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RU2017138532A - Оптическое волокно - Google Patents

Оптическое волокно Download PDF

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RU2017138532A
RU2017138532A RU2017138532A RU2017138532A RU2017138532A RU 2017138532 A RU2017138532 A RU 2017138532A RU 2017138532 A RU2017138532 A RU 2017138532A RU 2017138532 A RU2017138532 A RU 2017138532A RU 2017138532 A RU2017138532 A RU 2017138532A
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optical fiber
resin layer
compound
fiber according
group
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RU2017138532A
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RU2756680C2 (ru
RU2017138532A3 (ru
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Юя ХОММА
Кадзуюки СОХМА
Кенсаку СИМАДА
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Сумитомо Электрик Индастриз, Лтд.
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    • GPHYSICS
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    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/02395Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
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    • C03C25/326Polyureas; Polyurethanes
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    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/44Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
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    • C03C25/00Surface treatment of fibres or filaments made from glass, minerals or slags
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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    • C08G18/671Unsaturated compounds having only one group containing active hydrogen
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    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
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    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81Unsaturated isocyanates or isothiocyanates
    • C08G18/8141Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • C08G18/8175Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/53Phosphorus bound to oxygen bound to oxygen and to carbon only
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/53Phosphorus bound to oxygen bound to oxygen and to carbon only
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    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
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    • GPHYSICS
    • G02OPTICS
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    • G02B1/045Light guides
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    • G02OPTICS
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    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
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    • GPHYSICS
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    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/44Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
    • G02B6/4401Optical cables
    • G02B6/4402Optical cables with one single optical waveguide
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/44Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
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    • G02B6/443Protective covering

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  • Macromonomer-Based Addition Polymer (AREA)
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  • Surface Treatment Of Glass Fibres Or Filaments (AREA)

Claims (15)

1. Оптическое волокно, включающее
светопроводящую среду, имеющую сердцевину и оболочку;
первичный слой смолы, находящийся в контакте со светопроводящей средой и покрывающий светопроводящую среду; и
вторичный слой смолы, покрывающий первичный слой смолы,
где первичный слой смолы содержит отвержденный продукт композиции смолы, отверждаемой в ультрафиолетовом свете и содержащей в качестве компонентов уретан(мет)акрилатный олигомер, мономер, инициатор фотополимеризации и соединение, содержащее атомы фосфора и олова; и
модуль Юнга первичного слоя смолы равен 0,5 МПа или менее при 23°C.
2. Оптическое волокно по п. 1, где инициатор фотополимеризации содержит 2,4,6-триметилбензоилдифенилфосфин оксид.
3. Оптическое волокно по п. 1 или 2, где соединение, содержащее фосфор и олово, является продуктом взаимодействия, по меньшей мере, одного фосфорного соединения, выбранного из группы, включающей соединение, представленное формулой (1a), соединение, представленное формулой (1b), и соединение, представленное формулой (1c); и оловоорганического соединения:
Figure 00000001
,
где R1, R2, R3, и R4 каждый независимо обозначает алкильную группу, алкенильную группу или арильную группу.
4. Оптическое волокно по п. 3, где фосфорное соединение содержит, по меньшей мере, одно соединение, выбранное из группы, включающей дифенилфосфиновую кислоту, фенилфосфиновую кислоту и фенилфосфоновую кислоту.
5. Оптическое волокно по п. 3, где оловоорганическое соединение содержит, по меньшей мере, одно соединение, выбранное из группы, включающей дилаурат дибутилолова и диацетат дибутилолова.
6. Оптическое волокно по п. 1 или 2, где разница между температурой стеклования первичного слоя смолы и температурой стеклования вторичного слоя смолы составляет 150°C или менее.
7. Оптическое волокно по п. 1 или 2, где модуль Юнга первичного слоя смолы при 23°C составляет 0,25 МПа или менее.
8. Оптическое волокно по п. 1 или 2, где композиция смолы, отверждаемая в ультрафиолетовом свете, дополнительно содержит аминосоединение.
RU2017138532A 2016-11-08 2017-11-07 Оптическое волокно RU2756680C2 (ru)

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JP2016218039A JP2018077303A (ja) 2016-11-08 2016-11-08 光ファイバ心線
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RU2017138532A3 RU2017138532A3 (ru) 2021-03-19
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