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RU2005120000A - Каталитическая композиция для гидрокрекинга и способ превращения углеводородного сырья в низкокипящие материалы - Google Patents

Каталитическая композиция для гидрокрекинга и способ превращения углеводородного сырья в низкокипящие материалы Download PDF

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Publication number
RU2005120000A
RU2005120000A RU2005120000/04A RU2005120000A RU2005120000A RU 2005120000 A RU2005120000 A RU 2005120000A RU 2005120000/04 A RU2005120000/04 A RU 2005120000/04A RU 2005120000 A RU2005120000 A RU 2005120000A RU 2005120000 A RU2005120000 A RU 2005120000A
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zeolite
range
composition according
surface area
hydrocracking
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RU2005120000/04A
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RU2338590C2 (ru
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Эдвард Джулиус КРЕЙТОН (NL)
Эдвард Джулиус КРЕЙТОН
Корнелис ОУВЕХЕНД (NL)
Корнелис ОУВЕХЕНД
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Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL)
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/14—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/22—After treatment, characterised by the effect to be obtained to destroy the molecular sieve structure or part thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/14—Iron group metals or copper
    • B01J29/146—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/21—Faujasite, e.g. X, Y, CZS-3, ECR-4, Z-14HS, VHP-R

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  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Claims (11)

1. Каталитическая композиция для гидрокрекинга, включающая необязательный металлический гидрирующий компонент, нанесенный на носитель, содержащий цеолит фожазитной структуры с размером элементарной ячейки в интервале 24,10-24,40 Е, объемным соотношением оксид кремния: оксид алюминия (SAR) около 12, и площадью поверхности, по меньшей мере, 850 м2/г согласно измерению методом BET и ASTM D 4365-95 по адсорбции азота при значении р/ро 0,03.
2. Композиция по п.1, в которой цеолит имеет размер элементарной ячейки в интервале 24,14-24, 38 Е.
3. Композиция по п.1 или 2, в которой цеолит характеризуется величиной SAR в интервале 20-100.
4. Композиция по любому из пп.1 и 2, в которой площадь поверхности цеолита составляет, по меньшей мере, 890 м2/г.
5. Композиция по любому из пп.1 и 2, в которой цеолит имеет объем микропор, по меньшей мере, 0,28 мл/г.
6. Композиция по любому из пп.1 и 2, дополнительно содержащая второй цеолит.
7. Композиция по п.6, дополнительно содержащая 1-5 мас.% цеолита бета в расчете на общее количество носителя.
8. Композиция по любому из пп.1 и 2, дополнительно содержащая связующее вещество.
9. Каталитическая композиция для гидрокрекинга, включающая необязательный металлический гидрирующий компонент, нанесенный на цеолит по п.1, которую получают способом, включающим следующие стадии:
a) приготовление исходного цеолита фожазитной структуры с соотношением между оксидом кремния и оксидом алюминия в интервале 4,5-6,5 и содержанием щелочи менее 1,5 мас.%;
b) гидротермальную обработку указанного исходного цеолита при температуре 600-850°С и парциальном давлении пара, подаваемого из внешнего источника, в интервале 0,2-1 атмосфера в течение времени, эффективного для получения промежуточного цеолита с размером элементарной ячейки 24,30-24,45 Е;
c) контактирование промежуточного цеолита с подкисляющим раствором, содержащим кислоту и необязательную соль аммония, в условиях эффективных для получения цеолита с высокой площадью поверхности, размером элементарной ячейки в интервале 24,10-24,40 Е, молярным соотношением оксид кремния/оксид алюминия выше 12 и площадью поверхности более 850 м2/г, в результате чего получают цеолит с высокой площадью поверхности; и
d) регенерацию цеолита с высокой удельной площадью поверхности;
e) необязательные смешивание указанного цеолита со связующим веществом и/или вторым крекирующим компонентом, экструзия и прокаливание; и
f) необязательное введение, по меньшей мере, одного гидрирующего компонента в указанный цеолит со стадии (d) или в катализатор на стадии (е) или после нее.
10. Способ превращения углеводородного сырья в низкокипящие материалы, заключающийся в контактировании сырья с водородом при повышенной температуре и давлении в присутствии композиционного катализатора гидрокрекинга по любому из пп.1-9.
11. Способ по п.10, осуществляемый при температуре в интервале 250-500°С и общем давлении в интервале 3·106-3·107 Па.
RU2005120000/04A 2002-11-27 2003-11-25 Каталитическая композиция для гидрокрекинга и способ превращения углеводородного сырья в низкокипящие материалы RU2338590C2 (ru)

