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RU2013152876A - HEAT TRANSMISSION COMPOSITIONS AND METHODS OF HEAT TRANSFER - Google Patents

HEAT TRANSMISSION COMPOSITIONS AND METHODS OF HEAT TRANSFER Download PDF

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Publication number
RU2013152876A
RU2013152876A RU2013152876/05A RU2013152876A RU2013152876A RU 2013152876 A RU2013152876 A RU 2013152876A RU 2013152876/05 A RU2013152876/05 A RU 2013152876/05A RU 2013152876 A RU2013152876 A RU 2013152876A RU 2013152876 A RU2013152876 A RU 2013152876A
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RU
Russia
Prior art keywords
hfo
weight
heat transfer
hfc
transfer composition
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RU2013152876/05A
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Russian (ru)
Inventor
Сэмюэл Ф. Яна МОТТА
Марк В. СПАТЦ
Роналд П. ВОГЛ
Элизабет Дел Кармен Вера БЕСЕРРА
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Ханивелл Интернешнл Инк.
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Priority claimed from US13/099,218 external-priority patent/US20110219815A1/en
Application filed by Ханивелл Интернешнл Инк. filed Critical Ханивелл Интернешнл Инк.
Publication of RU2013152876A publication Critical patent/RU2013152876A/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02Materials undergoing a change of physical state when used
    • C09K5/04Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02Materials undergoing a change of physical state when used
    • C09K5/04Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/12Hydrocarbons
    • C09K2205/126Unsaturated fluorinated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/22All components of a mixture being fluoro compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/40Replacement mixtures

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Ink Jet (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1. Теплопередающая композиция, содержащая (а) от около 20% до около 30% по весу HFC-32; (б) от около 20% до около 30% по весу HFC-125; (в) от около 0% до около 15% по весу HFO-1234yf и от около 10% до около 30% по весу HFO-1234ze; (г) от около 15% до около 30% по весу HFC-134a в пересчете на общее содержание компонентов (а)-(г) в композиции.2. Теплопередающая композиция по п.1, в которой HFO-1234ze представляет собой транс-HFO-1234ze.3. Теплопередающая композиция по п.1, в которой весовое соотношение HFC-32 и HFC-125 составляет от около 0,9:1,2 до около 1,2:0,9.4. Теплопередающая композиция по п.1, содержащая от более 0% до около 15% по весу HFO-1234yf и от около 10% до около 30% по весу HFO-1234ze.5. Теплопередающая композиция по п.1, в которой весовое соотношение HFC-134a и сочетания HFO-1234ze и HFO-1234yf составляет от около 5:7 до около 1:1.6. Теплопередающая композиция по п.1, содержащая HFO-1234ze в количестве около 20% и HFO-1234yf в количестве около 9%.7. Теплопередающая композиция по п.1, содержащая HFO-1234ze в количестве около 26%.8. Теплопередающая композиция по п.1, содержащая HFO-1234ze в количестве около 17% и HFO-1234yf в количестве около 9%.9. Способ замены существующего жидкотекучего теплоносителя, содержащегося в системе теплопередачи, включающий удаление из системы по меньшей мере части имеющегося жидкотекучего теплоносителя, которым является HFC-404A, и замену по меньшей мере части имеющегося жидкотекучего теплоносителя путем включения в систему теплопередающей композиции, включающей (а) от около 20% до около 30% по весу HFC-32; (б) от около 20% до около 30% по весу HFC-125; (в) от около 0% до около 15% по весу HFO-1234yf и от около 10% до около 30% по весу HFO-1234ze; (г) от около 15% до около 30% по весу HFC-134a в пересчете на общее содержание компонентов (а)-(г) в композиции.10. Система т1. Heat transfer composition containing (a) from about 20% to about 30% by weight of HFC-32; (b) about 20% to about 30% by weight of HFC-125; (c) about 0% to about 15% by weight of HFO-1234yf and about 10% to about 30% by weight of HFO-1234ze; (d) from about 15% to about 30% by weight of HFC-134a based on the total content of components (a) - (d) in the composition. 2. The heat transfer composition of claim 1, wherein the HFO-1234ze is trans-HFO-1234ze. The heat transfer composition of claim 1, wherein the weight ratio of HFC-32 to HFC-125 is from about 0.9: 1.2 to about 1.2: 0.9. The heat transfer composition of claim 1, comprising more than 0% to about 15% by weight of HFO-1234yf and from about 10% to about 30% by weight of HFO-1234ze. The heat transfer composition of claim 1, wherein the weight ratio of HFC-134a and the combination of HFO-1234ze and HFO-1234yf is from about 5: 7 to about 1: 1.6. The heat transfer composition of claim 1, comprising about 20% HFO-1234ze and about 9% HFO-1234yf. The heat transfer composition of claim 1, comprising about 26% HFO-1234ze. The heat transfer composition of claim 1, comprising about 17% HFO-1234ze and about 9% HFO-1234yf. A method of replacing an existing heat transfer fluid contained in a heat transfer system, comprising removing from the system at least a portion of the existing heat transfer fluid, which is HFC-404A, and replacing at least a portion of the existing heat transfer fluid by including a heat transfer composition comprising (a) from about 20% to about 30% by weight of HFC-32; (b) about 20% to about 30% by weight of HFC-125; (c) about 0% to about 15% by weight of HFO-1234yf and about 10% to about 30% by weight of HFO-1234ze; (d) about 15% to about 30% by weight of HFC-134a based on the total content of components (a) - (d) in the composition. 10. System t

