[go: up one dir, main page]

RU2012113135A - METHOD OF UNITED GASIFICATION OF RESIDUALS OF LIQUID AND SOLID FUEL - Google Patents

METHOD OF UNITED GASIFICATION OF RESIDUALS OF LIQUID AND SOLID FUEL Download PDF

Info

Publication number
RU2012113135A
RU2012113135A RU2012113135/05A RU2012113135A RU2012113135A RU 2012113135 A RU2012113135 A RU 2012113135A RU 2012113135/05 A RU2012113135/05 A RU 2012113135/05A RU 2012113135 A RU2012113135 A RU 2012113135A RU 2012113135 A RU2012113135 A RU 2012113135A
Authority
RU
Russia
Prior art keywords
ash
reactor
solid fuel
gasification
fuel
Prior art date
Application number
RU2012113135/05A
Other languages
Russian (ru)
Other versions
RU2553156C2 (en
Inventor
Кристоф ХАНРОТТ
Макс ХАЙНРИЦ-АДРИАН
Адриан БРАНДЛЬ
Original Assignee
ТюссенКрупп Уде ГмбХ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ТюссенКрупп Уде ГмбХ filed Critical ТюссенКрупп Уде ГмбХ
Publication of RU2012113135A publication Critical patent/RU2012113135A/en
Application granted granted Critical
Publication of RU2553156C2 publication Critical patent/RU2553156C2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/50—Fuel charging devices
    • C10J3/506—Fuel charging devices for entrained flow gasifiers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C10J2300/0933—Coal fines for producing water gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C10J2300/0936—Coal fines for producing producer gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0989—Hydrocarbons as additives to gasifying agents to improve caloric properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/12—Heating the gasifier
    • C10J2300/1223—Heating the gasifier by burners

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Industrial Gases (AREA)
  • Processing Of Solid Wastes (AREA)
  • Combustion Of Fluid Fuel (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1. Способ получения синтез-газа путем газификации золосодержащих жидких остатков газификации в неподвижном слое при давлении от 0,3 до 0,8 МПа и температуре выше 1400°С с помощью кислородосодержащих газообразных газифицирующих агентов в охлаждаемом реакторе, отличающийся тем, чтозолосодержащее жидкое топливо и золосодержащее твердое топливо подают в реактор,жидкое и твердое топливо подают в реактор раздельно через несколько систем горелок,жидкое и твердое топливо подают в реактор по секущей к окружности реактора при угле горения более 0°С,золосодержащее твердое топливо, подаваемое в реактор, диспергировано в транспортном газе, изолосодержащее твердое топливо, по меньшей мере частично, состоит из мелких частиц угля, полученных при добыче угля, которые непригодны для газификации в неподвижном слое.2. Способ по п.1, отличающийся тем, что остаток газификации в неподвижном слое содержит углеводороды, в частности смолы, но также фенолы, жирные кислоты и аммиак.3. Способ по п.1, отличающийся тем, что углеродсодержащее твердое топливо представляет собой мелкие частицы угля, предпочтительно, менее 5 мм, которые непригодны для газификации в неподвижном слое.4. Способ по п.1, отличающийся тем, что система горелок для подачи золосодержащего жидкого топлива состоит из трех концентрично расположенных труб, при этом по внешней и внутренней трубе системы горелок подают кислород или кислородосодержащий газ, а золосодержащее жидкое топливо подают по среднему кольцевому зазору, образованному внешней и внутренней трубами.5. Способ по п.4, отличающийся тем, что система горелок с тремя концентрично расположенными трубами содержит су�1. A method for producing synthesis gas by gasifying ash-containing liquid gasification residues in a fixed bed at a pressure from 0.3 to 0.8 MPa and a temperature above 1400°C using oxygen-containing gaseous gasifying agents in a cooled reactor, characterized in that ash-containing liquid fuel and ash-containing solid fuel is supplied to the reactor, liquid and solid fuel are supplied to the reactor separately through several burner systems, liquid and solid fuel are supplied to the reactor along a secant line to the circumference of the reactor at a combustion angle of more than 0°C, ash-containing solid fuel supplied to the reactor is dispersed in transport gas, the ash-containing solid fuel consists at least in part of fine coal particles obtained from coal mining, which are unsuitable for gasification in a fixed bed.2. Method according to claim 1, characterized in that the gasification residue in the fixed bed contains hydrocarbons, in particular resins, but also phenols, fatty acids and ammonia.3. The method according to claim 1, characterized in that the carbon-containing solid fuel is fine coal particles, preferably less than 5 mm, which are unsuitable for gasification in a fixed bed.4. The method according to claim 1, characterized in that the burner system for supplying ash-containing liquid fuel consists of three concentrically located pipes, while oxygen or oxygen-containing gas is supplied through the outer and inner pipes of the burner system, and ash-containing liquid fuel is supplied through the middle annular gap formed external and internal pipes.5. The method according to claim 4, characterized in that the burner system with three concentrically located pipes contains dry

