RU2004135923A - Кристаллический алюмосиликатный цеолит uzm-4m, способ его получения и способ превращения углеводородов - Google Patents
Кристаллический алюмосиликатный цеолит uzm-4m, способ его получения и способ превращения углеводородов Download PDFInfo
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- RU2004135923A RU2004135923A RU2004135923/15A RU2004135923A RU2004135923A RU 2004135923 A RU2004135923 A RU 2004135923A RU 2004135923/15 A RU2004135923/15 A RU 2004135923/15A RU 2004135923 A RU2004135923 A RU 2004135923A RU 2004135923 A RU2004135923 A RU 2004135923A
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract 18
- 229910021536 Zeolite Inorganic materials 0.000 title claims abstract 15
- 239000010457 zeolite Substances 0.000 title claims abstract 15
- 238000000034 method Methods 0.000 title claims 9
- 229930195733 hydrocarbon Natural products 0.000 title claims 5
- 150000002430 hydrocarbons Chemical class 0.000 title claims 5
- 229910000323 aluminium silicate Inorganic materials 0.000 title abstract 2
- 230000001131 transforming effect Effects 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract 4
- 150000002910 rare earth metals Chemical class 0.000 claims abstract 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract 3
- 150000001340 alkali metals Chemical class 0.000 claims abstract 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract 3
- 229910052796 boron Inorganic materials 0.000 claims abstract 3
- 229910052733 gallium Inorganic materials 0.000 claims abstract 3
- 229910052738 indium Inorganic materials 0.000 claims abstract 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052742 iron Inorganic materials 0.000 claims abstract 3
- -1 cesium strontium barium potassium Chemical compound 0.000 claims 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 3
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 2
- 230000003197 catalytic effect Effects 0.000 claims 2
- 150000001768 cations Chemical class 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 229910052804 chromium Inorganic materials 0.000 claims 2
- 239000011651 chromium Substances 0.000 claims 2
- 239000002131 composite material Substances 0.000 claims 2
- 238000006317 isomerization reaction Methods 0.000 claims 2
- 229910017090 AlO 2 Inorganic materials 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- 229910004298 SiO 2 Inorganic materials 0.000 claims 1
- 230000029936 alkylation Effects 0.000 claims 1
- 238000005804 alkylation reaction Methods 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 238000004517 catalytic hydrocracking Methods 0.000 claims 1
- 239000012084 conversion product Substances 0.000 claims 1
- 238000007323 disproportionation reaction Methods 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 238000005342 ion exchange Methods 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 150000002892 organic cations Chemical class 0.000 claims 1
- 239000012188 paraffin wax Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 238000010025 steaming Methods 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 238000010555 transalkylation reaction Methods 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
- 229940104869 fluorosilicate Drugs 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical compound [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/026—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/30—Aromatics
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- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Cosmetics (AREA)
Claims (9)
1. Микропористый кристаллический цеолит (UZM-4M), обладающий трехмерной решеткой из по крайней мере тетраэдрических звеньев AlO2 и SiO2 и составом (на безводной основе), выраженным эмпирической формулой
Mla n+Al1-xExSiyOz,
где Ml является по меньшей мере одним способным к обмену катионом, выбираемым из группы, включающей щелочные металлы, щелочноземельные металлы, редкоземельные металлы, ион водорода, аммониевый ион и их смеси, а является мольным отношением Ml к (Al+Е) и имеет значения от 0,15 до 1,5, n является средневзвешенной валентностью Ml и имеет значения от 1 до 3, Е обозначает элемент, выбираемый из группы, состоящей из галлия, железа, бора, хрома, индия и их смесей, х обозначает молярную долю Е и имеет значения от 0 до 0,5, у является мольным отношением Si к (Al+Е) и имеет значения от 1,75 до 500 и z является мольным отношением О к (Al+Е) и имеет значение, определяемое уравнением:
z=[а·n+3+(4·у)]/2,
отличающийся тем, что он обладает рентгенограммой, имеющей по меньшей мере d-периоды и интенсивности, представленные в таблице А
2. Цеолит по п.1, отличающийся тем, что является термически устойчивым до температуры по меньшей мере 400°С.
3. Цеолит по любому из п.1 или 2, отличающийся тем, что Ml из выбирают из группы, включающей литий, натрий, цезий стронций барий калий, ион водорода, ион аммония и их смеси.
4. Цеолит по любому из п.1 или 2, отличающийся тем, что Ml является смесью редкоземельного металла и иона водорода.
