[go: up one dir, main page]

RU2001131721A - METHOD FOR PRODUCING ETHERIC ACID OR METHANOL ETHER AND THE CATALYST OF THIS METHOD - Google Patents

METHOD FOR PRODUCING ETHERIC ACID OR METHANOL ETHER AND THE CATALYST OF THIS METHOD

Info

Publication number
RU2001131721A
RU2001131721A RU2001131721/04A RU2001131721A RU2001131721A RU 2001131721 A RU2001131721 A RU 2001131721A RU 2001131721/04 A RU2001131721/04 A RU 2001131721/04A RU 2001131721 A RU2001131721 A RU 2001131721A RU 2001131721 A RU2001131721 A RU 2001131721A
Authority
RU
Russia
Prior art keywords
catalyst
alkali metal
formic acid
type catalyst
alkaline earth
Prior art date
Application number
RU2001131721/04A
Other languages
Russian (ru)
Other versions
RU2231521C2 (en
Inventor
Каору ФУДЗИМОТО
Норитацу ЦУБАКИ
Кенитиро ФУДЗИМОТО
Original Assignee
Ниппон Стил Корпорейшн
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ниппон Стил Корпорейшн filed Critical Ниппон Стил Корпорейшн
Publication of RU2001131721A publication Critical patent/RU2001131721A/en
Application granted granted Critical
Publication of RU2231521C2 publication Critical patent/RU2231521C2/en

Links

Claims (11)

