RU2015102031A - Сополимер для улучшения термического сопротивления метакриловой смолы - Google Patents
Сополимер для улучшения термического сопротивления метакриловой смолы Download PDFInfo
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- 229920001577 copolymer Polymers 0.000 title claims abstract 13
- 239000011347 resin Substances 0.000 title 1
- 229920005989 resin Polymers 0.000 title 1
- 239000000178 monomer Substances 0.000 claims abstract 16
- 239000010408 film Substances 0.000 claims abstract 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract 6
- 150000002148 esters Chemical class 0.000 claims abstract 6
- 239000000113 methacrylic resin Substances 0.000 claims abstract 6
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 claims abstract 6
- 239000011342 resin composition Substances 0.000 claims abstract 6
- 229920002554 vinyl polymer Polymers 0.000 claims abstract 6
- 239000002253 acid Substances 0.000 claims abstract 4
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 claims abstract 4
- 230000003287 optical effect Effects 0.000 claims abstract 2
- 239000012788 optical film Substances 0.000 claims abstract 2
- 230000001681 protective effect Effects 0.000 claims abstract 2
- 238000002834 transmittance Methods 0.000 claims abstract 2
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Abstract
1. Сополимер для улучшения термического сопротивления метакриловой смолы, содержащий:от 45 до 85% по весу ароматического винилового мономера,от 5 до 45% по весу мономера сложного эфира мет(акриловой) кислоты иот 10 до 20% по весу мономера ангидрида ненасыщенной дикарбоновой кислоты,при этом указанный сополимер имеет общий коэффициент пропускания света 88% или более, измеренный согласно ASTM D1003 на образце толщиной 2 мм.2. Сополимер по п. 1, содержащий:от 50 до 80% по весу ароматического винилового мономера,от 8 до 38% по весу мономера сложного эфира мет(акриловой) кислоты иот 12 до 18% по весу мономера ангидрида ненасыщенной дикарбоновой кислоты.3. Сополимер по п. 1 или 2, в котором среднемассовая молекулярная масса (Mw) сополимера составляет от 10×10до 20×10.4. Композиция смолы, содержащая:от 5 до 50% по весу сополимера по любому из пп. 1-3 и от 50 до 95% по весу метакриловой смолы.5. Композиция смолы по п. 4, в которой метакриловая смола содержит:от 70 до 100% по весу мономера сложного эфира мет(акриловой) кислоты и от 0 до 30% по весу ароматического винилового мономера.6. Литое изделие, содержащее композицию смолы по п. 4 или 5.7. Литое изделие по п. 6, являющееся оптической деталью.8. Литое изделие по п. 7, являющееся оптической пленкой.9. Литое изделие по п. 8, являющееся защитной пленкой для поляризационной пленки, фазокомпенсирующей пленкой или просветляющей пленкой.
Claims (9)
1. Сополимер для улучшения термического сопротивления метакриловой смолы, содержащий:
от 45 до 85% по весу ароматического винилового мономера,
от 5 до 45% по весу мономера сложного эфира мет(акриловой) кислоты и
от 10 до 20% по весу мономера ангидрида ненасыщенной дикарбоновой кислоты,
при этом указанный сополимер имеет общий коэффициент пропускания света 88% или более, измеренный согласно ASTM D1003 на образце толщиной 2 мм.
2. Сополимер по п. 1, содержащий:
от 50 до 80% по весу ароматического винилового мономера,
от 8 до 38% по весу мономера сложного эфира мет(акриловой) кислоты и
от 12 до 18% по весу мономера ангидрида ненасыщенной дикарбоновой кислоты.
3. Сополимер по п. 1 или 2, в котором среднемассовая молекулярная масса (Mw) сополимера составляет от 10×104 до 20×104.
4. Композиция смолы, содержащая:
от 5 до 50% по весу сополимера по любому из пп. 1-3 и от 50 до 95% по весу метакриловой смолы.
5. Композиция смолы по п. 4, в которой метакриловая смола содержит:
от 70 до 100% по весу мономера сложного эфира мет(акриловой) кислоты и от 0 до 30% по весу ароматического винилового мономера.
6. Литое изделие, содержащее композицию смолы по п. 4 или 5.
7. Литое изделие по п. 6, являющееся оптической деталью.
8. Литое изделие по п. 7, являющееся оптической пленкой.