Claims (10)

1. Способ получения синтез-газа путем газификации золосодержащих жидких остатков газификации в неподвижном слое при давлении от 0,3 до 0,8 МПа и температуре выше 1400°С с помощью кислородосодержащих газообразных газифицирующих агентов в охлаждаемом реакторе, отличающийся тем, что1. The method of producing synthesis gas by gasification of ash-containing liquid gasification residues in a fixed bed at a pressure of from 0.3 to 0.8 MPa and a temperature above 1400 ° C using oxygen-containing gaseous gasifying agents in a cooled reactor, characterized in that золосодержащее жидкое топливо и золосодержащее твердое топливо подают в реактор,ash-containing liquid fuel and ash-containing solid fuel are fed to the reactor, жидкое и твердое топливо подают в реактор раздельно через несколько систем горелок,liquid and solid fuels are fed to the reactor separately through several burner systems, жидкое и твердое топливо подают в реактор по секущей к окружности реактора при угле горения более 0°С,liquid and solid fuel is fed into the reactor along the secant to the circumference of the reactor at a combustion angle of more than 0 ° C, золосодержащее твердое топливо, подаваемое в реактор, диспергировано в транспортном газе, иthe ash-containing solid fuel supplied to the reactor is dispersed in the transport gas, and золосодержащее твердое топливо, по меньшей мере частично, состоит из мелких частиц угля, полученных при добыче угля, которые непригодны для газификации в неподвижном слое.ash-containing solid fuel, at least partially, consists of small particles of coal obtained by coal mining, which are unsuitable for gasification in a fixed bed. 2. Способ по п.1, отличающийся тем, что остаток газификации в неподвижном слое содержит углеводороды, в частности смолы, но также фенолы, жирные кислоты и аммиак.2. The method according to claim 1, characterized in that the gasification residue in the fixed bed contains hydrocarbons, in particular resins, but also phenols, fatty acids and ammonia. 3. Способ по п.1, отличающийся тем, что углеродсодержащее твердое топливо представляет собой мелкие частицы угля, предпочтительно, менее 5 мм, которые непригодны для газификации в неподвижном слое.3. The method according to claim 1, characterized in that the carbon-containing solid fuel is small particles of coal, preferably less than 5 mm, which are unsuitable for gasification in a fixed bed. 4. Способ по п.1, отличающийся тем, что система горелок для подачи золосодержащего жидкого топлива состоит из трех концентрично расположенных труб, при этом по внешней и внутренней трубе системы горелок подают кислород или кислородосодержащий газ, а золосодержащее жидкое топливо подают по среднему кольцевому зазору, образованному внешней и внутренней трубами.4. The method according to claim 1, characterized in that the burner system for supplying ash-containing liquid fuel consists of three concentrically arranged pipes, while oxygen or oxygen-containing gas is supplied through the outer and inner tubes of the burner system, and the ash-containing liquid fuel is fed through the middle annular gap formed by the outer and inner pipes. 5. Способ по п.4, отличающийся тем, что система горелок с тремя концентрично расположенными трубами содержит сужающийся на конус наконечник, так же как и охлаждающая камера в области выхода горелок.5. The method according to claim 4, characterized in that the burner system with three concentrically arranged pipes contains a tip tapering to a cone, as well as a cooling chamber in the burner exit region. 6. Способ по п.1, отличающийся тем, что углеродсодержащее топливо подают по двум или более расположенным напротив друг друга системам горелок, а по смещенным относительно них на угол 90° в горизонтальной плоскости двум или более расположенным напротив друг друга системам горелок подают золосодержащее жидкое топливо.6. The method according to claim 1, characterized in that the carbon-containing fuel is supplied via two or more opposed to each other burner systems, and ash-containing liquid is fed through two or more opposed to each other burner systems offset relative to them by a horizontal angle of 90 ° fuel. 7. Способ по п.1, отличающийся тем, что системы горелок размещены в одной или нескольких горизонтальных плоскостях.7. The method according to claim 1, characterized in that the burner system is placed in one or more horizontal planes. 8. Способ по п.1, отличающийся тем, что угол горения между направлением вытекания топлива и соединительной линией между соплом горелки и осью симметрии реактора составляет 3-6°.8. The method according to claim 1, characterized in that the combustion angle between the direction of flow of fuel and the connecting line between the nozzle of the burner and the axis of symmetry of the reactor is 3-6 °. 9. Способ по любому из пп.1-8, отличающийся тем, что угол горения по отношению к горизонтальной поверхности составляет более 0°.9. The method according to any one of claims 1 to 8, characterized in that the combustion angle with respect to the horizontal surface is more than 0 °. 10. Способ по п.9, отличающийся тем, что транспортный газ на 100% или менее состоит из азота или диоксида углерода, или сочетания этих газов. 10. The method according to claim 9, characterized in that the transport gas is 100% or less composed of nitrogen or carbon dioxide, or a combination of these gases.
RU2012113135/02A 2009-09-18 2010-09-09 Method for combined gasification of residual fluid and solid fuel RU2553156C2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102009041854A DE102009041854A1 (en) 2009-09-18 2009-09-18 Process for the combined residue gasification of liquid and solid fuels
DE102009041854.7 2009-09-18
PCT/EP2010/005542 WO2011032663A2 (en) 2009-09-18 2010-09-09 Method for the combined residue gasification of liquid and solid fuels

