018125648 A RU 2018125648A
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- Prior art keywords
- fiber
- polymer composition
- reinforced polymer
- mass
- propylene copolymer
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims 19
- 239000004743 Polypropylene Substances 0.000 title claims 12
- 229920001155 polypropylene Polymers 0.000 title claims 10
- -1 POLYPROPYLENE Polymers 0.000 title claims 7
- 229920002430 Fibre-reinforced plastic Polymers 0.000 claims 16
- 239000011151 fibre-reinforced plastic Substances 0.000 claims 16
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 10
- 229920001577 copolymer Polymers 0.000 claims 9
- 239000000835 fiber Substances 0.000 claims 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 2
- 239000005977 Ethylene Substances 0.000 claims 2
- 239000000945 filler Substances 0.000 claims 2
- 239000011521 glass Substances 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- 229920001384 propylene homopolymer Polymers 0.000 claims 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- 239000011324 bead Substances 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- 239000000919 ceramic Substances 0.000 claims 1
- 239000011152 fibreglass Substances 0.000 claims 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 1
- 239000011159 matrix material Substances 0.000 claims 1
- 239000000155 melt Substances 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000002557 mineral fiber Substances 0.000 claims 1
- 239000003607 modifier Substances 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
- 239000004711 α-olefin Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/28—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
- C08L2205/20—Hollow spheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
Claims (21)
1. Армированная волокном композиция полимера, содержащая:
(a) от 10 до 85 масс. % полипропилена (РР) от общей массы армированной волокном композиции полимера,
(b) от 12,5 до 53 масс. % волокна (F) от общей массы армированной волокно м композиции полимера,
(c) от 2 до 12 масс. % стеклянного наполнителя в виде шариков (GB) от общей массы армированной волокном композиции полимера, и
(d) от 0,5 до 5 масс. % полярного модифицированного полипропилена (РМР) в качестве связующего агента от общей массы армированной волокном композиции полимера.
2. Армированная волокном композиция полимера по п. 1, где полипропилен (РР) содержит гомополимер пропилена (Н-РР) и/или сополимер пропилена (С-РР).
3. Армированная волокном композиция полимера по п. 1 или 2, где полипропилен (РР) содержит гетерофазный сополимер пропилена (НЕСО), содержащий:
(a) полипропиленовую матрицу (М), представляющую гомополимер пропилена или сополимер пропилена, и
(b) эластомерный сополимер пропилена (Е), содержащий единицы, полученные из пропилена и
этилена и/или С4-С20 α-олефин.
4. Армированная волокном композиция полимера по п. 3, где гетерофазный сополимер пропилена (НЕСО) имеет:
(a) скорость течения расплава MFR2(230°C), измеренную согласно ISO1133, в пределах от 1,0 до 50 г/10 минут,
(b) содержание сомономера в пределах от 3,0 до 25 масс. % от общей массы гетерофазного сополимера пропилена (НЕСО), и
(c) содержание фракции, растворимой в холодном ксилоле (XCS), в пределах от 10 до 50 масс. % от общей массы гетерофазного сополимера пропилена (НЕСО).
5. Армированная волокном композиция полимера по любому из предшествующих пунктов, где армированная волокном композиция полимера дополнительно содержит вплоть до 20 масс. % модификатора, повышающего ударную прочность эластомерного полимера (IM), от общей массы армированной волокном композиции полимера.
6. Армированная волокном композиция полимера по любому из предшествующих пунктов, где волокна (F) имеют средний диаметр от 8 до 20 μм и аспектное соотношение от 125 до 650.
7. Армированная волокном композиция полимера по любому из предшествующих пунктов, где волокна (F) выбирают из группы, состоящей из стекловолокна, металлического волокна, минерального волокна, керамические волокна и их смесей.
8. Армированная волокном композиция полимера по любому из предшествующих пунктов, где стеклянный наполнитель в виде шариков (GB) имеет средний диаметр 10-50 μм.
9. Армированная волокном композиция полимера по любому из предшествующих пунктов, где полярный модифицированный полипропилен (РМР) представляет сополимер пропилена привитой малеиновым ангидридом, предпочтительно привитой малеиновым ангидридом сополимер пропилена содержит этилен в качестве сомономерных единиц.
