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RU2005139395A - METHOD AND CATALYST FOR REMOVING ARSENE AND COMPOUNDS OF ONE OR MORE OTHER METALS FROM ORIGINAL HYDROCARBON RAW MATERIAL - Google Patents

METHOD AND CATALYST FOR REMOVING ARSENE AND COMPOUNDS OF ONE OR MORE OTHER METALS FROM ORIGINAL HYDROCARBON RAW MATERIAL Download PDF

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Publication number
RU2005139395A
RU2005139395A RU2005139395/04A RU2005139395A RU2005139395A RU 2005139395 A RU2005139395 A RU 2005139395A RU 2005139395/04 A RU2005139395/04 A RU 2005139395/04A RU 2005139395 A RU2005139395 A RU 2005139395A RU 2005139395 A RU2005139395 A RU 2005139395A
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RU
Russia
Prior art keywords
ppm
metals
compounds
feedstock
terms
Prior art date
Application number
RU2005139395/04A
Other languages
Russian (ru)
Inventor
Терри Аллан РИД (US)
Терри Аллан РИД
Стивен Уэйн МЭЙО (US)
Стивен Уэйн МЭЙО
Original Assignee
Альбемарл Недерланд Б.В. (Nl)
Альбемарл Недерланд Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by Альбемарл Недерланд Б.В. (Nl), Альбемарл Недерланд Б.В. filed Critical Альбемарл Недерланд Б.В. (Nl)
Publication of RU2005139395A publication Critical patent/RU2005139395A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Claims (7)

1. Способ удаления мышьяка и соединений одного или более других металлов из углеводородного сырья, при котором углеводородное сырье, содержащее по меньшей мере 20 ч.млрд мышьяка и по меньшей мере 0,3 ч.млн упомянутых соединений других металлов, в присутствии водорода приводят в контакт с каталитической композицией, содержащей соединение молибдена и соединение никеля на носителе, причем соединение молибдена присутствует в количестве 8-18 мас.% в пересчете на триоксид, а соединение никеля присутствует в количестве 8-20 мас.% в перечете на оксид, и при этом каталитическая композиция имеет площадь поверхности по меньшей мере 200 м2/г.1. A method of removing arsenic and compounds of one or more other metals from a hydrocarbon feed, in which a hydrocarbon feed containing at least 20 ppm arsenic and at least 0.3 ppm of the above compounds of other metals is brought into the presence of hydrogen contact with a catalytic composition comprising a molybdenum compound and a nickel compound on a carrier, wherein the molybdenum compound is present in an amount of 8-18 wt.% in terms of trioxide, and the nickel compound is present in an amount of 8-20 wt.% in terms of oxide, and When this catalyst composition had a surface area of at least 200 m 2 / g. 2. Способ по п.1, в котором соединение молибдена присутствует в количестве 10-15 мас.% в пересчете на триоксид, а соединение никеля присутствует в количестве 8-15 мас.