1. Способ получения эфира муравьиной кислоты, включающий взаимодействие монооксида углерода со спиртом в присутствии катализатора типа щелочного металла, отличного от алкоксида щелочного металла, и/или катализатора типа щелочноземельного металла.1. A method of producing an ester of formic acid, comprising reacting carbon monoxide with an alcohol in the presence of an alkali metal type catalyst other than alkali metal alkoxide and / or an alkaline earth metal type catalyst. 2. Способ получения метанола, включающий взаимодействие монооксида углерода со спиртом в присутствии катализатора типа щелочного металла, отличного от алкоксида щелочного металла, и/или катализатора типа щелочноземельного металла с образованием эфира муравьиной кислоты, в котором в реакционной системе одновременно присутствует катализатор гидрогенолиза эфира муравьиной кислоты и водород для гидрирования образовавшегося эфира муравьиной кислоты с получением метанола.2. A method for producing methanol, comprising reacting carbon monoxide with alcohol in the presence of an alkali metal type catalyst other than alkali metal alkoxide and / or an alkaline earth metal type catalyst to form formic acid ester, in which formic acid ester hydrogenolysis catalyst is simultaneously present in the reaction system and hydrogen to hydrogenate the resulting formic acid ester to form methanol. 3. Способ получения метанола, включающий взаимодействие монооксида углерода со спиртом в присутствии катализатора типа щелочного металла, отличного от алкоксида щелочного металла, и/или катализатора типа щелочноземельного металла с образованием эфира муравьиной кислоты, выделение образовавшегося эфира муравьиной кислоты и гидрирование выделенного эфира муравьиной кислоты, при его контактировании с катализатором гидрогенолиза и водородом, с получением метанола.3. A method for producing methanol, comprising reacting carbon monoxide with alcohol in the presence of an alkali metal type catalyst other than alkali metal alkoxide and / or an alkaline earth metal type catalyst to form formic acid ester, isolating the formic acid ester formed and hydrogenating the isolated formic acid ester, when it is contacted with a hydrogenolysis catalyst and hydrogen, to produce methanol. 4. Способ получения метанола, включающий взаимодействие монооксида углерода со спиртом в присутствии катализатора типа щелочного металла, отличного от алкоксида щелочного металла, и/или катализатора типа щелочноземельного металла и катализатора, содержащего медь совместно с марганцем и/или рением для получения метанола из монооксида углерода и водорода.4. A method for producing methanol, comprising reacting carbon monoxide with an alcohol in the presence of an alkali metal type catalyst other than alkali metal alkoxide and / or an alkaline earth metal type catalyst and a catalyst containing copper together with manganese and / or rhenium to produce methanol from carbon monoxide and hydrogen. 5. Способ получения эфира муравьиной кислоты, включающий взаимодействие монооксида углерода со спиртом в присутствии катализатора, содержащего медь совместно с марганцем и/или рением.5. A method for producing an ester of formic acid, comprising reacting carbon monoxide with alcohol in the presence of a catalyst containing copper together with manganese and / or rhenium. 6. Способ по любому из пп.1-4, в котором катализатор типа щелочного металла, отличный от алкоксида щелочного металла, и катализатор типа щелочноземельного металла представляют собой катализатор, содержащий соль щелочного металла и катализатор, содержащий соль щелочноземельного металла, соответственно.6. The method according to any one of claims 1 to 4, wherein the alkali metal type catalyst other than alkali metal alkoxide and the alkaline earth metal type catalyst are a catalyst comprising an alkali metal salt and a catalyst comprising an alkaline earth metal salt, respectively. 7. Способ получения метанола по п.2 или 3, в котором катализатор гидрогенолиза является твердым, а используемый катализатор типа щелочного металла, отличный от алкоксида щелочного металла, и/или катализатор типа щелочноземельного металла, нанесен на указанный твердый катализатор.7. The method of producing methanol according to claim 2 or 3, in which the hydrogenolysis catalyst is solid, and the used alkali metal type catalyst other than alkali metal alkoxide, and / or an alkaline earth metal type catalyst, is supported on said solid catalyst. 8. Способ по любому из пп.1-5, в котором спирт представляет собой первичный спирт.8. The method according to any one of claims 1 to 5, in which the alcohol is a primary alcohol. 9. Катализатор для получения метанола, который получают путем нанесения катализатора типа щелочного металла, отличного от алкоксида щелочного металла, и/или катализатора типа щелочноземельного металла на твердый катализатор гидрогенолиза эфира муравьиной кислоты.9. A catalyst for producing methanol, which is obtained by depositing an alkali metal type catalyst other than alkali metal alkoxide and / or an alkaline earth metal type catalyst on a solid formic acid ester hydrogenolysis catalyst. 10. Катализатор для получения метанола, который состоит из катализатора типа щелочного металла, отличного от алкоксида щелочного металла, и/или катализатора типа щелочноземельного металла, а также катализатора, содержащего медь совместно с марганцем и/или рением.10. A catalyst for producing methanol, which consists of a catalyst such as an alkali metal other than alkali metal alkoxide, and / or a catalyst such as alkaline earth metal, and also a catalyst containing copper together with manganese and / or rhenium. 11. Катализатор для получения эфира муравьиной кислоты, содержащий медь совместно с марганцем и/или рением.11. A catalyst for producing an formic acid ester containing copper together with manganese and / or rhenium.
RU2001131721/04A 2000-02-25 2001-02-23 Method for preparing formic acid ester or methanol and catalyst for this method RU2231521C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2000050046 2000-02-25
JP2000-50046 2000-02-25

Publications (2)

Publication Number Publication Date
RU2001131721A true RU2001131721A (en) 2003-08-10
RU2231521C2 RU2231521C2 (en) 2004-06-27

Family

ID=18571884

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2001131721/04A RU2231521C2 (en) 2000-02-25 2001-02-23 Method for preparing formic acid ester or methanol and catalyst for this method

Country Status (10)