9. Литое изделие по п. 8, являющееся защитной пленкой для поляризационной пленки, фазокомпенсирующей пленкой или просветляющей пленкой.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012-168675 | 2012-07-30 | ||
| JP2012168675 | 2012-07-30 | ||
| PCT/JP2013/070484 WO2014021264A1 (ja) | 2012-07-30 | 2013-07-29 | メタクリル樹脂耐熱性向上用の共重合体 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2015102031A true RU2015102031A (ru) | 2016-09-20 |
| RU2623732C2 RU2623732C2 (ru) | 2017-06-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| RU2015102031A RU2623732C2 (ru) | 2012-07-30 | 2013-07-29 | Сополимер для улучшения термического сопротивления метакриловой смолы |
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| JP (1) | JP6055832B2 (ru) |
| KR (1) | KR102050371B1 (ru) |
| CN (1) | CN104540860B (ru) |
| IN (1) | IN2015DN01437A (ru) |
| RU (1) | RU2623732C2 (ru) |
| TW (1) | TWI572628B (ru) |
| WO (1) | WO2014021264A1 (ru) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2640362T3 (es) * | 2012-10-22 | 2017-11-02 | Denka Company Limited | Composición de resina de vinilo aromático-cianuro de vinilo con termorresistencia mejorada |
| WO2015178437A1 (ja) * | 2014-05-22 | 2015-11-26 | 電気化学工業株式会社 | 透明耐擦傷性板用共重合体、透明耐擦傷性板用積層体 |
| JP6693041B2 (ja) * | 2014-07-14 | 2020-05-13 | 三菱ケミカル株式会社 | 積層体 |
| JP2016037522A (ja) * | 2014-08-06 | 2016-03-22 | デンカ株式会社 | 発泡成形体用スチレン系共重合体 |
| EP3181600B1 (en) * | 2014-08-11 | 2018-06-13 | Denka Company Limited | Copolymer suitable for improving heat resistance of methacrylic resin |
| CN104497461B (zh) * | 2014-12-15 | 2017-08-29 | 上海锦湖日丽塑料有限公司 | 一种耐热耐刮擦高透过率pmma合金树脂组合物及其制备方法 |
| KR20170104534A (ko) * | 2015-01-15 | 2017-09-15 | 덴카 주식회사 | 투명한 고내열성 수지 조성물 |
| JP6475501B2 (ja) * | 2015-01-26 | 2019-02-27 | デンカ株式会社 | 塩化ビニル樹脂耐熱改質用共重合体、成形体、塩化ビニル配管 |
| WO2016132743A1 (ja) | 2015-02-20 | 2016-08-25 | 株式会社クラレ | 樹脂組成物、成形品および積層体 |
| KR20180004770A (ko) * | 2015-05-11 | 2018-01-12 | 덴카 주식회사 | 수지 조성물, 자동차 투명 부재용 수지 조성물, 미터 패널 투명 커버, 반구형 렌즈 |
| CN107614622A (zh) * | 2015-05-20 | 2018-01-19 | 电化株式会社 | 透明树脂组合物及其制造方法 |
| TW201714949A (zh) * | 2015-08-25 | 2017-05-01 | Denka Company Ltd | 發泡成形用熱塑性樹脂組合物、發泡體 |
| KR101874160B1 (ko) | 2015-09-30 | 2018-07-04 | 롯데첨단소재(주) | 투명 열가소성 수지 조성물 및 이로부터 형성된 성형품 |
| EP3385290A4 (en) | 2015-11-30 | 2018-12-05 | Denka Company Limited | Transparent highly heat-resistant styrene copolymer |
| WO2017162393A1 (en) * | 2016-03-21 | 2017-09-28 | Sabic Global Technologies B.V. | Polymer composition comprising a (meth)acrylic polymer having good optical properties and heat resistance |
| JP6707400B2 (ja) * | 2016-05-31 | 2020-06-10 | Psジャパン株式会社 | スチレン系樹脂、スチレン系樹脂組成物、そのシート及び成形品、並びにスチレン系樹脂の製造方法 |
| WO2018008579A1 (ja) * | 2016-07-06 | 2018-01-11 | デンカ株式会社 | 偏光子保護フィルム用樹脂組成物、偏光子保護フィルム |
| JP2018012530A (ja) * | 2016-07-21 | 2018-01-25 | デンカ株式会社 | 二軸延伸シートおよび包装用容器 |
| KR102261383B1 (ko) | 2016-07-22 | 2021-06-07 | 덴카 주식회사 | 수지 조성물 및 그 수지 조성물로 이루어진 필름 |
| FR3056218B1 (fr) | 2016-09-20 | 2020-10-02 | Arkema France | Composition de polymere, son procede de preparation, son utilisation et objet comprenant celle-ci |
| EP3581609B1 (en) | 2017-02-07 | 2023-08-02 | Kuraray Co., Ltd. | Acrylic resin biaxially stretched film and method for manufacturing the same |
| EP3676328B1 (en) * | 2017-08-29 | 2022-10-05 | SABIC Global Technologies B.V. | Lighting system component comprising a heat-resistant polymer |
| KR102236413B1 (ko) | 2018-11-30 | 2021-04-05 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 형성된 성형품 |
| JP2020011517A (ja) * | 2019-10-09 | 2020-01-23 | 三菱ケミカル株式会社 | 積層体 |