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US60/429,620 2002-11-27

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CN (1) CN1717277B (ru)
AU (1) AU2003298324A1 (ru)
BR (1) BR0316682A (ru)
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UA (1) UA86193C2 (ru)
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1613426B1 (en) * 2002-11-27 2015-10-21 PQ Holding, Inc. High surface area zeolites and methods for preparation and use thereof
US7169291B1 (en) * 2003-12-31 2007-01-30 Uop Llc Selective hydrocracking process using beta zeolite
CN100428995C (zh) * 2004-03-03 2008-10-29 国际壳牌研究有限公司 催化剂载体和催化剂组合物、其制备方法和用途
US7611689B2 (en) * 2004-09-24 2009-11-03 Shell Oil Company Faujasite zeolite, its preparation and use in hydrocracking
US7510645B2 (en) * 2005-11-04 2009-03-31 Uop Llc Hydrocracking catalyst containing beta and Y zeolites, and process for its use to produce naphtha
US7585405B2 (en) * 2005-11-04 2009-09-08 Uop Llc Hydrocracking catalyst containing beta and Y zeolites, and process for its use to make jet fuel or distillate
MY149329A (en) * 2006-03-30 2013-08-30 Nippon Oil Corp Hydrocracking catalyst and process for producing fuel base material
US20090048477A1 (en) * 2006-03-31 2009-02-19 Hiroyuki Seki Hydrocracking Catalyst, and Method for Production of Fuel Base Material
US20080011648A1 (en) * 2006-07-17 2008-01-17 Li Wang Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate
US20080011649A1 (en) * 2006-07-17 2008-01-17 Li Wang Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate
US20080011647A1 (en) * 2006-07-17 2008-01-17 Li Wang Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate
TW201029929A (en) * 2008-12-18 2010-08-16 Grace W R & Co Novel ultra stable zeolite Y and method for manufacturing the same
SG175067A1 (en) 2009-04-29 2011-11-28 Pq Corp Zeolite y
RU2540071C2 (ru) * 2009-04-29 2015-01-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Катализатор гидрокрекинга
EA021772B1 (ru) * 2009-06-22 2015-08-31 ДжейДжиСи КОРПОРЕЙШН Катализатор для получения низших олефинов и способ получения низших олефинов с его использованием
RU2548362C2 (ru) * 2009-06-25 2015-04-20 Чайна Петролеум & Кемикал Корпорейшн Катализатор каталитического крекинга и способ повышения селективности катализатора(варианты)
CN102648048B (zh) * 2009-12-03 2017-04-12 国际壳牌研究有限公司 八面沸石制备方法
US8637419B2 (en) * 2009-12-06 2014-01-28 Chevron U.S.A. Inc. Method for making a hydroprocessing catalyst
FR2970259B1 (fr) 2011-01-07 2014-07-18 IFP Energies Nouvelles Procede d'hydrocraquage utilisant un catalyseur zeolithique contenant deux fonctions hydrogenantes distinctes.
KR101162612B1 (ko) * 2011-11-30 2012-07-04 이엔에프씨 주식회사 폐원료로부터의 오일 생성 시스템 및 그 촉매
IN2014CN04670A (ru) * 2011-12-23 2015-09-18 Shell Int Research
KR101413993B1 (ko) * 2012-06-27 2014-08-07 주식회사 오일시티 바이오매스로부터의 오일 생성 시스템 및 그 촉매
US10864503B2 (en) * 2012-09-17 2020-12-15 Shell Oil Company Process for the preparation of a hydrocracking catalyst
FR3021748B1 (fr) * 2014-06-03 2016-09-02 Ifp Energies Now Procede pour l'evaluation d'au moins une caracteristique petroliere d'un echantillon de roche
WO2016057362A1 (en) 2014-10-07 2016-04-14 Shell Oil Company A hydrocracking process integrated with solvent deasphalting to reduce heavy polycyclic aromatic buildup in heavy oil hydrocracker ecycle stream
US9546331B2 (en) 2014-10-22 2017-01-17 Shell Oil Company Hydrocracking process integrated with vacuum distillation and solvent dewaxing to reduce heavy polycyclic aromatic buildup
EP3420050A1 (en) 2016-02-25 2019-01-02 SABIC Global Technologies B.V. Process for combined hydrodesulfurization and hydrocracking of heavy hydrocarbons
US10822552B2 (en) 2016-03-01 2020-11-03 Sabic Global Technologies B.V. Process for producing monoaromatic hydrocarbons from a hydrocarbon feed comprising polyaromatics
US20180105761A1 (en) 2016-10-14 2018-04-19 Exxonmobil Research And Engineering Company Lubricant basestock production with enhanced aromatic saturation
US20190309231A1 (en) 2018-04-06 2019-10-10 Exxonmobil Research And Engineering Company Catalysts and methods for distillate end point reduction
EP3802745B1 (en) 2018-05-25 2024-08-14 Shell Internationale Research Maatschappij B.V. A hydrocracking process for making middle distillate from a light hydrocarbon feedstock
CN112166172B (zh) 2018-05-25 2022-10-25 国际壳牌研究有限公司 由轻质烃原料制备中间馏出物的加氢裂化方法
US11680214B2 (en) 2018-08-30 2023-06-20 Shell Usa, Inc. Hazy-free at 0° C heavy base oil and a process for producing
US11148124B2 (en) * 2019-12-04 2021-10-19 Saudi Arabian Oil Company Hierarchical zeolite Y and nano-sized zeolite beta composite
FR3109899B1 (fr) * 2020-05-07 2023-11-24 Ifp Energies Now Catalyseur d’hydrogénation comprenant un support et un ratio NiMo spécifique
EP4243982A1 (en) * 2020-11-12 2023-09-20 Shell Internationale Research Maatschappij B.V. A method of preparing a hydrocracking catalyst
FR3130641A1 (fr) * 2021-12-16 2023-06-23 IFP Energies Nouvelles Catalyseur d’hydrocraquage comprenant une zeolithe y specifique et une zeolithe de type mfi pour la production d’une charge de vapocraquage