Country Link
US (2) US7208642B2 (en)
EP (1) EP1180511B1 (en)
JP (1) JP5067996B2 (en)
KR (2) KR100567039B1 (en)
CN (2) CN1275915C (en)
CA (1) CA2370793C (en)
DE (1) DE60139842D1 (en)
DK (1) DK1180511T3 (en)
RU (1) RU2231521C2 (en)
WO (1) WO2001062701A1 (en)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW592837B (en) * 2003-04-25 2004-06-21 Chung Shan Inst Of Science Photo-catalyst-coated air-cleaning fluorescent lamp and method for producing the same
WO2005030686A1 (en) * 2003-09-30 2005-04-07 Nippon Steel Corporation Method for producing organic compound
WO2006088253A1 (en) * 2005-02-21 2006-08-24 Nippon Steel Corporation Process for production of formic esters and methanol, catalysts for the production thereof, and process for production of the catalysts
US7608743B2 (en) 2005-04-15 2009-10-27 University Of Southern California Efficient and selective chemical recycling of carbon dioxide to methanol, dimethyl ether and derived products
CA2604574C (en) * 2005-04-15 2013-11-19 University Of Southern California Selective oxidative conversion of methane to methanol, dimethyl ether and derived products
WO2006113293A1 (en) * 2005-04-15 2006-10-26 University Of Southern California Efficient and selective conversion of carbon dioxide to methanol, dimethyl ether and derived products
US20060252959A1 (en) * 2005-05-05 2006-11-09 The Regents Of The University Of California Process for carbonylation of alkyl ethers
JP5264083B2 (en) * 2006-02-17 2013-08-14 新日鐵住金株式会社 Methanol synthesis catalyst, method for producing the catalyst, and method for producing methanol
JP5264084B2 (en) 2006-02-17 2013-08-14 新日鐵住金株式会社 Methanol synthesis catalyst, method for producing the catalyst, and method for producing methanol
JP4845530B2 (en) * 2006-02-17 2011-12-28 新日本製鐵株式会社 Methanol synthesis catalyst, method for producing the catalyst, and method for producing methanol
JP5127145B2 (en) * 2006-02-17 2013-01-23 新日鐵住金株式会社 Methanol synthesis catalyst, method for producing the catalyst, and method for producing methanol
US7378561B2 (en) * 2006-08-10 2008-05-27 University Of Southern California Method for producing methanol, dimethyl ether, derived synthetic hydrocarbons and their products from carbon dioxide and water (moisture) of the air as sole source material
US7795175B2 (en) 2006-08-10 2010-09-14 University Of Southern California Nano-structure supported solid regenerative polyamine and polyamine polyol absorbents for the separation of carbon dioxide from gas mixtures including the air
US7883318B2 (en) * 2007-04-05 2011-02-08 Joseph Voves Self-orienting, linear drive apparatus for harvesting power from the wind
US20140130670A1 (en) 2012-11-14 2014-05-15 Peter Eisenberger System and method for removing carbon dioxide from an atmosphere and global thermostat using the same
US8163066B2 (en) 2007-05-21 2012-04-24 Peter Eisenberger Carbon dioxide capture/regeneration structures and techniques
US8491705B2 (en) 2009-08-19 2013-07-23 Sunho Choi Application of amine-tethered solid sorbents to CO2 fixation from air
US9566574B2 (en) 2010-07-04 2017-02-14 Dioxide Materials, Inc. Catalyst mixtures
US20110237830A1 (en) 2010-03-26 2011-09-29 Dioxide Materials Inc Novel catalyst mixtures
US8956990B2 (en) 2010-03-26 2015-02-17 Dioxide Materials, Inc. Catalyst mixtures
US9957624B2 (en) 2010-03-26 2018-05-01 Dioxide Materials, Inc. Electrochemical devices comprising novel catalyst mixtures
US9790161B2 (en) 2010-03-26 2017-10-17 Dioxide Materials, Inc Process for the sustainable production of acrylic acid
US10173169B2 (en) 2010-03-26 2019-01-08 Dioxide Materials, Inc Devices for electrocatalytic conversion of carbon dioxide
US9193593B2 (en) 2010-03-26 2015-11-24 Dioxide Materials, Inc. Hydrogenation of formic acid to formaldehyde
US9815021B2 (en) 2010-03-26 2017-11-14 Dioxide Materials, Inc. Electrocatalytic process for carbon dioxide conversion
US9012345B2 (en) 2010-03-26 2015-04-21 Dioxide Materials, Inc. Electrocatalysts for carbon dioxide conversion
US9181625B2 (en) 2010-03-26 2015-11-10 Dioxide Materials, Inc. Devices and processes for carbon dioxide conversion into useful fuels and chemicals
PL2563495T3 (en) 2010-04-30 2020-05-18 Peter Eisenberger Method for carbon dioxide capture
US9028592B2 (en) 2010-04-30 2015-05-12 Peter Eisenberger System and method for carbon dioxide capture and sequestration from relatively high concentration CO2 mixtures
JP5626077B2 (en) * 2011-03-31 2014-11-19 新日鐵住金株式会社 Methanol production method and methanol production catalyst
CN102746145B (en) * 2012-07-19 2014-10-08 临海市联盛化学有限公司 Preparation method for ethyl formate
US11059024B2 (en) 2012-10-25 2021-07-13 Georgia Tech Research Corporation Supported poly(allyl)amine and derivatives for CO2 capture from flue gas or ultra-dilute gas streams such as ambient air or admixtures thereof
RU2015125054A (en) * 2012-11-26 2017-01-10 Басф Се METHOD FOR PRODUCING METHYL FORMAT BY INTERACTION OF METHANOL WITH CARBON MONOXIDE IN THE PRESENCE OF A CATALYTIC SYSTEM CONTAINING AN ALKALIUM METAL AND ALKALINE ALCOHOL
US8957244B2 (en) 2012-11-26 2015-02-17 Basf Se Process for preparing methyl formate by reaction of methanol with carbon monoxide in the presence of a catalyst system comprising alkali metal formate and alkali metal alkoxide
US10647652B2 (en) 2013-02-24 2020-05-12 Dioxide Materials, Inc. Process for the sustainable production of acrylic acid
MX389203B (en) * 2013-10-18 2025-03-20 Jx Nippon Oil & Energy Corp LUBRICANT OIL COMPOSITION.
WO2015103401A1 (en) 2013-12-31 2015-07-09 Eisenberger, Peter And Chichilnisky, Graciela, Jointly Rotating multi-monolith bed movement system for removing co2 from the atmosphere
CN103949268B (en) * 2014-04-17 2016-01-20 中国科学院山西煤炭化学研究所 The synthesis copper Mn catalyst of methyl formate and method for making and application
US10774431B2 (en) 2014-10-21 2020-09-15 Dioxide Materials, Inc. Ion-conducting membranes
US10975480B2 (en) 2015-02-03 2021-04-13 Dioxide Materials, Inc. Electrocatalytic process for carbon dioxide conversion
CN107973695A (en) * 2017-11-20 2018-05-01 中国科学院过程工程研究所 The method of non-substituted carbamate synthesizing methanol by hydrogenating and application
KR102489732B1 (en) * 2022-07-29 2023-01-18 한국화학연구원 Methyl formate continuous manufacturing process
KR102770386B1 (en) 2024-07-05 2025-02-21 최병렬 Methanol and dimethyl ether eco-friendly fuel production system using green hydrogen and carbon dioxide based on a high-efficiency compressor-reactor