% в пересчете на оксид.2. The method according to claim 1, in which the molybdenum compound is present in an amount of 10-15 wt.% In terms of trioxide, and the nickel compound is present in an amount of 8-15 wt.% In terms of oxide. 3. Способ по п.1 или 2, в котором каталитическая композиция имеет MPD между 9 и 15 нм.3. The method according to claim 1 or 2, in which the catalytic composition has an MPD between 9 and 15 nm. 4. Способ по п.1, в котором одно из упомянутых соединений других металлов представляет собой кремний.4. The method according to claim 1, in which one of the aforementioned compounds of other metals is silicon. 5. Способ по п.1, в котором сырье представляет собой сырье типа бензинолигроиновой фракции, которое имеет содержание мышьяка в по меньшей мере 20 ч.млрд (частей на миллиард по массе), предпочтительно - между 0,02 и 2 ч.млн, начальную температуру кипения - примерно 0-120°C, предпочтительно - примерно 30-90°C, и конечную температуру кипения примерно - 150-250°C, предпочтительно - примерно 160-220°C.5. The method according to claim 1, in which the feedstock is a feedstock of the type naphtha fraction, which has an arsenic content of at least 20 ppm (parts per billion by weight), preferably between 0.02 and 2 ppm, the initial boiling point is about 0-120 ° C, preferably about 30-90 ° C, and the final boiling point is about 150-250 ° C, preferably about 160-220 ° C. 6. Способ по п.5, в котором сырье типа бензинолигроиновой фракции имеет содержание кремния в по меньшей мере 0,5 ч.млн, в частности - между 1 ч.млн и 100 ч.млн.6. The method according to claim 5, in which the feedstock of the type of gasoline-naphtha fraction has a silicon content of at least 0.5 ppm, in particular between 1 ppm and 100 ppm. 7. Способ по п.1, который осуществляют при парциальном давлении водорода 10-200 бар, предпочтительно - 30-150 бар, температуре - 200-480°C, предпочтительно - 300-415°C, отношении водорода к сырью - 200-2000 Нл/л, предпочтительно - 500-1000 Нл/л, и LHSV -0,1-10 ч-1, предпочтительно - 0,5-3 ч-1.7. The method according to claim 1, which is carried out at a partial pressure of hydrogen of 10-200 bar, preferably 30-150 bar, temperature 200-480 ° C, preferably 300-415 ° C, the ratio of hydrogen to feedstock is 200-2000 Nl / L, preferably 500-1000 Nl / L, and LHSV -0.1-10 h -1 , preferably 0.5-3 h -1 .
RU2005139395/04A 2003-05-16 2004-05-06 METHOD AND CATALYST FOR REMOVING ARSENE AND COMPOUNDS OF ONE OR MORE OTHER METALS FROM ORIGINAL HYDROCARBON RAW MATERIAL RU2005139395A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US47086403P 2003-05-16 2003-05-16
US60/470,864 2003-05-16
EP03076720 2003-06-03
EP03076720.6 2003-06-03

