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RU2005119205A - METHOD FOR PRODUCING A SHEET FROM WEAR-RESISTANT STEEL AND OBTAINED BY THIS METHOD OF A STEEL SHEET - Google Patents

METHOD FOR PRODUCING A SHEET FROM WEAR-RESISTANT STEEL AND OBTAINED BY THIS METHOD OF A STEEL SHEET Download PDF

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Publication number
RU2005119205A
RU2005119205A RU2005119205/02A RU2005119205A RU2005119205A RU 2005119205 A RU2005119205 A RU 2005119205A RU 2005119205/02 A RU2005119205/02 A RU 2005119205/02A RU 2005119205 A RU2005119205 A RU 2005119205A RU 2005119205 A RU2005119205 A RU 2005119205A
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Prior art keywords
sheet
steel
necessary
product
chemical composition
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RU2005119205/02A
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Russian (ru)
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RU2326179C2 (en
Inventor
Жан БЕГИНО (FR)
Жан Бегино
Жан-Жорж БРИССОН (FR)
Жан-Жорж Бриссон
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Эндюстель Крезо (Fr)
Эндюстель Крезо
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/001—Austenite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/002—Bainite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/008—Martensite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Articles (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Claims (7)

1. Способ получения изделия или листа из износостойкой стали, имеющей следующий химический состав, вес.%:1. The method of obtaining a product or sheet of wear-resistant steel having the following chemical composition, wt.%: 0,24%≤C<0,35%0.24% ≤C <0.35% 0%≤Si≤2%0% ≤Si≤2% 0%≤Al≤2%0% ≤Al≤2% 0,5≤Si+Al≤2%0.5≤Si + Al≤2% 0%≤Mn≤2,5%0% ≤Mn≤2.5% 0%≤Ni≤5%0% ≤Ni≤5% 0%≤Cr≤5%0% ≤Cr≤5% 0%≤Мо≤1%0% ≤Mo≤1% 0%≤W≤2%0% ≤W≤2% 0,1%≤Mo+W/2≤1%0.1% ≤Mo + W / 2≤1% 0%≤B≤0,02%0% ≤B≤0.02% 0%≤Ti≤1,1%0% ≤Ti≤1.1% 0%≤Zr≤2,2%0% ≤Zr≤2.2% 0,35%≤Ti+Zr/2≤1,1%0.35% ≤Ti + Zr / 2≤1.1% 0%≤S≤0,15%0% ≤S≤0.15% N<0,03%,N <0.03%, при необходимости 0-1,5% меди,if necessary, 0-1.5% copper, при необходимости, по меньшей мере, один элемент, выбранный из Nb, Та и V, при содержании, например, Nb/2+Та/4+V≤0,5%,if necessary, at least one element selected from Nb, Ta and V, with a content of, for example, Nb / 2 + Ta / 4 + V≤0.5%, при необходимости, по меньшей мере, один элемент, выбранный из Se, Те, Са, Bi, Pb, при содержании меньшем или равном 0,1%, при этом остальное составляет железо и литьевые примеси, причем химический состав кроме того соответствует следующим отношениям:if necessary, at least one element selected from Se, Te, Ca, Bi, Pb, with a content of less than or equal to 0.1%, while the rest is iron and injection impurities, and the chemical composition also corresponds to the following relations: С*=С-Ti/4-Zr/8+7×N/8≥0,095%C * = C-Ti / 4-Zr / 8 + 7 × N / 8≥0.095% иand 1,05×Mn+0,54×Ni+0,50×Cr+0,3×(Mo+W/2)1/2+К>1,8,1.05 × Mn + 0.54 × Ni + 0.50 × Cr + 0.3 × (Mo + W / 2) 1/2 + K> 1.8, где К=0,5, если В≥0,0005%, и К=0, если В<0,0005%,where K = 0.5 if B≥0.0005%, and K = 0 if B <0.0005%, при котором лист подвергается термообработке путем закалки, обеспечиваемой теплом горячего деформирования, например, прокатки, или после аустенизации путем нагрева в печи, при этом для проведения закалки:in which the sheet is subjected to heat treatment by hardening, provided by heat of hot deformation, for example, rolling, or after austenization by heating in a furnace, while for hardening: изделие или лист охлаждают со средней скоростью, превышающей 0,5°С/с в интервале от температуры, превышающей АС3, до температуры, лежащей между Т=800-270×С*-90×Mn-37×Ni-70×Cr-83×(Мо+W/2) и Т-50°С,the product or sheet is cooled at an average rate exceeding 0.5 ° C / s in the range from a temperature exceeding AC 3 to a temperature lying between T = 800-270 × C * -90 × Mn-37 × Ni-70 × Cr -83 × (Mo + W / 2) and T-50 ° C, затем охлаждают насквозь изделие или лист со средней скоростью Vr<1150×ер-1,7 и выше 0,1°С/с в интервале от температуры Т до 100°С, при этом ер означает толщину листа в мм,then cool down through the product or sheet with an average speed of Vr <1150 × ep -1.7 and above 0.1 ° C / s in the range from temperature T to 100 ° C, while ep means the thickness of the sheet in mm, охлаждают изделие или лист до комнатной температуры и проводят при необходимости правку.cool the product or sheet to room temperature and correct if necessary. 