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE863046C (en) * 1942-12-06 1953-01-15 Degussa Process for the preparation of esters of formic acid with aliphatic alcohols
DE926785C (en) * 1952-09-02 1955-04-25 Knapsack Ag Process for the continuous production of esters of formic acid by reacting carbon monoxide with aliphatic alcohols, in particular methyl alcohol
JPS5229998B2 (en) * 1973-03-14 1977-08-05
GB1511961A (en) * 1976-03-12 1978-05-24 Ucb Sa Process for the production of methyl formate
DE3037089A1 (en) * 1980-10-01 1982-05-06 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING METHYL FORMATE
JPS57128642A (en) * 1981-02-04 1982-08-10 Mitsui Petrochem Ind Ltd Synthesis of oxygen-containing organic compound
JPS60185879A (en) * 1984-02-29 1985-09-21 竹本油脂株式会社 Oil agent for producing carbon fiber
US4939292A (en) 1985-08-01 1990-07-03 Phillips Petroleum Company Synthesis of esters from alcohols containing carbon monoxide as an impurity
GB8708005D0 (en) 1987-04-03 1987-05-07 Shell Int Research Production of methanol
AU606742B2 (en) 1987-09-04 1991-02-14 Shell Internationale Research Maatschappij B.V. Process for the production of methanol and catalyst composition for said process
GB8722461D0 (en) 1987-09-24 1987-10-28 Shell Int Research Production of methhnol
PL157499B1 (en) 1988-03-16 1992-06-30 Inst Ciezkiej Syntezy Orga Method of obtaining a mixture of lower aliphatic alcohols from synthesis gases
DE3913387A1 (en) 1989-04-24 1990-10-25 Henkel Kgaa METHOD FOR THE CATALYTIC HYDRATION OF LIQUID FATTY ACID METHYL ESTERS
JP2958994B2 (en) 1989-11-07 1999-10-06 三菱瓦斯化学株式会社 Methanol dehydrogenation catalyst
US5221652A (en) 1991-03-26 1993-06-22 The University Of Pittsburgh Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite for methanol synthesis
DE4309731A1 (en) * 1993-03-25 1994-09-29 Basf Ag Process for the preparation of methyl formate
JPH07118187A (en) * 1993-10-25 1995-05-09 Mitsubishi Chem Corp Method for hydrogenating organic carboxylic acid and / or carboxylic ester
JPH0940610A (en) * 1995-07-26 1997-02-10 Mitsubishi Gas Chem Co Inc Method for producing methyl formate
JP3804697B2 (en) * 1997-01-08 2006-08-02 三菱瓦斯化学株式会社 Method for producing methyl formate
GB9720593D0 (en) 1997-09-26 1997-11-26 Exxon Chemical Patents Inc Catalysts and processes using them