Publications (1)

Publication Number Publication Date
RU2005139395A true RU2005139395A (en) 2006-06-27

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Family Applications (1)

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RU2005139395/04A RU2005139395A (en) 2003-05-16 2004-05-06 METHOD AND CATALYST FOR REMOVING ARSENE AND COMPOUNDS OF ONE OR MORE OTHER METALS FROM ORIGINAL HYDROCARBON RAW MATERIAL

Country Status (5)

Country Link
US (1) US20070080099A1 (en)
EP (1) EP1627027A1 (en)
JP (1) JP2007502353A (en)
CA (1) CA2525635A1 (en)
RU (1) RU2005139395A (en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8734740B1 (en) 2013-03-15 2014-05-27 Clariant Corporation Process and composition for removal of arsenic and other contaminants from synthetic gas
FR3103822B1 (en) 2019-12-02 2022-07-01 Ifp Energies Now METHOD FOR TREATMENT OF PYROLYSIS OILS FROM PLASTICS WITH A VIEW TO RECYCLING THEM IN A STEAM CRACKING UNIT
FR3107530B1 (en) 2020-02-21 2022-02-11 Ifp Energies Now OPTIMIZED PROCESS FOR THE TREATMENT OF PLASTICS PYROLYSIS OILS WITH A VIEW TO THEIR RECOVERY
WO2021204819A1 (en) * 2020-04-07 2021-10-14 Total Research & Technology Feluy Purification of waste plastic based oil with a first trap and a first hydrotreatment and a second trap and a second hydrotreatment
FR3113061B1 (en) 2020-07-30 2023-04-21 Ifp Energies Now METHOD FOR TREATMENT OF PLASTICS PYROLYSIS OILS INCLUDING ONE-STEP HYDROCRACKING
FR3113060B1 (en) 2020-07-30 2023-04-28 Ifp Energies Now PROCESS FOR TREATMENT OF PLASTICS PYROLYSIS OILS INCLUDING TWO-STAGE HYDROCRACKING
FR3114598B1 (en) 2020-09-25 2023-09-29 Ifp Energies Now METHOD FOR TREATMENT OF PLASTIC PYROLYSIS OILS AND/OR RECOVERED SOLID FUELS LOADED WITH IMPURITIES
FR3118629B1 (en) 2021-01-04 2023-12-15 Ifp Energies Now METHOD FOR PROCESSING PLASTICS PYROLYSIS OILS INCLUDING A HYDROGENATION STEP
FR3122662B1 (en) 2021-05-07 2024-04-26 Ifp Energies Now METHOD FOR SIMULTANEOUS TREATMENT OF PLASTICS PYROLYSIS OILS AND A FEED FROM RENEWABLE SOURCES
FR3122663B1 (en) 2021-05-07 2024-04-26 Ifp Energies Now INTEGRATED PROCESS FOR TREATMENT OF PLASTICS PYROLYSIS OILS AND/OR RECOVERED SOLID FUELS LOADED WITH IMPURITIES
CN113231067B (en) * 2021-05-28 2023-08-22 中国海洋石油集团有限公司 Dearsenifying agent for light distillate oil hydrogenation and preparation method and application thereof
FR3128225B1 (en) 2021-10-19 2025-01-17 Ifp Energies Now PROCESS FOR TREATING PYROLYSIS OILS FROM PLASTICS AND/OR RECOVERED SOLID FUELS CHARGED WITH IMPURITIES
FR3129945B1 (en) 2021-12-03 2025-06-20 Ifp Energies Now PROCESS FOR TREATING PLASTIC PYROLYSIS OILS INCLUDING A HYDROGENATION STAGE AND HOT SEPARATION
FR3135090B1 (en) 2022-04-29 2025-11-28 Ifp Energies Now PROCESS FOR TREATMENT OF PLASTICS PYROLYSIS OIL INCLUDING AN H2S RECYCLING STEP
FR3144153A1 (en) 2022-12-21 2024-06-28 IFP Energies Nouvelles METHOD FOR TREATING PLASTICS AND/OR TIRES PYROLYSIS OILS INCLUDING THE ELIMINATION OF HALIDES BY WASHING BEFORE A HYDROTREATMENT STEP
FR3144155A1 (en) 2022-12-21 2024-06-28 IFP Energies Nouvelles METHOD FOR TREATMENT OF PYROLYSIS OILS OF PLASTICS AND/OR TIRES INCLUDING THE ELIMINATION OF HALIDES PRIOR TO A HYDROTREATMENT STEP
EP4658732A1 (en) * 2023-02-03 2025-12-10 Topsoe A/S Removal of arsenic in renewable fuel production
FR3152811A1 (en) 2023-09-13 2025-03-14 IFP Energies Nouvelles PROCESS FOR TREATING TIRE PYROLYSIS OIL
FR3152810A1 (en) 2023-09-13 2025-03-14 IFP Energies Nouvelles PROCESS FOR TREATING PYROLYSIS OIL INCLUDING PREFRACTIONATION
FR3152812A1 (en) 2023-09-13 2025-03-14 IFP Energies Nouvelles PYROLYSIS OIL TREATMENT PROCESS INCLUDING PREFRACTIONATION AND RECYCLE

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5183561A (en) * 1990-01-25 1993-02-02 Mobil Oil Corp. Demetallation of hydrocarbon feedstocks with a synthetic mesoporous crystalline material

Also Published As

Publication number Publication date
EP1627027A1 (en) 2006-02-22
CA2525635A1 (en) 2004-11-25
JP2007502353A (en) 2007-02-08
US20070080099A1 (en) 2007-04-12

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FA92 Acknowledgement of application withdrawn (lack of supplementary materials submitted)

Effective date: 20080408