Claims (10)

1. Теплопередающая композиция, содержащая (а) от около 20% до около 30% по весу HFC-32; (б) от около 20% до около 30% по весу HFC-125; (в) от около 0% до около 15% по весу HFO-1234yf и от около 10% до около 30% по весу HFO-1234ze; (г) от около 15% до около 30% по весу HFC-134a в пересчете на общее содержание компонентов (а)-(г) в композиции.1. A heat transfer composition comprising (a) from about 20% to about 30% by weight of HFC-32; (b) from about 20% to about 30% by weight of HFC-125; (c) from about 0% to about 15% by weight of HFO-1234yf and from about 10% to about 30% by weight of HFO-1234ze; (g) from about 15% to about 30% by weight of HFC-134a, calculated on the total content of components (a) to (g) in the composition. 2. Теплопередающая композиция по п.1, в которой HFO-1234ze представляет собой транс-HFO-1234ze.2. The heat transfer composition according to claim 1, wherein the HFO-1234ze is trans-HFO-1234ze. 3. Теплопередающая композиция по п.1, в которой весовое соотношение HFC-32 и HFC-125 составляет от около 0,9:1,2 до около 1,2:0,9.3. The heat transfer composition according to claim 1, in which the weight ratio of HFC-32 and HFC-125 is from about 0.9: 1.2 to about 1.2: 0.9. 4. Теплопередающая композиция по п.1, содержащая от более 0% до около 15% по весу HFO-1234yf и от около 10% до около 30% по весу HFO-1234ze.4. The heat transfer composition according to claim 1, containing from more than 0% to about 15% by weight of HFO-1234yf and from about 10% to about 30% by weight of HFO-1234ze. 5. Теплопередающая композиция по п.1, в которой весовое соотношение HFC-134a и сочетания HFO-1234ze и HFO-1234yf составляет от около 5:7 до около 1:1.5. The heat transfer composition according to claim 1, in which the weight ratio of HFC-134a and the combination of HFO-1234ze and HFO-1234yf is from about 5: 7 to about 1: 1. 6. Теплопередающая композиция по п.1, содержащая HFO-1234ze в количестве около 20% и HFO-1234yf в количестве около 9%.6. The heat transfer composition according to claim 1, containing HFO-1234ze in an amount of about 20% and HFO-1234yf in an amount of about 9%. 7. Теплопередающая композиция по п.1, содержащая HFO-1234ze в количестве около 26%.7. The heat transfer composition according to claim 1, containing HFO-1234ze in an amount of about 26%. 8. Теплопередающая композиция по п.1, содержащая HFO-1234ze в количестве около 17% и HFO-1234yf в количестве около 9%.8. The heat transfer composition according to claim 1, containing HFO-1234ze in an amount of about 17% and HFO-1234yf in an amount of about 9%. 9. Способ замены существующего жидкотекучего теплоносителя, содержащегося в системе теплопередачи, включающий удаление из системы по меньшей мере части имеющегося жидкотекучего теплоносителя, которым является HFC-404A, и замену по меньшей мере части имеющегося жидкотекучего теплоносителя путем включения в систему теплопередающей композиции, включающей (а) от около 20% до около 30% по весу HFC-32; (б) от около 20% до около 30% по весу HFC-125; (в) от около 0% до около 15% по весу HFO-1234yf и от