10. Изделие для автомобильной промышленности, содержащее армированную волокном композицию полимера по любому из предшествующих пунктов.
11. Вспененное изделие, содержащее армированную волокном композицию полимера по любому из пп. 1-9.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15202256.2 | 2015-12-23 | ||
| EP15202256.2A EP3184586B1 (en) | 2015-12-23 | 2015-12-23 | Light weight fiber reinforced polypropylene composition |
| PCT/EP2016/081854 WO2017108746A1 (en) | 2015-12-23 | 2016-12-20 | Light weight fiber reinforced polypropylene composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2018125648A true RU2018125648A (ru) | 2020-01-23 |
| RU2018125648A3 RU2018125648A3 (ru) | 2020-01-23 |
Family
ID=55027445
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2018125648A RU2018125648A (ru) | 2015-12-23 | 2016-12-20 | Композиция полипропилена с малой массой, армированная волокном |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20180371210A1 (ru) |
| EP (2) | EP3184586B1 (ru) |
| CN (1) | CN108368314B (ru) |
| BR (1) | BR112018012105A2 (ru) |
| CA (1) | CA3008194C (ru) |
| ES (2) | ES2728953T3 (ru) |
| MX (1) | MX2018007220A (ru) |
| RU (1) | RU2018125648A (ru) |
| WO (1) | WO2017108746A1 (ru) |
| ZA (1) | ZA201803456B (ru) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL3309211T3 (pl) | 2016-10-17 | 2019-05-31 | Borealis Ag | Kompozyt polipropylenowy wzmocniony włóknem |
| CN107236189A (zh) * | 2017-06-26 | 2017-10-10 | 吉利汽车研究院（宁波）有限公司 | 低密度长玻纤增强聚丙烯复合材料及其制备方法 |
| EP3502166A1 (en) * | 2017-12-22 | 2019-06-26 | SABIC Global Technologies B.V. | Polypropylene composition comprising glass fibers |
| US11161968B2 (en) * | 2018-04-20 | 2021-11-02 | Ford Global Technologies, Llc | Ultra-low density polypropylene plastic compound |
| US10590269B2 (en) | 2018-04-20 | 2020-03-17 | Ford Global Technologies, Llc | Ultra-low density polypropylene plastic compound |
| EP3604425A1 (en) * | 2018-07-31 | 2020-02-05 | Borealis AG | Foamed polypropylene composition comprising polymeric fibers |
| KR102856942B1 (ko) | 2019-04-29 | 2025-09-05 | 이네오스 스티롤루션 그룹 게엠베하 | 반결정질 폴리머를 함유하는 폴리머 조성물 및 제조방법 |
| US20230203293A1 (en) | 2020-05-29 | 2023-06-29 | Ineos Styrolution Group Gmbh | Low-density abs composites |
| WO2022120648A1 (en) * | 2020-12-09 | 2022-06-16 | Borouge Compounding Shanghai Co., Ltd. | Glass fiber-filled polyolefin compositions with low shrinkage and warpage |
| US20240141116A1 (en) | 2020-12-16 | 2024-05-02 | Ineos Styrolution Group Gmbh | Process for producing a thermoplastic polymer-containing fiber-reinforced composite material |
| US20240132679A1 (en) | 2020-12-16 | 2024-04-25 | Ineos Styrolution Group Gmbh | Filler-containing thermoplastic polymer composite material reinforced with continuous fibers and having good surface smoothness |
| WO2023227738A1 (en) * | 2022-05-27 | 2023-11-30 | Sabic Global Technologies B.V. | Polypropylene composition for use in high-frequency radio-wave applications |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL232500A (ru) | 1957-10-22 | |||
| US3230064A (en) | 1960-10-21 | 1966-01-18 | Standard Oil Co | Apparatus for spherulization of fusible particles |