5. Способ получения микропористого кристаллического цеолита UZM-4M, заявленного по любому из п.1, или 2, или 3, или 4, отличающийся тем, что включает обработку исходного микропористого кристаллического цеолита раствором или суспензией фторсиликата аммония с рН от 3 до 7 с получением микропористого кристаллического цеолита UZM-4M, где исходный цеолит имеет состав на безводной основе, выраженной эмпирической формулой
M’m,n+Rr’p+Al1-xExSiyOz, (III)
где m является мольным отношением М к (Al+Е) и имеет значения от 0 до 1,5, М’ является по меньшей мере одним пригодным для обмена катионом, выбранным из группы, состоящей из щелочных металлов, щелочноземельных металлов, редкоземельных металлов, ионов водорода, аммониевого иона и их смесей, R является по меньшей мере одним органическим катионом, выбранным из группы, состоящей из протонированных аминов, четвертичных аммониевых ионов, дичетвертичных аммониевых ионов, протонированных алканоламинов и кватернизированных алканоламмониевых ионов, r обозначает мольное отношение R к (Al+Е) и имеет значения от 0 до 1,5, р является средневзвешенной валентностью R и имеет значение от 1 до 2, Е означает элемент, выбранный из группы, состоящей из галлия, железа, бора, хрома, индия и их смесей, х обозначает молярную долю Е и имеет значения от 0 до 0,5, у обозначает отношение Si к (Al+Е) и имеет значения от 1,5 до 10,0 и z является мольным отношением О к (Al+Е) и определяется уравнением
z=[m·n+r·р+3+4·у)]/2.
6. Способ по п.5, отличающийся тем, что модифицированный цеолит дополнительно обрабатывают одним или более методами, выбранными из пропарки, прокаливания и ионного обмена, причем обработка выполняется в любой последовательности.
7. Способ превращения углеводородов, отличающийся тем, что вводят в контакт углеводороды с каталитическим композитом в условиях конверсии углеводородов с образованием продукта превращения, в котором каталитический композит включает микропористый кристаллический цеолит, заявленный в любом из пп.1, 2, 3 или 4.
8. Способ по п.7, отличающийся тем, что превращения углеводородов осуществляют методом, выбранным из группы, включающем гидрокрекинг, гидроизомеризацию парафинов, изомеризацию ксилола, трансалкилирование ароматических углеводородов, диспропорционирование ароматических углеводородов, алкилирование ароматических углеводородов и изомеризацию парафинов.
9. Способ разделения смеси молекулярных частиц, отличающийся тем, что вводят в контакт смесь с микропористым кристаллическим цеолитом UZM-4M, заявленным по любому из пп.1, 2, 3 или 4, с отделением от смеси, по меньшей мере, одного типа молекул.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/142,806 US6776975B2 (en) | 2002-05-09 | 2002-05-09 | Crystalline aluminosilicate zeolitic composition: UZM-4M |
| US10/142,806 | 2002-05-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2004135923A true RU2004135923A (ru) | 2005-06-10 |
| RU2322392C2 RU2322392C2 (ru) | 2008-04-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2004135923/15A RU2322392C2 (ru) | 2002-05-09 | 2003-05-08 | Кристаллический алюмосиликатный цеолит uzm-4m, способ его получения и способ превращения углеводородов |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6776975B2 (ru) |
| EP (1) | EP1551764B1 (ru) |
| JP (1) | JP4592419B2 (ru) |
| KR (1) | KR100986786B1 (ru) |
| CN (1) | CN1313372C (ru) |
| AT (1) | ATE409168T1 (ru) |
| AU (1) | AU2003299483A1 (ru) |
| CA (1) | CA2483926A1 (ru) |
| DE (1) | DE60323760D1 (ru) |
| ES (1) | ES2314283T3 (ru) |
| RU (1) | RU2322392C2 (ru) |
| WO (1) | WO2004039725A2 (ru) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2518074C1 (ru) * | 2010-03-31 | 2014-06-10 | Юоп Ллк | Способ алкилирования ароматических углеводородов с использованием алюмосиликатного цеолита uzm-37 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6982074B2 (en) | 2002-09-20 | 2006-01-03 | Uop Llc | High silica zeolites: UZM-5HS |
| US7713513B2 (en) * | 2003-03-21 | 2010-05-11 | Uop Llc | High silica zeolites: UZM-8HS |
| US20040182744A1 (en) * | 2003-03-21 | 2004-09-23 | Jan Deng Yang | High silica zeolites: UZM-8HS |