| WO2021193922A1 (ja) | 2020-03-26 | 2021-09-30 | 株式会社クラレ | アクリル系組成物及び成形体 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3725360A (en) * | 1971-03-11 | 1973-04-03 | Dow Chemical Co | Process for polymerizing styrene and maleic anhydride |
| JPS57153008A (en) * | 1981-03-19 | 1982-09-21 | Asahi Chem Ind Co Ltd | Methacrylic resin having excellent heat resistance |
| US4387191A (en) * | 1982-03-25 | 1983-06-07 | Monsanto Company | Heat stabilized polymers |
| JPH0686497B2 (ja) * | 1983-12-27 | 1994-11-02 | 三井東圧化学株式会社 | スチレン系共重合体 |
| JPH0214207A (ja) * | 1988-06-30 | 1990-01-18 | Kyowa Gas Chem Ind Co Ltd | 離型性の改良された注型成形品の製造法 |
| FR2852963A1 (fr) * | 2003-03-26 | 2004-10-01 | Atofina | Nouveau procede de synthese/fabrication de films acryliques |
| WO2006107970A2 (en) * | 2005-04-06 | 2006-10-12 | 3M Innovative Properties Company | Diffuse reflective polariziing films with orientable polymer blends |
| US11214045B2 (en) * | 2006-05-23 | 2022-01-04 | Trinseo Europe Gmbh | Multi-layer coextrusion method |
| JP5191667B2 (ja) * | 2007-01-29 | 2013-05-08 | 旭化成イーマテリアルズ株式会社 | スチレン系樹脂異方性フィルム |
| JPWO2009031544A1 (ja) | 2007-09-04 | 2010-12-16 | 電気化学工業株式会社 | 熱可塑性共重合樹脂及びその光学成形体 |
| CN101162364B (zh) * | 2007-11-30 | 2011-04-20 | 京东方科技集团股份有限公司 | 感光树脂组合物及其制备方法和成膜方法 |
| KR101035725B1 (ko) * | 2007-12-20 | 2011-05-19 | 주식회사 엘지화학 | 다층 구조의 아크릴계 위상차 필름 및 그 제조방법 |
| US8779076B2 (en) * | 2007-12-27 | 2014-07-15 | Asahi Kasei Chemicals Corporation | Thermoplastic acrylic resin and molded body for optical member |
| JP5340307B2 (ja) * | 2008-01-03 | 2013-11-13 | エルジー・ケム・リミテッド | 光学フィルム、偏光子保護フィルム、これを用いた偏光板、およびこれを用いた画像表示装置 |
| KR101105424B1 (ko) * | 2008-04-30 | 2012-01-17 | 주식회사 엘지화학 | 수지 조성물 및 이를 이용하여 형성된 광학 필름 |
| CN102272640B (zh) * | 2009-01-06 | 2013-09-11 | Lg化学株式会社 | 光学膜和包括该光学膜的液晶显示器 |
| TWI439474B (zh) * | 2009-10-22 | 2014-06-01 | Asahi Kasei Chemicals Corp | Methacrylic resin, which is molded into the manufacture of acrylic resins and methacrylic method |
| ES2640362T3 (es) * | 2012-10-22 | 2017-11-02 | Denka Company Limited | Composición de resina de vinilo aromático-cianuro de vinilo con termorresistencia mejorada |
-
2013
- 2013-07-29 WO PCT/JP2013/070484 patent/WO2014021264A1/ja not_active Ceased
- 2013-07-29 EP EP13825255.6A patent/EP2881407B1/en not_active Not-in-force
- 2013-07-29 KR KR1020157002361A patent/KR102050371B1/ko not_active Expired - Fee Related
- 2013-07-29 CN CN201380040699.8A patent/CN104540860B/zh not_active Expired - Fee Related
- 2013-07-29 RU RU2015102031A patent/RU2623732C2/ru active
- 2013-07-29 JP JP2014528145A patent/JP6055832B2/ja not_active Expired - Fee Related
- 2013-07-29 IN IN1437DEN2015 patent/IN2015DN01437A/en unknown
- 2013-07-29 US US14/417,721 patent/US20150203610A1/en not_active Abandoned
- 2013-07-30 TW TW102127211A patent/TWI572628B/zh not_active IP Right Cessation
-
2016
- 2016-07-21 US US15/216,265 patent/US9873787B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| RU2623732C2 (ru) | 2017-06-29 |
| US9873787B2 (en) | 2018-01-23 |
| EP2881407B1 (en) | 2017-12-06 |
| KR102050371B1 (ko) | 2019-11-29 |
| US20160326360A1 (en) | 2016-11-10 |
| CN104540860A (zh) | 2015-04-22 |
| EP2881407A1 (en) | 2015-06-10 |
| KR20150037919A (ko) | 2015-04-08 |
| EP2881407A4 (en) | 2016-04-13 |
| CN104540860B (zh) | 2017-03-08 |
| TWI572628B (zh) | 2017-03-01 |
| WO2014021264A1 (ja) | 2014-02-06 |
| US20150203610A1 (en) | 2015-07-23 |
| JP6055832B2 (ja) | 2016-12-27 |
| IN2015DN01437A (ru) | 2015-07-03 |
| TW201410718A (zh) | 2014-03-16 |
| JPWO2014021264A1 (ja) | 2016-07-21 |
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