[go: up one dir, main page]

RU2006125410A - OILED GLASS FIBERS WITH FAST IMPREGNATION FOR HARDENING POLYMERIC MATERIALS - Google Patents

OILED GLASS FIBERS WITH FAST IMPREGNATION FOR HARDENING POLYMERIC MATERIALS Download PDF

Info

Publication number
RU2006125410A
RU2006125410A RU2006125410/04A RU2006125410A RU2006125410A RU 2006125410 A RU2006125410 A RU 2006125410A RU 2006125410/04 A RU2006125410/04 A RU 2006125410/04A RU 2006125410 A RU2006125410 A RU 2006125410A RU 2006125410 A RU2006125410 A RU 2006125410A
Authority
RU
Russia
Prior art keywords
glass fiber
fiber according
polyester
composition
polyurethane
Prior art date
Application number
RU2006125410/04A
Other languages
Russian (ru)
Inventor
Дино ЛОМБИНО (FR)
Дино ЛОМБИНО
Клэр МЕТРА (FR)
Клэр Метра
Original Assignee
Сэн-Гобэн Ветротекс Франс С.А. (Fr)
Сэн-Гобэн Ветротекс Франс С.А.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Сэн-Гобэн Ветротекс Франс С.А. (Fr), Сэн-Гобэн Ветротекс Франс С.А. filed Critical Сэн-Гобэн Ветротекс Франс С.А. (Fr)
Publication of RU2006125410A publication Critical patent/RU2006125410A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/326—Polyureas; Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/323—Polyesters, e.g. alkyd resins
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/48—Coating with two or more coatings having different compositions
    • C03C25/54—Combinations of one or more coatings containing organic materials only with one or more coatings containing inorganic materials only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
  • Ropes Or Cables (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Reinforced Plastic Materials (AREA)

Claims (25)