Similar Documents

Publication Publication Date Title
RU2001131721A (en) METHOD FOR PRODUCING ETHERIC ACID OR METHANOL ETHER AND THE CATALYST OF THIS METHOD
US7081547B2 (en) Process for producing formic ester or methanol and synthesis catalyst therefor
Fan et al. Low-temperature methanol synthesis from carbon dioxide and hydrogen via formic ester
WO2001077054A3 (en) Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
US5883266A (en) Hydrogenated 5-carbon compound and method of making
TW200621697A (en) Process for preparing dimethyl ether from crude methanol in an adiabatic reactor
CN102464567B (en) Method for preparing isopropylbenzene by using hydrogenolysis alpha, alpha-dimethylbenzyl alcohol
EP0846671A3 (en) Production process for (poly) alkylene glycol monoalkyl ether
WO2003035582B1 (en) Hydrogenolysis of 6-carbon sugars and other organic compounds
EP1211234A3 (en) Process for preparing 1,3-alkandiols from 3-hydroxyesters
WO2003033140A3 (en) Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
DK1310172T3 (en) Process for the preparation of metal formate formic acid mixtures
CA2325478A1 (en) Process for production of acetic acid
RU2008134236A (en) CATALYST FOR METHANOL SYNTHESIS, METHOD FOR ITS PRODUCTION AND METHOD FOR PRODUCING METHANOL
CA2292651A1 (en) Vinyl acetate process utilizing a palladium-gold-copper catalyst
MY101210A (en) Process for producing fatty acids from lower alcohol ester of fatty acids.
Bricout et al. Homogeneous and Biphasic Nickel‐Catalyzed Isomerization of Allylic Alcohols
SU995705A3 (en) Process for preparing 5-fluoro-2-methyl-1-(methylsulfinyl-benzyledene)indenyl-3-acetic acid
US4126752A (en) Homologation of methanol with a carbon monoxide-water mixture
CN105085323B (en) Novel synthesis process of Darunavir intermediate
RU2008133565A (en) CATALYST FOR METHANOL SYNTHESIS, METHOD FOR ITS PRODUCTION AND METHOD FOR PRODUCING METHANOL
AU2001292243A1 (en) Process for producing fluorinated methyl-benzyl alcohol
JP5478510B2 (en) Method for producing alcohol compound
CA2076157A1 (en) Catalyst Used for Producing Carbonic Acid Esters and Methods of Producing Carbonic Acid Esters Using the Same
CA2520850A1 (en) Process for the preparation of a hydrogen-rich stream