RU2002128632A - Каталитическая конверсия алканов в алкены - Google Patents
Каталитическая конверсия алканов в алкеныInfo
- Publication number
- RU2002128632A RU2002128632A RU2002128632/04A RU2002128632A RU2002128632A RU 2002128632 A RU2002128632 A RU 2002128632A RU 2002128632/04 A RU2002128632/04 A RU 2002128632/04A RU 2002128632 A RU2002128632 A RU 2002128632A RU 2002128632 A RU2002128632 A RU 2002128632A
- Authority
- RU
- Russia
- Prior art keywords
- sulfide
- catalyst
- alkane
- preceding paragraphs
- sulfur
- Prior art date
Links
- 150000001335 aliphatic alkanes Chemical class 0.000 title claims 7
- 150000001336 alkenes Chemical class 0.000 title claims 2
- 230000003197 catalytic effect Effects 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims 15
- 239000003054 catalyst Substances 0.000 claims 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 7
- 229910052717 sulfur Inorganic materials 0.000 claims 6
- 239000011593 sulfur Substances 0.000 claims 6
- 150000001875 compounds Chemical class 0.000 claims 4
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 claims 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical group CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- INPLXZPZQSLHBR-UHFFFAOYSA-N cobalt(2+);sulfide Chemical compound [S-2].[Co+2] INPLXZPZQSLHBR-UHFFFAOYSA-N 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 229910052976 metal sulfide Inorganic materials 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 239000011733 molybdenum Substances 0.000 claims 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 2
- 230000000737 periodic effect Effects 0.000 claims 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 2
- 229910052721 tungsten Inorganic materials 0.000 claims 2
- 239000010937 tungsten Substances 0.000 claims 2
- -1 C 5 alkane Chemical class 0.000 claims 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical group O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 1
- 238000006555 catalytic reaction Methods 0.000 claims 1
- 229910000423 chromium oxide Inorganic materials 0.000 claims 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 claims 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical group 0.000 claims 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims 1
- 239000001294 propane Substances 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 claims 1
- 229910001928 zirconium oxide Inorganic materials 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/46—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with sulfur or a sulfur-containing compound as an acceptor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/18—Carbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
- C07C2527/04—Sulfides
- C07C2527/047—Sulfides with chromium, molybdenum, tungsten or polonium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
- C07C2527/04—Sulfides
- C07C2527/047—Sulfides with chromium, molybdenum, tungsten or polonium
- C07C2527/049—Sulfides with chromium, molybdenum, tungsten or polonium with iron group metals or platinum group metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
- C07C2527/04—Sulfides
- C07C2527/047—Sulfides with chromium, molybdenum, tungsten or polonium
- C07C2527/051—Molybdenum
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Claims (15)
1. Способ каталитической реакции от С2 до С5 алкана и серосодержащего соединения для получения соответствующего алкена и сероводорода, в котором реакционную смесь вводят в контакт с катализатором при температуре от 300 до 650°С, в котором катализатор имеет площадь поверхности более 100 м2/г.
2. Способ по п.1, проводимый при температуре от 450 до 580°С.
3. Способ по п.1 или 2, в котором катализатор имеет площадь поверхности от 100 до 600 м2/г.
4. Способ по каждому из предшествующих пунктов, в котором алкан и серосодержащее соединение присутствуют в молярном отношении от 0,1 до 10 моль серы на 1 моль алкана.
5. Способ по п.4, в котором алкан и серосодержащее соединение присутствуют в молярном отношении от 0,25 до 0,5 моль серы на 1 моль алкана.
6. Способ по каждому из предшествующих пунктов, в котором алкан представляет собой пропан.
7. Способ по каждому из предшествующих пунктов, в котором серосодержащее соединение представляет собой элементарную серу.
8. Способ по каждому из предшествующих пунктов, в котором катализатор представляет собой сульфид металла, в котором металл выбирают из V В, VI В, VII В, VIII В групп и группы I В Периодической таблицы.
9. Способ по п.7, в котором катализатор представляет собой сульфид металла, выбираемый из сульфида вольфрама, сульфида меди, сульфида никеля, сульфида молибдена, сульфида кобальта, сульфида вольфрам/никеля, сульфида молибден/никеля и сульфида молибден/кобальта или их смеси.
10. Способ по п.9, в котором катализатор представляет собой сульфид вольфрам/никеля.
11. Способ по каждому из пп.1-7, в котором катализатор представляет собой оксид металла, где металл выбирают из VI В группы Периодической таблицы или оксида алюминия.
12. Способ по п.11, в котором катализатор представляет собой оксид хрома или оксид алюминия.
13. Способ по каждому из предшествующих пунктов, в котором катализатор включает подложку, выбираемую из оксида алюминия, оксида титана, оксида циркония, диоксида кремния, алюмосиликатов или их смеси.