| US7638667B2 (en) * | 2003-03-21 | 2009-12-29 | Uop Llc | Hydrocarbon conversion processes using a catalyst comprising a UZM-8HS composition |
| US7578993B2 (en) * | 2003-10-31 | 2009-08-25 | Uop Llc | Process for preparing crystalline aluminosilicate compositions using charge density matching |
| KR100958149B1 (ko) * | 2004-04-20 | 2010-05-18 | 유오피 엘엘씨 | Ｕｚｍ-8 및 ｕｚｍ-8ｈｓ 결정질 알루미노실리케이트제올라이트 조성물 및 이 조성물을 이용하는 방법 |
| CN1972867B (zh) * | 2004-04-23 | 2010-11-03 | 环球油品公司 | 高氧化硅沸石uzm-5hs |
| US7638459B2 (en) * | 2005-05-25 | 2009-12-29 | Uop Llc | Layered composition and processes for preparing and using the composition |
| CN100594179C (zh) * | 2005-06-03 | 2010-03-17 | 中国科学院大连化学物理研究所 | 一种微孔结晶硅酸铝及其制备方法 |
| US8349291B2 (en) * | 2006-08-03 | 2013-01-08 | Uop Llc | Calcined UZM-22 and UZM-22HS aluminosilicate zeolites |
| US7744850B2 (en) * | 2006-08-03 | 2010-06-29 | Uop Llc | UZM-22 aluminosilicate zeolite, method of preparation and processes using UZM-22 |
| US20110124489A1 (en) * | 2006-09-19 | 2011-05-26 | Denso Corporation | Carbon-based material combustion catalyst, manufacturing method of the same, catalyst carrier, and manufacturing method of the same |
| JP5303130B2 (ja) * | 2006-09-19 | 2013-10-02 | 株式会社日本自動車部品総合研究所 | 炭素系物質燃焼触媒及びその製造方法、触媒担持体及びその製造方法 |
| US7888537B2 (en) * | 2006-12-29 | 2011-02-15 | Uop Llc | Solid acid catalyst and process for decomposition of cumene hydroperoxide |
| US20100012552A1 (en) * | 2008-07-18 | 2010-01-21 | James Jr Robert B | Process and apparatus for producing gasoline |
| US20120123178A1 (en) * | 2008-09-30 | 2012-05-17 | Uop Llc | Uzm-35hs aluminosilicate zeolite, method of preparation and processes using uzm-35hs |
| US7922997B2 (en) * | 2008-09-30 | 2011-04-12 | Uop Llc | UZM-35 aluminosilicate zeolite, method of preparation and processes using UZM-35 |
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| US2991151A (en) | 1957-12-05 | 1961-07-04 | Union Carbide Corp | Crystalline zeolite q |
| DE3136686A1 (de) * | 1981-09-16 | 1983-04-21 | Hoechst Ag, 6230 Frankfurt | "gallium- und/oder indiumhaltige zeolithe und verfahren zu deren herstellung sowie ihre verwendung" |
| US4610856A (en) | 1981-10-28 | 1986-09-09 | Union Carbide Corporation | Silicon substituted zeolite compositions and process for preparing same |
| US5382420A (en) | 1992-09-25 | 1995-01-17 | Exxon Research & Engineering Company | ECR-33: a stabilized rare-earth exchanged Q type zeolite |
| HU218835B (hu) * | 1997-10-28 | 2000-12-28 | Péter Siklósi | Eljárás zeolitok előállítására alkáli-alumínium-hidroszilikát-tartalmú nyersanyagokból |
| US6419895B1 (en) * | 2000-11-03 | 2002-07-16 | Uop Llc | Crystalline aluminosilicate zeolitic composition: UZM-4 |
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- 2003-05-08 EP EP03799771A patent/EP1551764B1/en not_active Expired - Lifetime
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- 2003-05-08 ES ES03799771T patent/ES2314283T3/es not_active Expired - Lifetime
- 2003-05-08 JP JP2004548261A patent/JP4592419B2/ja not_active Expired - Fee Related
- 2003-05-08 CN CNB038133482A patent/CN1313372C/zh not_active Expired - Fee Related
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2518074C1 (ru) * | 2010-03-31 | 2014-06-10 | Юоп Ллк | Способ алкилирования ароматических углеводородов с использованием алюмосиликатного цеолита uzm-37 |
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| Publication number | Publication date |
|---|---|
| EP1551764B1 (en) | 2008-09-24 |
| AU2003299483A1 (en) | 2004-05-25 |
| JP4592419B2 (ja) | 2010-12-01 |
| JP2006502075A (ja) | 2006-01-19 |
| WO2004039725A2 (en) | 2004-05-13 |
| KR20040108791A (ko) | 2004-12-24 |
| US6776975B2 (en) | 2004-08-17 |
| CA2483926A1 (en) | 2004-05-13 |
| KR100986786B1 (ko) | 2010-10-12 |
| WO2004039725A3 (en) | 2005-05-12 |
| CN1694844A (zh) | 2005-11-09 |
| RU2322392C2 (ru) | 2008-04-20 |
| EP1551764A2 (en) | 2005-07-13 |
| CN1313372C (zh) | 2007-05-02 |
| ATE409168T1 (de) | 2008-10-15 |
| US20030211034A1 (en) | 2003-11-13 |
| AU2003299483A8 (en) | 2004-05-25 |
| ES2314283T3 (es) | 2009-03-16 |
| DE60323760D1 (de) | 2008-11-06 |
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