RU2005133189A - Способ гидрирования алкиларилкетонов - Google Patents
Способ гидрирования алкиларилкетонов Download PDFInfo
- Publication number
- RU2005133189A RU2005133189A RU2005133189/04A RU2005133189A RU2005133189A RU 2005133189 A RU2005133189 A RU 2005133189A RU 2005133189/04 A RU2005133189/04 A RU 2005133189/04A RU 2005133189 A RU2005133189 A RU 2005133189A RU 2005133189 A RU2005133189 A RU 2005133189A
- Authority
- RU
- Russia
- Prior art keywords
- alkylaryl
- ketones
- contacting
- phenolic compounds
- feedstock
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 10
- 150000004983 alkyl aryl ketones Chemical class 0.000 claims 9
- -1 alkylaryl hydroperoxides Chemical class 0.000 claims 4
- 239000003054 catalyst Substances 0.000 claims 4
- 150000002989 phenols Chemical class 0.000 claims 4
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical group CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 125000002947 alkylene group Chemical group 0.000 claims 2
- 238000009904 heterogeneous catalytic hydrogenation reaction Methods 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 238000005984 hydrogenation reaction Methods 0.000 claims 2
- 239000011541 reaction mixture Substances 0.000 claims 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 125000002877 alkyl aryl group Chemical group 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 150000002736 metal compounds Chemical class 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
- C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Claims (6)
1. Способ гидрирования алкиларилкетонов, где указанный способ включает контактирование исходного сырья, содержащего алкиларилкетоны и от 0,5 до 30 мас.% фенольных соединений, с водородом в присутствии гетерогенного катализатора гидрирования.
2. Способ по п.1, где катализатор гидрирования содержит медь в виде металла или соединения металла.
3. Способ по п.1 или 2, где исходное сырье, содержащее алкиларилкетоны, получают способом, включающим следующие стадии:
(i) контакирование исходного сырья, содержащего алкиларильные соединения, с кислородом с получением сырья, содержащего алкиларилгидропероксиды и алкиларилкетоны,
(ii) контакирование сырья, полученного на стадии (i), с алкеном в присутствии катализатора с получением реакционной смеси, содержащей алкиленоксид, алкилариловый спирт и алкиларилкетоны, и
(iii) удаление, по меньшей мере, части алкиленоксида и алкилариловых спиртов из реакционной смеси, полученной на стадии (ii), с получением сырья, содержащего алкиларилкетоны.
4. Способ по п.1 или 2, где, по меньшей мере, часть фенольных соединений добавляют к исходному сырью, содержащему алкиларилкетоны.
5. Способ по п.1 или 2, где указанный способ включает следующие стадии:
(a) контактирование исходного сырья, содержащего алкиларилкетоны и от 0,5 до 30 мас.% фенольных соединений, с водородом в присутствии гетерогенного катализатора гидрирования и
(b) удаление, по меньшей мере, части алкиларилового спирта, образующегося на стадии (a), из потока, содержащего фенольные соединения.
6. Способ по п.1 или 2, где алкиларилкетон представляет собой ацетофенон.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03251987.8 | 2003-03-28 | ||
| EP03251987 | 2003-03-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2005133189A true RU2005133189A (ru) | 2006-03-10 |
| RU2335486C2 RU2335486C2 (ru) | 2008-10-10 |
Family
ID=33041091
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2005133189/04A RU2335486C2 (ru) | 2003-03-28 | 2004-03-25 | Способ гидрирования алкиларилкетонов |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6939996B2 (ru) |
| EP (1) | EP1608610B1 (ru) |
| JP (1) | JP2006521330A (ru) |
| KR (1) | KR101114594B1 (ru) |
| CN (1) | CN100400486C (ru) |
| AU (1) | AU2004224090B2 (ru) |
| BR (1) | BRPI0408745B1 (ru) |
| ES (1) | ES2403854T3 (ru) |
| RU (1) | RU2335486C2 (ru) |
| TW (1) | TW200500139A (ru) |
| WO (1) | WO2004085354A2 (ru) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100645667B1 (ko) * | 2003-02-12 | 2006-11-13 | 에스케이 주식회사 | 1-(ｎ-할로페닐)에탄올의 제조방법 |
| WO2007073792A1 (de) * | 2005-12-19 | 2007-07-05 | Bayer Schering Pharma Aktiengesellschaft | Verfahren zur herstellung von 4,4-diphenylcyclohexanol |
| WO2008049823A1 (en) * | 2006-10-24 | 2008-05-02 | Shell Internationale Research Maatschappij B.V. | Process for the hydrogenation of alkylaryl ketones |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB320638A (en) * | 1928-07-17 | 1929-10-17 | Schering Kahlbaum Ag | Process for the manufacture of alkylated phenols and their hydrogenation products |