14. Способ по каждому из предшествующих пунктов, проводимый при давлении от 0,05 до 50 бар и при объемной скорости от 50 до 5000 ч-1.
15. Способ по каждому из предшествующих пунктов, в котором любой непрореагировавший алкан рециркулируют в реактор.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00106398A EP1136467A1 (en) | 2000-03-24 | 2000-03-24 | Catalytic conversion of alkanes to alkenes |
| EP00106398.1 | 2000-03-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2002128632A true RU2002128632A (ru) | 2004-03-27 |
Family
ID=8168218
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2002128632/04A RU2002128632A (ru) | 2000-03-24 | 2001-03-23 | Каталитическая конверсия алканов в алкены |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20040092784A1 (ru) |
| EP (2) | EP1136467A1 (ru) |
| JP (1) | JP2003528063A (ru) |
| KR (1) | KR20020092999A (ru) |
| CN (1) | CN1419528A (ru) |
| AU (1) | AU2001273924A1 (ru) |
| BR (1) | BR0109505A (ru) |
| CA (1) | CA2402734A1 (ru) |
| MX (1) | MXPA02009285A (ru) |
| NZ (1) | NZ521424A (ru) |
| RU (1) | RU2002128632A (ru) |
| WO (1) | WO2001070655A1 (ru) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4559714B2 (ja) * | 2003-06-19 | 2010-10-13 | 独立行政法人科学技術振興機構 | アルケンの製造方法、硫化水素の製造方法、アルカンの脱水素方法、および触媒 |
| RU2280021C1 (ru) * | 2005-06-20 | 2006-07-20 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Способ получения олефинов |
| WO2008115242A1 (en) * | 2007-03-21 | 2008-09-25 | David Bradin | Production of alcohol blend usable in flexible fuel vehicles via fischer-tropsch synthesis |
| JP2009076865A (ja) | 2007-08-29 | 2009-04-09 | Fujifilm Corp | 有機電界発光素子 |
| WO2011031752A2 (en) | 2009-09-08 | 2011-03-17 | The Ohio State University Research Foundation | Synthetic fuels and chemicals production with in-situ co2 capture |
| CN103861619A (zh) * | 2012-12-11 | 2014-06-18 | 江苏省海洋石化股份有限公司 | 一种烷烃脱氢硫化物催化剂及烷烃脱氢的方法 |
| CN104069778B (zh) * | 2013-03-27 | 2016-08-31 | 中国石油天然气集团公司 | 一种在线硫化烷烃脱氢制烯烃的流化床反应装置和方法 |
| CN104069779B (zh) * | 2013-03-27 | 2016-08-31 | 中国石油天然气集团公司 | 一种烷烃脱氢制烯烃的流化床反应装置和方法 |
| CN106715367A (zh) * | 2014-09-29 | 2017-05-24 | 托普索公司 | 烷烃脱氢成烯烃 |
| WO2017162427A1 (en) * | 2016-03-22 | 2017-09-28 | Haldor Topsøe A/S | Sulfide-based alkane dehydrogenation catalysts |
| AU2017250214B2 (en) | 2016-04-12 | 2021-08-12 | Ohio State Innovation Foundation | Chemical looping syngas production from carbonaceous fuels |
| US11090624B2 (en) | 2017-07-31 | 2021-08-17 | Ohio State Innovation Foundation | Reactor system with unequal reactor assembly operating pressures |
| WO2020033500A1 (en) | 2018-08-09 | 2020-02-13 | Ohio State Innovation Foundation | Systems, methods and materials for hydrogen sulfide conversion |
| WO2020036923A1 (en) * | 2018-08-13 | 2020-02-20 | Northwestern University | Oxidative dehydrogenation of alkanes to alkenes using sulfur as an oxidant |
| EP3894061B1 (en) | 2019-01-17 | 2023-12-20 | Ohio State Innovation Foundation | Systems, methods and materials for stable phase syngas generation |
| CA3129146A1 (en) * | 2019-04-09 | 2020-10-15 | Liang-Shih Fan | Alkene generation using metal sulfide particles |
| EP4010115A4 (en) | 2019-08-19 | 2023-07-19 | Ohio State Innovation Foundation | MESOPOROUS SUPPORT-IMMOBILIZED NANOPARTICLES BASED ON METAL OXIDE |
| CA3149858C (en) | 2019-09-03 | 2023-10-10 | Liang-Shih Fan | Redox reaction facilitated carbon dioxide capture from flue gas and conversion to carbon monoxide |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2126817A (en) * | 1936-06-03 | 1938-08-16 | Standard Oil Dev Co | Dehydrogenation of hydrocarbons |
| US3456026A (en) * | 1967-11-01 | 1969-07-15 | Exxon Research Engineering Co | Sulfur dehydrogenation of organic compounds |
| US3787517A (en) * | 1970-02-07 | 1974-01-22 | Mobil Oil Corp | Oxidative dehydrogenation of paraffins |