Publications (2)

Publication Number Publication Date
RU2012113135A true RU2012113135A (en) 2013-11-10
RU2553156C2 RU2553156C2 (en) 2015-06-10

Family

ID=43603419

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2012113135/02A RU2553156C2 (en) 2009-09-18 2010-09-09 Method for combined gasification of residual fluid and solid fuel

Country Status (13)

Country Link
US (1) US20120266539A1 (en)
EP (1) EP2478072A2 (en)
KR (1) KR20120093881A (en)
CN (1) CN102549117A (en)
AU (1) AU2010294844B2 (en)
BR (1) BR112012005838A2 (en)
CA (1) CA2774445A1 (en)
DE (1) DE102009041854A1 (en)
RU (1) RU2553156C2 (en)
TW (1) TWI500755B (en)
UA (1) UA107470C2 (en)
WO (1) WO2011032663A2 (en)
ZA (1) ZA201202798B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2012324965B2 (en) * 2011-10-21 2015-06-11 Air Products And Chemicals, Inc. Gasification reactor
KR101353783B1 (en) 2011-12-27 2014-01-22 주식회사 포스코 Method for Coal Gasifying and Apparatus Therefor
CN104694170B (en) * 2015-03-25 2017-02-22 西北化工研究院 Method for producing synthesis gas with carbon powder and natural gas/methane as raw materials
KR102184265B1 (en) * 2016-03-04 2020-11-30 루머스 테크놀로지 엘엘씨 Gasification process with two-stage gasifier and feedstock flexibility

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE543003C (en) * 1927-10-02 1932-02-02 Carl Salat Burners for dusty, liquid and gaseous fuels
DE3219316A1 (en) 1982-05-22 1983-11-24 Ruhrchemie Ag, 4200 Oberhausen METHOD AND DEVICE FOR PRODUCING SYNTHESIS GAS BY PARTIAL OXIDATION OF COAL-WATER SUSPENSIONS
DD267880A3 (en) 1987-08-17 1989-05-17 Freiberg Brennstoffinst METHOD FOR THE COMMON GASIFICATION OF LIQUID AND SOLID, DUST-SOUND FUELS
DE4125521C1 (en) * 1991-08-01 1992-10-29 Energiewerke Schwarze Pumpe Ag, O-7610 Schwarze Pumpe, De
DE4226015C1 (en) 1992-08-06 1994-01-13 Schwarze Pumpe Energiewerke Ag Process for the disposal of solid and liquid waste in the gasification process in fixed bed pressure gasification
DE4226034C1 (en) * 1992-08-06 1994-02-17 Schwarze Pumpe Energiewerke Ag Combined process for the gasification of solid, pasty and liquid residues and / or waste materials
DE4317319B4 (en) 1993-05-25 2005-10-20 Schwarze Pumpe Energiewerke Ag Process of flexible and integrated residue gasification
CN1054080C (en) * 1995-09-07 2000-07-05 华东理工大学 Three-way channel combined water coal slurry gasification nozzle with cyclone
DE19608093C2 (en) * 1996-03-02 2000-08-10 Krc Umwelttechnik Gmbh Process for recycling residual and waste materials as well as low calorific fuels in a cement kiln
DE19829385C1 (en) * 1998-07-01 1999-10-28 Krc Umwelttechnik Gmbh Pressurised slagging gasifier for treating ash-containing carbonaceous materials
DE102005035921B4 (en) * 2005-07-28 2008-07-10 Choren Industries Gmbh Process for the endothermic gasification of carbon
CN101003755B (en) * 2006-01-19 2010-09-29 神华集团有限责任公司 Gasification stove with multi nozzle, and gasification method
DE102006059149B4 (en) * 2006-12-14 2009-06-25 Siemens Ag Residual flow reactor for the gasification of solid and liquid energy sources
DE102007006981B4 (en) * 2007-02-07 2009-01-29 Technische Universität Bergakademie Freiberg Process, gasification reactor and plant for entrained flow gasification of solid fuels under pressure
RU2333929C1 (en) * 2007-02-26 2008-09-20 Институт химии и химической технологии СО РАН (ИХХТ СО РАН) Method and device for hard fuel gasification
KR101534040B1 (en) * 2007-03-15 2015-07-06 쉘 인터내셔날 리써취 마트샤피지 비.브이. Gasification reactor vessel with internal multi-tube wall and multiple burners