| US2575403A (en) | 1943-10-14 | 1951-11-20 | Union Carbide & Carbon Corp | Catalytic hydrogenation of acetophenone to phenyl methyl carbinol |
| GB587181A (en) * | 1943-10-14 | 1947-04-16 | Carbide & Carbon Chem Corp | Improvement in catalytic hydrogenation of acetophenone to phenyl methyl carbinol |
| FR913996A (fr) * | 1944-10-17 | 1946-09-25 | Rhone Poulenc Sa | Procédé de préparation du n. méthyl-p. aminophénol |
| GB664851A (en) * | 1949-05-04 | 1952-01-16 | Peter William Reynolds | Improvements in and relating to the preparation of catalysts |
| US3927120A (en) * | 1974-09-03 | 1975-12-16 | Atlantic Richfield Co | Preparation of phenyl methyl carbinol |
| ES461521A1 (es) * | 1976-08-19 | 1978-06-16 | Atlantic Richfield Co | Mejoras introducidas en un metodo de coproduccion de estire-no y de un oxido de alquileno inferior. |
| US4208539A (en) * | 1978-05-23 | 1980-06-17 | Halcon Research And Development Corporation | Hydrogenation of acetophenone using barium-copper chromite-zinc |
| US4160746A (en) * | 1978-05-23 | 1979-07-10 | Malcon Research & Development Corporation | Catalyst for hydrogenation of acetophenone |
| JPS56131541A (en) * | 1980-03-19 | 1981-10-15 | Sumitomo Chem Co Ltd | Preparation of acetophenone |
| US4418005A (en) * | 1982-06-28 | 1983-11-29 | Conoco Inc. | Pressure activation of magnesium oxide catalysts |
| GB8815328D0 (en) * | 1988-06-28 | 1988-08-03 | Shell Int Research | Process for reduction of carbonyl compounds |
| US5015787A (en) * | 1989-04-10 | 1991-05-14 | Allied-Signal Inc. | Process for production cyclohexanol |
| JPH0632747A (ja) * | 1992-07-15 | 1994-02-08 | Sumitomo Chem Co Ltd | 水素化方法 |
| DE4242947A1 (de) * | 1992-12-18 | 1994-06-23 | Bayer Ag | Verfahren zur Herstellung eines Gemisches von Cyclohexanon und Cyclohexanol |
| US5663458A (en) | 1994-12-02 | 1997-09-02 | Sumitomo Chemical Company, Limited. | Process for producing α-phenylethyl alcohol |
| JP3560377B2 (ja) * | 1995-01-06 | 2004-09-02 | 昭和電工株式会社 | 水素化触媒及びそれを用いた反応 |
| RU2121475C1 (ru) * | 1997-01-20 | 1998-11-10 | Акционерное общество "Нижнекамскнефтехим" | Способ получения метилфенилкарбинола |
| DE19727710A1 (de) * | 1997-06-30 | 1999-01-07 | Bayer Ag | Verfahren zur Herstellung von Cyclohexanonen durch Hydrierung der entsprechenden Phenole (II.) |
| SG66476A1 (en) * | 1997-07-14 | 1999-07-20 | Sumitomo Chemical Co | Process for producing alpha-phenylethyl alcohol |
| JP3899764B2 (ja) | 2000-01-19 | 2007-03-28 | 住友化学株式会社 | α−フェニルエチルアルコールの製造方法 |
| US6888035B2 (en) * | 2000-09-25 | 2005-05-03 | Exxonmobil Chemical Patents Inc. | Hydrogenation of cleavage effluents in phenol production |
-
2004
- 2004-03-25 CN CNB2004800086168A patent/CN100400486C/zh not_active Expired - Fee Related
- 2004-03-25 BR BRPI0408745-3A patent/BRPI0408745B1/pt not_active IP Right Cessation
- 2004-03-25 RU RU2005133189/04A patent/RU2335486C2/ru active
- 2004-03-25 US US10/808,858 patent/US6939996B2/en not_active Expired - Lifetime
- 2004-03-25 JP JP2006505489A patent/JP2006521330A/ja active Pending
- 2004-03-25 WO PCT/EP2004/050362 patent/WO2004085354A2/en not_active Ceased
- 2004-03-25 AU AU2004224090A patent/AU2004224090B2/en not_active Ceased
- 2004-03-25 EP EP04741441A patent/EP1608610B1/en not_active Expired - Lifetime
- 2004-03-25 ES ES04741441T patent/ES2403854T3/es not_active Expired - Lifetime
- 2004-03-25 KR KR1020057017903A patent/KR101114594B1/ko not_active Expired - Fee Related
- 2004-03-26 TW TW093108341A patent/TW200500139A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006521330A (ja) | 2006-09-21 |
| AU2004224090A1 (en) | 2004-10-07 |
| RU2335486C2 (ru) | 2008-10-10 |
| AU2004224090B2 (en) | 2007-10-25 |
| EP1608610B1 (en) | 2013-04-03 |
| US6939996B2 (en) | 2005-09-06 |
| KR20050114259A (ko) | 2005-12-05 |
| ES2403854T3 (es) | 2013-05-22 |
| EP1608610A2 (en) | 2005-12-28 |
| BRPI0408745B1 (pt) | 2014-06-24 |
| WO2004085354A3 (en) | 2005-03-17 |
| WO2004085354A2 (en) | 2004-10-07 |
| CN100400486C (zh) | 2008-07-09 |
| US20040220431A1 (en) | 2004-11-04 |
| CN1768023A (zh) | 2006-05-03 |
| BRPI0408745A (pt) | 2006-03-28 |
| KR101114594B1 (ko) | 2012-03-05 |
| TW200500139A (en) | 2005-01-01 |
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