1. Стекловолокно, покрытое водной замасливающей композицией, отличающееся тем, что указанная композиция содержит в качестве клейких пленкообразующих агентов по меньшей мере один сложный полиэфир, по меньшей мере один поливинилацетат и по меньшей мере один полиуретан.1. Glass fiber coated with an aqueous sizing composition, characterized in that said composition contains at least one polyester, at least one polyvinyl acetate and at least one polyurethane as adhesive film-forming agents. 2. Стекловолокно по п.1, отличающееся тем, что сложный полиэфир имеет молекулярный вес, в диапазоне от 4000 до 17000 г/моль.2. The fiberglass according to claim 1, characterized in that the polyester has a molecular weight in the range from 4000 to 17000 g / mol. 3. Стекловолокно по п.1 или 2, отличающееся тем, что сложный полиэфир получен взаимодействием поликарбоновой кислоты (кислот) и/или ангидрида(ов) этих кислот и полиола(ов).3. The glass fiber according to claim 1 or 2, characterized in that the polyester is obtained by the interaction of polycarboxylic acids (acids) and / or anhydride (s) of these acids and polyol (s). 4. Стекловолокно по п.3, отличающееся тем, что кислота выбрана из насыщенных, ненасыщенных или ароматических кислот, таких, как фумаровая кислота, изофталевая кислота, терефталевая кислота, ангидрид выбран из фталевого ангидрида и малеинового ангидрида, и полиол выбран из полиалкиленгликолей, таких, как полиэтиленгликоль и пропиленгликоль, ароматических полиолов, таких, как бисфенол A или F, и новолачных смол.4. The glass fiber according to claim 3, wherein the acid is selected from saturated, unsaturated or aromatic acids, such as fumaric acid, isophthalic acid, terephthalic acid, an anhydride selected from phthalic anhydride and maleic anhydride, and the polyol is selected from polyalkylene glycols such such as polyethylene glycol and propylene glycol, aromatic polyols such as bisphenol A or F, and novolac resins. 5. Стекловолокно по п.1 или 2, отличающееся тем, что поливинилацетат имеет молекулярный вес ниже 80000 г/моль, предпочтительно ниже 70000 г/моль.5. The glass fiber according to claim 1 or 2, characterized in that the polyvinyl acetate has a molecular weight below 80,000 g / mol, preferably below 70,000 g / mol. 6. Стекловолокно по п.1 или 2, отличающееся тем, что полиуретан получается при реакции по меньшей мере одного полиизоцианата и по меньшей мере одного полиола с алифатической или циклоалифатической цепью.6. Glass fiber according to claim 1 or 2, characterized in that the polyurethane is obtained by the reaction of at least one polyisocyanate and at least one polyol with an aliphatic or cycloaliphatic chain. 7. Стекловолокно по п.1 или 2, отличающееся тем, что молекулярный вес полиуретана ниже 20000 г/моль, предпочтительно составляет от 4000 до 15000 г/моль.7. The glass fiber according to claim 1 or 2, characterized in that the molecular weight of the polyurethane is below 20,000 g / mol, preferably from 4000 to 15000 g / mol. 8. Стекловолокно по п.1 или 2, отличающееся тем, что композиция дополнительно содержит смазку.8. Glass fiber according to claim 1 or 2, characterized in that the composition further comprises a lubricant. 9. Стекловолокно по п.8, отличающееся тем, что смазочный материал выбран из катионных соединений типа полиалкиленимида и неионных соединений типа эфиров жирных кислот и поли(алкиленгликоля)/поли(оксиалкилена) или типа амидов жирных кислот и поли(оксиалкилена).9. The glass fiber of claim 8, wherein the lubricant is selected from cationic compounds such as polyalkyleneimide and nonionic compounds such as fatty acid esters and poly (alkylene glycol) / poly (oxyalkylene) or fatty acid amide and poly (oxyalkylene) type. 10. Стекловолокно по п.1 или 2, отличающееся тем, что композиция содержит, кроме того, связующее, выбранное из силанов, силоксанов, титанатов, цирконатов и смесей этих соединений.10. The glass fiber according to claim 1 or 2, characterized in that the composition contains, in addition, a binder selected from silanes, siloxanes, titanates, zirconates and mixtures of these compounds. 11. Стекловолокно по п.10, отличающееся тем, что связующее содержит ненасыщенный силан и аминосилан.11. Glass fiber according to claim 10, characterized in that the binder contains an unsaturated silane and aminosilane. 12. Стекловолокно по п.11, отличающееся тем, что ненасыщенный силан содержит по меньшей мере одну акриловую или метакриловую группу, а аминосилан является бис-(гамма-триметоксисилилпропил)силаном или бис-(гамма-триэтоксисилилпропил)силаном.12. Glass fiber according to claim 11, characterized in that the unsaturated silane contains at least one acrylic or methacrylic group, and the aminosilane is a bis- (gamma-trimethoxysilylpropyl) silane or bis- (gamma-triethoxysilylpropyl) silane. 