Also Published As

Publication number Publication date
KR20120093881A (en) 2012-08-23
DE102009041854A1 (en) 2011-03-24
RU2553156C2 (en) 2015-06-10
UA107470C2 (en) 2015-01-12
AU2010294844B2 (en) 2015-05-07
TW201116616A (en) 2011-05-16
CN102549117A (en) 2012-07-04
US20120266539A1 (en) 2012-10-25
TWI500755B (en) 2015-09-21
AU2010294844A1 (en) 2012-04-05
ZA201202798B (en) 2012-12-27
CA2774445A1 (en) 2011-03-24
EP2478072A2 (en) 2012-07-25
BR112012005838A2 (en) 2017-05-30
WO2011032663A2 (en) 2011-03-24
WO2011032663A3 (en) 2011-12-08

Similar Documents

Publication Publication Date Title
AU2011203614B2 (en) Gasification system and method using fuel injectors
AU2008221508B2 (en) Entrained-flow gasifier with cooling screen and sliding seal
US9200803B2 (en) System and method for coupling coolant fluid conduit to feed injector tip
US9464610B2 (en) Fuel injector having differential tip cooling system and method
CN102660329B (en) Two-stage entrained bed solid slagging gasifying device, gasifying method for carbon-containing substance and application of gasifying device
RU2012113135A (en) METHOD OF UNITED GASIFICATION OF RESIDUALS OF LIQUID AND SOLID FUEL
EP3543317A1 (en) Gasification agent mixing and pre-combustion technique and device
CN100535517C (en) Multi-channel liquid stage fuel partial oxidation generating synthesis gas burner and uses thereof
CN101679885B (en) Process to start-up a coal gasification reactor
BRPI0921897A2 (en) device for generating fuel product from carbon-containing raw materials
CN103275760B (en) Novel gasifier and industrial application thereof
CN106675600A (en) Coal gasification apparatus and coal gasification method for rich hydrogen by adopting coal gasification apparatus
CN103146434B (en) Multi-nozzle entrained-flow bed gasification furnace
CN202717757U (en) Two-section entrained-flow bed solid slag discharging gasification device
CN207072928U (en) One kind pyrolysis and gasification decoupling gasification furnace
CN107418632B (en) Gasification system and gasification method for simultaneously producing methane pyrolysis gas and synthesis gas
CN100374531C (en) Method for preparing synthesis gas by partial oxidation of solid carbonaceous substances using three-channel nozzles
CN107099339B (en) Pyrolysis and gasification decoupling gasification furnace
CN207330862U (en) Produce the gasification system that methane thermal is vented one's spleen with synthesis gas at the same time
CN105441136A (en) Gasifying method for jointly feeding residual oil, dry powder and coal-water slurry
US20110243804A1 (en) Method and system for superheating steam
CN104560204B (en) Water coal slurry and natural gas combined gasification furnace with multiple nozzles
CN204224553U (en) Vaporized chemical nozzle
CN104403689B (en) Gasification agent nozzle
CN104194838B (en) Gasification furnace

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20170910