| US3801661A (en) * | 1972-07-11 | 1974-04-02 | Dow Chemical Co | Selective process for the continuous dyhydrogenation of nonaromatic hydrocarbons |
-
2000
- 2000-03-24 EP EP00106398A patent/EP1136467A1/en not_active Withdrawn
-
2001
- 2001-03-23 RU RU2002128632/04A patent/RU2002128632A/ru unknown
- 2001-03-23 AU AU2001273924A patent/AU2001273924A1/en not_active Abandoned
- 2001-03-23 KR KR1020027012607A patent/KR20020092999A/ko not_active Withdrawn
- 2001-03-23 US US10/239,358 patent/US20040092784A1/en not_active Abandoned
- 2001-03-23 JP JP2001568869A patent/JP2003528063A/ja not_active Withdrawn
- 2001-03-23 EP EP01940297A patent/EP1268373A1/en not_active Withdrawn
- 2001-03-23 BR BR0109505-6A patent/BR0109505A/pt not_active Application Discontinuation
- 2001-03-23 WO PCT/EP2001/003954 patent/WO2001070655A1/en not_active Ceased
- 2001-03-23 NZ NZ521424A patent/NZ521424A/en unknown
- 2001-03-23 MX MXPA02009285A patent/MXPA02009285A/es unknown
- 2001-03-23 CN CN01807081A patent/CN1419528A/zh active Pending
- 2001-03-23 CA CA002402734A patent/CA2402734A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| BR0109505A (pt) | 2004-01-13 |
| JP2003528063A (ja) | 2003-09-24 |
| AU2001273924A1 (en) | 2001-10-03 |
| CA2402734A1 (en) | 2001-09-27 |
| MXPA02009285A (es) | 2003-12-11 |
| CN1419528A (zh) | 2003-05-21 |
| KR20020092999A (ko) | 2002-12-12 |
| NZ521424A (en) | 2004-06-25 |
| EP1136467A1 (en) | 2001-09-26 |
| US20040092784A1 (en) | 2004-05-13 |
| EP1268373A1 (en) | 2003-01-02 |
| WO2001070655A1 (en) | 2001-09-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2002128632A (ru) | Каталитическая конверсия алканов в алкены | |
| EP0332289B1 (en) | A process for the production of mono-olefins by the catalytic oxidative dehydrogenation of gaseous paraffinic hydrocarbons having two or more carbon atoms | |
| US4908199A (en) | CO+H2 O catalytic conversions | |
| US4465893A (en) | Oxidative condensation of natural gas or methane into gasoline range hydrocarbons | |
| AU2002307548B2 (en) | Oxidative halogenation and optional dehydrogenation of C3+ hydrocarbons | |
| US4780449A (en) | Catalyst for the conversion of methane | |
| RU99107565A (ru) | Каталитическая композиция, пригодная для способа фишера-тропша | |
| EP0084564A1 (en) | ACID-BASED BIFUNCTIONAL CATALYZED CONVERSION OF HETERO-SUBSTITUTED METHANES TO OLEFINS. | |
| EP0227750A1 (en) | Method and catalyst for the conversion of methane | |
| DE69815149D1 (de) | Herstellung von olefinen | |
| JPH0729058B2 (ja) | 化学方法および触媒 | |
| EA000319B1 (ru) | Катализатор и способ получения углеводородов | |
| EA029026B1 (ru) | Катализатор и способ селективного получения низших углеводородов с1-с5 из синтез-газа с низким выходом метана и co | |
| Reddy et al. | Dehydrogenation of ethylbenzene to styrene with carbon dioxide over ZrO2-based composite oxide catalysts | |
| GB2065490A (en) | Methanation process and catalyst | |
| WO2018013349A1 (en) | Integrated process combining methane oxidative coupling and dry methane reforming | |
| US11141712B2 (en) | Catalyst for producing olefin having enhanced stability, conversion rate and selectivity, and preparation method thereof | |
| RU2002111560A (ru) | Способ извлечения сернистых соединений из газа | |
| KR101653429B1 (ko) | 파라핀계 저급 탄화수소의 산화적 탈수소반응 방법 | |
| JPS6270325A (ja) | 低級オレフインの製造方法 | |
| EP4662190A1 (en) | Process for mitigating a reaction of hydrogen bromide and an olefinically unsaturated compound | |
| AU777050B2 (en) | Process for the production of olefins | |
| US5384027A (en) | Reforming hydrocarbons using transition metal carbide catalyst and gaseous oxygen | |
| CN114656320A (zh) | 一种氧化脱氢制备低碳烯烃的方法及氧化锑的用途 | |
| AU2198101A (en) | Process for the production of olefins |