13. Стекловолокно по п.1 или 2, отличающееся тем, что оно имеет потерю на угар ниже 2,2%, предпочтительно выше 1%.13. The fiberglass according to claim 1 or 2, characterized in that it has a loss on waste below 2.2%, preferably above 1%. 14. Стекловолокно по п.1 или 2, отличающееся тем, что оно образовано из нитей диаметром, варьирующимся от 9 до 17 мкм.14. Fiberglass according to claim 1 or 2, characterized in that it is formed from threads with a diameter ranging from 9 to 17 microns. 15. Стекловолокно по п.1 или 2, отличающееся тем, что его титр составляет от 30 до 160 текс, предпочтительно от 40 до 60 текс.15. The glass fiber according to claim 1 or 2, characterized in that its titer is from 30 to 160 tex, preferably from 40 to 60 tex. 16. Стекловолокно по п.1 или 2, отличающееся тем, что оно содержит, кроме того, сверхсмазку, содержащую антистатик типа соли четвертичного аммония.16. The glass fiber according to claim 1 or 2, characterized in that it contains, in addition, a superfluid containing an antistatic agent such as a quaternary ammonium salt. 17. Стекловолокно по п.16, отличающееся тем, что соль четвертичного аммония является цетилтриметиламмонийхлоридом.17. The glass fiber according to clause 16, wherein the quaternary ammonium salt is cetyltrimethylammonium chloride. 18. Композиция для смазки, предназначенная для покрытия стекловолокна по одному из пп.1-17, отличающаяся тем, что она содержит водную смесь по меньшей мере одного сложного полиэфира, по меньшей мере одного полиацетата и по меньшей мере одного полиуретана.18. A lubricant composition for coating glass fiber according to one of claims 1 to 17, characterized in that it contains an aqueous mixture of at least one polyester, at least one polyacetate and at least one polyurethane. 19. Композиция по п.18, отличающаяся тем, что она содержит указанные ниже составляющие в следующих весовых содержаниях, выраженных в процентах твердого вещества:19. The composition according to p. 18, characterized in that it contains the following components in the following weight contents, expressed as a percentage of solids: от 50 до 80% по меньшей мере одного сложного полиэфира, предпочтительно от 50 до 70%from 50 to 80% of at least one polyester, preferably from 50 to 70% от 10 до 40% по меньшей мере одного поливинилацетата, предпочтительно от 20 до 30%from 10 to 40% of at least one polyvinyl acetate, preferably from 20 to 30% от 8 до 15% по меньшей мере одного полиуретана, предпочтительно от 8 до 10%from 8 to 15% of at least one polyurethane, preferably from 8 to 10% от 0 до 5 % по меньшей мере одного смазочного материалаfrom 0 to 5% of at least one lubricant от 1 до 6% по меньшей мере одного агента связывания, предпочтительно больше или равно 1,5%.from 1 to 6% of at least one binding agent, preferably greater than or equal to 1.5%. 20. Композиция по п.18 или 19, отличающаяся тем, что она содержит от 5 до 15 вес.% твердого вещества, предпочтительно от 6 до 11%.20. The composition according to p. 18 or 19, characterized in that it contains from 5 to 15 wt.% Solids, preferably from 6 to 11%. 21. Композит, содержащий по меньшей мере один термоотверждающийся полимерный материал и упрочняющее стекловолокно, отличающийся тем, что все или часть волокон состоит из волокон по одному из пп.1-17.21. A composite containing at least one thermosetting polymer material and a reinforcing glass fiber, characterized in that all or part of the fibers consists of fibers according to one of claims 1 to 17. 22. Композит по п.21, отличающееся тем, что термоотверждающийся материал является сложным полиэфиром, виниловым эфиром, полиакрилатом, фенольной смолой или эпоксидной смолой.22. The composite according to item 21, wherein the thermosetting material is a polyester, vinyl ether, polyacrylate, phenolic resin or epoxy resin. 23. Композит по п.21 или 22, отличающийся тем, что он содержит от 20 до 45 вес.% стекла.23. The composite according to item 21 or 22, characterized in that it contains from 20 to 45 wt.% Glass. 24. Применение стекловолокна по одному из пп.1-17 для изготовления изделий по методу формования в открытой форме, в частности, путем одновременного напыления указанных волокон и смолы.24. The use of fiberglass according to one of claims 1 to 17 for the manufacture of products by the method of molding in open form, in particular, by simultaneously spraying said fibers and resin. 25. Применение стекловолокна по одному из пп.1-17 для изготовления труб методом центрифугирования путем одновременного напыления указанных волокон и смолы.25. The use of fiberglass according to one of claims 1 to 17 for the manufacture of pipes by centrifugation by simultaneously spraying said fibers and resin.
RU2006125410/04A 2003-12-17 2004-12-02 OILED GLASS FIBERS WITH FAST IMPREGNATION FOR HARDENING POLYMERIC MATERIALS RU2006125410A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0314802A FR2864073B1 (en) 2003-12-17 2003-12-17 QUICK-IMPREGNATED ENSIMES GLASS YARNS FOR REINFORCING POLYMERIC MATERIALS
FR0314802 2003-12-17