около 10% до около 30% по весу HFO-1234ze; (г) от около 15% до около 30% по весу HFC-134a в пересчете на общее содержание компонентов (а)-(г) в композиции.9. A method of replacing an existing fluid fluid contained in a heat transfer system, comprising removing from the system at least a portion of the existing fluid fluid, which is HFC-404A, and replacing at least a portion of the existing fluid fluid by incorporating a heat transfer composition comprising (a ) from about 20% to about 30% by weight of HFC-32; (b) from about 20% to about 30% by weight of HFC-125; (c) from about 0% to about 15% by weight of HFO-1234yf and from about 10% to about 30% by weight of HFO-1234ze; (g) from about 15% to about 30% by weight of HFC-134a, calculated on the total content of components (a) to (g) in the composition. 10. Система теплопередачи, содержащая компрессор, конденсатор и испаритель, образующие канал для движения текучей среды, и содержащая теплопередающую композицию, содержащую (а) от около 20% до около 30% по весу HFC-32; (б) от около 20% до около 30% по весу HFC-125; (в) от около 0% до около 15% по весу HFO-1234yf и от около 10% до около 30% по весу HFO-1234ze; (г) от около 15% до около 30% по весу HFC-134a, в пересчете на общее содержание компонентов (а)-(г) в композиции, при этом рабочая температура конденсатора составляет от около 35°С до около 45°C. 10. A heat transfer system comprising a compressor, a condenser, and an evaporator forming a channel for moving a fluid, and comprising a heat transfer composition comprising (a) from about 20% to about 30% by weight of HFC-32; (b) from about 20% to about 30% by weight of HFC-125; (c) from about 0% to about 15% by weight of HFO-1234yf and from about 10% to about 30% by weight of HFO-1234ze; (g) from about 15% to about 30% by weight of HFC-134a, in terms of the total content of components (a) to (g) in the composition, wherein the working temperature of the condenser is from about 35 ° C to about 45 ° C.
RU2013152876/05A 2011-05-02 2012-05-02 HEAT TRANSMISSION COMPOSITIONS AND METHODS OF HEAT TRANSFER RU2013152876A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US13/099,218 US20110219815A1 (en) 2009-05-08 2011-05-02 Heat transfer compositions and methods
US13/099,218 2011-05-02
US201261598056P 2012-02-13 2012-02-13
US61/598,056 2012-02-13
PCT/US2012/036056 WO2012151238A2 (en) 2011-05-02 2012-05-02 Heat transfer compositions and methods

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KR (1) KR20140027362A (en)
CN (1) CN103635558A (en)
AU (1) AU2012250863A1 (en)
BR (1) BR112013028071A2 (en)
CA (1) CA2834894A1 (en)
MX (1) MX2013012673A (en)
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EP2705107A2 (en) 2014-03-12
KR20140027362A (en) 2014-03-06
CN103635558A (en) 2014-03-12
CA2834894A1 (en) 2012-11-08
BR112013028071A2 (en) 2020-08-04
AU2012250863A1 (en) 2013-11-14
MX2013012673A (en) 2013-12-02
EP2705107A4 (en) 2014-10-15
WO2012151238A2 (en) 2012-11-08
WO2012151238A3 (en) 2013-02-28
JP2014514423A (en) 2014-06-19

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