| US3365315A (en) | 1963-08-23 | 1968-01-23 | Minnesota Mining & Mfg | Glass bubbles prepared by reheating solid glass partiles |
| US4391646A (en) | 1982-02-25 | 1983-07-05 | Minnesota Mining And Manufacturing Company | Glass bubbles of increased collapse strength |
| US4767726A (en) | 1987-01-12 | 1988-08-30 | Minnesota Mining And Manufacturing Company | Glass microbubbles |
| IT1260495B (it) | 1992-05-29 | 1996-04-09 | Himont Inc | Concentrati adatti alla preparazione di poliolefine funzionalizzate e processo di funzionalizzazione mediante detti concentrati |
| KR20070004756A (ko) * | 2004-03-22 | 2007-01-09 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 충전된 섬유로 강화된 열가소성 복합재 |
| WO2006055612A1 (en) | 2004-11-16 | 2006-05-26 | 3M Innovative Properties Company | Microsphere filled polymer composites |
| KR100683230B1 (ko) * | 2006-02-16 | 2007-03-12 | 현대모비스 주식회사 | 폴리프로필렌 복합소재 조성물 |
| KR100921332B1 (ko) * | 2007-08-31 | 2009-10-13 | 지에스칼텍스 주식회사 | 착색 장섬유 강화 펠렛 및 이를 이용하여 제조된 착색 수지성형품 |
| EP2803693B1 (en) * | 2012-01-10 | 2020-03-04 | Toray Industries, Inc. | Carbon fiber-reinforced polypropylene sheet and molded article thereof |
| KR101495488B1 (ko) * | 2012-04-04 | 2015-02-24 | 보레알리스 아게 | 고-유동 섬유 강화 폴리프로필렌 조성물 |
| US20150187459A1 (en) * | 2012-07-03 | 2015-07-02 | Polyone Corporation | Low specific gravity thermoplastic compounds for neutral buoyancy underwater articles |
| KR101521147B1 (ko) * | 2013-12-10 | 2015-05-20 | 현대모비스 주식회사 | 내충격성이 향상된 장섬유강화 열가소성 수지 조성물 및 이에 의해 제조된 성형품 |
| WO2015103099A1 (en) | 2013-12-30 | 2015-07-09 | 3M Innovative Properties Company | Polyolefin composition including hollow glass microspheres and method of using the same |
-
2015
- 2015-12-23 EP EP15202256.2A patent/EP3184586B1/en active Active
- 2015-12-23 ES ES15202256T patent/ES2728953T3/es active Active
-
2016
- 2016-12-20 RU RU2018125648A patent/RU2018125648A/ru unknown
- 2016-12-20 BR BR112018012105A patent/BR112018012105A2/pt not_active Application Discontinuation
- 2016-12-20 WO PCT/EP2016/081854 patent/WO2017108746A1/en not_active Ceased
- 2016-12-20 US US16/062,377 patent/US20180371210A1/en not_active Abandoned
- 2016-12-20 MX MX2018007220A patent/MX2018007220A/es unknown
- 2016-12-20 EP EP16812760.3A patent/EP3394171B1/en active Active
- 2016-12-20 CN CN201680073393.6A patent/CN108368314B/zh not_active Expired - Fee Related
- 2016-12-20 ES ES16812760T patent/ES2774530T3/es active Active
- 2016-12-20 CA CA3008194A patent/CA3008194C/en not_active Expired - Fee Related
-
2018
- 2018-05-24 ZA ZA2018/03456A patent/ZA201803456B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017108746A1 (en) | 2017-06-29 |
| ZA201803456B (en) | 2019-02-27 |
| CN108368314B (zh) | 2019-05-31 |
| CA3008194C (en) | 2018-10-09 |
| ES2774530T3 (es) | 2020-07-21 |
| MX2018007220A (es) | 2018-08-01 |
| US20180371210A1 (en) | 2018-12-27 |
| CN108368314A (zh) | 2018-08-03 |
| RU2018125648A3 (ru) | 2020-01-23 |
| EP3184586B1 (en) | 2019-04-10 |
| BR112018012105A2 (pt) | 2018-12-04 |
| ES2728953T3 (es) | 2019-10-29 |
| EP3184586A1 (en) | 2017-06-28 |
| EP3394171B1 (en) | 2020-02-05 |
| EP3394171A1 (en) | 2018-10-31 |
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