Publications (1)

Publication Number Publication Date
RU2006125410A true RU2006125410A (en) 2008-01-27

Family

ID=34630245

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2006125410/04A RU2006125410A (en) 2003-12-17 2004-12-02 OILED GLASS FIBERS WITH FAST IMPREGNATION FOR HARDENING POLYMERIC MATERIALS

Country Status (9)

Country Link
US (1) US20070148453A1 (en)
EP (1) EP1697270A2 (en)
JP (1) JP4977857B2 (en)
CN (1) CN1918081B (en)
AU (1) AU2004299305B2 (en)
BR (1) BRPI0417705A (en)
FR (1) FR2864073B1 (en)
RU (1) RU2006125410A (en)
WO (1) WO2005058771A2 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070057404A1 (en) * 2005-09-12 2007-03-15 Hager William G Compression and injection molding applications utilizing glass fiber bundles
US20070059506A1 (en) * 2005-09-12 2007-03-15 Hager William G Glass fiber bundles for mat applications and methods of making the same
JP5702659B2 (en) * 2010-08-05 2015-04-15 積水化学工業株式会社 Manufacturing method of multi-layer pipe with flange and multi-layer pipe with flange
EP2631337B1 (en) * 2012-02-24 2015-09-23 EMS-Patent AG Fibre-resin composite material and method for producing the same
CN103160235B (en) * 2012-04-17 2014-10-29 南京彤天广元高分子材料有限公司 Resin powder bonding agent
US20180282938A1 (en) * 2015-10-08 2018-10-04 Ocv Intellectual Capital, Llc Post-coating composition for reinforcement fibers
CN106431014A (en) * 2016-08-28 2017-02-22 山东玻纤集团股份有限公司 Glass fiber impregnating compound for woven roving and preparation method of glass fiber impregnating compound
CN106348623A (en) * 2016-08-28 2017-01-25 山东玻纤集团股份有限公司 Glass fiber soakage agent for high-pressure piping and preparation method of glass fiber soakage agent
CN106365470A (en) * 2016-08-28 2017-02-01 山东玻纤集团股份有限公司 Reinforced glass fiber impregnating agent for SMC and preparation method thereof
CN106348624A (en) * 2016-08-29 2017-01-25 山东玻纤集团股份有限公司 Impregnating compound for spraying glass fiber and preparing method thereof
CN106587659B (en) * 2016-11-04 2019-05-21 巨石集团有限公司 A kind of glass fiber infiltration agent and application thereof
JP6772815B2 (en) * 2016-12-16 2020-10-21 日本電気硝子株式会社 Sizing agent, glass strands, and cement composites

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4029623A (en) * 1974-10-07 1977-06-14 Ppg Industries, Inc. Glass fiber sizing compositions for the reinforcement of resin matrices
SE405083B (en) * 1976-06-10 1978-11-20 Torgersen Lars PROCEDURE FOR LAMINATE CONSTRUCTION OF REINFORCED OR UNARMED HEAT PLASTIC IN PRESSURE CHAMBER
US4137209A (en) * 1977-11-14 1979-01-30 Owens-Corning Fiberglas Corporation Glass fiber size composition
US4156668A (en) * 1978-02-08 1979-05-29 Owens-Corning Fiberglas Corporation Aqueous binder composition comprising a polyvinyl acetate and a polyester useful for glass fiber mats
JPS55126552A (en) * 1979-03-22 1980-09-30 Asahi Fiber Glass Co Ltd Glass fiber sizing agent
US4370439A (en) * 1979-03-22 1983-01-25 Ppg Industries, Inc. Method of preparing a sizing composition for treating glass fibers
US4341877A (en) * 1980-06-04 1982-07-27 Ppg Industries, Inc. Sizing composition and sized glass fibers and process
US4477496A (en) * 1981-06-15 1984-10-16 Ppg Industries, Inc. Process for preparing sized glass fiber roving
DE3336845A1 (en) * 1983-10-11 1985-04-25 Bayer Ag, 5090 Leverkusen GLASSING FIBER FOR GLASS FIBERS
US4752527A (en) * 1985-06-25 1988-06-21 Ppg Industries, Inc. Chemically treated glass fibers for reinforcing polymeric materials processes
US4789593A (en) * 1985-06-25 1988-12-06 Ppg Industries, Inc. Glass fibers with fast wettability and method of producing same
CA1340052C (en) * 1988-03-31 1998-09-22 Narasimhan Raghupathi Chemically treated glass fibers for reinforcing thermosetting polymer matrices
US5247004A (en) * 1989-02-03 1993-09-21 Ppg Industries, Inc. Polymeric-containing compositions with improved oxidative stability
US5219656A (en) * 1991-07-12 1993-06-15 Ppg Industries Inc. Chemically treated glass fibers for reinforcing polymeric materials
US5242958A (en) * 1991-07-12 1993-09-07 Ppg Industries, Inc. Chemical treating composition for glass fibers having emulsified epoxy with good stability and the treated glass fibers
CA2172609C (en) * 1993-09-27 2000-01-11 Michael Walter Klett Fiber glass sizing compositions, sized glass fibers and methods of using the same
US5670255A (en) * 1995-01-23 1997-09-23 Ppg Industries, Inc. Antioxidant compositions for coating substrates, substrates coated with the same and methods for inhibiting the oxidation of such compositions applied to a substrate
DE19523512A1 (en) * 1995-06-28 1997-01-02 Bayer Ag Sizing composition, sized glass fibers and their use
US5824413A (en) * 1996-07-15 1998-10-20 Ppg Industries, Inc. Secondary coating for fiber strands, coated strand reinforcements, reinforced polymeric composites and a method of reinforcing a polymeric material
FR2755127B1 (en) * 1996-10-29 1998-11-27 Vetrotex France Sa SIZED GLASS WIRES FOR THE REINFORCEMENT OF POLYMERIC MATERIALS
US5877240A (en) * 1997-09-26 1999-03-02 Owens Corning Fiberglas Technology, Inc. Sizing composition for glass fibers for reinforcement of engineered thermoplastic materials
US6593255B1 (en) * 1998-03-03 2003-07-15 Ppg Industries Ohio, Inc. Impregnated glass fiber strands and products including the same
DE19857530C2 (en) * 1998-12-14 2001-11-15 Bayer Ag Sizing composition for glass fibers
US6399198B1 (en) * 1998-12-23 2002-06-04 Owens Corning Fiberglas Technology, Inc. Nonaqueous sizing system for glass fibers and injection moldable polymers
FR2819801B1 (en) 2001-01-24 2004-10-01 Saint Gobain Vetrotex SIZED GLASS WIRES, SIZING COMPOSITION AND COMPOSITES COMPRISING SAID WIRES
FR2826359B1 (en) * 2001-06-21 2004-05-07 Saint Gobain Vetrotex SIZED GLASS WIRES, SIZING COMPOSITION AND COMPOSITES COMPRISING SAID WIRES
US6787226B2 (en) * 2001-10-23 2004-09-07 Asahi Fiber Glass Company Limited Chopped strands and molded product of unsaturated polyester resin BMC employing them
JP4370140B2 (en) * 2003-09-30 2009-11-25 オーウェンスコーニング製造株式会社 Glass fiber sizing agent for reinforcing fiber reinforced unsaturated polyester resin,