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3130007A (en) 1961-05-12 1964-04-21 Union Carbide Corp Crystalline zeolite y
US4085069A (en) 1976-08-27 1978-04-18 Filtrol Corporation Hydrothermally stable catalysts containing ammonium faujasite zeolites
CA1131195A (en) 1978-02-23 1982-09-07 David E. Earls Ultrahydrophobic zeolite y
US4401556A (en) 1979-11-13 1983-08-30 Union Carbide Corporation Midbarrel hydrocracking
CA1203191A (en) 1982-02-11 1986-04-15 Susan Bradrick Middistillate production
NZ204090A (en) 1982-05-18 1986-02-21 Mobil Oil Corp Hydrocracking catalyst containing large pore zeolite,which exhibits improved distillate selectivity
FR2561946B1 (fr) * 1984-03-30 1986-10-03 Pro Catalyse Nouveau catalyseur d'hydrocraquage destine a la production de distillats moyens
FR2582665B1 (fr) 1985-06-04 1988-08-05 Inst Francais Du Petrole Procede de craquage catalytique
GB8613132D0 (en) 1986-05-30 1986-07-02 Shell Int Research Hydrocarbon conversion catalysts
GB8722839D0 (en) 1987-09-29 1987-11-04 Shell Int Research Hydrocracking of hydrocarbon feedstock
GB8722840D0 (en) 1987-09-29 1987-11-04 Shell Int Research Converting hydrocarbonaceous feedstock
US5223240A (en) * 1989-08-16 1993-06-29 Degussa Aktiengesellschaft Method of preparing zeolite Y
JPH0818819B2 (ja) 1989-10-04 1996-02-28 出光興産株式会社 新規なフォージャサイト型アルミノシリケート及びその製造方法並びに重質油水素化分解触媒
GB8925980D0 (en) 1989-11-16 1990-01-04 Shell Int Research Process for converting hydrocarbon oils
US5350501A (en) 1990-05-22 1994-09-27 Union Oil Company Of California Hydrocracking catalyst and process
TW252053B (ru) * 1991-11-01 1995-07-21 Shell Internat Res Schappej Bv
US5242677A (en) * 1992-06-11 1993-09-07 Pq Corporation Stable zeolite of low unit cell constant and method of making same
US5234876A (en) 1992-10-20 1993-08-10 Corning Incorporated Thermally stable chromium-exchanged zeolites and method of making same
US5435987A (en) 1993-07-22 1995-07-25 Pq Corporation Process for preparing ammonium zeolites of low alkali metal content
WO1995015208A1 (en) * 1993-12-03 1995-06-08 W.R. Grace & Co.-Conn. Pt-containing catalyst for the reduction of nitric oxide by organic compounds
FR2735764B1 (fr) * 1995-06-21 1997-08-22 Irma Zeolithe y desaluminee, son procede de fabrication et son application a l'adsorption des composes organiques volatils en presence de vapeur d'eau
US5853566A (en) * 1995-11-28 1998-12-29 Shell Oil Company Zeolite-beta containing catalyst compositions and their use in hydrocarbon conversion processes for producing low boiling point materials
US5925235A (en) 1997-12-22 1999-07-20 Chevron U.S.A. Inc. Middle distillate selective hydrocracking process
US6136291A (en) * 1998-10-08 2000-10-24 Mobile Oil Corporation Faujasite zeolitic materials
BR0008462A (pt) * 1999-03-03 2002-01-29 Pq Holding Inc Processo para preparar um zeólito modificado
CN1108356C (zh) 2000-10-26 2003-05-14 中国石油化工股份有限公司 一种高活性高中油性加氢裂化催化剂及其制备方法
EP1613426B1 (en) * 2002-11-27 2015-10-21 PQ Holding, Inc. High surface area zeolites and methods for preparation and use thereof

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BR0316682A (pt) 2005-10-18
US7192900B2 (en) 2007-03-20
CN1717277B (zh) 2014-07-02
KR101062641B1 (ko) 2011-09-06
ZA200503826B (en) 2006-11-29
US20040152587A1 (en) 2004-08-05
JP4813797B2 (ja) 2011-11-09
WO2004047988A1 (en) 2004-06-10
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KR20050072149A (ko) 2005-07-08
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