2. Способ по п.1, отличающийся тем, что химический состав стали удовлетворяет, по меньшей мере, одной из последовательностей условий:2. The method according to claim 1, characterized in that the chemical composition of the steel satisfies at least one of the sequences of conditions: 1,05×Mn+0,54×Ni+0,50×Cr+0,3×(Мо+W/2)1/2+К>2,1.05 × Mn + 0.54 × Ni + 0.50 × Cr + 0.3 × (Mo + W / 2) 1/2 + K> 2, Ti+Zr/2≥0,4%,Ti + Zr / 2≥0.4%, С*≥0,12%,C * ≥0.12%, Si+Al≥0,7%.Si + Al≥0.7%. 3. Способ по любому из п.1 или 2, отличающийся тем, что дополнительно проводят отпуск при температуре ниже или равной 350°С.3. The method according to any one of claim 1 or 2, characterized in that they additionally spend a vacation at a temperature below or equal to 350 ° C. 4. Способ по любому из п.1 или 2, отличающийся тем, что для введения в сталь титана жидкую сталь приводят в контакт со шлаком, содержащим титан, и обеспечивают медленную диффузию титана из шлака в жидкую сталь.4. The method according to any one of claims 1 or 2, characterized in that for introducing titanium into the steel, molten steel is brought into contact with the slag containing titanium, and the titanium diffuses slowly from the slag into the molten steel. 5. Изделие, в частности, лист, из износостойкой стали, имеющей следующий химический состав, в вес.%:5. The product, in particular the sheet, from wear-resistant steel having the following chemical composition, in wt.%: 0,24≤С<0,350.24≤C <0.35 0≤Si≤20≤Si≤2 0≤Al≤20≤Al≤2 0,5≤Si+Al≤20,5≤Si + Al≤2 0≤Mn≤2,50≤Mn≤2.5 0≤Ni≤50≤Ni≤5 0≤Cr≤50≤Cr≤5 0≤Мо≤10≤Mo≤1 0≤W≤20≤W≤2 0,1≤Mo+W/2≤10.1≤Mo + W / 2≤1 0≤B≤0,020≤B≤0.02 0≤Ti≤1,10≤Ti≤1,1 0≤Zr≤2,20≤Zr≤2,2 0,35≤Ti+Zr/2≤1,10.35≤Ti + Zr / 2≤1.1 0≤S 0,150≤S 0.15 N<0,03,N <0.03, при необходимости 0-1,5 меди,if necessary, 0-1.5 copper, при необходимости, по меньшей мере, один элемент, выбранный из Nb, Та и V, при содержании, например, Nb/2+Та/4+V≤0,5,if necessary, at least one element selected from Nb, Ta and V, with a content of, for example, Nb / 2 + Ta / 4 + V≤0.5, при необходимости, по меньшей мере, один элемент, выбранный из Se, Те, Са, Bi, Pb, при содержании меньшем или равном 0,1, при этом остальное составляет железо и литьевые примеси, причем химический состав кроме того соответствует следующим отношениям:if necessary, at least one element selected from Se, Te, Ca, Bi, Pb, with a content of less than or equal to 0.1, while the rest is iron and injection impurities, and the chemical composition also corresponds to the following relations: С-Ti/4-Zr/8+7×N/8≥0,095C-Ti / 4-Zr / 8 + 7 × N / 8≥0.095 иand 1,05×Mn+0,54×Ni+0,50×Cr+0,3×(Mo+W/2)1/2+К>1,8,1.05 × Mn + 0.54 × Ni + 0.50 × Cr + 0.3 × (Mo + W / 2) 1/2 + K> 1.8, где К=0,5, если В≥0,0005%, и К=0, если В<0,0005%,where K = 0.5 if B≥0.0005%, and K = 0 if B <0.0005%, при этом сталь имеет мартенситную или мартенситно-бейнитовую структуру, причем указанная структура содержит 5-20% остаточного аустенита и карбиды.while the steel has a martensitic or martensitic-bainitic structure, and this structure contains 5-20% of residual austenite and carbides. 6. Изделие по п.5, отличающееся тем, что химический состав стали удовлетворяет, по меньшей мере, одной из последовательностей условий:6. The product according to claim 5, characterized in that the chemical composition of the steel satisfies at least one of the sequences of conditions: 1,05×Mn+0,54×Ni+0,50×Cr+0,3×(Мо+W/2)1/2+К>2,1.05 × Mn + 0.54 × Ni + 0.50 × Cr + 0.3 × (Mo + W / 2) 1/2 + K> 2, Ti+Zr/2≥0,4%,Ti + Zr / 2≥0.4%, С*≥0,12%,C * ≥0.12%, Si+Al≥0,7%.Si + Al≥0.7%. 7. Изделие по любому из п.5 или 6, отличающееся тем, что им является лист толщиной 2-150 мм.7. The product according to any one of claim 5 or 6, characterized in that it is a sheet 2-150 mm thick.
RU2005119205/02A 2002-11-19 2003-11-13 Method of manufacture of wear-resistant steel sheet and steel sheet manufactured using this method RU2326179C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR02/14426 2002-11-19
FR0214426A FR2847272B1 (en) 2002-11-19 2002-11-19 METHOD FOR MANUFACTURING AN ABRASION RESISTANT STEEL SHEET AND OBTAINED SHEET

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RU2326179C2 RU2326179C2 (en) 2008-06-10

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EP (1) EP1563105B1 (en)
JP (1) JP4535876B2 (en)
KR (1) KR101010571B1 (en)
CN (1) CN100348738C (en)
AR (1) AR042073A1 (en)
AT (1) ATE382716T1 (en)
AU (1) AU2003295014B2 (en)
BR (1) BR0315693B1 (en)
CA (1) CA2506349C (en)
DE (1) DE60318478T2 (en)
ES (1) ES2298605T3 (en)
FR (1) FR2847272B1 (en)
PE (1) PE20040484A1 (en)
PL (1) PL202086B1 (en)
RU (1) RU2326179C2 (en)
UA (1) UA78624C2 (en)
WO (1) WO2004048619A1 (en)
ZA (1) ZA200504150B (en)

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