Also Published As

Publication number Publication date
CN1918081A (en) 2007-02-21
JP2007514633A (en) 2007-06-07
CN1918081B (en) 2012-04-11
EP1697270A2 (en) 2006-09-06
AU2004299305A1 (en) 2005-06-30
BRPI0417705A (en) 2007-03-20
JP4977857B2 (en) 2012-07-18
WO2005058771A2 (en) 2005-06-30
FR2864073B1 (en) 2006-03-31
WO2005058771A3 (en) 2006-02-09
US20070148453A1 (en) 2007-06-28
FR2864073A1 (en) 2005-06-24
AU2004299305B2 (en) 2010-08-19

Similar Documents

Publication Publication Date Title
RU2006125410A (en) OILED GLASS FIBERS WITH FAST IMPREGNATION FOR HARDENING POLYMERIC MATERIALS
KR101700041B1 (en) Reinforced composite material
CA2671889A1 (en) Sizing compositions and glass fiber reinforced thermoplastic composites
US5549969A (en) Enhanced surface for glass fiber reinforced plastics
FI74720B (en) BELAEGGNINGSPULVER FOER ANVAENDNING VID FORMBELAEGGNINGSTEKNIK.
EP0097870B1 (en) A reinforced polyester composition having an improved strength
US4748197A (en) Fiber for reinforcing plastic composites and reinforced plastic composites therefrom
JP2007514633A5 (en)
ZA200309284B (en) Sized glass fibres, sizing composition and composites comprising said fibres.
CA1303273C (en) Optimum formulation regions of reinforced thermoset composites
US5811480A (en) Size composition, sized glass fibers and use thereof
US5759687A (en) Sized glass threads for reinforcing organic materials
EP2912112A1 (en) Resin compositions
KR101929095B1 (en) Sizing Composition for Glassfiber
US4857405A (en) Fiber for reinforcing plastic composites and reinforced plastic composites therefrom
CA2502712C (en) Polyester-based dimethacrylates designed for laminating applications
EP0051674B1 (en) Method of reparing surface defects
US4880871A (en) Fiber for reinforcing plastic composites and reinforced plastic composites therefrom
US12474011B2 (en) Multi-functional polyol based fiber glass binder composition
US4873144A (en) Fiber for composite reinforcement with anti-blocking finish
KR970061958A (en) Low profile additive based on asymmetric glycols and aromatic diacids for polyester resin systems
CN1221622C (en) Adhesive for felt sheet
US4443240A (en) Method for producing glass particles in moisture protected condition
CA1246775A (en) Control of fiber prominence in vinyl ester resin compositions
van Benthem et al. Thermosets

Legal Events

Date Code Title Description
FA94 Acknowledgement of application withdrawn (non-payment of fees)

Effective date: 20101013